JP2007044017A - Method for producing common salt - Google Patents

Method for producing common salt Download PDF

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JP2007044017A
JP2007044017A JP2005252547A JP2005252547A JP2007044017A JP 2007044017 A JP2007044017 A JP 2007044017A JP 2005252547 A JP2005252547 A JP 2005252547A JP 2005252547 A JP2005252547 A JP 2005252547A JP 2007044017 A JP2007044017 A JP 2007044017A
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salt
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processed water
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JP4482890B2 (en
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Makoto Yafuji
眞 八藤
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KUMAMOTO ETSUAKI
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<P>PROBLEM TO BE SOLVED: To provide a method for producing common salt containing natural delicious ingredients which marine products have through suppressing energy to be used and a raw material cost. <P>SOLUTION: This method for producing the common salt comprises filtering and dehydrating salinity-containing processing water used for processing marine products, such as wakame seaweed, tangle and salmon roe as a basic structure for pulverization, and secondarily using heat generated from a heating mechanism to be used as a dehydrating means of processing water in a processing stage, and if necessary, heating and baking the product, and crushing the product by a high-speed mill. The method enables effective use of resources and energy and obtaining the common salt which contains nutrient ingredients and delicious ingredients contained in marine products and is excellent in quality. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

この発明は、食塩の製造方法に関するものであり、一層詳細には、使用するエネルギーや原料コストを低く抑えしかも天然の旨味成分を含有した食塩の製造方法に関するものである。  The present invention relates to a method for producing salt, and more particularly, to a method for producing salt containing a natural umami component while keeping the energy and raw material costs used low.

現在、日本における食塩は、メキシコ原塩、オーストラリア原塩、中国原塩等の輸入塩やイオン交換膜を使用して海水から製造したイオン交換塩などを原料とし、需要者の使用目的に応じて適宜加工したものが提供されている。  At present, salt in Japan is made from imported salt such as Mexican raw salt, Australian raw salt, Chinese raw salt, etc., and ion exchange salt produced from seawater using ion exchange membranes, depending on the purpose of use by the customer. Properly processed products are provided.

これらの原料塩のうち、輸入塩の多くは、塩分濃度が3.0〜3.5%の海水を塩田に引き込んでその水分を太陽の熱と風の力だけで飛ばし、海水中に存在できなくなって析出した塩化ナトリウム(NaCl)を採取して乾燥させた天日塩である。  Of these raw material salts, many of the imported salts can be present in seawater by drawing seawater with a salinity of 3.0-3.5% into the salt field and flying the water with the power of the sun and wind. It is the sun salt which collected and dried sodium chloride (NaCl) which disappeared.

そしてこの天日塩は水分を完全に飛ばせば海水中にある全てのミネラル成分(ミネラルイオン)を含む理想に近い塩となるが、NaClはその濃度が35%程度になると析出するため海水中に含まれる有用なミネラルイオンの大部分はニガリとして塩田に残されることになり、従って、輸入塩においてもNa以外のミネラルイオンの含有量は多いとは言い難く、NaClの純度が高いのが現状である。  And if this salt is completely free of moisture, it will become an ideal salt containing all the mineral components (mineral ions) in the seawater, but NaCl will be included in the seawater because it precipitates when its concentration is about 35%. Most of the useful mineral ions are left in the salt fields as bitterns. Therefore, it is difficult to say that the content of mineral ions other than Na is high in imported salts, and the purity of NaCl is high at present.

一方、イオン交換塩は、濾過した海水を陰イオン交換膜と陽イオン交換膜を交互に配置した析出槽に導入し、通電によってイオン交換と化学反応を同時に行って順次塩分を集めて飽和塩水をつくり、この飽和塩水を煎熬して真空蒸発缶で煮詰めたのち遠心分離して乾燥することにより製造されるが、このイオン交換塩においても煎熬工程で濃縮されるときにNaClだけが析出し、塩化マグネシウムや塩化カルシウムなどはニガリ成分として分離されてしまい、輸入塩以上にミネラルイオンの含有量が少なくなっている。  On the other hand, the ion exchange salt introduces filtered seawater into a precipitation tank in which anion exchange membranes and cation exchange membranes are alternately arranged, and simultaneously conducts ion exchange and chemical reaction by energization to collect salinity and collect saturated brine. This saturated salt water is decocted, boiled in a vacuum evaporator and then centrifuged and dried, but even in this ion exchange salt, only NaCl is precipitated when concentrated in the decoction process, Magnesium, calcium chloride, and the like are separated as bittern components, and the content of mineral ions is less than that of imported salts.

