JP2007197540A - Water-soluble washing film - Google Patents
Water-soluble washing film Download PDFInfo
- Publication number
- JP2007197540A JP2007197540A JP2006016976A JP2006016976A JP2007197540A JP 2007197540 A JP2007197540 A JP 2007197540A JP 2006016976 A JP2006016976 A JP 2006016976A JP 2006016976 A JP2006016976 A JP 2006016976A JP 2007197540 A JP2007197540 A JP 2007197540A
- Authority
- JP
- Japan
- Prior art keywords
- water
- soluble
- film
- cleaning film
- soluble cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 229920003002 synthetic resin Polymers 0.000 description 1
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- SWGJCIMEBVHMTA-UHFFFAOYSA-K trisodium;6-oxido-4-sulfo-5-[(4-sulfonatonaphthalen-1-yl)diazenyl]naphthalene-2-sulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(N=NC3=C4C(=CC(=CC4=CC=C3O)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C(S([O-])(=O)=O)C2=C1 SWGJCIMEBVHMTA-UHFFFAOYSA-K 0.000 description 1
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Images
Abstract
Description
この発明は、洗剤組成物が含有されてなる、水溶性洗浄用フィルムに関するものである。 The present invention relates to a water-soluble cleaning film comprising a detergent composition.
従来から、洗顔料、歯磨き剤あるいはその他の洗剤は、固形状、液状、ペースト状あるいは粉状といった種々の形体のものがあった。そして、これらの洗剤は、全量が専用の容器に入れられており、使用時に、これら洗剤を入れたそれぞれの容器から適当と思われる量を取り出して使用していた。 Conventionally, face wash, dentifrice or other detergents have various forms such as solid, liquid, paste or powder. And all of these detergents were put in a dedicated container, and at the time of use, an appropriate amount was taken out from each container containing these detergents and used.
従って、これら従来の洗剤は、一回一回使うときに、必要量以上に多くの洗剤を使用してしまったり、あるいは、必要量よりも少なかったりして、一定量だけの使用とか使用量の調整が容易ではなかった。 Therefore, when these conventional detergents are used once each time, more detergents are used than necessary, or less than necessary, so that only a certain amount of use or use amount is required. Adjustment was not easy.
この発明は、上記した従来の欠点を解決するためになされたものであり、その目的とするところは、一定量だけの使用とか使用量の調整が容易であり、しかも、フィルム形態でありながらも、洗浄力に優れた、水溶性洗浄用フィルムを提供することにある。 The present invention has been made in order to solve the above-mentioned conventional drawbacks, and the object of the present invention is to use only a certain amount or to adjust the amount of use, and in the form of a film. An object of the present invention is to provide a water-soluble cleaning film having excellent detergency.
この発明に係る水溶性洗浄用フィルムは、前記目的を達成するために、次の構成からなる。すなわち、
請求項１に記載の発明に係る水溶性洗浄用フィルムは、水溶性ポリマーと、少なくとも発泡性洗浄剤を成分とする洗剤組成物とを含有し、前記発泡性洗浄剤の含有量が、１５〜４５重量％であることを特徴としている。このように、この水溶性洗浄用フィルムは、高い濃度で発泡性洗浄剤を含有しているので、質量の小さなフィルム形態でありながらも、優れた洗浄力を備える。また、この水溶性洗浄用フィルムは、フィルムの大きさが同じであれば、その水溶性洗浄用フィルムに含まれる発泡性洗浄剤も同量であるので、常に同様の洗浄力を確保することができるとともに、フィルムの必要な枚数（個数）に基づく一定量だけの使用が容易である。さらに、洗浄力の調整をする際には、使用する水溶性洗浄用フィルムの枚数（個数）を増減させればよく、容易に使用量を調整することができる。なお、「フィルム」との用語は、広義の意味であって、特にシートと区別してその厚みを限定する趣旨のものではなく、例えば０．５ｍｍ程度の厚さのものであっても、この「フィルム」の概念に含まれるものとなる。
In order to achieve the object, the water-soluble cleaning film according to the present invention has the following configuration. That is,
