JP2007262548A - Method of forming functional metal coated film onto metal product provided with temperature control function - Google Patents

Method of forming functional metal coated film onto metal product provided with temperature control function Download PDF

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JP2007262548A
JP2007262548A JP2006092822A JP2006092822A JP2007262548A JP 2007262548 A JP2007262548 A JP 2007262548A JP 2006092822 A JP2006092822 A JP 2006092822A JP 2006092822 A JP2006092822 A JP 2006092822A JP 2007262548 A JP2007262548 A JP 2007262548A
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temperature control
metal film
control function
temperature
metal
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JP4644814B2 (en
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Toshitaka Watanabe
利隆 渡辺
Susumu Yamada
享 山田
Tomoki Fujino
知樹 藤野
Shigeru Moriya
茂 森谷
Satoru Nakano
哲 中野
Mutsuto Kato
睦人 加藤
Toru Yahagi
徹 矢作
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WATANABE CHUZOSHO KK
Yamagata Prefecture
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WATANABE CHUZOSHO KK
Yamagata Prefecture
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of efficiently forming a functional metal coated film by using a small amount of raw material with respect to a desired surface of a casting product such as an injection molding die provided with a temperature control function. <P>SOLUTION: A temperature-controlled medium of a temperature controller is connected to a metal member to be treated provided with a temperature-controlled function to permit temperature control of the member to be treated, thereafter, is controlled into a first temperature range suitable for a degreasing process for a metal coated film forming surface of the member to perform degreasing, subsequently, is controlled into a second temperature range to perform a rinsing process of degreasing liquid, an acid activation process for the coated film forming surface and a rinsing process of acid activation liquid and, subsequently, is set into a third temperature range suitable for metal coated film formation to simultaneously perform coated film formation by injecting liquid agent for coated film formation. Thereafter, temperature control is performed into a fourth temperature range suitable for washing of the liquid agent to discharge the liquid agent, the washing is repeated such that the liquid agent does not remain by washing liquid such as ion exchanged water and, as the result, the functional metal coated film formation to a metal product provided with a temperature control function is performed. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、正確な温度調節が必要となる鋳造製品、例えば射出成形用金型、プレス用金型、加工機用ベッド、半導体製造プロセス用炉体、押出機用バレル等金属製品の所要面に対して、機能性金属被膜を効率良く形成する機能性金属被膜形成方法に関する。 The present invention can be applied to required surfaces of metal products such as injection molds, press dies, processing machine beds, furnace bodies for semiconductor manufacturing processes, barrels for extruders and the like that require precise temperature control. On the other hand, the present invention relates to a functional metal film forming method for efficiently forming a functional metal film.

高精度の要求される精密装置の架台、支持材、駆動部構成材、プレス用金型、プラスチック射出成形用金型等にあっては、正確な温度調節(以下、「温調」と略記する)を行うために温調媒体を通流させるための温調用配管が装備されている鋳造製品を利用するものが多い。このような鋳造製品に温調配管を形成するには種々の方式があるが、最も確実な手法は鋳造工程において鋳型内に配管材を配設して、いわゆる鋳包み(いぐるみ)法によって形成するものである。 Accurate temperature control (hereinafter abbreviated as “temperature control”) for precision equipment racks, supports, drive components, press molds, plastic injection molds, etc. that require high precision In many cases, a cast product equipped with a temperature control pipe for passing a temperature control medium is used. There are various methods for forming temperature control pipes in such cast products, but the most reliable method is to form the pipe material in the mold in the casting process and form it by the so-called cast-in method. To do.

本出願人は、特願2005−260164号において所定成分の原材料であってマルテンサイト変態開始温度が室温付近にあり、マルテンサイト変態開始温度が氷点下であるマルテンサイト鋳造材を開示している。併せて、この技術によって得られる鋳造材により、鋳包み法によって温調配管、電熱ヒーターや測温センサ等の取り付け配管等を設けた鋳造製品の製造方法を開示している。 In Japanese Patent Application No. 2005-260164, the present applicant discloses a martensitic cast material which is a raw material of a predetermined component, has a martensitic transformation start temperature near room temperature, and has a martensitic transformation start temperature below freezing point. In addition, there is disclosed a method for producing a cast product in which a temperature control pipe, an installation pipe for an electric heater, a temperature sensor, and the like are provided by a casting method using a cast material obtained by this technique.

一方、温調配管を設けた鋳造製品の表面の耐久性を高める場合、さらには製品表面を鏡面仕上げとする場合、研磨よりも安価かつ短時間に処理し得る機能性金属被膜を形成する手段が広く採用される。機能性金属被膜を形成する手法としては、例えば、電気めっき、無電解めっき、溶射、PVD/CVD、スパッタリング等各種方式が知られているが、装置が高価であったり、高度の処理技術が要求されたり、処理製品のサイズが限定されるものなどが混在し、全ての分野で適用可能なものはない。これらの中で、電気めっき、無電解めっき等のめっき法は、管や筒の内部から複雑な外形の表面をはじめ、大型の対象物表面などへの金属被膜形成に適しており、広い分野で採用されている。 On the other hand, when enhancing the durability of the surface of the cast product provided with temperature control piping, and further, when the product surface is mirror-finished, means for forming a functional metal film that can be processed at a lower cost and in a shorter time than polishing. Widely adopted. Various methods such as electroplating, electroless plating, thermal spraying, PVD / CVD, and sputtering are known as methods for forming a functional metal film, but the apparatus is expensive or requires advanced processing technology. Or products whose processing product sizes are limited are mixed, and there is nothing that can be applied in all fields. Of these, plating methods such as electroplating and electroless plating are suitable for forming metal coatings on the surface of large objects, starting from the inside of pipes and cylinders, to the surface of complex shapes. It has been adopted.

