JP2007201458A - Anisotropic cooling element and semiconductor element equipped with the same - Google Patents

Anisotropic cooling element and semiconductor element equipped with the same Download PDF

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JP2007201458A
JP2007201458A JP2006355278A JP2006355278A JP2007201458A JP 2007201458 A JP2007201458 A JP 2007201458A JP 2006355278 A JP2006355278 A JP 2006355278A JP 2006355278 A JP2006355278 A JP 2006355278A JP 2007201458 A JP2007201458 A JP 2007201458A
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anisotropic
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JP4833827B2 (en
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Hidemichi Fujiwara
英道 藤原
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Furukawa Electric Co Ltd
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<P>PROBLEM TO BE SOLVED: To provide an anisotropic cooling element which enables space-saving and improvement of thermal conversion efficiency, and to provide a semiconductor element that is equipped with it. <P>SOLUTION: The anisotropic cooling element 100 comprises an anisotropic thermally conductive member 110 attached to a heating element 10, the cooling/heat-radiating means 120<SB>1</SB>and 120<SB>2</SB>, which adsorb heat transmitted through the anisotropic thermally conductive member 110 to cool or radiate heat, and a contact layer which thermally forms the anisotropic thermally conductive member 110, in contact with each of the cooling/heat-radiating means 120<SB>1</SB>and 120<SB>2</SB>. The anisotropic thermally conductive member 110 is constituted by alternately laminating a plurality of thermally conductive layers, comprising a material having heat conductivity higher than that of the heating element 10 at least within a plane, and thermal resonator layers whose layer thickness is determined, according to the mean free path and the wavelength of the phonons that are to be the object. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明は、熱伝導率が面に垂直方向に比して面内方向で高い異方性熱伝導部材を用いた異方性冷却素子およびこれを備えた半導体素子に関する。   The present invention relates to an anisotropic cooling element using an anisotropic heat conductive member whose thermal conductivity is higher in an in-plane direction than in a direction perpendicular to the plane, and a semiconductor element including the same.

従来、半導体素子、レーザ素子、及びこれらのモジュール等(以下、発熱素子等という。)の発熱体の冷却は、Cu、Al等の熱伝導率の高い材料からなるヒートシンクを発熱素子等に取り付ける方法が広く用いられてきた。この方法では、発熱素子等にヒートシンクを接触させ、ヒートシンクを介して熱が放熱される。また、ヒートシンクは、発熱素子等内の熱分布の均一性を高くする機能も有し、発熱素子等内の局所的に突出して温度の高い部分を除去することができる。そして、高い放熱性能を必要とする場合は、ファンを用いて空冷する方法、特定の気体、液体等の冷却媒体を循環させて冷却する方法等がとられる。さらに、ヒートシンクを用いて放熱する方法、ファンを用いて空冷する方法、特定の気体・液体等の冷却媒体を循環させて冷却する方法を組み合わせる方法等がある。   Conventionally, cooling of heating elements of semiconductor elements, laser elements, and modules (hereinafter referred to as heating elements) is a method of attaching a heat sink made of a material having high thermal conductivity such as Cu or Al to the heating elements. Has been widely used. In this method, a heat sink is brought into contact with a heating element or the like, and heat is radiated through the heat sink. The heat sink also has a function of increasing the uniformity of the heat distribution in the heating element and the like, and can locally protrude in the heating element and remove a high temperature portion. And when high heat dissipation performance is required, the method of cooling with an air using a fan, the method of cooling by circulating cooling media, such as specific gas and liquid, etc. are taken. Further, there are a method of radiating heat using a heat sink, a method of air cooling using a fan, a method of combining a method of cooling by circulating a cooling medium such as a specific gas / liquid.

また、ペルチェ素子を発熱素子等に接触させ、省スペースと高い冷却性能とを両立させる冷却方法も用いられている。さらに、近年、携帯端末等では、内蔵する発熱素子等からの熱を熱電対等の熱電素子で電力に変換して電源にフィードバックし、電力の消費をできるだけ低減しようとする技術も検討されている。かかる用途での熱電素子の利用の場合でも、熱電変換効率の観点から高熱側と冷熱側での熱分布の均一化が必要となる。   A cooling method is also used in which a Peltier element is brought into contact with a heating element or the like to achieve both space saving and high cooling performance. Furthermore, in recent years, a technique for reducing power consumption as much as possible by converting heat from a built-in heating element into electric power by a thermoelectric element such as a thermocouple and feeding it back to a power source has been studied. Even in the use of thermoelectric elements for such applications, it is necessary to make the heat distribution uniform on the high temperature side and the cold side from the viewpoint of thermoelectric conversion efficiency.

携帯電話機等の携帯端末には、機能の拡大、送信電力の増大等の要求が一層高まってきている。かかる要求に応えるためには、内蔵する発熱素子等からの発熱量の増大の問題を解決しなければならない。極言すると、現状のままの放熱方法では、手で持つことさえ不可能になると言われている。そのため、内蔵する発熱素子等の効率的な冷却技術がきわめて重要となってきている。また、機能の拡大に伴う部品点数の増大により、発熱素子等に用いられる冷却手段は省スペース化が可能なものでなければならない。   For mobile terminals such as mobile phones, demands such as expansion of functions and increase of transmission power are increasing. In order to meet such a demand, the problem of an increase in the amount of heat generated from the built-in heating element or the like must be solved. In other words, it is said that the heat dissipation method as it is cannot be held by hand. For this reason, efficient cooling technology for built-in heating elements and the like has become extremely important. Further, due to the increase in the number of parts accompanying the expansion of functions, the cooling means used for the heat generating element or the like must be able to save space.

ここで、等方的な熱伝導部材を用いたのでは、熱が輸送の途中で拡散してしまい、効果的に輸送できず、冷却、熱電変換等を効率的に行うことができないという問題があった。そのため、熱伝導部材として、例えばα−Si3N4リッチ相とβ−Si3N4リッチ相とを交互に積層して多層化した多層熱伝導部材を形成し、異層界面におけるフォノン散乱を利用して、層に垂直な方向のフォノン散乱を生じやすくし、この方向の熱絶縁性(以下、層垂直方向熱絶縁性という。)を向上させる方法なども検討されている(例えば、特許文献1参照)。しかし、この熱絶縁材料は、固溶体のある層と固溶体のない層とを積層したものであり、積層厚が100μm程度とフォノンの自由行程距離よりも大幅に大きい厚さであり、さらに本発明のように膜厚方向には熱絶縁化しているが、膜面内では高熱伝性を有していない。   Here, when an isotropic heat conducting member is used, heat is diffused in the middle of transportation and cannot be transported effectively, and cooling, thermoelectric conversion, etc. cannot be performed efficiently. there were. Therefore, as a heat conduction member, for example, an α-Si3N4 rich phase and a β-Si3N4 rich phase are alternately laminated to form a multilayer heat conduction member, and the layer is formed by utilizing phonon scattering at the interface between different layers. A method of making phonon scattering in the vertical direction easy to occur and improving thermal insulation in this direction (hereinafter referred to as layer vertical direction thermal insulation) has been studied (for example, see Patent Document 1). However, this thermal insulation material is a laminate of a layer with a solid solution and a layer without a solid solution, and the laminate thickness is about 100 μm, which is significantly larger than the free path distance of phonons. Thus, although it is thermally insulated in the film thickness direction, it does not have high thermal conductivity in the film plane.

特開平8−276537号公報JP-A-8-276537

しかしながら、従来の多層熱伝導部材を用いた冷却素子および異方性熱電素子では、層に垂直方向の熱浸透率である層垂直方向熱浸透率を低く抑えて高い冷却効率および熱電変換効率を実現するのが困難であるという問題があった。これは、多層熱伝導部材を構成する各層の膜厚が100μm程度以上と、フォノンの平均自由行程よりも大幅に大きく、多層熱伝導部材が熱を面内に効率よく閉じ込めることができず、相当量の熱が熱輸送の際に拡散してしまうことによるものであった。   However, with conventional cooling elements and anisotropic thermoelectric elements using multilayer heat conducting members, high cooling and thermoelectric conversion efficiencies are achieved by keeping the layer vertical heat permeability that is perpendicular to the layers low. There was a problem that it was difficult to do. This is because the thickness of each layer constituting the multilayer heat conducting member is about 100 μm or more, which is significantly larger than the mean free path of phonons, and the multilayer heat conducting member cannot efficiently confine heat in the plane. This was due to the amount of heat diffusing during heat transport.

本発明は、このような問題を解決するためになされたもので、省スペースかつ冷却効率の向上が可能な異方性冷却素子およびこれを備えた半導体素子を実現することを目的とする。   The present invention has been made to solve such a problem, and an object thereof is to realize an anisotropic cooling element that can save space and improve cooling efficiency, and a semiconductor element including the same.

上記課題を解決するために、本発明の第1の態様に係る異方性冷却素子は、取り付けられる発熱体よりも熱伝導率の高い材料からなる熱伝導層と対象とするフォノンの平均自由行程および波長に応じて層厚が決定される熱共振体層とが交互に積層された異方性熱伝導部材と、前記発熱体から前記異方性熱伝導部材を介して伝達した熱を吸熱して冷却または放熱する1つ以上の冷却放熱手段と、を備えたことを特徴とする。   In order to solve the above-described problem, the anisotropic cooling element according to the first aspect of the present invention includes a heat conductive layer made of a material having a higher thermal conductivity than a heating element to be attached and a mean free path of a target phonon. And an anisotropic heat conducting member in which layer thicknesses are determined alternately depending on the wavelength, and heat transferred from the heating element through the anisotropic heat conducting member are absorbed. And one or more cooling / dissipating means for cooling or dissipating heat.

この態様によれば、熱伝導層と熱共振体層を交互に積層された異方性熱伝導部材により層に垂直方向の熱浸透率である層垂直方向熱浸透率が低く抑えられると共に、発熱体からの熱が異方性熱伝導部材を介して冷却放熱手段に伝達されるので、省スペースかつ冷却効率および熱電変換効率の向上が可能な異方性冷却素子を実現できる。なお、ここにいう「対象とするフォノン」は、共振を起こす周波数のフォノン、つまり、共振条件を満たす波長のフォノンという意味で用いている。   According to this aspect, the anisotropic heat conducting member in which the heat conducting layers and the thermal resonator layers are alternately stacked can suppress the layer vertical heat permeability, which is the heat permeability perpendicular to the layer, and generate heat. Since heat from the body is transmitted to the cooling and heat radiating means via the anisotropic heat conducting member, an anisotropic cooling element that can save space and improve cooling efficiency and thermoelectric conversion efficiency can be realized. Here, “target phonon” is used to mean a phonon having a frequency that causes resonance, that is, a phonon having a wavelength that satisfies the resonance condition.

本発明の他の態様に係る異方性冷却素子は、前記発熱体と前記異方性熱伝導部材との間に接触層が設けられていることを特徴とする。この態様によれば、熱接触抵抗が低減され、発熱体から異方性熱伝導部材への熱の伝達を効率化できる。   An anisotropic cooling element according to another aspect of the present invention is characterized in that a contact layer is provided between the heating element and the anisotropic heat conducting member. According to this aspect, the thermal contact resistance is reduced, and the heat transfer from the heating element to the anisotropic heat conducting member can be made efficient.

本発明の他の態様に係る異方性冷却素子は、前記異方熱性伝導部材と前記冷却放熱手段との間に接触層が設けられていることを特徴とする。この態様によれば、熱接触抵抗が低減され、異方性熱伝導部材から冷却放熱手段への熱の伝達を効率化でき、冷却効率が向上する。   An anisotropic cooling element according to another aspect of the present invention is characterized in that a contact layer is provided between the anisotropic heat conductive member and the cooling and heat dissipation means. According to this aspect, the thermal contact resistance is reduced, the heat transfer from the anisotropic heat conducting member to the cooling heat radiating means can be made efficient, and the cooling efficiency is improved.

本発明の他の態様に係る異方性冷却素子は、少なくとも1つ以上の異方性熱伝導部材が、前記発熱体の1つの面上の一部または全部に接触するように設けられ、各異方性熱伝導部材が対応する接触層を介して冷却放熱手段に接続されていることを特徴とする。   An anisotropic cooling element according to another aspect of the present invention is provided such that at least one or more anisotropic heat conducting members are in contact with part or all of one surface of the heating element, The anisotropic heat conducting member is connected to the cooling and radiating means through a corresponding contact layer.

本発明の他の態様に係る異方性冷却素子は、少なくとも1つ以上の異方性熱伝導部材が、前記発熱体の対向する1対の面の各面上の一部または全部に接触するように設けられ、各異方性熱伝導部材が対応する接触層を介して冷却放熱手段に接続されていることを特徴とする。   In an anisotropic cooling element according to another aspect of the present invention, at least one or more anisotropic heat conductive members are in contact with a part or all of each surface of a pair of opposing surfaces of the heating element. The anisotropic heat conducting members are connected to the cooling and radiating means via corresponding contact layers.

