JP2008208413A - High-strength titanium alloy billet for cold forging - Google Patents

High-strength titanium alloy billet for cold forging Download PDF

Info

Publication number
JP2008208413A
JP2008208413A JP2007045452A JP2007045452A JP2008208413A JP 2008208413 A JP2008208413 A JP 2008208413A JP 2007045452 A JP2007045452 A JP 2007045452A JP 2007045452 A JP2007045452 A JP 2007045452A JP 2008208413 A JP2008208413 A JP 2008208413A
Authority
JP
Japan
Prior art keywords
cross
cold forging
section
mass
cold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2007045452A
Other languages
Japanese (ja)
Other versions
JP5010309B2 (en
Inventor
Kazuhiro Takahashi
一浩 高橋
Hideki Fujii
秀樹 藤井
Hiroyuki Horimura
弘幸 堀村
Kousuke Doi
航介 土居
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honda Motor Co Ltd
Nippon Steel Corp
Original Assignee
Honda Motor Co Ltd
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honda Motor Co Ltd, Nippon Steel Corp filed Critical Honda Motor Co Ltd
Priority to JP2007045452A priority Critical patent/JP5010309B2/en
Publication of JP2008208413A publication Critical patent/JP2008208413A/en
Application granted granted Critical
Publication of JP5010309B2 publication Critical patent/JP5010309B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Forging (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a high-strength titanium alloy billet for cold forging which is a billet for cold forging with a cylindrical shape and is characterized in having ≥700 MPa tensile strength by addition of low-cost reinforcing elements and also having superior cold forgeability (deformability and isotropy of metal flow) and where pressing is applied in a direction of height of the cylindrical shape. <P>SOLUTION: Respective contents of Fe, O, N and C as low-cost reinforcing elements and an oxygen equivalent value Q are regulated to values within prescribed ranges, respectively, to secure ≥700 MPa tensile strength. A β-phase composed of a body-centered cubic crystal having many slip systems is made present to some extent by making Fe content to 0.5 to 1.3 mass% and integrated crystal orientation of an α-phase as a main phase is regulated so that it satisfies prescribed relations in view of the slip systems and a cold forging direction to obtain cold forgeability more excellent than conventional ones. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、引張強さが700MPa以上の高強度を有する、棒線に代表される円柱形を成すチタン合金製冷間鍛造用素材に関する。なお、この冷間鍛造用素材は、冷間鍛造工程において素材円柱形の高さ方向に圧縮加工が加わるものである。   The present invention relates to a material for cold forging made of a titanium alloy having a cylindrical shape typified by a rod having a high tensile strength of 700 MPa or more. In addition, this cold forging material is subjected to compression processing in the height direction of the material cylinder in the cold forging process.

ボルトやナットなどのファスナー類、自動車などのエンジン部品例えばバルブリテーナなどの部品は、軽量且つ高強度が要求されることから、チタン合金が適している。使用部位によって異なるもののチタンを使用して軽量化メリットを得るためには、低くとも700MPa、好ましくは750MPa以上の引張強さが求められている。代表的なα+β型チタン合金として、Ti−3Al−2.5VやTi−6Al−4Vがあるが、比較的高価な元素であるVを多量に含有していることから、決して廉価ではない。   Titanium alloys are suitable for fasteners such as bolts and nuts, and engine parts such as automobiles such as valve retainers because they are lightweight and require high strength. In order to obtain weight saving merit by using titanium, which differs depending on the use site, a tensile strength of at least 700 MPa, preferably 750 MPa or more is required. Typical α + β type titanium alloys include Ti-3Al-2.5V and Ti-6Al-4V, but they are not inexpensive because they contain a large amount of V, which is a relatively expensive element.

これに対して、AlもVも含有せず、比較的廉価な強化元素として、Fe,O,N等を含有したチタン合金が、特許文献1,特許文献2,特許文献3で提案されている。以降、[Fe]はFe含有量(質量%)、[O]はO含有量(質量%)、[N]はN含有量(質量%)を意味する。   In contrast, Patent Document 1, Patent Document 2, and Patent Document 3 propose titanium alloys containing neither Al nor V but containing Fe, O, N, etc. as relatively inexpensive reinforcing elements. . Hereinafter, [Fe] means Fe content (% by mass), [O] means O content (% by mass), and [N] means N content (% by mass).

特許文献1に記載の発明は、Feの含有量が0.1〜0.8質量%で、酸素等価量([O]+2.77「N」+0.1[Fe])が0.35〜1.0となるようにOとNの含有量(質量%)を調整し、さらにα+β二相等軸組織またはラメラー相状微細組織とすることによって、65kgf/mm2(637MPa)以上の引張強さとしたものである。特許文献1の図1と図2より、横軸の酸素等価値が約0.42以上で、引張強さは700MPa以上となり、その全伸びは約22〜25%以下である。 In the invention described in Patent Document 1, the Fe content is 0.1 to 0.8% by mass, and the oxygen equivalent amount ([O] +2.77 “N” +0.1 [Fe]) is 0.35 to The tensile strength of 65 kgf / mm 2 (637 MPa) or more is obtained by adjusting the content (mass%) of O and N so as to be 1.0, and further forming an α + β biphasic equiaxed structure or a lamellar phase microstructure. It is a thing. 1 and 2 of Patent Document 1, the oxygen equivalent value on the horizontal axis is about 0.42 or more, the tensile strength is 700 MPa or more, and the total elongation is about 22 to 25% or less.

特許文献2に記載の発明は、Feの含有量を0.9〜2.3質量%、Nの含有量を0.5質量%以下として、酸素等価量([O]+2.77「N」+0.1[Fe])が0.34〜1.00となるようにOの含有量を調整することによって、引張強さが700MPa以上で且つ伸びが15%以上の高強度・高延性とするものである。特許文献2の図1と図2より、横軸の酸素等価値が0.34以上で、引張強さは700MPa以上となり、その全伸びは約25〜27%以下である。さらに、引張強さが750MPa以上で全伸びは約25%以下、引張強さが850MPa以上で全伸びは15%以下になる。また、Fe含有量の一部をNi,Crで置換したものもある。   In the invention described in Patent Document 2, the Fe content is 0.9 to 2.3 mass%, the N content is 0.5 mass% or less, and the oxygen equivalent amount ([O] +2.77 “N”). By adjusting the O content so that +0.1 [Fe]) is 0.34 to 1.00, the tensile strength is 700 MPa or more and the elongation is 15% or more. Is. 1 and 2 of Patent Document 2, the oxygen equivalent value on the horizontal axis is 0.34 or more, the tensile strength is 700 MPa or more, and the total elongation is about 25 to 27% or less. Furthermore, when the tensile strength is 750 MPa or more, the total elongation is about 25% or less, and when the tensile strength is 850 MPa or more, the total elongation is 15% or less. In addition, some of the Fe content is substituted with Ni and Cr.

特許文献3に記載の発明は、Oを0.2〜0.8質量%、Cを0.01〜0.15質量%、Nを0.01〜0.07質量%、Feを0.3〜1.0質量%含有することによって、引張強さを750MPa以上とするものである。さらに、FeをNi,Crで置換したものもある。特許文献3の表1の実施例から、直径20mmの丸棒にて引張強さは753MPa以上で伸び(全伸び)は23.5%以下である。   In the invention described in Patent Document 3, O is 0.2 to 0.8 mass%, C is 0.01 to 0.15 mass%, N is 0.01 to 0.07 mass%, and Fe is 0.3 mass%. By containing ˜1.0% by mass, the tensile strength is 750 MPa or more. In addition, there are some in which Fe is replaced with Ni and Cr. From the Example of Table 1 of patent document 3, tensile strength is 753 Mpa or more and elongation (total elongation) is 23.5% or less with the round bar of diameter 20mm.