金属製品の表面に金属被膜を形成する方法として、特許文献1は、被処理部材である内燃エンジン用シリンダのピストン摺動面となる内周面等のめっきを必要とする部分のみにめっきを適正に施す技術を開示している。ここでは底部に吸・排気弁等の開口部を有するシリンダの内面に無電解めっきを施そうとするものであり、シリンダ内に無電解めっき液を導入し、所定流速で通過させながらシリンダ内周の所望部位に無電解めっきを施そうとするものである。この場合、処理温度の管理は処理速度や仕上げ品質に大きな影響を与えるめっき液管理は別途行わなければならない。 As a method for forming a metal film on the surface of a metal product, Patent Document 1 discloses that plating is appropriate only for a portion that requires plating, such as an inner peripheral surface serving as a piston sliding surface of a cylinder for an internal combustion engine that is a member to be processed. The technique applied to is disclosed. Here, electroless plating is applied to the inner surface of a cylinder having an opening such as an intake / exhaust valve at the bottom, and an electroless plating solution is introduced into the cylinder and allowed to pass at a predetermined flow rate while the inner circumference of the cylinder is being passed. It is intended to apply electroless plating to the desired part. In this case, the management of the plating temperature, which greatly affects the processing speed and finishing quality, must be performed separately for the processing temperature management.

特許文献2は、有底の孔を有する被処理物の孔の内壁面に無電解めっき法により均一な金属膜を形成する技術を開示している。ここでは、有底の孔の開口部から底部付近まで細管を挿入配置し、この細管内を通して、流速2〜200cm/分で無電解めっき液を供給することにより、均一な金属被膜を形成することを開示している。このような手法により、例えば金型の冷却水管内壁面に防錆効果の高い金属膜を形成することができ、管内に防錆剤や防錆油の塗布などの防錆対策が不要となり、冷却効果の変動が防止でき、作業効率の向上、経費削減等が期待できることを開示している。しかし、この技術は、有底の孔内壁面に対する無電解めっき方法であり、展開する凹部や被対象物の外表面に適用することはできない。 Patent Document 2 discloses a technique for forming a uniform metal film on an inner wall surface of a hole of a workpiece having a bottomed hole by an electroless plating method. Here, a uniform metal film is formed by inserting and arranging a thin tube from the opening of the bottomed hole to the vicinity of the bottom and supplying an electroless plating solution through the thin tube at a flow rate of 2 to 200 cm / min. Is disclosed. By such a method, for example, a metal film having a high rust prevention effect can be formed on the inner wall surface of the cooling water pipe of the mold. It discloses that it is possible to prevent fluctuations in the effect, and to improve work efficiency and reduce costs. However, this technique is an electroless plating method for the inner wall surface of a hole with a bottom, and cannot be applied to a concave portion to be developed or an outer surface of an object.

特許文献3は、長尺金属管内面に無電解めっきを行う技術を開示するものであり、金属管の両端を通電電極として通電・加熱する手法で予備加熱を行い、通電加熱を行いながら所定のめっき温度よりも高温に加熱しためっき液を連続的に通液して長尺金属管の内面に金属被覆層を形成する技術思想を開示している。この方法では、金属管を抵抗体として捉え、通電した際のジュール熱を利用して金属管を予備加熱しようとするものである。そのため、金属管の電気抵抗、したがって当該金属管の材質、管径、肉厚、長さ等の諸寸法、他物との接触の状態などによって大きく左右され、全ての金属管において満足な結果が得られるとは限らない。また、展開する凹部や被対象物の外表面に適用することは困難である。
特開2005−120413号公報 特開平09−13174号公報 特開平09−279357号公報
Patent Document 3 discloses a technique for performing electroless plating on the inner surface of a long metal tube. Preheating is performed using a method in which both ends of the metal tube are energized and heated as current-carrying electrodes. A technical idea is disclosed in which a plating solution heated to a temperature higher than the plating temperature is continuously passed to form a metal coating layer on the inner surface of a long metal tube. In this method, a metal tube is regarded as a resistor, and the metal tube is preheated using Joule heat when energized. Therefore, it depends greatly on the electrical resistance of the metal tube, and therefore the material, tube diameter, thickness, length and other dimensions of the metal tube, and the contact state with other objects. It is not necessarily obtained. Moreover, it is difficult to apply to the recessed part to expand | deploy and the outer surface of a target object.
Japanese Patent Laid-Open No. 2005-120413 Japanese Patent Laid-Open No. 09-13174 JP 09-279357 A

本発明は、温調機能を備えた鋳造製品、例えば射出成形用金型、プレス用金型、加工機用ベッド、半導体製造プロセス用炉体、押出機バレル等の所望面に対して、少量の素材を用いて機能性金属被膜を効率良く形成する、機能性金属被膜形成方法を提供することを課題とする。 The present invention provides a casting product having a temperature control function, such as an injection mold, a press mold, a processing machine bed, a furnace for a semiconductor manufacturing process, a barrel for an extruder, a desired amount of surface, etc. It is an object of the present invention to provide a method for forming a functional metal film that efficiently forms a functional metal film using a material.

請求項1に記載の発明は、温調機における温調媒体の出口2Bおよび入口2Aを、温調機能を具備する金属製被処理部材23の対応する温調媒体接続部にそれぞれ接続することにより温度調節を可能とした上、前記被処理部材の金属被膜形成面に対する脱脂工程に適する第1の温度範囲に調整してから被処理部材の脱脂工程を実行し、脱脂工程終了後に温度調節を行って、第2の温度範囲に調整してから脱脂液の水洗工程を実行し、次いで金属被膜形成面に対して酸活性化工程を実行し、次いで酸活性液の水洗工程を実行し、次いで金属被膜形成処理に適する第3の温度範囲に設定すると同時に金属被膜形成用液剤を注入し、金属被膜が形成された後、金属被膜形成用液剤の洗浄に適する第4の温度範囲に温調を行いながら、金属被膜形成用液剤を排出し、さらにイオン交換水等の洗浄液により金属被膜形成用液剤が残留しないよう洗浄を繰返す、温調機能を具備する金属製品への機能性金属被膜形成方法であることを特徴とする。 According to the first aspect of the present invention, the outlet 2B and the inlet 2A of the temperature control medium in the temperature controller are respectively connected to the corresponding temperature control medium connecting portions of the metal member 23 having a temperature control function. In addition to adjusting the temperature, the degreasing step for the member to be processed is performed after adjusting the temperature to the first temperature range suitable for the degreasing step for the metal film forming surface of the member to be treated, and the temperature is adjusted after the degreasing step is completed. Then, after adjusting to the second temperature range, the degreasing liquid washing step is performed, then the metal film forming surface is subjected to the acid activation step, then the acid activation liquid washing step is performed, and then the metal is washed. At the same time as setting the third temperature range suitable for the film forming treatment, the metal film forming solution is injected, and after the metal film is formed, the temperature is adjusted to the fourth temperature range suitable for cleaning the metal film forming solution. While forming a metal film It is a method for forming a functional metal film on a metal product having a temperature control function, in which the agent is discharged and the cleaning is repeated so that the metal film forming liquid does not remain with a cleaning liquid such as ion exchange water.

