JP2008019185A - Oxidation hair dye composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an oxidation hair dye composition which has good spreadability on hairs, when applied to the hairs, is excellent in usability, prevents the damages of the hairs during the application, has good finger passableness, imparts the original natural gloss of the hairs, and is excellent in hair-dyeing levelness. <P>SOLUTION: This oxidation hair dye composition comprises (a) a polyoxyethylene hydrogenated castor oil, (b) a silicone oil, preferably a polyoxyalkylene-modified silicone, and (c) a quaternary ammonium salt represented by the general formula (1) [co is a branched fatty acid residue or a lanolin fatty acid residue; R<SP>2</SP>to R<SP>4</SP>are each a 1 to 3C alkyl; (n) is an integer of 2 to 3; X<SP>-</SP>is a halogen ion, methyl sulfate ion, or ethyl sulfate ion], and, if desired, (d) a fatty acid amide, (e) an alkyl quaternary ammonium salt, and (f) a hydrocarbon. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to an oxidative hair dye composition.

  In general, the oxidative hair dye is generally of a two-part formula comprising a first agent containing an alkaline agent and a second agent containing hydrogen peroxide. This two-part oxidative hair dye generates oxygen by mixing the first agent and the second agent at the time of use, and oxidatively decomposes melanin pigment in the hair with this oxygen, and also converts the oxidative dye into the hair. To oxidatively polymerize and dye hair. In addition to the action of hydrogen peroxide, the alkaline agent in the first agent has an effect of improving the hair dyeing effect by swelling the cuticle on the hair surface and penetrating the dye into the hair. For this reason, compared with a temporary hair dye, an acid hair dye, etc., it is possible to dye in a lighter color tone than the original hair, and there is an advantage that the hair dyeing effect is continuous.

  However, since the oxidative hair dye needs to be mixed with the first agent and the second agent at the time of use, and the oxidative polymerization reaction of the dye is performed on the hair, if the two agents are not sufficiently mixed, There is a problem that it is difficult to dye evenly. In addition, since an alkaline agent is used, the keratin protein on the hair surface is decomposed to damage the hair, and the hair after dyeing has a problem that it is inferior in fingering and gloss.

  In order to solve such problems, a hair dye containing a dimethyldiallylammonium chloride / acrylic acid copolymer and a protein hydrolyzate (see Patent Document 1), 2- (β-hydroxyethyl) -p-phenylenediamine And hair dye containing a marine collagen hydrolyzate and a silicone derivative (see Patent Document 3), and the like. ing.

  However, these hair dyes are intended to impart luster and fingering properties to the hair using protein hydrolysates, and the imparted effects are not yet satisfactory.

JP 2002-338443 A JP 2002-226339 A JP 2005-343826 A

  The present invention has been made in view of the above-described conventional technology, and is excellent in usability during the treatment because it has good elongation on the hair and is excellent in usability and prevents hair damage during the treatment. It is an object of the present invention to provide an oxidative hair dye composition that imparts good fingering properties and the natural natural luster of hair, and is excellent in leveling of hair.

で表される四級アンモニウム塩を含有してなる酸化染毛剤組成物、
〔２〕 前記（ｂ）成分が、ポリオキシアルキレン変性シリコーンである前記〔１〕に記載の酸化染毛剤組成物、
〔３〕 （ｄ）下記一般式２

で表される脂肪酸アミドアミン化合物、及び／又は（ｅ）下記一般式３

で表されるアルキル四級アンモニウム塩を含有してなる前記〔１〕又は〔２〕に記載の酸化染毛剤組成物、
〔４〕 （ｆ）炭化水素類を含有してなる前記〔１〕〜〔３〕のいずれかに記載の酸化染毛剤組成物、並びに
〔５〕 前記（ｆ）成分が、室温で固形の炭化水素類である前記〔４〕に記載の酸化染毛剤組成物
に関する。 That is, the present invention
[1] (a) polyoxyethylene hydrogenated castor oil, (b) silicones, and (c) the following general formula 1

An oxidative hair dye composition comprising a quaternary ammonium salt represented by:
[2] The oxidative hair dye composition according to [1], wherein the component (b) is a polyoxyalkylene-modified silicone,
[3] (d) The following general formula 2

And / or (e) the following general formula 3

The oxidative hair dye composition according to the above [1] or [2], comprising an alkyl quaternary ammonium salt represented by:
[4] (f) The oxidative hair dye composition according to any one of [1] to [3], which contains hydrocarbons, and [5] The component (f) is solid at room temperature. It is related with the oxidative hair dye composition as described in said [4] which is hydrocarbons.