本発明の他の態様に係る異方性冷却素子は、積層された発熱体の各発熱体間に1つ以上の異方性熱伝導部材が発熱体に接触するように設けられ、前記各異方性熱伝導部材が対応する接触層を介して冷却放熱手段に接続されていることを特徴とする。   The anisotropic cooling element according to another aspect of the present invention is provided such that one or more anisotropic heat conducting members are in contact with the heating elements between the heating elements of the stacked heating elements. The isotropic heat conducting member is connected to the cooling and radiating means via a corresponding contact layer.

本発明の他の態様に係る異方性冷却素子は、前記異方性熱伝導部材が、端面または端面近傍の所定の領域にいずれか1つ以上の前記接触層を形成する接触領域を有することを特徴とする。   In the anisotropic cooling element according to another aspect of the present invention, the anisotropic heat conducting member has a contact region in which any one or more of the contact layers are formed in a predetermined region near the end surface or the end surface. It is characterized by.

本発明の他の態様に係る異方性冷却素子は、前記異方性熱伝導部材のいずれか1つ以上の前記熱伝導層が、前記異方性熱伝導部材のいずれか1つ以上の前記接触領域内の一部または全部で露出していることを特徴とする。   In the anisotropic cooling element according to another aspect of the present invention, any one or more of the anisotropic heat conductive members may include any one or more of the anisotropic heat conductive members. The contact area is partially or entirely exposed.

本発明の他の態様に係る異方性冷却素子は、冷却放熱手段の異方性熱伝導部材との接触領域の形状が、対応する異方性熱伝導部材の接触領域内の熱伝導層が露出した部分と密着する形状となっていることを特徴とする。   In the anisotropic cooling element according to another aspect of the present invention, the shape of the contact region with the anisotropic heat conductive member of the cooling heat radiating means has a heat conductive layer in the contact region of the corresponding anisotropic heat conductive member. It is characterized in that it is in close contact with the exposed part.

本発明の他の態様に係る異方性冷却素子は、冷却放熱手段の異方性熱伝導部材との接触領域に形成された接触層がナノ粒子からなる材料を主要材料として含むナノ粒子含有材料を用いて形成されることを特徴とする。この態様によれば、接触層を、ナノ粒子が異方性熱伝導部材と各冷却放熱手段との間の隙間を密に埋めることができ、もって熱接触抵抗を低く抑えることができる。   An anisotropic cooling element according to another aspect of the present invention is a nanoparticle-containing material in which a contact layer formed in a contact region with the anisotropic heat conducting member of the cooling heat radiating means includes a material composed of nanoparticles as a main material. It is formed using. According to this aspect, the contact layer can close the gap between the anisotropic heat conducting member and each cooling and radiating means densely with the nanoparticles, so that the thermal contact resistance can be kept low.

本発明の他の態様に係る異方性冷却素子は、前記接触層のナノ粒子が、接触層のナノ粒子が、銀、銅若しくは金のいずれか、又は酸化銀若しくは酸化銅のいずれかからなることを特徴とする。この態様によれば、ナノ粒子として、銀、銅若しくは金のいずれか、又は酸化銀若しくは酸化銅のいずれかからなるものを用いることは、熱接触抵抗を更に低く抑えることができる。   In the anisotropic cooling element according to another aspect of the present invention, the nanoparticles of the contact layer are made of either silver, copper, or gold, or silver oxide or copper oxide. It is characterized by that. According to this aspect, the use of silver, copper, or gold, or silver oxide or copper oxide as the nanoparticles can further reduce the thermal contact resistance.

本発明の他の態様に係る異方性冷却素子は、前記ナノ粒子含有材料がナノ粒子からなる材料以外に、バインダ樹脂および界面活性剤のうちの1つ以上を含むことを特徴とする。この態様によれば、ナノ粒子を異方性熱伝導部材または各冷却放熱手段に良好に固定できる。   An anisotropic cooling element according to another aspect of the present invention is characterized in that the nanoparticle-containing material includes one or more of a binder resin and a surfactant in addition to the material made of nanoparticles. According to this aspect, the nanoparticles can be satisfactorily fixed to the anisotropic heat conducting member or each cooling and radiating means.

本発明の他の態様に係る異方性冷却素子は、前記ナノ粒子が少なくとも酸化銀および酸化銅を含む酸化物のうちのいずれか1つ以上の物質からなる場合、さらに、炭化物、遷移金属酸化物、典型金属酸化物、又は、典型金属元素の合金の酸化物を還元用焼結助剤として含むことを特徴とする。この態様によれば、酸化物に対する還元反応が促進し、金属ナノ粒子が形成しやすくなる。   In the anisotropic cooling element according to another aspect of the present invention, when the nanoparticles are made of any one or more of oxides containing at least silver oxide and copper oxide, further, carbide, transition metal oxidation And an oxide of a typical metal oxide or an alloy of typical metal elements as a sintering aid for reduction. According to this aspect, the reduction reaction for the oxide is promoted, and the metal nanoparticles are easily formed.

本発明の他の態様に係る異方性冷却素子は、前記ナノ粒子含有材料がハンダ粒子からなる材料又はハンダ粒子を含む材料であることを特徴とする。この態様によれば、異方性熱伝導部材と各冷却放熱手段の接着性を向上させ、バインダ樹脂および界面活性剤等を要しない。   An anisotropic cooling element according to another aspect of the present invention is characterized in that the nanoparticle-containing material is a material made of solder particles or a material containing solder particles. According to this aspect, the adhesiveness between the anisotropic heat conducting member and each cooling and heat dissipating means is improved, and no binder resin and surfactant are required.

本発明の他の態様に係る異方性冷却素子は、前記ナノ粒子の平均の直径が1nm以上200nm以下であることを特徴とする。
本発明の他の態様に係る異方性冷却素子は、前記ナノ粒子含有材料を用いて形成される接触層の厚さが200nm以下であることを特徴とする。
An anisotropic cooling element according to another aspect of the present invention is characterized in that an average diameter of the nanoparticles is 1 nm or more and 200 nm or less.
An anisotropic cooling element according to another aspect of the present invention is characterized in that a contact layer formed using the nanoparticle-containing material has a thickness of 200 nm or less.

本発明の他の態様に係る異方性冷却素子は、前記ナノ粒子含有材料がレーザ光の照射又は高周波電磁波の印加によって焼成され、接触層を形成することを特徴とする。   An anisotropic cooling element according to another aspect of the present invention is characterized in that the nanoparticle-containing material is fired by laser light irradiation or high-frequency electromagnetic wave application to form a contact layer.

本発明の他の態様に係る異方性冷却素子は、いずれか1つ以上の前記冷却放熱手段が、それぞれヒートシンク又はペルチェ素子を用いて構成されることを特徴とする。この態様によれば、冷却放熱手段としてペルチェ素子を用いることで、高機能の実現に伴って増大した熱を効果的に吸熱できる。   An anisotropic cooling element according to another aspect of the present invention is characterized in that any one or more of the cooling and radiating means is configured using a heat sink or a Peltier element, respectively. According to this aspect, by using the Peltier element as the cooling and radiating means, it is possible to effectively absorb the heat increased with the realization of the high function.

本発明の他の態様に係る異方性冷却素子は、いずれか1つ以上の前記冷却放熱手段をゼーベック素子で置き換えたことを特徴とする。この態様によれば、冷却放熱手段としてゼーベック素子を用いることは、変換して得られた電気エネルギーを内蔵する電池に帰還させることによってエネルギー消費を低減できる。   An anisotropic cooling element according to another aspect of the present invention is characterized in that any one or more of the cooling and radiating means is replaced with a Seebeck element. According to this aspect, the use of the Seebeck element as the cooling / dissipating means can reduce the energy consumption by returning the converted electric energy to the built-in battery.

本発明の他の態様に係る異方性冷却素子は、ペルチェ素子が複数同一面内に放熱面または冷却面を揃えて配置された冷却手段と、前記冷却手段を前記放熱面と前記冷却面との両方から挟持する1対の受熱基板と、熱伝導率の高い材料からなる熱伝導層と対象とするフォノンの平均自由行程および波長に応じて層厚を調整する熱共振体層とが交互に積層された部材であって、前記冷却手段と前記受熱基板との間に配置される異方性熱伝導部材とを備えたことを特徴とする。   An anisotropic cooling element according to another aspect of the present invention includes a cooling unit in which a plurality of Peltier elements are arranged in the same plane with a heat radiating surface or a cooling surface aligned, and the cooling unit includes the heat radiating surface and the cooling surface. A pair of heat receiving substrates sandwiched from both, a heat conducting layer made of a material having high thermal conductivity, and a thermal resonator layer that adjusts the layer thickness according to the mean free path and wavelength of the target phonon are alternately arranged It is a laminated member, and comprises an anisotropic heat conducting member disposed between the cooling means and the heat receiving substrate.

本発明の他の態様に係る異方性冷却素子は、ペルチェ素子が複数同一面内に放熱面または冷却面を揃えて配置された冷却手段と、 前記冷却手段の前記放熱面と前記冷却面との間に設けられ、前記冷却手段を保持するホルダー基板と、 熱伝導率の高い材料からなる熱伝導層と対象とするフォノンの平均自由行程および波長に応じて層厚を調整する熱共振体層とが交互に積層された部材であって、前記ホルダー基板の対向する面上に配置される異方性熱伝導部材とを備えたことを特徴とする。   An anisotropic cooling element according to another aspect of the present invention includes a cooling unit in which a plurality of Peltier elements are arranged in the same plane with a heat radiating surface or a cooling surface, and the heat radiating surface and the cooling surface of the cooling unit. A holder substrate for holding the cooling means, a heat conductive layer made of a material having high thermal conductivity, and a thermal resonator layer that adjusts the layer thickness according to the mean free path and wavelength of the target phonon And an anisotropic heat conducting member disposed on the opposing surface of the holder substrate.

本発明の第2の態様に係る半導体素子は、上記態様のいずれか一つに記載の異方性冷却素子の異方性熱伝導部材と、前記発光体としての発光ダイオードチップと、基板とを備え、前記基板上に前記異方性熱伝導部材が形成されており、前記異方性熱伝導部材の表面上に前記発光ダイオードチップが実装されていることを特徴とする。   A semiconductor element according to a second aspect of the present invention includes an anisotropic heat conducting member of the anisotropic cooling element according to any one of the above aspects, a light emitting diode chip as the light emitter, and a substrate. The anisotropic heat conducting member is formed on the substrate, and the light emitting diode chip is mounted on the surface of the anisotropic heat conducting member.

この態様によれば、基板上に異方性熱伝導部材を形成し、この異方性熱伝導部材の表面上に発光ダイオードチップを実装することで半導体素子を作製できるので、図16に示す従来技術のような素子設計上、構造に制約がなくなる。これにより、構造が簡単で、汎用基板への高効率成膜が可能となり、製造コストを低減することができる。また、異方性熱伝導部材により発光ダイオードチップ全体の温度、特にそのピーク温度が下げられるので、発光ダイオードの長寿命化を図れる。   According to this aspect, the semiconductor element can be manufactured by forming the anisotropic heat conductive member on the substrate and mounting the light emitting diode chip on the surface of the anisotropic heat conductive member. There are no restrictions on the structure in terms of element design such as technology. Thereby, the structure is simple, high-efficiency film formation on a general-purpose substrate is possible, and the manufacturing cost can be reduced. Further, the temperature of the entire light emitting diode chip, particularly its peak temperature, is lowered by the anisotropic heat conducting member, so that the life of the light emitting diode can be extended.

本発明の他の態様に係る半導体素子は、前記異方性熱伝導部材の側面と前記基板の側面のうち、少なくとも前記異方性熱伝導部材の側面に前記冷却放熱手段が設けられていることを特徴とする。この態様によれば、異方性熱伝導部材により層に垂直方向の熱浸透率である層垂直方向熱浸透率が低く抑えられると共に、発光ダイオードチップからの熱が異方性熱伝導部材を介して冷却放熱手段に伝達され、放熱されるので、省スペースかつ冷却効率および熱電変換効率の向上が可能な半導体素子を実現できる。
本発明の第3の態様に係る半導体素子は、上記態様のいずれか一つに記載の異方性冷却素子と、前記発光体としての発光層とおよび電流狭窄層を有する半導体レーザ素子と、を備え、前記異方性冷却素子の異方性熱伝導部材が前記電流狭窄層の内部、上部および下部のいずれかに形成されていることを特徴とする。
In the semiconductor element according to another aspect of the present invention, the cooling / dissipating means is provided on at least a side surface of the anisotropic heat conductive member among a side surface of the anisotropic heat conductive member and a side surface of the substrate. It is characterized by. According to this aspect, the anisotropic heat conduction member can suppress the layer vertical heat permeability, which is the heat permeability in the direction perpendicular to the layer, and heat from the light-emitting diode chip can pass through the anisotropic heat conduction member. Since the heat is transmitted to the cooling heat radiating means and radiated, a semiconductor element that can save space and improve cooling efficiency and thermoelectric conversion efficiency can be realized.
A semiconductor device according to a third aspect of the present invention includes the anisotropic cooling element according to any one of the above aspects, a semiconductor laser element having a light emitting layer as the light emitter and a current confinement layer. And the anisotropic heat conductive member of the anisotropic cooling element is formed in any one of the inside, the upper part, and the lower part of the current confinement layer.

