JP2007313538A - Method and device for manufacturing metallic material - Google Patents

Method and device for manufacturing metallic material Download PDF

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JP2007313538A
JP2007313538A JP2006145218A JP2006145218A JP2007313538A JP 2007313538 A JP2007313538 A JP 2007313538A JP 2006145218 A JP2006145218 A JP 2006145218A JP 2006145218 A JP2006145218 A JP 2006145218A JP 2007313538 A JP2007313538 A JP 2007313538A
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brazing material
metal plate
brazing
heating
layer
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JP4858826B2 (en
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Nobuhiro Tazoe
信広 田添
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IHI Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method and a device for manufacturing a metallic material capable of producing a brazing filler metal powder adhesive material in which a brazing filler metal powder adhesive layer is adhered to a surface of a metal plate with high efficiency, and depositing the brazing filler metal powder adhesive layer of high accuracy on the surface of the metal plate. <P>SOLUTION: The device for manufacturing the metallic material comprises a rewinding machine 2 for rewinding a metal plate 1, a blowing device 5 for uniformly coating a slurry-like brazing filler metal liquid 3 with a brazing filler metal powder and a binder being mixed with each other on a surface of the metal plate 1 rewound from the rewinding machine 2, a heating and drying furnace 8 for manufacturing a brazing filler metal powder adhesive material 10 with the brazing filler metal powder adhesive layer being deposited on the surface of the metal plate 1 by heating the metal plate 1 with the brazing filler metal liquid 3 coated thereon, and blowing off the binder in the brazing filler metal liquid 3, and a winding machine 15 for winding the brazing filler metal powder adhesive material 10 manufactured by the heating and drying furnace 8. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は金属材料製造方法及び装置に関するものである。   The present invention relates to a metal material manufacturing method and apparatus.

近年、例えば、母材であるステンレス或いは耐熱合金等の金属板の両面又は片面に、ニッケル(Ni)等を主成分とするロウ材を有する金属粉末を圧着してロウ材圧着材を製造することが行なわれるようになっている。   In recent years, for example, a metal powder having a brazing material mainly composed of nickel (Ni) or the like is pressure-bonded to both or one side of a base metal plate such as stainless steel or a heat-resistant alloy to produce a brazing material. Is to be performed.

このようなロウ材圧着材を製造する方法と関連する一般的技術水準を示すものとしては、特許文献1に示されるものがある。
特開2004−025251号公報
Patent Document 1 discloses a general technical level related to a method for manufacturing such a brazing material pressure bonding material.
JP 2004-025251 A

しかし、特許文献1に示すような従来のロウ材圧着材を製造する方法は、所定形状に切断した金属板の各々の表面にロウ材層を圧着して形成する作業をバッチ方式で行っているために、作業が繁雑で生産性が低く、しかもロウ材層の層厚を高い精度で一定に形成することが難しいという問題を有していた。   However, in the conventional method for manufacturing a brazing material pressure bonding material as shown in Patent Document 1, the operation of pressure bonding a brazing material layer to each surface of a metal plate cut into a predetermined shape is performed in a batch system. Therefore, there is a problem that the work is complicated and the productivity is low, and it is difficult to form the brazing material layer with a high accuracy and constant thickness.

本発明は、上記実情に鑑みてなしたもので、金属板の表面にロウ材粉末接着層を備えたロウ材粉末接着材料を高能率に製造でき、且つ、前記ロウ材粉末接着層の層厚を高い精度で形成することができ、更に、ロウ材粉末接着材料のロウ材粉末接着層を融解させて金属板の表面に融着層が一体化したロウ材融着材料を高能率に製造できるようにした金属材料製造方法及び装置を提供することを目的とするものである。   The present invention has been made in view of the above circumstances, and can efficiently produce a brazing powder adhesive material having a brazing powder adhesive layer on the surface of a metal plate, and the layer thickness of the brazing powder adhesive layer. Can be formed with high accuracy, and the brazing material powder bonding layer of the brazing material powder bonding material can be melted to produce a brazing material fusion material in which the fusing layer is integrated on the surface of the metal plate with high efficiency. It is an object of the present invention to provide a metal material manufacturing method and apparatus.

本発明の金属材料製造方法は、移動する金属板の表面にロウ材粉末とバインダーを混合したスラリー状のロウ材液を吹付手段により均一に塗布し、続いて加熱乾燥手段により加熱して前記ロウ材液のバインダーを飛ばすことにより金属板の表面にロウ材粉末接着層が接着したロウ材粉末接着材料を製造することを特徴とする。   In the metal material manufacturing method of the present invention, a slurry-like brazing material liquid in which a brazing material powder and a binder are mixed is uniformly applied to the surface of a moving metal plate by a spraying means, followed by heating by a heating / drying means. A brazing material powder bonding material in which a brazing material powder bonding layer is bonded to the surface of a metal plate is produced by blowing a binder of the material liquid.

本発明の金属材料製造方法は、移動する金属板の表面にロウ材粉末とバインダーを混合したスラリー状のロウ材液を押出塗布手段により所定厚さの層状に押し出して塗布し、続いて加熱乾燥手段により加熱して前記ロウ材液のバインダーを飛ばすことにより金属板の表面にロウ材粉末接着層が接着したロウ材粉末接着材料を製造することを特徴とする。   In the metal material manufacturing method of the present invention, a slurry-like brazing material liquid in which a brazing powder and a binder are mixed is extruded onto a surface of a moving metal plate by extruding and applying a layer of a predetermined thickness, followed by heat drying. A brazing material powder adhesive material in which a brazing material powder adhesive layer is adhered to the surface of the metal plate is produced by heating by means and blowing off the binder of the brazing material liquid.

上記金属材料製造方法において、前記加熱乾燥手段の少なくとも後段に設けた圧下手段で圧下し、所定の層厚で均一なロウ材粉末接着層が金属板の表面に形成されたロウ材粉末接着材料を製造することは好ましい。   In the above metal material manufacturing method, a brazing material powder adhesive material in which a uniform brazing material powder adhesive layer is formed on the surface of the metal plate with a predetermined layer thickness that is reduced by a reduction means provided at least after the heating and drying means. It is preferable to manufacture.