請求項2に記載の発明は、前記温調機能を具備する被処理部材のキャビティ部、炉体空洞部、一方を閉塞させた筒状体等の凹部に対して、前記脱脂、水洗、酸活性化、水洗、金属被膜形成処理および洗浄の諸工程に要する各処理液を直接注液することにより金属被膜形成が実行される、温調機能を具備する金属製品への機能性金属被膜形成方法であることを特徴とする。 In the invention according to claim 2, the degreasing, rinsing, and acid activity are performed on the cavity portion of the member to be processed having the temperature control function, the cavity portion of the furnace body, and the concave portion such as the cylindrical body that is closed on one side. In a method for forming a functional metal film on a metal product having a temperature control function, the metal film is formed by directly injecting each processing solution required for various steps of crystallization, water washing, metal film formation treatment and washing It is characterized by being.

請求項3に記載の発明は、前記温調機能を具備する被処理部材の平面部、突出部ならびに液体を貯えるに足りる十分な深さのない浅い凹部等に対して機能性金属被膜を形成するために、該機能性金属被膜形成部を包囲する防液壁を仮止めし、このように形成された防液壁に包囲された凹部に対して、前記脱脂、水洗、酸活性化、水洗、金属被膜形成処理および洗浄の諸工程に要する各処理液を直接注液することにより金属被膜形成が実行される、温調機能を具備する金属製品への機能性金属被膜形成方法であることを特徴とする。 According to a third aspect of the present invention, a functional metal film is formed on a planar portion, a protruding portion, and a shallow concave portion that is not deep enough to store a liquid, etc. of the member to be processed having the temperature control function. For this purpose, the liquid barrier surrounding the functional metal film forming portion is temporarily fixed, and the degreasing, water washing, acid activation, water washing, and the recess surrounded by the liquid barrier formed in this way, A method for forming a functional metal film on a metal product having a temperature control function, in which the metal film is formed by directly injecting treatment liquids required for various processes of metal film formation and cleaning. And

請求項4に記載の発明は、前記温調機能を具備する被処理部材の全面ないし大部分の面に対して機能性金属被膜を形成するために、該被処理部材全体を僅かな余裕をもって収容し得る容器に納め、当該容器と被処理部材との間に対して、前記脱脂、水洗、酸活性化、水洗、金属被膜形成処理および洗浄の諸工程に要する各処理液を直接注液することにより金属被膜形成が実行される、温調機能を具備する金属製品への機能性金属被膜形成方法であることを特徴とする。 According to a fourth aspect of the present invention, in order to form a functional metal film on the entire surface or most of the surface of the member to be processed having the temperature control function, the entire member to be processed is accommodated with a slight margin. Each processing solution required for the steps of the degreasing, water washing, acid activation, water washing, metal film forming treatment and washing is directly poured between the container and the member to be treated. The method is characterized in that the metal film is formed by the method for forming a functional metal film on a metal product having a temperature control function.

請求項5に記載の発明は、前記金属被膜形成処理が無電解めっき液を使用する無電解めっき処理であり、前記脱脂工程にはNaOH、KOH、Na2CO3、Na3PO4、界面活性剤等から選ばれた1ないし複数種のアルカリ脱脂剤が使用される温調機能を具備する金属製品への機能性金属被膜形成方法であることを特徴とする。前記めっき液は酸性又はアルカリ性のめっき液を使用することができる。また、前記脱脂工程に使用されるアルカリ脱脂剤としてはグリコン酸ナトリウムを使用することができ、その成分はNaOH等に限定されるものではない。 The invention described in claim 5, wherein the metal film formation process is an electroless plating process using an electroless plating solution, NaOH in the degreasing step, KOH, Na 2 CO 3, Na 3 PO 4, surfactant It is a method for forming a functional metal film on a metal product having a temperature control function in which one or more types of alkali degreasing agents selected from agents and the like are used. As the plating solution, an acidic or alkaline plating solution can be used. In addition, as the alkaline degreasing agent used in the degreasing step, sodium glycolate can be used, and its component is not limited to NaOH or the like.

請求項6に記載の発明は、前記金属被膜形成処理が無電解Ni-P(ニッケル-リン)めっき液を使用する無電解めっき処理である、温調機能を具備する金属製品への機能性金属被膜形成方法であることを特徴とする。 The invention according to claim 6 is a functional metal for a metal product having a temperature control function, wherein the metal film forming treatment is an electroless plating treatment using an electroless Ni-P (nickel-phosphorus) plating solution. It is a film forming method.

請求項7に記載の発明は、前記第1の温度範囲が45℃〜95℃、第2の温度範囲が5℃〜40℃、第3の温度範囲が45℃〜98℃、そして第4の温度範囲が5℃〜40℃である、温調機能を具備する金属製品への機能性金属被膜形成方法であることを特徴とする。また、前記温度範囲はこれらに限定されるものではなく、−100℃〜300℃の範囲においても実施可能である。このような広い温度範囲は、温調媒体として例えばふっ素系不活性冷媒、水、けい素系油等を使用することにより実現できる。 In the invention according to claim 7, the first temperature range is 45 ° C to 95 ° C, the second temperature range is 5 ° C to 40 ° C, the third temperature range is 45 ° C to 98 ° C, and the fourth temperature range is It is a method for forming a functional metal film on a metal product having a temperature control function, which has a temperature range of 5 ° C to 40 ° C. Moreover, the said temperature range is not limited to these, It can implement also in the range of -100 degreeC-300 degreeC. Such a wide temperature range can be realized by using, for example, a fluorine-based inert refrigerant, water, silicon-based oil or the like as the temperature control medium.

請求項8に記載の発明は、前記被処理部材が温調配管を具備する射出成形用金型またはプレス加工用金型のいずれかである、温調機能を具備する金属製品への機能性金属被膜形成方法であることを特徴とする。 The invention according to claim 8 is a functional metal to a metal product having a temperature control function, wherein the member to be processed is either an injection mold having a temperature control pipe or a press mold. It is a film forming method.

