JP2008146200A - Communication medium and production method therefor - Google Patents

Communication medium and production method therefor Download PDF

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JP2008146200A
JP2008146200A JP2006330357A JP2006330357A JP2008146200A JP 2008146200 A JP2008146200 A JP 2008146200A JP 2006330357 A JP2006330357 A JP 2006330357A JP 2006330357 A JP2006330357 A JP 2006330357A JP 2008146200 A JP2008146200 A JP 2008146200A
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communication medium
antenna
metal layer
adhesive
pattern
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JP4942465B2 (en
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Katsuhiro Yoshida
勝弘 吉田
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General Technology Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To solve the following problems of a conventional production method for a non-contact communication medium, wherein the conventional production method is costly and is not adequate for high-mix low-volume production, and pattern accuracy is not sufficient. <P>SOLUTION: In the production method for the communication medium having at least a base material for the communication medium and an antenna, provided are processes of: stamping out a metal layer and an adhesive layer of a metal layer transfer member having the metal layer on one face of a support body and the adhesive layer thereon in the same pattern as the antenna; thermally transferring an adhesive onto a surface of the base material for the communication medium in the same pattern as the antenna to form an adhesive bonding pattern layer; and transferring a portion stamped out in the same pattern as the antenna of the metal layer onto the adhesive bonding pattern layer to form the antenna are performed. Thereby, the antenna of the prescribed pattern is easily formed on the surface of the base material for the communication medium with high accuracy at a low cost. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は通信媒体、特に非接触通信媒体または非接触通信媒体用アンテナに関し、さらに詳しくは、通信媒体用アンテナを金属層の転写により形成する非接触通信媒体の製造方法および該製造方法によって製造された通信媒体に関する。   The present invention relates to a communication medium, particularly a non-contact communication medium or an antenna for a non-contact communication medium, and more specifically, a method for manufacturing a non-contact communication medium in which the antenna for a communication medium is formed by transferring a metal layer, and the manufacturing method. Relates to a communication medium.

近年、車載用アンテナなど、薄膜フィルムにパターンを組み込んだ通信媒体が盛んに開発、使用されている。また、様々な情報を書き込んだ超小型のICチップを組み込んだいわゆるICタグやICカードは、商品管理や流通管理、また各種証明書などの幅広い分野での応用が期待されている。これらICタグ、ICカード等は、一般に小さな送受信用の無線アンテナが取り付けられており、ICタグやICカードに接触せずに専用の読みとり装置と通信できる機能を有するため、非接触通信媒体(カード化やタグ化していないインレットの状態も含む)と呼ばれている。   In recent years, communication media in which a pattern is incorporated in a thin film such as an in-vehicle antenna have been actively developed and used. In addition, so-called IC tags and IC cards incorporating ultra-small IC chips in which various information is written are expected to be applied in a wide range of fields such as product management, distribution management, and various certificates. These IC tags, IC cards, etc. are generally equipped with a small wireless antenna for transmission and reception, and have a function of communicating with a dedicated reading device without contacting the IC tag or IC card. Including the state of inlets that are not tagged or tagged).

かかる通信媒体、特に非接触通信媒体に用いられているアンテナの製造方法としては、従来、1)エッチングによる方法、2)スクリーン印刷による方法等が用いられていた。これらのうちエッチングによる方法については、感光性樹脂被膜形成用の塗布装置や露光装置、現像乾燥装置等の高価な設備が必要であり、少量生産の場合には非常に製造コストが高いものとなる。また、その製造工程で使用する各種中間材料もまた高価であり、しかも塗布した材料はエッチングにより除去される部分がアンテナとして有効に残る部分よりも圧倒的に多いため非常に製造コストの高いものとなっていた。   Conventionally, as a manufacturing method of an antenna used for such a communication medium, particularly a non-contact communication medium, 1) a method by etching, 2) a method by screen printing, and the like have been used. Of these methods, the etching method requires expensive equipment such as a coating apparatus, an exposure apparatus, and a development drying apparatus for forming a photosensitive resin film, and the production cost is very high in the case of small-scale production. . In addition, various intermediate materials used in the manufacturing process are also expensive, and the applied material is overwhelmingly more than the portion that remains effectively as an antenna because it is etched away. It was.

また、スクリーン印刷による方法では、スクリーン版を変更することによりパターンを自由に変更できるという利点は有するものの、アンテナ形成用材料である導電性ペースト自体が高価である。また、スクリーン版を作成するのに長時間を要し、さらにペーストを塗布した後の硬化に長時間に亘る熱処理が必要となるため、大量生産に用いないかぎり結果的にコスト高となる。   In addition, the screen printing method has an advantage that the pattern can be freely changed by changing the screen plate, but the conductive paste itself as the antenna forming material is expensive. Moreover, since it takes a long time to produce a screen plate and further a heat treatment for a long time is required for curing after applying the paste, the cost is increased as a result unless it is used for mass production.

