JP2008207146A - Manufacturing method for drinking water - Google Patents

Manufacturing method for drinking water Download PDF

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JP2008207146A
JP2008207146A JP2007048558A JP2007048558A JP2008207146A JP 2008207146 A JP2008207146 A JP 2008207146A JP 2007048558 A JP2007048558 A JP 2007048558A JP 2007048558 A JP2007048558 A JP 2007048558A JP 2008207146 A JP2008207146 A JP 2008207146A
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shell
water
mixture
drinking water
weight
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JP4973850B2 (en
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Michihisa Sasaki
道寿 佐々木
Tomokazu Yamane
朋一 山根
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing drinking water that promotes health simply and inexpensively. <P>SOLUTION: The process of calcining a shell 2 at 1,800-2,000°C and of making it stand to cool to the ordinary temperature is repeated at least twice (P1-P4). The obtained calcined substance 3 is mixed with water in a weight ratio of 1:10-40 (P5). The obtained mixture 4 is boiled and concentrated until the weight of the mixture 4 is boiled down to 1/2 or less than that before boiling (P6), and the mixture 4 after concentration is filtrated out (P7). The shell 2 is calcined at 1,800-2,000°C by holding a carbonized substance in which sawdust is compressed and carbonized and the shell 2 in an incinerator, and by burning the carbonized substance. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、貝殻の焼成物を用いた飲料水の製造方法に関するものである。   The present invention relates to a method for producing drinking water using a baked shellfish.

水質を評価する基準としては、例えば酸化還元電位(Oxidation Reduction Potential。以下、「ORP値」という。)が知られている。水道水のORP値は、+450mVから+550mV程度であることが多いが、+750mVに達する場合もある。   As a standard for evaluating water quality, for example, an oxidation reduction potential (hereinafter referred to as “ORP value”) is known. The ORP value of tap water is often about +450 mV to +550 mV, but may reach +750 mV.

一方、飲料水のORP値は、+200mV以下であることが好ましいものと考えられている。これに対し、上記の水道水のようなORP値が+200mVを大きく超える、いわゆる酸化水は、飲料水として用いれば、人間を含む動植物に悪影響があるといわれ、また、鉄等の金属の腐食の原因ともなる。 On the other hand, it is considered that the ORP value of drinking water is preferably +200 mV or less. In contrast, so-called oxidized water having an ORP value exceeding +200 mV, such as the above-mentioned tap water, is said to have adverse effects on animals and plants, including humans, when used as drinking water, and it also corrodes metals such as iron. It can also be a cause.

そこで、上記のような問題点を解決すべく、水を電気的に処理する手段、例えば、
〔1〕水路の途中に電極対を配置し、直流電流を印加して電解処理することによって、水中に含まれる懸濁物を凝集させてろ過する水処理装置(例えば、特許文献1参照。)や、
〔2〕粒状又は断片状のセラミックキャパシタを、水の電解で発生するプロトンと電子の電荷体として使用することによって、水のORP値を下げる整水器(例えば、特許文献2参照。)、
が提案されている。
特開2004−358449号公報 特開2003−260467号公報
Therefore, in order to solve the above problems, means for electrically treating water, for example,
[1] A water treatment apparatus for aggregating and filtering a suspension contained in water by disposing an electrode pair in the middle of a water channel and applying a direct current to perform electrolytic treatment (see, for example, Patent Document 1). Or
[2] A water conditioner that lowers the ORP value of water by using a granular or fragmented ceramic capacitor as a charge body of protons and electrons generated by electrolysis of water (for example, see Patent Document 2).
Has been proposed.
JP 2004-358449 A JP 2003-260467 A

しかし、上記のような従来の技術においては、水の電気的処理のための設備等にコストがかかるので、経済的に問題がある。また、水の電気的処理における操作や設備の維持管理が煩雑であるという問題点がある。更に、水の電気的処理によりORP値を下げることはできるものの、水に他の成分を付加することができないので、健康を増進可能な飲料水を製造することができないという問題点がある。   However, the conventional techniques as described above are economically problematic because the cost for facilities for electrical treatment of water is high. In addition, there is a problem in that the operation and maintenance of facilities in the electrical treatment of water are complicated. Furthermore, although the ORP value can be lowered by electrical treatment of water, there is a problem that it is impossible to produce drinking water that can promote health because other components cannot be added to the water.

