JP2008098327A - Method of processing inside of holes of printed circuit board - Google Patents

Method of processing inside of holes of printed circuit board Download PDF

Info

Publication number
JP2008098327A
JP2008098327A JP2006277113A JP2006277113A JP2008098327A JP 2008098327 A JP2008098327 A JP 2008098327A JP 2006277113 A JP2006277113 A JP 2006277113A JP 2006277113 A JP2006277113 A JP 2006277113A JP 2008098327 A JP2008098327 A JP 2008098327A
Authority
JP
Japan
Prior art keywords
printed circuit
circuit board
hole
processing
processing solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2006277113A
Other languages
Japanese (ja)
Inventor
Satoyuki Miyazaki
智行 宮崎
Tadashi Iida
飯田正
Yoshimasa Tashiro
田代義昌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP2006277113A priority Critical patent/JP2008098327A/en
Publication of JP2008098327A publication Critical patent/JP2008098327A/en
Pending legal-status Critical Current

Links

Images

Landscapes

  • Printing Elements For Providing Electric Connections Between Printed Circuits (AREA)
  • Manufacturing Of Printed Wiring (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of processing the inside of holes of a printed circuit board that reliably allows a processing solution to pass through through-holes with a hole diameter of 0.3 mm or less and an aspect ratio of over 15, and allows the processing solution to pass through each hole distributed in the surface evenly and uniformly. <P>SOLUTION: Liquid current directed to a predetermined direction flows on one surface of the printed circuit board which is soaked in a processing solution, and a difference in flow velocity arises between the front and back of the printed circuit board. According to Bernoulli's theorem, a surface with a faster flow velocity has a negative pressure, thus facilitating drawing and flowing the processing solution into the through-holes. In order to flow a liquid current in a predetermined direction on one surface of the printed circuit board, a nozzle is disposed at a position along one surface of the printed circuit board, and the outlet of the nozzle is directed to a direction substantially parallel with the printed circuit board for processing solution discharge. Furthermore, a current plate is provided at a position along one surface of the printed circuit board, and the processing solution is flown into between the printed circuit board and current plate. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、プリント基板にあけた貫通穴内に水や薬液等の処理液を容易に通すための処理方法に関するものである。   The present invention relates to a processing method for easily passing a processing solution such as water or a chemical solution through a through hole formed in a printed circuit board.

プリント基板にあけた貫通穴内を水や薬液等で洗浄・処理しようとした場合、図4のように穴に対して垂直に処理液を吹き付ける方法が広く用いられている(特許文献1参照)。   When cleaning and processing the inside of a through hole formed in a printed circuit board with water or a chemical solution, a method of spraying a processing liquid perpendicularly to the hole as shown in FIG. 4 is widely used (see Patent Document 1).

特開2003−37351号公報Japanese Patent Laid-Open No. 2003-37351

上記特許文献1の方法では、プリント基板のアスペクト比(板厚/穴径)が大きくなるほど、穴内に処理液の残りや異物の残渣等の処理不足が発生しやすくなり、これに対して効率良く小径穴内を処理する方法が無かった。   In the method of Patent Document 1, as the aspect ratio (thickness / hole diameter) of the printed circuit board increases, insufficient processing such as processing liquid residue or foreign substance residue is likely to occur in the hole, and this is more efficient. There was no way to treat the inside of the small hole.

本発明の目的は、プリント基板のアスペクト比が大きくなっても、貫通穴内に効率良く、且つ確実に処理液を通すことと、面内に分布する各穴に対して均一にムラ無く処理液を通すことができるプリント基板の穴内処理方法を提供することにある。   The object of the present invention is to pass the treatment liquid efficiently and surely through the through-holes even when the aspect ratio of the printed circuit board is large, and to uniformly distribute the treatment liquid to each hole distributed in the surface. An object of the present invention is to provide an in-hole processing method for a printed circuit board that can be passed.