特開平1−252747号公報JP-A-1-252747 特許第3426605号公報Japanese Patent No. 3426605 特開2004−269982号公報JP 2004-269982 A

上述した部品類の多くは、高強度であるとともに、冷間鍛造によって創形されるため冷間鍛造性をも併せ持つことが要求される。冷間鍛造性のひとつは、所定の形状を得るための変形能を有することであり、この変形能は、材料の延性に呼応する他に、すべり変形方向が限定される稠密六方晶(以降、hcp)を有するチタンα相においてはhcpの集積方位の影響を受ける。なお、強化元素を添加したチタンα相では、軟質な工業用純チタンJIS1種やJIS2種のような双晶変形はほとんど起きず、すべり変形のみに限定される。   Many of the above-described parts are required to have both high strength and cold forgeability because they are formed by cold forging. One of the cold forgeability is to have a deformability for obtaining a predetermined shape. This deformability corresponds to the ductility of the material, and in addition to the dense hexagonal crystal (hereinafter referred to as a slip deformation direction). The titanium α phase having hcp) is affected by the hcp accumulation orientation. In addition, in the titanium α phase to which the strengthening element is added, twin deformation like soft industrial pure titanium JIS type 1 and JIS type 2 hardly occurs and is limited to slip deformation only.

また、実際の部品製造では、高い材料歩留を維持するために、冷間鍛造によるメタルフローの等方性が、変形能以上に冷間鍛造性の重要な因子となる。例えば、円柱形を成す素材を高さ方向に冷間鍛造したとき、円柱形底面(円形)の半径方向へのメタルフローに着目すると、メタルフローが等方的ならば材料は相似的に円形断面を維持したまま変形する。しかし、等方的でなく半径方向によってメタルフローに差異がある場合には、図1に示すように相似形の円形断面ではなく楕円形や角形になってしまう。そのために、冷間鍛造によって得ようとしている所定の形状に対して、メタルフローが不足したり、反対に部分的にオーバーフローしたり、材料歩留を低下させてしまう。   Moreover, in actual component manufacturing, in order to maintain a high material yield, the isotropy of the metal flow by cold forging becomes an important factor of cold forgeability more than deformability. For example, when cold forging a cylindrical material in the height direction, paying attention to the metal flow in the radial direction of the cylindrical bottom surface (circular), if the metal flow is isotropic, the material will have a similar circular cross section Deforms while maintaining However, when there is a difference in the metal flow depending on the radial direction rather than isotropic, it becomes an ellipse or a square instead of a similar circular section as shown in FIG. For this reason, the metal flow is insufficient with respect to a predetermined shape to be obtained by cold forging, or on the contrary, it partially overflows, and the material yield is reduced.

特許文献1,特許文献2,特許文献3は、廉価な強化元素を含有し700MPa以上の引張強さとある程度の延性(引張の全伸び)を有するものの、実際の成形部品を得るために施される冷間鍛造においては、円柱形素材をその高さ方向に冷間鍛造すると、成形形状によっては上述したような冷間鍛造性(変形能、メタルフローの等方性)が不十分な場合があり、課題である。   Patent Document 1, Patent Document 2, and Patent Document 3 contain an inexpensive reinforcing element and have a tensile strength of 700 MPa or more and a certain degree of ductility (total tensile elongation), but are applied to obtain an actual molded part. In cold forging, when cold forging a cylindrical material in its height direction, depending on the shape, cold forgeability (deformability, isotropic metal flow) may be insufficient. It is a problem.

そこで、本発明は、円柱形を成す冷間鍛造用素材であり、廉価な強化元素の添加によって700MPa以上の引張強さを有し、且つより優れた冷間鍛造性(変形能、メタルフローの等方性)を有することを特徴とする円柱形の高さ方向に圧縮加工が加わる高強度チタン合金製冷間鍛造用素材を提供することを目的とするものである。   Therefore, the present invention is a cold forging material having a cylindrical shape, has a tensile strength of 700 MPa or more by the addition of an inexpensive reinforcing element, and has better cold forgeability (deformability, metal flow). It is an object of the present invention to provide a material for cold forging made of high-strength titanium alloy in which compression is applied in the height direction of a cylindrical shape characterized by having isotropic properties.

上記課題を解決するために本発明の要旨は、以下のとおりである。
(1)質量%で、Feを0.5〜1.3%、Nを0.001〜0.05%、Cを0.001〜0.15%、Oを[1]式の酸素等価量Qが0.34〜0.55となる範囲で含有し、残部がTiおよび不可避的不純物からなる円柱形を成す冷間鍛造素材であり、且つチタンα相の各結晶面からのX線回折強度Iが、[2],[3],[4],[5]式の関係にあり、引張強さが700MPa以上であることを特徴とする冷間鍛造工程において円柱形の高さ方向に圧縮加工が加わる高強度チタン合金製冷間鍛造用素材。
酸素等価量Q=[O]+2.77[N]+0.086[Fe] ・・・[1]式
ここで、[O]はO含有量(質量%)、[N]はN含有量(質量%)、[Fe]はFe含有量(質量%)である。
円柱形のL断面において測定したX線回折強度Iの大小関係が、
I(0 0 0 2)>I(1 0 −1 0) ・・・[2]式
I(0 0 0 2)>I(1 0 −1 1) ・・・[3]式
円柱形のT断面において測定したX線回折強度Iの大小関係が、
I(1 0 −1 0)>I(0 0 0 2) ・・・[4]式
I(1 0 −1 0)>I(1 0 −1 1) ・・・[5]式
ここで、I(0 0 0 2)、I(1 0 −1 0)、I(1 0 −1 1)は、各々、稠密六方晶であるチタンα相の(0 0 0 2)面、(1 0 −1 0)面、
(1 0 −1 1)面からの回折強度である。なお、L断面とは円柱形素材の高さ方向に平行な長方形を成す断面であり、T断面とは円柱形素材の高さ方向に直交する円形を成す断面である。
(2)請求項1の高強度チタン合金製冷間鍛造用素材において、直径が16mm以下の冷間ヘッダー加工用のチタン合金棒線。
In order to solve the above problems, the gist of the present invention is as follows.
(1) In mass%, Fe is 0.5 to 1.3%, N is 0.001 to 0.05%, C is 0.001 to 0.15%, and O is an oxygen equivalent amount of the formula [1]. X-ray diffraction intensity from each crystal plane of the titanium α-phase, which is a cold forging material containing Q in a range of 0.34 to 0.55, and the balance being Ti and inevitable impurities I is in the relationship of the formulas [2], [3], [4], and [5], and the tensile strength is 700 MPa or more. Material for cold forging made of high-strength titanium alloy to which processing is applied.
Oxygen equivalent amount Q = [O] +2.77 [N] +0.086 [Fe] (1) formula [0] where [O] is the O content (mass%), and [N] is the N content ( Mass%) and [Fe] are Fe contents (mass%).
The magnitude relationship of the X-ray diffraction intensity I measured in the cylindrical L cross section is
I (0 0 0 2)> I (1 0 −1 0) (2) Formula I (0 0 0 2)> I (1 0 −1 1) (3) Formula Cylindrical T The magnitude relationship of the X-ray diffraction intensity I measured in the cross section is
I (1 0 −1 0)> I (0 0 0 2) (4) Formula I (1 0 −1 0)> I (1 0 −1 1) (5) Formula where I (0 0 0 2), I (1 0 −1 0), and I (1 0 −1 1) are respectively a (0 0 0 2) plane of a titanium α phase that is a dense hexagonal crystal, (1 0 − 1 0) plane,
It is the diffraction intensity from the (1 0 -1 1) plane. The L cross section is a cross section that forms a rectangle parallel to the height direction of the cylindrical material, and the T cross section is a cross section that forms a circle perpendicular to the height direction of the cylindrical material.
(2) A titanium alloy bar wire for cold header processing having a diameter of 16 mm or less in the high-strength titanium alloy cold forging material according to claim 1.