本発明は、以上のような事情や問題点に鑑みてなされたものであり、健康を増進可能な飲料水を簡単かつ安価に製造できる方法を提供することを目的とする。   This invention is made | formed in view of the above situations and problems, and it aims at providing the method which can manufacture the drinking water which can improve health simply and cheaply.

上記目的を達成するための第1の発明は、貝殻を1800〜2000℃で焼成してから常温まで放冷する工程を少なくとも2回繰り返し、得られた焼成物と水とを1:(10〜40)の重量比で混合し、得られた混合物を煮沸して前記混合物の重量が煮沸前の重量の1/2以下になるまで濃縮し、濃縮後の混合物をろ過するものである。   1st invention for achieving the said objective repeats the process which bakes a shell at 1800-2000 degreeC, and is left to cool to normal temperature at least twice, and the obtained baked product and water are 1: (10-10 40) The mixture is boiled, and the resulting mixture is boiled and concentrated until the weight of the mixture becomes 1/2 or less of the weight before boiling, and the concentrated mixture is filtered.

第2の発明は、オガ屑を圧縮及び炭化した炭化物と前記貝殻とを焼成炉内に収容し、前記炭化物を燃焼させることによって、前記貝殻を1800〜2000℃で焼成するものである。   According to a second aspect of the present invention, a carbide obtained by compressing and carbonizing sawdust and the shell are housed in a firing furnace, and the shell is fired at 1800 to 2000 ° C. by burning the carbide.

第1の発明によれば、貝殻特有の臭みを完全に消すことができると共に、粉砕機により別途粉砕しなくても貝殻を粉末状にすることができるので、健康を増進可能な飲料水を簡単かつ安価に製造することができる。また、廃棄物としての貝殻を再利用すれば、廃棄物の減量化にも寄与することができる。   According to the first invention, the odor peculiar to the shell can be completely eliminated, and the shell can be powdered without being separately pulverized by a pulverizer. And it can be manufactured at low cost. Moreover, if the shell as waste is reused, it can also contribute to the reduction of waste.

第2の発明によれば、より簡単かつ安価に貝殻を焼成することができる。   According to the second invention, the shell can be fired more easily and inexpensively.

以下、本発明の実施形態を図面に基づいて説明する。
図1に示すように、本実施形態に係る飲料水1の製造方法は、焼成工程(P1〜P4)、混合工程(P5)、煮沸工程(P6)、及びろ過工程(P7)を有している。すなわち、この製造方法は、貝殻2を1800〜2000℃で焼成してから常温まで放冷する工程を例えば2回繰り返し(P1〜P4)、得られた焼成物3と水とを1:(10〜40)〔1:10から1:40〕の重量比で混合し(P5)、得られた混合物4を煮沸して混合物4の重量が煮沸前の重量の1/2以下になるまで濃縮し(P6)、濃縮後の混合物4をろ過(P7)するものである。次に、各工程について詳細に説明する。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
As shown in FIG. 1, the manufacturing method of the drinking water 1 which concerns on this embodiment has a baking process (P1-P4), a mixing process (P5), a boiling process (P6), and a filtration process (P7). Yes. That is, in this manufacturing method, the process of baking the shell 2 at 1800 to 2000 ° C. and then allowing it to cool to room temperature is repeated, for example, twice (P1 to P4), and the obtained fired product 3 and water are 1: (10 -40) Mix in a weight ratio of [1:10 to 1:40] (P5), boil the resulting mixture 4 and concentrate until the weight of the mixture 4 is less than or equal to 1/2 the weight before boiling. (P6) The mixture 4 after concentration is filtered (P7). Next, each step will be described in detail.

〔焼成工程〕
飲料水1の製造に際しては、まず、貝殻2を1800〜2000℃で1時間以上、好ましくは2時間以上焼成(P1)してから常温まで放冷する(P2)。
[Baking process]
In producing the drinking water 1, the shell 2 is first baked (P1) at 1800 to 2000 ° C. for 1 hour or more, preferably 2 hours or more, and then allowed to cool to room temperature (P2).