上記目的を達成するために本発明は、処理液中に浸漬させたプリント基板の片面に一定方向の液流を起こすことを特徴とし、プリント基板の表裏に流速差を生じさせて、処理液を引き込み流す。プリント基板の片面に一定方向の液流を起こすために、プリント基板の片面に沿った位置にノズルを配置し、ノズルの噴き出し口をプリント基板とほぼ平行になるように向け処理液を吐出する。さらに、プリント基板の片面に沿った位置に整流板を設け、プリント基板と整流板の間に処理液を流し込む。   In order to achieve the above object, the present invention is characterized in that a liquid flow in a certain direction is caused on one side of a printed circuit board immersed in the processing liquid, and a flow rate difference is generated between the front and back surfaces of the printed circuit board. Draw in. In order to generate a liquid flow in a certain direction on one side of the printed circuit board, a nozzle is arranged at a position along one side of the printed circuit board, and the processing liquid is discharged so that the nozzle outlet is substantially parallel to the printed circuit board. Further, a rectifying plate is provided at a position along one side of the printed circuit board, and the processing liquid is poured between the printed circuit board and the rectifying plate.

プリント基板の片面にだけ処理液の流れを発生させるため、流速が速い方が反対面に比べ圧力が低くなり、貫通穴を介して処理液が吸い寄せられる。また、プリント基板表裏の流速差が大きくなるほど、その効果も大きくなり、貫通穴を通る処理液量も増加するため処理能力が拡大する。さらに広い面で一定の流速が得られるほどプリント基板の面内が同じ処理条件となるため、プリント基板の片面に沿った位置に整流板を設け、プリント基板と整流板の間に処理液を流し込むことで、発生させる液流速を広い範囲で一定に保つことができ、プリント基板の処理がより均一となる。ノズルからの吐出量が一定であれば、整流板を基板に近づけるほど処理液の流速が増し効果も増大する。また、穴径が0.3mm以下でアスペクト比が15を超える貫通穴内に効率良く処理液を通すことが可能になる。   Since the flow of the processing liquid is generated only on one side of the printed circuit board, the higher the flow velocity, the lower the pressure compared to the opposite side, and the processing liquid is sucked through the through hole. In addition, as the flow rate difference between the front and back of the printed circuit board increases, the effect increases, and the processing capacity increases because the amount of processing liquid passing through the through hole increases. Since the surface of the printed circuit board has the same processing conditions as a constant flow velocity is obtained on a wider surface, a flow straightening plate is provided at a position along one side of the printed circuit board, and the processing liquid is poured between the printed circuit board and the flow straightening plate. The generated liquid flow rate can be kept constant over a wide range, and the processing of the printed circuit board becomes more uniform. If the discharge amount from the nozzle is constant, the flow rate of the processing liquid increases and the effect increases as the rectifying plate is brought closer to the substrate. Further, it becomes possible to efficiently pass the treatment liquid into the through hole having a hole diameter of 0.3 mm or less and an aspect ratio exceeding 15.

以下に、本発明の一実施形態を、図面を用いて詳細に説明する。 Hereinafter, an embodiment of the present invention will be described in detail with reference to the drawings.

図1を用いて、実施例1を説明する。   Example 1 will be described with reference to FIG.

600×500mmのガラスエポキシ製プリント基板4を板厚3.8mmと5.3mmの2種準備し、それぞれにドリル径0.25mmで貫通穴5をあけ、アスペクト比15.2とアペクト比21.2のサンプルを製作した。また、水平搬送タイプ処理装置のコンベアロール2の横には処理液の噴き出しノズル1を設置した。この際、噴き出しノズル1はプリント基板4とほぼ平行に処理液が流れるようにセットし(例えば、噴き出しノズル1を、プリント基板4に対して−45度から+45度の傾きになるように設置する。望ましくはプリント基板4と平行でもよい。)、処理液が15L/分でノズルから噴き出す流量に調整した。   Two types of glass epoxy printed circuit board 4 of 600 × 500 mm having a plate thickness of 3.8 mm and 5.3 mm are prepared, and a through hole 5 is formed in each with a drill diameter of 0.25 mm, an aspect ratio of 15.2 and an aspect ratio of 21. Two samples were made. Further, a jet nozzle 1 for processing liquid was installed beside the conveyor roll 2 of the horizontal transfer type processing apparatus. At this time, the ejection nozzle 1 is set so that the processing liquid flows substantially parallel to the printed circuit board 4 (for example, the ejection nozzle 1 is installed so as to have an inclination of −45 degrees to +45 degrees with respect to the printed circuit board 4. Desirably, it may be parallel to the printed circuit board 4), and the flow rate of the processing liquid is adjusted to 15 L / min.