この態様によれば、電流狭窄層の内部、上部および下部のいずれかに形成された異方性熱伝導部材により半導体レーザ素子の発光層近傍の温度分布が平坦化されて、発光層近傍のピーク温度が下げられる。これにより、発光層近傍の低温化、特に発光層近傍のピーク温度の低温化を図ることができるので、半導体素子の長寿命化を図ることができる。   According to this aspect, the temperature distribution in the vicinity of the light emitting layer of the semiconductor laser element is flattened by the anisotropic heat conductive member formed inside, above or below the current confinement layer, and the peak in the vicinity of the light emitting layer is obtained. The temperature is lowered. Thereby, the temperature near the light emitting layer can be lowered, particularly the peak temperature near the light emitting layer can be lowered, so that the life of the semiconductor element can be extended.

本発明の他の態様に係る半導体素子は、前記半導体レーザ素子の側面に前記冷却放熱手段が設けられていることを特徴とする。この態様によれば、異方性熱伝導部材により層に垂直方向の熱浸透率である層垂直方向熱浸透率が低く抑えられると共に、半導体レーザ素子からの熱が異方性熱伝導部材を介して冷却放熱手段に伝達されるので、省スペースかつ冷却効率および熱電変換効率の向上が可能な半導体素子を実現できる。   A semiconductor device according to another aspect of the present invention is characterized in that the cooling heat dissipation means is provided on a side surface of the semiconductor laser device. According to this aspect, the anisotropic heat conducting member can suppress the layer vertical heat permeability, which is the heat permeability in the direction perpendicular to the layer, and heat from the semiconductor laser element can be transmitted through the anisotropic heat conducting member. Therefore, a semiconductor device that can save space and improve cooling efficiency and thermoelectric conversion efficiency can be realized.

本発明によれば、層に垂直方向の熱浸透率である層垂直方向熱浸透率を低く抑えるようにした積層構造の異方性熱伝導部材を用いて発熱体からの熱を冷却放熱手段に移送するようにしたため、省スペースかつ冷却効率および熱電変換効率の向上が可能な異方性冷却素子を実現できる。   According to the present invention, heat from a heating element is used as a cooling and heat dissipating means by using an anisotropic heat conduction member having a laminated structure in which the layer vertical heat permeability, which is the heat permeability in the direction perpendicular to the layer, is kept low. Since it is transported, an anisotropic cooling element capable of saving space and improving cooling efficiency and thermoelectric conversion efficiency can be realized.

以下、本発明の各実施形態について、図面を用いて詳細に説明する。
(第1実施態様)
図1は、本発明の第1実施態様に係る異方性冷却素子の断面構造を示す模式図である。図1において、異方性冷却素子100は、半導体素子、レーザ素子、及びこれらのモジュール等(以下、発熱素子等という。)の発熱体10に取り付けられる異方性熱伝導部材110と、異方性熱伝導部材110を介して伝達した熱を吸熱して冷却または放熱する1つ以上の冷却放熱手段120、120と、異方性熱伝導部材110と各冷却放熱手段120、120とを熱的に接触させる、冷却放熱手段120、120毎の接触層とを備えるように構成される。
Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
(First embodiment)
FIG. 1 is a schematic diagram showing a cross-sectional structure of an anisotropic cooling element according to the first embodiment of the present invention. In FIG. 1, an anisotropic cooling element 100 is anisotropically different from an anisotropic heat conducting member 110 attached to a heating element 10 of a semiconductor element, a laser element, and a module thereof (hereinafter referred to as a heating element). One or more cooling heat dissipation means 120 1 , 120 2 that absorbs the heat transmitted through the heat conductive member 110 and cools or dissipates it, the anisotropic heat conduction member 110, and each cooling heat dissipation means 120 1 , 120 2. And a contact layer for each of the cooling and radiating means 120 1 , 120 2 .

図2は、本発明の第1実施態様に係る異方性冷却素子100の異方性熱伝導部材の断面構造の一例を模式的に示す図である。図2において、異方性熱伝導部材110は、少なくとも面内で発熱体10よりも熱伝導率の高い材料からなる複数の熱伝導層111〜111nと、対象とするフォノンの平均自由行程および波長に応じて層厚が決定される熱共振体層112〜112(n+1)とが交互に積層されて構成される。ここで、熱伝導層111〜111nの層数、各熱伝導層111〜111nの膜厚は、輸送する熱量に応じて決定される。 FIG. 2 is a diagram schematically showing an example of a cross-sectional structure of the anisotropic heat conducting member of the anisotropic cooling element 100 according to the first embodiment of the present invention. In FIG. 2, the anisotropic heat conducting member 110 includes a plurality of heat conducting layers 111 1 to 111 n made of a material having a thermal conductivity higher than that of the heating element 10 at least in the plane, an average free path of the target phonons, and Thermal resonator layers 112 1 to 112 (n + 1) whose layer thickness is determined according to the wavelength are alternately stacked. Here, the heat conductive layer 111 1 number of layers of ~111N, the thickness of the thermally conductive layer 111 1 ~111N is determined according to the amount of heat transport.

各熱共振体層112〜112(n+1)は、フォノンの平均自由行程が長い材料によって構成され、層厚が対象とするフォノンの平均自由行程よりも短く、かつ、以下の条件を満たすように厚さになっている。
mλ/2.2<t<mλ/1.8 (mは整数)
ここで、mは自然数であり、λは対象とするフォノンの波長、つまり共振条件を満たすフォノンの波長である。
Each of the thermal resonator layers 112 1 to 112 (n + 1) is made of a material having a long phonon mean free path, the layer thickness is shorter than the target phonon mean free path, and satisfies the following conditions: It is thick.
mλ / 2.2 <t <mλ / 1.8 (m is an integer)
Here, m is a natural number, and λ is the target phonon wavelength, that is, the phonon wavelength satisfying the resonance condition.

熱伝導層111〜111は、例えば、Au、Ag、Cu等の熱伝導率の高い材料を用いて形成され、熱伝導層112〜112(n+1)は、Si等の平均自由行程を長くできる材料を用いて形成される。熱共振体層112〜112(n+1)の厚さは、Siを材料に用いる場合、例えば、数nm〜数十nmとし、動作温度でのフォノンの平均自由行程よりも短くする。 The heat conductive layers 111 1 to 111 n are formed using a material having high thermal conductivity such as Au, Ag, and Cu, for example, and the heat conductive layers 112 1 to 112 (n + 1) have an average free path such as Si. It is formed using a material that can be lengthened. The thickness of the thermal resonator layers 112 1 to 112 (n + 1) is, for example, several nanometers to several tens of nanometers when Si is used as a material, and is shorter than the mean free path of phonons at the operating temperature.

熱伝導層111〜111および熱共振体層112〜112(n+1)の成膜方法として、例えば、CVD法、MBE法、イオンクラスタビーム法等を用いことができる。これらの成膜方法を用いて熱伝導層111〜111および熱共振体層112〜112(n+1)を単結晶もしくは膜厚方向に結晶が連続し膜厚方向には結晶粒界が存在しない結晶膜によって構成することは、層内の結晶粒界等でのフォノンの散乱を除去または低減できるため、好ましい。 As a film formation method of the heat conductive layers 111 1 to 111 n and the thermal resonator layers 112 1 to 112 (n + 1) , for example, a CVD method, an MBE method, an ion cluster beam method, or the like can be used. Using these film forming methods, the thermal conductive layers 111 1 to 111 n and the thermal resonator layers 112 1 to 112 (n + 1) are single crystals or crystals are continuous in the film thickness direction, and there are crystal grain boundaries in the film thickness direction. It is preferable to use a crystal film that is not formed because phonon scattering at a grain boundary or the like in the layer can be removed or reduced.

また、結晶膜によって構成される熱共振体層112〜112(n+1)は、対象とするフォノンの平均自由行程が熱共振体層112〜112(n+1)の膜厚以上となる大きさおよび数の結晶粒界を有するのでもよい。このような結晶粒界を有する結晶膜で熱共振体層112〜112(n+1)を構成するによって、成膜方法および条件を緩和することができる。ただし、熱伝導層111〜111および熱共振体層112〜112(n+1)の成膜方法は、上記の方法に限定されるものではなく、その他の結晶膜の成膜方法を用いるのでも、連続的な膜を形成するその他の適切な成膜方法を用いるのでもよい。 Further, the thermal resonator layers 112 1 to 112 (n + 1) constituted by the crystal films have a size such that the mean free path of the target phonon is equal to or larger than the film thickness of the thermal resonator layers 112 1 to 112 (n + 1). It may have several grain boundaries. By forming the thermal resonator layers 112 1 to 112 (n + 1) with a crystal film having such a crystal grain boundary, the film forming method and conditions can be relaxed. However, the film formation method of the heat conductive layers 111 1 to 111 n and the thermal resonator layers 112 1 to 112 (n + 1) is not limited to the above method, and other crystal film formation methods are used. However, other suitable film forming methods for forming a continuous film may be used.

Agからなり厚さ6nmの熱伝導層111〜111とSiからなり厚さ6nmの熱共振体層112〜112(n+1)とを交互に50層ずつSi基板上に積層して得られた異方性熱伝導部材110と、同様の形状の単層のSiシートとを対象に、熱浸透率について比較した。サーモリフレクタンス法を用いて測定した結果、Si基板上に形成された異方性熱伝導部材110およびSiシートに対して、熱浸透率は、それぞれ、1100、35000Js−0.5−2−1となった。すなわち、異方性熱伝導部材110の熱浸透率がSiシートの熱浸透率の1/20以下の値となった。
このように、異方性熱伝導部材110を用いることによって層に垂直方向への熱の拡散を抑えることが可能となり、ヒートシンク等への熱伝達を効率的にすることができるため、冷却効率が5倍以上も飛躍的に改善できる。
It is obtained by alternately stacking 50 thermal conductive layers 111 1 to 111 n made of Ag and 6 nm thick thermal resonator layers 112 1 to 112 (n + 1) on a Si substrate. The heat permeability was compared for the anisotropic heat conducting member 110 and a single-layer Si sheet having the same shape. As a result of measurement using the thermoreflectance method, the thermal permeabilities of the anisotropic heat conductive member 110 and the Si sheet formed on the Si substrate are 1100 and 35000 Js −0.5 m −2 K, respectively. -1 . That is, the heat permeability of the anisotropic heat conducting member 110 was a value of 1/20 or less of the heat permeability of the Si sheet.
As described above, by using the anisotropic heat conductive member 110, it becomes possible to suppress the diffusion of heat in the direction perpendicular to the layer, and the heat transfer to the heat sink or the like can be made efficient, so that the cooling efficiency is improved. It can improve dramatically by more than 5 times.

以下、本発明の第1実施態様に係る異方性冷却素子100の作用について、図面を参照して説明する。まず、発熱体10が発生した熱は、異方性熱伝導部材110に伝わっていき、異方性熱伝導部材110内を温度勾配に応じて流れる。熱は、異方性熱伝導部材110内を温度の低い冷却放熱手段120、120側に伝達し、冷却放熱手段120、120で外部に放熱される。ここで、異方性熱伝導部材110は、熱伝導率の異方性が高いため、熱は、外部に拡散せず異方性熱伝導部材110内の2次元的空間に閉じ込められたまま冷却放熱手段120、120側に伝達する。その結果、発熱体10を効率良く冷却できると共に、小型化できる。さらに、発熱体10内の温度分布の偏りを減少させることが可能となる
Hereinafter, the operation of the anisotropic cooling element 100 according to the first embodiment of the present invention will be described with reference to the drawings. First, the heat generated by the heating element 10 is transferred to the anisotropic heat conducting member 110 and flows in the anisotropic heat conducting member 110 according to the temperature gradient. Heat is transmitted through the anisotropic heat conducting member 110 to the cooling heat dissipating means 120 1 , 120 2 having a low temperature, and is radiated to the outside by the cooling heat dissipating means 120 1 , 120 2 . Here, since the anisotropic heat conducting member 110 has a high thermal conductivity anisotropy, the heat is not diffused to the outside and is cooled while being confined in the two-dimensional space in the anisotropic heat conducting member 110. It transmits to the heat radiating means 120 1 , 120 2 side. As a result, the heating element 10 can be efficiently cooled and downsized. Furthermore, it is possible to reduce the uneven temperature distribution in the heating element 10.