従って、このようなイオン交換塩を原料とする並塩や食塩などはミネラルの含有量が極めて少なく、現在日本たばこ産業株式会社が市販している家庭用食塩(食卓塩)の組成は99.5%以上が塩化ナトリウムとなっており、塩カドのあるまずい塩になるのも必然的な結果といえる。  Therefore, such salt and salt, which are made from such an ion exchange salt, have an extremely low mineral content, and the composition of household salt (table salt) currently marketed by Japan Tobacco Inc. is 99.5. More than% is sodium chloride, and it can be said that it is an inevitable result that the salt becomes salty.

ところで、塩化物イオン(Cl)は細胞外イオンとなるものが多く、またナトリウムイオンも細胞外イオンとして存在し、その化合物である塩化ナトリウムは細胞外液となる。細胞内に存在するイオンはカリウムの有機酸塩とするのが妥当で細胞の内と外はカリウムとナトリウムがバランスをとっている。By the way, many chloride ions (Cl ) become extracellular ions, sodium ions also exist as extracellular ions, and sodium chloride, which is a compound thereof, becomes an extracellular fluid. It is appropriate to use potassium organic acid salt as the ion present in the cell, and potassium and sodium are balanced inside and outside the cell.

そして細胞内に取り込まれるイオンはカルシウムとマグネシウムのイオンであり、栄養素を運ぶのもカルシウムであり、従って、食塩には塩化ナトリウムだけでなくカルシウム、マグネシウム、カリウムが含まれているのが理想的といえる。  And the ions taken into the cells are calcium and magnesium ions, and it is also the calcium that carries nutrients, so it is ideal that the salt contains not only sodium chloride but also calcium, magnesium, and potassium. I can say that.

そこで、例えば、真水で溶解した輸入天日塩にニガリ(塩化マグネシウム)などを加えて平釜で再結晶させたり、あるいは真水で溶解した輸入天日塩に貝化石などの炭酸カルシウムを加えて真空乾燥させることにより製造した自然塩と称する食塩が需要者に提供されているが、塩化マグネシウムは潮解性を有しているため水分を吸収してべたついたりするだけでなくその後乾燥すると固化して塊状になって使いにくくなり、また炭酸カルシウムは水に溶けず細胞内に入りこめないため、塩カドの解消には至らないのが現状である。  Therefore, for example, by adding bittern (magnesium chloride) to imported sun salt dissolved in fresh water and recrystallizing in a flat pot, or by adding calcium carbonate such as shell fossil to imported sun salt dissolved in fresh water and vacuum drying. Sodium chloride, which is produced as natural salt, is provided to customers. Magnesium chloride has deliquescent properties, so it absorbs moisture and becomes sticky. In addition, since calcium carbonate does not dissolve in water and cannot enter cells, salt cadmium is not resolved.

このような事情から、ミネラルバランスに優れしかも旨味のある食塩が待望されているため様々な方法が提案され実施化されているが、いずれの製造方法も塩分濃度が3.0〜3.5%の海水を煎熬して煮詰めたり、遠心分離したり、さらには乾燥するなどの工程を採用していることから使用エネルギーのコストが嵩み、工業的な面も含めて需要者の要望に十分答えられないのが実情となっている。  Under such circumstances, various methods have been proposed and put into practice since salty salt with excellent mineral balance and umami has been awaited, but all the manufacturing methods have a salt concentration of 3.0 to 3.5%. The process uses processes such as decoction and simmering of seawater, centrifuging, and drying, increasing the cost of energy used and answering the demands of customers, including industrial aspects. The fact is that it is not possible.

ところで、海に囲まれた日本では古くから様々な海産物が多用されており、わかめや昆布など食用としている海藻類などの栄養価は、食物繊維、ビタミン、ミネラル、葉緑素などを含んでいるため海の野菜という位置づけがなされているが、例えば、わかめなどは、採集後数日で変質してしまうことから年間を通じ流通させることができるよう加工処理が施されている。  By the way, in Japan surrounded by the sea, various marine products have been used extensively for a long time. However, for example, wakame has been processed so that it can be distributed throughout the year because it changes quality within a few days after collection.

