JPH08319576A - Electroless plating method and plating device for long-sized pipe - Google Patents
Electroless plating method and plating device for long-sized pipeInfo
- Publication number
- JPH08319576A JPH08319576A JP12408195A JP12408195A JPH08319576A JP H08319576 A JPH08319576 A JP H08319576A JP 12408195 A JP12408195 A JP 12408195A JP 12408195 A JP12408195 A JP 12408195A JP H08319576 A JPH08319576 A JP H08319576A
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- Prior art keywords
- plating
- long
- tube
- long tube
- pipe
- Prior art date
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Abstract
Description
【0001】[0001]
【産業上の利用分野】本発明は、油井管やラインパイプ
のような長尺で大重量の金属管の内面および外面を無電
解めっき法によりめっきするのに適した長尺管のめっき
方法及びめっき装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for plating a long pipe suitable for plating the inner and outer surfaces of a long and heavy metal pipe such as an oil well pipe or a line pipe by electroless plating. Regarding plating equipment.
【0002】[0002]
【従来の技術】鋼管は、使用環境に応じて、内面および
外面に表面処理が施されることがある。例えば、防錆の
目的で塗油または薄膜塗装が施されることがある。さら
に、一層強力な防錆用として、或いは摺動や摩耗に耐え
るようにするための表面硬化処理として、内面や外面の
めっきが行われている。この種のめっきの例として、亜
鉛または亜鉛合金めっき、クロムめっき、ニッケルめっ
き、コバルトめっきなどがある。これらのめっきのう
ち、亜鉛または亜鉛合金めっきは、溶融めっき法または
電解めっき法により行うのが普通であるが、その他のめ
っきは電解めっき法または無電解めっき(化学めっき)
法により一般にめっきが行われる。2. Description of the Related Art Steel pipes may be surface-treated on their inner and outer surfaces depending on the environment of use. For example, oil coating or thin film coating may be applied for the purpose of rust prevention. In addition, the inner surface or the outer surface is plated for stronger rust prevention or as a surface hardening treatment to withstand sliding and abrasion. Examples of this type of plating include zinc or zinc alloy plating, chromium plating, nickel plating, cobalt plating and the like. Of these platings, zinc or zinc alloy plating is usually performed by hot dipping or electrolytic plating, but other platings are electrolytic or electroless plating (chemical plating).
Plating is generally performed by the method.
【0003】一般に鋼管のめっきは、被めっき鋼管より
大きなめっき槽の中に鋼管を水平、垂直、または傾斜さ
せて収容することにより行われる。無電解めっきでは、
この方法では鋼管の内外面が同時にめっきされる。内面
めっきの場合には、鋼管の両端を封止し、この鋼管をめ
っき槽として、鋼管の内部に無電解めっき液を供給する
ことにより、内面をめっきを施すことも知られている。
しかし、鋼管の外面のみを無電解めっき法によりめっき
する方法は確立していなかった。Generally, the plating of a steel pipe is carried out by housing the steel pipe horizontally, vertically, or inclined in a plating tank larger than the steel pipe to be plated. In electroless plating,
In this method, the inner and outer surfaces of the steel pipe are plated at the same time. In the case of inner surface plating, it is also known that both ends of a steel pipe are sealed, the steel pipe is used as a plating tank, and an electroless plating solution is supplied to the inside of the steel pipe to plate the inner surface.
However, a method of plating only the outer surface of the steel pipe by electroless plating has not been established.
【0004】近年、鋼管の製造技術が向上して、継ぎ目
なし鋼管でも10mを超えるような長尺の鋼管の製造が可
能となり、それに伴って、めっき槽の大型化とめっき工
程間の鋼管の移動が問題となっている。また、従来はめ
っき槽とは別にめっき前処理用の槽を使用し、何種類も
の槽を配置するのに広い場所が必要であった。また、め
っき槽が大きいと多量のめっき液と各前処理液が必要と
なり、電気めっき法に比べてめっき液が高価な無電解め
っき法は、コスト的に不利となる。さらに、各工程間で
は水洗も行うため、廃液処理の必要な汚染水が多量に発
生する。In recent years, the technology for manufacturing steel pipes has improved, and it has become possible to manufacture long steel pipes having a length of more than 10 m even for seamless steel pipes, and as a result, the plating tank becomes larger and the steel pipe moves between plating processes. Is a problem. Further, conventionally, a bath for plating pretreatment was used in addition to the plating bath, and a wide space was required to arrange many types of baths. Further, if the plating bath is large, a large amount of plating solution and each pretreatment solution are required, and the electroless plating method, which requires more expensive plating solution than the electroplating method, has a cost disadvantage. Furthermore, since washing is performed between each process, a large amount of contaminated water that requires waste liquid treatment is generated.
【0005】電解めっき法では、管の中央部では両端か
ら送られてくる電流(I=V/R)が管の電気抵抗によ
って低下するため、10mを超えるような長尺管になる
と、管端部に比べた中央部の電流の低下が顕著となり、
電流に依存するめっき厚みが管端部より中央部で著しく
小さくなる。従って、均一な厚みのめっき皮膜を形成す
るには、管の長さに限界がある。In the electroplating method, the electric current (I = V / R) sent from both ends at the center of the pipe is lowered by the electric resistance of the pipe. The decrease of the current in the central part is remarkable compared to the part,
The plating thickness, which depends on the current, is significantly smaller at the center than at the tube end. Therefore, there is a limit to the length of the tube in order to form a plating film having a uniform thickness.
【0006】しかし、無電解めっき法は、めっき液中の
還元剤による金属イオンから金属への析出という化学反
応によりめっき皮膜が生成するため、反応条件、特に温
度を鋼管内で均一に保持できれば、鋼管の長さに関係な
く、全長にわたって均一な厚みのめっき皮膜を形成でき
る。従って、鋼管の長さに制限がないので、無電解めっ
き法は長尺管のめっき法として適している。[0006] However, in the electroless plating method, a plating film is formed by a chemical reaction in which metal ions are deposited on a metal by a reducing agent in a plating solution. Therefore, if the reaction conditions, especially the temperature, can be kept uniform in the steel pipe, Regardless of the length of the steel pipe, a plating film of uniform thickness can be formed over the entire length. Therefore, since the length of the steel pipe is not limited, the electroless plating method is suitable as a plating method for a long pipe.
【0007】長尺管の内面の無電解めっき法として、特
開昭54−121239号および同57−169097号各公報には、直
立させた長尺管の内部に無電解めっき液を圧送してめっ
きを行う方法が記載されている。長尺管を直立させるの
は、めっき均一性を確保するためである。しかし、長さ
が10mを超えるような長尺管になると、重量も 100〜10
00 kg に達し、直立させてめっきを行うことは困難とな
る。即ち、このような超長尺・大重量の金属管では、安
定な水平姿勢でめっきを行うことが、設備面およびハン
ドリング面で不可欠である。As an electroless plating method for the inner surface of a long tube, Japanese Patent Laid-Open Nos. 54-121239 and 57-169097 disclose that an electroless plating solution is pumped into an upright tube. A method of plating is described. The long tube is made to stand upright in order to ensure uniform plating. However, if the length of a long pipe exceeds 10 m, the weight will be 100 to 10
It reaches 00 kg, and it becomes difficult to plate upright. That is, in such an ultra-long and heavy metal tube, it is indispensable to perform plating in a stable horizontal posture in terms of equipment and handling.