この状態で処理液が貫通穴内を流れることを確認するため、処理液として無電解銅めっき液を使用しめっき銅を析出させ、プリント基板表面と穴内とで銅膜の成長具合を断面研磨後測定し比較した。穴内をめっき液が一定量以上通っていれば表面と穴内は同一のめっき厚になるが、通っていないか通っている量が少なければ穴内の銅イオンが消費され銅膜の成長は停止するか、または表面より反応が遅くなり、穴内部のめっき厚は薄くなってしまう。   In order to confirm that the treatment liquid flows in the through hole in this state, use an electroless copper plating solution as the treatment liquid to deposit plated copper, and measure the degree of growth of the copper film between the printed circuit board surface and the inside of the hole after cross-sectional polishing. And compared. If the plating solution passes through the hole more than a certain amount, the surface and the inside of the hole will have the same plating thickness, but if it does not pass or if the passing amount is small, the copper ions in the hole are consumed and the copper film growth stops Or, the reaction is slower than the surface, and the plating thickness inside the hole becomes thin.

2種製作した前記プリント基板4に、縦型ディップ式の銅めっき装置を用いコンディショニング、ソフトエッチング、触媒付与、活性化といった一般的な前処理を施した後、前記水平搬送タイプの処理装置で無電解銅めっきを施した。このときのコンベア搬送速度は0.4m/分で搬送し、トータルめっき時間が2時間30分になるまで処理を行なった。無電解銅めっき液は、プリント基板で一般的に使用される厚付け用のめっき液を使用した。   The two types of printed circuit boards 4 are subjected to general pretreatments such as conditioning, soft etching, catalyst application, and activation using a vertical dip type copper plating apparatus, and then the horizontal transfer type processing apparatus is used. Electrolytic copper plating was applied. The conveyor conveyance speed at this time was conveyed at 0.4 m / min, and processing was performed until the total plating time reached 2 hours 30 minutes. As the electroless copper plating solution, a plating solution for thickening generally used in a printed circuit board was used.

このように製作した2種のプリント基板の貫通穴部をそれぞれ50穴づつ断面研磨し、プリント基板の表面部に析出しためっき厚と貫通穴中央部に析出しためっき厚を金属顕微鏡により測定した。この結果、アスペクト比15.2のサンプルでは表面部4.91μm、貫通穴中央部4.93μmの銅が析出しており、表面と穴内がほぼ同等のめっき厚で穴中央部のつきまわり性(穴中央部めっき厚/表面部めっき厚×100)としては100%であったが、アスペクト比21.2のサンプルでは表面部4.85μm、貫通穴中央部4.16μmと、つきまわり性が86%となった。   The through hole portions of the two types of printed circuit boards thus manufactured were each subjected to cross section polishing by 50 holes, and the plating thickness deposited on the surface portion of the printed circuit board and the plating thickness deposited on the central portion of the through hole were measured with a metal microscope. As a result, in the sample having an aspect ratio of 15.2, copper having a surface portion of 4.91 μm and a through-hole center portion of 4.93 μm is deposited, and the surface and the inside of the hole have approximately the same plating thickness and the throwing power of the center portion of the hole ( The hole center portion plating thickness / surface portion plating thickness × 100) was 100%, but in the sample having an aspect ratio of 21.2, the surface portion was 4.85 μm and the through hole center portion was 4.16 μm. %.

また、プリント基板に対して垂直に処理液を噴き付ける従来技術で同様に行なった比較評価では、アスペクト比15.2のサンプルで表面部4.87μmに対して貫通穴中央部3.08μmと、つきまわり性63%であったことから、本発明により貫通穴内の処理液通過量を増加できていることが証明できた。   Moreover, in the comparative evaluation similarly performed by the prior art which sprays a process liquid perpendicularly | vertically with respect to a printed circuit board, a through-hole center part 3.08micrometer with respect to the surface part 4.87micrometer with the sample of aspect ratio 15.2; Since the throwing power was 63%, it was proved that the amount of treatment liquid passing through the through hole could be increased by the present invention.