わかめの加工品については、日持ちのする干しわかめと生わかめに大別されるが、風味の優れた生わかめが需要者から支持されている。この生わかめには湯通しわかめと湯通し塩蔵わかめとがあるが、湯通しすることによって鮮やかな緑になり商品価値も上昇することと保存性の面などからその多くは湯通し塩蔵わかめとして加工されている。
湯通し塩蔵わかめは、採取したわかめを、海水などに食塩を加えることにより塩分濃度を上げた処理用湯水でブランチング(湯通し)してから塩もみを行ったのち、加圧して水分を抜き、さらに必要に応じて少量の塩をまぶすことにより製造されるが、この加工工程で使用された塩分濃度の高い処理水はそのほとんどが海洋に投棄されているため、海洋汚染の原因となっているだけでなく生態系への影響なども大きな問題となってきている。
Wakame processed products are roughly divided into long-lived dried wakame and fresh seaweed, but customers are favoring raw seaweed with excellent flavor. There are two types of raw wakame: boiled wakame and boiled salted wakame. Most of the raw wakame are processed as boiled salted wakame due to its vibrant green color and increased commercial value.
For boiled salted seaweed seaweed, blanched (boiled) the collected seaweed with processing hot water that has been increased in salt concentration by adding salt to seawater, etc., and then salted to remove water. However, most of the high-salt treated water used in this processing process is dumped into the ocean, causing only ocean pollution. The impact on the ecosystem has also become a major problem.

そこでこの発明では、このような海産物の処理水には通常10%以上の高濃度の塩分が含まれているだけでなく対象となる海藻など海産物に含まれている栄養成分なども溶解していることに着目したものであり、具体的には、海産物の加工に使用した塩分を含む処理水を濾過脱水して微粉化することにより食塩を製造することを基本的な構成として採用するものである。  Therefore, in the present invention, such seawater treated water usually contains not only high concentrations of salt of 10% or more, but also nutrients contained in marine products such as seaweed. Specifically, the basic configuration is to produce salt by filtering and dewatering the treated water containing salt used for processing of marine products to make fine powder. .

この場合、海産物の処理水としては、わかめ処理水のほかに昆布処理水、イクラ処理水、ホタテ処理水さらにはカニ処理水なども使用することができ、この処理水には、対象となる海産物の煮汁および/もしくはしぼり汁も併せて使用するのが好適である。  In this case, as seawater treated water, in addition to seaweed treated water, kelp treated water, salmon treated water, scallop treated water, and crab treated water can also be used. It is also preferable to use simmered juice and / or squeezed juice.

なお、加工処理水の脱水手段としては、海産物の加工処理工程で使用されるボイラーなどの加熱機構から発生する熱を利用するのが好適であり、具体的には、この加熱機構から発生する熱を二次利用して脱水したのち、三次利用して乾燥を行い、さらには必要に応じて加熱焼成して高速ミルで粉砕するのが好ましい。  In addition, it is preferable to use heat generated from a heating mechanism such as a boiler used in a marine product processing step as the dewatering means of the processed water. Specifically, the heat generated from this heating mechanism is used. After being dehydrated by secondary use, it is preferably dried by tertiary use, and further heated and fired as necessary and pulverized by a high-speed mill.

一方、加工処理水の脱水および/もしくは乾燥時にエレクトロンを供給すれば、酸化防止とともに熱効率の向上を図ることができる。  On the other hand, if electrons are supplied at the time of dehydration and / or drying of the processed water, it is possible to prevent oxidation and improve thermal efficiency.

また、海産物の処理水に1〜30重量%の水溶性ミネラル含有液を加えれば、製造される食塩のミネラルバランスを好適に保持することができ、そしてこのような製造方法により得られた食塩は、わかめをはじめとする海産物に含まれる天然の旨味成分や有効成分を有する旨味食塩として提供される。  Moreover, if 1-30 weight% of water-soluble mineral containing liquid is added to the processed water of marine products, the mineral balance of the salt produced can be suitably maintained, and the salt obtained by such a production method is It is provided as umami salt having natural umami ingredients and active ingredients contained in seafood such as seaweed.

一方、海産物の加工に使用した塩分を含む処理水の一部を濾過したのち海産物の加工処理用水に還流させて使用すれば、海産物加工処理水の再利用を好適に図ることができ、さらに、この還流させる処理水に水溶性ミネラル含有液を加えれば、処理する海産物の品質向上も図ることができるものである。  On the other hand, if a part of the treated water containing salt used for the processing of marine products is filtered and then returned to the processing water for marine products, it can be suitably reused. If a water-soluble mineral-containing liquid is added to the treated water to be refluxed, the quality of marine products to be treated can be improved.