  The oxidative hair dye composition of the present invention has an effect that it extends well on the hair during the treatment and is excellent in usability and prevents damage to the hair during the treatment. Moreover, the hair after dyeing is excellent in fingering properties, imparts the natural natural luster of the hair, and has the effect of being excellent in hair leveling.

  The oxidative hair dye composition of the present invention contains (a) polyoxyethylene hydrogenated castor oil, (b) silicones, and (c) a quaternary ammonium salt as essential components.

  The number of moles of ethylene oxide added to the polyoxyethylene hydrogenated castor oil as component (a) is not particularly limited, but the number of moles added is 5 to 100 from the viewpoint of good elongation on the hair and leveling after treatment. And those having an added mole number of 10 to 50 are more preferred.

  The content of the component (a) is not particularly limited as long as the effect of the present invention is exhibited. However, from the viewpoint of good elongation on the hair and leveling after treatment, the content is usually 0.00. It is 1% by weight or more, preferably 1% by weight or more. Further, from the viewpoint of suppressing skin irritation during the treatment, it is usually 10% by weight or less, preferably 8% by weight or less in the composition. Accordingly, the content of the component (a) is usually 0.1 to 10% by weight, preferably 1 to 8% by weight.

  The silicone of component (b) is not particularly limited as long as the effects of the present invention are exhibited. For example, amino-modified silicone derivatives such as aminoethylaminopropylsiloxane / dimethylsiloxane copolymer and trimethylsilylamodimethicone; dimethylsiloxane Alcohol-modified silicones such as methyl stearoxysiloxane copolymers; polyoxyalkylene-modified silicones such as poly (oxyethylene / oxypropylene) methylpolysiloxane copolymers and dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymers; Examples include cyclic silicones such as methylcyclopolysiloxane; polyglycerin-modified silicones such as polyglyceryl-3 · disiloxane · dimethicone; dimethylpolysiloxane, methylphenylpolysiloxane, and the like. Can, aliphatic alcohol-modified silicones, epoxy-modified silicones, fluorine-modified silicones, perfluoroalkyl polyoxyalkylene-modified silicone, may be other modified silicones such as ammonium modified silicones. Of these, polyoxyalkylene-modified silicones can be preferably used from the viewpoint of improving the fingering after treatment and the gloss of hair.

  The content of the component (b) is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of improving the fingering property after the treatment and the gloss of the hair, it is usually 0.01 in the composition. % By weight or more, preferably 0.1% by weight or more. Further, from the viewpoint of storage stability of the preparation, it is usually 10% by weight or less, preferably 5% by weight or less in the composition. Accordingly, the content of component (b) is usually 0.01 to 10% by weight, preferably 0.1 to 5% by weight.

As the quaternary ammonium salt of component (c), a quaternary ammonium salt represented by the following general formula 4 is used in the present invention.

  Specifically, ethyl sulfate isoalkanoic acid (14-20) aminopropylethyldimethylammonium ethylsulfate isoalkanoate (18-22) aminopropylethyldimethylammonium, ethylsulfate isostearate aminopropylethyldimethylammonium, ethylsulfate isononanoate amino Propylethyldimethylammonium, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, ethyl sulfate lanolin fatty acid aminoethyltriethylammonium, ethyl sulfate lanolin fatty acid aminoethyl diethylmethylammonium, ethyl sulfate lanolin fatty acid aminoethyltrimethylammonium, ethyl sulfate lanolin fatty acid aminopropyltriethyl Ammonium, lanolin methylsulfate fatty acid aminoethyltrimethylan Bromide, can be exemplified methyl sulfate lanolin fatty acid aminopropyl ethyl dimethyl ammonium and the like. Among them, it is preferable to use a quaternary ammonium salt of a lanolin fatty acid derivative such as ethyl sulfate lanolin fatty acid aminopropylethyldimethylammonium from the viewpoint of improving the fingering after treatment and the gloss of hair.

  The content of the component (c) is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of improving the fingering property after the treatment and the gloss of the hair, the content is usually 0.1. % By weight or more, preferably 0.5% by weight or more. Moreover, from a viewpoint of suppressing the squeaky feeling to hair, it is 5 weight% or less normally in a composition, Preferably it is 3 weight% or less. Accordingly, the content of component (c) is usually 0.1 to 5% by weight, preferably 0.5 to 3% by weight.

