JP2008105420A5 - - Google Patents

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Publication number
JP2008105420A5
JP2008105420A5 JP2007256485A JP2007256485A JP2008105420A5 JP 2008105420 A5 JP2008105420 A5 JP 2008105420A5 JP 2007256485 A JP2007256485 A JP 2007256485A JP 2007256485 A JP2007256485 A JP 2007256485A JP 2008105420 A5 JP2008105420 A5 JP 2008105420A5
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JP
Japan
Prior art keywords
decorative sheet
dimensional processing
curable resin
ionizing radiation
radiation curable
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JP2007256485A
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Japanese (ja)
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JP4985288B2 (en
JP2008105420A (en
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Priority to JP2007256485A priority Critical patent/JP4985288B2/en
Priority claimed from JP2007256485A external-priority patent/JP4985288B2/en
Publication of JP2008105420A publication Critical patent/JP2008105420A/en
Publication of JP2008105420A5 publication Critical patent/JP2008105420A5/ja
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Claims (8)

支持体の上に少なくとも表面保護層を積層してなる三次元加工用加飾シートであって、該支持体のＡＳＴＭ Ｄ６４８法による熱変形温度より４０℃高い温度において該三次元加工用加飾シートが３００％を超える破断伸度（ＪＩＳ Ｋ ７１２７に準拠）を有し、かつ該表面保護層が電離放射線硬化性樹脂組成物を架橋硬化してなり、０．２〜６．０μｍの膜厚を有することを特徴とする三次元加工用加飾シート。   A decorative sheet for three-dimensional processing formed by laminating at least a surface protective layer on a support, wherein the decorative sheet for three-dimensional processing is at a temperature 40 ° C higher than the thermal deformation temperature of the support according to ASTM D648 method. Has a breaking elongation exceeding 300% (based on JIS K 7127), and the surface protective layer is obtained by crosslinking and curing the ionizing radiation curable resin composition, and has a film thickness of 0.2 to 6.0 μm. A decorative sheet for three-dimensional processing, comprising: 以下の測定条件で測定した１４０℃における前記表面保護層の貯蔵弾性率が７．７×１０5〜１．２×１０8Ｐａの範囲であることを特徴とする請求項１に記載の三次元加工用加飾シート。
貯蔵弾性率の測定条件：ＪＩＳ Ｋ７２４４−１及び７２４４−４に準拠し、前記電離放射線硬化性樹脂組成物を架橋硬化して製膜した幅１０ｍｍ、厚さ１５μｍのシートをクランプ間距離１０ｍｍ、開始温度３０℃、終了温度１８０℃、昇温速度５℃／分、測定周波数１Ｈｚにて測定する。 3. The three-dimensional image according to claim 1, wherein the storage elastic modulus of the surface protective layer at 140 ° C. measured under the following measurement conditions is in the range of 7.7 × 10 5 to 1.2 × 10 8 Pa. Decorative sheet for processing.
Storage elastic modulus measurement conditions: In accordance with JIS K7244-1 and 7244-4, a sheet of 10 mm width and 15 μm thickness formed by crosslinking and curing the ionizing radiation curable resin composition was 10 mm in distance between clamps. The measurement is performed at a temperature of 30 ° C., an end temperature of 180 ° C., a temperature increase rate of 5 ° C./min, and a measurement frequency of 1 Hz. 前記電離放射線硬化性樹脂組成物が電離放射線硬化性樹脂と熱可塑性樹脂を７５：２５〜２０：８０の比率（質量比）で含む樹脂組成物である請求項１又は２に記載の三次元加工用加飾シート。   The three-dimensional processing according to claim 1 or 2, wherein the ionizing radiation curable resin composition is a resin composition containing an ionizing radiation curable resin and a thermoplastic resin in a ratio (mass ratio) of 75:25 to 20:80. Decorative sheet. 前記支持体と前記表面保護層との間に、さらに透明熱可塑性樹脂層を設けてなる請求項１〜３のいずれかに記載の三次元加工用加飾シート。   The decorative sheet for three-dimensional processing according to any one of claims 1 to 3, wherein a transparent thermoplastic resin layer is further provided between the support and the surface protective layer. 前記支持体と前記透明熱可塑性樹脂層との間に、さらに第２熱可塑性樹脂層を設けてなる請求項４に記載の三次元加工用加飾シート。   The decorative sheet for three-dimensional processing according to claim 4, wherein a second thermoplastic resin layer is further provided between the support and the transparent thermoplastic resin layer. 前記電離放射線硬化性樹脂が電子線硬化性樹脂である請求項３〜５のいずれかに記載の三次元加工用加飾シート。   The decorative sheet for three-dimensional processing according to any one of claims 3 to 5, wherein the ionizing radiation curable resin is an electron beam curable resin. 三次元加工がインサート成形である請求項１〜６のいずれかに記載の三次元加工用加飾シート。   The decorative sheet for three-dimensional processing according to any one of claims 1 to 6, wherein the three-dimensional processing is insert molding. 樹脂成形物に請求項１〜７のいずれかに記載の三次元加工用加飾シートを一体化させてなる加飾樹脂成形体。A decorative resin molded product obtained by integrating the decorative sheet for three-dimensional processing according to any one of claims 1 to 7 with a resin molded product.
JP2007256485A 2006-09-29 2007-09-28 Decorative sheet for 3D processing Active JP4985288B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007256485A JP4985288B2 (en) 2006-09-29 2007-09-28 Decorative sheet for 3D processing