The film for water-soluble cleaning according to the invention of
また、請求項２に記載の水溶性洗浄用フィルムのように、請求項１に記載の水溶性洗浄用フィルムにおいて、前記水溶性ポリマーの含有量が２５〜５５重量％であるのが望ましい。水溶性ポリマーの含有量が少ないと、フィルムの形成が不良となり、また、水溶性ポリマーの含有量が多いと、水への溶解性が低下してしまう虞があるが、水溶性ポリマーの含有量の範囲が２５〜５５重量％であるので、水溶性洗浄用フィルムは、水への溶解性に優れた洗浄用フィルムが形成されることとなる。
Further, like the water-soluble cleaning film according to
また、請求項３に記載の水溶性洗浄用フィルムのように、請求項２に記載の水溶性洗浄用フィルムにおいて、前記水溶性ポリマーがセルロース誘導体であるのが望ましい。このように、水溶性ポリマーがセルロース誘導体であると、セルロース誘導体が強靭なフィルムを形成する。
Further, like the water-soluble cleaning film according to
また、請求項４に記載の発明に係る水溶性洗浄用フィルムのように、請求項１ないし３のいずれか１項に記載の水溶性洗浄用フィルムにおいて、前記水溶性ポリマーおよび洗剤組成物のほかに、付着防止剤を含有していてもよい。これにより、湿度が高い環境下においても、水溶性洗浄用フィルム同士が付着するのを防ぐことができる。
Further, in the water-soluble cleaning film according to any one of
また、請求項５に記載の発明に係る水溶性洗浄用フィルムのように、請求項１ないし４のいずれか１項に記載の水溶性洗浄用フィルムにおいて、前記洗剤組成物が、歯磨き用洗剤組成物であってもよい。
Moreover, in the water-soluble cleaning film according to any one of
本願発明に係る水溶性洗浄用フィルムによれば、一定量だけの使用とか使用量の調整が容易であるとともに、フィルム形態でありながらも、洗浄力に優れる。 According to the water-soluble cleaning film according to the present invention, it is easy to use only a certain amount or to adjust the amount used, and it is excellent in detergency even though it is in a film form.
以下、本発明に係る水溶性洗浄用フィルムを実施するための最良の形態について、図面に基づいて説明する。 Hereinafter, the best mode for carrying out the water-soluble cleaning film according to the present invention will be described with reference to the drawings.
図１および図２は、本発明の一実施の形態を示す。図中符号１は、水溶性洗浄用フィルムであり、例えば、６０ミクロン程度の厚みを備えるとともに、矩形状、図示実施の形態においては、長方形状に形成されている。この水溶性洗浄用フィルム１は、水溶性ポリマーと、少なくとも発泡性洗浄剤を成分とする洗剤組成物と、付着防止剤とを含有している。
1 and 2 show an embodiment of the present invention.
水溶性ポリマーとしては、例えば、ヒドロキシプロピルメチルセルロース、カルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、メチルセルロース等のセルロース誘導体、プルラン、ペクチン、アラビノキシラン、大豆多糖類、ポリビニルピロリドン、ポリビニルアルコール、アルギン酸ナトリウム、ポリエチレングリコール、トラントガム、グァーガム、ローカストビーンガム、キサンタンガム、グルコマンナン、アラビアガム、ポリアクリル酸、メタクリル酸メチルコポリマー、カルボキシビニルポリマー、ヒドロキシプロピル化スターチ、カルボキシメチル化スターチ、オクテニルコハク酸スターチ、デキストリン、キチン、キトサン、レバン、エルシナン、コラーゲン、ゼラチン、ツェイン、グルテン、大豆タンパク質、カゼイン、アルブミン、および、それらの２種以上の混合物を使用することができる。その中でも、形成されるフィルムの強度が優れることから、セルロース誘導体、特に、ヒドロキシプロピルメチルセルロースあるいはカルボキシメチルセルロースを、好適に使用することができる。 Examples of the water-soluble polymer include cellulose derivatives such as hydroxypropylmethylcellulose, carboxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose, pullulan, pectin, arabinoxylan, soybean polysaccharide, polyvinylpyrrolidone, polyvinyl alcohol, sodium alginate, polyethylene glycol, Trant gum, guar gum, locust bean gum, xanthan gum, glucomannan, gum arabic, polyacrylic acid, methyl methacrylate copolymer, carboxyvinyl polymer, hydroxypropylated starch, carboxymethylated starch, octenyl succinic acid starch, dextrin, chitin, chitosan, levan , Erucinan, collagen, gelatin, zein Gluten, soy protein, casein, albumin, and can use them in a mixture of two or more. Among these, since the strength of the formed film is excellent, a cellulose derivative, particularly hydroxypropylmethylcellulose or carboxymethylcellulose can be preferably used.