ところで、近年、例えば特許文献1〜特許文献4に開示されるように熱転写技術を利用したアンテナの製造方法が提案されている。   By the way, in recent years, as disclosed in Patent Documents 1 to 4, for example, a method of manufacturing an antenna using a thermal transfer technique has been proposed.

特開2001−160123号公報JP 2001-160123 A 特開2000−268149号公報JP 2000-268149 A 特開2003− 30619号公報JP 2003-30619 A 特開2003−243918号公報JP 2003-243918 A

これらのうち特許文献1には、予め金属箔を支持基材に貼り合わせてベースシートを形成し、この金属箔にアンテナのパターンの金型を用いて、金属箔が完全に打ち抜かれる深さまで切込みを入れ、切込みを入れた金属箔のアンテナとして残すべき領域の表面にスクリーン印刷により接着剤を選択的に塗布し、通信媒体用基材にローラで加熱、圧着する非接触通信媒体の製造方法が開示されている。   Among these, in Patent Document 1, a base sheet is formed by pasting a metal foil on a supporting substrate in advance, and an antenna pattern mold is used to cut the metal foil to a depth at which the metal foil is completely punched. A method of manufacturing a non-contact communication medium in which an adhesive is selectively applied by screen printing to the surface of a region to be left as an antenna of a metal foil with a cut, and is heated and pressure-bonded to a communication medium substrate with a roller. It is disclosed.

しかし、かかる方法にあっては、接着剤を金属箔のアンテナとして残すべき領域の表面にスクリーン印刷により選択的に塗布するのにスクリーン版を製作することが必要となるため、(i)多品種、少量生産に柔軟に対応することが困難である、(ii)オンデマンド性に欠け、商品開発に長期間を要する等の問題があった。また、接着剤を金属箔の所定の領域にのみスクリーン印刷で塗布しようとする場合、濡れ性の高い接着剤を使用すると接着剤が流れて所定領域以外の領域にも付着し、ローラで加熱、圧着した後、ピーリングする際に金属箔の不要な領域まで転写してしまうおそれがある。また、濡れ性の低い接着剤を用いるとその表面張力のために基材に接触する接着剤の領域の周辺部のエッジが忠実に形成されず、加熱、圧着後、ピーリングした場合、必要な領域を正確に転写できないおそれがあった。   However, in such a method, it is necessary to produce a screen plate in order to selectively apply the adhesive to the surface of the region to be left as the antenna of the metal foil by screen printing. However, it is difficult to flexibly deal with small-scale production, (ii) lack of on-demand, and product development takes a long time. In addition, when trying to apply the adhesive only to a predetermined area of the metal foil by screen printing, if an adhesive with high wettability is used, the adhesive flows and adheres to an area other than the predetermined area, and is heated with a roller. After the pressure bonding, there is a risk of transferring to an unnecessary region of the metal foil when peeling. Also, if an adhesive with low wettability is used, the edge of the peripheral area of the adhesive area that contacts the base material is not formed faithfully due to its surface tension, and the necessary area when peeling after heating and pressure bonding May not be accurately transferred.

本発明は、このような従来の構成が有していた問題を解決しようとするものであり、通信媒体用基材の表面に所定パターンのアンテナを高いパターン精度で、容易に、かつ低コストで形成し得る通信媒体の製造方法ならびに該製造方法によって製造された通信媒体を実現することを目的とするものである。   The present invention is intended to solve the problems of such a conventional configuration. An antenna of a predetermined pattern is easily and inexpensively provided with a high pattern accuracy on the surface of a communication medium substrate. An object of the present invention is to realize a communication medium manufacturing method that can be formed and a communication medium manufactured by the manufacturing method.

そして、本発明は上記目的を達成するために、少なくとも通信媒体用基材とアンテナとを有する通信媒体の製造方法において、支持体の一方の面に金属層、さらにその上に接着剤層を有してなる金属層転写部材の該金属層および接着剤層を該アンテナと同一のパターンに打ち抜く工程、通信媒体用基材の表面に接着剤を該アンテナと同一のパターンに熱転写して接着パターン層を形成する工程、および該接着パターン層上に該金属層のアンテナと同一のパターンに打ち抜かれた部分を転写してアンテナを形成する工程を行うようにしたものである。   In order to achieve the above object, according to the present invention, in a method for producing a communication medium having at least a base material for communication medium and an antenna, a metal layer is provided on one surface of the support, and an adhesive layer is further provided thereon. Punching the metal layer and the adhesive layer of the metal layer transfer member formed into the same pattern as the antenna, and thermally transferring the adhesive to the same pattern as the antenna on the surface of the base material for the communication medium. And a step of forming an antenna by transferring a portion of the metal layer punched into the same pattern as the antenna onto the adhesive pattern layer.