ここで、上記の円柱形を成す冷間鍛造用素材のL断面とT断面とは、具体的には図2に示す断面である。図2の(a),(b)が、各々、L断面とT断面に対応する。   Here, the L cross section and the T cross section of the cold forging material having the above-described columnar shape are specifically the cross sections shown in FIG. 2A and 2B correspond to the L cross section and the T cross section, respectively.

本発明によって、円柱形を成す冷間鍛造用素材において、廉価な強化元素の添加によって700MPa以上、さらには750MPa以上の引張強さを有し、且つより優れた冷間鍛造性(変形能、メタルフローの等方性)を有することを特徴とする円柱形の高さ方向に圧縮加工が加わる高強度チタン合金製冷間鍛造用素材を提供できる。これによって、軽量且つ高強度なチタン合金製冷間鍛造製部品を、従来よりも高い材料歩留を維持し且つ廉価に製造することができる。   According to the present invention, a cold forging material having a cylindrical shape has a tensile strength of 700 MPa or more, further 750 MPa or more by addition of an inexpensive strengthening element, and more excellent cold forgeability (deformability, metal) It is possible to provide a material for cold forging made of high-strength titanium alloy to which compression processing is applied in the height direction of a cylindrical shape characterized by having a flow isotropic property. This makes it possible to manufacture a lightweight and high-strength titanium alloy cold forged part while maintaining a higher material yield and at a lower cost than in the past.

本発明者らは、廉価な強化元素であるFe,O,N,Cの添加とチタンα相(hcp)の結晶方位制御によって、700MPa以上の引張強さとより優れた冷間鍛造性(変形能、メタルフローの等方性)を兼ね備えた円柱形を成す高強度チタン合金製冷間鍛造用素材について鋭意研究を重ねた。その結果、Fe,O,N,Cの含有量と上述の[1]式の酸素等価量Qによって700MPa以上の引張強さを確保し、Fe含有量を0.5〜1.3質量%とすることによって多くのすべり系を有する体心立方晶(以降 bcc)からなるβ相をある程度存在させるとともに、主な相であるα相(hcp)の集積結晶方位をそのすべり系と冷間鍛造方向を考慮して上述の[2],[3],[4],[5]式のように制御することによって、従来よりも優れた冷間鍛造性(変形能、メタルフローの等方性)が得られることを見出した。   The inventors have added a tensile strength of 700 MPa or more and better cold forgeability (deformability) by adding inexpensive reinforcing elements Fe, O, N, C and controlling the crystal orientation of the titanium α phase (hcp). In addition, we conducted extensive research on a cold-forging material made of high-strength titanium alloy that has a cylindrical shape that combines the isotropic nature of metal flow. As a result, the tensile strength of 700 MPa or more is secured by the content of Fe, O, N, C and the oxygen equivalent amount Q of the above-mentioned formula [1], and the Fe content is 0.5 to 1.3% by mass. As a result, a β phase composed of body-centered cubic crystals (hereinafter referred to as bcc) having many slip systems is present to some extent, and the accumulated crystal orientation of the main phase α phase (hcp) is determined by the slip system and the cold forging direction. In consideration of the above, by controlling as in the above formulas [2], [3], [4], [5], cold forgeability (deformability, isotropic metal flow) superior to conventional ones It was found that can be obtained.

以下に本発明の各要素の設定根拠について説明する。   The basis for setting each element of the present invention will be described below.

まず、Fe,N,O,Cを含有した高強度チタン合金において、α相(hcp)の集積結晶方位を制御することによって冷間鍛造性を向上できることについて説明する。   First, it will be described that in a high-strength titanium alloy containing Fe, N, O, and C, the cold forgeability can be improved by controlling the α-phase (hcp) integrated crystal orientation.

冷間鍛造素材となる円柱形試料のL断面とT断面からのX線回折強度の大小関係が、図3のパターンの場合には、高さ方向に圧縮した際のメタルフローの等方性が非常に良好であり、且つ材料強度の上昇に伴う変形能の低下が抑制される。直径10.5mmで高さ7mmの円柱形試料を用いて高さ方向に圧縮すると、圧縮後の長径と短径の差が、3.5mm圧縮時に0.5mm以下、4.5mm圧縮時に0.65mm以下と小さく、これは圧縮後の平均直径に対して±1.6%以下に相当する。ここで、図1に示したように、高さ方向に圧縮した後、図1(b)の斜線断面部の直径をノギスで測定し、最大値を長径、最小値を短径とした。後述するが、変形能に対応する限界据え込み率は、所定の成分範囲においては材料強度が上昇しても70%以上を維持できる。   In the case of the pattern of FIG. 3 in which the magnitude relationship between the X-ray diffraction intensity from the L cross section and the T cross section of the cylindrical sample that is a cold forging material, the metal flow isotropic when compressed in the height direction. It is very good, and a decrease in deformability accompanying an increase in material strength is suppressed. When a cylindrical sample having a diameter of 10.5 mm and a height of 7 mm is used and compressed in the height direction, the difference between the major axis and the minor axis after compression is 0.5 mm or less when 3.5 mm is compressed, and is 0. As small as 65 mm or less, this corresponds to ± 1.6% or less of the average diameter after compression. Here, as shown in FIG. 1, after compressing in the height direction, the diameter of the cross-sectional area of the hatched line in FIG. 1 (b) was measured with calipers, and the maximum value was the major axis and the minimum value was the minor axis. As will be described later, the limit upsetting rate corresponding to the deformability can be maintained at 70% or more in the predetermined component range even if the material strength is increased.

なお、図3のパターンにおいて、相対的な強度比に多少違いがあっても、上述の[2],[3],[4],[5]式の大小関係を満たすものであれが、上述の優れた冷間鍛造性を成し得た。   In the pattern of FIG. 3, even if there is a slight difference in the relative intensity ratio, the above-described [2], [3], [4], and [5] satisfy the magnitude relationship of the above expressions. It was possible to achieve excellent cold forgeability.

上記の冷間鍛造性に優れる理由は、以下の通りである。図3のパターンは、hcpのC軸が円柱形を成す冷間鍛造用素材の円周方向に多く揃っていると解釈できる。hcpのすべり方向はhcpのC軸に直交することが知られている。円柱形素地を高さ方向に圧縮したとき、図3のパターンはα相(hcp)のすべり方向が半径方向に多く揃っており、円柱形の半径方向にすべり変形が起きやすいためである。   The reason why the cold forgeability is excellent is as follows. The pattern in FIG. 3 can be interpreted as having many ccp axes in the circumferential direction of the cold forging material having a cylindrical shape. It is known that the sliding direction of hcp is perpendicular to the C axis of hcp. This is because, when the cylindrical substrate is compressed in the height direction, the α-phase (hcp) slip direction is more aligned in the radial direction in the pattern of FIG. 3, and slip deformation tends to occur in the cylindrical radial direction.