【0008】[0008]
【発明が解決しようとする課題】本発明の目的は、安定
な水平姿勢で、長尺管の内面および外面を均一かつ良好
にめっきできる長尺管の無電解めっき方法及び装置を提
供することである。本発明の別の目的は、広い場所を必
要とせず、かつ高価な無電解めっき液を多量に使用せず
に長尺管の内面および外面を無電解めっき法により簡便
な操作でめっきすることができるめっき方法および装置
を提供することである。SUMMARY OF THE INVENTION It is an object of the present invention to provide an electroless plating method and apparatus for a long tube, which is capable of uniformly and satisfactorily plating the inner surface and the outer surface of the long tube in a stable horizontal posture. is there. Another object of the present invention is to plate the inner surface and the outer surface of a long tube by a simple operation by an electroless plating method without using a large space and without using a large amount of expensive electroless plating solution. It is to provide a plating method and apparatus capable of performing plating.
【0009】[0009]
【課題を解決するための手段】本発明により、下記(1)
〜(4) のめっき方法および装置が提供される。 (1) 長尺管の内面の無電解めっき方法であって、水平に
支持された長尺管の内部空間に、まずめっき前処理液を
供給して長尺管の内面のめっき前処理を行った後、次に
無電解めっき液を圧送して長尺管の内面めっきを行い、
少なくともめっき中は長尺管を周方向に回転させること
を特徴とする、長尺管の内面の無電解めっき方法。[Means for Solving the Problems] According to the present invention, the following (1)
The plating method and apparatus of (4) are provided. (1) An electroless plating method for the inner surface of a long tube, in which the plating pretreatment liquid is first supplied to the inner space of the horizontally supported long tube to perform the pretreatment of the inner surface of the long tube. After that, the electroless plating solution is sent under pressure to plate the inner surface of the long tube,
A method for electroless plating the inner surface of a long tube, which comprises rotating the long tube in the circumferential direction at least during plating.
【0010】(2) 長尺管の外面の無電解めっき方法であ
って、長尺管を水平に支持されたより大径の外套管の内
部に同心状に配置し、この長尺管と外套管との間に形成
された環状空間に、まずめっき前処理液を供給して長尺
管の外面のめっき前処理を行った後、次に無電解めっき
液を圧送して長尺管の外面めっきを行い、少なくともめ
っき中は長尺管を周方向に回転させることを特徴とす
る、長尺管の外面の無電解めっき方法。(2) A method for electroless plating the outer surface of a long tube, wherein the long tube is concentrically arranged inside a horizontally supported larger diameter outer tube, and the long tube and the outer tube are The plating pretreatment liquid is first supplied to the annular space formed between and to perform the plating pretreatment on the outer surface of the long tube, and then the electroless plating solution is pumped to plate the outer surface of the long tube. And rotating the long tube in the circumferential direction at least during plating, the electroless plating method for the outer surface of the long tube.
【0011】(3) 被めっき長尺管の両側の管端に装着さ
れた、長尺管の内部空間を密封する一対の封止蓋、長尺
管を水平に支持し、かつ周方向に回転させる支持回転機
構、および長尺管の内部空間に前記封止蓋を介して処理
液を供給するための給液機構、を備えた、長尺管の内面
の無電解めっき装置。(3) A pair of sealing lids attached to both ends of the long pipe to be plated for sealing the internal space of the long pipe, supporting the long pipe horizontally and rotating in the circumferential direction. An electroless plating apparatus for an inner surface of a long tube, comprising: a supporting / rotating mechanism for allowing the inner space of the long tube; and a liquid supply mechanism for supplying a processing liquid to the internal space of the long tube via the sealing lid.
【0012】(4) 被めっき長尺管が内部に収容される外
套管、長尺管を外套管内に同心状に支持すると共に、長
尺管と外套管との間に形成された環状空間を密封する、
外套管の両側の管端に装着された一対の封止蓋、外套管
を水平に支持し、かつ外套管を内部に収容された長尺管
と共に周方向に回転させる支持回転機構、および前記環
状空間に前記封止蓋を介して処理液を供給するための給
液機構、を備えた、長尺管の外面の無電解めっき装置。(4) An outer tube in which the long tube to be plated is housed, the long tube is concentrically supported in the outer tube, and an annular space formed between the long tube and the outer tube is formed. To seal,
A pair of sealing lids attached to both tube ends of the outer tube, a supporting and rotating mechanism for horizontally supporting the outer tube and rotating the outer tube in the circumferential direction together with the long tube housed therein, and the ring. An electroless plating apparatus for an outer surface of a long tube, comprising a liquid supply mechanism for supplying a processing liquid to a space through the sealing lid.
【0013】[0013]
【作用】本発明にかかる長尺管の内面の無電解めっき方
法およびめっき装置においては、水平に支持された長尺
管それ自体をめっき槽として利用し、この長尺管の内部
空間をめっき室とする。そして、このめっき室に無電解
めっき液を供給することにより、長尺管の内面をめっき
する。めっき室の容積をさらに小さくし、めっき液の使
用量を節約するため、長尺管の内部に棒または管を、好
ましくは長尺管と同心状に挿入してもよい。その場合に
は、この棒または管と長尺管との間の環状空間がめっき
室となる。In the electroless plating method and plating apparatus for the inner surface of a long pipe according to the present invention, the horizontally supported long pipe itself is used as a plating tank, and the internal space of the long pipe is used as a plating chamber. And Then, the electroless plating solution is supplied to the plating chamber to plate the inner surface of the long tube. In order to further reduce the volume of the plating chamber and save the amount of plating solution used, a rod or tube may be inserted inside the long tube, preferably concentrically with the long tube. In that case, the annular space between the rod or tube and the long tube becomes the plating chamber.
【0014】本発明にかかる長尺管の外面の無電解めっ
き方法およびめっき装置においては、長尺管を内部に同
心状に収容した外套管をめっき槽として利用し、この外
套管と長尺管との間の環状空間がめっき室となる。そし
て、この環状のめっき室にめっき液を供給することによ
り、長尺管の外面をめっきする。In the electroless plating method and the plating apparatus for the outer surface of the long tube according to the present invention, the outer tube in which the long tube is concentrically housed is used as a plating tank, and the outer tube and the long tube are used. The annular space between and becomes the plating chamber. Then, the plating solution is supplied to the annular plating chamber to plate the outer surface of the long tube.