さらに、本発明は、少なくとも通信媒体用基材とアンテナとを有する通信媒体において、該アンテナを、支持体の一方の面に金属層を、さらにその上に接着剤層を有してなる金属層転写部材の該金属層および接着剤層を該アンテナと同一のパターンに打ち抜き、通信媒体用基材に接着剤を該アンテナと同一のパターンに熱転写して接着パターン層を形成し、さらに該接着パターン層上に該金属層のアンテナと同一のパターンに打ち抜かれた部分を転写することにより形成するようにしたものである。   Furthermore, the present invention provides a communication medium having at least a base material for a communication medium and an antenna, the metal layer comprising the antenna, a metal layer on one surface of the support, and an adhesive layer thereon. The metal layer and the adhesive layer of the transfer member are punched in the same pattern as the antenna, and the adhesive pattern layer is formed by thermally transferring the adhesive to the same pattern as the antenna on the base material for the communication medium. A portion of the metal layer punched out in the same pattern as the antenna is transferred onto the layer.

本発明において、前記通信媒体は、非接触通信媒体用基材、送受信アンテナ、およびICチップを有する非接触通信媒体であることが好ましい。   In the present invention, the communication medium is preferably a non-contact communication medium having a non-contact communication medium substrate, a transmission / reception antenna, and an IC chip.

以下、本発明の実施の形態を図1に基づいて説明する。尚、図1は説明の便宜上、実際のものとは寸法、縮尺等を変えて表してある。   Hereinafter, an embodiment of the present invention will be described with reference to FIG. For convenience of explanation, FIG. 1 is illustrated by changing dimensions, scales, and the like from actual ones.

本発明の製造方法においては、最初に図1(a)に示すように、支持体1の一方の表面上に金属層2を有し、該金属層2の表面上にさらに接着剤層3を有する金属層転写部材4を用意する。   In the production method of the present invention, first, as shown in FIG. 1A, a metal layer 2 is provided on one surface of a support 1, and an adhesive layer 3 is further provided on the surface of the metal layer 2. A metal layer transfer member 4 is prepared.

次いで、図1(b)に示すように、金属層転写部材4の金属層2および接着剤層3を、形成すべきアンテナと同一のパターン様に打ち抜くことにより、金属層2および接着剤層3を、それぞれアンテナと同一のパターンを有する部分21、31とそれ以外の部分とに切り分ける。   Next, as shown in FIG. 1B, the metal layer 2 and the adhesive layer 3 of the metal layer transfer member 4 are punched out in the same pattern as the antenna to be formed. Are divided into portions 21 and 31 each having the same pattern as the antenna and other portions.

一方、図1(c)〜(d)に示すように、別に用意した例えばアンテナ基材のような通信媒体用基材8の表面に、基材シート5の一方の面に接着剤層6を設けてなる接着剤層転写部材7を用いて、接着剤層6のうちアンテナと同一のパターンを有する部分(以下、接着パターン層という)61のみを熱転写する。   On the other hand, as shown in FIGS. 1C to 1D, the adhesive layer 6 is provided on one surface of the base sheet 5 on the surface of the base 8 for communication medium such as an antenna base prepared separately. Using the adhesive layer transfer member 7 provided, only a portion (hereinafter referred to as an adhesive pattern layer) 61 having the same pattern as the antenna in the adhesive layer 6 is thermally transferred.

次いで、図1(e)に示すように、表面にアンテナパターン様に接着パターン層61が形成された通信媒体用基材8に、金属層転写部材4を、パターン化接着剤層31と接着パターン層61とが対向するように、かつ接着パターン層61のアンテナパターンとパターン化金属層21、パターン化接着剤層31のアンテナパターンとがそれらの輪郭同士が合致するように位置合わせして重ね合わせた後、加熱、加圧等を行ってパターン化金属層21を通信媒体用基材8上に転写する。   Next, as shown in FIG. 1 (e), the metal layer transfer member 4 is bonded to the patterned adhesive layer 31 and the adhesive pattern on the communication medium substrate 8 having an adhesive pattern layer 61 formed like an antenna pattern on the surface. The antenna pattern of the adhesive pattern layer 61 and the antenna pattern of the patterned metal layer 21 and the patterned adhesive layer 31 are aligned and overlapped so that the layers 61 face each other. Then, the patterned metal layer 21 is transferred onto the communication medium substrate 8 by heating, pressurizing, or the like.

最後に、図1(f)に示すように、金属層転写部材4を通信媒体用基材8から剥離して所定パターンの金属層21からなるアンテナを通信媒体用基材8上に形成する。   Finally, as shown in FIG. 1 (f), the metal layer transfer member 4 is peeled from the communication medium substrate 8 to form an antenna made of the metal layer 21 having a predetermined pattern on the communication medium substrate 8.