この水溶性ポリマーの含有量は、水溶性洗浄用フィルム１の全体に対して、２５〜５５重量％、特に、３０〜５０重量％であるのが望ましい。水溶性ポリマーの含有量が、２５重量％より少ないと、フィルムの形成が不良となり、逆に、５５重量％より多いと、水への溶解性が低下してしまう虞がある。
The content of the water-soluble polymer is preferably 25 to 55% by weight, particularly 30 to 50% by weight, based on the entire water-
洗剤組成物は、例えば、衣類を洗うための洗濯用洗剤組成物であったり、顔を洗うための洗顔用洗剤組成物であったり、歯を磨くための歯磨き用洗剤組成物であったり、あるいはその他のものであったりしてもよい。すなわち、洗剤組成物は、少なくとも発泡性洗浄剤を成分として含んでいるものであればよく、水溶性洗浄用フィルム１で洗浄しようとする洗浄対象物にあわせて、発泡性洗浄剤以外の成分（例えば、香料、薬用成分あるいはその他の成分）を含んでいてもよい。
The detergent composition is, for example, a laundry detergent composition for washing clothes, a face washing detergent composition for washing the face, a toothpaste detergent composition for brushing teeth, or Others may be used. That is, the detergent composition only needs to contain at least an effervescent cleaning agent as a component, and in addition to the cleaning object to be cleaned with the water-
発泡性洗浄剤としては、ラウリル硫酸ナトリウム、ラウリルジメチルアミノ酢酸ベタイン、塩化ラウルトリメチルアンモニウム、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ＰＥＧ−２水添ヒマシ油、ココアンホ酢酸ナトリウム、ステアリン酸カリウム、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステル、ステアロイルグルタミン酸ナトリウム、Ｎ−ステアロイル−Ｎ−メチルタウリンナトリウム、ポリオキシエチレンアルキルエーテル、塩化ベンザルコニウム、ポリソルベート８０、ヤシ油脂肪酸ナトリウム、サポニン、レシチン、および、それらの２種以上の混合物を使用することができる。 Effervescent detergents include sodium lauryl sulfate, lauryl dimethylaminoacetic acid betaine, raurtrimethylammonium chloride, polyoxyethylene lauryl ether sodium sulfate, PEG-2 hydrogenated castor oil, sodium cocoamphoacetate, potassium stearate, sucrose fatty acid ester , Polyglycerol fatty acid ester, sodium stearoyl glutamate, sodium N-stearoyl-N-methyl taurate, polyoxyethylene alkyl ether, benzalkonium chloride, polysorbate 80, sodium coconut oil fatty acid, saponin, lecithin, and two or more thereof Can be used.
前記発泡性洗浄剤の含有量は、水溶性洗浄用フィルム１の全体に対して、１５〜４５重量％、好ましくは、２０〜４０重量％である。発泡性洗浄剤の含有量が、１５重量％より少ないと、洗浄力が劣り、逆に、４５重量％より多いと、フィルム化したときの柔軟性が低くなる。
The content of the foamable cleaning agent is 15 to 45% by weight, preferably 20 to 40% by weight, based on the entire water-
付着防止剤としては、水に不溶である結晶セルロースを好適に使用できる。この付着防止剤は、前記水溶性洗浄用フィルム１同士の付着を防止するために含有されるものであり、その含有量は、０．５〜１０重量％、特に、１〜４重量％であるのが望ましい。もっとも、付着防止剤は、上記のとおり、水溶性洗浄用フィルム１が、保存中に吸湿して互いに付着することを防止するためのものであり、水溶性洗浄用フィルム１を乾燥剤とともに容器に入れて保存する等の方法により、水溶性洗浄用フィルム１の吸湿を防ぐことができるのであれば、必ずしも含有されている必要はない。なお、水溶性洗浄用フィルム１同士の付着を防止するには、前述のように水溶性洗浄用フィルム１に付着防止剤を含有させる以外に、水溶性洗浄用フィルム１の表面にエンボス加工を施すようにしてもよい。また、水溶性洗浄用フィルム１の片方もしくは両方の表面が吸湿性の低いフィルム層で被われるように、水溶性洗浄用フィルム１を複層化することによっても付着を防止することができる。