【0015】内面めっきと外面めっきのいずれの場合
も、無電解めっき液は、めっき室内を圧送して1方向に
流通させる、即ち、めっき液貯槽から送られてきためっ
き液を、長尺管 (または外套管) の一端からめっき室内
に圧送し、他端から排出されためっき液を貯槽に戻すこ
とにより、めっき室内を循環させることが好ましい。そ
れにより、めっき時に発生する水素などのガスの多くが
管外に排出される。また、めっき液が長尺管内を流れる
ことにより、めっき室内の温度が均一に保持され、めっ
き析出のための化学反応がめっき室内で長手方向に均一
に起こる。そのため、全長にわたって均一な厚みのめっ
き皮膜が形成され、電解めっき法で見られるような中央
部での薄めっきが避けられる。In both the case of the inner surface plating and the case of the outer surface plating, the electroless plating solution is pressure-fed in the plating chamber to flow in one direction, that is, the plating solution sent from the plating solution storage tank is treated with a long pipe ( Alternatively, it is preferable to circulate in the plating chamber by pumping from one end of the outer tube) into the plating chamber and returning the plating solution discharged from the other end to the storage tank. As a result, most of the gas such as hydrogen generated during plating is discharged outside the tube. Further, since the plating solution flows in the long tube, the temperature in the plating chamber is kept uniform, and the chemical reaction for depositing the plating occurs uniformly in the longitudinal direction in the plating chamber. Therefore, a plating film having a uniform thickness is formed over the entire length, and thin plating at the central portion as seen in the electrolytic plating method can be avoided.
【0016】さらに、めっき時に長尺管を周方向に回転
させることにより、管内に残ったガスが上部に溜まって
不めっきや気泡傷が局部的に発生することが避けられ
る。この回転はめっきの均一性の向上にも寄与する。Further, by rotating the long tube in the circumferential direction during plating, it is possible to avoid the gas remaining in the tube from accumulating in the upper part and locally causing non-plating or bubble damage. This rotation also contributes to the improvement of plating uniformity.
【0017】以上のめっき液の循環圧送と長尺管の回転
により、水平姿勢で長尺管をめっきするにもかかわら
ず、不めっきや気泡傷が少なく、かつ厚みおよび組成
(合金めっきの場合) が周方向および長手方向の両方向
について均一な、品質良好なめっき皮膜が長尺管の内面
または外面に形成される。Although the long pipe is plated in a horizontal position by the circulating feeding of the plating solution and the rotation of the long pipe as described above, there is little non-plating or bubble scratches, and the thickness and composition are small.
(In the case of alloy plating), a plating film of good quality, which is uniform in both the circumferential direction and the longitudinal direction, is formed on the inner surface or the outer surface of the long tube.
【0018】本発明によれば、めっき室は前処理にも利
用されるので、別に前処理用の処理槽を設置する必要が
ない。無電解めっき用のめっき前処理としては、鋼管を
始めとする金属管では脱脂および酸洗が、またABSや
エポキシ樹脂とグラスファイバーからなるFRP管など
の樹脂管の場合には、貴金属化合物と還元剤を利用した
活性化処理が行われる。これらの各前処理用の処理液の
貯槽から、配管系に設けたバルブの切替えにより、上記
めっき室に処理液を順次供給して、各前処理 (脱脂、酸
洗等) を行う。各処理の間には、水を配管系からめっき
室内に供給して水洗を行い、液混じりを防止する。めっ
き前処理時にも、必要であれば、めっき液と同様に処理
液をめっき室に循環圧送してもよく、或いは単に滞留さ
せるだけでもよい。また、めっき時と同様に長尺管を周
方向に回転させることが好ましい。According to the present invention, since the plating chamber is also used for pretreatment, it is not necessary to separately install a treatment tank for pretreatment. As a pretreatment for electroless plating, degreasing and pickling are performed on metal pipes such as steel pipes, and in the case of resin pipes such as FRP pipes made of ABS or epoxy resin and glass fiber, reduction with precious metal compound Activation treatment using the agent is performed. The pretreatment (degreasing, pickling, etc.) is performed by sequentially supplying the treatment liquid from the storage tank for each pretreatment liquid to the plating chamber by switching the valve provided in the piping system. During each treatment, water is supplied from the piping system into the plating chamber to wash with water to prevent liquid mixing. Even during the pretreatment of plating, if necessary, the treatment liquid may be circulated under pressure to the plating chamber in the same manner as the plating liquid, or may simply be retained. Further, it is preferable to rotate the long tube in the circumferential direction as in the case of plating.
【0019】従って、スペースとしては、被めっき長尺
管を水平に設置でき、かつめっき液とめっき前処理液の
貯槽および付設配管と支持回転機構とが設置できる広さ
があればよく、狭い場所でも実施できる。また、めっき
室が狭いため、高価な無電解めっき液の使用量も少なく
てすむ。さらに、めっきの全工程 (例、脱脂→水洗→酸
洗→水洗→めっき→水洗) を、めっき室に供給する液種
の切替えだけで、被めっき長尺管を移動させずに実施で
きるので、移動が困難な大重量の長尺管にも適してい
る。Therefore, the space is sufficient if the long pipe to be plated can be installed horizontally and the storage tank for the plating solution and the pretreatment solution for plating and the attached piping and the supporting / rotating mechanism can be installed. But you can do it. Further, since the plating chamber is small, the amount of expensive electroless plating solution used can be small. Furthermore, all plating steps (e.g., degreasing → washing with water → pickling → washing with water → plating → washing with water) can be performed without changing the long pipe to be plated, simply by switching the type of liquid supplied to the plating chamber. It is also suitable for long heavy tubes that are difficult to move.
【0020】本発明の方法および装置により無電解めっ
き可能な長尺管の材質は特に制限されない。鋼管を始め
とする各種の金属または合金製の金属管のみならず、F
RP管などの樹脂管(樹脂種はエポキシ樹脂、ABS樹
脂が好ましい)にも適用できる。ただし、長尺管の材質
によって、めっき前処理に用いる処理液の種類が変わる
場合がある。例えば、樹脂管の場合には、前処理は脱脂
と酸洗ではなく、例えば、還元剤(例、Sn2+イオン)を
含有する溶液による感応化(センシタイゼーション)処
理と貴金属(例、Pd)イオンを含有する溶液による活性
化処理とが行われ、樹脂管のめっき面に、触媒活性のあ
る貴金属の核を予め形成しておく。The material of the long tube which can be electroless plated by the method and apparatus of the present invention is not particularly limited. Not only metal tubes made of various metals or alloys such as steel tubes, but also F
It can also be applied to resin pipes such as RP pipes (preferably epoxy resin and ABS resin are used as the resin type). However, depending on the material of the long tube, the type of treatment liquid used for the pretreatment for plating may change. For example, in the case of a resin tube, the pretreatment is not degreasing and pickling, but, for example, a sensitization treatment with a solution containing a reducing agent (eg Sn 2+ ion) and a precious metal (eg Pd ) An activation treatment with a solution containing ions is performed to form a noble metal nucleus having catalytic activity in advance on the plated surface of the resin tube.