金属層転写部材4の支持体1としては、たとえば、ポリエチレンテレフタレート、ポリエチレン−2,6−ナフタレート、ポリカーボネート、ポリメチルメタクリレート、ポリアミド、ポリイミド、ポリアミドイミド、ポリエチレン、ポリプロピレン、ポリスルホン等からなるプラスチックフィルム、合成紙、パルプ紙等を使用することができる。中でも、二軸延伸ポリエチレンテレフタレートが、熱に対する高い寸法安定性、高い機械的強度を有することから好ましい。支持体の厚さは、2.0〜10.0μmであることが好ましい。また、支持体の長手方向のヤング率は2〜12GPaが好ましく、幅方向のヤング率は2.5〜16GPaであることが好ましい。さらに、支持体の長手方向のF−5値は49〜490MPaであることが好ましく、幅方向のF−5値は29〜300MPaであることが好ましい。また、支持体の長手方向及び幅方向の100℃×30分での熱収縮率は3.0%以下であることが好ましく、2.0%以下であることがより好ましい。さらに、支持体の長手方向及び幅方向の破断強度は98〜980MPaであることが好ましい。   As the support 1 of the metal layer transfer member 4, for example, a plastic film made of polyethylene terephthalate, polyethylene-2,6-naphthalate, polycarbonate, polymethyl methacrylate, polyamide, polyimide, polyamideimide, polyethylene, polypropylene, polysulfone, or the like, synthetic Paper, pulp paper, etc. can be used. Among these, biaxially stretched polyethylene terephthalate is preferable because it has high dimensional stability against heat and high mechanical strength. The thickness of the support is preferably 2.0 to 10.0 μm. The Young's modulus in the longitudinal direction of the support is preferably 2 to 12 GPa, and the Young's modulus in the width direction is preferably 2.5 to 16 GPa. Furthermore, the F-5 value in the longitudinal direction of the support is preferably 49 to 490 MPa, and the F-5 value in the width direction is preferably 29 to 300 MPa. The thermal shrinkage rate at 100 ° C. for 30 minutes in the longitudinal direction and the width direction of the support is preferably 3.0% or less, and more preferably 2.0% or less. Furthermore, the breaking strength in the longitudinal direction and the width direction of the support is preferably 98 to 980 MPa.

上記の支持体1の表面上に設けられる金属層2は、銅またはアルミニウムからなるものが好ましい。支持体1上への金属層2の形成方法としては、蒸着、電解メッキ、貼合せ等特に制限はされないが、充分な金属層の厚さを得るためには、銅張り板等の予め貼合せにより形成されたものが市場での入手容易性も含めて好ましい。   The metal layer 2 provided on the surface of the support 1 is preferably made of copper or aluminum. The method for forming the metal layer 2 on the support 1 is not particularly limited, such as vapor deposition, electrolytic plating, and bonding. However, in order to obtain a sufficient metal layer thickness, a copper-clad plate or the like is bonded in advance. It is preferable that it is formed by including the availability in the market.

金属層2の厚さは特に制限されないが、例えば非接触通信媒体の送受信アンテナとしての所望の体積固有抵抗率を得るためには、1μm以上の厚さであることが好ましく、10μm以上の厚さであることがより好ましい。但し、後の転写工程で転写可能な厚さである必要があることから、その上限は好ましくは40μm、さらに好ましくは35μm、最も好ましくは20μmである。   The thickness of the metal layer 2 is not particularly limited. For example, in order to obtain a desired volume resistivity as a transmission / reception antenna of a non-contact communication medium, the thickness is preferably 1 μm or more, and is preferably 10 μm or more. It is more preferable that However, the upper limit is preferably 40 μm, more preferably 35 μm, and most preferably 20 μm because the thickness needs to be transferable in a subsequent transfer step.

上記の金属層2の表面に形成される接着剤層3に使用する接着剤は特に制限されないが、金属/樹脂用の接着剤であることが好ましく、例えばポリエステル系、塩化ビニル−酢酸ビニル系、エポキシ系の各種接着剤が好適に用いられる。接着剤層の形成方法には特に制限はないが、各種コーター、例えばバーコーター、グラビアコーター等により形成することができる。また、接着剤層の厚さは特に制限されないが、好ましくは0.1〜5μm、より好ましくは1〜3μmである。   The adhesive used for the adhesive layer 3 formed on the surface of the metal layer 2 is not particularly limited, but is preferably a metal / resin adhesive, for example, polyester-based, vinyl chloride-vinyl acetate-based, Various epoxy adhesives are preferably used. Although there is no restriction | limiting in particular in the formation method of an adhesive bond layer, It can form with various coaters, for example, a bar coater, a gravure coater, etc. The thickness of the adhesive layer is not particularly limited, but is preferably 0.1 to 5 μm, more preferably 1 to 3 μm.

金属層2および接着剤層3を、形成すべきアンテナと同一のパターン様に打ち抜く方法としては、例えばアンテナと同一パターンの金型を予め作製しておき、該金型を用いて打ち抜く方法や、カッティングプロッターで打ち抜く方法等が挙げられるが、オンデマンド性を考慮するとカッティングプロッターで打ち抜くことが好ましい。   As a method of punching the metal layer 2 and the adhesive layer 3 in the same pattern as the antenna to be formed, for example, a mold having the same pattern as the antenna is prepared in advance, and a method of punching using the mold, Although the method of punching with a cutting plotter is mentioned, it is preferable to punch with a cutting plotter in consideration of on-demand property.