携帯機器用の半導体素子、パワー素子向けの半導体素子、これらのモジュール等で用いられるパッケージでは、半導体チップの劣化を防ぐためにラミネート加工が施されており、パッケージ内の半導体素子から熱を逃がすためにヒートシンクを取り付けても有効に熱を逃がすことが難しい。そのため、以上説明したように本発明の第1実施形態では、半導体チップ等の発熱体10に直に異方性熱伝導部材110を接触させ、さらに異方性熱伝導部材110の端部にヒートシンク等の冷却放熱手段120、120を設けて放熱する構成とし、効果的に放熱できるようにした。 In semiconductor devices for portable devices, semiconductor devices for power devices, and packages used in these modules, lamination processing is applied to prevent deterioration of the semiconductor chip, and heat is released from the semiconductor devices in the package. It is difficult to effectively release heat even if a heat sink is attached. Therefore, as described above, in the first embodiment of the present invention, the anisotropic heat conductive member 110 is brought into direct contact with the heating element 10 such as a semiconductor chip, and a heat sink is further attached to the end of the anisotropic heat conductive member 110. The cooling heat radiation means 120 1 , 120 2 , etc. are provided to dissipate heat so that heat can be effectively dissipated.

(第2実施形態)
図3は、本発明の第2実施形態に係る異方性冷却素子100の異方性熱伝導部材110と発熱体10との接続を説明するための模式的な断面図である。異方性熱伝導部材110には、中央部等に発熱体10をマウントする所定の領域(以下、マウント領域と言う。)が設けられ、異方性熱伝導部材110は、マウント領域で発熱体10に接触層131を介して接触するようになっている。ここで、異方性熱伝導部材110のマウント領域で、図3に示すように、いずれかの熱伝導層111(x:1〜n)が露出するように構成される。本例では、熱伝導層111〜111のうち熱伝導層111と熱伝導層111が、発熱体10の外面に露出している。
(Second Embodiment)
FIG. 3 is a schematic cross-sectional view for explaining the connection between the anisotropic heat conducting member 110 and the heating element 10 of the anisotropic cooling element 100 according to the second embodiment of the present invention. The anisotropic heat conductive member 110 is provided with a predetermined region (hereinafter referred to as a mount region) for mounting the heating element 10 at the center or the like. 10 through a contact layer 131. Here, as shown in FIG. 3, one of the heat conductive layers 111 x (x: 1 to n) is exposed in the mounting region of the anisotropic heat conductive member 110. In this example, thermally conductive layer 111 1-111 out thermally conductive layer 111 1 of n and thermally conductive layer 111 2 is exposed to the outer surface of the heating element 10.

このようにマウント領域を構成することは、熱接触抵抗を低減し、発熱体10から異方性熱伝導部材110への熱の伝達を効率化できるため、好ましい。
(第3実施形態)
図4に示す本発明の第3実施形態に係る異方性冷却素子100では、異方性熱伝導部材110のマウント領域で、図3に示す上記第2実施形態の場合よりも多くの熱伝導層111(x:1〜n)が露出するように構成される。このようにマウント領域を構成することは、熱接触抵抗をさらに低減し、発熱体10から異方性熱伝導部材110への熱の伝達をより一層効率化できるため、好ましい。
なお、異方性熱伝導部材110が熱を輸送する主要な熱伝導層111(p:1〜n)を有する場合、上記の「x」として、この「p」または「p」の近傍とすることは、さらに熱接触抵抗の低減等の観点から好ましい。
It is preferable to configure the mount region in this way because the thermal contact resistance can be reduced and the heat transfer from the heating element 10 to the anisotropic heat conducting member 110 can be made efficient.
(Third embodiment)
In the anisotropic cooling element 100 according to the third embodiment of the present invention shown in FIG. 4, more heat conduction is performed in the mount region of the anisotropic heat conducting member 110 than in the second embodiment shown in FIG. The layer 111 x (x: 1 to n) is configured to be exposed. It is preferable to configure the mount region in this way because the thermal contact resistance can be further reduced and the heat transfer from the heating element 10 to the anisotropic heat conducting member 110 can be made more efficient.
In addition, when the anisotropic heat conductive member 110 has the main heat conductive layers 111 p (p: 1 to n) that transport heat, the above “p” or the vicinity of “p” It is further preferable from the viewpoint of reducing thermal contact resistance.

(第4実施形態)
図5に示す本発明の第4実施形態に係る異方性冷却素子100では、異方性熱伝導部材110は、端面又は端面近傍の所定の領域に、各冷却放熱手段120、120との良好な熱接触をとるための階段状の接触領域を有する。異方性熱伝導部材110は、接触領域の一部または全部でマウント領域と同様に、いずれか1つ以上の熱伝導層111〜111が露出するように構成される。図5で符号「141」は、異方性熱伝導部材110と各冷却放熱手段120、120との間に設けられた接触層である。
(Fourth embodiment)
In anisotropic cooling device 100 according to a fourth embodiment of the present invention shown in FIG. 5, the anisotropic heat conducting member 110, in a predetermined region in the vicinity of the end face or end face, and the cooling heat dissipating means 120 1, 120 2 A step-like contact area for good thermal contact. The anisotropic heat conducting member 110 is configured such that any one or more of the heat conducting layers 111 1 to 111 n are exposed in a part or all of the contact region, similarly to the mount region. In FIG. 5, reference numeral “141” denotes a contact layer provided between the anisotropic heat conducting member 110 and each cooling and radiating means 120 1 , 120 2 .

接触層141は、図5に示すように、冷却放熱手段120、120毎に設けられ、異方性熱伝導部材110と各冷却放熱手段120、120とを熱的に接触させるようになっている。接触層141を、ナノ粒子含有材料を用いて形成することは、ナノ粒子が異方性熱伝導部材110と各冷却放熱手段120、120との間の隙間を密に埋めることができ、もって熱接触抵抗を低く抑えることができるため好ましい。 Contact layer 141, as shown in FIG. 5, provided in the cooling heat dissipating means 120 1, 120 every two, the anisotropic heat conducting member 110 the cooling heat dissipating means 120 1, 120 2 and so as to thermally contact the It has become. Forming the contact layer 141 using a nanoparticle-containing material allows the nanoparticle to close the gap between the anisotropic heat conducting member 110 and each of the cooling and heat radiation means 120 1 and 120 2 , Therefore, it is preferable because the thermal contact resistance can be kept low.

ナノ粒子として、銀、銅若しくは金のいずれか、又は酸化銀若しくは酸化銅の物質からなるものを用いるのでもよい。このナノ粒子として、Au、Ag、Cu等の熱伝導率の高い物質からなるものを用いることは、熱接触抵抗を更に低く抑えることができるため好ましい。また、ナノ粒子含有材料がナノ粒子からなる材料以外にバインダ樹脂および界面活性剤のうちの1つ以上を含むのは、ナノ粒子を異方性熱伝導部材110または各冷却放熱手段120、120に良好に固定できるため好ましい。バインダ樹脂および界面活性剤のうちの1つ以上を含むナノ粒子含有材料として、例えば、Au、Ag、Cu等の熱伝導率の高い金属のナノ粒子を含む金属ナノペーストを用いるのでもよい。 Nanoparticles made of silver, copper, or gold, or silver oxide or copper oxide may be used. It is preferable to use a nano-particle made of a material having a high thermal conductivity such as Au, Ag, or Cu because the thermal contact resistance can be further reduced. In addition, the nanoparticle-containing material includes one or more of a binder resin and a surfactant in addition to the material made of nanoparticles. The nanoparticle is made of the anisotropic heat conducting member 110 or each of the cooling and radiating means 120 1 , 120. 2 is preferable because it can be fixed satisfactorily. As the nanoparticle-containing material containing one or more of a binder resin and a surfactant, for example, a metal nanopaste containing metal nanoparticles having a high thermal conductivity such as Au, Ag, or Cu may be used.

なお、ナノ粒子含有材料をハンダ粒子からなる材料又はハンダ粒子を含む材料とすることは、異方性熱伝導部材110と各冷却放熱手段120、120の接着性を向上させ、バインダ樹脂および界面活性剤等を要しないこと等の観点から好ましい。ここで、ナノ粒子が酸化銀、酸化銅等の酸化物のうちのいずれか1つ以上の物質からなる場合、ナノ粒子含有材料は、さらに、炭化物、遷移金属酸化物、典型金属酸化物、又は、典型金属元素の合金の酸化物を還元用焼結助剤として含むのでもよい。このようにすることによって、酸化物に対する還元反応が促進し、金属ナノ粒子が形成しやすくなるからである。 In addition, making the nanoparticle-containing material a material made of solder particles or a material containing solder particles improves the adhesion between the anisotropic heat conducting member 110 and each of the cooling and radiating means 120 1 , 120 2 , This is preferable from the viewpoint of not requiring a surfactant or the like. Here, when the nanoparticles are made of any one or more substances of oxides such as silver oxide and copper oxide, the nanoparticle-containing material further includes a carbide, a transition metal oxide, a typical metal oxide, or An oxide of a typical metal element alloy may be included as a sintering aid for reduction. By doing so, the reduction reaction for the oxide is promoted, and the metal nanoparticles are easily formed.

ここで、ナノ粒子として、平均の直径が1nmから200nm以下のものを用いることができる。接触層の形成は、ナノ粒子含有材料を接触領域内に塗布した後に、レーザ光を照射すること、例えばMHz台以上の高周波電磁波を印加すること等によってナノ粒子含有材料を加熱し、ナノ粒子含有材料を焼成する方法等を用いて行われる。ナノ粒子含有材料を用いて形成される接触層の厚さとして、ナノ粒子の径の上限とほぼ同じ200nm以下とするのが良いが、熱抵抗低減の観点からは、100nm以下が好ましく、さらには数十nm以下等のものが好ましい。また、ナノ粒子のサイズが小さくなると、ナノ粒子自体の融点が低下する効果もあり、特にこの点では、ナノ粒子のサイズは100nm以下が好ましい。  Here, nanoparticles having an average diameter of 1 nm to 200 nm or less can be used. The contact layer is formed by applying the nanoparticle-containing material in the contact region, and then irradiating the laser beam, for example, by applying a high-frequency electromagnetic wave of the MHz range or more, and heating the nanoparticle-containing material to contain the nanoparticle. This is performed using a method of firing the material. The thickness of the contact layer formed using the nanoparticle-containing material is preferably 200 nm or less, which is substantially the same as the upper limit of the diameter of the nanoparticles, but is preferably 100 nm or less from the viewpoint of reducing thermal resistance, Those of several tens of nm or less are preferable. Further, when the size of the nanoparticles is reduced, there is an effect that the melting point of the nanoparticles themselves is lowered. In particular, the size of the nanoparticles is preferably 100 nm or less.

マウント領域と同様に、異方性熱伝導部材110が熱を輸送する主要な熱伝導層111(p:1〜n)を有する場合、上記の「x」として、この「p」または「p」の近傍とすることは、さらに熱接触抵抗の低減等の観点から好ましい。 Similarly to the mount region, when the anisotropic heat conducting member 110 has the main heat conducting layer 111 p (p: 1 to n) that transports heat, the “p” or “p” "In the vicinity of" is preferable from the viewpoint of reducing thermal contact resistance.

なお、熱伝導層111〜111が露出した異方性熱伝導部材110の接触領域の形状は、階段状に限らず、異方性熱伝導部材110の厚さが接触領域において異方性熱伝導部材110の中央側から端面側に向けて単調に減少するものであっても良い。 Note that the shape of the contact region of the anisotropic heat conductive member 110 where the heat conductive layers 111 1 to 111 n are exposed is not limited to a step shape, and the thickness of the anisotropic heat conductive member 110 is anisotropic in the contact region. The heat conductive member 110 may be monotonously decreased from the center side toward the end face side.

具体的には、異方性熱伝導部材110の厚さが、冷却放熱手段1201,1202側の端面に向けて徐々にまたは単調に増加する、刃状、階段状、又はこれらを組み合わせた形状等が好ましい。ただし、本発明は異方性熱伝導部材110の厚さが接触領域において上記のように減少する構成には限定されず、その他の構成でもよい。また、上記のように異方性熱伝導部材110が熱を輸送する主要な熱伝導層111(p:1〜n)を有する場合、接触領域の断面形状を、この「p」または「p」の近傍の熱伝導層との接触面積が高なるようにすることは、熱接触抵抗を低減し、冷却、放熱等を効率的に行うという観点から好ましい。 Specifically, the thickness of the anisotropic heat conducting member 110 gradually or monotonously increases toward the end faces on the cooling and heat dissipating means 1201 and 1202 side, a blade shape, a step shape, or a combination of these, etc. Is preferred. However, the present invention is not limited to the configuration in which the thickness of the anisotropic heat conducting member 110 decreases as described above in the contact region, and other configurations may be used. In addition, when the anisotropic heat conducting member 110 has the main heat conducting layer 111 p (p: 1 to n) that transports heat as described above, the cross-sectional shape of the contact region is expressed as “p” or “p”. It is preferable to increase the contact area with the heat conductive layer in the vicinity of “from the viewpoint of reducing the thermal contact resistance and efficiently performing cooling, heat dissipation, and the like.