ここでいう貝殻とは、食用等の貝から貝肉を取り外した殻部分をいう。貝としては、カキ(牡蠣)、ホタテ(帆立)、シジミ(蜆)、アワビ(鮑)、サザエ等が挙げられる。貝肉を取り外した後に廃棄物として捨てられる貝殻2を利用すれば、原料を安価且つ大量に入手できると共に、廃棄物の有効利用を図ることができるという利点がある。なお、貝殻2は、焼成前に水等で洗浄し、汚れを除去しておくのが望ましい。また、貝殻2の代わりに又は貝殻2と共に、ウニの殻及び/又はカニの殻を使用してもよい。   The term “shell” as used herein refers to a shell portion obtained by removing shell meat from an edible shellfish. Examples of shellfish include oysters (oysters), scallops (scallops), swordfish (clams), abalone (clams), and turban shells. If the shell 2 that is discarded as waste after removing the shell meat is used, there are advantages that raw materials can be obtained in a large amount at a low cost and that the waste can be effectively used. The shell 2 is preferably washed with water or the like before firing to remove dirt. Further, instead of or together with the shell 2, a sea urchin shell and / or a crab shell may be used.

貝殻2は、適宜の熱源を有する焼成炉内に収容した状態で焼成すればよいが、オガ屑を圧縮及び炭化させた炭化物と貝殻2とを焼成炉内に収容し、炭化物を燃焼させることによって、貝殻2を1800〜2000℃で焼成するようにすれば、より簡単かつ安価に貝殻2を焼成できるという利点がある。1800〜2000℃で焼成する理由は、貝殻2の炭化に適しているからである。1800℃以下であると十分に炭化されず、2000℃以上であると灰となって残らなくなるからである。オガ屑(大鋸屑)を圧縮及び炭化した炭化物としては、オガ屑を棒状に圧縮した木質系固形燃料〔例えば、オガライト(商品名)〕を更に炭化した炭化物〔例えば、オガ炭(商品名)〕等が挙げられる。   The shell 2 may be fired in a state where it is housed in a firing furnace having an appropriate heat source, but the carbide 2 obtained by compressing and carbonizing sawdust and the shell 2 are housed in the firing furnace, and the carbide is burned. If the shell 2 is fired at 1800 to 2000 ° C., there is an advantage that the shell 2 can be fired more easily and inexpensively. The reason for firing at 1800 to 2000 ° C. is because it is suitable for carbonization of the shell 2. This is because if it is 1800 ° C. or lower, it is not sufficiently carbonized, and if it is 2000 ° C. or higher, it does not remain as ash. The carbide obtained by compressing and carbonizing sawdust (large sawdust) is a carbide obtained by further carbonizing wood solid fuel [for example, Ogarite (trade name)] obtained by compressing sawdust into a rod shape [for example, Oga charcoal (trade name)], etc. Is mentioned.

次いで、放冷後の焼成物3を再度1800〜2000℃で1時間以上、好ましくは2時間以上焼成(P3)してから常温まで放冷する(P4)。   Next, the fired product 3 after being allowed to cool is fired again at 1800 to 2000 ° C. for 1 hour or longer, preferably 2 hours or longer (P3) and then allowed to cool to room temperature (P4).

このように、1800〜2000℃での焼成を2回繰り返せば、貝殻2特有の臭みを完全に消すことができると共に、粉砕機により別途粉砕しなくても貝殻2を粉末状にすることができるという利点がある。なお、上記のような焼成及び放冷は、必要に応じて3回以上繰り返してもよい。   In this way, if the baking at 1800 to 2000 ° C. is repeated twice, the odor peculiar to the shell 2 can be completely eliminated, and the shell 2 can be powdered without being separately pulverized by a pulverizer. There is an advantage. In addition, you may repeat 3 times or more as needed above baking and standing_to_cool.