また、通信媒体用基材8としては、特に制限はないが、例えば非接触通信媒体の基材として用いられている例として、ポリエチレンテレフタレートフィルム、カード、ポリプロピレン合成紙等が挙げられる。   The base material 8 for the communication medium is not particularly limited. Examples of the base material used for the non-contact communication medium include a polyethylene terephthalate film, a card, and a polypropylene synthetic paper.

上記の通信媒体用基材8にアンテナパターン様の接着パターン層61を熱転写により形成するための接着剤層転写部材7の例としては以下のものを挙げることができる。   Examples of the adhesive layer transfer member 7 for forming the antenna pattern-like adhesive pattern layer 61 on the communication medium substrate 8 by thermal transfer include the following.

基材シート5としては、通常の熱転写媒体の基材として広く用いられている、例えばポリエチレンテレフタレート、ポリエチレン−2,6−ナフタレート、ポリカーボネート、ポリメチルメタクリレート、ポリアミド、ポリイミド、ポリアミドイミド、ポリエチレン、ポリプロピレン、ポリスルホンなどからなる高分子フィルムを使用することができる。なかでも、二軸延伸ポリエチレンテレフタレートが、熱に対する高い寸法安定性、高い機械的強度を有することからとりわけ好ましい。   As the base material sheet 5, it is widely used as a base material for ordinary thermal transfer media, such as polyethylene terephthalate, polyethylene-2,6-naphthalate, polycarbonate, polymethyl methacrylate, polyamide, polyimide, polyamideimide, polyethylene, polypropylene, A polymer film made of polysulfone or the like can be used. Among these, biaxially stretched polyethylene terephthalate is particularly preferable because it has high dimensional stability against heat and high mechanical strength.

基材シート5の厚さは、2.0〜10.0μmであることが好ましい。また、基材シートの長手方向のヤング率は2〜12GPaであることが好ましく、幅方向のヤング率は2.5〜16GPaであることが好ましい。さらに、基材シートの長手方向のF−5値は49〜490MPaであることが好ましく、幅方向のF−5値は29〜300MPaであることが好ましい。また、基材シートの長手方向及び幅方向の100℃×30分での熱収縮率は好ましくは3.0%以下、より好ましくは2.0%以下である。さらに、基材シートの長手方向及び幅方向の破断強度は98〜980MPaであることが好ましい。   It is preferable that the thickness of the base material sheet 5 is 2.0-10.0 micrometers. The Young's modulus in the longitudinal direction of the base sheet is preferably 2 to 12 GPa, and the Young's modulus in the width direction is preferably 2.5 to 16 GPa. Further, the F-5 value in the longitudinal direction of the base sheet is preferably 49 to 490 MPa, and the F-5 value in the width direction is preferably 29 to 300 MPa. Moreover, the thermal shrinkage rate at 100 ° C. for 30 minutes in the longitudinal direction and the width direction of the base sheet is preferably 3.0% or less, more preferably 2.0% or less. Furthermore, it is preferable that the breaking strength of the base material sheet in the longitudinal direction and the width direction is 98 to 980 MPa.

上記の基材シート5の一方の面に形成される接着剤層6の材料としては、特に制限はないが、例えば金属/樹脂用の接着剤が好ましく、例えばポリエステル系、塩化ビニル−酢酸ビニル系、エポキシ系の各種接着剤が好適に用いられる。また、接着剤層6の形成方法は特に制限されず、各種コーター、例えばバーコーター、グラビアコーター等により形成することができる。さらに、接着剤層の厚さに特に制限はないが、好ましくは0.1〜5μm、より好ましくは1〜3μmである。 特に、上述した金属層2の表面に形成された接着剤層3と同系統、とりわけ同種の接着剤であることが好ましい。   The material of the adhesive layer 6 formed on one surface of the base sheet 5 is not particularly limited, but is preferably a metal / resin adhesive, for example, polyester-based, vinyl chloride-vinyl acetate-based. Epoxy-based adhesives are preferably used. Moreover, the formation method in particular of the adhesive bond layer 6 is not restrict | limited, It can form with various coaters, for example, a bar coater, a gravure coater, etc. Furthermore, although there is no restriction | limiting in particular in the thickness of an adhesive bond layer, Preferably it is 0.1-5 micrometers, More preferably, it is 1-3 micrometers. In particular, an adhesive of the same type as that of the adhesive layer 3 formed on the surface of the metal layer 2 described above, particularly the same kind of adhesive is preferable.

上記基材シート5と接着剤層6との間には離型処理を施し、あるいは離型層を形成することが好ましく、例えば、基材シート5としてシリコーン離型処理が施されたポリエチレンテレフタレートフィルムを用いたり、基材シート5としてのポリエチレンテレフタレートフィルムと接着剤層6との間にセルロース系、メラミン系の離型剤を塗工したりすることが好ましい。   It is preferable to perform a mold release treatment or to form a mold release layer between the base sheet 5 and the adhesive layer 6. For example, a polyethylene terephthalate film subjected to a silicone mold release process as the base sheet 5. It is preferable that a cellulose-based or melamine-based release agent is applied between the polyethylene terephthalate film as the base sheet 5 and the adhesive layer 6.