一方、図4のパターンの場合には、同様に円柱形試料を高さ方向に圧縮すると、長径と短径の差が、3.5mm圧縮時に0.6mm以上、4.5mm圧縮時に1mm以上と大きく、これは圧縮後の平均直径に対して±2〜2.7%以上に相当する。冷間鍛造ままの形状で使用することを想定すると、1mmにも及ぶ差異は製品精度としては不十分である。また、変形能に対応する限界据え込み率は、材料強度の上昇に伴いこれに呼応して低下する傾向にある。このように、図4のパターンの場合には、十分な高い冷間鍛造性を確保できなくなる。図4のパターンは、hcpのC軸が円柱形の半径方向に多く揃っていることを示しており、この場合、高さ方向に圧縮した際に半径方向に材料がフローできるすべり系が極めて少ないためである。   On the other hand, in the case of the pattern of FIG. 4, when the cylindrical sample is similarly compressed in the height direction, the difference between the major axis and the minor axis is 0.6 mm or more at 3.5 mm compression and 1 mm or more at 4.5 mm compression. It is large, which corresponds to ± 2 to 2.7% or more with respect to the average diameter after compression. Assuming that the cold forging is used, a difference of up to 1 mm is insufficient for product accuracy. Further, the limit upsetting rate corresponding to the deformability tends to decrease in response to the increase in material strength. Thus, in the case of the pattern of FIG. 4, it becomes impossible to ensure sufficiently high cold forgeability. The pattern of FIG. 4 shows that the hcp C-axis is aligned in the radial direction of the cylinder, and in this case, there are very few slip systems in which the material can flow in the radial direction when compressed in the height direction. Because.

ここで、図3、図4は、円柱形試料のL断面とT断面において、チタンα相(hcp)の各面からのX線回折強度を相対強度で図示したもので、X線回折測定にはCu管球を用いた。また、以上のhcp集積方位による冷間鍛造性の違いは、焼鈍温度が750℃と800℃の両方で同様であり、焼鈍温度の影響は極めて小さかった。   Here, FIG. 3 and FIG. 4 illustrate the X-ray diffraction intensity from each surface of the titanium α phase (hcp) as relative intensity in the L cross section and the T cross section of the cylindrical sample. Used a Cu tube. Further, the difference in cold forgeability due to the above hcp accumulation orientation was the same at both annealing temperatures of 750 ° C. and 800 ° C., and the influence of the annealing temperature was extremely small.

なお、上述の圧縮試験に用いた円柱形試料は、種々条件(温度、加工率、圧下スケジュールなど)にて熱間圧延した棒線を、または更に冷間伸線を加えた棒線を焼鈍した素材から、機械加工して作製した。   In addition, the cylindrical sample used for the above-mentioned compression test annealed the bar wire which carried out hot rolling on various conditions (temperature, a processing rate, a rolling schedule, etc.), or the bar wire which added cold drawing further. Made from material by machining.

以上のことから、図3のパターンの大小関係において、優れた冷間鍛造性を有することから、本発明の請求項1では[2],[3],[4],[5]式の大小関係を満たすものとする。   From the above, because of the excellent cold forgeability in the pattern size relationship of FIG. 3, in claim 1 of the present invention, the sizes of the equations [2], [3], [4], and [5] Satisfy the relationship.

また、図3のパターン([2],[3],[4],[5]式の関係)を満たす素材は、L断面とT断面のビッカース硬さに差があり、L断面の方がT断面よりも約10〜30ポイント大きいといった特徴を有する。これは、α相のhcp底面が集積している面ほど硬いことから、図3のようなhcpの方位集積を現した結果である。   In addition, materials satisfying the pattern of FIG. 3 (relationships of equations [2], [3], [4], and [5]) have a difference in Vickers hardness between the L cross section and the T cross section. It is characterized by being about 10 to 30 points larger than the T section. This is the result of the hcp orientation accumulation as shown in FIG. 3 because the α-phase hcp bottom surface is harder.

図3の特徴を有する棒線は、棒線を熱間圧延する際に圧延後段に740〜840℃の温度域で断面減少率が50%以上の加工が施されており、仕上げ圧延に相当する圧延後段において比較的狭い温度範囲である程度大きな加工量の棒線圧延を実施することが重要である。一方、図4に代表される図3とは異なるパターンを有する棒線は、温度域が上記範囲を外れているか断面減少率が小さいかのいずれかであった。   The bar wire having the characteristics shown in FIG. 3 corresponds to finish rolling, in which, when the bar wire is hot-rolled, the post-rolling stage is processed with a cross-section reduction rate of 50% or more in a temperature range of 740 to 840 ° C. It is important to carry out bar rolling with a relatively large processing amount in a relatively narrow temperature range in the latter stage of rolling. On the other hand, the bar wire having a pattern different from that of FIG. 3 represented by FIG. 4 has either a temperature range outside the above range or a small cross-sectional reduction rate.

次に、図3のパターン([2],[3],[4],[5]式の関係)を満たすものにおいて、本発明の成分範囲について説明する。   Next, the component range of the present invention will be described in the case of satisfying the pattern of FIG. 3 (relationship of [2], [3], [4], [5] equations).

Feはbccであるチタンβ相を安定化させる置換型元素である。bccはhcpに比べて多くのすべり系を有することから冷間加工性の改善に寄与する。冷間鍛造性を向上させるためには、Fe含有量は0.5質量%以上が必要である。なお、より冷間鍛造性を安定して高めることから、Fe含有量は0.8質量%を超えるものが好ましい。   Fe is a substitutional element that stabilizes the titanium β phase which is bcc. Since bcc has many slip systems compared with hcp, it contributes to the improvement of cold workability. In order to improve the cold forgeability, the Fe content needs to be 0.5% by mass or more. In addition, in order to improve cold forgeability more stably, the Fe content is preferably more than 0.8% by mass.

一方、Feは凝固時に偏析しやすいことから、多量に含有すると、成分偏析によって冷間鍛造時のメタルフローの等方性が損なわれる場合がある。冷間鍛造時の等方的なメタルフローを確保する観点から、従来と同等以上にFe偏析に留意する必要があり、本発明ではFe含有量を1.3質量%以下とする。   On the other hand, since Fe is easily segregated during solidification, if it is contained in a large amount, the isotropy of metal flow during cold forging may be impaired due to component segregation. From the viewpoint of securing an isotropic metal flow during cold forging, it is necessary to pay attention to Fe segregation as much as or more than before, and in the present invention, the Fe content is set to 1.3% by mass or less.