(第5実施形態)
図6に示す本発明の第5実施形態に係る異方性冷却素子100では、異方性熱伝導部材110の端面又は端面近傍の所定の領域に、冷却放熱手段120、120と図5に示す第4実施形態よりも大きな面積で熱接触をとるための接触領域が形成されている。図6で符号「142」は、異方性熱伝導部材110と各冷却放熱手段120、120との間に設けられた接触層である。
(Fifth embodiment)
In the anisotropic cooling element 100 according to the fifth embodiment of the present invention shown in FIG. 6, the cooling / dissipating means 120 1 , 120 2 and the predetermined region near the end face of the anisotropic heat conducting member 110 and FIG. The contact area | region for taking a thermal contact with a larger area than 4th Embodiment shown in FIG. In FIG. 6, reference numeral “142” denotes a contact layer provided between the anisotropic heat conducting member 110 and each cooling / radiating means 120 1 , 120 2 .

(第6実施形態)
図7は本発明の第6実施形態に係る異方性冷却素子500を示している。
上記冷却放熱手段120、120は、例えば、異方性熱伝導部材110を介して伝達した熱を放熱するヒートシンク、伝達した熱を吸熱して冷却するペルチェ素子等によって構成される。冷却放熱手段をペルチェ素子とする構成としては、上記の構成における冷却放熱手段120、120をペルチェ素子で置き換えたものに加えて、図7に示す異方性冷却素子500のように、ペルチェ素子520、520の放熱面Hと対向する冷却面Cを異方性熱伝導部材510に接触するように取り付ける構成等がある。図7で符号「20」は発熱体である。発熱体20の上面に異方性熱伝導部材510が取り付けられている。また、冷却放熱手段の一部をゼーベック素子で置き換えた構成でもよい。この構成では、ゼーベック素子が異方性熱伝導部材110を介して伝達した熱を電気エネルギーに変換し、得られた電気エネルギーは内蔵する電池に帰還される。
(Sixth embodiment)
FIG. 7 shows an anisotropic cooling element 500 according to a sixth embodiment of the present invention.
The cooling / dissipating means 120 1 , 120 2 includes, for example, a heat sink that dissipates the heat transmitted through the anisotropic heat conducting member 110, a Peltier element that absorbs and cools the transmitted heat, and the like. As a configuration in which the cooling heat dissipation means is a Peltier element, in addition to the cooling heat dissipation means 120 1 , 120 2 in the above configuration replaced with a Peltier element, a Peltier element such as an anisotropic cooling element 500 shown in FIG. There is a configuration in which the cooling surface C facing the heat radiation surface H of the elements 520 1 and 520 2 is attached so as to be in contact with the anisotropic heat conducting member 510. In FIG. 7, reference numeral “20” denotes a heating element. An anisotropic heat conducting member 510 is attached to the upper surface of the heating element 20. Moreover, the structure which replaced a part of cooling-heat-dissipating means with the Seebeck element may be sufficient. In this configuration, the Seebeck element converts the heat transmitted through the anisotropic heat conducting member 110 into electric energy, and the obtained electric energy is fed back to the built-in battery.

冷却放熱手段としてペルチェ素子を用いることは、高機能の実現に伴って増大した熱を効果的に吸熱できるため好ましい。また、冷却放熱手段としてゼーベック素子を用いることは、変換して得られた電気エネルギーを内蔵する電池に帰還させることによってエネルギー消費を低減できるため好ましい。冷却放熱手段の異方性熱伝導部材との接触領域の形状は、対応する異方性熱伝導部材の接触領域の形状に応じて決定され、異方性熱伝導部材の接触領域内の熱伝導層が露出した部分と密着する形状となっている。   It is preferable to use a Peltier element as the cooling and radiating means because it can effectively absorb the heat increased with the realization of a high function. In addition, it is preferable to use a Seebeck element as the cooling and radiating means because the energy consumption can be reduced by returning the electric energy obtained by conversion to the built-in battery. The shape of the contact area of the cooling heat dissipation means with the anisotropic heat conducting member is determined according to the shape of the contact area of the corresponding anisotropic heat conducting member, and the heat conduction in the contact area of the anisotropic heat conducting member. The layer is in close contact with the exposed portion.

(第7実施形態)
図8は本発明の第7実施形態に係る異方性冷却素子601を示している。
冷却放熱手段621、621は、図8に示すように、異方性熱伝導部材611から離れた位置に配置され、例えばヒートリード631、631を介して異方性熱伝導部材611に接続される構成となっている。図8で符号「30」は発熱体である。なお、冷却放熱手段621、621は、基板であってもよい。
(Seventh embodiment)
FIG. 8 shows an anisotropic cooling element 601 according to the seventh embodiment of the present invention.
As shown in FIG. 8, the cooling and radiating means 621 1 and 621 2 are arranged at positions away from the anisotropic heat conductive member 611, and for example, the anisotropic heat conductive member 611 via the heat leads 631 1 and 631 2. It is configured to be connected to. In FIG. 8, reference numeral “30” denotes a heating element. The cooling and radiating means 621 1 and 621 2 may be a substrate.

(第8実施形態)
図9は本発明の第8実施形態に係る異方性冷却素子602を示している。
異方性熱伝導部材612は、発熱体40の対向する1対の面の各面上の一部または全部に接触するように設けられ、各異方性熱伝導部材612が対応する接触層を介して冷却放熱手段622、622に接続されるのでもよい。
(Eighth embodiment)
FIG. 9 shows an anisotropic cooling element 602 according to the eighth embodiment of the present invention.
The anisotropic heat conductive member 612 is provided so as to be in contact with a part or all of each of a pair of opposed surfaces of the heating element 40, and each anisotropic heat conductive member 612 has a corresponding contact layer. It may be connected to the cooling and radiating means 622 1 , 622 2 .

この構成においても、冷却放熱手段622、622は、図9に示すように、異方熱伝導部材612から離れた位置に配置され、例えばヒートリード632、632を介して異方性熱伝導部材612に接続される。また、図示しないヒートシンクが発熱体40と基板との間に発熱体と基板によって挟持されるように形成され、異方性熱伝導部材612と冷却放熱手段622、6221との接続はヒートリード632、632等によって行われるような構成である。 Also in this configuration, the cooling / dissipating means 622 1 , 622 2 is disposed at a position away from the anisotropic heat conducting member 612 as shown in FIG. 9, and is anisotropic via, for example, the heat leads 632 1 , 632 2. It is connected to the heat conducting member 612. Further, a heat sink (not shown) is formed between the heating element 40 and the substrate so as to be sandwiched between the heating element and the substrate, and the anisotropic heat conducting member 612 and the cooling and radiating means 622 1 , 6221 2 are connected to the heat lead. 632 1 , 632 2 and the like.

(第9実施形態)
図10は本発明の第8実施形態に係る異方性冷却素子700を示している。
図10に示すように、発熱体50が積層され、各発熱体50間に異方性熱伝導部材710が発熱体50に接触するように又は発熱体50を挟むように設けられるのでもよい。そして、図10に示す例では、各異方性熱伝導部材710がヒートリード720を介して冷却放熱手段としての基板730に接続されている。ここで、ヒートリード720が異方性熱伝導部材710の接触領域に設けられた接触層に取り付けられ、発熱体50が同様にマウント領域に設けられた接触層に取り付けられるのは、熱接触抵抗を低減できるため好ましい。上記の構成のように、各発熱体50間に異方性熱伝導部材710を設けることによって、内部の発熱体50からの熱を効果的に放熱できるため、極めて好ましい。また、発熱体50が半導体回路等からなる場合、必要に応じて貫通電極740を設け各発熱体50間を接続するのでもよい。
(Ninth embodiment)
FIG. 10 shows an anisotropic cooling element 700 according to the eighth embodiment of the present invention.
As shown in FIG. 10, the heating elements 50 may be stacked, and the anisotropic heat conductive member 710 may be provided between the heating elements 50 so as to contact the heating elements 50 or sandwich the heating elements 50. And in the example shown in FIG. 10, each anisotropic heat conductive member 710 is connected to the board | substrate 730 as a cooling heat dissipation means via the heat lead 720. As shown in FIG. Here, the heat lead 720 is attached to the contact layer provided in the contact region of the anisotropic heat conducting member 710, and the heating element 50 is attached to the contact layer similarly provided in the mount region. Can be reduced. By providing the anisotropic heat conducting member 710 between the heating elements 50 as in the above configuration, it is very preferable because the heat from the internal heating elements 50 can be effectively radiated. Further, when the heating element 50 is made of a semiconductor circuit or the like, a through electrode 740 may be provided as necessary to connect the heating elements 50.

(第10実施形態)
図11は、本発明の第10実施形態に係る異方性冷却素子801の断面構造を示す模式図である。図11において、異方性冷却素子801は、ペルチェ素子が複数同一面内に放熱面または冷却面を揃えて配置された冷却手段811と、冷却手段811を放熱面と冷却面との両方から挟持する1対の受熱基板831、831と、冷却手段811と受熱基板831、831との間に配置される異方性熱伝導部材821、821とを備えた構成を有する。
(10th Embodiment)
FIG. 11 is a schematic diagram showing a cross-sectional structure of an anisotropic cooling element 801 according to the tenth embodiment of the present invention. In FIG. 11, an anisotropic cooling element 801 includes a cooling means 811 in which a plurality of Peltier elements are arranged in the same plane with a heat radiating surface or a cooling surface, and the cooling means 811 sandwiched from both the heat radiating surface and the cooling surface. And a pair of heat receiving substrates 831 1 and 831 2 and anisotropic heat conducting members 821 1 and 821 2 disposed between the cooling means 811 and the heat receiving substrates 831 1 and 831 2 .

ここで、冷却手段811が有するペルチェ素子は、例えば、導電型の異なる不純物がドープされた2種類の半導体が銅等の金属で接続された構成を有する。ここで、上記の半導体として、Bi、Te、Sb、Se、Si、Ge、Gd、Fe、Pb、Cu、Ag等の化合物から成るものを用いることができる。   Here, the Peltier element included in the cooling unit 811 has a configuration in which, for example, two types of semiconductors doped with impurities of different conductivity types are connected with a metal such as copper. Here, as the semiconductor, a semiconductor composed of a compound such as Bi, Te, Sb, Se, Si, Ge, Gd, Fe, Pb, Cu, or Ag can be used.

異方性熱伝導部材821、821は、本発明の第1実施態様で説明したものと同様の積層構造を有する。ここで、ペルチェ素子が設けられるマウント領域は、垂直方向の熱伝導性を考慮して受熱基板831、831側近くまで掘り込んだ例えば凹状の断面形状を有するのでもよい。 The anisotropic heat conducting members 821 1 and 821 2 have the same laminated structure as that described in the first embodiment of the present invention. Here, the mount region in which the Peltier element is provided may have, for example, a concave cross-sectional shape that is dug to the heat receiving substrates 831 1 and 831 2 side in consideration of the thermal conductivity in the vertical direction.

(第11実施形態)
図12は、本発明の第11実施形態に係る異方性冷却素子810の断面構造を示す模式図である。
なお、上記第10実施形態では、受熱基板831、831が、冷却手段811を放熱面と冷却面との両方から挟持する構成について説明したが、本実施形態に係る異方性冷却素子802では、図12に示すように、受熱基板831、831に代えて冷却放熱手段812を保持するホルダー基板832を設け、異方性熱伝導部材822、822がホルダー基板832の対向する面上に配置される構成としている。ホルダー基板が図12に示す構成を採用する場合は、可撓性を有するペルチェモジュールが得られる。
(Eleventh embodiment)
FIG. 12 is a schematic diagram showing a cross-sectional structure of an anisotropic cooling element 810 according to the eleventh embodiment of the present invention.
In the tenth embodiment, the configuration in which the heat receiving substrates 831 1 and 831 2 sandwich the cooling unit 811 from both the heat radiation surface and the cooling surface has been described. However, the anisotropic cooling element 802 according to the present embodiment. Then, as shown in FIG. 12, instead of the heat receiving substrates 831 1 and 831 2 , a holder substrate 832 for holding the cooling and radiating means 812 is provided, and the anisotropic heat conducting members 822 1 and 822 2 face the holder substrate 832. It is set as the structure arrange | positioned on a surface. When the holder substrate adopts the configuration shown in FIG. 12, a flexible Peltier module is obtained.