尚、上記の金属層転写部材4と接着剤層転写部材7とはそれぞれ別々の部材として用意してもよいが、例えば金属層転写部分と接着剤層転写部分を同一の基体上に面順次に形成することで一部材として用意することも可能である。   The metal layer transfer member 4 and the adhesive layer transfer member 7 may be prepared as separate members. For example, the metal layer transfer portion and the adhesive layer transfer portion are arranged on the same substrate in the surface order. It is also possible to prepare as one member by forming.

さらに、金属層21を通信媒体用基材8に転写する方法としては、熱ロールによる加熱、加圧転写、熱転写プリンターを用いたパターン状加熱による転写等が挙げられる。   Furthermore, examples of the method for transferring the metal layer 21 to the communication medium substrate 8 include heating by a heat roll, pressure transfer, transfer by pattern heating using a thermal transfer printer, and the like.

本発明をさらに詳細に説明するために以下に実施例を示すが、本発明は下記の各実施例によって何ら限定されるものではない。なお、以下、非接触通信媒体を例にとって本発明を説明するが、本発明は非接触通信媒体に限定されるものではなく、それ以外の種々の通信媒体にも適用し得ることは上記の説明から明らかである。また、以下の各実施例中の成分量「部」は重量部を意味している。   In order to describe the present invention in more detail, examples are shown below, but the present invention is not limited to the following examples. In the following, the present invention will be described by taking a non-contact communication medium as an example. However, the present invention is not limited to the non-contact communication medium, and can be applied to various other communication media. It is clear from In addition, the component amount “parts” in the following examples means parts by weight.

(実施例1)
<金属層転写部材の作製>
支持体1としての厚さ6μmのポリエチレンテレフタレートフィルムの表面に接着層(図示せず)を介して、金属層2としての厚さ20μmの銅板を貼り合わせた。次いで、銅板の表面に下記組成を有する接着剤層塗工液1をバーコーターにより厚さ1μmに塗工し、乾燥して接着剤層3を形成することによって金属層転写部材4を作製した(図1(a)参照)。
(接着剤層塗工液1)
ポリエステル樹脂(バイロン200(商品名);東洋紡(株)製) 75部
ポリエステル樹脂(バイロン300(商品名);東洋紡(株)製) 25部
イソシアネート(クロスネートD70(商品名);大日精化(株)製 ) 1部
トルエン/MEK(1:1) 900部
次いで、得られた金属層転写部材4の金属層2を、接着剤層3側から金属層2の支持体1との界面まで、カッティングプロッターを用いて所定のアンテナのパターンにカットして非接触通信媒体の送受信用アンテナパターン21を形成した(図1(b)参照)。
(Example 1)
<Production of metal layer transfer member>
A copper plate with a thickness of 20 μm as the metal layer 2 was bonded to the surface of a polyethylene terephthalate film with a thickness of 6 μm as the support 1 via an adhesive layer (not shown). Next, the adhesive layer coating liquid 1 having the following composition was applied to the surface of the copper plate with a bar coater to a thickness of 1 μm, and dried to form the adhesive layer 3, thereby preparing the metal layer transfer member 4 ( FIG. 1 (a)).
(Adhesive layer coating solution 1)
Polyester resin (Byron 200 (trade name); manufactured by Toyobo Co., Ltd.) 75 parts Polyester resin (Byron 300 (trade name); manufactured by Toyobo Co., Ltd.) 25 parts Isocyanate (Crosnate D70 (trade name); Dainichi Seika ( 1 part Toluene / MEK (1: 1) 900 parts Next, the metal layer 2 of the obtained metal layer transfer member 4 is moved from the adhesive layer 3 side to the interface with the support 1 of the metal layer 2. Using a cutting plotter, the antenna pattern 21 for transmission / reception of a non-contact communication medium was formed by cutting into a predetermined antenna pattern (see FIG. 1B).