As the adhesion preventing agent, crystalline cellulose that is insoluble in water can be suitably used. This anti-adhesive agent is contained to prevent the water-
この水溶性洗浄用フィルム１は、以下のように製造される。まず、水に、水溶性ポリマーと、洗剤組成物と、付着防止剤とを添加し、水溶性ポリマーを十分に溶解させて、塗工液を作製する。次に、この塗工液を、図２に示すように、ポリエチレンフィルムやポリプロピレンフィルム等の合成樹脂フィルムからなるベース材２上に塗布（前記塗工液を、前記ベース材上に塗布するには、コンマコーター機、ナイフコーター機等の各種コーター機を用いて塗布したり、グラビア印刷、シルク印刷、その他周知の印刷方法を用いて塗布したり、あるいは、刷毛、スプレー等で塗布してもよい。）し、温風または遠赤外線によって、乾燥させる。これにより、ベース材２上に塗布された塗工液は、フィルム状となり、水溶性洗浄用フィルム１となる。そして、この水溶性洗浄用フィルム１は、ベース材２から剥がすようにして巻き取られ、さらに一定の大きさにカットされた後、複数枚が一緒に容器に収容されることとなる。なお、図２は、水溶性洗浄用フィルム１とベース材２との位置関係を示すものであって、厚さについては、正確には示していない。
This water-
以上の構成からなる、水溶性洗浄用フィルム１によれば、次のような作用効果がある。この水溶性洗浄用フィルム１には、高い濃度で発泡性洗浄剤が含有されているので、質量の小さなフィルム形態でありながらも、優れた洗浄力を備える。また、水溶性洗浄用フィルム１は、フィルム状に形成されているので、例えば一定の大きさにカットしてケース等に収納するようにすれば、携帯に便利であり、また、携帯するにあたっては、必要量を簡単に分けることができるとともに、その分けた分量のみを持ち運ぶこともできる。また、水溶性洗浄用フィルム１の大きさが同じであれば、その水溶性洗浄用フィルム１に含まれる発泡性洗浄剤も同量であるので、常に同様の洗浄力を確保することができるとともに、フィルムの必要な枚数に基づく一定量だけの使用が容易である。さらに、洗浄力の調整をする際には、使用する水溶性洗浄用フィルム１の枚数を増減させればよく、容易に使用量を調整することができる。また、水溶性洗浄用フィルム１には、結晶セルロースからなる付着防止剤が含有されているので、水溶性洗浄用フィルム１同士が付着するのを抑えることができる。
The water-
なお、本発明は、上述した実施の形態に限定されるわけではなく、その他種々の変更が可能である。例えば、水溶性洗浄用フィルム１は、長方形状等の矩形状に形成されていなくても、円形状等のその他の形状であってもよい。また、この水溶性洗浄用フィルム１は、フィルム状のまま、例えば１〜５平方ミリメートル程度の大きさに粉砕して使用してもよく、この場合、粉石けんとは異なり飛散して顔や衣類などに付着するようなこともない。
水溶性洗浄用フィルム１の厚みも、前記した数値に限定されるわけではない。
The present invention is not limited to the above-described embodiment, and various other changes can be made. For example, the water-
The thickness of the water-
また、水溶性洗浄用フィルムには、水溶性ポリマー、洗剤組成物および付着防止剤以外に、可塑剤が含有されていてもよい。この可塑剤としては、グリセリン、プロピレングリコール、ポリエチレングリコール、ソルビトール、マルチトール、ラクチトール、エリスリトール、ブチレングリコールなどのポリオールを挙げることができる。前記可塑剤の含有量は、水溶性洗浄用フィルムの全体に対して、４〜２０重量％であることが望ましい。このように、水溶性洗浄用フィルムに可塑剤が含有されると、その水溶性洗浄用フィルムは、柔軟性を備えて破れにくくなる。 Further, the water-soluble cleaning film may contain a plasticizer in addition to the water-soluble polymer, the detergent composition and the anti-adhesion agent. Examples of the plasticizer include polyols such as glycerin, propylene glycol, polyethylene glycol, sorbitol, maltitol, lactitol, erythritol, and butylene glycol. The plasticizer content is preferably 4 to 20% by weight based on the entire water-soluble cleaning film. Thus, when a plasticizer is contained in the water-soluble cleaning film, the water-soluble cleaning film has flexibility and is difficult to break.
