JP2006307032A - Bottom cover tape for small electronic part carrier - Google Patents

Bottom cover tape for small electronic part carrier Download PDF

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JP2006307032A
JP2006307032A JP2005131940A JP2005131940A JP2006307032A JP 2006307032 A JP2006307032 A JP 2006307032A JP 2005131940 A JP2005131940 A JP 2005131940A JP 2005131940 A JP2005131940 A JP 2005131940A JP 2006307032 A JP2006307032 A JP 2006307032A
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small electronic
copolymer resin
bottom cover
cover tape
adhesive layer
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Katsuzo Shimizu
勝三 清水
Masayoshi Ito
正義 伊東
Kentaro Ikeda
健太郎 池田
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LINE PLAST KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a bottom cover tape which is used for small electronic part carriers, ensures adhesiveness to paper carriers, has excellent antistaticity, and prevents the tape adhesion and corrosion of small electronic parts. <P>SOLUTION: This bottom cover tape for small electronic part carriers is characterized by comprising a laminate of a support, an adhesive layer, and an anti-static layer, wherein the adhesive layer comprises (A) 90 to 50 wt.% of a polyolefin-based resin as a base polymer and (B) 10 to 50 wt.% of one of ethylene-ethyl acrylate copolymer resin, ethylene-methyl methacrylate copolymer resin, and ethylene-ethyl methacrylate copolymer resin, or a copolymer comprising their mixture, having a monomer content; and the anti-static layer comprises an alkyl dimethylethylammonium ethosulfate. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

本発明はチップ型電子部品の搬送体に使用されるキャリアテープの底面を熱シールにて被覆する小型電子部品搬送体用ボトムカバーテープに関する。   The present invention relates to a bottom cover tape for a small electronic component carrier that covers a bottom surface of a carrier tape used for a chip type electronic component carrier with a heat seal.

従来、ICチップやコンデンサ等の小型電子部品等の搬送方法として、一定の幅であるテープ状厚紙をその長さ方向に一定の間隔で小型電子部品を収納する角穴を打ち抜いた紙キャリアと呼ばれるキャリアテープの底面を熱シールにてボトムカバーテープで被覆することで小型電子部品の収納部分を形成し、この部分に小型電子部品を収納した直後に紙キャリアの上面を熱シールにてトップカバーテープで被覆され、リール状に巻き取られて搬送される方法が一般的に採用されている。   Conventionally, as a method for transporting small electronic components such as IC chips and capacitors, it is called a paper carrier in which tape-like cardboard having a certain width is punched with square holes for accommodating small electronic components at regular intervals in the length direction. The bottom of the carrier tape is covered with a bottom cover tape with a heat seal to form a small electronic component storage part. Immediately after the small electronic component is stored in this part, the top surface of the paper carrier is heat sealed with a top cover tape. In general, a method in which the film is covered with, wound in a reel shape, and conveyed.

小型電子部品を使用する際には、トップカバーテープを剥離してエアノズルにて小型電子部品を吸着させて回路基板に装着するという自動組み入れシステムが主流となっている。   When using small electronic components, an automatic assembly system in which the top cover tape is peeled off and the small electronic components are adsorbed by an air nozzle and mounted on a circuit board has become the mainstream.

そして、搬送中に小型電子部品の振動により静電気が発生することで、小型電子部品がテープに付着し、保管環境(温度・湿度)によってテープの接着剤層への付着、また、テープによる小型電子部品の腐食という問題が発生している。帯電防止性や接着剤層への付着抑制に関する改善について数多くの提案がなされている(例えば、特許文献1,2参照。)。
特開2001−3014号公報 特開2003−292033号公報
Then, static electricity is generated by vibration of the small electronic components during transportation, so that the small electronic components adhere to the tape, adhere to the adhesive layer of the tape depending on the storage environment (temperature / humidity), and the small electronic components using the tape. There is a problem of corrosion of parts. Many proposals have been made on improvements relating to antistatic properties and adhesion suppression to the adhesive layer (see, for example, Patent Documents 1 and 2).
JP 2001-3014 A JP 2003-292033 A