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2006269913 2006-09-29
JP2006269913 2006-09-29
JP2007256485A JP4985288B2 (en) 2006-09-29 2007-09-28 Decorative sheet for 3D processing

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2012021216A Division JP2012116200A (en) 2006-09-29 2012-02-02 Decorative sheet for three-dimensional processing

Publications (3)

Publication Number Publication Date
JP2008105420A JP2008105420A (en) 2008-05-08
JP2008105420A5 true JP2008105420A5 (en) 2008-06-19
JP4985288B2 JP4985288B2 (en) 2012-07-25

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Family Applications (1)

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JP2007256485A Active JP4985288B2 (en) 2006-09-29 2007-09-28 Decorative sheet for 3D processing

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JP (1) JP4985288B2 (en)

Families Citing this family (20)

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Publication number Priority date Publication date Assignee Title
JP5272322B2 (en) * 2006-03-31 2013-08-28 大日本印刷株式会社 Resin composition and decorative sheet using the resin composition
DE102008023499A1 (en) 2008-05-14 2009-11-19 Bayer Materialscience Ag Printing ink or printing varnish, coated laminate therewith and process for producing a laminate
JP2009274378A (en) * 2008-05-16 2009-11-26 Sanwa Screen Meiban:Kk Film for film insert molding and molded article
JP5487685B2 (en) * 2008-06-30 2014-05-07 大日本印刷株式会社 Decorative sheet, decorative resin molded product manufacturing method, and decorative resin molded product
JP5585011B2 (en) * 2008-06-30 2014-09-10 大日本印刷株式会社 Decorative sheet, decorative resin molded product manufacturing method, and decorative resin molded product
EP2298526B1 (en) * 2008-06-30 2019-04-03 Dai Nippon Printing Co., Ltd. Decorative sheet, process for producing decorative resin molded product
JP5267018B2 (en) * 2008-09-30 2013-08-21 大日本印刷株式会社 Decorative sheet, decorative resin molded product manufacturing method, and decorative resin molded product
JP5267017B2 (en) * 2008-09-30 2013-08-21 大日本印刷株式会社 Decorative sheet, decorative resin molded product manufacturing method, and decorative resin molded product
JP5589297B2 (en) * 2009-03-31 2014-09-17 大日本印刷株式会社 Decorative sheet, decorative resin molded product manufacturing method, and decorative resin molded product
CN101987523A (en) * 2009-07-31 2011-03-23 康准电子科技（昆山）有限公司 Composite material product and forming method thereof
JP5476903B2 (en) * 2009-09-30 2014-04-23 大日本印刷株式会社 Decorative sheet and decorative resin molded product using the same
JP5402607B2 (en) * 2009-12-18 2014-01-29 東洋紡株式会社 Hard coat film for molding and molded body
JP5831086B2 (en) * 2010-09-29 2015-12-09 大日本印刷株式会社 Decorative sheet and decorative molded product
JP5724525B2 (en) * 2010-09-30 2015-05-27 大日本印刷株式会社 Cosmetic sheet and cosmetic material
JP5818489B2 (en) * 2011-04-12 2015-11-18 積水化学工業株式会社 Combustion resistant sheet
US9757973B2 (en) 2012-06-08 2017-09-12 Toray Industries, Inc. Film for decorative forming and production method for decorative formed body
TW201431683A (en) * 2012-12-27 2014-08-16 Mitsubishi Plastics Inc Molding resin laminate and molded article
WO2014109372A1 (en) * 2013-01-10 2014-07-17 三菱樹脂株式会社 Molded body and method for producing same
JP6269125B2 (en) * 2014-02-07 2018-01-31 日油株式会社 Anti-glare film for insert molding
JP6574088B2 (en) 2014-12-24 2019-09-11 スリーエム イノベイティブ プロパティズ カンパニー Film and decorative film capable of coating article having three-dimensional shape by heat stretching

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4463919B2 (en) * 2000-01-18 2010-05-19 大日本印刷株式会社 Painting sheet and injection molding simultaneous painting method
EP1731285B1 (en) * 2004-03-30 2011-11-30 Dai Nippon Printing Co., Ltd. Sheet for decoration simultaneous with injection molding and decorated resin molding

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