本発明に係る食塩の製造方法によれば;
(1)海産物の加工製造に使用した塩分濃度の高い処理水を廃棄することなく再利用するので、投棄による海洋汚染や生態系への影響などを回避することができるだけでなく、加工製造時の廃熱も使用するのでエネルギーおよび資源の有効利用を図ることができる。
(2)また、海産物に含まれる各種の栄養成分や旨味成分を含有する品質の優れた食塩を製造することができる。
(3)さらに原料となる加工処理水には水溶性ミネラル含有液を加えるので、ミネラルリッチでバランスのとれた食塩を製造することができる。
(4)さらにまた、一部の処理水を海産物の加工製造に再利用するので資源の有効利用とともに、風味や栄養素の損失も少ない湯通し塩蔵わかめなどの海産物製品を得ることができる。
(5)そしてまた、この処理水に水溶性ミネラル含有液を加えて海産物を加工するので海産物製品の品質向上も図ることができる、
など種々の利点を有するものである。
According to the method for producing salt according to the present invention;
(1) Since the high-salinity treated water used in the processing and production of marine products is reused without being discarded, it is possible not only to avoid marine pollution and impact on the ecosystem due to dumping, but also during processing and manufacturing. Since waste heat is also used, energy and resources can be used effectively.
(2) Moreover, the salt which was excellent in the quality containing the various nutrient components and umami components contained in marine products can be manufactured.
(3) Further, since a water-soluble mineral-containing liquid is added to the processed water as a raw material, mineral-rich and balanced salt can be produced.
(4) Furthermore, since some of the treated water is reused for the processing and production of marine products, it is possible to obtain marine products such as boiled salted seaweed with less loss of flavor and nutrients as well as effective use of resources.
(5) And since seafood is processed by adding water-soluble mineral-containing liquid to this treated water, the quality of seafood products can be improved.
It has various advantages.

次に、本発明に係る食塩の製造方法における最良の実施の形態を例示し、添付図面を参照しながら以下詳細に説明する。
図1において、本発明に係る食塩の製造方法では、海産物の加工処理10で使用した塩分を含む処理水12を濾過し、脱水濃縮したのち乾燥して焼成し、さらに粉砕して微粉化することにより食塩14を製造することを基本とするものである。
Next, the best embodiment in the manufacturing method of the salt which concerns on this invention is illustrated, and it demonstrates in detail below, referring an accompanying drawing.
In FIG. 1, in the method for producing salt according to the present invention, the treated water 12 containing salt used in the marine product processing 10 is filtered, dehydrated and concentrated, dried and fired, and further pulverized into fine powder. It is based on manufacturing the salt 14 by this.

なお、本実施の形態において処理水12としては、湯通し塩蔵わかめを製造する場合を例にすると、採取されたわかめのブランチング(湯通し)に使用した湯水、すなわち、海水あるいは真水などに並塩を加えた処理用水16をボイラーなどの加熱機構18で加熱することによりその塩分濃度を10%程度に高めたものを使用するものであり、この処理水12は、塩もみしたわかめを加圧加工処理したときに生成する塩分濃度が20%〜25%のわかめ細胞汁(塩蔵しぼり汁)なども含んだものを総称するものである。  In the present embodiment, as the treated water 12, for example, in the case of producing a boiled salted seaweed seaweed, hot water used for blanching (blanched) the collected seaweed, that is, seawater or fresh water, etc. The treated water 16 is heated by a heating mechanism 18 such as a boiler, and its salt concentration is increased to about 10%. It is a collective term that includes seaweed cell juice (salt squeezed juice) having a salt concentration of 20% to 25%.

この場合、前記処理水12としては、採取した昆布をすき昆布に加工する際に使用した塩分濃度が10%程度の昆布加工処理水、あるいは、鮭の卵巣をほぐしてスジコに加工する際に使用した塩分濃度が15%〜25%程度のイクラ加工処理水、さらにはホタテ加工処理水、カニ加工処理水などその対象となる海産物加工処理プラントごとの処理水を適宜使用することができることは言うまでもない。  In this case, the treated water 12 is used for processing the collected kelp into suki-kombu and processing the kombu-treated water having a salt concentration of about 10%, or when loosening the ovary of salmon and processing it into a sujiko. It goes without saying that treated water for each seafood processing plant that is the target, such as salmon processed water having a salinity of about 15% to 25%, as well as scallop processed water, crab processed water, etc., can be used. .