高強度化のために、N,O,Cの含有量を増すと、α相(hcp)の集積方位が図3のパターン([2],[3],[4],[5]式の関係)を満たすものであっても、ある含有量を超えると、強度の上昇に呼応して冷間鍛造性が低下してしまう。本発明では図3の大小関係にあるα相の方位集積とすることによって、高さ方向の圧縮に対してα相のすべり変形が容易になるようにしており、高強度化に伴う変形能の低下を補っている。しかし、本発明の含有量の範囲を超えると、変形能の低下の方が支配的となり、α相の結晶方位集積による効果では不十分となるためである。以上のことから、引張強さ700MPa以上で且つ上述のような優れた冷間鍛造性が得られる成分範囲として、本発明の請求項1では、質量%で、Feを0.5〜1.3%、Nを0.001〜0.05%、Cを0.001〜0.15%、Oを[1]式の酸素等価量Qが0.34〜0.55となる範囲で含有することとした。好ましくは、より高強度であっても優れた冷間鍛造性が維持されることから、質量%で、Feの含有量が0.8%を超え1.3%以下で、Nを0.001〜0.04%、Cを0.001〜0.05%、Oを[1]式の酸素等価量Qが0.37〜0.5となる範囲とする。   When the content of N, O, and C is increased to increase the strength, the accumulation direction of the α phase (hcp) is changed to the pattern of [2], [3], [4], and [5] in FIG. Even if satisfying the relationship), if it exceeds a certain content, the cold forgeability decreases in response to the increase in strength. In the present invention, the α phase orientation accumulation having the magnitude relationship shown in FIG. 3 is adopted, so that the α phase slip deformation becomes easier with respect to the compression in the height direction, and the deformability accompanying the increase in strength is improved. Make up for the decline. However, when the content range of the present invention is exceeded, the lowering of the deformability becomes dominant, and the effect of the α-phase crystal orientation accumulation becomes insufficient. From the above, as a component range in which the tensile strength is 700 MPa or more and the above-described excellent cold forgeability is obtained, in claim 1 of the present invention, Fe is 0.5 to 1.3 by mass%. %, N is 0.001 to 0.05%, C is 0.001 to 0.15%, and O is contained in a range where the oxygen equivalent amount Q of the formula [1] is 0.34 to 0.55. It was. Preferably, since excellent cold forgeability is maintained even at higher strength, the Fe content is more than 0.8% and not more than 1.3% by mass%, and N is 0.001. -0.04%, C is 0.001-0.05%, and O is the range where the oxygen equivalent amount Q of the formula [1] is 0.37-0.5.

なお、本発明のチタン合金は通常の純チタンまたはチタン合金と同様に、H,Ni,Cr,Mo,Mn,Si,S等を不可避的に含有するが、その含有量は一般的には各々0.05質量%未満である。但し、本発明の効果を損なわない限り、その含有量は0.05質量%未満の限りではない。   The titanium alloy of the present invention inevitably contains H, Ni, Cr, Mo, Mn, Si, S, etc., as in the case of ordinary pure titanium or titanium alloy. It is less than 0.05% by mass. However, as long as the effects of the present invention are not impaired, the content is not limited to less than 0.05% by mass.

また、α相を本発明の集積方位にすることによって、円柱形素材の高さ方向に引張試験を実施した場合、その全伸びは25〜30%以上と従来(特許文献1,2,3)よりも高位に位置する。本発明の成分範囲において、焼鈍状態で引張強さは700MPa以上さらに750MPaを超え850MPa程度までは高められるが、それでも全伸びは25〜30%を維持できており、本発明によって高強度化に伴う伸びの低下を抑制できる。   Further, when the α phase is set to the accumulating orientation of the present invention, when a tensile test is performed in the height direction of the cylindrical material, the total elongation is 25 to 30% or more in the past (Patent Documents 1, 2, and 3). It is located higher than. In the component range of the present invention, the tensile strength in the annealed state is 700 MPa or more, further increased to over 750 MPa and to about 850 MPa, but the total elongation can still be maintained at 25 to 30%. Decrease in elongation can be suppressed.

冷間鍛造の際に金型にかかる許容荷重は、金型の材質から限界がある。円柱形をなす冷間鍛造用素材の直径を16mm以下に限定することによって、金型への負荷荷重を小さくすることができ、金型材質および鍛造形状の両自由度が増し、本発明の効果を最大限に活かすことができる。また、冷間鍛造のうち冷間ヘッダー加工は、棒線素材からの連続加工であるため生産性が非常に高い。その一方で、変形の均一性、変形の安定性、発生するバリの大きさなど、素材に対してより高いレベルが要求される。以上の点から、本発明の請求項2では、請求項1の高強度チタン合金製冷間鍛造用素材において、直径が16mm以下の冷間ヘッダー加工用のチタン合金棒線とする。   The allowable load applied to the mold during cold forging is limited by the material of the mold. By limiting the diameter of the cold forging material in the form of a cylinder to 16 mm or less, the load applied to the mold can be reduced, and the freedom of both the mold material and the forging shape is increased, and the effects of the present invention are achieved. Can make the most of it. Further, in cold forging, the cold header processing is a continuous processing from a bar wire material, so the productivity is very high. On the other hand, higher levels are required for the material, such as uniformity of deformation, stability of deformation, and the size of burrs generated. In view of the above, in claim 2 of the present invention, the high strength titanium alloy cold forging material of claim 1 is a titanium alloy rod for cold header processing having a diameter of 16 mm or less.

本発明を、以下の実施例を用いて詳細に説明する。   The invention is explained in detail using the following examples.

表1に、実施例である棒線の、成分(Fe,O,N,C)、酸素等価量Q([1]式)、α相のhcp各結晶面からのX線回折強度の大小関係([2]〜[5]式)、断面ビッカース硬さ(L断面とT断面およびその差)を示す。表2に、その引張強さ、全伸び、円柱形素材の限界据え込み率、長径と短径の差を示す。   Table 1 shows the magnitude relationship between the component (Fe, O, N, C), the oxygen equivalent amount Q (formula [1]), and the X-ray diffraction intensity from each hcp crystal plane of the α-phase. ([2] to [5] formulas) and cross-section Vickers hardness (L cross-section and T cross-section and their differences). Table 2 shows the tensile strength, total elongation, the limit upsetting rate of the cylindrical material, and the difference between the major axis and the minor axis.

Figure 2008208413
Figure 2008208413

Figure 2008208413
Figure 2008208413

表1に示す実施例は、インゴットを熱間鍛造、熱間圧延して、直径13mmに加工した棒線を、750℃で焼鈍した。X線回折強度はCu管球を用いて測定した。断面ビッカース硬さは、荷重9.8Nで断面内を表面から1mm間隔で全直径範囲を測定し、その平均値を求めた。引張強さと全伸びは、平行部が直径6.25mm、長さが32mmに加工した試験片を用いて、標点間距離25mmで引張試験を行い測定した。   The Example shown in Table 1 annealed at 750 degreeC the rod wire which hot-forged and hot-rolled the ingot and was processed into diameter 13mm. X-ray diffraction intensity was measured using a Cu tube. The cross-section Vickers hardness was determined by measuring the entire diameter range at 1 mm intervals from the surface within the cross-section with a load of 9.8 N, and calculating the average value. Tensile strength and total elongation were measured by performing a tensile test at a distance between gauge points of 25 mm using a test piece having a parallel part with a diameter of 6.25 mm and a length of 32 mm.

