JP2007514846A5 - - Google Patents

Claims (15)

A crude material having a residue content (measured by ASTM method D5307) of 0.2 g or more per gram of crude material, in the presence of one or more catalysts in which at least one of the catalysts contains one or more transition metal sulfides A step of producing a total product including a crude product which is a liquid mixture at 25 ° C. and 0.101 MPa, and a coke content of the crude product is 0.05 g or less per gram of crude product And the naphtha having an octane number of 70 or more in the crude product is 0.001 g or more per gram of crude product, temperature, pressure, crude feed stream, total product stream, residence time, hydrogen source stream, or A step of controlling the contact condition comprising a combination of them ,
A method for producing a crude product comprising:   The method according to claim 1, wherein the naphtha has a benzene content of 0.01 g or less, 0.005 g or less, or 0.002 g or less per 1 g of naphtha. At least one transition metal of the transition metal sulfide is one or more transition metals in columns 6 to 10 of the periodic table, one or more compounds of one or more transition metals in columns 6 to 10 of the periodic table, or The method according to claim 1 or 2, comprising a mixture thereof. 4. The method of claim 3, wherein the at least one transition metal of the transition metal sulfide is iron. The method according to any one of claims 1 to 4, wherein the atomic ratio of sulfur in the transition metal to transition metal sulfide is 0.5-10. The transition metal sulfide catalyst is one or more alkali metals, one or more compounds of one or more alkali metals, one or more alkaline earth metals, one or more compounds of one or more alkaline earth metals The method according to claim 1, further comprising zinc, one or more compounds of zinc, or a mixture thereof. 7. The method of claim 6, wherein the atomic ratio of alkali metal, alkaline earth metal, or zinc to transition metal is in the range of greater than 0 to 1 or less. During contact, the contact conditions are also set so as to form non-condensable hydrocarbons at 25 ° C. and 0.101 MPa, 0.2 g or less, 0.15 g or less, or 0.1 g or less (measured by mass balance) per gram of crude raw material. 8. A method according to any one of claims 1 to 7, which is controlled. 2. At least a portion of the total product is produced as steam, and the method further comprises the step of condensing at least a portion of the steam at 25 ° C. and 0.101 MPa to produce a crude product. 9. The method according to any one of items 8. The method according to any one of claims 1 to 9, wherein the residual content of the crude raw material is 0.2 to 0.99 g or 0.3 to 0.8 g per gram of the crude raw material. The method according to any one of claims 1 to 10, wherein the crude product contains 0.00001 to 0.03 g or 0.0001 to 0.01 g of coke per gram of crude product. 12. A method according to any one of the preceding claims, further comprising the step of blending the crude product with crude oil that is the same as or different from the crude feedstock to form a blend. 13. The method according to any one of claims 1 to 12, further comprising producing a transportation fuel, a heating fuel, a lubricant or a chemical. 14. The method of claim 13, wherein the processing step comprises distilling the crude product or blend into one or more distillate fractions. The method according to claim 13 or 14, wherein the treatment step includes a hydrotreatment step.