  The oxidative hair dye composition of the present invention may further contain (d) a fatty acid amidoamine compound and / or (e) an alkyl quaternary ammonium salt from the viewpoint of improving the fingering property during hair washing.

As the fatty acid amide amine compound of component (d), a fatty acid amide amine compound represented by the following general formula 5 is used in the present invention.

  Specifically, palmitic acid dimethylaminoethylamide, palmitic acid diethylaminoethylamide, palmitic acid dimethylaminopropylamide, palmitic acid diethylaminopropylamide, stearic acid dimethylaminoethylamide, stearic acid diethylaminoethylamide, stearic acid dimethylaminopropylamide , Stearic acid diethylaminopropylamide, stearic acid dipropylaminoethylamide, stearic acid dipropylaminopropylamide, stearic acid dibutylaminoethylamide, stearic acid dibutylaminopropylamide, isostearic acid diethylaminoethylamide, behenic acid dimethylaminoethylamide, Behenic acid diethylaminoethylamide, behenic acid dimethylaminopropylamide Behenic acid diethylaminopropylamide, oleic acid dimethylaminopropylamide can be exemplified stearic acid diethanol aminoethyl amide.

In addition, as the alkyl quaternary ammonium salt of component (e), an alkyl quaternary ammonium salt represented by the following general formula 6 is used in the present invention.

  Specifically, lauryl trimethyl ammonium chloride, myristyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, oleyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, cocoyl trimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, distearyl dimethyl chloride Examples thereof include ammonium, dicocoyldimethylammonium chloride, tricetylmethylammonium chloride, and the like.

  The content of the component (d) and / or the component (e) is not particularly limited as long as the effect of the present invention is exhibited, but it is usually 0 in the composition from the viewpoint of improving the fingering property during hair washing. 0.05% by weight or more, preferably 0.1% by weight or more. Further, from the viewpoint of suppressing skin irritation during treatment, it is usually 5% by weight or less, preferably 3% by weight or less in the composition. Accordingly, the content of the component (d) and / or the component (e) is usually 0.05 to 5% by weight, preferably 0.1 to 3% by weight.

  The oxidative hair dye composition of the present invention further comprises (f) a hydrocarbon from the viewpoint of improving the retention in hair and exhibiting the effects of the present invention, and improving the storage stability of the preparation. Can be included. Specifically, liquid paraffin, squalane, polybutene, ceresin, paraffin wax, microcrystalline wax and the like can be exemplified. Of these, hydrocarbons that are solid at room temperature such as ceresin, paraffin wax, and microcrystalline wax are preferably used, and microcrystalline wax is particularly preferably used. In addition, the room temperature in this invention means the atmosphere of 1-30 degreeC.

  The content of the component (f) is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of improving the retention in hair and the storage stability, it is usually 0.05% by weight or more in the composition. The content is preferably 0.1% by weight or more. Moreover, from a viewpoint of making the elongation on hair favorable, it is 5 weight% or less normally in a composition, Preferably it is 3 weight% or less. Accordingly, the content of the component (f) is usually 0.05 to 5% by weight, preferably 0.1 to 3% by weight.

  The oxidative dye used in the present invention is a dye used for oxidative hair dyes such as oxidative dye precursors and couplers. Examples of oxidative dye precursors include phenylenediamines, aminophenols, diaminopyridines, And salts thereof such as hydrochlorides and sulfates thereof. Specifically, p-phenylenediamine, toluene-2,5-diamine, toluene-3,4-diamine, 2,5-diaminoanisole, N-phenyl-p-phenylenediamine, N-methyl-p-phenylenediamine N, N-dimethyl-p-phenylenediamine, 6-methoxy-3-methyl-p-phenylenediamine, N, N-diethyl-2-methyl-p-phenylenediamine, N-ethyl-N- (hydroxyethyl) -P-phenylenediamine, N- (2-hydroxypropyl) -p-phenylenediamine, 2-chloro-6-methyl-p-phenylenediamine, 2-chloro-p-phenylenediamine, N, N-bis- (2 -Hydroxyethyl) -p-phenylenediamine, 2,6-dichloro-p-phenylenediamine, 2-chloro-6-butyl Phenylenediamines such as mu-p-phenylenediamine; p-aminophenol, o-aminophenol, 2,4-diaminophenol, 5-aminosalicylic acid, 2-methyl-4-aminophenol, 3-methyl-4-amino Phenol, 2,6-dimethyl-4-aminophenol, 3,5-dimethyl-4-aminophenol, 2,3-dimethyl-4-aminophenol, 2,5-dimethyl-4-aminophenol, 2-chloro- Examples include aminophenols such as 4-aminophenol and 3-chloro-4-aminophenol; diaminopyridines such as 2,5-diaminopyridine, and salts thereof.