図2を用い実施例2を説明する。   A second embodiment will be described with reference to FIG.

600×500mmで板厚5.3mmのガラスエポキシ製プリント基板4を準備し、それにドリル径0.25mmで貫通穴5をあけたアスペクト比21.2のサンプルを製作した。また、水平搬送タイプ処理装置のコンベアロール2の横に、プリント基板と水平に整流板6を設置した。プリント基板と整流板の距離は5mmとし、この間に処理液を流し込むため整流板の一部を45°の角度で折り曲げ、そこへ向けてノズル1から処理液を噴き出す構造とした。処理液の吐出量は実施例1と同様に15L/分とした。これにより噴き出された処理液はプリント基板と整流板の間に集められ、一定の流速でプリント基板に沿って流すことができる。   A glass epoxy printed circuit board 4 of 600 × 500 mm and a thickness of 5.3 mm was prepared, and a sample with an aspect ratio of 21.2 was prepared by drilling a through hole 5 with a drill diameter of 0.25 mm. Moreover, the baffle plate 6 was installed beside the printed circuit board beside the conveyor roll 2 of the horizontal conveyance type processing apparatus. The distance between the printed circuit board and the rectifying plate was 5 mm, and a part of the rectifying plate was bent at an angle of 45 ° in order to flow the processing liquid therebetween, and the processing liquid was jetted from the nozzle 1 toward the rectifying plate. The discharge rate of the treatment liquid was 15 L / min as in Example 1. As a result, the sprayed processing liquid is collected between the printed circuit board and the current plate, and can flow along the printed circuit board at a constant flow rate.

この状態で処理液が貫通穴内を流れることを確認するため、実施例1と同様、処理液として無電解銅めっき液を使用した。   In order to confirm that the treatment liquid flows in the through hole in this state, an electroless copper plating solution was used as the treatment liquid as in Example 1.

前記プリント基板4に、縦型ディップ式の銅めっき装置を用いコンディショニング、ソフトエッチング、触媒付与、活性化といった一般的な前処理を施した後、前記水平搬送タイプの処理装置で無電解銅めっきを施した。このときのコンベア搬送速度は0.4m/分で搬送し、トータルめっき時間が2時間30分になるまで処理を行なった。無電解銅めっき液は、プリント基板で一般的に使用される厚付け用のめっき液を使用した。   The printed circuit board 4 is subjected to general pretreatments such as conditioning, soft etching, catalyst application, and activation using a vertical dip type copper plating apparatus, and then electroless copper plating is performed using the horizontal transfer type processing apparatus. gave. The conveyor conveyance speed at this time was conveyed at 0.4 m / min, and processing was performed until the total plating time reached 2 hours 30 minutes. As the electroless copper plating solution, a plating solution for thickening generally used in a printed circuit board was used.

このように製作したプリント基板を断面研磨し、プリント基板の表面に析出しためっき厚と貫通穴中央部に析出しためっき厚を金属顕微鏡により測定した。この結果、アスペクト比21.2のサンプルにおいて表面部4.99μm、貫通穴中央部4.94μmの銅が析出しており、表面と穴内がほぼ同等のめっき厚で穴中央部のつきまわり性(穴中央部めっき厚/表面部めっき厚)としては99%で、実施例1よりも向上した。   The printed board thus produced was subjected to cross-sectional polishing, and the plating thickness deposited on the surface of the printed board and the plating thickness deposited at the center of the through hole were measured with a metal microscope. As a result, in the sample having an aspect ratio of 21.2, copper having a surface portion of 4.99 μm and a center portion of the through hole of 4.94 μm was deposited, and the surface and the inside of the hole had almost the same plating thickness and the throwing power of the center portion of the hole ( The hole center portion plating thickness / surface portion plating thickness) was 99%, which was higher than Example 1.