請求項9に記載の発明は前記被処理部材が温調配管を具備する精密加工機用ベッドであることを特徴とし、請求項10に記載の発明は前記被処理部材が温調配管を具備し一端側を仮閉塞させた押出機バレルであることを特徴とし、請求項11に記載の発明は、前記被処理部材が温調配管を具備する半導体製造プロセス用炉体であることを特徴とする、温調機能を具備する金属製品への機能性金属被膜形成方法である。 The invention according to claim 9 is characterized in that the member to be treated is a bed for a precision processing machine having a temperature control pipe, and the member according to claim 10 has a temperature control pipe. It is an extruder barrel with one end side temporarily closed, and the invention according to claim 11 is characterized in that the member to be processed is a furnace body for a semiconductor manufacturing process having temperature control piping. This is a method for forming a functional metal film on a metal product having a temperature control function.

請求項12に記載の発明は前記被処理部材の温調配管が鋳包み事前配管によって鋳造と同時に形成されることを特徴とし、請求項13に記載の発明は、前記被処理部材の温調配管が後加工によって形成されることを特徴とする温調機能を具備する金属製品への機能性金属被膜形成方法である。 The invention according to claim 12 is characterized in that the temperature control pipe of the member to be processed is formed simultaneously with casting by the cast-in pre-pipe, and the invention according to claim 13 is a temperature control pipe of the member to be processed. Is a method for forming a functional metal film on a metal product having a temperature control function, characterized by being formed by post-processing.

本発明により特定された手法により実行される機能性金属被膜形成方法によれば、温調配管を具備する被処理部材としての金属製品、例えば金型や炉体等にあって、キャビティや溶融対象を受容するための空洞部などの凹部内面、一端を仮閉塞した押出機バレル等の筒状体の内壁面等に対して機能性金属被膜を高効率で経済性にも優れた手法により形成することができる。 According to the functional metal film forming method executed by the method specified by the present invention, a metal product as a member to be processed having a temperature control pipe, for example, a mold, a furnace body, etc. A functional metal coating is formed on the inner surface of a concave portion such as a cavity for receiving a gas, and the inner wall surface of a cylindrical body such as an extruder barrel that is temporarily closed at one end by a highly efficient and economical method. be able to.

実施にあたっては、被処理部材に付属する温調配管により機能性金属被膜形成に適する温度となるように温度調節を行いながら、これらキャビティや空洞等の凹部内壁面に予備処理液、洗浄液、機能性金属被膜形成処理液等を直接注液及び抜き取りを繰返しながら、内壁面に所望の金属被膜を形成することができる。また、被処理部材における金属被膜形成処理面が平坦ないし凸面である場合は、金属被膜形成対象部を包囲する防液壁を仮設し、その内部に所要処理液を注入することにより凹部内面と同様に所望の金属被膜を形成することができる。さらに、被処理部材の外面の大部分または全面に機能性金属被膜を形成する場合には、被処理部材より僅かに大きな容積の容器を用いて、このような容器内に被処理部材を収容し、温度調節を行いながら各処理液等を注入及び抜き取りながら処理すればよい。 In carrying out the pretreatment liquid, cleaning liquid, and functionality on the inner wall of the cavity such as a cavity or cavity, while adjusting the temperature so that the temperature is adjusted to a temperature suitable for functional metal film formation by the temperature control pipe attached to the member to be processed. A desired metal film can be formed on the inner wall surface while directly injecting and extracting the metal film forming treatment liquid and the like. In addition, when the metal film forming treatment surface of the member to be treated is flat or convex, a liquid barrier surrounding the metal film formation target part is temporarily installed, and the required treatment liquid is injected into the inside thereof to provide the same as the inner surface of the recess. A desired metal film can be formed. Further, when a functional metal film is formed on most or the entire outer surface of the member to be processed, a container having a volume slightly larger than that of the member to be processed is used, and the member to be processed is accommodated in such a container. The treatment may be performed while injecting and extracting each treatment solution while adjusting the temperature.

本発明に係る温調機能を具備する被処理部材に対する機能性金属被膜形成処理として、無電解めっき処理が有利に適用可能である。この場合、被処理部材の構成成分に対して少なくとも部分的に重なる成分を含有する無電解めっき液を用いることにより、当該加工物の用済み後リサイクルが有利に実施可能となる。例えば、本出願人の出願にかかる特願2005−260164において開示したサブゼロ処理によって低温でマルテンサイト変態が得られるマルテンサイト鋳造材による金型や半導体プロセス用炉体等の製品の場合、無電解NiP(ニッケル-リン)めっき液を用いる無電解めっきを行った場合、用済み後にはこれらめっき液による金属被膜を研磨その他の手段で除去することなくそのまま溶解することにより、良質の再生地金を得ることができる。 As the functional metal film forming process for the member to be processed having the temperature control function according to the present invention, an electroless plating process can be advantageously applied. In this case, by using an electroless plating solution containing a component that at least partially overlaps the component of the member to be treated, post-use recycling of the workpiece can be advantageously performed. For example, in the case of a product such as a mold or a semiconductor process furnace body made of martensite cast material which can obtain martensite transformation at a low temperature by the sub-zero treatment disclosed in Japanese Patent Application No. 2005-260164 according to the present applicant's application, electroless NiP When electroless plating using a (nickel-phosphorous) plating solution is performed, a high-quality recycled metal is obtained after use by dissolving the metal film without removing it by polishing or other means. be able to.

本発明に係る機能性金属被膜形成処理、例えば無電解めっき処理を行う場合、従来のめっき処理では、アルカリ浸漬脱脂、酸洗浄、酸活性、無電解めっき処理、湯洗等の各処理がそれぞれ異なる浴液槽によって行われていた。被処理部材が大型製品、例えば自動車や列車等の運輸機械用部品製造におけるプレス用金型、射出成形用金型等の大型被処理部材の場合、各工程毎の浴液槽を多数併設する必要があり、大規模な設備ならびに床面積が必要となる。それに伴い、各工程で使用される液剤をはじめ各種資材も大量に必要となり、さらに被処理部材の各浴液槽への浸漬・取り出し工程、各浴液槽間の移動、等のために大型のクレーン移動が必要となり、サイクルタイムも長くなる。これに対して、本発明に係る機能性金属被膜形成処理では、処理場の敷地、建屋、付帯設備等が大幅に節減でき、所要資材ならびに使用エネルギーも少なく、処理時間も短縮できるため経済性に優れており、当該分野における産業の発達に資することができる。 When performing a functional metal film forming process according to the present invention, for example, an electroless plating process, in the conventional plating process, each process such as alkali immersion degreasing, acid cleaning, acid activity, electroless plating process, and hot water washing is different. It was done by bath bath. If the workpiece is a large product, for example, a large mold such as a press mold or an injection mold used in the manufacture of parts for transport machinery such as automobiles and trains, a large number of baths are required for each process. Large-scale equipment and floor space are required. Along with this, a large amount of various materials including liquid agents used in each process is required, and further, a large size is required for the process of immersing and removing the member to be treated in each bath liquid tank, movement between each bath liquid tank, etc. Crane movement is required and cycle time is increased. On the other hand, in the functional metal film forming treatment according to the present invention, the site of the treatment plant, the building, the incidental facilities, etc. can be greatly saved, the required materials and energy used are small, and the treatment time can be shortened, so that it is economical. It is excellent and can contribute to the development of industry in this field.