また、加工処理水12を脱水処理するに際しては、この加工処理水12を濾過したのち、配管20によってわかめの加工処理工程で使用されるボイラーなどの加熱機構18に導き、この加熱機構14から発生する熱(廃熱・余熱)を二次利用することによりエネルギーの有効利用を図ることができる。  Further, when the processed water 12 is dehydrated, the processed water 12 is filtered and then led to the heating mechanism 18 such as a boiler used in the seaweed processing process by the pipe 20, and is generated from the heating mechanism 14. Effective use of energy can be achieved by secondary use of the heat (waste heat / residual heat).

そして、加熱機構14の熱を使用して脱水濃縮した加工処理水12は、例えば、噴霧してから直接乾燥したり、あるいは釜など公知の加熱装置で焼成し、さらに高速ミルで粉砕したのちさらに挟雑物などの除去を行って食塩14として調製し製品化する。
この場合、加工処理水12の脱水濃縮時および/または噴霧・乾燥時にエレクトロン(電子=−e)を供給して作業を行えば、製品の酸化防止とともに熱効率の向上を図ることができ、さらには、乾燥の熱源として加熱機構14から発生する熱を三次利用する構成を採用すれば、エネルギーのさらなる有効利用を図ることができ好適である。
The processed water 12 dehydrated and concentrated using the heat of the heating mechanism 14 is sprayed and directly dried, or baked with a known heating device such as a kettle, and further pulverized with a high-speed mill. The product is prepared as salt 14 by removing foreign substances.
In this case, if the work is performed by supplying electrons (electrons = −e) at the time of dehydration concentration and / or spraying / drying of the processed water 12, it is possible to prevent the oxidation of the product and improve the thermal efficiency. If a configuration in which the heat generated from the heating mechanism 14 is thirdarily used as a heat source for drying is used, it is possible to further effectively use energy, which is preferable.

また、食塩14の原料となる処理水12には、濾過後および/もしくは脱水後に必要に応じて1〜30重量%の水溶性ミネラル含有液22を加えれば、製造される食塩14のミネラルバランスを所望に応じて調整することができる。  In addition, the treated water 12 that is the raw material of the salt 14 is added with 1 to 30% by weight of a water-soluble mineral-containing liquid 22 as necessary after filtration and / or dehydration. It can be adjusted as desired.

なお、この水溶性ミネラル含有液22は、例えば、澱粉および/もしくは穀類と種子と卵殻とを2.5:3.0:0.5の重量比で含む粉砕混合物を醗酵タンクに投入し、この混合原料1に対し水3を加え、攪拌しながら50〜100℃に加熱して澱粉をα化した後、30〜40℃に保温して粘稠な混合液とし、この混合液を30〜40℃に保温して所定の麹菌を加えて複合醗酵させ、さらにこの複合醗酵させた混合液を1〜2ケ月熟成させることにより調製したものを使用するが、前記水溶性ミネラル含有液22の添加量が1重量%未満であると所望のミネラルバランスに調整することが難しく、また添加量が30重量%を超過すると水溶性ミネラル含有液22に含まれる有機酸成分が多くなって若干の酸臭が生じるだけでなく、製造コストの面などから費用対効果の点で問題が生じることになる。  The water-soluble mineral-containing liquid 22 is, for example, charged into a fermentation tank with a pulverized mixture containing starch and / or cereals, seeds and eggshells in a weight ratio of 2.5: 3.0: 0.5. Water 3 is added to the mixed raw material 1 and heated to 50 to 100 ° C. with stirring to gelatinize the starch, and then kept at 30 to 40 ° C. to form a viscous mixed solution. Incubate the mixture at a temperature of 0 ° C. and add a predetermined gonococcus for complex fermentation, and then ripen this mixed fermentation mixture for 1 to 2 months, but add the water-soluble mineral-containing liquid 22 Is less than 1% by weight, it is difficult to adjust to the desired mineral balance, and when the added amount exceeds 30% by weight, the organic acid component contained in the water-soluble mineral-containing liquid 22 increases and a slight acid odor is generated. As well as manufacturing costs And the like of the surface to be a problem in terms of cost-effective results.

なお、前述のようにして調製された水溶性ミネラル含有液22は、5〜10重量%のミネラル成分(灰分)を含み、多量のカルシュウム、マグネシウム、ナトリウム、カリウム、鉄などのミネラルイオンの他に燐、銅、亜鉛、マンガン、硫黄、珪素などの微量ミネラル元素を含有している。  The water-soluble mineral-containing liquid 22 prepared as described above contains 5 to 10% by weight of a mineral component (ash), and in addition to a large amount of mineral ions such as calcium, magnesium, sodium, potassium, iron and the like. It contains trace mineral elements such as phosphorus, copper, zinc, manganese, sulfur and silicon.