しかしながら、ことに、近年は、小型電子部品が搬送中の振動により静電気が発生することでテープに付着したり、保管環境の変化により湿度が低下して帯電防止性能が不十分であったり、テープの接着剤層に付着することで、小型電子部品がエアノズルに吸着できない問題に加えて、テープによる小型電子部品の腐食という問題も発生している。   However, in particular, in recent years, static electricity has been generated due to vibrations caused by small electronic components being transported, and the antistatic performance has been insufficient due to a decrease in humidity due to changes in the storage environment. In addition to the problem that the small electronic component cannot be adsorbed to the air nozzle, the problem of corrosion of the small electronic component by the tape has also occurred.

本発明の目的は、紙キャリアヘの接着性を確保し、帯電防止性に優れ、小型電子部品のテープヘの付着や腐食を防止する小型電子部品搬送体用ボトムカバーテープを提供することにある。   An object of the present invention is to provide a bottom cover tape for a small electronic component transporter that ensures adhesion to a paper carrier, has excellent antistatic properties, and prevents adhesion of small electronic components to the tape and corrosion.

本発明は以下の構成を備えることにより上記課題を解決できる。   The present invention can solve the above-described problems by including the following configuration.

(1)支持体に接着剤層と帯電防止層の積層物であり、接着剤層が、(A)ベースポリマーとしてポリオレフィン系樹脂90〜50重量%と(B)10〜50重量%のモノマー含量5重量%以上のエチレンエチルアクリレート共重合樹脂、エチレンメチルメタアクリレート共重合樹脂、エチレンエチルメタクリレート共重合樹脂のいずれか1種か、またはそれらの混合物である共重合樹脂からなり、帯電防止層がアルキルジメチルエチルアンモニウムエトサルフェートからなることを特徴とする小型電子部品搬送体用ボトムカバーテープ。   (1) It is a laminate of an adhesive layer and an antistatic layer on a support, and the adhesive layer has a monomer content of (A) 90-50% by weight of a polyolefin resin as a base polymer and (B) a monomer content of 10-50% by weight. 5% by weight or more of an ethylene ethyl acrylate copolymer resin, an ethylene methyl methacrylate copolymer resin, an ethylene ethyl methacrylate copolymer resin, or a copolymer resin thereof, and the antistatic layer is alkyl. A bottom cover tape for a small electronic component carrier characterized by comprising dimethylethylammonium etosulphate.

(2)接着剤層の厚みが10〜50μmであることを特徴とする前記(1)記載の小型電子部品搬送体用ボトムカバーテープ。   (2) The bottom cover tape for a small electronic component carrier according to (1) above, wherein the adhesive layer has a thickness of 10 to 50 μm.

(3)帯電防止層の厚みが有効成分換算で0.01〜0.001μmであり、表面抵抗率において低湿度下(20%程度)でも10〜1012Ω/□の性能を保持することができる前記(1)又は(2)記載の小型電子部品搬送体用ボトムカバーテープ。 (3) The thickness of the antistatic layer is 0.01 to 0.001 μm in terms of active ingredient, and the surface resistivity is maintained at 10 8 to 10 12 Ω / □ even under low humidity (about 20%). The bottom cover tape for a small electronic component transport body according to the above (1) or (2).