本発明に係る機能性金属被膜形成処理に適する温調機能を具備する金属製品としては、上述の射出成形用やプレス用の金型類以外に、温調管等の所要部材を鋳包んだ、プラスチックの溶融混練用押出機のバレル、直管ないし曲折した温調配管を鋳包んだ黒体炉、PVD・CVD・ドライエッチング、ウエットエッチング等の炉体、プラズマ発生装置、半導体加工装置炉体、半導体マスク製造用ステッパー、アライナー、精密加工装置の摺動面の精密温度調節機構、シリンダライナー、エンジンブロックなどの各種エンジン用鋳造部品等に有利に適用可能である。なお、これらは単なる例示であり、その他類似構造の温調配管または潤滑油配管等を具備する金属製品にも適用することができ、これら例示に限定されるものではない。 As a metal product having a temperature control function suitable for the functional metal film forming process according to the present invention, in addition to the above-mentioned molds for injection molding and press, a required member such as a temperature control tube is cast-in, Extruder barrel for plastic melting and kneading, black body furnace with straight pipe or bent temperature control pipe, furnace body for PVD / CVD / dry etching, wet etching, plasma generator, semiconductor processing equipment furnace body, The present invention is advantageously applicable to various types of engine casting parts such as semiconductor mask manufacturing steppers, aligners, precision temperature control mechanisms for sliding surfaces of precision processing equipment, cylinder liners, engine blocks, and the like. These are merely examples, and can also be applied to metal products having temperature control pipes or lubricating oil pipes having other similar structures, and are not limited to these examples.

次に、本発明に係る温調機能を具備する金属製品への機能性金属被膜形成方法の内容について開示する。図1は本発明に係る機能性金属被膜形成処理方法によってめっき処理を行う実施態様を示す概念図である。金型である被処理部材1は温調配管2を具備しており、図中央の曲線で示したようなキャビティ3が形成されており、このキャビティ3の壁面に機能性金属被膜としてのめっき層4を形成しようとするものである。 Next, the contents of the method for forming a functional metal film on a metal product having a temperature control function according to the present invention will be disclosed. FIG. 1 is a conceptual diagram showing an embodiment in which plating is performed by the functional metal film forming method according to the present invention. A member 1 to be processed, which is a mold, includes a temperature control pipe 2 and a cavity 3 as shown by a curve in the center of the figure is formed. A plating layer as a functional metal film is formed on the wall surface of the cavity 3. 4 is to be formed.

キャビティ3の周囲を包囲するように、処理液の飛散を防止するための仮設隔壁5が形成されている。この仮設隔壁の材質、取り付け範囲および高さ等については、被処理部材1の大きさ、キャビティ3の形状、容積、処理液6の種類等によって決定すべきものである。また、処理液6は、ムラのない高品位の金属被膜形成のために処理液循環ポンプ7によって適宜循環させ、さらに必要に応じて撹拌装置8によって撹拌するように構成することもできる。 A temporary partition wall 5 is formed so as to prevent the processing liquid from scattering so as to surround the cavity 3. The material, attachment range, height, and the like of the temporary partition wall should be determined according to the size of the member 1 to be processed, the shape and volume of the cavity 3, the type of the processing liquid 6, and the like. Further, the treatment liquid 6 may be appropriately circulated by the treatment liquid circulation pump 7 in order to form a high-quality metal film without unevenness, and may be further agitated by the stirring device 8 as necessary.

なお、温調の効率を高めるために、被処理部材である金型1の外表面を保温材9で包囲しておくと一定温度保持のために都合が良い。さらに、工程中の温度制御において被加工面温度を前処理よりも低下させることもあるため、保温材9は着脱自在であると都合が良い。 In order to increase the efficiency of temperature control, it is convenient to maintain a constant temperature by surrounding the outer surface of the mold 1 as a member to be processed with the heat insulating material 9. Furthermore, since the surface temperature to be processed may be lower than that in the pretreatment in the temperature control during the process, it is convenient that the heat insulating material 9 is detachable.

このような構成において、温調配管2の入口2Aおよび出口2Bを温調のための熱媒体、例えば水、熱水、蒸気、熱媒体油、ふっ素系不活性冷媒等を通流させるための温調機(図示していない)の対応する接続部位にそれぞれ接続し、媒体温度、通流量等を適宜調節することにより、被処理部材である金型の温度を処理に適する温度となるように調節する。この場合の温調手法は、被処理部材が完成した後における温調媒体の種類及び通流方向、流量等と一部異なっていても差し支えないが、管径、曲折部の構成、接続継ぎ手部分の流動抵抗の正逆差等も全くないとはいえないため同じ手法であればなお都合がよい。 In such a configuration, the inlet 2A and outlet 2B of the temperature control pipe 2 are heated to flow a heat medium for temperature control, such as water, hot water, steam, heat medium oil, fluorine-based inert refrigerant, and the like. Adjust the temperature of the mold, which is the member to be processed, to a temperature suitable for processing by connecting to the corresponding connection part of the controller (not shown) and adjusting the medium temperature and flow rate as appropriate. To do. The temperature control method in this case may be partially different from the type and flow direction of the temperature control medium after the processed member is completed, the flow rate, etc., but the pipe diameter, the configuration of the bent part, the connection joint part Since it cannot be said that there is no forward / reverse difference in the flow resistance, the same technique is still more convenient.