限界据え込み率は、加工した直径10.5mmで高さ7mmの円柱形素材で用いて、高さ方向に圧縮量を0.5mm間隔で変えて圧縮した後、その表面を肉眼で観察して割れの有無を評価した。円柱形を高さ方向に圧縮した後の長径と短径の差は、加工した直径10.5mmで高さ7mmの円柱形素材を、圧縮量3.5mmと4.5mmで高さ方向に圧縮した後にノギスを用いて測定した。なお、圧縮量4.5mmの場合、一部は限界据え込み率を超えて圧縮後に割れが観察されたため、長径と短径の測定を行わなかった。   The limit upsetting rate is a cylindrical material with a processed diameter of 10.5 mm and a height of 7 mm. After compressing the compression amount in the height direction at intervals of 0.5 mm, the surface is observed with the naked eye. The presence or absence of cracks was evaluated. The difference between the major axis and the minor axis after compressing the cylindrical shape in the height direction is that the processed cylindrical material with a diameter of 10.5 mm and a height of 7 mm is compressed in the height direction with a compression amount of 3.5 mm and 4.5 mm. After that, it was measured using calipers. In the case of a compression amount of 4.5 mm, since some cracks were observed after compression exceeding the limit upsetting rate, measurement of the major axis and the minor axis was not performed.

発明例である試料No.3−1,4,5,6,7−1,8,9,10−1,11,12,13−1,14,15−1は、引張強さが700MPa以上で限界据え込み率が70%以上と高く、長径と短径の差は3.5mm圧縮時に0.5mm以下、4.5mm圧縮時に0.65mm以下と極めて小さく、メタルフローの等方性も良好である。なお、成分が、上述した好ましい範囲(質量%でFeが0.8%を超え1.3%以下、Nが0.001〜0.04%、Cが0.001〜0.05%、Oを[1]式の酸素等価量Qが0.37〜0.5)で、且つ、X線回折強度の大小関係が[2]〜[5]式の関係を満たす試料No.6,7−1,8,9,10−1,11,12は、その引張強さが750MPa以上とより高く、冷間鍛造性も非常に良好である。   Sample No. which is an example of the invention. 3-1, 4, 5, 6, 7-1, 8, 9, 10-1, 11, 12, 13-1, 14, 15-1 have a tensile strength of 700 MPa or more and a limit upsetting ratio of 70. The difference between the major axis and the minor axis is as small as 0.5 mm or less when compressed to 3.5 mm and 0.65 mm or less when compressed to 4.5 mm, and the isotropy of the metal flow is also good. In addition, a component is the preferable range mentioned above (Fe exceeds 0.8% and 1.3% or less by mass%, N is 0.001-0.04%, C is 0.001-0.05%, O Sample No. 1 in which the oxygen equivalent amount Q of the formula [1] is 0.37 to 0.5) and the X-ray diffraction intensity magnitude relationship satisfies the relationships of the formulas [2] to [5] 6,7-1,8,9,10-1,11,12 has a higher tensile strength of 750 MPa or more and a very good cold forgeability.

Qが0.3と本発明の下限を切っている試料No.1は引張強さが700MPaに満たない。試料No.2は、Qが0.43で引張強さが776MPaであるが、Feが0.34質量%と本発明の下限値を外れており、限界据え込み率が64.3%と、同等の引張強さを有する発明例(試料No.7−1,8,9)に比べて低い。一方で、N,C,Qが本発明の上限を超えている試料No.16−1,16−2,17は、X線回折強度の大小関係が本発明の条件を満たしていても、限界据え込み率が50%と低く、冷間鍛造性が良好ではない。   Sample No. Q is 0.3, which is below the lower limit of the present invention. No. 1 has a tensile strength of less than 700 MPa. Sample No. 2 has a Q of 0.43 and a tensile strength of 776 MPa, but Fe is 0.34% by mass, which is outside the lower limit of the present invention, and the limit upsetting rate is 64.3%, which is the same tensile strength. It is low compared with the invention example (sample No.7-1, 8, 9) which has strength. On the other hand, sample No. N, C, Q exceeded the upper limit of the present invention. 16-1, 16-2, and 17 have a limit upsetting ratio as low as 50% even when the magnitude relationship of the X-ray diffraction intensity satisfies the conditions of the present invention, and the cold forgeability is not good.

成分が本発明の範囲内であっても、X線回折強度の大小関係が[2]〜[5]式を満たしていない試料No.3−2,7−2,10−2,13−2,15−2は、同じ成分の本発明例(No.3−1,7−1,10−1,13−1,15−1)に比べて、限界据え込み率が低く、長径と短径の差は3.5mm圧縮時に0.6mmを、4.5mm圧縮時に1mmを越えている。   Even if the component is within the range of the present invention, the sample No. 2 in which the magnitude relationship of the X-ray diffraction intensity does not satisfy the equations [2] to [5]. 3-2, 7-2, 10-2, 13-2, 15-2 are examples of the present invention having the same components (No. 3-1, 7-1, 10-1, 13-1, 15-1). In comparison, the marginal upsetting ratio is low, and the difference between the major axis and the minor axis exceeds 0.6 mm when compressed by 3.5 mm and exceeds 1 mm when compressed by 4.5 mm.

ここで、X線回折強度の大小関係が本発明の条件を満たしている試料No.3−1,4,5,6,7−1,8,9,10−1,11,12,13−1,14,15−1は、棒線の熱間圧延の際に、その圧延後段に740〜840℃の温度域で断面減少率が50%以上の加工が施されており、一方、X線回折強度の大小関係が本発明の条件を満たしていない試料No.3−2,7−2,10−2,13−2,15−2は、温度域が上記範囲を外れているか断面減少率が小さいかのいずれかであった。   Here, Sample No. whose X-ray diffraction intensity magnitude relationship satisfies the conditions of the present invention. 3-1,4,5,6,7-1,8,9,10-1,11,12,13-1,14,15-1 are the post-rolling stages during hot rolling of bar wires. In the temperature range of 740 to 840 ° C., the cross-sectional reduction rate is 50% or more, while the X-ray diffraction intensity magnitude relationship does not satisfy the conditions of the present invention. 3-2, 7-2, 10-2, 13-2, and 15-2 were either in the temperature range outside the above range or the cross-section reduction rate was small.

本発明について、以下の実施例を用いて更に詳細に説明する。   The present invention will be described in further detail using the following examples.

表3と表4に、表1の試料No.6および試料No.9と同じ成分組成である種々棒線において、その加工・焼鈍工程とその特性を示す。試料No.A−1〜A−4は試料No.6と、試料No.B−1〜B−8は試料No.9と同じ成分である。表3に、各々の加工・焼鈍工程、X線回折強度の大小関係、断面ビッカース硬さを、表4に、その引張強さ、全伸び、冷間鍛造性を示す。   Tables 3 and 4 show the sample Nos. 6 and sample no. 9 shows the processing / annealing process and characteristics of various bar wires having the same component composition as No. 9. Sample No. A-1 to A-4 are sample Nos. 6 and sample no. B-1 to B-8 are sample Nos. 9 is the same component. Table 3 shows the respective processing / annealing steps, the magnitude relationship of the X-ray diffraction intensity, and the cross-section Vickers hardness. Table 4 shows the tensile strength, total elongation, and cold forgeability.

Figure 2008208413
Figure 2008208413

Figure 2008208413
Figure 2008208413

ここで、伸線率が62%の線材はその直径が8mmである。そのため、引張試験には平行部の直径が4mmの引張試験片を用いた。また、冷間鍛造性(限界据え込み率、メタルフローの等方性)の評価には、直径7.5mm、高さ5mmの円柱形試験片を用いており、この形状は他の太い棒線を評価した試料(直径10.5mm、高さ7mm)と相似形である。   Here, the wire having a drawing rate of 62% has a diameter of 8 mm. Therefore, a tensile test piece having a parallel part diameter of 4 mm was used for the tensile test. In addition, for the evaluation of cold forgeability (limit upsetting rate, metal flow isotropic), a cylindrical specimen having a diameter of 7.5 mm and a height of 5 mm is used, and this shape is another thick bar wire. It is similar to the sample (diameter 10.5 mm, height 7 mm) evaluated.