本発明によれば、支持体をベースにして接着剤層と帯電防止層の三層で構成され、接着剤層が(A)ベースポリマーとしてポリオレフィン系樹脂と(B)モノマー含量5重量%以上のエチレンエチルアクリレート共重合樹脂、エチレンメチルメタアクリレート共重合樹脂、エチレンエチルメタクリレート共重合樹脂のいずれか1種か、またはそれらの混合物である共重合樹脂からなることで、紙キャリアヘの良好な熱接着性を確保しつつ、上記の共重合樹脂は金属接着に有利とされる酸基を含まないため、保管環境の変化により小型電子部品が接着剤層に付着しにくく、酸による腐食も防止できるとともに、帯電防止層のアルキルジメチルエチルアンモニウムエトサルフェートがハロゲンフリーであるため、長期にわたる搬送過程においてもまた、気温の急激な昇降条件の変化に対しても、小型電子部品を腐食させることもない。また、アルキルジメチルエチルアンモニウムエトサルフェートの性能として、低湿度下でも帯電防止性能が損なわれないため、常に小型電子部品の搬送を安全かつ品質保持を可能とすることができる。   According to the present invention, it is composed of three layers of an adhesive layer and an antistatic layer based on a support, and the adhesive layer is (A) a polyolefin resin as a base polymer and (B) a monomer content of 5% by weight or more. Good thermal adhesiveness to paper carrier by comprising a copolymer resin that is one of ethylene ethyl acrylate copolymer resin, ethylene methyl methacrylate copolymer resin, ethylene ethyl methacrylate copolymer resin, or a mixture thereof. As the above copolymer resin does not contain an acid group that is advantageous for metal bonding, small electronic components are less likely to adhere to the adhesive layer due to changes in the storage environment, and corrosion by acid can be prevented, Since the alkyldimethylethylammonium ethoxide in the antistatic layer is halogen free, And, even for a rapid change in elevation condition in temperature, never corrode small electronic components. In addition, as the performance of alkyldimethylethylammonium ethosulphate, since the antistatic performance is not impaired even under low humidity, it is always possible to safely transport and maintain the quality of small electronic components.

以下本発明を実施するための最良の形態を、実施例により詳しく説明する。   Hereinafter, the best mode for carrying out the present invention will be described in detail with reference to examples.

以下、図面を用いて本発明の構成について説明する。図1は本発明の構成を示す断面図である。1はボトムカバーテープ、2は支持体層、3は接着剤層、4は帯電防止層である。   The configuration of the present invention will be described below with reference to the drawings. FIG. 1 is a cross-sectional view showing the configuration of the present invention. 1 is a bottom cover tape, 2 is a support layer, 3 is an adhesive layer, and 4 is an antistatic layer.

支持体層2を構成するものは自己支特性を有するものであればよく、例えば、和紙、薄葉紙、混抄紙などの紙や、ポリエチレン、ポリプロピレンなどのオレフィン系樹脂からなる不織布があげられ、坪量として5〜100g/m、好ましくは10〜50g/mが好ましい。また、支持体層2の接着剤層側には投錨性を向上させるために表面処理が施されてもよく、コロナ処理などが一般的に用いられる手法である。さらには、支持体層1の接着剤層反対側に、必要に応じて帯電防止処理や保温処理なども施してもよい。 What constitutes the support layer 2 only needs to have a self-supporting property, and examples thereof include paper such as Japanese paper, thin paper, and mixed paper, and nonwoven fabric made of olefin resin such as polyethylene and polypropylene. 5 to 100 g / m 2 , preferably 10 to 50 g / m 2 . Further, a surface treatment may be applied to the adhesive layer side of the support layer 2 in order to improve anchoring properties, and a corona treatment or the like is a commonly used technique. Furthermore, an antistatic treatment, a heat retention treatment, or the like may be performed on the opposite side of the support layer 1 as necessary.