  Couplers include resorcin, m-aminophenol, m-phenylenediamine, 2,4-diaminophenoxyethanol, 5-amino-o-cresol, 2-methyl-5-hydroxyethylaminophenol, 2,6-diaminopyridine, catechol And pyrogallol, gallic acid, tannic acid and the like and salts thereof.

  As others, those listed in "Quasi-drug raw material standards" (issued in June 1991, Yakuji Nippo) can also be used as appropriate. Moreover, the above-mentioned oxidation dye precursor and coupler can be used individually by 1 type or in combination of 2 or more types, It is preferable to use an oxidation dye precursor at least. In addition, content of oxidation dye should just be about 0.01 to 10 weight% in a composition from viewpoints of safety, such as hair dyeing property and skin irritation.

  The alkali agent used in the present invention is not particularly limited. For example, ammonia, ammonium carbonate, ammonium bicarbonate, isopropanolamine, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-1-propanol These can be used, and one of these can be used alone, or two or more can be used in appropriate combination.

  The content of the alkaline agent is not particularly limited, but is preferably 0.01% by weight or more, more preferably 0.1% by weight or more in the composition from the viewpoint of hair dyeing power. Moreover, from a viewpoint of the hair damage prevention effect, 20 weight% or less is preferable in a composition, and 10 weight% or less is more preferable. From these, preferable content is 0.01 to 20 weight%, More preferably, it is 0.1 to 10 weight%.

  The oxidizing agent used in the present invention is not particularly limited as long as it exhibits an oxidizing action, and examples thereof include hydrogen peroxide, urea peroxide, and alkali metal bromate. Of these, hydrogen peroxide is preferably used, and is usually used as a hydrogen peroxide solution.

  The content of the oxidizing agent is preferably 0.1 to 5% by weight, more preferably 0.5 to 4% by weight in the composition from the viewpoint of exhibiting an oxidizing action and suppressing hair damage. preferable.

  In addition, ascorbic acid and / or an ascorbic acid derivative can be contained from the viewpoint of preventing oxidation of the oxidative dye during preparation storage. Ascorbic acid derivatives that can be used include, for example, sodium ascorbate, potassium ascorbate, calcium ascorbate, ammonium ascorbate, erythorbic acid, sodium erythorbate, magnesium ascorbate phosphate, ascorbyl citrate, ascorbyl acetate, tartaric acid Examples include ascorbyl, ascorbyl palmitate, ascorbyl stearate, and ascorbyl glucoside. In addition to these ascorbic acid or ascorbic acid derivatives, antioxidants such as sulfurous acid, bisulfite, thiosulfuric acid, thiolactic acid, thioglycolic acid, L-cysteine, N-acetyl-L-cysteine, and salts thereof may be used. good.

  In the oxidative hair dye composition of the present invention, in addition to the above-mentioned components, lower alcohols such as ethanol and isopropanol; lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, etc., as long as the effects of the present invention are not impaired Higher alcohols; higher fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid; esters such as myristyl myristate, isostearyl myristate, stearyl stearate; animals and plants such as avocado oil, olive oil, safflower oil, and hardened oil Oil; polyhydric alcohols such as polyethylene glycol, glycerin, polyglycerin, 1,3-butylene glycol, 1,2-pentanediol, 1,2-octanediol; sorbitan fatty acid ester, glycerin fatty acid ester, and alkyls thereof Nonionic surfactants such as oxide adducts, polyglycerin fatty acid esters, polyoxyalkylene alkyl ethers, polyoxyalkylene fatty acid esters, polyoxyethylene lanolin; higher fatty acid soaps, alkyl sulfates, alkyl phosphates, polyoxyethylene alkyls Anionic surfactants such as ether sulfate, alkyl ether phosphate, alkyl ether carboxylate, acylmethyl taurate, alkyl sulfosuccinic acid and salts thereof; alkyl glycine salt, carboxymethyl glycine salt, N-acylaminoethyl-N Glycine-type amphoteric surfactants such as 2-hydroxyethylglycine salt, aminopropionic acid-type amphoteric surfactants such as alkylaminopropionate and alkyliminodipropionate, alkyldimethyl Amphoteric surfactants such as aminoacetic acid betaine, fatty acid amidopropyldimethylaminoacetic acid betaine, and other aminoacetic acid betaine type amphoteric surfactants, and sulfobetaine type amphoteric surfactants such as alkylhydroxysulfobetaine; Red No. 2, Red No. 102, Yellow 202 (1), Yellow 202 (2), Yellow 203, Black 401 and other pigments; cationic polymers, hydrolyzed peptides, pH stabilizers, chelating agents, thickeners, anti-inflammatory agents , Ultraviolet absorbers, various amino acids, plant extracts, fragrances, water and the like can be appropriately contained depending on the purpose.