<接着剤層転写部材の作製>
基材シート5としての、一方の面が離型処理された厚さ6μmのポリエチレンテレフタレートフィルムの離型処理面に下記組成を有する接着剤層塗工液2をバーコーターにより厚さ1μmに塗工し、乾燥して接着剤層6を形成することにより接着剤層転写部材7を作製した(図1(c)上部参照)。
(接着剤層塗工液2)
ポリエステル樹脂(バイロン200(商品名);東洋紡(株)製) 75部
ポリエステル樹脂(バイロン300(商品名);東洋紡(株)製) 25部
イソシアネート(クロスネートD70(商品名);大日精化(株)製 ) 1部
トルエン/MEK(1:1) 900部
次いで、得られた接着剤層転写部材7を熱転写プリンター((株)山櫻製;CARD MATE Digica(商品名))にセットし、厚さ1μmのポリエチレンテレフタレートフィルムからなる非接触通信媒体用基材8の表面上に、接着剤層6の一部を、上記の金属層2に形成したアンテナパターン21と同じパターンに熱転写することにより接着パターン層61を形成した(図1(c)および(d)参照)。
<Preparation of adhesive layer transfer member>
The adhesive layer coating solution 2 having the following composition is applied to a thickness of 1 μm by a bar coater on a release treatment surface of a polyethylene terephthalate film having a thickness of 6 μm on which one surface is release-treated as the base sheet 5. Then, the adhesive layer transfer member 7 was produced by forming the adhesive layer 6 by drying (see the upper part of FIG. 1C).
(Adhesive layer coating solution 2)
Polyester resin (Byron 200 (trade name); manufactured by Toyobo Co., Ltd.) 75 parts Polyester resin (Byron 300 (trade name); manufactured by Toyobo Co., Ltd.) 25 parts Isocyanate (Crosnate D70 (trade name); Dainichi Seika ( 1 part Toluene / MEK (1: 1) 900 parts Next, the obtained adhesive layer transfer member 7 was set in a thermal transfer printer (manufactured by Yamagata Corp .; CARD MATE Digitala (trade name)), By thermally transferring a part of the adhesive layer 6 to the same pattern as the antenna pattern 21 formed on the metal layer 2 on the surface of the non-contact communication medium substrate 8 made of a polyethylene terephthalate film having a thickness of 1 μm. An adhesive pattern layer 61 was formed (see FIGS. 1C and 1D).

次いで、金属層転写部材4を通信媒体用基材8の上に、上記接着パターン層61とパターン化金属層21の両パターンの輪郭同士が合致するように位置合わせしつつ重ね合わせ、熱ローラにて加熱、圧着した(図1(e)参照)。   Next, the metal layer transfer member 4 is superposed on the communication medium substrate 8 while aligning the contours of the two patterns of the adhesive pattern layer 61 and the patterned metal layer 21 with each other on the heat roller. And heated and pressed (see FIG. 1 (e)).

その後、金属層転写部材4を通信媒体用基材8から、パターン化金属層21を残してピーリングすることによって所定のアンテナパターンを有する金属層21を非接触通信媒体用基材8の表面に転写した(図1(f)参照)。   Thereafter, the metal layer transfer member 4 is peeled from the communication medium base material 8 while leaving the patterned metal layer 21, thereby transferring the metal layer 21 having a predetermined antenna pattern onto the surface of the non-contact communication medium base material 8. (See FIG. 1 (f)).

得られた金属層21からなるアンテナパターンを観察したところ、抜けや欠け、余分な金属層の付着等もなく、カティングプロッターで形成したパターンが忠実に再現された送受信用アンテナパターンを形成することができた。   When the obtained antenna pattern made of the metal layer 21 was observed, it was possible to form a transmission / reception antenna pattern in which the pattern formed by the cutting plotter was faithfully reproduced without omission, chipping, or adhesion of an extra metal layer. did it.

(実施例2)
実施例1と同様の手順に従い、非接触通信媒体用基材8の表面に接着パターン層61を20mm×20mmの正方形パターンにベタで熱転写し、次いで支持体1上にカッティングプロッターにより金属層2が接着パターン層61と同一パターンに形成された金属層転写部材4のパターン部分21と接着パターン層61とを重ね合わせて、加熱ローラにより加熱、圧着したのち、ピーリングして体積抵抗率の測定サンプルを作製した。得られたサンプルの転写金属層21の体積抵抗率をデジタルマルチメータAD−5523(商品名;エーアンドアイ(株)製)を用いて測定した。測定結果は体積固有抵抗が3×10−6Ω・cmであり、非接触通信媒体の送受信アンテナとして用いた場合、感度が非常に良好であることが確認できた。
(Example 2)
In accordance with the same procedure as in Example 1, the adhesive pattern layer 61 was thermally transferred to a 20 mm × 20 mm square pattern on the surface of the non-contact communication medium substrate 8, and then the metal layer 2 was formed on the support 1 with a cutting plotter. The pattern portion 21 of the metal layer transfer member 4 formed in the same pattern as the adhesive pattern layer 61 and the adhesive pattern layer 61 are superposed, heated and pressure-bonded by a heating roller, and then peeled to obtain a sample for measuring volume resistivity. Produced. The volume resistivity of the transfer metal layer 21 of the obtained sample was measured using a digital multimeter AD-5523 (trade name; manufactured by A & I Co., Ltd.). As a result of the measurement, the volume resistivity was 3 × 10 −6 Ω · cm, and it was confirmed that the sensitivity was very good when used as a transmission / reception antenna of a non-contact communication medium.