〔混合工程〕
そして、得られた焼成物3と水とを煮沸容器に入れて混合物4とする(P5)。焼成物3と水との重量比は、1:(10〜40)〔1:10から1:40〕とする。水としては、地下水等の軟水が好適である。ここでいう軟水とは、硬度10度以下の水をいう。この軟水は、硬水に比べてカルシウムイオンやマグネシウムイオン等の含有量が少ないと共に、水道水のように塩素成分を多く含んでいるものではないので、軟水を使用すれば、焼成物3中のミネラル成分が水に溶出し易いという利点がある。加える水の量が少ない時には得られる飲料水1のORP値がより低くなるが、重量比で10より小さい時にはそれがほとんど同じで生産効率が悪いので10を下限値とし、又、重量比で40より大きい時にはORP値が小さくなって効果が少なくなるからである。
[Mixing process]
And the obtained baked product 3 and water are put into a boiling container, and it is set as the mixture 4 (P5). The weight ratio of the fired product 3 to water is 1: (10 to 40) [1:10 to 1:40]. As water, soft water such as groundwater is suitable. Soft water here refers to water having a hardness of 10 degrees or less. This soft water contains less calcium ions, magnesium ions, etc. than hard water and does not contain as much chlorine component as tap water, so if soft water is used, the minerals in the calcined product 3 There is an advantage that the components are easily eluted in water. When the amount of water to be added is small, the ORP value of the drinking water 1 obtained is lower, but when the weight ratio is less than 10, it is almost the same and the production efficiency is poor, so 10 is set as the lower limit value, and the weight ratio is 40 This is because when the value is larger, the ORP value becomes smaller and the effect becomes smaller.

〔煮沸工程〕
次いで、得られた混合物4を煮沸し、混合物4の重量が煮沸前の重量の1/2以下になるまで濃縮する(P6)。すなわち、煮沸により、混合物4の重量が1/2以下になるまで混合物4中の水を蒸発させる。これにより、貝殻2の焼成物3中のミネラル成分を水中に十分に溶出させることができる。
[Boiling process]
Next, the obtained mixture 4 is boiled and concentrated until the weight of the mixture 4 is ½ or less of the weight before boiling (P6). That is, the water in the mixture 4 is evaporated by boiling until the weight of the mixture 4 becomes 1/2 or less. Thereby, the mineral component in the baked product 3 of the shell 2 can be sufficiently eluted in water.

〔ろ過工程〕
そして、煮沸後の混合物4を必要に応じて常温まで放冷してからろ過(P7)すれば、残渣と飲料水1とを分離することができる。
[Filtration process]
And if the mixture 4 after boiling is left to cool to normal temperature as needed and filtered (P7), a residue and the drinking water 1 can be isolate | separated.

上記のようにして得られた飲料水1は、焼成物3から溶出したミネラル成分を含み、ORP値が+200mVを大きく下回る−400mV以下であると共に、殺菌効果を有している。また、この飲料水1には、臭いもない。なお、ろ別した残渣は、石鹸、洗髪剤、入浴剤等として使用することができる。   The drinking water 1 obtained as described above contains a mineral component eluted from the calcined product 3, has an ORP value of −400 mV or less, which is significantly lower than +200 mV, and has a bactericidal effect. Further, the drinking water 1 has no odor. The filtered residue can be used as a soap, a hair washing agent, a bath agent or the like.

このように、上記のような製造方法によれば、貝殻2特有の臭みを完全に消すことができると共に、粉砕機により別途粉砕しなくても貝殻2を粉末状にすることができるので、健康を増進可能な飲料水1を簡単かつ安価に製造できるという利点がある。また、廃棄物としての貝殻2を再利用すれば、廃棄物の減量化にも寄与できるという利点がある。   Thus, according to the manufacturing method as described above, the odor peculiar to the shell 2 can be completely eliminated, and the shell 2 can be powdered without being separately pulverized by a pulverizer. There is an advantage that the drinking water 1 capable of improving the temperature can be manufactured easily and inexpensively. Further, if the shell 2 as waste is reused, there is an advantage that it can contribute to reduction of waste.