ところで、本発明の水溶性洗浄用フィルムに含有される洗剤組成物が、洗濯用洗剤組成物、洗顔用洗剤組成物、歯磨き用洗剤組成物、あるいは、その他のものであってもよいことは、前述したが、以下には、洗剤組成物が歯磨き用洗剤組成物である実施例について説明する。 By the way, the detergent composition contained in the water-soluble cleaning film of the present invention may be a laundry detergent composition, a face washing detergent composition, a toothpaste detergent composition, or other things. As described above, an example in which the detergent composition is a toothpaste detergent composition will be described below.
まず、水（イオン交換水）に、水溶性ポリマーと、歯磨き用洗剤組成物（発泡性洗浄剤、香料、甘味料および薬用成分からなる。）、付着防止剤および可塑剤を添加し、下記組成からなる塗工液を作製した。 First, water (ion-exchanged water) is added with a water-soluble polymer, a toothpaste detergent composition (consisting of a foaming detergent, a fragrance, a sweetener and a medicinal component), an anti-adhesive agent and a plasticizer. A coating solution consisting of
塗工液の組成
ヒドロキシプロピルメチルセルロース（水溶性ポリマー） １１．４重量％
微結晶セルロース（付着防止剤） ０．７１重量％
グリセリン（可塑剤） ３．００重量％
ラウリル硫酸ナトリウム（発泡性洗浄剤） １０．７重量％
サッカリンナトリウム（甘味料） ０．１４重量％
ペパーミントフレーバー（香料） ０．４３重量％
ｄ−α−トコフェロール製剤（薬用成分） ０．２５重量％
グリチルリチン酸ジカリウム（薬用成分） ０．０４３重量％
塩化セチルピリジウム（薬用成分） ０．００２５重量％
水（イオン交換水） 残量
Composition of coating solution Hydroxypropyl methylcellulose (water-soluble polymer) 11.4% by weight
Microcrystalline cellulose (anti-adhesive agent) 0.71% by weight
Glycerin (plasticizer) 3.00% by weight
Sodium lauryl sulfate (foaming detergent) 10.7% by weight
Saccharin sodium (sweetener) 0.14% by weight
Peppermint flavor (fragrance) 0.43% by weight
d-α-tocopherol preparation (medicinal ingredient) 0.25% by weight
Dipotassium glycyrrhizinate (medicinal ingredient) 0.043% by weight
Cetylpyridinium chloride (medicinal ingredient) 0.0025% by weight
Water (ion exchange water)
そして、前記塗工液を、ポリエチレンフィルムあるいはポリプロピレンフィルムからなるベース材上に塗布し、温風または遠赤外線によって、乾燥させることにより、前記ベースフィルム上に、下記組成からなる水溶性洗浄用フィルムを形成した。 And the said coating liquid is apply | coated on the base material which consists of a polyethylene film or a polypropylene film, and the water-soluble washing | cleaning film which consists of the following composition on the said base film by drying with warm air or far infrared rays. Formed.
水溶性洗浄用フィルムの組成
ヒドロキシプロピルメチルセルロース ３９．３重量％
微結晶セルロース ２．５重量％
グリセリン １０．４重量％
ラウリル硫酸ナトリウム ３６．９重量％
サッカリンナトリウム ０．４８重量％
ペパーミントフレーバー １．５重量％
ｄ−α−トコフェロール製剤 ０．８６重量％
グリチルリチン酸ジカリウム ０．１５重量％
塩化セチルピリジウム ０．００９重量％
水 残量
Composition of water-soluble cleaning film Hydroxypropyl methylcellulose 39.3% by weight
Microcrystalline cellulose 2.5% by weight
Glycerin 10.4% by weight
Sodium lauryl sulfate 36.9% by weight
Saccharin sodium 0.48% by weight
Peppermint flavor 1.5% by weight
d-α-tocopherol formulation 0.86% by weight
Dipotassium glycyrrhizinate 0.15% by weight
Cetylpyridium chloride 0.009% by weight
Water remaining
この水溶性洗浄用フィルムは、口の中に入れることで、唾液により溶解し、歯ブラシでブラッシングすることで、発泡して、歯を洗浄することができる。 This water-soluble cleaning film can be dissolved in saliva by being put in the mouth and foamed by brushing with a toothbrush to clean the teeth.