本発明の金属材料製造方法は、上記金属材料製造方法で製造したロウ材粉末接着材料を加熱することにより、ロウ材粉末接着層を融解して金属板の表面に融着層が一体に形成されたロウ材融着材料を製造することを特徴とする。   In the metal material manufacturing method of the present invention, the brazing powder powder adhesive material manufactured by the above metal material manufacturing method is heated, so that the brazing powder powder adhesive layer is melted and the fusion layer is integrally formed on the surface of the metal plate. It is characterized by producing a brazing material.

本発明の金属材料製造装置は、金属板を巻き戻す巻戻機と、巻戻機から巻き出された金属板の表面にロウ材粉末とバインダーを混合したスラリー状のロウ材液を均一に塗布する吹付装置と、ロウ材液が塗布された金属板を加熱して前記ロウ材液のバインダーを飛ばすことにより金属板の表面にロウ材粉末接着層が形成されたロウ材粉末接着材料を製造する加熱乾燥炉と、該加熱乾燥炉で製造したロウ材粉末接着材料を巻き取る巻取機とを備えたことを特徴とする。   The metal material manufacturing apparatus of the present invention uniformly applies a rewinding machine for rewinding a metal plate, and a slurry-like brazing material liquid in which a brazing powder and a binder are mixed on the surface of the metal plate unwound from the rewinding machine. A brazing material powder adhesive material in which a brazing material powder adhesive layer is formed on the surface of the metal plate by heating the metal plate coated with the brazing material liquid and heating the brazing material liquid binder. A heating and drying furnace and a winder for winding the brazing material powder adhesive material produced in the heating and drying furnace are provided.

本発明の金属材料製造装置は、金属板を巻き戻す巻戻機と、巻戻機から巻き出された金属板の表面にロウ材粉末とバインダーを混合したスラリー状のロウ材液を押し出して所定厚さの層状に塗布する押出塗布装置と、ロウ材液が塗布された金属板を加熱して前記ロウ材液のバインダーを飛ばすことにより金属板の表面にロウ材粉末接着層が形成されたロウ材粉末接着材料を製造する加熱乾燥炉と、該加熱乾燥炉で製造したロウ材粉末接着材料を巻き取る巻取機とを備えたことを特徴とする。   The metal material manufacturing apparatus of the present invention includes a rewinding machine that rewinds a metal plate, and extrudes a slurry-like brazing material liquid in which a brazing material powder and a binder are mixed onto the surface of the metal plate that is unwound from the rewinding machine. An extrusion coating apparatus for coating in a layered thickness and a brazing material powder adhesive layer formed on the surface of the metal plate by heating the metal plate coated with the brazing material liquid and flying the binder of the brazing material liquid. A heating / drying furnace for manufacturing the material powder adhesive material and a winder for winding the brazing material powder adhesive material manufactured in the heating / drying furnace are provided.

上記金属材料製造装置において、前記押出塗布装置は、ロウ材液をスリット開口から押し出して金属板の表面にロウ材液の層を付着させるロウ材液押出部と、ロウ材液押出部から金属板の表面に押し出されたロウ材液の層厚を調整する厚さ調整部とからなることは好ましい。   In the metal material manufacturing apparatus, the extrusion coating apparatus includes: a brazing material liquid extruding unit that extrudes a brazing material liquid from a slit opening and deposits a brazing material liquid layer on the surface of the metal plate; And a thickness adjusting part for adjusting the layer thickness of the brazing material liquid extruded on the surface.

上記金属材料製造装置において、前記加熱乾燥炉の少なくとも後段に配置して圧下することにより金属板の表面に形成されるロウ材粉末接着層を所定の層厚で均一に調整するための圧下装置を備えることは好ましい。   In the metal material manufacturing apparatus, a reduction device for uniformly adjusting the brazing powder adhering layer formed on the surface of the metal plate with a predetermined layer thickness by arranging and reducing at least the latter stage of the heating and drying furnace. It is preferable to provide.

本発明の金属材料製造装置は、上記金属材料製造装置で製造したロウ材粉末接着材料を加熱してロウ材粉末接着層を融解することにより金属板の表面に融着層が一体に形成されたロウ材融着材料を製造する融解加熱炉を備えたことを特徴とする。   In the metal material manufacturing apparatus of the present invention, the fusion bonding layer is integrally formed on the surface of the metal plate by heating the brazing material powder bonding material manufactured by the metal material manufacturing apparatus and melting the brazing material powder bonding layer. A melting heating furnace for producing a brazing filler material is provided.

本発明の金属材料製造方法及び装置によれば、移動する金属板の表面にロウ材液を吹付手段により吹き付けて塗布し、又は押出塗布手段によりロウ材液を押し出して塗布し、続いて加熱乾燥手段により塗布したロウ材のバインダーを飛ばして金属板の表面にロウ材粉末接着層が接着されたロウ材粉末接着材料を製造するようにしたので、金属材の表面にロウ材粉末接着層を備えたロウ材粉末接着材料を連続して高能率に製造することができ、更に、ロウ材粉末接着層の層厚が容易に調整できるという優れた効果を奏し得る。   According to the metal material manufacturing method and apparatus of the present invention, the brazing material liquid is sprayed and applied to the surface of the moving metal plate by the spraying means, or the brazing material liquid is extruded and applied by the extrusion coating means, followed by heat drying. Since the brazing material powder adhesive material is manufactured by blowing the brazing material binder applied by means and bonding the brazing material powder adhesion layer to the surface of the metal plate, the brazing material powder adhesion layer is provided on the metal material surface. In addition, the brazing material powder adhesive material can be produced continuously and efficiently, and an excellent effect that the thickness of the brazing material powder adhesive layer can be easily adjusted can be obtained.

加熱乾燥手段の少なくとも後段において圧下手段で圧下することにより、ロウ材粉末接着層が所定の層厚で均一になるように調整されたロウ材粉末接着材料を容易に製造できる効果がある。   There is an effect that it is possible to easily manufacture a brazing material powder adhesive material adjusted so that the brazing material powder adhesive layer is uniform with a predetermined layer thickness by reducing the temperature by at least the latter stage of the heating and drying means.

前記ロウ材粉末接着層を備えたロウ材粉末接着材料を融解加熱手段で加熱することにより、ロウ材粉末接着層を融解させて金属板の表面に融着層が一体に形成されたロウ材融着材料を連続して高能率に製造できるという優れた効果を奏し得る。   The brazing material powder adhesive layer provided with the brazing material powder adhesive layer is heated by a melting heating means to melt the brazing material powder adhesive layer, and the fusion layer is integrally formed on the surface of the metal plate. The excellent effect that a dressing material can be manufactured continuously and highly efficiently can be produced.