【0021】また、めっき金属種についても制限はな
く、無電解めっき可能な任意の金属または合金めっきに
適用できる。めっき種としては、例えば、ニッケル合金
(例、Ni−B、Ni−Pなど) 、銅などが挙げられる。Further, there is no limitation on the kind of plating metal, and it can be applied to any metal or alloy plating that can be electrolessly plated. As the plating species, for example, nickel alloy
(Eg, Ni-B, Ni-P, etc.), copper, etc.
【0022】本発明は、直立させてめっきを行うことが
困難な、長さ10m、重さ100 kgを超えるような長尺金属
管の内面および外面めっきに特に適しているが、長尺管
の長さと重さに特に制限はない。The present invention is particularly suitable for the inner and outer surface plating of a long metal tube having a length of 10 m and a weight of more than 100 kg, which is difficult to plate upright, but There are no particular restrictions on length and weight.
【0023】以下、添付図面を参照して、長尺金属管に
対して本発明のめっき方法および装置を適用する場合に
ついて具体的に説明する。図1は、本発明の内面無電解
めっき装置を示すものである。被めっき長尺管10は、水
平姿勢で支持回転機構20に載置される。回転機構20は、
長尺管10の管軸方向に配列された複数の回転ローラ22を
備え、これにより長尺管10を水平に支持する。各位置の
回転ローラ22は、付設のモータMにより一方向の回転か
または正逆両方向に同期駆動され、長尺管10を周方向に
回転させる。The case of applying the plating method and apparatus of the present invention to a long metal tube will be specifically described below with reference to the accompanying drawings. FIG. 1 shows an inner surface electroless plating apparatus of the present invention. The long pipe 10 to be plated is placed on the support rotation mechanism 20 in a horizontal posture. The rotation mechanism 20
A plurality of rotating rollers 22 arranged in the tube axis direction of the long tube 10 are provided, and the long tube 10 is supported horizontally by this. The rotary roller 22 at each position is rotated in one direction by an attached motor M or is synchronously driven in both forward and reverse directions to rotate the long tube 10 in the circumferential direction.
【0024】長尺管10の両端には、ねじ込み式の封止蓋
(フランジ) 40が環状シールリング(Oリング) 42を介
して装着され、長尺管の内部空間Aが密封される。封止
蓋40には、長尺管の内部空間Aの一端から他端に向かっ
てめっき液等の処理液を流通させるために、通液孔44が
設けられている。At both ends of the long tube 10, screw-in type sealing lids are provided.
The (flange) 40 is mounted via an annular seal ring (O-ring) 42, and the internal space A of the long tube is sealed. A liquid passage hole 44 is provided in the sealing lid 40 to allow a processing liquid such as a plating liquid to flow from one end to the other end of the internal space A of the long tube.
【0025】封止蓋40の材質としては、無電解めっきを
受けにくく (表面が不活性) で耐食性に優れたものが好
ましい。例えば、合成樹脂、表面に不動態酸化皮膜を形
成し易いステンレス鋼、或いは熱処理により表面に酸化
皮膜を形成した金属材料などが使用できるが、合成樹脂
が特に好ましい。The material of the sealing lid 40 is preferably one that is less susceptible to electroless plating (the surface is inactive) and has excellent corrosion resistance. For example, a synthetic resin, stainless steel that easily forms a passive oxide film on the surface, or a metal material having an oxide film formed on the surface by heat treatment can be used, but a synthetic resin is particularly preferable.
【0026】両側の封止蓋40の各通液孔44をフレキシブ
ル・ホースにより給液機構60に接続する。給液機構60
は、脱脂液62、酸洗液64、無電解めっき液66の各貯槽を
備え、ポンプPとバルブV1 〜V8 の切替えにより、長
尺管10の内部空間に脱脂液、酸洗液、めっき液、および
洗浄水をそれぞれ独立して圧送することができる。脱脂
液62と無電解めっき液は、貯槽に設けたスチーム加熱装
置68により、所定温度に保持されている。Each liquid passage hole 44 of the sealing lid 40 on both sides is connected to the liquid supply mechanism 60 by a flexible hose. Liquid supply mechanism 60
Includes a degreasing solution 62, a pickling solution 64, and an electroless plating solution 66, and by switching between the pump P and the valves V 1 to V 8 , the degreasing solution, the pickling solution, The plating solution and the cleaning water can be independently pumped. The degreasing liquid 62 and the electroless plating liquid are kept at a predetermined temperature by the steam heating device 68 provided in the storage tank.
【0027】図1に示した装置を用いて本発明の内面無
電解めっきを行うには、まず脱脂液62を長尺管10の内部
空間Aに一端から他端に1方向に循環圧送し、長尺管の
内面を脱脂する。脱脂が終了して、脱脂液が完全に長尺
管から排出された後、洗浄水を空間Aに圧送して、長尺
管の内部を洗浄する。次いで、同様にして酸洗液64を循
環圧送して長尺管の内面の酸洗を行った後、水洗する。
これらの各処理中、支持回転機構20のモータを作動させ
て、長尺管を一方向回転か正逆両方向に繰り返し回転さ
せる。また、各液および洗浄水の圧送の間には休止期間
を挟む。To carry out the electroless plating of the inner surface of the present invention using the apparatus shown in FIG. 1, first, the degreasing liquid 62 is circulated under pressure in one direction from one end to the other end in the internal space A of the long pipe 10, Degrease the inner surface of the long tube. After the degreasing is completed and the degreasing liquid is completely discharged from the long tube, cleaning water is pressure-fed to the space A to wash the inside of the long tube. Then, similarly, the pickling solution 64 is circulated and pressure-fed to pickle the inner surface of the long tube and then to wash with water.
During each of these processes, the motor of the support rotation mechanism 20 is operated to rotate the long tube in one direction or repeatedly in both forward and reverse directions. In addition, a pause period is inserted between the pumping of each liquid and the washing water.
【0028】その後、長尺管を支持回転機構20により回
転させながら、無電解めっき液66を長尺管10の内部空間
Aに1方向に循環圧送して、長尺管の内面に所定の厚さ
のめっき皮膜を形成する。めっき終了後、長尺管10の内
部空間に洗浄水を圧送して、水洗を行うと、一連のめっ
き作業が完了する。なお、この時のめっき装置の運転プ
ログラムを表1に示す。After that, while rotating the long tube by the supporting and rotating mechanism 20, the electroless plating solution 66 is circulated under pressure in one direction into the internal space A of the long tube 10 so that the inner surface of the long tube has a predetermined thickness. To form a plating film. After the plating is completed, washing water is pumped into the internal space of the long tube 10 to wash it, and a series of plating operations are completed. Table 1 shows the operation program of the plating apparatus at this time.