次に、図2に示すフロー図を参照して、典型的金属被膜形成処理である無電解めっき処理工程について開示する。ステップS1において被処理面のアルカリ液浸脱脂処理を50℃以上で10分間実施する。次いでステップS2において、水洗浄を行う。次いで、ステップS3において酸活性化を常温において数秒〜数10秒実施する。その後、ステップS4において、再び水洗浄を実行して酸を除去する。その後、ステップS5において処理の中核である無電解めっき処理を80〜90℃の温度範囲で30分〜1時間程度実施する。 Next, an electroless plating process that is a typical metal film forming process will be disclosed with reference to the flowchart shown in FIG. In step S1, alkaline liquid immersion degreasing treatment of the surface to be processed is performed at 50 ° C. or higher for 10 minutes. Next, in step S2, water washing is performed. Next, in step S3, acid activation is performed at room temperature for several seconds to several tens of seconds. Thereafter, in step S4, the water is washed again to remove the acid. Then, in step S5, the electroless plating process which is the core of the process is performed at a temperature range of 80 to 90 ° C. for about 30 minutes to 1 hour.

めっき処理完了後、ステップS6においてめっき後の湯洗を行い、ステップS7の乾燥工程において水分を除去して一連の処理を終了する。従来広く実施されている大型被処理対象に対するめっき処理においては、上記各工程の処理槽がそれぞれ独立して設けられていて、被処理部材をクレーンで吊り上げて移動させながら順次各浴槽の該当する液に浸漬する方法が行われてきた。これに対し、本願発明に係るめっき処理では被処理対象の所要表面に直接めっき処理を行うため、設備が簡素化されるばかりでなく、処理に要するサイクルタイムも短縮され、所要エネルギーも大幅に節減される。 After completion of the plating process, hot water washing after plating is performed in step S6, moisture is removed in the drying process of step S7, and a series of processes is completed. In the plating process for a large target to be processed which has been widely performed conventionally, the processing tanks of the respective steps are provided independently, and the liquids corresponding to the respective baths are sequentially applied while the target member is lifted and moved by a crane. The method of immersing in is carried out. On the other hand, in the plating process according to the present invention, the plating process is performed directly on the required surface of the object to be processed, which not only simplifies the equipment, but also shortens the cycle time required for the process and greatly reduces the required energy. Is done.

図3は大型金属製品に対して従来の金属被膜形成法、例えばめっき処理法を実施するための設備の典型例を示すものである。処理槽21には脱脂、洗浄、活性化、めっき液等いずれかの処理液22が満たされており、大型金属製品である被処理部材23が処理液22に浸漬される。この被処理部材23は、レール20Rを走行する天井走行クレーン20により吊り上げ−走行−吊り下げ動作を経て前工程から順次隣接する次工程まで移動せしめられる。処理槽21内の液温は、所望反応に適した温度に維持する必要があるから、液内に配設される槽内部ヒーター24、液槽周囲に埋め込まれる埋め込み温調配管25等のいずれか一方または双方の組合わせにより温調制御がなされる。また、処理槽21に満たされる処理液22は、付属する処理液循環装置26により浄化、加熱、冷却等の処理が加えられ、供給配管27、回収配管28を介して循環せしめられる。 FIG. 3 shows a typical example of equipment for performing a conventional metal film forming method, for example, a plating method, on a large metal product. The treatment tank 21 is filled with any treatment liquid 22 such as degreasing, cleaning, activation, or plating solution, and a member to be treated 23 that is a large metal product is immersed in the treatment liquid 22. The member 23 to be processed is moved from the previous process to the next process, which is sequentially adjacent, through a lifting-running-hanging operation by the overhead traveling crane 20 traveling on the rail 20R. Since the liquid temperature in the treatment tank 21 needs to be maintained at a temperature suitable for the desired reaction, either the tank internal heater 24 disposed in the liquid, the embedded temperature control pipe 25 embedded around the liquid tank, or the like. Temperature control is performed by one or a combination of both. The processing liquid 22 filled in the processing tank 21 is subjected to processing such as purification, heating, and cooling by an attached processing liquid circulation device 26, and is circulated through a supply pipe 27 and a recovery pipe 28.

このような従来例に係る大型金属製品の金属被膜形成装置にあっては、処理槽21をはじめ、天井走行クレーン20、液槽に付随する処理液循環装置26等は、処理される最大の金属製品の寸法、形状、重量を想定してそれぞれの規模、定格等を決定し、これらに安全係数を乗じて設備構成を行わなければならない。 In such a metal film forming apparatus for large metal products according to the conventional example, the processing tank 21, the overhead traveling crane 20, the processing liquid circulation device 26 associated with the liquid tank, etc. are the largest metal to be processed. It is necessary to determine the size, rating, etc. of each product, assuming the dimensions, shape, and weight of the product, and multiply these by the safety factor to configure the equipment.

したがって、想定される最大寸法の処理対象を受容するための処理槽21が処理工程毎に併置されるため、極めて大きな床面積と、過大設備投資が必要となる。天井走行クレーン20も想定される最大寸法かつ最大重量の被処理金属製品を想定して吊り上げ荷重、走行性能等を決定する必要があり、中・小型製品を処理する場合に過剰定格となり作業効率やエネルギー効率を悪化させる原因となる。また、クレーン設備に関しては一定期間ごとに法定点検等も義務付けられるため、管理上の負担も大きくなる。その他、処理液循環装置26を含め各種付帯設備に関しても同様の過剰設備を前提とすることになる。 Therefore, since the processing tank 21 for receiving the processing target of the assumed maximum dimension is juxtaposed for each processing step, an extremely large floor area and excessive equipment investment are required. The overhead traveling crane 20 is also required to determine the lifting load, traveling performance, etc., assuming the metal product to be treated with the maximum dimensions and maximum weight, which is overrated when processing small and medium-sized products. It becomes a cause of deteriorating energy efficiency. In addition, since legal inspections are required at regular intervals for crane facilities, the administrative burden is also increased. In addition, regarding the various incidental facilities including the treatment liquid circulation device 26, similar excess facilities are assumed.