以下、本発明の実施の形態を添付図面を参照して説明する。
図1は本発明におけるロウ材粉末接着材料を製造する装置形態の一例を示したものである。
Embodiments of the present invention will be described below with reference to the accompanying drawings.
FIG. 1 shows an example of an apparatus for producing a brazing powder adhesive material according to the present invention.

図1中、1はロウ材粉末接着材料を製造するための母材である金属板であり、該金属板1はロール状に巻かれており、巻戻機2に装着されて巻き出されるようになっている。巻戻機2から巻き出された金属板1の先端は前記巻戻機2と間隔を隔てて設けられた巻取機15に巻き取られようになっており、該巻取機15の巻き取りによって前記金属板1にテンションが掛けられるようになっている。   In FIG. 1, reference numeral 1 denotes a metal plate which is a base material for producing a brazing material powder adhesive material. The metal plate 1 is wound in a roll shape so that it is unwound after being mounted on a rewinding machine 2. It has become. The tip of the metal plate 1 unwound from the unwinder 2 is wound around a winder 15 provided at a distance from the unwinder 2, and the winder 15 is wound up. Thus, tension is applied to the metal plate 1.

前記金属板1を巻き出す巻戻機2の下流には、ロウ材粉末をバインダーに混合したスラリー状のロウ材液3を金属板1表面に吹き付けて均一に塗布する吹付ノズル4を備えた吹付装置5(吹付手段)を設けている。前記吹付ノズル4は金属板1の幅方向(図1の紙面に対して鉛直方向)に複数備えられて幅方向で均一に塗布できるようになっている。また、前記吹付ノズル4によるロウ材液3の噴射量の調節と金属板1の巻出し速度の調節のいずれか一方を行うことによって、金属板1に塗布されるロウ材液3の塗布層厚を調節できるようになっている。前記ロウ材液3は、前記金属板1がステンレス或いは耐熱合金等の場合には、図3に示す如く、ニッケル(Ni)等を主成分とするロウ材の粉末3aを有機性等のバインダー3b、例えばセルロースエーテルをエタノールおよび/またはメタノールに溶解したバインダーに混合してスラリー状としてあり、上記スラリー状のロウ材液3は、前記吹付ノズル4により噴射して金属板1の表面に層状に塗布するようにしている。   A spraying nozzle 4 is provided downstream of the unwinding machine 2 for unwinding the metal plate 1. The spraying nozzle 4 sprays a slurry-like brazing material liquid 3 in which a brazing material powder is mixed with a binder onto the surface of the metal plate 1 and uniformly coats it. A device 5 (spraying means) is provided. A plurality of the spray nozzles 4 are provided in the width direction of the metal plate 1 (perpendicular to the paper surface of FIG. 1) so that it can be applied uniformly in the width direction. Further, the thickness of the coating layer of the brazing material liquid 3 applied to the metal plate 1 is adjusted by either adjusting the injection amount of the brazing material liquid 3 by the spray nozzle 4 or adjusting the unwinding speed of the metal plate 1. Can be adjusted. When the metal plate 1 is made of stainless steel or a heat-resistant alloy, the brazing material liquid 3 is obtained by using, as shown in FIG. 3, a brazing material powder 3a mainly composed of nickel (Ni) or the like as an organic binder 3b. For example, cellulose ether is mixed with ethanol and / or a binder dissolved in methanol to form a slurry. The slurry-like brazing material liquid 3 is sprayed by the spray nozzle 4 and applied in a layered manner on the surface of the metal plate 1. Like to do.

前記ロウ材液3は、図1に示すように金属板1の両面に塗布してもよく、また、金属板1の片面に塗布してもよい。   The brazing material liquid 3 may be applied to both surfaces of the metal plate 1 as shown in FIG. 1, or may be applied to one surface of the metal plate 1.

前記吹付装置5の後段には、ロウ材液3が塗布された金属板1を加熱して前記ロウ材液3のバインダー3bを飛ばすための加熱乾燥炉8(加熱乾燥手段)を設けている。加熱乾燥炉8はバインダー3bを飛ばすことが目的であるため、バインダー3bの蒸発が促進できる程度の温度で加熱すればよい。更に、加熱乾燥炉8では、空気等の乾燥ガス8aを供給してバインダーの蒸発除去を促進させるようにしている。   A heating / drying furnace 8 (heating / drying means) for heating the metal plate 1 coated with the brazing material liquid 3 and flying the binder 3b of the brazing material liquid 3 is provided at the subsequent stage of the spraying device 5. The purpose of the heating and drying furnace 8 is to fly the binder 3b, and therefore, the heating and drying furnace 8 may be heated at a temperature that can promote the evaporation of the binder 3b. Further, in the heating and drying furnace 8, a drying gas 8a such as air is supplied to promote evaporation and removal of the binder.

前記加熱乾燥炉8でバインダーを飛ばすことにより、図4に示す如く金属板1の表面にロウ材粉末接着層9が一体に接着されたロウ材粉末接着材料10が製造できる。金属板1の表面にロウ材粉末接着層9が接着したロウ材粉末接着材料10は図1の前記巻取機15によって巻き取られる。   By blowing the binder in the heating and drying furnace 8, a brazing material powder adhesive material 10 in which a brazing material powder adhesive layer 9 is integrally bonded to the surface of the metal plate 1 as shown in FIG. 4 can be manufactured. A brazing material powder bonding material 10 having a brazing material powder bonding layer 9 bonded to the surface of the metal plate 1 is wound up by the winder 15 shown in FIG.

次に、図1に示した形態の作動を説明する。   Next, the operation of the embodiment shown in FIG. 1 will be described.

図1の巻戻機2から巻き出した金属板1の先端を巻取機15に巻き付け、該巻取機15によって前記金属板1にテンションを掛けた状態とし、巻取機15によって金属板1の巻き取りを開始すると共に、吹付装置5の吹付ノズル4からロウ材液3をスプレー状に吹き付け、図3に示す如く金属板1の表面にロウ材液3の層を形成する。この時、前記吹付ノズル4によるロウ材液3の噴射量の調節と金属板1の巻出し速度の調節のいずれか一方を行うことによって、金属板1に塗布されるロウ材液3の層厚を調節することができる。   The tip of the metal plate 1 unwound from the unwinder 2 in FIG. 1 is wound around a winder 15, and the metal plate 1 is tensioned by the winder 15, and the metal plate 1 is wound by the winder 15. The brazing material liquid 3 is sprayed from the spray nozzle 4 of the spraying device 5 in a spray form to form a layer of the brazing material liquid 3 on the surface of the metal plate 1 as shown in FIG. At this time, the thickness of the brazing material liquid 3 applied to the metal plate 1 is adjusted by either adjusting the injection amount of the brazing material liquid 3 by the spray nozzle 4 or adjusting the unwinding speed of the metal plate 1. Can be adjusted.