このようにして製造された食塩14は、処理された海産物に含まれる各種の栄養成分や旨味成分を含有する品質の優れた旨味塩として調製されるだけでなく、水溶性ミネラル含有液22を添加するので、ミネラルリッチでバランスのとれた食塩となるものである。  The salt 14 produced in this way is not only prepared as a high-quality umami salt containing various nutritional components and umami components contained in the processed marine products, but also added with a water-soluble mineral-containing liquid 22 Therefore, it becomes a salt rich in mineral rich and balanced.

なお、海産物の加工に使用した塩分を含む加工処理水12の一部は、適宜濾過したのち加工処理用水16に還流させ、加熱機構18で再び過熱して海産物の加工に使用すれば加工処理水の再利用を図ることができる。
さらにこの際、還流させた処理水12に水溶性ミネラル含有液22を加えれば、海産物の品質向上とともに好適な処理を行うことができるものである。
A part of the processed water 12 containing salt used for processing seafood is appropriately filtered and then returned to the processing water 16, and heated again by the heating mechanism 18 to be used for processing seafood. Can be reused.
At this time, if the water-soluble mineral-containing liquid 22 is added to the treated water 12 that has been refluxed, the quality of marine products can be improved and a suitable treatment can be performed.

実施例1
並塩を使用した塩分濃度3〜15%のわかめ処理水12を濾過したのち、ボイラー18の余熱を利用してエレクトロンの供給雰囲気で脱水濃縮したのち焼成釜で焼成し、次いで高速ミルで粉砕して挟雑物を除去することによりわかめ塩Aを製造した。
この手順によって得られたわかめ塩Aと前記並塩とを分析して比較したところ、その主な成分組成(重量%、100g当り)は表1の通りであった。
Example 1
After filtering the seaweed treated water 12 having a salt concentration of 3 to 15% using normal salt, it is dehydrated and concentrated in the electron supply atmosphere using the residual heat of the boiler 18 and then baked in a baking kettle and then pulverized in a high-speed mill. The wakame salt A was produced by removing the contaminants.
When the wakame salt A obtained by this procedure was analyzed and compared with the above-mentioned ordinary salt, the main component composition (% by weight, per 100 g) was as shown in Table 1.

実施例2
前記の実施例1と同様に並塩を使用した塩分濃度3〜15%のわかめ処理水12を濾過したのち、このわかめ処理水12に対して水溶性ミネラル含有液を10重量%加え、ボイラー18の余熱を利用してエレクトロンの供給雰囲気で脱水濃縮したのち焼成釜で焼成し、次いで高速ミルで粉砕して挟雑物を除去することによりわかめ塩Bを製造した。
この手順によって得られたわかめ塩Bの主な成分組成(重量%、100g当り)は表1の通りであった。
Example 2
After filtering the seaweed treated water 12 having a salt concentration of 3 to 15% using normal salt in the same manner as in Example 1 above, 10% by weight of a water-soluble mineral-containing liquid was added to the seaweed treated water 12 to obtain a boiler 18. The remaining heat was dehydrated and concentrated in an electron supply atmosphere, calcined in a calcining pot, and then pulverized in a high-speed mill to remove interstitial substances, thereby producing seaweed salt B.
Table 1 shows the main component composition (% by weight, per 100 g) of seaweed salt B obtained by this procedure.

Figure 2007044017
Figure 2007044017

表1の分析結果からも明らかなように、並塩に比べてわかめ塩A(実施例1)はミネラル成分の含有量が飛躍的に増大し、食塩としてのミネラルバランスも向上している。また、わかめ塩B(実施例2)はこのわかめ塩A(実施例1)に比べてミネラル成分がさらに増大し、ミネラルバランスも体液組成に近づき体に良いまろやかな食塩となることが確認された。
さらに、わかめ塩Aおよびわかめ塩Bは、わかめに含まれるグルタミン酸、アスパラギン酸、グリシン、アラニンなど各種アミノ酸も含有しているので旨味が増加し、わかめのふくよかな風味を有する食塩であることが確認された。
As is clear from the analysis results in Table 1, the content of the mineral component of the seaweed salt A (Example 1) is dramatically increased and the mineral balance as salt is improved as compared with the normal salt. In addition, it was confirmed that the seaweed salt B (Example 2) further increases the mineral component compared to the seaweed salt A (Example 1), and the mineral balance is close to the body fluid composition and becomes mellow salt that is good for the body. .
Furthermore, seaweed salt A and seaweed salt B contain various amino acids such as glutamic acid, aspartic acid, glycine and alanine contained in seaweed, so that the umami increases and it is confirmed that they are salt having a seaweed plump flavor. It was done.