(第12実施形態)
次に、本発明を具体化した第12実施形態に係る半導体素子を図13に基づいて説明する。
(Twelfth embodiment)
Next, a semiconductor device according to a twelfth embodiment embodying the present invention will be described with reference to FIG.

本実施形態に係る半導体素子は、上記各実施形態で説明した異方性冷却素子の異方性熱伝導部材を放熱に利用したハイパワーLED(発光ダイオード)素子である。
半導体素子としてのハイパワーLED素子70は、異方性熱伝導部材としての異方性熱伝導膜71と、発熱体としてのLEDチップ72と、基板73とを備える。基板73は汎用基板である。この基板73上に異方性熱伝導膜71が形成されている。この異方性熱伝導膜71の表面上にLEDチップ72が実装されている。異方性熱伝導膜71は、上記第1実施形態で説明した異方性熱伝導部材110(図1、図2参照)と同様の構成を有する。
The semiconductor element according to the present embodiment is a high power LED (light emitting diode) element that uses the anisotropic heat conducting member of the anisotropic cooling element described in the above embodiments for heat dissipation.
A high power LED element 70 as a semiconductor element includes an anisotropic heat conductive film 71 as an anisotropic heat conductive member, an LED chip 72 as a heating element, and a substrate 73. The substrate 73 is a general-purpose substrate. An anisotropic heat conductive film 71 is formed on the substrate 73. An LED chip 72 is mounted on the surface of the anisotropic heat conductive film 71. The anisotropic heat conductive film 71 has the same configuration as the anisotropic heat conductive member 110 (see FIGS. 1 and 2) described in the first embodiment.

ハイパワーLED素子70の両側面には、冷却放熱手段74が接触層75をそれぞれ介して配置されており、異方性熱伝導膜71の露出した両端面が接触層75をそれぞれ介してペルチェ素子74と熱的に良好に接触するようになっている。冷却放熱手段74としては、例えばペルチェ素子が用いられる。   On both side surfaces of the high-power LED element 70, cooling heat dissipation means 74 are arranged via contact layers 75, and both exposed end faces of the anisotropic heat conductive film 71 are Peltier elements via the contact layers 75. 74 is in good thermal contact. As the cooling and heat dissipation means 74, for example, a Peltier element is used.

ここで、本実施形態に係る半導体素子70との比較例として、2つの従来技術を図16および図17に基づいて説明する   Here, as a comparative example with the semiconductor element 70 according to the present embodiment, two conventional techniques will be described with reference to FIGS. 16 and 17.

図16は、複合構造により発熱体の放熱をする従来のハイパワーLED素子を示している。このハイパワーLED素子は、金属製の基板である金属ベース76と、中央に開口部を有するように金属ベース76の表面に形成された樹脂層77と、樹脂層77の開口部で露出した金属ベース76の表面および樹脂層77の一部の表面上に、V字形状の断面を有するように形成されたAlNパッケージ78と、このAlNパッケージ78中央の平坦面上に実装されたLEDチップ79とを備えている。この従来技術では、素子設計上、構造に制約がある。   FIG. 16 shows a conventional high-power LED element that dissipates heat from a heating element using a composite structure. This high power LED element includes a metal base 76 that is a metal substrate, a resin layer 77 formed on the surface of the metal base 76 so as to have an opening at the center, and a metal exposed at the opening of the resin layer 77. An AlN package 78 formed to have a V-shaped cross section on the surface of the base 76 and a part of the surface of the resin layer 77, and an LED chip 79 mounted on a flat surface in the center of the AlN package 78 It has. In this prior art, there is a restriction on the structure in terms of element design.

また、図17は、高熱発熱パッケージ構造により発熱体の放熱をする従来のハイパワーLED素子を示している。このハイパワーLED素子は、AlN製のAlN基板80と、AlN基板80中央の表面上に実装されたLEDチップ81と、LEDチップ81の周囲を囲むようにAlN基板80の表面上に形成されたAlNパッケージ82とを備えている。この従来技術では、基板自体がAlN製であり、部品コストが高くなる。   FIG. 17 shows a conventional high-power LED element that dissipates heat from the heating element with a high-heat-generation package structure. This high power LED element is formed on the surface of the AlN substrate 80 so as to surround the periphery of the LED chip 81, the AlN substrate 80 made of AlN, the LED chip 81 mounted on the center surface of the AlN substrate 80, and the LED chip 81. And an AlN package 82. In this prior art, the substrate itself is made of AlN, which increases the component cost.

以上の構成を有する第12実施形態によれば、以下の作用効果を奏する。
○基板73上に異方性熱伝導膜71を形成し、この異方性熱伝導膜71の表面上にLEDチップ72を実装することでハイパワーLED素子70を作製できるので、図16に示す上記従来技術のような素子設計上、構造に制約がなくなる。これと共に、基板73は汎用基板で良いので、部品コストを低減できる。これにより、構造が簡単で、汎用基板への高効率成膜が可能となり、製造コストを低減することができる。
○異方性熱伝導膜71によりLEDチップ72全体の温度分布が平坦化されて、LEDチップ72のピーク温度が下げられるので、ハイパワーLED素子70の長寿命化を図ることができる。
○異方性熱伝導膜71の露出した両端面が接触層75をそれぞれ介してペルチェ素子74と熱的に良好に接触するようになっている。このため、異方性熱伝導膜71により層に垂直方向の熱浸透率である層垂直方向熱浸透率が低く抑えられると共に、LEDチップ72からの熱が異方性熱伝導膜71を介してペルチェ素子74に伝達され、放熱されるので、省スペースかつ冷却効率および熱電変換効率の向上が可能なハイパワーLED素子を実現できる。
According to 12th Embodiment which has the above structure, there exist the following effects.
A high power LED element 70 can be manufactured by forming the anisotropic heat conductive film 71 on the substrate 73 and mounting the LED chip 72 on the surface of the anisotropic heat conductive film 71, as shown in FIG. There are no restrictions on the structure in terms of element design as in the prior art. At the same time, since the substrate 73 may be a general-purpose substrate, the component cost can be reduced. As a result, the structure is simple, high-efficiency film formation on a general-purpose substrate is possible, and the manufacturing cost can be reduced.
The temperature distribution of the entire LED chip 72 is flattened by the anisotropic heat conductive film 71 and the peak temperature of the LED chip 72 is lowered, so that the life of the high power LED element 70 can be extended.
The exposed end faces of the anisotropic heat conductive film 71 are in good thermal contact with the Peltier element 74 through the contact layers 75, respectively. For this reason, the anisotropic heat conductive film 71 can suppress the layer vertical heat permeability, which is the heat permeability in the direction perpendicular to the layer, and heat from the LED chip 72 through the anisotropic heat conductive film 71. Since it is transmitted to the Peltier element 74 and dissipated, it is possible to realize a high-power LED element that can save space and improve cooling efficiency and thermoelectric conversion efficiency.

(第13実施形態)
次に、本発明を具体化した第13実施形態に係る半導体素子を図14および図15に基づいて説明する。
(13th Embodiment)
Next, a semiconductor device according to a thirteenth embodiment embodying the present invention will be described with reference to FIGS.

本実施形態に係る半導体素子は、上記各実施形態で説明した異方性冷却素子の異方性熱伝導部材を放熱に利用した半導体レーザ素子である。図14はこの半導体レーザ素子の概略構成を示す斜視図で、図15はその詳細な構造を一部破断して示した斜視図である。なお、図14と図15は同じ構成の半導体素子を示しているが、図14は異方性熱伝導膜を電流狭窄層の内部に形成した例を示してあり、図15は異方性熱伝導膜を電流狭窄層の下部に形成した例を示してある。   The semiconductor element according to the present embodiment is a semiconductor laser element that utilizes the anisotropic heat conducting member of the anisotropic cooling element described in the above embodiments for heat dissipation. FIG. 14 is a perspective view showing a schematic configuration of the semiconductor laser device, and FIG. 15 is a perspective view showing a part of the detailed structure thereof. 14 and 15 show a semiconductor element having the same configuration, FIG. 14 shows an example in which an anisotropic heat conductive film is formed inside the current confinement layer, and FIG. 15 shows an anisotropic heat conduction film. An example in which a conductive film is formed below the current confinement layer is shown.

半導体素子としての半導体レーザ素子90は、図14に示すように、多重量子井戸(MQW)層からなる活性層91と電流狭窄層92とを有し、異方性熱伝導部材としての異方性熱伝導膜93が電流狭窄層92の内部に形成されている。   As shown in FIG. 14, a semiconductor laser element 90 as a semiconductor element has an active layer 91 made of a multiple quantum well (MQW) layer and a current confinement layer 92, and is anisotropic as an anisotropic heat conducting member. A heat conductive film 93 is formed inside the current confinement layer 92.

また、半導体レーザ素子90は、図14および図15に示すように、基板103と、基板103の裏面側に形成された下部電極94と、基板103の表面側に順に形成されたn型下部クラッド層95、活性層91、p型上部クラッド層96、p型コンタクト層97および上部電極98と、を備える。電流狭窄層92は、n型下部クラッド層95に隣接するp型層92と、p型上部クラッド層96に隣接するn型層92とを有する。符号「99」はトンネル接合である。 Further, as shown in FIGS. 14 and 15, the semiconductor laser element 90 includes a substrate 103, a lower electrode 94 formed on the back side of the substrate 103, and an n-type lower clad formed on the surface side of the substrate 103 in this order. A layer 95, an active layer 91, a p-type upper cladding layer 96, a p-type contact layer 97, and an upper electrode 98. The current confinement layer 92 has a p-type layer 92 1 adjacent the n-type lower cladding layer 95, an n-type layer 92 2 adjacent to the p-type upper cladding layer 96. Reference numeral “99” is a tunnel junction.

本実施形態では、異方性熱伝導膜93は、電流狭窄層92の内部で、p型層92とn型層92との間に形成されている。この異方性熱伝導膜93は、以下の製造方法で形成する。 In this embodiment, the anisotropic heat conduction layer 93 is an internal current confinement layer 92 is formed between the p-type layer 92 1 and the n-type layer 92 2. This anisotropic heat conductive film 93 is formed by the following manufacturing method.

まず、電流狭窄のためのp型層92を形成後、異方性熱伝導膜93を形成し、その後、n型層92を形成する。
また、図14において、符号「150」は半導体レーザ素子90の光出射側端面に形成された反射防止膜(AR膜)或いは非反射膜であり、符号「15」はその光反射側端面に形成された高反射膜(HR膜)である。なお、図14において、高反射膜150の奥は本来見えないが、高反射膜150を透視的に示して半導体レーザ素子90の光出射側端面の断面構造が見えるようにしてある。そして、半導体レーザ素子90の両側面には、図13に示すハイパワーLED素子70と同様に、冷却放熱手段が接触層をそれぞれ介して配置されており、異方性熱伝導膜93の露出した両端面が接触層をそれぞれ介してペルチェ素子等の冷却放熱手段と熱的に良好に接触するようになっている。
First, after forming the p-type layer 92 1 for current confinement, form an anisotropic thermal conductive film 93, then forming the n-type layer 92 2.
In FIG. 14, reference numeral “150” is an antireflection film (AR film) or non-reflective film formed on the light emitting side end face of the semiconductor laser element 90, and reference numeral “15” is formed on the light reflecting side end face. This is a highly reflective film (HR film). In FIG. 14, the depth of the high reflection film 150 is not originally visible, but the high reflection film 150 is shown in a transparent manner so that the cross-sectional structure of the light emitting side end face of the semiconductor laser element 90 can be seen. Then, on both side surfaces of the semiconductor laser element 90, similarly to the high power LED element 70 shown in FIG. 13, cooling and heat radiation means are arranged through the contact layers, respectively, and the anisotropic heat conductive film 93 is exposed. Both end surfaces are in good thermal contact with the cooling and radiating means such as Peltier elements through the contact layers.

このような構成を有する半導体レーザ素子90では、下部電極(陰極)94と上部電極(陽極)98間に電流を注入すると、上部電極98から注入された電流は、左右の電流狭窄層92により電流流路を制限されて横方向に流れた後、トンネル接合99を通過して流れ、正孔となって活性層91に至る。こうして活性層91に注入された正孔は、下部電極94から注入される電子と再結合されて発光する。この発光した光が光出射側端面の反射防止膜150と光反射側端面の高反射膜151間を往復することで増幅されてレーザ発振に至り、反射防止膜150を通過してレーザ光として外部へ出射される。   In the semiconductor laser device 90 having such a configuration, when a current is injected between the lower electrode (cathode) 94 and the upper electrode (anode) 98, the current injected from the upper electrode 98 is made into a current by the current confinement layers 92 on the left and right. After flowing in the lateral direction with the flow path restricted, it flows through the tunnel junction 99 and reaches the active layer 91 as holes. The holes injected into the active layer 91 in this way are recombined with electrons injected from the lower electrode 94 to emit light. The emitted light is amplified by reciprocating between the antireflection film 150 on the light emission side end face and the high reflection film 151 on the light reflection side end face to cause laser oscillation, and passes through the antireflection film 150 to be externally emitted as laser light. Is emitted.