〔実施例1〕
(1)カキの貝殻50kgを洗浄した後、オガ炭(商品名)を燃やして炉内温度が約1900℃に保つようにある炉内に入れて2時間焼成した。その後、これを炉内に入れたままオガ炭の自然消化と共に自然冷却して常温まで温度を下げたままの状態を半日程度維持した後に、この冷却されたカキの貝殻の入った炉内にオガ炭を入れて再び燃やして炉内温度が約1900℃になるまで加熱し、この温度状態を約3時間保つようにして焼成した。そして、これを前と同じように炉内に入れたままの状態で常温になるまで自然冷却してカキの貝殻の焼成物を得た。この時の焼成物の重量は410gであった。(P1〜P4の工程)
[Example 1]
(1) After washing 50 kg of oyster shells, Oga charcoal (trade name) was burned and placed in a furnace to keep the furnace temperature at about 1900 ° C. and baked for 2 hours. After that, the OG charcoal is naturally cooled with natural digestion of the OG charcoal while being kept in the furnace to maintain the state where the temperature is lowered to room temperature for about half a day, and then the OG in the furnace containing the cooled oyster shell. Charcoal was added, burned again and heated until the furnace temperature reached about 1900 ° C., and this temperature state was maintained for about 3 hours and fired. And this was naturally cooled to room temperature in the state where it was put in the furnace like before, and the baked material of the oyster shell was obtained. The weight of the fired product at this time was 410 g. (Steps P1 to P4)

(2)この焼成物410gに地下水8Lを加えてよく混合し(P5)、この白濁色となっている混合物を煮沸容器に入れて蓋をしない状態で加熱して煮沸させて水を蒸発させ(P6)、全体の重量が煮沸前の約1/2になった時点で、加熱を止めて常温になるまで自然放冷した。 (2) 8L of ground water is added to 410g of the fired product and mixed well (P5), and the mixture in a cloudy color is placed in a boiling vessel and heated without boiling to evaporate the water ( P6) When the total weight was about ½ before boiling, the heating was stopped and the mixture was allowed to cool to room temperature.

(3)この自然放冷した混合物を、ろ過して目的の飲料水約3.8Lを得た。この飲料水を分析した結果〔エネルギー分散型X線分析装置(株式会社堀場製作所製)によるスペクトルチャート〕を図2に示す。 (3) The naturally cooled mixture was filtered to obtain about 3.8 L of target drinking water. FIG. 2 shows the result of analyzing this drinking water [spectrum chart by energy dispersive X-ray analyzer (manufactured by Horiba, Ltd.)].

(4)ろ別した残渣は湿った白い粉状物であるが、この粉状物はNaやKを多く含んでいるので、家畜の餌に混ぜて使用したり、風呂に入れて使用することができる。家畜の餌とした場合には、家畜の成育と健康を維持することができ、風呂の入浴剤とした場合には肌につやが出るなどの効果があった。更に又、この粉状物にはまだ前記飲料水と同じ成分が残っているので、再び水を加えて混合し、加熱煮沸させてからろ別することによって、同じ飲料水を得ることが出来た。 (4) Although the residue filtered off is moist white powder, this powder contains a lot of Na and K, so use it in livestock feed or in a bath. Can do. When used as a livestock feed, the growth and health of the livestock can be maintained, and when used as a bath bath, it has effects such as gloss on the skin. Furthermore, since the same component as the drinking water still remains in the powdery material, the same drinking water could be obtained by adding water again, mixing, heating and boiling, and filtering. .

〔実施例2〕
アワビの貝殻とホタテの貝殻との混合物50kgを用いて実施例1と同様の操作を行った。これにより得られた飲料水の分析結果〔エネルギー分散型X線分析装置(株式会社堀場製作所製)によるスペクトルチャート〕を図3に示す。
[Example 2]
The same operation as in Example 1 was performed using 50 kg of a mixture of abalone shell and scallop shell. The analysis result of the drinking water thus obtained [spectrum chart by energy dispersive X-ray analyzer (manufactured by Horiba, Ltd.)] is shown in FIG.

以上のように、本発明に係る飲料水の製造方法は、健康を増進可能な飲料水を簡単かつ安価に製造するのに適している。   As mentioned above, the manufacturing method of the drinking water which concerns on this invention is suitable for manufacturing the drinking water which can improve health simply and cheaply.