ロウ材液3が塗布された金属板1は、加熱乾燥炉8に導かれて加熱されることにより、前記ロウ材液3のバインダー3bが飛ばされ、これにより図4に示す如く金属板1の表面にロウ材粉末接着層9が一体に接着されたロウ材粉末接着材料10が連続して製造される。前記加熱乾燥炉8において空気等の乾燥ガス8aを供給するとバインダーの蒸発除去を促進させることができる。   The metal plate 1 to which the brazing material liquid 3 is applied is guided to the heating / drying furnace 8 and heated, whereby the binder 3b of the brazing material liquid 3 is blown off. As a result, as shown in FIG. A brazing material powder bonding material 10 having a brazing material powder bonding layer 9 integrally bonded to the surface is continuously manufactured. If the drying gas 8a such as air is supplied in the heating and drying furnace 8, the evaporation removal of the binder can be promoted.

金属板1の表面にロウ材粉末接着層9が一体に接着されたロウ材粉末接着材料10は前記巻取機15によって巻き取られる。   The brazing material powder adhesive material 10 in which the brazing material powder adhesive layer 9 is integrally bonded to the surface of the metal plate 1 is wound up by the winder 15.

図2は前記図1に示したロウ材粉末接着材料を製造する形態の変形例を示したものであり、前記加熱乾燥炉8の後段に圧下装置11(圧下手段)を配置し、金属板1の表面にロウ材粉末接着層9が接着されたロウ材粉末接着材料10を圧下するようにしている。加熱乾燥炉8の後段に設置する圧下装置11は複数段備えるようにしてもよい。   FIG. 2 shows a modification of the embodiment for producing the brazing powder adhering material shown in FIG. 1. A reduction device 11 (reduction means) is arranged at the rear stage of the heating and drying furnace 8, and the metal plate 1 The brazing material powder bonding material 10 having the brazing material powder bonding layer 9 adhered to the surface thereof is pressed down. You may make it provide the rolling reduction apparatus 11 installed in the back | latter stage of the heating-drying furnace 8 with two or more stages.

また、図2では前記圧下装置11を加熱乾燥炉の後段に配置しているが、図中破線で示すように、加熱乾燥炉8の前段に圧下装置11aを設けるようにしてもよい。   In FIG. 2, the reduction device 11 is arranged at the rear stage of the heating and drying furnace. However, as shown by the broken line in the figure, the reduction device 11 a may be provided at the front stage of the heating and drying furnace 8.

図2に示した変形例では、加熱乾燥炉8の後段に圧下装置11を備えたので、該圧下装置11にて前記ロウ材粉末接着材料10を圧下することにより、図5に示す如く、ロウ材粉末接着層9を所定の層厚で且つ均一(平坦)な層厚になるように調整することができる。また、図2中破線で示したように、加熱乾燥炉8の前段に圧下装置11aを設けて圧下することにより、加熱乾燥炉8に導かれる金属板1のロウ材液3の層厚を均一に調整することができる。前記吹付ノズル4の吹き付けによって金属板1表面に形成されるロウ材液3の層の表面は、通常図3に示すように凹凸を有しており、しかも金属板1の幅方向に対して厚さの不均一が生じ易いため、加熱乾燥炉8の前段において圧下装置11aによりロウ材液3の層厚を均一に調整することは好ましい。   In the modification shown in FIG. 2, the reduction device 11 is provided at the rear stage of the heating and drying furnace 8. By reducing the brazing material powder adhesive material 10 with the reduction device 11, as shown in FIG. The material powder adhesive layer 9 can be adjusted to have a predetermined layer thickness and a uniform (flat) layer thickness. In addition, as shown by the broken line in FIG. 2, the pressure reduction device 11 a is provided in the front stage of the heating / drying furnace 8 to reduce the thickness of the brazing material liquid 3 of the metal plate 1 guided to the heating / drying furnace 8. Can be adjusted. The surface of the layer of the brazing material liquid 3 formed on the surface of the metal plate 1 by the spraying of the spray nozzle 4 has irregularities as shown in FIG. 3 and is thicker than the width of the metal plate 1. Since unevenness is likely to occur, it is preferable to uniformly adjust the layer thickness of the brazing material liquid 3 by the reduction device 11 a in the front stage of the heating and drying furnace 8.

図6は本発明におけるロウ材粉末接着材料を製造する他の形態を示したものである。この形態では、前記図1の形態で備えた吹付装置5に代えて、押出塗布装置16(押出塗布手段)を設けた場合を示しており、上記押出塗布装置16を設けた以外の構成は図1の場合と同様である。   FIG. 6 shows another embodiment for producing the brazing powder adhesive material in the present invention. In this embodiment, a case where an extrusion coating device 16 (extrusion coating means) is provided instead of the spraying device 5 provided in the configuration of FIG. 1 is shown, and the configuration other than the provision of the extrusion coating device 16 is shown in the figure. This is the same as the case of 1.

前記押出塗布装置16は、ロウ材液3を受けるようにした容器17aと、該容器17aの下端において前記金属板1の幅方向(図6の紙面に対して鉛直方向)に長く形成されて前記金属板1の表面に接近したスリット開口17bとを有するロウ材液押出部17と、該ロウ材液押出部17の後段に備えて該ロウ材液押出部17から金属板1の表面に押し出されたロウ材液3の層厚を調整するブレード18或は堰からなる厚さ調整部19とにより構成されている。   The extrusion coating device 16 is formed to be long in the width direction of the metal plate 1 (perpendicular to the plane of FIG. 6) at the lower end of the container 17a that receives the brazing material liquid 3, and the lower end of the container 17a. The brazing material liquid extruding part 17 having a slit opening 17b close to the surface of the metal plate 1 and the brazing material liquid extruding part 17 are extruded from the brazing material liquid extruding part 17 to the surface of the metal plate 1 in preparation for the subsequent stage. Further, the blade 18 or the thickness adjusting unit 19 including a weir is used to adjust the layer thickness of the brazing material liquid 3.