【0029】[0029]
【表1】 [Table 1]
【0030】図2に、本発明の外面無電解めっき装置の
部分図を示す。この外面めっき装置が図1に示した内面
めっき装置と異なるのは、長尺管10を外套管70の内部に
挿入し、外側の外套管70を支持回転機構20に水平に載置
した点である。長尺管10の外面を全長にわたってめっき
するため、外套管70を長尺管より若干長くすることが好
ましい。FIG. 2 shows a partial view of the external electroless plating apparatus of the present invention. This outer plating apparatus is different from the inner plating apparatus shown in FIG. 1 in that the long tube 10 is inserted into the outer tube 70 and the outer outer tube 70 is horizontally placed on the support rotation mechanism 20. is there. Since the outer surface of the long tube 10 is plated over the entire length, the outer tube 70 is preferably made slightly longer than the long tube.
【0031】外套管70の内部に挿入された長尺管10は、
外套管70の両端に装着されたねじ込み式の封止蓋40によ
り、外套管70と同心状に水平姿勢で支持される。封止蓋
40と外套管70および長尺管10の端面との間に環状シール
リング42を介在させ、外套管70と長尺管10との間に形成
された環状空間Bを密封する。封止蓋40は、この環状空
間Bに処理液を流通させるための通液孔44を備えてい
る。封止蓋40と外套管70の材質は、図1の封止蓋に関し
て説明したものと同様でよい。The long tube 10 inserted into the outer tube 70 is
It is supported in a horizontal posture concentrically with the outer tube 70 by screw-in type sealing lids 40 attached to both ends of the outer tube 70. Sealing lid
An annular seal ring 42 is interposed between 40 and the outer tube 70 and the end surface of the long tube 10 to seal the annular space B formed between the outer tube 70 and the long tube 10. The sealing lid 40 has a liquid passage hole 44 for allowing the processing liquid to flow in the annular space B. The materials of the sealing lid 40 and the outer tube 70 may be the same as those described for the sealing lid of FIG.
【0032】図2に示した装置を用いた本発明の外面無
電解めっきは、本質的に上記の内面無電解めっきと同様
にして実施する。即ち、各処理液を、長尺管10の内部空
間ではなく、長尺管10と外套管70の間の環状空間Bに圧
送し、外套管70をその内部に同心状に収容した長尺管10
と一緒に回転させる点を除いて、操作は同じである。こ
れにより、従来は困難であった長尺管の外面無電解めっ
きを、狭い場所で容易に実施することが可能となる。The outer electroless plating of the present invention using the apparatus shown in FIG. 2 is carried out essentially in the same manner as the inner electroless plating described above. That is, each processing solution is pressure-fed to the annular space B between the long tube 10 and the outer tube 70, not the inner space of the long tube 10, and the outer tube 70 is concentrically housed therein. Ten
The operation is the same, except that it is rotated with. As a result, it becomes possible to easily perform the electroless plating on the outer surface of the long tube, which has been difficult in the past, in a narrow place.
【0033】上記の内面および外面のいずれの無電解め
っきにおいても、めっき液の1方向循環圧送と長尺管の
回転により、発生ガスによる不めっきや気泡疵の発生、
管周方向の不均一めっきが防止される。また、液種の切
替えや長尺管10の回転操作は、外部のプログラムコント
ローラにより自動制御することができる。なお、ロータ
リージョイント等の使用によりホースの捩じれが起こら
ない場合には、回転方向は、正逆両方向ではなく、1方
向に回転させることができる。In both electroless plating on the inner surface and the outer surface described above, non-plating due to generated gas and generation of bubble defects are caused by unidirectional circulating pressure feeding of the plating solution and rotation of the long tube.
Non-uniform plating in the pipe circumferential direction is prevented. Further, the switching of the liquid type and the rotating operation of the long tube 10 can be automatically controlled by an external program controller. When the hose is not twisted due to the use of a rotary joint or the like, the hose can be rotated in one direction instead of both the forward and reverse directions.
【0034】めっき液の圧送量は、毎分 0.1V (Vはめ
っき室、即ち、空間AまたはBの容積) 以上が望まし
い。この圧送量が小さいと、十分なガス排出効果が得ら
れず、また長尺管の温度が保持できない場合がある。圧
送量が過大になると、ポンプの負荷が増し、大型ポンプ
が必要となるので、通常は3V以下で十分である。長尺
管の回転速度は1rpm 以上が望ましい。回転速度が高す
ぎると回転が不安定になるので、10 rpm以下、通常は5
rpm 以下で十分である。The amount of the plating solution pumped is preferably 0.1 V / min (V is the volume of the plating chamber, that is, the space A or B) or more. If this amount of pumping is small, a sufficient gas discharging effect may not be obtained, and the temperature of the long tube may not be maintained. If the pumping amount is too large, the load on the pump increases and a large pump is required, so 3 V or less is usually sufficient. The rotation speed of the long tube is preferably 1 rpm or more. If the rotation speed is too high, the rotation will be unstable, so 10 rpm or less, usually 5
Below rpm is sufficient.
【0035】[0035]
(実施例1)図1に示した本発明にかかる内面めっき装置
を用いて下記条件で長尺鋼管の内面に無電解ニッケルめ
っきを施した。なお、通液孔へのホースの接続にはロー
タリージョイントを用い、前処理中とめっき中の鋼管の
回転は1方向に行った。(Example 1) Using the inner surface plating apparatus according to the present invention shown in FIG. 1, electroless nickel plating was applied to the inner surface of a long steel pipe under the following conditions. A rotary joint was used to connect the hose to the liquid passage, and the steel pipe was rotated in one direction during pretreatment and plating.
【0036】めっき用鋼管 寸法:外径168 mm、内径152 mm、長さ12.0m(内部空間
の容積=218 L) 材質:炭素鋼封止蓋 材質:ポリ塩化ビニル樹脂脱脂条件 脱脂液:3%オルト硅酸ソーダ水溶液 条件: 温度60〜70℃、時間5分間酸洗条件 酸洗液:10%塩酸 (常温、2分間)めっき条件 めっき液:市販無電解ニッケルめっき液(上村工業製、
ニムデンスーパー) 温度: 90±2℃ 時間: 30分圧送量 各処理液: 50 L/分 (0.23V/分) めっき液:400 L/分 (1.83V/分) 水洗水 : 80 L/分 (0.37V/分)鋼管回転速度 :2rpm (1方向回転) 長さ12.0mの長尺鋼管の内面の全長にニッケルめっき層
が形成された。めっき層の厚みは、長手方向および周方
向で均一であり、管端部と中央部の全周において、いず
れも18±0.5 μmであった。めっき外観を肉眼により検
査したところ、不めっきや気泡疵は認められなかった。 Steel pipe for plating Dimensions: outer diameter 168 mm, inner diameter 152 mm, length 12.0 m (internal space volume = 218 L) Material: carbon steel sealing lid Material: polyvinyl chloride resin Degreasing condition Degreasing liquid: 3% Aqueous sodium orthosilicate solution Conditions: Temperature 60-70 ° C, time 5 minutes Pickling conditions Pickling solution: 10% hydrochloric acid (room temperature, 2 minutes) Plating conditions Plating solution: Commercial electroless nickel plating solution (Kamimura Kogyo,
Nimden Super) Temperature: 90 ± 2 ℃ Time: 30 minutes Pumping amount Each treatment liquid: 50 L / min (0.23 V / min) Plating liquid: 400 L / min (1.83 V / min) Rinse water: 80 L / min (0.37 V / min) Steel pipe rotation speed : 2 rpm (one direction rotation) A nickel plating layer was formed on the entire length of the inner surface of a long steel pipe having a length of 12.0 m. The thickness of the plating layer was uniform in the longitudinal direction and the circumferential direction, and was 18 ± 0.5 μm in the entire circumference of the tube end portion and the central portion. When the plating appearance was visually inspected, no plating or bubble defects were found.