これに対して本発明に係る処理法によれば、金型キャビティ、各種炉体内部等の凹部を有する被処理部材にあっては、その内部に処理液類を直接注液し、温調は被処理部材金属製品が具備する温調機能による、いわゆる内部直接加熱によって当該処理液に必要な温度に保持しながら、金属製品表面への金属被膜形成が可能となる。また被処理面が平坦部ないし凸部を有する場合は防液仮設壁内部に液体を注いで処理を行い、そして所定時間経過後に前工程の処理液を排出し、次いで次工程の処理液を注ぎながら順次異なる処理を実行するものである。 On the other hand, according to the processing method according to the present invention, in the member to be processed having recesses such as the mold cavity and various furnace bodies, the processing liquids are directly injected into the inside thereof, and the temperature control is performed. A metal film can be formed on the surface of the metal product while maintaining the temperature required for the treatment liquid by so-called internal direct heating by the temperature control function of the metal product to be processed. If the surface to be processed has a flat or convex part, the liquid is poured into the liquid-proof temporary wall for processing, and after a predetermined time has elapsed, the processing liquid in the previous process is discharged, and then the processing liquid in the next process is poured. However, different processes are executed sequentially.

本発明に係る処理法によれば、処理槽間をクレーン等によって移動させる必要もなく、工数削減ならびに処理時間短縮が可能となる。この場合、処理液量は従来装置に比して比較し得ないほど少量であるから、注液−排液のためのポンプ動力、温調に要するエネルギー消費も大幅に節減できる。したがって、典型例として例示したような図3の従来技術に係る処理装置のような過剰設備、過剰定格、効率低下、エネルギー損失の増大のような問題は一挙に解消される。 According to the treatment method of the present invention, it is not necessary to move between treatment tanks with a crane or the like, and man-hours and treatment time can be shortened. In this case, since the amount of the processing liquid is so small that it cannot be compared with the conventional apparatus, the pump power for injection and drainage and the energy consumption required for temperature control can be greatly reduced. Therefore, problems such as excess equipment such as the processing apparatus according to the prior art of FIG. 3 as exemplified as a typical example, excess rating, efficiency reduction, and increase in energy loss are solved at once.

本発明に係る金属製品への機能性金属被膜形成方法は、本来的に温度調節機能を具備する金属製品の所望面に機能性金属被膜、例えば無電解めっきによる金属被膜を形成する際に、金属製品自体が具備する温調機能を活用して温度制御を行いながら処理液を直接注液することにより、経済的に機能性金属被膜を形成しようとするものである。このような手法によれば、自動車、鉄道車両、航空機、船舶等の各種輸送機械等に使用される大型金属部材製造用の金型、プラスチック射出成形用金型、半導体プロセス用炉体、押出機用バレル、その他大型金属部材の製造に当たって、大きな利益が得られる。 The method for forming a functional metal film on a metal product according to the present invention is characterized in that when a functional metal film, for example, a metal film by electroless plating is formed on a desired surface of a metal product that originally has a temperature control function, A functional metal film is economically formed by directly injecting a treatment liquid while performing temperature control using a temperature control function of the product itself. According to such a technique, a metal mold for manufacturing a large metal member, a plastic injection mold, a furnace body for a semiconductor process, an extruder used for various transport machines such as automobiles, railway vehicles, airplanes, and ships. There are significant benefits in manufacturing barrels and other large metal components.

本発明に係る温調機能を具備する金属製品への機能性金属被膜形成方法の実施状態を示す概念図である。It is a conceptual diagram which shows the implementation state of the functional metal film formation method to the metal product which comprises the temperature control function which concerns on this invention. 本発明に係る温調機能を具備する金属製品への機能性金属被膜形成方法である無電解めっき処理の典型的処理工程を示すフロー図である。It is a flowchart which shows the typical process process of the electroless-plating process which is a functional metal film formation method to the metal product which comprises the temperature control function which concerns on this invention. 従来技術に係る機能性金属被膜形成方法の実施状態を示す概念図である。It is a conceptual diagram which shows the implementation state of the functional metal film formation method which concerns on a prior art.

符号の説明Explanation of symbols

1 鋳包み温調配管付き被処理部材(金型)
2 温調配管
2A 温調媒体入口
2B 温調媒体出口
3 キャビティ
4 機能性金属被膜(めっき層)
5 仮設隔壁
6 処理液
7 処理液循環ポンプ
8 撹拌装置
9 保温材
20 天井走行クレーン
20R レール
21 処理槽
22 処理液
23 被処理部材
24 槽内部ヒーター
25 埋め込み温調配管
26 処理液循環装置
27 処理液供給配管
28 処理液回収配管
1 Processed parts with mold temperature control piping (mold)
2 Temperature control piping 2A Temperature control medium inlet 2B Temperature control medium outlet 3 Cavity 4 Functional metal coating (plating layer)
5 Temporary partition wall 6 Treatment liquid 7 Treatment liquid circulation pump 8 Stirrer 9 Thermal insulation material 20 Overhead crane 20R Rail 21 Treatment tank 22 Treatment liquid 23 Processed member 24 Tank internal heater 25 Embedded temperature control pipe 26 Treatment liquid circulation apparatus 27 Treatment liquid Supply piping 28 Treatment liquid recovery piping

Claims (13)