接着剤層3は、熱可塑性樹脂からなり、ベースポリマーであるポリオレフィン系樹脂とエチレン系共重合樹脂で構成され、具体的にベースポリマーとしては、低密度ポリエチレン、リニアー低密度ポリエチレン、メタロセン触媒系リニアー低密度ポリエチレンなどのいずれか1種か、またはそれらの混合物を使用する。エチレン系共重合樹脂としてはモノマー含量5重量%以上のエチレンエチルアクリレート共重合樹脂、エチレンメチルメタアクリレート共重合樹脂、エチレンエチルメタクリレート共重合樹脂のいずれか1種か、またはそれらの混合物を使用できる。エチレン系樹脂にはエチレン酢酸ビニル共重合樹脂、アイオノマー樹脂、エチレンアクリル酸共重合樹脂、エチレンメタクリル酸共重合樹脂などは金属に対する接着が優れているが、逆に小型電子部品が付着しやすい可能性や、熱分解等により発生する酸により金属を腐食させる可能性があることから、本発明には適さない。   The adhesive layer 3 is made of a thermoplastic resin, and is composed of a polyolefin resin as a base polymer and an ethylene copolymer resin. Specifically, the base polymer includes low density polyethylene, linear low density polyethylene, and metallocene catalyst linear. Any one such as low density polyethylene or a mixture thereof is used. As the ethylene copolymer resin, any one of ethylene ethyl acrylate copolymer resin, ethylene methyl methacrylate copolymer resin, ethylene ethyl methacrylate copolymer resin having a monomer content of 5% by weight or more, or a mixture thereof can be used. For ethylene resins, ethylene vinyl acetate copolymer resin, ionomer resin, ethylene acrylic acid copolymer resin, ethylene methacrylic acid copolymer resin, etc. have excellent adhesion to metals, but conversely, small electronic components may easily adhere. In addition, since there is a possibility that the metal is corroded by an acid generated by thermal decomposition or the like, it is not suitable for the present invention.

ベースポリマーとエチレン系共重合樹脂の配合量は、ベースポリマー90〜50重量%、エチレン系共重合樹脂10〜50重量%であり、好ましくはベースポリマー75〜60重量%、エチレン系共重合樹脂25〜40重量%程度で、接着剤層3の厚みは10〜50μm、好ましくは15〜35μmである。   The blending amount of the base polymer and the ethylene copolymer resin is 90 to 50% by weight of the base polymer and 10 to 50% by weight of the ethylene copolymer resin, preferably 75 to 60% by weight of the base polymer and 25 of the ethylene copolymer resin 25. The thickness of the adhesive layer 3 is about 10 to 50 μm, preferably 15 to 35 μm.

また、接着剤層3の支持体層1側には、投錨性を向上させるためオゾン処理等の表面処理を施してもよく、さらには必要に応じて接着剤層3の帯電防止層4側にコロナ処理等の表面処理を施してもよい。   Further, the support layer 1 side of the adhesive layer 3 may be subjected to surface treatment such as ozone treatment to improve anchoring properties, and further to the antistatic layer 4 side of the adhesive layer 3 as necessary. Surface treatment such as corona treatment may be applied.

帯電防止層4は、アルキルジメチルエチルアンモニウムエトサルフェートを用いる。アルキルジメチルエチルアンモニウムエトサルフェートはハロゲンフリーであるカチオン系帯電防止剤であるが、帯電防止剤層の厚みが有効成分換算で0.01〜0.001μmの塗布厚でも表面抵抗率が10〜1012Ω/□を確保することが可能であり、また低湿度下(20%程度)においても帯電防止性能損なわれない性能を保持している。塗布方法は特に限定するものではないが、高圧ノズルによる噴霧処理や遠心力による噴霧処理といった非接触塗布方法や、グラビアコート処理などがあげられる。 The antistatic layer 4 uses alkyldimethylethylammonium ethosulphate. Alkyldimethylethylammonium etosulphate is a halogen-free cationic antistatic agent, but the surface resistivity is 10 8 to 10 even when the thickness of the antistatic agent layer is 0.01 to 0.001 μm in terms of active ingredient. 12 Ω / □ can be ensured, and the antistatic performance is not impaired even under low humidity (about 20%). The application method is not particularly limited, and examples thereof include a non-contact application method such as a spray process using a high-pressure nozzle and a spray process using centrifugal force, and a gravure coat process.