【0037】(実施例2)図2に示した本発明にかかる外
面めっき装置を用いて、下記条件で長尺鋼管の外面に無
電解めっき銅めっきを施した。なお、通液孔へのホース
の接続にはロータリージョイントを用い、前処理中とめ
っき中の鋼管と外套管の回転は1方向に行った。(Example 2) Using the external plating apparatus according to the present invention shown in FIG. 2, electroless plating copper plating was applied to the external surface of a long steel pipe under the following conditions. A rotary joint was used to connect the hose to the liquid passage, and the steel pipe and the outer pipe were rotated in one direction during pretreatment and plating.
【0038】めっき用鋼管 寸法:外径168 mm、内径152 mm、長さ4.0 m 材質:炭素鋼外套管 寸法:外径 267mm、内径 240mm、長さ4.01m 材質:ポリ塩化ビニル樹脂(鋼管との間の環状空間の容
積=92 L)封止蓋 の材質:実施例1と同じ脱脂/酸洗条件 :実施例1と同じめっき条件 めっき液:市販無電解銅めっき液(上村工業製、スルカ
ップELC-SR) 温度: 55±1.5 ℃ 時間: 25分圧送量 各処理液: 30 L/分 (0.32V/分) めっき液:200 L/分 (2.18V/分) 水洗水: 80 L/分 (0.87V/分)鋼管/外套管回転速度 :実施例1と同じ 長さよ4.0 mの長尺鋼管の外面の全長に銅めっき層が形
成された。めっき層の厚みは、長手方向および周方向で
均一であり、管端部と中央部の全周において、いずれも
1±0.2 μmであった。めっき外観を肉眼により検査し
たところ、不めっきや気泡疵は認められなかった。 Steel pipe for plating Dimensions: outer diameter 168 mm, inner diameter 152 mm, length 4.0 m Material: carbon steel jacket tube dimensions: outer diameter 267 mm, inner diameter 240 mm, length 4.01 m Material: polyvinyl chloride resin (with steel pipe) Volume of the annular space between them = 92 L) Material of sealing lid : Degreasing / pickling conditions same as in Example 1: Plating conditions same as in Example 1 Plating solution: Commercial electroless copper plating solution (Uemura Kogyo, Sulcup ELC) -SR) Temperature: 55 ± 1.5 ° C Time: 25 minutes Pressure feed Each processing solution: 30 L / min (0.32 V / min) Plating solution: 200 L / min (2.18 V / min) Rinse water: 80 L / min ( 0.87 V / min) Steel pipe / jacket rotation speed : A copper plating layer was formed on the entire length of the outer surface of a long steel pipe having the same length as in Example 1 and having a length of 4.0 m. The thickness of the plating layer was uniform in the longitudinal direction and the circumferential direction, and was 1 ± 0.2 μm in the entire circumference of the tube end portion and the central portion. When the plating appearance was visually inspected, no plating or bubble defects were found.
【0039】(比較例1)前処理中とめっき中の長尺鋼管
の回転を停止した以外は実施例1と同様にして、長さ1
2.0mの長尺鋼管の内面に無電解めっきニッケルめっき
を施した。その結果、めっき厚さは長さ12.0mの鋼管の
全長にわたってほぼ均一であったが、鋼管の天井部分に
線状の不めっき部が発生した。Comparative Example 1 A length of 1 mm was obtained in the same manner as in Example 1 except that the rotation of the long steel pipe during the pretreatment and during plating was stopped.
Electroless plating nickel plating was applied to the inner surface of a 2.0 m long steel pipe. As a result, the plating thickness was almost uniform over the entire length of the steel pipe having a length of 12.0 m, but a linear unplated portion was generated in the ceiling portion of the steel pipe.
【0040】(比較例2)図1と同様な装置を用いて、長
尺鋼管の内面に電解めっき法によりニッケルめっきを施
した。但し、電解めっきに必要な通電を行うため、図1
の装置において、長尺鋼管10の内部に、長尺管より細く
長い管状電極を同心状に挿入し、鋼管と内部管状電極と
の間の環状空間をめっき室として用いた。脱脂工程およ
びめっき工程においては、内部の管状電極が陽極、長尺
鋼管が陰極となるように外部電源から通電を行った。各
処理の条件を次に示す。Comparative Example 2 Using the same apparatus as that shown in FIG. 1, the inner surface of the long steel pipe was nickel-plated by electrolytic plating. However, in order to apply the current required for electrolytic plating,
In the above apparatus, a tubular electrode thinner and longer than the long tube was concentrically inserted inside the long steel tube 10, and an annular space between the steel tube and the inner tubular electrode was used as a plating chamber. In the degreasing step and the plating step, electricity was supplied from an external power source so that the inner tubular electrode served as the anode and the long steel tube served as the cathode. The conditions of each process are shown below.