従って、整流板を設置することにより、プリント基板の貫通穴に対する処理効果がさらに向上することがわかる。これらを表1にまとめる。   Therefore, it can be seen that the processing effect on the through hole of the printed circuit board is further improved by installing the current plate. These are summarized in Table 1.

Figure 2008098327
Figure 2008098327

実施例1および実施例2では、処理液中に浸漬させたプリント基板の片面に一定方向の液流を起こすことを特徴とし、プリント基板の表裏に流速差を生じさせることで、ベルヌーイの定理から図3のように流速が速い面が陰圧となり、貫通穴内に容易に処理液を引き込み流すことができる。プリント基板の片面に一定方向の液流を起こすために、プリント基板の片面に沿った位置にノズルを配置し、ノズルの噴き出し口をプリント基板とほぼ平行になるように向け処理液を吐出する。さらに、プリント基板の片面に沿った位置に整流板を設け、プリント基板と整流板の間に処理液を流し込むことで、発生させる液流速を広い範囲で一定に保つことができ、プリント基板の穴内処理が面内でより均一となり効果が上がる。   Example 1 and Example 2 are characterized in that a liquid flow in a certain direction is caused on one side of a printed circuit board immersed in the processing liquid, and by generating a flow velocity difference between the front and back of the printed circuit board, from Bernoulli's theorem As shown in FIG. 3, the surface having a high flow rate becomes negative pressure, and the processing liquid can be easily drawn into the through hole. In order to generate a liquid flow in a certain direction on one side of the printed circuit board, a nozzle is arranged at a position along one side of the printed circuit board, and the processing liquid is discharged so that the nozzle outlet is substantially parallel to the printed circuit board. Furthermore, by providing a current plate at a position along one side of the printed circuit board and pouring the processing liquid between the printed circuit board and the current plate, the generated liquid flow rate can be kept constant over a wide range, and the processing in the hole of the printed circuit board can be performed. It becomes more uniform in the plane and the effect is improved.

また、穴径が0.3mm以下で、アスペクト比が15を超える貫通穴内に効率良く、且つ確実に処理液を通すことと、面内に分布する各穴に対して均一にムラ無く処理液を通すことができる。   In addition, when the hole diameter is 0.3 mm or less and the aspect ratio exceeds 15, the treatment liquid is efficiently and surely passed, and the treatment liquid is uniformly and uniformly distributed to each hole distributed in the surface. Can pass through.

請求項1に記載した処理方法の断面図Sectional drawing of the processing method of Claim 1 請求項2に記載した整流板を用いた処理方法の断面図Sectional drawing of the processing method using the baffle plate described in Claim 2 図1および図2の貫通穴部を拡大した液流方向の概略図Schematic diagram of the liquid flow direction in which the through hole portion of FIGS. 1 and 2 is enlarged 従来処理方法の断面図Cross-sectional view of conventional processing method

符号の説明Explanation of symbols

1 スプレーノズル
2 コンベアロール
3 押さえロール
4 プリント基板
5 プリント基板の貫通穴
6 整流板
DESCRIPTION OF SYMBOLS 1 Spray nozzle 2 Conveyor roll 3 Pressing roll 4 Printed circuit board 5 Through hole of printed circuit board 6 Current plate

Claims (2)