なお、この実施例においては、香料として、ペパーミントフレーバーを使用しているが、これ以外に、スペアミントなどのミント系フレーバーとか、シナモン、ジンジャーなどの香辛料系フレーバーとか、オレンジ、レモン、グレープフルーツ、シトラス、ライムなどの柑橘系フレーバーとか、ブルーベリー、アップル、ストロベリー、メロン、グレープ、バナナ、ピーチ、パイナップルなどのフルーツ系フレーバー等を使用することができる。 In this example, peppermint flavor is used as a flavor. Citrus flavors such as lime, fruit flavors such as blueberry, apple, strawberry, melon, grape, banana, peach and pineapple can be used.
前記甘味料としては、サッカリンナトリウム以外に、アスパルテーム、アセスルファムカリウム、スクラロース、ソーマチン、グリチルリチン酸二ナトリウム、ステビア抽出物、甘草抽出物、タウマチン、Ｄ−キシロース、エリスリトール、ソルビトール、マルチトール、キシリトール等を使用することができる。 As the sweetener, in addition to saccharin sodium, aspartame, acesulfame potassium, sucralose, thaumatin, disodium glycyrrhizinate, stevia extract, licorice extract, thaumatin, D-xylose, erythritol, sorbitol, maltitol, xylitol, etc. are used. be able to.
前記薬用成分としては、ｄ−α−トコフェロール製剤、グリチルリチン酸ジカリウム、塩化セチルピリジウム以外に、ポリエチレングリコール、リンゴ酸、酢酸トコフェロール、α−リポ酸、フラボノイド類、ビタミンＣ、コエンザイムＱ１０、ビタミンＡ、Ｌメントール、エッセンシャルオイル類、カテキン、ユーカリエキス、ローズマリーエキス、パラオキシ安息香酸メチル、キシリトール、ＣＰＰ−ＡＣＰ、ハイドロキシアパタイト、フクロノリ抽出物、フッ化カリウム、カミツレエキス、オウバクエキス、イラクサエキス、ラタニアチンキ、ミルラチンキ、甘草エキス、クチナシエキス、グリチルレチン酸ステアリル、デキストラナーゼ、フッ化ナトリウム、モノフルオロリ酸ナトリウム、水溶性コラーゲン、各種アミノ酸等を使用することができる。 Examples of the medicinal component include d-α-tocopherol preparation, dipotassium glycyrrhizinate, cetylpyridium chloride, polyethylene glycol, malic acid, tocopherol acetate, α-lipoic acid, flavonoids, vitamin C, coenzyme Q10, vitamin A, L menthol, essential oils, catechin, eucalyptus extract, rosemary extract, methyl paraoxybenzoate, xylitol, CPP-ACP, hydroxyapatite, fukuronori extract, potassium fluoride, chamomile extract, buckwheat extract, nettle extract, latania tincture, myrrh tincture, Use licorice extract, gardenia extract, stearyl glycyrrhetinate, dextranase, sodium fluoride, sodium monofluorophosphate, water-soluble collagen, various amino acids, etc. Can.
また、この実施例においては、歯磨き用洗剤組成物は、発泡性洗浄剤、香料、甘味料および薬用成分をその成分として含んでいるが、これら以外に、着色料、研磨剤、唾液促進剤、あるいはその他の成分、例えば、グルコシルトランスフェラーゼの活性阻害材としてのＩｇＹ（卵黄抗体）を含む卵黄粉末等を含んでいてもよい。特に、歯磨き用洗剤組成物の成分として、唾液促進剤が含まれると、水溶性洗浄用フィルムを口に含んだ際に、唾液の分泌が促進されて、そのフィルムが溶解し易くなる。この唾液促進剤の含有量は、水溶性洗浄用フィルムの全体に対して、１〜１０重量％であるのが望ましい。また、唾液促進剤としては、クエン酸、りんご酸、フマル酸、酒石酸、乳酸、アルコルビン酸、グルコン酸などの有機酸や、Ｌメントール等を使用することができる。 Further, in this example, the toothpaste detergent composition contains foaming detergent, fragrance, sweetener and medicinal component as its components, but in addition to these, coloring agent, abrasive, saliva promoter, Alternatively, other components such as egg yolk powder containing IgY (egg yolk antibody) as a glucosyltransferase activity inhibitor may be included. In particular, when a saliva promoter is included as a component of a toothpaste detergent composition, when a water-soluble cleaning film is included in the mouth, secretion of saliva is promoted and the film is easily dissolved. The content of the saliva promoter is desirably 1 to 10% by weight with respect to the entire water-soluble cleaning film. As saliva promoters, organic acids such as citric acid, malic acid, fumaric acid, tartaric acid, lactic acid, alcorbic acid and gluconic acid, L menthol and the like can be used.