  When the oxidative hair dye composition of the present invention is used as a two-part oxidative hair dye, among the above components, the first agent contains an alkali agent and an oxidative dye, and the second agent oxidizes. The first agent and the second agent may be mixed and used at a ratio of usually 1: 5 to 5: 1.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to this Example. The content represents “% by weight” unless otherwise specified. Further, the number of moles of polyoxyethylene added is, for example, expressed as POE (20) hydrogenated castor oil when the number of moles added is 20 moles.

(Sample preparation)
According to the composition described in Table 1 and Table 2, the first oxidation hair dye was prepared by a conventional method. Moreover, the following formula was prepared by a conventional method as an oxidative hair dye second agent. The obtained 1st agent and 2nd agent were mixed by weight ratio 1: 1, and the oxidative hair dye composition of Examples 1-4 and Comparative Examples 1-4 was obtained.

(Second agent)
35% hydrogen peroxide solution 16.5
60% hydroxyethanediphosphonic acid 0.2
85% phosphoric acid 0.01
Purified water balance
Total 100.0

[Test Example 1: Evaluation of oxidative hair dye composition]
Each oxidative hair dye composition obtained above was uniformly applied to a white human hair bundle having a weight of 3 g and a length of 10 cm, and then allowed to stand in an atmosphere at 30 ° C. for 20 minutes. The drug was washed with water using a shampoo and then dried with a dryer.

  According to the following evaluation criteria, 20 expert panelists will stretch on the hair bundle at the time of treatment (at the time of application), leveling after treatment (after drying), smoothness of fingers (smoothness), and gloss. evaluated. The results are shown in Tables 1 and 2.

(Evaluation criteria for elongation during treatment)
◎: Reply if 16 or more out of 20 people are good. ○: Reply if 11-15 people out of 20 are good. △: Reply if 6-10 people out of 20 are good. ×: 5 out of 20 people. Answered that the first name or less

(Evaluation criteria for leveling)
◎: Reply that 16 or more out of 20 people are uniformly dyed and gray hair is not noticeable ○: Reply that 11 to 15 out of 20 people are evenly dyed and white hair is not conspicuous Answer that hair is uniformly dyed and gray hair is inconspicuous ×: 5 or less of 20 people are uniformly hair dyed and white hair is inconspicuous

(Assessment criteria for fingering)
◎: Answer that 16 or more out of 20 people should follow the finger ○: Answer that 11 to 15 out of 20 people should follow the finger △: Answer that 6 to 10 out of 20 people should follow the finger ×: 20 5 or less people answered that they should follow their finger

(Evaluation criteria for gloss)
◎: More than 16 out of 20 responded that the gloss of the hair is natural gloss ○: 11-15 out of 20 responded that the gloss of the hair was natural △: 6-10 out of 20 Answered that hair gloss is natural gloss ×: 5 or less of 20 people answered that hair gloss is natural gloss

  From the results of Tables 1 and 2, it can be seen that the length on the hair is good during the treatment and the usability is excellent, and that after the treatment, the leveling property is excellent. Further, it can be seen that the hair after dyeing is imparted with excellent fingering properties and natural natural luster of the hair.

  Hereinafter, formulation examples of the oxidative hair dye composition of the present invention will be shown. The blending amount represents “% by weight”.

[Prescription Example 1]
(Oxidative hair dye 1st agent)
Polyoxyethylene (20) hydrogenated castor oil 5.0
Polyoxyethylene (20) cetyl ether 2.5
30% stearyltrimethylammonium chloride 3.0
Polyoxyethylene (50)
Methylpolysiloxane copolymer 1.0
Ethanol sulfate lanolin fatty acid aminopropyl
Ethyldimethylammonium 1.0
Microcrystalline wax 1.0
Cetyl alcohol 4.0
Oleyl alcohol 2.0
Concentrated glycerin 2.0
Monoethanolamine 4.0
28% ammonia water 3.0
Ammonium carbonate 0.8
Paraphenylenediamine 0.4
Resorcin 0.35
2,4-Diaminophenoxyethanol hydrochloride 0.03
Metaaminophenol 0.05
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Jojoba oil 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Purified water balance
Total 100.0