プリント基板の水平搬送タイプの処理装置における穴内処理方法において、
処理液中でプリント基板の片面に設置されたノズルによって、前記プリント基板の表裏に流速差を生じさせるように前記ノズルから処理液を噴き出し、
前記プリント基板にあいた貫通穴内に前記処理液を通すことを特徴とするプリント基板の穴内処理方法。
In the processing method in a hole in a horizontal transfer type processing apparatus of a printed circuit board,
With the nozzle installed on one side of the printed circuit board in the processing liquid, the processing liquid is ejected from the nozzle so as to cause a flow velocity difference between the front and back of the printed circuit board.
An in-hole processing method for a printed circuit board, wherein the processing liquid is passed through a through hole formed in the printed circuit board.
請求項1記載のプリント基板の穴内処理方法において、
整流板を前記プリント基板とほぼ平行に設置し、前記整流板と前記プリント基板との間に処理液を流し込んで、前記処理液を前記プリント基板とほぼ水平に流し、前記プリント基板の表裏に流速差を生じさせることを特徴とするプリント基板の穴内処理方法。
In the printed circuit board in-hole processing method according to claim 1,
A rectifying plate is installed substantially parallel to the printed circuit board, a processing liquid is poured between the rectifying plate and the printed circuit board, the processing liquid is flowed substantially horizontally with the printed circuit board, and a flow velocity is applied to the front and back of the printed circuit board. A method for in-hole processing of a printed circuit board characterized by causing a difference.
JP2006277113A 2006-10-11 2006-10-11 Method of processing inside of holes of printed circuit board Pending JP2008098327A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006277113A JP2008098327A (en) 2006-10-11 2006-10-11 Method of processing inside of holes of printed circuit board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006277113A JP2008098327A (en) 2006-10-11 2006-10-11 Method of processing inside of holes of printed circuit board

Publications (1)

Publication Number Publication Date
JP2008098327A true JP2008098327A (en) 2008-04-24

Family

ID=39380874

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006277113A Pending JP2008098327A (en) 2006-10-11 2006-10-11 Method of processing inside of holes of printed circuit board

Country Status (1)

Country Link
JP (1) JP2008098327A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02150095A (en) * 1988-11-30 1990-06-08 C B C Eng Kk Method of treating inside of through-hole of printed board
JPH0350792A (en) * 1989-07-19 1991-03-05 Canon Inc Very small hole treatment for printed board and device therefor
JPH0354887A (en) * 1989-07-24 1991-03-08 Canon Inc Method and apparatus for treatment of fine hole in printed board

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02150095A (en) * 1988-11-30 1990-06-08 C B C Eng Kk Method of treating inside of through-hole of printed board
JPH0350792A (en) * 1989-07-19 1991-03-05 Canon Inc Very small hole treatment for printed board and device therefor
JPH0354887A (en) * 1989-07-24 1991-03-08 Canon Inc Method and apparatus for treatment of fine hole in printed board

Similar Documents

Publication Publication Date Title
KR101917848B1 (en) suction plating device
KR20100019481A (en) Apparatus and method for the electrolytic treatment of a plate-shaped product
TWI280990B (en) Etching device for electroplating substrate
CN112680760A (en) Electroplating device and electroplating method for printed circuit board
JP2008098327A (en) Method of processing inside of holes of printed circuit board
JP2011032538A (en) Electroless plating method
JP6710402B2 (en) Method for producing film-forming substrate and surface treatment agent
JPH11515142A (en) Method and apparatus for treating holes or depressions extending in a workpiece with a liquid treatment agent
JP6195998B2 (en) Processing module for horizontal wet chemical processing equipment for large substrates
JP4920365B2 (en) Treatment tank
JPH0697632A (en) Method for oxygen feeding to electroless plating solution and equipment
KR20220100539A (en) Manufacturing Method of Roll-to-roll Flexible Printed Circuit Board including Inkjet Printing Process
JP2007197788A (en) Electrodeposition coating method for metal flat plate
JPH0354887A (en) Method and apparatus for treatment of fine hole in printed board
JP2644848B2 (en) Hole processing jig
CN103097584A (en) Device and method for spraying a surface of a substrate
JP5146352B2 (en) Surface roughening device for build-up substrate insulation layer
KR102575905B1 (en) plating apparatus
JP3450179B2 (en) Surface treatment equipment
US20170100753A1 (en) Sheet material surface treatment method and system
JP2014114483A (en) Snout floating scum removal device for molten zinc plating line
JP3220470U (en) Resin film wet processing equipment
JP2011018780A (en) Surface roughening device of build-up substrate insulating layer
JP6127726B2 (en) Plating equipment
JP2005101304A (en) Method for manufacturing wiring board

Legal Events

Date Code Title Description
A621 Written request for application examination

Effective date: 20090129

Free format text: JAPANESE INTERMEDIATE CODE: A621

A131 Notification of reasons for refusal

Effective date: 20110531

Free format text: JAPANESE INTERMEDIATE CODE: A131

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110531

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20111004