実施形態に係る飲料水の製造方法を示すフローチャートである。It is a flowchart which shows the manufacturing method of the drinking water which concerns on embodiment. 実施例1で得られた飲料水のエネルギー分散型X線分析装置によるスペクトルチャートである。It is a spectrum chart by the energy dispersive X-ray analyzer of the drinking water obtained in Example 1. 実施例2で得られた飲料水のエネルギー分散型X線分析装置によるスペクトルチャートである。It is a spectrum chart by the energy dispersive X-ray analyzer of the drinking water obtained in Example 2.

符号の説明Explanation of symbols

1 飲料水
2 貝殻
3 焼成物
4 混合物
1 Drinking water 2 Seashell 3 Baked product 4 Mixture

Claims (2)

貝殻を1800〜2000℃で焼成してから常温まで放冷する工程を少なくとも2回繰り返し、
得られた焼成物と水とを1:(10〜40)の重量比で混合し、
得られた混合物を煮沸して前記混合物の重量が煮沸前の重量の1/2以下になるまで濃縮し、
濃縮後の混合物をろ過することを特徴とする飲料水の製造方法。
Repeat the process of firing the shell at 1800-2000 ° C. and then allowing it to cool to room temperature at least twice,
The obtained fired product and water are mixed at a weight ratio of 1: (10-40),
The resulting mixture is boiled and concentrated until the weight of the mixture becomes 1/2 or less of the weight before boiling,
A method for producing drinking water, comprising filtering the mixture after concentration.
オガ屑を圧縮及び炭化した炭化物と前記貝殻とを焼成炉内に収容し、前記炭化物を燃焼させることによって、前記貝殻を1800〜2000℃で焼成する請求項1記載の飲料水の製造方法。   The manufacturing method of the drinking water of Claim 1 which bakes the said shell at 1800-2000 degreeC by accommodating the carbide | carbonized_material which compressed and carbonized sawdust, and the said shell in a baking furnace, and burning the said carbide.
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Publication number Priority date Publication date Assignee Title
JP2020147556A (en) * 2019-03-06 2020-09-17 株式会社プラスラボ Oyster shell powder

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JPH07136670A (en) * 1993-11-17 1995-05-30 Takashi Sato Production of natural calcium ion water
JPH08132072A (en) * 1994-11-14 1996-05-28 Yoshio Harada Treatment of shellfish fossil and water quality improving material and filter material produced by using the treatment
JP2001026508A (en) * 1999-03-17 2001-01-30 Ion Corporation Kk Antimicrobial agent comprising shell, cleaning of water using the antimicrobial agent and washing of field crop using the antimicrobial agent
JP2003094072A (en) * 2001-09-21 2003-04-02 Clay Baan Gijutsu Kenkyusho:Kk Water quality improving agent and manufacturing method therefor
JP2004330065A (en) * 2003-05-07 2004-11-25 Zuisei Inada Natural calcium water and its production method
JP2004337828A (en) * 2003-05-16 2004-12-02 Nippon Solid Co Ltd Mineral water preparing agent

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07136670A (en) * 1993-11-17 1995-05-30 Takashi Sato Production of natural calcium ion water
JPH08132072A (en) * 1994-11-14 1996-05-28 Yoshio Harada Treatment of shellfish fossil and water quality improving material and filter material produced by using the treatment
JP2001026508A (en) * 1999-03-17 2001-01-30 Ion Corporation Kk Antimicrobial agent comprising shell, cleaning of water using the antimicrobial agent and washing of field crop using the antimicrobial agent
JP2003094072A (en) * 2001-09-21 2003-04-02 Clay Baan Gijutsu Kenkyusho:Kk Water quality improving agent and manufacturing method therefor
JP2004330065A (en) * 2003-05-07 2004-11-25 Zuisei Inada Natural calcium water and its production method
JP2004337828A (en) * 2003-05-16 2004-12-02 Nippon Solid Co Ltd Mineral water preparing agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020147556A (en) * 2019-03-06 2020-09-17 株式会社プラスラボ Oyster shell powder
JP7341406B2 (en) 2019-03-06 2023-09-11 株式会社プラスラボ oyster shell powder

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