以上の構成を有する第12実施形態によれば、以下の作用効果を奏する。
○電流狭窄層92内部に形成された異方性熱伝導膜93により半導体レーザ素子90の発光層91近傍の温度分布が平坦化されて、発光層91近傍のピーク温度が下げられる。これにより、発光層91近傍の低温化、特に発光層91近傍のピーク温度の低温化を図ることができるので、半導体レーザ素子90の長寿命化を図ることができる。
○半導体レーザ素子90の両側面には、冷却放熱手段が接触層をそれぞれ介して配置され、異方性熱伝導膜93の露出した両端面が接触層をそれぞれ介してペルチェ素子等の冷却放熱手段と熱的に良好に接触するようになっている。これにより、異方性熱伝導膜93により層に垂直方向の熱浸透率である層垂直方向熱浸透率が低く抑えられると共に、半導体レーザ素子90からの熱が異方性熱伝導膜93を介して冷却放熱手段に伝達されるので、省スペースかつ冷却効率および熱電変換効率の向上が可能な半導体レーザ素子90を実現できる。
According to 12th Embodiment which has the above structure, there exist the following effects.
The temperature distribution in the vicinity of the light emitting layer 91 of the semiconductor laser element 90 is flattened by the anisotropic thermal conductive film 93 formed in the current confinement layer 92, and the peak temperature in the vicinity of the light emitting layer 91 is lowered. As a result, the temperature near the light emitting layer 91 can be lowered, particularly the peak temperature near the light emitting layer 91 can be lowered, so that the life of the semiconductor laser element 90 can be extended.
A cooling heat dissipation means is disposed on both side surfaces of the semiconductor laser element 90 via contact layers, respectively, and both exposed end faces of the anisotropic heat conductive film 93 are cooled heat dissipation means such as Peltier elements via the contact layers, respectively. And come into good thermal contact. Thereby, the anisotropic thermal conductive film 93 suppresses the layer vertical thermal permeability, which is the thermal permeability in the direction perpendicular to the layer, and heat from the semiconductor laser element 90 passes through the anisotropic thermal conductive film 93. Therefore, the semiconductor laser device 90 can be realized which can save space and improve the cooling efficiency and the thermoelectric conversion efficiency.

なお、この発明は以下のように変更して具体化することもできる。
・上記第2実施形態では、異方性熱伝導部材110は、マウント領域で発熱体10に接触層131を介して接触するようしているが、異方性熱伝導部材110が発熱体10に直に接触する構成にも本発明は適用可能である。
In addition, this invention can also be changed and embodied as follows.
In the second embodiment, the anisotropic heat conductive member 110 is in contact with the heating element 10 via the contact layer 131 in the mount region. The present invention can also be applied to a structure that is in direct contact.

・図14に示す上記第13実施形態では、異方性熱伝導膜93を、電流狭窄層92の内部で、p型層92とn型層92との間に形成した例について説明したが、異方性熱伝導膜93を電流狭窄層92のp型層92の内部、或いは、n型層92の内部に形成しても良い。 · In the first 13 embodiment shown in FIG. 14, the anisotropic thermal conductive film 93, an internal current confinement layer 92, an example was described in which formed between the p-type layer 92 1 and the n-type layer 92 2 but the inside of the p-type layer 92 1 of the current confinement layer 92 an anisotropic thermal conductive film 93, or may be formed in the n-type layer 92 2.

・また、異方性熱伝導膜93を図15に示すように電流狭窄層92の下部に形成してもよい。この異方性熱伝導膜93は、次の製造方法で形成する。メサストラップを形成後、周辺部分に異方性熱伝導膜93を形成し、その上層に電流狭窄のための電流狭窄層92を構成するp型層92と、n型層92を順次形成する。 Further, the anisotropic heat conductive film 93 may be formed below the current confinement layer 92 as shown in FIG. The anisotropic heat conductive film 93 is formed by the following manufacturing method. After forming the mesa strap, forming an anisotropic thermal conductive film 93 in the peripheral portion, and the p-type layer 92 1 forming the current confinement layer 92 for current confinement thereon, sequentially forming an n-type layer 92 2 To do.

・また、異方性熱伝導膜93を電流狭窄層92の上部に形成してもよい。この異方性熱伝導膜93は、次の製造方法で形成する。電流狭窄のためのp型層92、n型層92を形成後、異方性熱伝導膜93を形成する。 Further, the anisotropic heat conductive film 93 may be formed on the current confinement layer 92. The anisotropic heat conductive film 93 is formed by the following manufacturing method. After forming the p-type layer 92 1, n-type layer 92 2 for current confinement, to form the anisotropic thermal conductive film 93.

・このように、本発明は、異方性熱伝導膜93が活性層91の近傍に配置される構成、つまり、異方性冷却素子の異方性熱伝導部材としての異方性熱伝導膜93が電流狭窄層92の内部、上部および下部のいずれかに形成されている半導体素子に広く適用可能である。   As described above, according to the present invention, the anisotropic heat conductive film 93 is disposed in the vicinity of the active layer 91, that is, the anisotropic heat conductive film as an anisotropic heat conductive member of the anisotropic cooling element. 93 is widely applicable to a semiconductor device formed inside, above or below the current confinement layer 92.

本発明の異方性冷却素子は、熱伝導率の高い熱伝導層と熱共振層とを交互に積層した異方熱伝導部材を用いることで、冷却効率および熱電変換効率の向上並びに省スペース化が可能という効果を有し、かかる効果が有効な電子素子、電子機器、その他の発熱体の冷却を行う異方性冷却素子等として有用である。   The anisotropic cooling element of the present invention uses an anisotropic heat conduction member in which heat conduction layers and heat resonance layers having high heat conductivity are alternately laminated, thereby improving cooling efficiency and thermoelectric conversion efficiency and saving space. It is useful as an anisotropic cooling element that cools electronic elements, electronic devices, and other heat generating elements that have the effect of being capable of being effective.

本発明の第1実施態様に係る異方性冷却素子の概略構成を示す断面図。Sectional drawing which shows schematic structure of the anisotropic cooling element which concerns on 1st embodiment of this invention. 同異方性冷却素子の異方性熱伝導部材を示す拡大断面図。The expanded sectional view which shows the anisotropic heat conductive member of the same anisotropic cooling element. 本発明の第2実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 2nd embodiment of this invention. 本発明の第3実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 3rd embodiment of this invention. 本発明の第4実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 4th embodiment of this invention. 本発明の第5実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 5th embodiment of this invention. 本発明の第6実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 6th embodiment of this invention. 本発明の第7実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 7th embodiment of this invention. 本発明の第8実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 8th embodiment of this invention. 本発明の第9実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 9th embodiment of this invention. 本発明の第10実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 10th embodiment of this invention. 本発明の第11実施態様に係る異方性冷却素子の主要部を示す断面図。Sectional drawing which shows the principal part of the anisotropic cooling element which concerns on the 11th embodiment of this invention. 本発明の第12実施態様に係るハイパワーLED素子の概略構成を示す断面図。Sectional drawing which shows schematic structure of the high power LED element which concerns on the 12th embodiment of this invention. 本発明の第13実施態様に係る半導体レーザ素子の概略構成を示す斜視図。A perspective view showing a schematic structure of a semiconductor laser device according to a thirteenth embodiment of the present invention. 同半導体レーザ素子の詳細な構造を一部破断して示した斜視図。The perspective view which showed the detailed structure of the semiconductor laser element partially broken. 発熱体の放熱をする従来のハイパワーLED素子の概略構成を示す断面図。Sectional drawing which shows schematic structure of the conventional high power LED element which thermally radiates a heat generating body. 従来のハイパワーLED素子の概略構成を示す断面図。Sectional drawing which shows schematic structure of the conventional high power LED element.

符号の説明Explanation of symbols

10、20、30、40、50 発熱体
70 ハイパワーLED素子
71 異方性熱伝導膜
72 LEDチップ
73 基板
90 半導体レーザ素子
91 活性層
92 電流狭窄層
93 異方性熱伝導膜
100、500、601、602、700、801、802 異方性冷却素子
110、510、611、612、710、821、821、822、822
異方性熱伝導部材
111〜111(n+1) 熱伝導層
112〜112(n+1) 熱共振体層
120、120、621、621、622、622 冷却放熱手段
13、13 接触層
14、14 接触層
520、520、811、812 ペルチェ素子
631、6312、632、632、720 ヒートリード
730 基板
740 貫通電極
831、831 受熱基板
832 ホルダー基板
10, 20, 30, 40, 50 Heating element 70 High power LED element 71 Anisotropic heat conductive film 72 LED chip 73 Substrate 90 Semiconductor laser element 91 Active layer 92 Current confinement layer 93 Anisotropic heat conductive film 100, 500, 601, 602, 700, 801, 802 Anisotropic cooling element 110, 510, 611, 612, 710, 821 1 , 821 2 , 822 1 , 822 2
Anisotropic heat conducting members 111 1 to 111 (n + 1) Thermal conducting layers 112 1 to 112 (n + 1) Thermal resonator layers 120 1 , 120 2 , 621 1 , 621 2 , 622 1 , 622 2 Cooling heat dissipation means 13 1 , 13 2 Contact layer 14 1 , 14 2 Contact layer 520 1 , 520 2 , 811, 812 Peltier element 631 1 , 6312, 632 1 , 632 2 , 720 Heat lead 730 Substrate 740 Through electrode 831 1 , 831 2 Heat receiving substrate 832 Holder substrate

Claims (25)