なお、長径と短径の差は、[実施例1]と同様に、高さを50%圧縮した後(直径10.5で高さ7mmの試験片は3.5mm圧縮、直径7.5mmで高さ5mmの試験片では2.5mm圧縮)、および高さ約64%圧縮した後(直径10.5で高さ7mmの試験片は4.5mm圧縮、直径7.5mmで高さ5mmの試験片では3.2mm圧縮)に測定した。   The difference between the major axis and the minor axis is the same as in [Example 1], after compressing the height by 50% (the test piece having a diameter of 10.5 and a height of 7 mm is compressed by 3.5 mm and the diameter is 7.5 mm. For a 5 mm high test piece, 2.5 mm compression) and after about 64% height compression (10.5 diameter and 7 mm high test piece, 4.5 mm compression, 7.5 mm diameter and 5 mm high test) It measured to 3.2 mm compression in the piece.

表4に示したように、本発明の範囲にある試料No.A−1,A−2およびNo.B−1,B−2,B−3,B−4は、引張強さが750MPa以上と高く、限界据え込み率が78%以上、長径と短径の差が高さ50%圧縮後で0.5mm以下、高さ約64%圧縮後は0.65mm以下である。これに対して、同一の成分であっても、X線回折強度の大小関係が本発明の条件を満たしていない試料No.A−3,A−4およびNoB−5,B−6,B−7,B−8は、限界据え込み率が約64%と低く、長径と短径の差が大きい。なお、直径が8mmと小さい棒線である試料No.B−4とB−8は、他と比較して長径と短径の差が小さい値である。これは圧縮試験を実施した試験片のサイズが小さいためである。長径と短径の差(絶対値)そのものも発明例である試料No.B−4の方が小さいが、圧縮後の平均直径に対する比率で比較すると、発明例である試料No.B−4は±1.5%、比較例である試料No.B−8は±2.4%であり、各々、他の発明例、他の比較例と同程度の値である。ここで、X線回折強度の大小関係が本発明の条件を満たしている試料No.A−1,A−2およびNo.B−1,B−2,B−3,B−4は、棒線の熱間圧延の際に、その圧延後段に740〜840℃の温度域で断面減少率が50%以上の加工が施されており、一方、X線回折強度の大小関係が本発明の条件を満たしていない試料No.A−3,A−4およびNoB−5,B−6,B−7,B−8は、温度域が上記範囲を外れているか断面減少率が小さいかのいずれかであった。   As shown in Table 4, sample Nos. Within the scope of the present invention. A-1, A-2 and No. B-1, B-2, B-3, and B-4 have a high tensile strength of 750 MPa or more, a limit upsetting ratio of 78% or more, and a difference between the major axis and the minor axis is 0% after compression by 50% in height. 0.5 mm or less, height is about 64%, and after compression is 0.65 mm or less. On the other hand, even for the same component, the sample No. whose X-ray diffraction intensity magnitude relationship does not satisfy the conditions of the present invention. A-3, A-4, and NoB-5, B-6, B-7, and B-8 have a low limit upsetting rate of about 64% and a large difference between the major axis and the minor axis. In addition, sample no. B-4 and B-8 are values in which the difference between the major axis and the minor axis is small compared to others. This is because the size of the test piece subjected to the compression test is small. The difference between the major axis and the minor axis (absolute value) itself is the sample number of the invention. B-4 is smaller, but when compared by the ratio to the average diameter after compression, Sample No. B-4 is ± 1.5%, sample No. as a comparative example. B-8 is ± 2.4%, which is the same level as those of other inventive examples and other comparative examples. Here, Sample No. whose X-ray diffraction intensity magnitude relationship satisfies the conditions of the present invention. A-1, A-2 and No. B-1, B-2, B-3, and B-4 were subjected to processing with a cross-section reduction rate of 50% or more in the temperature range of 740 to 840 ° C. in the post-rolling stage when the bar wire was hot rolled. On the other hand, Sample No. whose X-ray diffraction intensity magnitude relationship does not satisfy the conditions of the present invention. A-3, A-4, and NoB-5, B-6, B-7, and B-8 had either a temperature range outside the above range or a small cross-sectional reduction rate.

以上のように、本発明の範囲にあれば、棒線の加工および焼鈍の工程の違いによらず、高い引張強さと優れた冷間鍛造性を示しており、本発明の効果が得られている。   As described above, as long as it is within the scope of the present invention, it exhibits high tensile strength and excellent cold forgeability regardless of differences in the processing of bar wire and annealing, and the effects of the present invention are obtained. Yes.

円柱形素材を高さ方向に圧縮した場合の長径と短径を説明する図である。It is a figure explaining the major axis and minor axis at the time of compressing a column-shaped raw material to a height direction. 円柱形素材のL断面とT断面を示す図である。It is a figure which shows the L cross section and T cross section of a cylindrical raw material. 円柱形素材のL断面とT断面におけるチタンα相の各結晶面からのX線回折強度の大小関係を示す図である。It is a figure which shows the magnitude relationship of the X-ray diffraction intensity from each crystal plane of the titanium alpha phase in the L cross section and T cross section of a cylindrical raw material. 円柱形素材のL断面とT断面におけるチタンα相の各結晶面からのX線回折強度の大小関係を示す図である。It is a figure which shows the magnitude relationship of the X-ray diffraction intensity from each crystal plane of the titanium alpha phase in the L cross section and T cross section of a cylindrical raw material.

Claims (2)