実施例3
採取した昆布をすき昆布に加工する際に使用した昆布処理水12(並塩を使用し、塩分濃度が1〜10%程度)を濾過したのち、ボイラー18の余熱を利用してエレクトロンの供給雰囲気で噴霧・乾燥して挟雑物を除去することにより昆布塩Aを製造した。
この手順によって得られた昆布塩Aを分析して前記並塩(コントロール)と比較したところ、その主な成分組成(重量%、100g当り)は表2の通りであった。
Example 3
The kelp-treated water 12 used to process the collected kelp into suki-kombu (using normal salt, with a salinity of about 1 to 10%) is filtered, and then the supply atmosphere of electrons using the residual heat of the boiler 18 The kelp salt A was produced by spraying and drying in order to remove the foreign matter.
When the kelp salt A obtained by this procedure was analyzed and compared with the above-mentioned average salt (control), the main component composition (% by weight, per 100 g) was as shown in Table 2.

実施例4
前記の実施例3と同様に並塩を使用した塩分濃度1〜10%程度の昆布処理水12を濾過したのち、この昆布処理水12に対して水溶性ミネラル含有液を10重量%加え、ボイラー18の余熱を利用してエレクトロンの供給雰囲気で噴霧・乾燥して挟雑物を除去することにより昆布Bを製造した。
この手順によって得られたわかめ塩Bの主な成分組成(重量%、100g当り)は表2の通りであった。
Example 4
After filtering the kelp treated water 12 having a salt concentration of about 1 to 10% using normal salt in the same manner as in Example 3 above, 10% by weight of a water-soluble mineral-containing liquid is added to the kelp treated water 12 to obtain a boiler. The kelp B was manufactured by spraying and drying in the electron supply atmosphere using the remaining heat of 18 to remove the foreign matter.
Table 2 shows the main component composition (% by weight, per 100 g) of seaweed salt B obtained by this procedure.

Figure 2007044017
Figure 2007044017

表2の分析結果によると、昆布塩A(実施例3)は、並塩や前述のわかめ塩A(実施例1、)わかめ塩B(実施例2)に比べてミネラル成分の含有量が飛躍的に増大し、食塩としてのミネラルバランスが向上し、また、昆布塩B(実施例4)はこの昆布塩A(実施例3)に比べてカルシウム成分がさらに増大して、ミネラルバランスの優れたまろやかな食塩となることが確認された。
さらに、昆布塩Aおよび昆布塩Bは、昆布に含まれるタウリン、グルタミン酸、アスパラギン酸、グリシン、システインなど各種のアミノ酸も大量に含有しており、旨味の優れた風味の良い食塩であることが確認された。
According to the analysis results in Table 2, the kelp salt A (Example 3) has a dramatic increase in the content of mineral components compared to the average salt and the seaweed salt A (Example 1) and the seaweed salt B (Example 2). The mineral balance as salt is improved, and the kelp salt B (Example 4) has a further increased calcium component compared to the kelp salt A (Example 3), and has an excellent mineral balance. It was confirmed that the salt was mild.
Furthermore, kelp salt A and kelp salt B contain a large amount of various amino acids such as taurine, glutamic acid, aspartic acid, glycine and cysteine contained in kelp, and it is confirmed that they are tasty and tasty salt. It was done.

このように前記各実施例により製造された食塩が夫々の海産物の成分を含有しているのは、加工処理により対象となるわかめや昆布から溶出した各種成分を含む処理水を廃棄せずに原料水として再利用しているからであり、また、水溶性ミネラル含有液も適宜加えているので従来の製法ではニガリ成分として分離されてしまう塩化マグネシウムや塩化カルシウムなども含有するミネラルバランスの優れた食塩を得ることができるものである。
なお、実施例として、わかめ処理水、昆布処理水を使用した食塩を例示したが、鮭の卵巣をほぐしてスジコに加工する際に使用した塩分濃度が15%〜25%程度のイクラ加工処理水、さらにはホタテ加工処理水、カニ加工処理水など使用して得られた食塩も対象となる海産物の旨味を有し、ミネラルバランスの優れた風味の良い食塩であることが確認されている。
Thus, the salt produced according to each of the above examples contains the components of the respective marine products because the raw materials are not disposed of, without discarding the treated water containing various components eluted from the wakame and kelp that are the target of processing. This is because it is reused as water, and a water-soluble mineral-containing liquid is also added as appropriate, so that it contains magnesium chloride and calcium chloride that are separated as a bitter ingredient in the conventional manufacturing method and has excellent mineral balance. Can be obtained.
In addition, although the salt using the seaweed process water and the kelp process water was illustrated as an Example, the salinity processed water whose salinity used about 15%-25% was used when loosening the ovary of a salmon and processing it into a sujiko. Furthermore, it has been confirmed that the salt obtained by using scallop processed water, crab processed water, etc. also has the taste of the target marine product and is a savory salt with an excellent mineral balance.