図6ではロウ材液押出部17が金属板1の上側に配置されていて、容器17a内のロウ材液3が重力或は容器17aに作用させた加圧力によってスリット開口17bから金属板1上に押し出されて層状に塗布されるが、この時、スリット開口17bの大きさ、容器17a内のロウ材液3の貯留量(重力)及び金属板1の巻出し速度の少なくとも1つを調節することによって、金属板1に塗布されるロウ材液3の層厚を調節することができる。   In FIG. 6, the brazing material liquid extruding portion 17 is disposed on the upper side of the metal plate 1, and the brazing material liquid 3 in the container 17a is applied to the metal plate 1 from the slit opening 17b by gravity or a pressure applied to the container 17a. At this time, at least one of the size of the slit opening 17b, the storage amount (gravity) of the brazing material liquid 3 in the container 17a, and the unwinding speed of the metal plate 1 is adjusted. Thus, the layer thickness of the brazing material liquid 3 applied to the metal plate 1 can be adjusted.

また、前記容器17aに加圧力を作用させてロウ材液3を押し出すようにした場合には、前記ロウ材液押出部17と厚さ調整部19からなる押出塗布装置16を金属板1の下側に設けて、金属板1の上面にロウ材液3を塗布することもできる。前記押出塗布装置16の後段には、図1と同様に加熱乾燥炉8(加熱乾燥手段)及び巻取機15が設けられている。   Further, when the brazing material liquid 3 is pushed out by applying a pressure to the container 17a, the extrusion coating device 16 comprising the brazing material liquid extruding part 17 and the thickness adjusting part 19 is placed under the metal plate 1. It is also possible to apply the brazing material liquid 3 on the upper surface of the metal plate 1. A heating and drying furnace 8 (heating and drying means) and a winder 15 are provided at the subsequent stage of the extrusion coating device 16 as in FIG.

次に、図6に示した形態の作動を説明する。   Next, the operation of the embodiment shown in FIG. 6 will be described.

巻戻機2から巻き出された金属板1の先端を巻取機15に巻き付け、該巻取機15によって前記金属板1にテンションを掛けた状態とし、巻取機15により金属板1の巻き取りを開始すると共に、押出塗布装置16におけるロウ材液押出部17のスリット開口17bからロウ材液3を押し出して金属板1の表面にロウ材液3を層状に塗布する。ロウ材液3が層状に塗布された金属板1は厚さ調整部19に導かれ、ブレード18或は堰等により層厚が調整され、図8に示すように所定層厚で均一なロウ材液3層が形成される。   The tip of the metal plate 1 unwound from the unwinder 2 is wound around a winder 15 so that the metal plate 1 is tensioned by the winder 15, and the metal plate 1 is wound by the winder 15. At the same time, the brazing material liquid 3 is extruded from the slit opening 17b of the brazing material liquid extruding unit 17 in the extrusion coating device 16 to apply the brazing material liquid 3 in a layered manner on the surface of the metal plate 1. The metal plate 1 on which the brazing material liquid 3 is applied in layers is guided to the thickness adjusting unit 19 and the thickness of the metal plate 1 is adjusted by a blade 18 or a weir. As shown in FIG. Three layers of liquid are formed.

厚さ調整部19でロウ材液3の層厚が調整された金属板1は、加熱乾燥炉8に導かれて加熱されロウ材液3のバインダー3bが飛ばされることにより、図9に示す如く金属板1の表面にロウ材粉末接着層9が一体に接着されたロウ材粉末接着材料10が製造される。このとき、前記ロウ材粉末接着層9は厚さ調整部19によって厚さ調整されているため、所定層厚で且つ均一な層厚のロウ材粉末接着層9を備えたロウ材粉末接着材料10が連続して製造される。   The metal plate 1 whose layer thickness of the brazing material liquid 3 has been adjusted by the thickness adjusting unit 19 is guided to the heating and drying furnace 8 and heated, and the binder 3b of the brazing material liquid 3 is blown off, as shown in FIG. A brazing material powder bonding material 10 in which the brazing material powder bonding layer 9 is integrally bonded to the surface of the metal plate 1 is manufactured. At this time, since the thickness of the brazing material powder bonding layer 9 is adjusted by the thickness adjusting unit 19, the brazing material powder bonding material 10 having the brazing material powder bonding layer 9 having a predetermined layer thickness and a uniform layer thickness. Is manufactured continuously.

図7は前記図6に示したロウ材粉末接着材料を製造する形態の変形例を示したものであり、前記加熱乾燥炉8の後段に圧下装置11(圧下手段)を配置し、金属板1の表面にロウ材粉末接着層9が接着されたロウ材粉末接着材料10を圧下するようにしている。加熱乾燥炉8の後段に設置する圧下装置11は複数段備えるようにしてもよい。   FIG. 7 shows a modification of the embodiment for producing the brazing powder adhering material shown in FIG. 6. A reduction device 11 (reduction means) is arranged at the rear stage of the heating and drying furnace 8, and the metal plate 1 The brazing material powder bonding material 10 having the brazing material powder bonding layer 9 adhered to the surface thereof is pressed down. You may make it provide the rolling reduction apparatus 11 installed in the back | latter stage of the heating-drying furnace 8 with two or more stages.

また、図7では前記圧下装置11を加熱乾燥炉の後段に配置しているが、図中破線で示すように、加熱乾燥炉8の前段に圧下装置11aを設けるようにしてもよい。   In FIG. 7, the reduction device 11 is arranged at the rear stage of the heating and drying furnace, but as shown by the broken line in the figure, the reduction device 11 a may be provided at the front stage of the heating and drying furnace 8.

図7に示したように、加熱乾燥炉8の後段に圧下装置11を備えて前記ロウ材粉末接着材料10を圧下すると、図10に示す如く、ロウ材粉末接着層9の所定層厚と均一化を更に高い精度で達成することができる。また、図7中破線で示したように、加熱乾燥炉8の前段に圧下装置11aを設けて圧下すると、加熱乾燥炉8に導かれる金属板1のロウ材液3の層厚を均一に調整することができる。   As shown in FIG. 7, when the brazing material powder adhesive material 10 is crushed by providing a reduction device 11 at the rear stage of the heating and drying furnace 8, as shown in FIG. Can be achieved with higher accuracy. In addition, as shown by the broken line in FIG. 7, when the reduction device 11 a is provided in the preceding stage of the heating and drying furnace 8, the layer thickness of the brazing material liquid 3 of the metal plate 1 led to the heating and drying furnace 8 is adjusted uniformly. can do.