[Prescription Example 2]
(Oxidative hair dye 1st agent)
Polyoxyethylene (40) hydrogenated castor oil 5.0
Polyoxyethylene (20) stearyl ether 2.0
30% stearyltrimethylammonium chloride 3.0
Polyoxyethylene (50)
Methylpolysiloxane copolymer 1.0
Ethanol sulfate lanolin fatty acid aminopropyl
Ethyldimethylammonium 2.0
Paraffin 1.0
Stearyl alcohol 4.0
Isostearyl alcohol 2.0
Monoethanolamine 4.0
28% ammonia water 3.0
Paraphenylenediamine 0.4
Paraaminophenol 0.2
Resorcin 0.35
Metaaminophenol 0.05
L-cysteine hydrochloride 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
L-glutamic acid 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Purified water balance
Total 100.0

[Prescription Example 3]
(Oxidative hair dye 1st agent)
Polyoxyethylene (20) hydrogenated castor oil 5.0
Polyoxyethylene (20) behenyl ether 2.5
30% stearyltrimethylammonium chloride 3.0
Polyoxyethylene (50)
Methylpolysiloxane copolymer 1.0
Aminopropyl isostearate ethylsulfate
Ethyldimethylammonium 1.0
Behenyl alcohol 4.0
Light liquid isoparaffin 2.0
Isopropanolamine 4.0
28% ammonia water 3.0
Ammonium carbonate 0.8
Paraphenylenediamine 0.4
Resorcin 0.35
Metaaminophenol 0.05
5- (2-Hydroxyamino) -2-methylphenol 0.2
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Panthenol 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Purified water balance
Total 100.0

[Prescription Example 4]
(Oxidative hair dye 1st agent)
Polyoxyethylene (20) hydrogenated castor oil 5.0
Polyoxyethylene (20) cetyl ether 2.5
30% stearyltrimethylammonium chloride 3.0
Aminoethylaminopropylmethylsiloxane
Dimethylsiloxane copolymer 1.0
Ethanol sulfate lanolin fatty acid aminopropyl
Triethylammonium 1.0
Vaseline 1.0
Cetyl alcohol 4.0
Oleyl alcohol 2.0
Monoethanolamine 4.0
28% ammonia water 3.0
Ammonium carbonate 0.8
Toluene sulfate-2,5-diamine 0.4
Resorcin 0.35
5-aminoorthocresol 0.03
Metaaminophenol 0.05
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Loquat leaf extract 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Purified water balance
Total 100.0

[Prescription Example 5]
(Oxidative hair dye 1st agent)
Polyoxyethylene (20) hydrogenated castor oil 3.0
Polyoxyethylene (20) cetyl ether 2.0
30% stearyltrimethylammonium chloride 3.0
Polyoxyethylene (50)
Methylpolysiloxane copolymer 1.0
Microcrystalline wax 1.0
Cetyl alcohol 3.0
Oleyl alcohol 2.0
Monoethanolamine 4.0
28% ammonia water 3.0
Ammonium carbonate 0.8
Paraphenylenediamine 0.4
Resorcin 0.35
2,4-Diaminophenoxyethanol hydrochloride 0.03
Metaaminophenol 0.05
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Water-soluble collagen 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Polyoxyethylene (20) hydrogenated castor oil 0.5
Polyoxyethylene (20) cetyl ether 2.0
Aminopropyl isostearate ethylsulfate
Ethyldimethylammonium 0.8
Cetanol 2.0
60% hydroxyethanediphosphonic acid 0.2
85% phosphoric acid 0.01
Purified water balance
Total 100.0

Claims (5)

(A) polyoxyethylene hydrogenated castor oil, (b) silicones, and (c) the following general formula 1

An oxidative hair dye composition comprising a quaternary ammonium salt represented by the formula: The oxidative hair dye composition according to claim 1, wherein the component (b) is a polyoxyalkylene-modified silicone. (D) The following general formula 2

And / or (e) the following general formula 3

The oxidative hair dye composition of Claim 1 or 2 formed by containing the alkyl quaternary ammonium salt represented by these. (F) The oxidative hair dye composition according to any one of claims 1 to 3, comprising a hydrocarbon. The oxidative hair dye composition according to claim 4, wherein the component (f) is a hydrocarbon that is solid at room temperature.