本発明に係る食塩の製造方法の好適な実施の形態を示す概略説明図であって、食塩製造の前段となる海産物処理工程および処理水の再利用工程も含む概略工程説明図である。BRIEF DESCRIPTION OF THE DRAWINGS It is a schematic explanatory drawing which shows suitable embodiment of the manufacturing method of the salt which concerns on this invention, Comprising: It is a schematic process explanatory drawing also including the seafood treatment process used as a front | former stage of salt manufacture, and the reuse process water.

符号の説明Explanation of symbols

10…海産物の加工処理、
12…加工処理水、
14…食塩、
16…処理用水、
18…加熱機構(ボイラー)、
20…配管、
22…水溶性ミネラル含有液、
10 ... processing of marine products,
12 ... Processed water,
14 ... salt,
16 ... treatment water,
18 ... heating mechanism (boiler),
20 ... Piping,
22 ... Water-soluble mineral-containing liquid,

Claims (10)

海産物の加工に使用した塩分を含む処理水を濾過脱水して乾燥し、さらに微粉化することを特徴とする食塩の製造方法。A method for producing salt, characterized in that treated water containing salt used for processing seafood is filtered, dehydrated, dried and further pulverized. 海産物の加工処理水は、わかめ加工処理水、昆布加工処理水、イクラ加工処理水、ホタテ加工処理水、カニ加工処理水のいずれかの処理水である請求項1に記載の食塩の製造方法。The method for producing salt according to claim 1, wherein the seawater processed water is any one of seaweed processed water, kelp processed water, salmon processed water, scallop processed water, and crab processed water. 加工処理水は、対象となる海産物の煮汁および/もしくはしぼり汁を含むことからなる請求項1または2に記載の食塩の製造方法。Processed water is a manufacturing method of the salt of Claim 1 or 2 which consists of boiled juice and / or squeezed soup of the target seafood. 加工処理水の脱水手段として、海産物の加工処理工程で使用される加熱機構から発生する熱を二次利用することからなる請求項1〜3のいずれかにに記載の食塩の製造方法。The method for producing salt according to any one of claims 1 to 3, wherein the heat generated from a heating mechanism used in a marine product processing step is secondarily used as a dewatering means for processed water. 加熱機構から発生する熱を二次利用したのち、三次利用して乾燥し、さらに加熱焼成して高速ミルで粉砕することからなる請求項4に記載の食塩の製造方法。The method for producing sodium chloride according to claim 4, wherein the heat generated from the heating mechanism is secondarily used, then dried thirdly, further heated and fired, and pulverized with a high-speed mill. 加工処理水の脱水および/もしくは乾燥時にエレクトロンを供給することからなる請求項4または5に記載の食塩の製造方法。The method for producing salt according to claim 4 or 5, comprising supplying electrons at the time of dehydration and / or drying of the processed water. 加工処理水に1重量%〜30重量%の水溶性ミネラル含有液を加えることを特徴とする請求項1〜6のいずれかに記載の食塩の製造方法。The method for producing sodium chloride according to any one of claims 1 to 6, wherein 1 to 30 wt% of a water-soluble mineral-containing liquid is added to the processed water. 請求項1〜7に記載の方法により製造された食塩。Salt produced by the method according to claim 1. 海産物の加工に使用した塩分を含む処理水の一部を濾過したのち海産物の加工処理用水に還流させて使用することを特徴とする海産物加工処理水の再利用方法。A method for reusing marine product processed water, wherein a portion of treated water containing salt used for processing marine products is filtered and then returned to seawater processed water. 還流させる処理水に水溶性ミネラル含有液を加えることを特徴とする請求項9に記載の海産物加工処理水の再利用方法。The method for reusing marine product processed water according to claim 9, wherein a water-soluble mineral-containing liquid is added to the treated water to be refluxed.
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