図1、図2及び図6、図7に示したように、金属板1の表面にロウ材粉末接着層9が一体に接着して製造されたロウ材粉末接着材料10によれば、前記ロウ材粉末接着層9の表面に固定する目的材料を密着させた状態に保持して、前記ロウ材粉末接着層9が溶融する温度で加熱処理することにより、前記金属板1と目的材料がロウ材を介して一体に固着された製品を得ることができる。   As shown in FIGS. 1, 2, 6, and 7, according to the brazing material powder bonding material 10 manufactured by integrally bonding the brazing material powder bonding layer 9 to the surface of the metal plate 1, The target material to be fixed to the surface of the material powder adhesive layer 9 is held in close contact, and heat treatment is performed at a temperature at which the brazing material powder adhesive layer 9 melts, whereby the metal plate 1 and the target material are brazed. It is possible to obtain a product that is integrally fixed via the.

図11は本発明におけるロウ材融着材料を製造する形態の一例を示したものである。   FIG. 11 shows an example of a form for producing the brazing filler material in the present invention.

この形態では、図1の形態における加熱乾燥炉8の後段に融解加熱炉12(融解加熱手段)を配置して、前記図1の手段によって金属板1の表面にロウ材粉末接着層9が一体に接着されたロウ材粉末接着材料10を加熱するようにしている。融解加熱炉12は前記ロウ材粉末接着材料10を、ロウ材粉末接着層9の金属粒子が軟化して融着する温度に加熱するようになっている。前記融解加熱炉12では例えば窒素N2等の不活性ガス12aを供給することにより前記融着層13の酸化を防止している。   In this embodiment, a melting and heating furnace 12 (melting and heating means) is disposed after the heating and drying furnace 8 in the embodiment shown in FIG. 1, and the brazing powder adhering layer 9 is integrated on the surface of the metal plate 1 by the means shown in FIG. The brazing material powder adhesive material 10 adhered to the substrate is heated. The melting furnace 12 heats the brazing material powder bonding material 10 to a temperature at which the metal particles of the brazing material powder bonding layer 9 are softened and fused. In the melting furnace 12, for example, an inert gas 12 a such as nitrogen N 2 is supplied to prevent the fusion layer 13 from being oxidized.

図11の形態によれば、吹付装置5により金属板1の表面にロウ材液3が塗布され、更に加熱乾燥炉8でロウ材液3層のバインダーが飛ばされてロウ材粉末接着層9が一体に接着されたロウ材粉末接着材料10は、融解加熱炉12により加熱されてロウ材粉末接着層9が融解され、図13に示す如く金属板1に融着層13が一体に形成されたロウ材融着材料14が連続して製造される。   According to the form of FIG. 11, the brazing material liquid 3 is applied to the surface of the metal plate 1 by the spraying device 5, and the binder of the brazing material liquid 3 layer is further blown off in the heating and drying furnace 8, so that the brazing material powder adhesive layer 9 is formed. The integrally bonded brazing material powder bonding material 10 is heated by the melting furnace 12 to melt the brazing material powder bonding layer 9, and the fusion layer 13 is integrally formed on the metal plate 1 as shown in FIG. The brazing filler material 14 is continuously produced.

なお、上記図11の形態においても、図12にその変形例を示すように、前記加熱乾燥炉8の後段にロウ材粉末接着材料10を圧下する圧下装置11を設けたり、また図12中破線で示すように、加熱乾燥炉8の前段にロウ材液3層を圧下する圧下装置11aを設けることにより、製造されるロウ材融着材料14の融着層13の所定層厚と均一化を図るようにすることができる。   In the embodiment of FIG. 11 as well, as shown in FIG. 12, a reduction device 11 for reducing the brazing powder adhesive material 10 is provided at the rear stage of the heating and drying furnace 8, or a broken line in FIG. As shown in FIG. 4, by providing a reduction device 11a for reducing the three layers of brazing material liquid in the previous stage of the heating and drying furnace 8, a predetermined layer thickness and uniformization of the fusion layer 13 of the brazing material fusion material 14 to be manufactured are achieved. It can be designed.

上記したように、金属板1の表面にロウ材粉末接着層9による融着層13が一体に形成されたロウ材融着材料14は、前記融着層13が金属板1に強固に固定されているため、前記ロウ材融着材料14の切断、打ち抜き、曲げ等の加工を行っても、前記融着層13が金属板1から剥離する問題を生じることがない。   As described above, in the brazing material fusion material 14 in which the fusion layer 13 made of the brazing material powder adhesive layer 9 is integrally formed on the surface of the metal plate 1, the fusion layer 13 is firmly fixed to the metal plate 1. Therefore, even if the brazing material 14 is cut, punched, bent, or the like, there is no problem that the fusion layer 13 is peeled off from the metal plate 1.

図14は本発明におけるロウ材融着材料を製造する他の形態を示したものである。この形態では、前記図12の形態で備えた吹付装置5に代えて、図6の形態と同様の押出塗布装置16(押出塗布手段)を設けた場合を示しており、上記押出塗布装置16を備えた以外の構成は図12の場合と同様である。   FIG. 14 shows another embodiment for producing the brazing filler material in the present invention. This embodiment shows a case where an extrusion coating device 16 (extrusion coating means) similar to the configuration of FIG. 6 is provided instead of the spraying device 5 provided in the configuration of FIG. The configuration other than the provision is the same as in FIG.

図14の形態では、押出塗布装置16により金属板1の表面にロウ材液3が塗布され、更に加熱乾燥炉8でロウ材液3層のバインダーが飛ばされてロウ材粉末接着層9が一体に接着されたロウ材粉末接着材料10は、融解加熱炉12により加熱されてロウ材粉末接着層9が融解され、図13に示した如く金属板1に融着層13が一体に形成されたロウ材融着材料14が連続して製造される。   In the form of FIG. 14, the brazing material liquid 3 is applied to the surface of the metal plate 1 by the extrusion coating device 16, and the binder of the brazing material liquid 3 layer is further blown off in the heating and drying furnace 8 so that the brazing material powder adhesive layer 9 is integrated. The brazing powder adhering material 10 adhered to is heated by a melting heating furnace 12 to melt the brazing powder adhering layer 9, and the fused layer 13 is integrally formed on the metal plate 1 as shown in FIG. The brazing filler material 14 is continuously produced.