温調機における温調媒体の出口および入口を、温調機能を具備する金属製被処理部材の対応する温調媒体接続部にそれぞれ接続することにより温度調節を可能とした上、前記被処理部材の金属被膜形成面に対する脱脂工程に適する第1の温度範囲に調整してから被処理部材の脱脂工程を実行し、脱脂工程終了後に温度調節を行って、第2の温度範囲に調整してから脱脂液の水洗工程を実行し、次いで金属被膜形成面に対して酸活性化工程を実行し、次いで酸活性液の水洗工程を実行し、次いで金属被膜形成処理に適する第3の温度範囲に設定すると同時に金属被膜形成用液剤を注入し、金属被膜が形成された後、金属被膜形成用液剤の洗浄に適する第4の温度範囲に温調を行いながら、金属被膜形成用液剤を排出し、さらにイオン交換水等の洗浄液により金属被膜形成用液剤が残留しないよう洗浄を繰返す、ことを特徴とする温調機能を具備する金属製品への機能性金属被膜形成方法。 Temperature control is possible by connecting the outlet and the inlet of the temperature control medium in the temperature controller to the corresponding temperature control medium connection part of the metal processed member having a temperature control function, and then the processed member After adjusting to the first temperature range suitable for the degreasing process on the metal film forming surface, the degreasing process for the member to be treated is performed, and after the degreasing process, the temperature is adjusted to the second temperature range. Execute a degreasing water washing step, then perform an acid activation step on the metal film forming surface, then perform an acid activation water washing step, and then set to a third temperature range suitable for the metal film forming treatment At the same time, the metal film forming liquid is injected, and after the metal film is formed, the metal film forming liquid is discharged while adjusting the temperature to a fourth temperature range suitable for cleaning the metal film forming liquid. Washing ion exchange water A method for forming a functional metal film on a metal product having a temperature control function, characterized in that the cleaning is repeated so that the liquid agent for forming a metal film does not remain in the cleaning liquid. 前記温調機能を具備する被処理部材のキャビティ部、炉体空洞部、一方を閉塞させた筒状体等の凹部に対して、前記脱脂、水洗、酸活性化、水洗、金属被膜形成処理および洗浄の諸工程に要する各処理液を直接注液することにより金属被膜形成が実行される、ことを特徴とする請求項1に記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 The degreasing, rinsing, acid activation, rinsing, metal film forming treatment, and the like for the cavity portion of the member to be treated having the temperature control function, the cavity portion of the furnace body, and the concave portion such as the cylindrical body closed on one side 2. The formation of a functional metal film on a metal product having a temperature control function according to claim 1, wherein the metal film is formed by directly injecting each processing solution required for cleaning steps. Method. 前記温調機能を具備する被処理部材の平面部、突出部ならびに液体を貯えるに足りる十分な深さのない浅い凹部等に対して機能性金属被膜を形成するために、該機能性金属被膜形成部を包囲する防液壁を仮止めし、このように形成された防液壁に包囲された凹部に対して、前記脱脂、水洗、酸活性化、水洗、金属被膜形成処理および洗浄の諸工程に要する各処理液を直接注液することにより金属被膜形成が実行される、ことを特徴とする請求項1に記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 In order to form a functional metal film on a planar portion, a projecting portion, and a shallow concave portion that is not deep enough to store liquid, the functional metal film is formed. Steps of degreasing, water washing, acid activation, water washing, metal film forming treatment and washing are performed on the recess surrounded by the liquid barrier wall formed by temporarily fixing the liquid barrier surrounding the portion. The method for forming a functional metal film on a metal product having a temperature control function according to claim 1, wherein the metal film is formed by directly injecting each processing solution required for the treatment. 前記温調機能を具備する被処理部材の全面ないし大部分の面に対して機能性金属被膜を形成するために、該被処理部材全体を僅かな余裕をもって収容し得る容器に納め、該容器と被処理部材との間に対して、前記脱脂、水洗、酸活性化、水洗、金属被膜形成処理および洗浄の諸工程に要する各処理液を直接注液することにより金属被膜形成が実行される、ことを特徴とする請求項1に記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 In order to form a functional metal film on the entire surface or most of the member to be processed having the temperature control function, the entire member to be processed is placed in a container that can be accommodated with a slight margin. Metal film formation is performed by directly injecting each treatment liquid required for the steps of degreasing, water washing, acid activation, water washing, metal film formation treatment and washing with respect to the member to be treated. The method for forming a functional metal film on a metal product having a temperature control function according to claim 1. 前記金属被膜形成処理が無電解めっき液を使用する無電解めっき処理であり、前記脱脂工程にはNaOH、KOH、Na2CO3、Na3PO4、界面活性剤等から選ばれた1ないし複数種のアルカリ脱脂剤が使用される、ことを特徴とする請求項1ないし4のいずれかに記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 The metal film forming treatment is an electroless plating treatment using an electroless plating solution, and the degreasing step includes one or more selected from NaOH, KOH, Na 2 CO 3 , Na 3 PO 4 , a surfactant, and the like. A method for forming a functional metal film on a metal product having a temperature control function according to any one of claims 1 to 4, wherein a seed alkali degreasing agent is used. 前記金属被膜形成処理が無電解Ni-P(ニッケル-リン)めっき液を使用する無電解めっき処理である、ことを特徴とする請求項5に記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 6. The function for a metal product having a temperature control function according to claim 5, wherein the metal film forming process is an electroless plating process using an electroless Ni-P (nickel-phosphorus) plating solution. Metal film forming method. 前記第1の温度範囲が45℃〜95℃、第2の温度範囲が5℃〜40℃、第3の温度範囲が45℃〜98℃、そして第4の温度範囲が5℃〜40℃である、ことを特徴とする請求項1に記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 The first temperature range is 45 ° C to 95 ° C, the second temperature range is 5 ° C to 40 ° C, the third temperature range is 45 ° C to 98 ° C, and the fourth temperature range is 5 ° C to 40 ° C. The method for forming a functional metal film on a metal product having a temperature control function according to claim 1. 前記被処理部材が温調配管を具備する射出成形用金型またはプレス加工用金型のいずれかである、ことを特徴とする請求項1ないし7のいずれかに記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 The temperature control function according to claim 1, wherein the member to be processed is either an injection mold having a temperature control pipe or a press mold. A method for forming a functional metal film on a metal product. 前記被処理部材が温調配管を具備する精密加工機用ベッドである、ことを特徴とする請求項1ないし7のいずれかに記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 The functional metal film is formed on a metal product having a temperature control function according to any one of claims 1 to 7, wherein the member to be processed is a bed for a precision processing machine including a temperature control pipe. Method. 前記被処理部材が温調配管を具備し、一端側を仮閉塞させた押出機バレルである、ことを特徴とする請求項1ないし7のいずれかに記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 The metal member having a temperature control function according to any one of claims 1 to 7, wherein the member to be processed is an extruder barrel having a temperature control pipe and having one end side temporarily closed. Functional metal film forming method. 前記被処理部材が温調配管を具備する半導体製造プロセス用炉体である、ことを特徴とする請求項1ないし7のいずれかに記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 The functional metal coating on a metal product having a temperature control function according to any one of claims 1 to 7, wherein the member to be processed is a furnace body for a semiconductor manufacturing process including a temperature control pipe. Forming method. 前記被処理部材の温調配管が鋳包み事前配管によって鋳造と同時に形成される、ことを特徴とする請求項1ないし7のいずれかに記載の温調機能を具備する金属製品への機能性金属被膜形成方法。 The functional metal to a metal product having a temperature control function according to any one of claims 1 to 7, wherein the temperature control pipe of the member to be processed is formed simultaneously with casting by a cast-in pre-pipe. Film formation method. 前記被処理部材の温調配管が後加工によって形成される、ことを特徴とする請求項1ないし7のいずれかに記載の温調機能を具備する金属製品への機能性金属被膜形成方法。
The method for forming a functional metal film on a metal product having a temperature control function according to any one of claims 1 to 7, wherein the temperature control piping of the member to be processed is formed by post-processing.
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