質量%で、Feを0.5〜1.3%、Nを0.001〜0.05%、Cを0.001〜0.15%、Oを[1]式の酸素等価量Qが0.34〜0.55となる範囲で含有し、残部がTiおよび不可避的不純物からなる円柱形を成す冷間鍛造素材であり、且つチタンα相の各結晶面からのX線回折強度Iが、[2],[3],[4],[5]式の関係にあり、引張強さが700MPa以上であることを特徴とする冷間鍛造工程において円柱形の高さ方向に圧縮加工が加わる高強度チタン合金製冷間鍛造用素材。
酸素等価量Q=[O]+2.77[N]+0.086[Fe] ・・・[1]式
ここで、[O]はO含有量(質量%)、[N]はN含有量(質量%)、[Fe]はFe含有量(質量%)である。
円柱形のL断面において測定したX線回折強度Iの大小関係が、
I(0 0 0 2)>I(1 0 −1 0) ・・・[2]式
I(0 0 0 2)>I(1 0 −1 1) ・・・[3]式
円柱形のT断面において測定したX線回折強度Iの大小関係が、
I(1 0 −1 0)>I(0 0 0 2) ・・・[4]式
I(1 0 −1 0)>I(1 0 −1 1) ・・・[5]式
ここで、I(0 0 0 2)、I(1 0 −1 0)、I(1 0 −1 1)は、各々、稠密六方晶であるチタンα相の(0 0 0 2)面、(1 0 −1 0)面、(1 0 −1 1)面からの回折強度である。なお、L断面とは円柱形素材の高さ方向に平行な長方形を成す断面であり、T断面とは円柱形素材の高さ方向に直交する円形を成す断面である。
In mass%, Fe is 0.5 to 1.3%, N is 0.001 to 0.05%, C is 0.001 to 0.15%, and O is the oxygen equivalent amount Q of the formula [1] is 0. .34 to 0.55, the balance is a cold forging material comprising a columnar shape composed of Ti and inevitable impurities, and the X-ray diffraction intensity I from each crystal plane of the titanium α phase is [2], [3], [4], [5] are related, and the tensile strength is 700 MPa or more. In the cold forging process, compression is applied in the height direction of the cylindrical shape. High strength titanium alloy cold forging material.
Oxygen equivalent amount Q = [O] +2.77 [N] +0.086 [Fe] (1) formula [0] where [O] is the O content (mass%), and [N] is the N content ( Mass%) and [Fe] are Fe contents (mass%).
The magnitude relationship of the X-ray diffraction intensity I measured in the cylindrical L cross section is
I (0 0 0 2)> I (1 0 −1 0) (2) Formula I (0 0 0 2)> I (1 0 −1 1) (3) Formula Cylindrical T The magnitude relationship of the X-ray diffraction intensity I measured in the cross section is
I (1 0 −1 0)> I (0 0 0 2) (4) Formula I (1 0 −1 0)> I (1 0 −1 1) (5) Formula where I (0 0 0 2), I (1 0 −1 0), and I (1 0 −1 1) are respectively a (0 0 0 2) plane of a titanium α phase that is a dense hexagonal crystal, (1 0 − It is the diffraction intensity from the (1 0) plane and the (1 0 -1 1) plane. The L cross section is a cross section that forms a rectangle parallel to the height direction of the cylindrical material, and the T cross section is a cross section that forms a circle perpendicular to the height direction of the cylindrical material.
請求項1の高強度チタン合金製冷間鍛造用素材において、直径が16mm以下の冷間ヘッダー加工用のチタン合金棒線。   The high strength titanium alloy cold forging material according to claim 1, wherein the diameter of the titanium alloy bar wire is 16mm or less for cold header processing.
JP2007045452A 2007-02-26 2007-02-26 High strength titanium alloy material for cold forging Active JP5010309B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007045452A JP5010309B2 (en) 2007-02-26 2007-02-26 High strength titanium alloy material for cold forging

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007045452A JP5010309B2 (en) 2007-02-26 2007-02-26 High strength titanium alloy material for cold forging

Publications (2)

Publication Number Publication Date
JP2008208413A true JP2008208413A (en) 2008-09-11
JP5010309B2 JP5010309B2 (en) 2012-08-29

Family

ID=39784971

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007045452A Active JP5010309B2 (en) 2007-02-26 2007-02-26 High strength titanium alloy material for cold forging

Country Status (1)

Country Link
JP (1) JP5010309B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011025269A (en) * 2009-07-23 2011-02-10 Kobe Steel Ltd Press forming method for titanium sheet
WO2011068247A1 (en) 2009-12-02 2011-06-09 新日本製鐵株式会社 α+β TITANIUM ALLOY PART AND METHOD OF MANUFACTURING SAME
CN102172756A (en) * 2011-01-04 2011-09-07 无锡透平叶片有限公司 Thermoforming method for TC11 alloy convergent section
CN111940654A (en) * 2020-08-12 2020-11-17 中国第二重型机械集团德阳万航模锻有限责任公司 Method for improving and stabilizing flaw detection level of TC6 titanium alloy cake blank
WO2023100603A1 (en) * 2021-11-30 2023-06-08 住友電気工業株式会社 Titanium material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996033292A1 (en) * 1995-04-21 1996-10-24 Nippon Steel Corporation High-strength, high-ductility titanium alloy and process for preparing the same
JP2005290480A (en) * 2004-03-31 2005-10-20 Honda Motor Co Ltd Valve spring retainer made of titanium

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996033292A1 (en) * 1995-04-21 1996-10-24 Nippon Steel Corporation High-strength, high-ductility titanium alloy and process for preparing the same
JP2005290480A (en) * 2004-03-31 2005-10-20 Honda Motor Co Ltd Valve spring retainer made of titanium

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011025269A (en) * 2009-07-23 2011-02-10 Kobe Steel Ltd Press forming method for titanium sheet
WO2011068247A1 (en) 2009-12-02 2011-06-09 新日本製鐵株式会社 α+β TITANIUM ALLOY PART AND METHOD OF MANUFACTURING SAME
US9187807B2 (en) 2009-12-02 2015-11-17 Nippon Steel & Sumitomo Metal Corporation α+beta-type titanium alloy part and method of production of same
CN102172756A (en) * 2011-01-04 2011-09-07 无锡透平叶片有限公司 Thermoforming method for TC11 alloy convergent section
CN111940654A (en) * 2020-08-12 2020-11-17 中国第二重型机械集团德阳万航模锻有限责任公司 Method for improving and stabilizing flaw detection level of TC6 titanium alloy cake blank
WO2023100603A1 (en) * 2021-11-30 2023-06-08 住友電気工業株式会社 Titanium material

Also Published As

Publication number Publication date
JP5010309B2 (en) 2012-08-29

Similar Documents

Publication Publication Date Title
KR101418775B1 (en) Beta type titanium alloy with low elastic modulus and high strength
JP6965986B2 (en) Manufacturing method of α + β type titanium alloy wire and α + β type titanium alloy wire
KR101455913B1 (en) α+β TITANIUM ALLOY PART AND METHOD OF MANUFACTURING SAME
JP6889418B2 (en) Manufacturing method of Ni-based super heat-resistant alloy and Ni-based super heat-resistant alloy
JP4493029B2 (en) Α-β type titanium alloy with excellent machinability and hot workability
US20030168138A1 (en) Method for processing beta titanium alloys
JP4493028B2 (en) Α-β type titanium alloy with excellent machinability and hot workability
KR20210043652A (en) Titanium alloy wire rod and method of manufacturing titanium alloy wire rod
JPH10306335A (en) Alpha plus beta titanium alloy bar and wire rod, and its production
CN112639144B (en) Copper alloy material, method for producing same, and member or component made of copper alloy material
JP2008133531A (en) Beta titanium alloy
WO2012115187A1 (en) Ti-mo alloy and method for producing same
JP5010309B2 (en) High strength titanium alloy material for cold forging
JP5594244B2 (en) Α + β type titanium alloy having a low Young&#39;s modulus of less than 75 GPa and method for producing the same
JP5621571B2 (en) Α + β type titanium alloy having a low Young&#39;s modulus of less than 75 GPa and method for producing the same
JP2019060026A (en) Magnesium-based alloy extension material and manufacturing method therefor
JP2010222632A (en) HIGH STRENGTH Fe-Ni-Co-Ti BASED ALLOY AND METHOD FOR PRODUCING THE SAME
JP2017002390A (en) Titanium alloy forging material
JP2010053419A (en) Titanium alloy for heat resistant member having excellent creep resistance and high temperature fatigue strength
JP6812460B2 (en) High-strength low thermal expansion alloy
JP2018053313A (en) α+β TYPE TITANIUM ALLOY BAR AND MANUFACTURING METHOD THEREFOR
JP2017002373A (en) Titanium alloy forging material
JP5549981B2 (en) Mg-based alloy cold worked parts
JP2003201530A (en) High-strength titanium alloy with excellent hot workability
JP2016023315A (en) Titanium plate and manufacturing method therefor

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20090827

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110928

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120522

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120601

R150 Certificate of patent or registration of utility model

Ref document number: 5010309

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150608

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150608

Year of fee payment: 3

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150608

Year of fee payment: 3

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313117

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350