なお、上記図14の形態においても、図15にその変形例を示すように、前記加熱乾燥炉8の後段にロウ材粉末接着材料10を圧下する圧下装置11を設けたり、また図15中破線で示すように、加熱乾燥炉8の前段にロウ材液層を圧下する圧下装置11aを設けることにより、製造されるロウ材融着材料14の融着層13の所定層厚と均一化を図るようにすることができる。   In the embodiment of FIG. 14 as well, as shown in FIG. 15, a reduction device 11 for reducing the brazing powder adhesive material 10 is provided at the rear stage of the heating and drying furnace 8, or a broken line in FIG. As shown in FIG. 5, by providing a reduction device 11a for reducing the brazing material liquid layer in the front stage of the heating and drying furnace 8, a predetermined layer thickness and uniformization of the fusion layer 13 of the brazing material fusion material 14 to be manufactured are achieved. Can be.

図11、図12及び図14、図15に示したように、金属板1の表面にロウ材による融着層13が一体に形成されたロウ材融着材料14は、ロウ材融着材料14の切断、打ち抜き、曲げ等の加工を行っても、前記融着層13が金属板1から剥離する問題を生じないため、種々の加工を行う材料のロウ付けに好適に用いることができる。   As shown in FIGS. 11, 12, 14, and 15, the brazing material fusion material 14 in which the fusion layer 13 made of the brazing material is integrally formed on the surface of the metal plate 1 is the brazing material fusion material 14. Even if cutting, punching, bending, or the like is performed, the problem that the fusion layer 13 peels off from the metal plate 1 does not occur, and therefore, it can be suitably used for brazing materials for various processing.

なお、本発明は上記形態に限定されるものではなく、本発明の要旨を逸脱しない範囲内において種々変更を加え得ることは勿論である。   In addition, this invention is not limited to the said form, Of course, a various change can be added in the range which does not deviate from the summary of this invention.

本発明におけるロウ材粉末接着材料を製造する装置形態の一例を示す側面図である。It is a side view which shows an example of the apparatus form which manufactures the brazing material powder adhesive material in this invention. 図1に示したロウ材粉末接着材料を製造する形態の変形例を示す側面図である。It is a side view which shows the modification of the form which manufactures the brazing material powder adhesive material shown in FIG. 吹付装置によりロウ材が金属板の表面に層状に塗布された状態を示す断面図である。It is sectional drawing which shows the state by which the brazing material was apply | coated to the surface of the metal plate in the layer form by the spraying apparatus. 金属板の表面にロウ材粉末接着層が一体に接着されたロウ材粉末接着材料の断面図である。It is sectional drawing of the brazing material powder adhesive material by which the brazing material powder adhesion layer was adhere | attached integrally on the surface of the metal plate. ロウ材粉末接着層が均一な層厚に調整された状態を示す断面図である。It is sectional drawing which shows the state in which the brazing material powder contact bonding layer was adjusted to the uniform layer thickness. 本発明におけるロウ材粉末接着材料を製造する他の形態を示す側面図である。It is a side view which shows the other form which manufactures the brazing material powder adhesive material in this invention. 図6に示したロウ材粉末接着材料を製造する形態の変形例を示す側面図である。It is a side view which shows the modification of the form which manufactures the brazing material powder adhesive material shown in FIG. 押出塗布装置によりロウ材が金属板の表面に均一な層状に塗布された状態を示す断面図である。It is sectional drawing which shows the state by which the brazing material was apply | coated to the surface of the metal plate in the uniform layer form by the extrusion coating apparatus. 金属板の表面に均一層厚のロウ材粉末接着層が一体に接着されたロウ材粉末接着材料の断面図である。FIG. 3 is a cross-sectional view of a brazing powder adhesive material in which a brazing powder adhesive layer having a uniform layer thickness is integrally bonded to the surface of a metal plate. ロウ材粉末接着層の層厚と均一化が更に高められた状態を示す断面図である。It is sectional drawing which shows the state which the layer thickness and uniformity of the brazing material powder adhesion layer were further improved. 本発明におけるロウ材融着材料を製造する形態の一例を示す側面図である。It is a side view which shows an example of the form which manufactures the brazing filler material in this invention. 図11の変形例を示す側面図である。It is a side view which shows the modification of FIG. 金属板に融着層が一体に形成されたロウ材融着材料を示す断面図である。It is sectional drawing which shows the brazing | wax material fusion | melting material by which the fusion | melting layer was integrally formed on the metal plate. 本発明におけるロウ材融着材料を製造する他の形態を示す側面図である。It is a side view which shows the other form which manufactures the brazing material fusion material in this invention. 図14の変形例を示す側面図である。It is a side view which shows the modification of FIG.

符号の説明Explanation of symbols

1 金属板
2 巻戻機
3 ロウ材液
3a 粉末
3b バインダー
5 吹付装置
8 加熱乾燥炉
9 ロウ材粉末接着層
10 ロウ材粉末接着材料
11 圧下装置
11a 圧下装置
12 融解加熱炉
13 融着層
14 ロウ材融着材料
15 巻取機
16 押出塗布装置
DESCRIPTION OF SYMBOLS 1 Metal plate 2 Rewinder 3 Brazing material liquid 3a Powder 3b Binder 5 Spraying device 8 Heating and drying furnace 9 Brazing material powder adhesion layer 10 Brazing material powder adhesion material 11 Reduction device 11a Reduction device 12 Melting heating furnace 13 Fusion layer 14 Low Material fusion material 15 Winder 16 Extrusion coating device

Claims (9)