(実施例3)
金属層2として厚さ2μmの銅箔を貼り合わせたものを用いた以外は実施例1と同様にして、金属層転写部材4を得た。得られた金属層転写部材を用いて実施例1と同様にしてアンテナパターンを非接触通信媒体用基材8上に形成し、アンテナパターンを観察したところ、抜けや欠け、余分な金属層の付着等もなく、カッティングプロッターで形成したパターンが忠実に再現された送受信用アンテナパターンを形成することができた。 また、本実施例で得られた金属層転写部材4を用いて、実施例2と同様にして体積抵抗率の測定サンプルを作製し、実施例2と同様の方法で体積抵抗率を測定したところ、8×10−6Ω・cmであり、非接触通信媒体の送受信アンテナとして用いた場合、感度が良好であることが確認できた。
(Example 3)
A metal layer transfer member 4 was obtained in the same manner as in Example 1 except that a 2 μm thick copper foil was used as the metal layer 2. Using the obtained metal layer transfer member, an antenna pattern was formed on the non-contact communication medium substrate 8 in the same manner as in Example 1, and the antenna pattern was observed. Thus, it was possible to form a transmission / reception antenna pattern in which the pattern formed by the cutting plotter was faithfully reproduced. Further, using the metal layer transfer member 4 obtained in this example, a volume resistivity measurement sample was prepared in the same manner as in Example 2, and the volume resistivity was measured in the same manner as in Example 2. 8 × 10 −6 Ω · cm, and when used as a transmission / reception antenna for a non-contact communication medium, it was confirmed that the sensitivity was good.

本発明の実施の形態に係る非接触通信媒体の製造工程を説明する模式的断面図である。It is typical sectional drawing explaining the manufacturing process of the non-contact communication medium which concerns on embodiment of this invention.

符号の説明Explanation of symbols

1 支持体
2 金属層
3 接着剤層
4 金属層転写部材
5 基材シート
6 接着剤層
7 接着剤層転写部材
8 通信媒体用基材
21 金属層のアンテナと同一のパターンを有する部分
31 接着剤層のアンテナと同一のパターンを有する部分
61 接着パターン層
DESCRIPTION OF SYMBOLS 1 Support body 2 Metal layer 3 Adhesive layer 4 Metal layer transfer member 5 Base material sheet 6 Adhesive layer 7 Adhesive layer transfer member 8 Base material for communication media 21 Part which has the same pattern as the antenna of a metal layer 31 Adhesive A portion having the same pattern as the antenna of the layer 61 Adhesive pattern layer

Claims (4)

少なくとも通信媒体用基材とアンテナとを有する通信媒体の製造方法であって、支持体の一方の面に金属層、さらにその上に接着剤層を有してなる金属層転写部材の該金属層および接着剤層を該アンテナと同一のパターンに打ち抜く工程、通信媒体用基材の表面に接着剤を該アンテナと同一のパターンに熱転写して接着パターン層を形成する工程、および該接着パターン層上に該金属層のアンテナと同一のパターンに打ち抜かれた部分を転写してアンテナを形成する工程を有することを特徴とする通信媒体の製造方法。   A method for producing a communication medium having at least a base material for a communication medium and an antenna, the metal layer of a metal layer transfer member having a metal layer on one side of a support and an adhesive layer thereon Punching the adhesive layer into the same pattern as the antenna, forming the adhesive pattern layer by thermally transferring the adhesive to the same pattern as the antenna on the surface of the base material for the communication medium, and on the adhesive pattern layer And a step of forming an antenna by transferring a portion of the metal layer punched into the same pattern as the antenna. 前記通信媒体が、非接触通信媒体用基材、送受信アンテナ、およびICチップを有する非接触通信媒体である請求項1記載の通信媒体の製造方法。   The method of manufacturing a communication medium according to claim 1, wherein the communication medium is a non-contact communication medium having a non-contact communication medium substrate, a transmission / reception antenna, and an IC chip. 少なくとも通信媒体用基材とアンテナとを有する通信媒体であって、該アンテナが、支持体の一方の面に金属層を、さらにその上に接着剤層を有してなる金属層転写部材の該金属層および接着剤層を該アンテナと同一のパターンに打ち抜き、通信媒体用基材に接着剤を該アンテナと同一のパターンに熱転写して接着パターン層を形成し、さらに該接着パターン層上に該金属層のアンテナと同一のパターンに打ち抜かれた部分を転写することにより形成されていることを特徴とする通信媒体。   A communication medium having at least a base material for a communication medium and an antenna, wherein the antenna has a metal layer on one surface of a support and an adhesive layer on the metal layer. The metal layer and the adhesive layer are punched in the same pattern as the antenna, and the adhesive is thermally transferred to the same pattern as the antenna on the base material for the communication medium to form an adhesive pattern layer. A communication medium formed by transferring a portion punched into the same pattern as an antenna of a metal layer. 非接触通信媒体用基材、送受信アンテナ、およびICチップを有する非接触通信媒体である請求項3記載の通信媒体。   The communication medium according to claim 3, which is a non-contact communication medium having a non-contact communication medium substrate, a transmission / reception antenna, and an IC chip.
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