【0041】めっき用鋼管 寸法:外径168 mm、内径152 mm、長さ7.5 m 材質:炭素鋼内部管状電極 寸法:外径70 mm 、内径46 mm 、長さ8.0 m 材質:SUS 304 ステンレス鋼(鋼管と電極間の環状空間
の容積=107 L)封止蓋 の材質:実施例1と同じ脱脂条件 脱脂液:3%オルト硅酸ソーダ水溶液 条件:温度60〜70℃、電流密度4A/dm2、時間2分酸洗条件 酸洗液:10%塩酸 (常温、1分間)めっき条件 めっき液:ワット浴(pH 3.5) 硫酸ニッケル 250 g/l 塩化ニッケル 70 g/l ホウ酸 40 g/l 温度: 40〜50℃ 電流密度:5A/dm2 時間: 25分圧送量 各処理液: 50 L/分 (0.47V/分) めっき液:107 L/分 (1.0 V/分) 水洗水: 80 L/分 (0.75V/分)鋼管回転速度 :4rpm(めっき中と脱脂中、正逆反復回
転) 長さ7.5 mの長尺鋼管の内面の全長にニッケルめっき層
が形成された。しかし、めっき層の厚みは最大26μm
(管端部) 、最小18μm (中央部) であり、長手方向の
変動幅が8μmに達した。この長手方向のめっき厚みの
変動幅は、長尺鋼管の長さが3.5 mと短くなると、2μ
mに減少した。従って、長尺鋼管の長さが実施例1のよ
うに12.0mと長くなると、めっき厚みの長手方向の変動
幅は8μmよりもさらに著しく大きくなる。これに対し
て、実施例1の無電解めっき法では、長さ12.0mの長尺
鋼管におけるめっき厚みの長手方向の変動幅が1μm
と、電解めっき法に比べて極めて小さくてすんだ。 Steel pipe for plating Dimensions: outer diameter 168 mm, inner diameter 152 mm, length 7.5 m Material: carbon steel inner tubular electrode Dimensions: outer diameter 70 mm, inner diameter 46 mm, length 8.0 m Material: SUS 304 stainless steel ( Volume of annular space between steel pipe and electrode = 107 L) Material of sealing lid : same degreasing condition as in Example 1 degreasing liquid: 3% sodium orthosilicate aqueous solution condition: temperature 60 to 70 ° C., current density 4 A / dm 2 , Time 2 minutes Pickling condition Pickling solution: 10% hydrochloric acid (room temperature, 1 minute) Plating condition Plating solution: Watt bath (pH 3.5) Nickel sulfate 250 g / l Nickel chloride 70 g / l Boric acid 40 g / l Temperature : 40 to 50 ° C Current density: 5 A / dm 2 hours: 25 minutes Pumping amount Each processing solution: 50 L / min (0.47 V / min) Plating solution: 107 L / min (1.0 V / min) Rinse water: 80 L / Min (0.75V / min) Steel pipe rotation speed : 4 rpm (during plating and degreasing, reciprocal reciprocating rotation) A nickel plating layer was formed on the entire inner surface of a 7.5 m long steel pipe. However, the maximum thickness of the plating layer is 26 μm
(Tube end), minimum 18 μm (center), and fluctuation width in the longitudinal direction reached 8 μm. The fluctuation range of the plating thickness in the longitudinal direction is 2μ when the length of the long steel pipe becomes as short as 3.5 m.
It decreased to m. Therefore, when the length of the long steel pipe becomes as long as 12.0 m as in Example 1, the variation range of the plating thickness in the longitudinal direction becomes much larger than 8 μm. On the other hand, in the electroless plating method of Example 1, in the long steel pipe having a length of 12.0 m, the fluctuation range of the plating thickness in the longitudinal direction is 1 μm
Therefore, it is much smaller than the electrolytic plating method.
【0042】なお、めっき中に長尺鋼管を回転させたた
め、周方向のめっき厚みの変動幅は、管端部で26±0.6
μm、中央部で18±0.5 μmと小さかった。Since the long steel pipe was rotated during the plating, the fluctuation range of the plating thickness in the circumferential direction was 26 ± 0.6 at the pipe end.
μm and 18 ± 0.5 μm in the central part.
【0043】[0043]
【発明の効果】本発明の効果としては、次の点を挙げる
ことができる。 長尺管の内面めっきと外面めっきのどちらも実施でき
る。 めっき液を圧送して循環させることにより、10mを超
えるような長尺管をめっきする場合でも、管の長手方向
のめっき厚みの変動が著しく少ない。電解法では、めっ
き液の圧送を行っても、中央部の薄めっきを避けること
ができない。また、めっき中に長尺管を回転させること
により、めっき厚さは長尺管の周方向でも均一となる。
従って、長手方向と周方向の両方向とも均一な厚みを持
っためっき皮膜が形成される。The effects of the present invention are as follows. Both inner surface plating and outer surface plating of long tubes can be performed. By pumping and circulating the plating solution, even when plating a long pipe of more than 10 m, the variation of the plating thickness in the longitudinal direction of the pipe is extremely small. In the electrolysis method, even if the plating solution is pumped, thin plating in the central part cannot be avoided. Further, by rotating the long tube during plating, the plating thickness becomes uniform in the circumferential direction of the long tube.
Therefore, a plating film having a uniform thickness is formed in both the longitudinal direction and the circumferential direction.
【0044】めっき液の圧送と長尺管の回転により、
気泡やガスの管外への排出が促進され、またその局部的
な滞留が阻止される結果、不めっきや気泡疵の少ないめ
っき皮膜が形成される。By pumping the plating solution and rotating the long tube,
The discharge of bubbles and gas to the outside of the tube is promoted, and the local retention thereof is prevented, so that a plating film with less plating and less bubble defects is formed.
【0045】重い長尺管を移動させることなく、水平
に配置した状態で、めっき前処理から無電解めっきまで
を、外部のポンプと各貯槽に設けられたバルブを操作す
ることにより、ほぼ自動的に実施できる。With the heavy long pipes arranged horizontally without moving, the pre-plating process to the electroless plating can be performed almost automatically by operating the external pump and the valves provided in each storage tank. Can be carried out.
【0046】被めっき長尺管の内部 (内面めっきの場
合) または長尺管を収容した外套管と長尺管との間の環
状空間 (外面めっきの場合) をめっき室として利用する
ので、めっき室の容積が比較的小さく、高価な無電解め
っき液を含む各処理液の使用量が少なくてすみ、また汚
染された洗浄水の排出量も少なくなる。 脱脂や酸洗をめっきと同じ処理装置で行うため、比較
的狭いスペースで実施できる。Since the inside of the long tube to be plated (in the case of inner surface plating) or the annular space between the outer tube and the long tube containing the long tube (in the case of outer surface plating) is used as a plating chamber, The volume of the chamber is relatively small, the amount of each processing solution including an expensive electroless plating solution used is small, and the amount of contaminated cleaning water discharged is also small. Since degreasing and pickling are performed in the same processing equipment as plating, it can be performed in a relatively narrow space.
【図1】本発明にかかる長尺管の内面無電解めっき装置
を示す説明図である。FIG. 1 is an explanatory view showing an inner surface electroless plating apparatus for a long tube according to the present invention.
【図2】本発明にかかる長尺管の外面無電解めっき装置
の部分を示す説明図である。FIG. 2 is an explanatory view showing a portion of an outer surface electroless plating apparatus for a long tube according to the present invention.