移動する金属板の表面にロウ材粉末とバインダーを混合したスラリー状のロウ材液を吹付手段により均一に塗布し、続いて加熱乾燥手段により加熱して前記ロウ材液のバインダーを飛ばすことにより金属板の表面にロウ材粉末接着層が接着したロウ材粉末接着材料を製造することを特徴とする金属材料製造方法。   A slurry-like brazing material liquid in which a brazing powder and a binder are mixed is uniformly applied to the surface of a moving metal plate by spraying means, and then heated by a heating and drying means to blow off the binder of the brazing material liquid. A method for producing a metal material, comprising producing a brazing powder adhering material having a brazing powder adhering layer adhered to a surface of a plate. 移動する金属板の表面にロウ材粉末とバインダーを混合したスラリー状のロウ材液を押出塗布手段により所定厚さの層状に押し出して塗布し、続いて加熱乾燥手段により加熱して前記ロウ材液のバインダーを飛ばすことにより金属板の表面にロウ材粉末接着層が接着したロウ材粉末接着材料を製造することを特徴とする金属材料製造方法。   A slurry-like brazing material liquid in which a brazing powder and a binder are mixed is extruded and applied to a surface of a moving metal plate by extrusion coating means into a layer having a predetermined thickness, followed by heating by a heating and drying means, and the brazing material liquid. A method for producing a metal material, comprising: producing a brazing material powder adhesive material in which a brazing material powder adhesion layer is adhered to the surface of a metal plate by removing the binder. 前記加熱乾燥手段の少なくとも後段に設けた圧下手段で圧下し、所定の層厚で均一なロウ材粉末接着層が金属板の表面に形成されたロウ材粉末接着材料を製造することを特徴とする請求項1又は2に記載の金属材料製造方法。   A brazing material powder adhesive material in which a uniform brazing material powder adhesive layer is formed on the surface of the metal plate by a reduction by a reduction means provided at least in the subsequent stage of the heating and drying means is produced. The metal material manufacturing method according to claim 1 or 2. 請求項1〜3のいずれか1つに記載の金属材料製造方法で製造したロウ材粉末接着材料を加熱することにより、ロウ材粉末接着層を融解して金属板の表面に融着層が一体に形成されたロウ材融着材料を製造することを特徴とする金属材料製造方法。   The brazing material powder adhesive material manufactured by the metal material manufacturing method according to any one of claims 1 to 3 is heated to melt the brazing material powder adhesive layer so that the fusion layer is integrated with the surface of the metal plate. A method for producing a metal material, comprising producing a brazing material fusion material formed on the metal. 金属板を巻き戻す巻戻機と、巻戻機から巻き出された金属板の表面にロウ材粉末とバインダーを混合したスラリー状のロウ材液を均一に塗布する吹付装置と、ロウ材液が塗布された金属板を加熱して前記ロウ材液のバインダーを飛ばすことにより金属板の表面にロウ材粉末接着層が形成されたロウ材粉末接着材料を製造する加熱乾燥炉と、該加熱乾燥炉で製造したロウ材粉末接着材料を巻き取る巻取機とを備えたことを特徴とする金属材料製造装置。   A rewinding machine for rewinding a metal plate, a spraying device for uniformly applying a slurry-like brazing material liquid in which a brazing powder and a binder are mixed on the surface of the metal plate unwound from the rewinding machine, and a brazing material liquid A heating / drying furnace for producing a brazing material powder adhesive material in which a brazing material powder adhesive layer is formed on the surface of the metal plate by heating the coated metal plate and flying the binder of the brazing material liquid, and the heating / drying furnace A metal material manufacturing apparatus comprising: a winder that winds up the brazing material powder adhesive material manufactured in (1). 金属板を巻き戻す巻戻機と、巻戻機から巻き出された金属板の表面にロウ材粉末とバインダーを混合したスラリー状のロウ材液を押し出して所定厚さの層状に塗布する押出塗布装置と、ロウ材液が塗布された金属板を加熱して前記ロウ材液のバインダーを飛ばすことにより金属板の表面にロウ材粉末接着層が形成されたロウ材粉末接着材料を製造する加熱乾燥炉と、該加熱乾燥炉で製造したロウ材粉末接着材料を巻き取る巻取機とを備えたことを特徴とする金属材料製造装置。   A rewinding machine that rewinds a metal plate, and an extrusion coating that extrudes a slurry-like brazing material liquid in which a brazing material powder and a binder are mixed onto the surface of the metal plate that has been unwound from the rewinding machine, and applies it to a layer having a predetermined thickness. Heat drying to manufacture a brazing material powder adhesive material in which a brazing material powder adhesive layer is formed on the surface of the metal plate by heating the apparatus and the metal plate coated with the brazing material liquid to blow off the binder of the brazing material liquid An apparatus for producing a metal material, comprising: a furnace; and a winder that winds up the brazing material powder adhesive material produced in the heating and drying furnace. 前記押出塗布装置は、ロウ材液をスリット開口から押し出して金属板の表面にロウ材液の層を付着させるロウ材液押出部と、ロウ材液押出部から金属板の表面に押し出されたロウ材液の層厚を調整する厚さ調整部とからなることを特徴とする請求項6に記載の金属材料製造装置。   The extrusion coating apparatus includes a brazing material liquid extruding unit that extrudes a brazing material liquid from a slit opening to adhere a brazing material liquid layer to the surface of the metal plate, and a brazing material extruded from the brazing material liquid extruding unit to the surface of the metal plate. The metal material manufacturing apparatus according to claim 6, further comprising a thickness adjusting unit that adjusts a layer thickness of the material liquid. 前記加熱乾燥炉の少なくとも後段に配置して圧下することにより金属板の表面に形成されるロウ材粉末接着層を所定の層厚で均一に調整するための圧下装置を備えたことを特徴とする請求項5〜7のいずれか1つに記載の金属材料製造装置。   A reduction device is provided for uniformly adjusting the brazing material powder adhesive layer formed on the surface of the metal plate with a predetermined layer thickness by arranging and reducing at least the latter stage of the heating and drying furnace. The metal material manufacturing apparatus as described in any one of Claims 5-7. 請求項5〜8のいずれか1つに記載の金属材料製造装置で製造したロウ材粉末接着材料を加熱してロウ材粉末接着層を融解することにより金属板の表面に融着層が一体に形成されたロウ材融着材料を製造する融解加熱炉を備えたことを特徴とする金属材料製造装置。   The fusion bonding layer is integrally formed on the surface of the metal plate by heating the brazing powder adhering material produced by the metal material producing apparatus according to claim 5 to melt the brazing powder adhering layer. A metal material manufacturing apparatus comprising a melting heating furnace for manufacturing a formed brazing material.
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CN108080817A (en) * 2017-12-29 2018-05-29 郑州机械研究所有限公司 A kind of preparation facilities and preparation method of spiral state solder cake
CN111867780A (en) * 2020-06-08 2020-10-30 郑州机械研究所有限公司 Device and method for manufacturing coated welding rod
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