前記着色料としては、食用赤色２号およびそのアルミニウムレーキ、食用赤色３号およびそのアルミニウムレーキ、食用赤色４０号およびそのアルミニウムレーキ、食用赤色１０２号、食用赤色１０４号、食用赤色１０５号、食用赤色１０６号、ムラサキイモ色素、クチナシ赤色素、エルダーベリー色素、シソ色素、ムラサキトウモロコシ色素、ブドウ果汁色素、ビートレッド、コチニール色素（中性）、ラック色素（中性）、ベニバナ赤色素、ベニコウジ色素、ボイセンベリー色素、アカネ色素、食用黄色４号およびそのアルミニウムレーキ、食用黄色５号およびそのアルミニウムレーキ、アナトー色素、水溶性アナトー、コチニール色素（酸性）、ラック色素（酸性）、トウガラシ色素、ウコン色素、オレンジ色素、クチナシ黄色素、トウモロコシ色素、にんじんカロテン、β−カロテン、ベニバナ黄色素、リボフラビン（ビタミンＢ２）、食用緑色３号およびそのアルミニウムレーキ、クロロフィリン、クロロフィル、銅クロロフィリンナトリウム、鉄クロロフィリンナトリウム、食用青色１号およびそのアルミニウムレーキ、食用青色２号およびそのアルミニウムレーキ、クチナシ青色素、スピルリナ色素、カカオ色素、タマネギ色素、カラメル色素、コウリャン色素、タマリンド色素等を使用することができる。
Examples of the colorant include food red No. 2 and its aluminum lake, food red No. 3 and its aluminum lake, food red No. 40 and its aluminum lake, food red No. 102, food red No. 104, food red No. 105, food red No. 106, purple potato pigment, gardenia red pigment, elderberry pigment, perilla pigment, purple corn pigment, grape juice pigment, beet red, cochineal pigment (neutral), lac pigment (neutral), safflower red pigment, red beetle pigment, Boysenberry dye, Akane dye, Food yellow No. 4 and its aluminum lake, Food yellow No. 5 and its aluminum lake, Anato dye, Water-soluble Anato, Cochineal dye (acidic), Lac dye (acidic), Pepper dye, Turmeric dye, Orange pigment, gardenia yellow, Sorghum pigment, carrot carotene, β-carotene, safflower yellow, riboflavin (vitamin B2),
また、研磨剤としては、重質炭酸カルシウム、酸化チタン等を使用することができる。 Moreover, heavy calcium carbonate, titanium oxide, etc. can be used as an abrasive | polishing agent.
なお、洗剤組成物が歯磨き用洗剤組成物である水溶性洗浄用フィルム１は、その大きさについては、歯ブラシのブラシ部の長さに合わせてカットするのが好ましい。この場合、例えば図３に示されるように、カットした水溶性洗浄用フィルム１を筒状に成形し、この筒状に成形した溶性洗浄用フィルム１ａ（１）を、歯ブラシ３、例えば使い捨て歯ブラシ３のブラシ部３ａに、そのブラシ部３ａを巻くような状態で装着する。そして、この歯ブラシ３を密封袋内に収めておく。歯ブラシ３を使用する際には、前記密封袋を開封して歯ブラシ３を取り出し、そのブラシ部３ａに巻かれた前記水溶性洗浄用フィルム１ａ（１）に水を付ければ、そのまま歯磨きを始めることができる。図中符号１ｂ（１）は、歯ブラシ３の柄部３ｂに装着した、予備用の水溶性洗浄用フィルムである。この実施の形態に示されるように、水溶性洗浄用フィルム１には、シート状、すなわち薄板状のもののみならず、そのシート状のものを立体的に形作ったものも含まれることとなる。
In addition, about the magnitude | size, it is preferable to cut the water-
１ 水溶性洗浄用フィルム
２ ベース材
1 Water-
Claims (5)
前記発泡性洗浄剤の含有量が、１５〜４５重量％であることを特徴とする、水溶性洗浄用フィルム。 A water-soluble cleaning film comprising a water-soluble polymer and a detergent composition containing at least a foamable cleaning agent as a component,
Content of the said foamable cleaning agent is 15 to 45 weight%, The film for water-soluble cleaning characterized by the above-mentioned.
The water-soluble cleaning film according to claim 1, wherein the detergent composition is a toothpaste detergent composition.
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