10:長尺管、20:支持回転機構、22:回転ローラ22、4
0:封止蓋、42:環状シールリング、44:通液孔44、6
0:給液機構、62:脱脂液、64:酸洗液、66:無電解め
っき液、68:スチーム加熱装置、70:外套管、A:長尺
管内部空間、B:環状空間、M:モータ、P:ポンプ、
V1 〜V8 :バルブ10: Long tube, 20: Support rotation mechanism, 22: Rotating rollers 22, 4
0: Sealing lid, 42: Annular seal ring, 44: Liquid passage holes 44, 6
0: Liquid supply mechanism, 62: Degreasing solution, 64: Pickling solution, 66: Electroless plating solution, 68: Steam heating device, 70: Outer tube, A: Long tube inner space, B: Annular space, M: Motor, P: Pump,
V 1 ~V 8: valve
───────────────────────────────────────────────────── フロントページの続き (72)発明者 佐藤 淳 尼崎市東向島西之町1番地 住友金属工業 株式会社関西製造所特殊管事業所内 ─────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Atsushi Sato No. 1 Nishinomachi, Higashimukaijima, Amagasaki City Sumitomo Metal Industries, Ltd. Kansai Works Special Pipe Works
Claims (4)
て、水平に支持された長尺管の内部空間に、まずめっき
前処理液を供給して長尺管の内面のめっき前処理を行っ
た後、次に無電解めっき液を圧送して長尺管の内面めっ
きを行い、少なくともめっき中は長尺管を周方向に回転
させることを特徴とする、長尺管の内面の無電解めっき
方法。1. A method for electroless plating the inner surface of a long tube, wherein a plating pretreatment liquid is first supplied to the inner space of the horizontally supported long tube to perform the pretreatment of the inner surface of the long tube. After that, the electroless plating solution is pressure-fed to perform plating on the inner surface of the long tube, and at least during plating, the long tube is rotated in the circumferential direction. Electrolytic plating method.
て、長尺管を水平に支持されたより大径の外套管の内部
に同心状に配置し、この長尺管と外套管との間に形成さ
れた環状空間に、まずめっき前処理液を供給して長尺管
の外面のめっき前処理を行った後、次に無電解めっき液
を圧送して長尺管の外面めっきを行い、少なくともめっ
き中は長尺管を周方向に回転させることを特徴とする、
長尺管の外面の無電解めっき方法。2. A method for electroless plating an outer surface of a long tube, wherein the long tube is concentrically arranged inside a horizontally supported outer tube having a larger diameter, and the long tube and the outer tube are provided. In the annular space formed between the two, the plating pretreatment liquid is first supplied to perform the plating pretreatment on the outer surface of the long tube, and then the electroless plating solution is pumped to perform the outer surface plating of the long tube. And rotating the long tube in the circumferential direction at least during plating,
Electroless plating method for outer surface of long tube.
た、長尺管の内部空間を密封する一対の封止蓋、 長尺管を水平に支持し、かつ周方向に回転させる支持回
転機構、および長尺管の内部空間に前記封止蓋を介して
処理液を供給するための給液機構、を備えた、長尺管の
内面の無電解めっき装置。3. A pair of sealing lids, which are attached to both ends of the long pipe to be plated, for sealing the internal space of the long pipe, horizontally supporting the long pipe and rotating in the circumferential direction. An electroless plating apparatus for an inner surface of a long tube, comprising: a supporting / rotating mechanism; and a liquid supply mechanism for supplying a processing liquid to the internal space of the long tube via the sealing lid.
管、 長尺管を外套管内に同心状に支持すると共に、長尺管と
外套管との間に形成された環状空間を密封する、外套管
の両側の管端に装着された一対の封止蓋、 外套管を水平に支持し、かつ外套管を内部に収容された
長尺管と共に周方向に回転させる支持回転機構、および
前記環状空間に前記封止蓋を介して処理液を供給するた
めの給液機構、を備えた、長尺管の外面の無電解めっき
装置。4. An outer tube in which a long tube to be plated is housed, a long tube is concentrically supported in the outer tube, and an annular space formed between the long tube and the outer tube is sealed. A pair of sealing lids attached to both ends of the outer tube, a supporting and rotating mechanism for horizontally supporting the outer tube and rotating the outer tube in the circumferential direction together with the long tube housed therein, and An electroless plating apparatus for an outer surface of a long pipe, comprising a liquid supply mechanism for supplying a processing liquid to the annular space via the sealing lid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12408195A JPH08319576A (en) | 1995-05-23 | 1995-05-23 | Electroless plating method and plating device for long-sized pipe |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12408195A JPH08319576A (en) | 1995-05-23 | 1995-05-23 | Electroless plating method and plating device for long-sized pipe |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH08319576A true JPH08319576A (en) | 1996-12-03 |
Family
ID=14876463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12408195A Pending JPH08319576A (en) | 1995-05-23 | 1995-05-23 | Electroless plating method and plating device for long-sized pipe |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH08319576A (en) |
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---|---|---|---|---|
CN1297687C (en) * | 2003-10-16 | 2007-01-31 | 李天忠 | Process for preventing coupling corrosion and thread gluing of tubings |
JP2007262548A (en) * | 2006-03-30 | 2007-10-11 | Yamagata Prefecture | Method of forming functional metal coated film onto metal product provided with temperature control function |
KR101252144B1 (en) * | 2010-07-06 | 2013-04-08 | 홍정표 | Electroless Plating Apparatus |
WO2014103595A1 (en) | 2012-12-28 | 2014-07-03 | 三菱重工業株式会社 | Method for manufacturing rotary machine, method for plating rotary machine, and rotary machine |
WO2014104166A1 (en) | 2012-12-28 | 2014-07-03 | 三菱重工業株式会社 | Manufacturing method for rotating machine, plating method for rotating machine, and rotating machine |
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-
1995
- 1995-05-23 JP JP12408195A patent/JPH08319576A/en active Pending
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1297687C (en) * | 2003-10-16 | 2007-01-31 | 李天忠 | Process for preventing coupling corrosion and thread gluing of tubings |
JP2007262548A (en) * | 2006-03-30 | 2007-10-11 | Yamagata Prefecture | Method of forming functional metal coated film onto metal product provided with temperature control function |
KR101252144B1 (en) * | 2010-07-06 | 2013-04-08 | 홍정표 | Electroless Plating Apparatus |
WO2014103595A1 (en) | 2012-12-28 | 2014-07-03 | 三菱重工業株式会社 | Method for manufacturing rotary machine, method for plating rotary machine, and rotary machine |
WO2014104166A1 (en) | 2012-12-28 | 2014-07-03 | 三菱重工業株式会社 | Manufacturing method for rotating machine, plating method for rotating machine, and rotating machine |
JP2014129575A (en) * | 2012-12-28 | 2014-07-10 | Mitsubishi Heavy Ind Ltd | Manufacturing method of rotary machine, plating method of rotary machine and rotary machine |
JP2014129574A (en) * | 2012-12-28 | 2014-07-10 | Mitsubishi Heavy Ind Ltd | Manufacturing method of rotary machine, plating method of rotary machine and rotary machine |
CN104508182A (en) * | 2012-12-28 | 2015-04-08 | 三菱重工业株式会社 | Manufacturing method for rotating machine, plating method for rotating machine, and rotating machine |
US9745863B2 (en) | 2012-12-28 | 2017-08-29 | Mitsubishi Heavy Industries Compressor Corporation | Method of manufacturing rotary machine, method of plating rotary machine, and rotary machine |
US10113237B2 (en) | 2012-12-28 | 2018-10-30 | Mitsubishi Heavy Industries, Ltd. | Manufacturing method of rotating machine, plating method of rotating machine, and rotating machine |
CN118668196A (en) * | 2024-08-23 | 2024-09-20 | 中国科学院金属研究所 | In-situ online chemical plating method for copper alloy heat transfer tube of heat exchanger |
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