取り付けられる発熱体よりも熱伝導率の高い材料からなる熱伝導層と対象とするフォノンの平均自由行程および波長に応じて層厚が決定される熱共振体層とが交互に積層された異方性熱伝導部材と、
前記発熱体から前記異方性熱伝導部材を介して伝達した熱を吸熱して冷却または放熱する1つ以上の冷却放熱手段と、
を備えたことを特徴とする異方性冷却素子。
Anisotropy in which a heat conducting layer made of a material having a higher thermal conductivity than the heating element to be attached and a thermal resonator layer whose layer thickness is determined according to the mean free path and wavelength of the target phonon are alternately laminated Heat conductive member,
One or more cooling and radiating means for absorbing or cooling or radiating heat transferred from the heating element via the anisotropic heat conducting member;
An anisotropic cooling element comprising:
前記発熱体と前記異方性熱伝導部材との間に接触層が設けられていることを特徴とする請求項1に記載の異方性冷却子。   The anisotropic cooling element according to claim 1, wherein a contact layer is provided between the heating element and the anisotropic heat conducting member. 前記異方熱性伝導部材と前記冷却放熱手段との間に接触層が設けられていることを特徴とする請求項1又は2に記載の異方性冷却子。   The anisotropic cooler according to claim 1, wherein a contact layer is provided between the anisotropic heat conductive member and the cooling and heat radiating means. 少なくとも1つ以上の異方性熱伝導部材が、前記発熱体の1つの面上の一部または全部に接触するように設けられ、各異方性熱伝導部材が対応する接触層を介して冷却放熱手段に接続されていることを特徴とする請求項1に記載の異方性冷却素子。   At least one or more anisotropic heat conductive members are provided so as to contact a part or all of one surface of the heating element, and each anisotropic heat conductive member is cooled through a corresponding contact layer. The anisotropic cooling element according to claim 1, wherein the anisotropic cooling element is connected to a heat radiating means. 少なくとも1つ以上の異方性熱伝導部材が、前記発熱体の対向する1対の面の各面上の一部または全部に接触するように設けられ、各異方性熱伝導部材が対応する接触層を介して冷却放熱手段に接続されていることを特徴とする請求項1に記載の異方性冷却素子。   At least one or more anisotropic heat conductive members are provided so as to be in contact with a part or all of the surfaces of the pair of opposing surfaces of the heating element, and each anisotropic heat conductive member corresponds to each other. The anisotropic cooling element according to claim 1, wherein the anisotropic cooling element is connected to the cooling and radiating means via a contact layer. 積層された発熱体の各発熱体間に1つ以上の異方性熱伝導部材が発熱体に接触するように設けられ、前記各異方性熱伝導部材が対応する接触層を介して冷却放熱手段に接続されていることを特徴とする請求項1に記載の異方性冷却素子。   One or more anisotropic heat conducting members are provided between the heat generating members of the stacked heat generating members so as to contact the heat generating members, and each of the anisotropic heat conducting members is cooled and dissipated through a corresponding contact layer. The anisotropic cooling element according to claim 1, wherein the anisotropic cooling element is connected to the means. 前記異方性熱伝導部材が、端面または端面近傍の所定の領域にいずれか1つ以上の前記接触層を形成する接触領域を有することを特徴とする請求項1乃至請求項6のいずれか1項に記載の異方性冷却素子。   The said anisotropic heat conductive member has a contact area | region which forms any one or more said contact layers in the predetermined area | region of an end surface or end surface vicinity, The any one of Claim 1 thru | or 6 characterized by the above-mentioned. The anisotropic cooling element according to item. 前記異方性熱伝導部材のいずれか1つ以上の前記熱伝導層が、前記異方性熱伝導部材のいずれか1つ以上の前記接触領域内の一部または全部で露出していることを特徴とする請求項1乃至請求項7のいずれか1項に記載の異方性冷却素子。   Any one or more of the thermally conductive layers of the anisotropic heat conductive member are exposed in a part or all of the contact region of any one or more of the anisotropic heat conductive members. The anisotropic cooling element according to claim 1, wherein the anisotropic cooling element is characterized. 冷却放熱手段の異方性熱伝導部材との接触領域の形状が、対応する異方性熱伝導部材の接触領域内の熱伝導層が露出した部分と密着する形状となっていることを特徴とする請求項1乃至請求項6のいずれか1項に記載の異方性冷却素子。   The shape of the contact area with the anisotropic heat conducting member of the cooling and heat radiating means is such that the heat conduction layer in the contact area of the corresponding anisotropic heat conducting member is in close contact with the exposed portion. The anisotropic cooling element according to any one of claims 1 to 6. 冷却放熱手段の異方性熱伝導部材との接触領域に形成された接触層がナノ粒子からなる材料を主要材料として含むナノ粒子含有材料を用いて形成されることを特徴とする請求項1乃至請求項9のいずれか1項に記載の異方性冷却素子。   The contact layer formed in the contact region with the anisotropic heat conducting member of the cooling and heat radiating means is formed using a nanoparticle-containing material containing a material composed of nanoparticles as a main material. The anisotropic cooling element of any one of Claim 9. 前記接触層のナノ粒子が、銀、銅若しくは金のいずれか、又は酸化銀若しくは酸化銅のいずれかからなることを特徴とする請求項10に記載の異方性冷却素子。   The anisotropic cooling element according to claim 10, wherein the nanoparticles of the contact layer are made of either silver, copper, or gold, or silver oxide or copper oxide. 前記ナノ粒子含有材料がナノ粒子からなる材料以外に、バインダ樹脂および界面活性剤のうちの1つ以上を含むことを特徴とする請求項10又は請求項11に記載の異方性冷却素子。   The anisotropic cooling element according to claim 10 or 11, wherein the nanoparticle-containing material includes one or more of a binder resin and a surfactant in addition to a material composed of nanoparticles. 前記ナノ粒子が少なくとも酸化銀および酸化銅を含む酸化物のうちのいずれか1つ以上の物質からなる場合、さらに、炭化物、遷移金属酸化物、典型金属酸化物、又は、典型金属元素の合金の酸化物を還元用焼結助剤として含むことを特徴とする請求項11に記載の異方性冷却素子。   In the case where the nanoparticles are made of at least one of oxides containing silver oxide and copper oxide, carbides, transition metal oxides, typical metal oxides, or alloys of typical metal elements The anisotropic cooling element according to claim 11, comprising an oxide as a sintering aid for reduction. 前記ナノ粒子含有材料がハンダ粒子からなる材料又はハンダ粒子を含む材料であることを特徴とする請求項10に記載の異方性冷却素子。   The anisotropic cooling element according to claim 10, wherein the nanoparticle-containing material is a material made of solder particles or a material containing solder particles. 前記ナノ粒子の平均の直径が1nm以上200nm以下であることを特徴とする請求項10に記載の異方性冷却素子。   The anisotropic cooling element according to claim 10, wherein an average diameter of the nanoparticles is 1 nm or more and 200 nm or less. 前記ナノ粒子含有材料を用いて形成される接触層の厚さが200nm以下であることを特徴とする請求項8乃至請求項15のいずれか1項に記載の異方性冷却素子。   The anisotropic cooling element according to claim 8, wherein the contact layer formed using the nanoparticle-containing material has a thickness of 200 nm or less. 前記ナノ粒子含有材料がレーザ光の照射又は高周波電磁波の印加によって焼成され、接触層を形成することを特徴とする請求項8乃至請求項16のいずれか1項に記載の異方性冷却素子。   The anisotropic cooling element according to any one of claims 8 to 16, wherein the nanoparticle-containing material is baked by laser light irradiation or high-frequency electromagnetic wave application to form a contact layer. いずれか1つ以上の前記冷却放熱手段が、それぞれヒートシンク又はペルチェ素子を用いて構成されることを特徴とする請求項1乃至請求項17のいずれか1項に記載の異方性冷却素子。   18. The anisotropic cooling element according to claim 1, wherein any one or more of the cooling and radiating means is configured by using a heat sink or a Peltier element, respectively. いずれか1つ以上の前記冷却放熱手段をゼーベック素子で置き換えたことを特徴とする請求項1乃至請求項17のいずれか1項に記載の異方性冷却素子。   The anisotropic cooling element according to any one of claims 1 to 17, wherein any one or more of the cooling and radiating means is replaced with a Seebeck element. ペルチェ素子が複数同一面内に放熱面または冷却面を揃えて配置された冷却手段と、 前記冷却手段を前記放熱面と前記冷却面との両方から挟持する1対の受熱基板と、熱伝導率の高い材料からなる熱伝導層と対象とするフォノンの平均自由行程および波長に応じて層厚を調整する熱共振体層とが交互に積層された部材であって、前記冷却手段と前記受熱基板との間に配置される異方性熱伝導部材とを備えたことを特徴とする異方性冷却素子。   A cooling means in which a plurality of Peltier elements are arranged in the same plane with a heat radiating surface or a cooling surface, a pair of heat receiving substrates sandwiching the cooling means from both the heat radiating surface and the cooling surface, and thermal conductivity A member in which a heat conducting layer made of a high-temperature material and a thermal resonator layer that adjusts the layer thickness according to the mean free path and wavelength of the target phonon are alternately laminated, the cooling means and the heat receiving substrate An anisotropic cooling element comprising: an anisotropic heat conducting member disposed between the two. ペルチェ素子が複数同一面内に放熱面または冷却面を揃えて配置された冷却手段と、 前記冷却手段の前記放熱面と前記冷却面との間に設けられ、前記冷却手段を保持するホルダー基板と、 熱伝導率の高い材料からなる熱伝導層と対象とするフォノンの平均自由行程および波長に応じて層厚を調整する熱共振体層とが交互に積層された部材であって、前記ホルダー基板の対向する面上に配置される異方性熱伝導部材とを備えたことを特徴とする異方性冷却素子。   A cooling means in which a plurality of Peltier elements are arranged in the same plane with a heat radiating surface or a cooling surface, a holder substrate provided between the heat radiating surface and the cooling surface of the cooling means, and holding the cooling means; A member in which a heat conductive layer made of a material having high thermal conductivity and a thermal resonator layer that adjusts the layer thickness according to the mean free path and wavelength of the target phonon are alternately laminated, the holder substrate An anisotropic cooling element comprising: an anisotropic heat conducting member disposed on opposite surfaces of the element. 上記請求項1乃至21のいずれか1項に記載の異方性冷却素子の異方性熱伝導部材と、前記発光体としての発光ダイオードチップと、基板とを備え、前記基板上に前記異方性熱伝導部材が形成されており、前記異方性熱伝導部材の表面上に前記発光ダイオードチップが実装されていることを特徴とする半導体素子。   The anisotropic heat conducting member of the anisotropic cooling element according to any one of claims 1 to 21, a light emitting diode chip as the light emitter, and a substrate, wherein the anisotropic material is provided on the substrate. A semiconductor element, wherein a heat conductive member is formed, and the light emitting diode chip is mounted on a surface of the anisotropic heat conductive member. 前記異方性熱伝導部材の側面と前記基板の側面のうち、少なくとも前記異方性熱伝導部材の側面に前記冷却放熱手段が設けられていることを特徴とする請求項22に記載の半導体素子。   23. The semiconductor element according to claim 22, wherein the cooling and radiating means is provided on at least a side surface of the anisotropic heat conductive member among a side surface of the anisotropic heat conductive member and a side surface of the substrate. . 上記請求項1乃至21のいずれか1項に記載の異方性冷却素子と、前記発光体としての発光層とおよび電流狭窄層を有する半導体レーザ素子と、を備え、前記異方性冷却素子の異方性熱伝導部材が前記電流狭窄層の内部、上部および下部のいずれかに形成されていることを特徴とする半導体素子。   The anisotropic cooling element according to any one of claims 1 to 21, a semiconductor laser element having a light emitting layer as the light emitter and a current confinement layer, wherein the anisotropic cooling element includes: A semiconductor element, wherein an anisotropic heat conductive member is formed in any one of an inside, an upper part, and a lower part of the current confinement layer. 前記半導体レーザ素子の側面に前記冷却放熱手段が設けられていることを特徴とする請求項24に記載の半導体素子。
25. The semiconductor device according to claim 24, wherein the cooling and radiating means is provided on a side surface of the semiconductor laser device.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101847623A (en) * 2009-03-23 2010-09-29 丰田自动车株式会社 Power model
JP2012016935A (en) * 2010-07-09 2012-01-26 Nisshin Steel Co Ltd Anisotropy heat transfer body and production method thereof
KR20140127795A (en) * 2011-10-05 2014-11-04 사반치 유니버시티 Nanoplasmonic device with nanoscale cooling
WO2015161051A1 (en) * 2014-04-18 2015-10-22 Laird Technologies, Inc. Thermal solutions and methods for dissipating heat from electronic devices using the same side of an anisotropic heat spreader
JP2019079880A (en) * 2017-10-23 2019-05-23 富士通オプティカルコンポーネンツ株式会社 Electronic device

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101517784B1 (en) * 2014-03-27 2015-05-06 서울시립대학교 산학협력단 Thermoelectric materials having high figure of merit and manufacturing method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10247708A (en) * 1997-03-04 1998-09-14 Akutoronikusu Kk Face-to-face heat conductive plate
JP2004193200A (en) * 2002-12-09 2004-07-08 Japan Science & Technology Agency Superlattice thermoelectric material
JP2004296629A (en) * 2003-03-26 2004-10-21 Matsushita Electric Ind Co Ltd Thermoelectric conversion material and manufacturing method therefor
JP2005251917A (en) * 2004-03-03 2005-09-15 Denso Corp Thermoelectric transducer
JP2005294321A (en) * 2004-03-31 2005-10-20 Furukawa Electric Co Ltd:The Laminated circuit material
JP2006229174A (en) * 2005-02-21 2006-08-31 Furukawa Electric Co Ltd:The Anisotropic heat conducting material and heat transfer method using it

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10247708A (en) * 1997-03-04 1998-09-14 Akutoronikusu Kk Face-to-face heat conductive plate
JP2004193200A (en) * 2002-12-09 2004-07-08 Japan Science & Technology Agency Superlattice thermoelectric material
JP2004296629A (en) * 2003-03-26 2004-10-21 Matsushita Electric Ind Co Ltd Thermoelectric conversion material and manufacturing method therefor
JP2005251917A (en) * 2004-03-03 2005-09-15 Denso Corp Thermoelectric transducer
JP2005294321A (en) * 2004-03-31 2005-10-20 Furukawa Electric Co Ltd:The Laminated circuit material
JP2006229174A (en) * 2005-02-21 2006-08-31 Furukawa Electric Co Ltd:The Anisotropic heat conducting material and heat transfer method using it

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101847623A (en) * 2009-03-23 2010-09-29 丰田自动车株式会社 Power model
JP2012016935A (en) * 2010-07-09 2012-01-26 Nisshin Steel Co Ltd Anisotropy heat transfer body and production method thereof
KR20140127795A (en) * 2011-10-05 2014-11-04 사반치 유니버시티 Nanoplasmonic device with nanoscale cooling
JP2015503175A (en) * 2011-10-05 2015-01-29 サバンチ ユニバーシテシ Nano-plasmon device with nano-scale cooling function
KR101719886B1 (en) * 2011-10-05 2017-04-04 사반치 유니버시티 Nanoplasmonic device with nanoscale cooling
WO2015161051A1 (en) * 2014-04-18 2015-10-22 Laird Technologies, Inc. Thermal solutions and methods for dissipating heat from electronic devices using the same side of an anisotropic heat spreader
JP2019079880A (en) * 2017-10-23 2019-05-23 富士通オプティカルコンポーネンツ株式会社 Electronic device
JP7027801B2 (en) 2017-10-23 2022-03-02 富士通オプティカルコンポーネンツ株式会社 Electronics

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