また、帯電防止層4の塗布膜が極めて薄いことから、接着剤層の紙キャリアヘの熱シールによる接着力を妨げることもない。   Moreover, since the coating film of the antistatic layer 4 is extremely thin, the adhesive force of the adhesive layer by heat sealing to the paper carrier is not hindered.

つぎに、具体的な製造方法について以下に示す。   Next, a specific manufacturing method will be described below.

〔積層フィルムの作成〕
坪量14g/mの薄葉紙にコロナ処理を施した上に、ベースポリマーとして低密度ポリエチレン(スミカセンL−405(登録商標):住友化学)75重量%に対し、エチレン系共重合樹脂としてエチレンメチルメタアクリレート共重合樹脂(アクリフトWH302(登録商標):住友化学)を25重量%配合した接着剤層を、押出ラミネートにより20μmの厚さで積層した。その後に接着剤層にコロナ処理を施した上に、帯電防止層としてアルキルジメチルエチルアンモニウムエトサルフェートをグラビアコート処理にて、塗布厚0.005μmを積層したテープを得た。
[Creation of laminated film]
A corona treatment is applied to a thin paper having a basis weight of 14 g / m 2 , and 75% by weight of low density polyethylene (Sumikasen L-405 (registered trademark): Sumitomo Chemical) as a base polymer, and ethylene methyl as an ethylene copolymer resin. An adhesive layer containing 25% by weight of a methacrylate copolymer resin (ACRIFTH WH302 (registered trademark): Sumitomo Chemical) was laminated to a thickness of 20 μm by extrusion lamination. Thereafter, the adhesive layer was subjected to corona treatment, and a tape having a coating thickness of 0.005 μm was obtained by gravure coating treatment with alkyldimethylethylammonium ethosulphate as an antistatic layer.

実施例で得られたボトムカバーテープの接着剤層に、粒径1mm程度のニッケルを50個載せた上に、およそ150gの金属板を載せて荷重をかけて、80℃×90%の環境下に120時間放置して、ニッケルの腐食の確認や接着剤層への付着数を確認した。その結果、ニッケルの腐食、及び接着剤層への付着は認められなかった。   On the adhesive layer of the bottom cover tape obtained in the examples, 50 nickel particles having a particle diameter of about 1 mm were placed on top, and a load of about 150 g of a metal plate was applied to the adhesive layer in an environment of 80 ° C. × 90%. For 120 hours to confirm the corrosion of nickel and the number of adhesion to the adhesive layer. As a result, nickel corrosion and adhesion to the adhesive layer were not observed.

また、23℃×20%の環境下に120時間放置した後に表面抵抗率を確認したところ、10Ω/□の表面抵抗率を示した。 Further, when the surface resistivity was confirmed after being left in an environment of 23 ° C. × 20% for 120 hours, it showed a surface resistivity of 10 9 Ω / □.

図1においてそれぞれの層の厚さは以下の通りである。
1:ボトムカバーテープ(全体の厚さ) 40μm
2:支持体層 20μm(坪量14g/m
3:接着剤層 20μm
4:帯電防止層 0.005μm(有効成分換算)
なお、上記実施例は、単なる例示であり、接着層において(A)および(B)の重量%は、この範囲で好ましく、この範囲以外だと熱シールした際に接着剤層の低温熱シール機能や小型電子部品の付着抑制機能の低下のおそれ、コストメリットがなくなるなどの不具合が生じる。さらに支持体も強度を保持できる厚さが必要条件であり、材質により異なって一定しないと共に帯電防止層も亦、小型電子部品の大きさ、容積に関係するが必ずしも一定の条件には拘束されるものではない。
In FIG. 1, the thickness of each layer is as follows.
1: Bottom cover tape (total thickness) 40 μm
2: Support layer 20 μm (basis weight 14 g / m 2 )
3: Adhesive layer 20 μm
4: Antistatic layer 0.005 μm (in terms of active ingredient)
In addition, the said Example is a mere illustration, The weight% of (A) and (B) in an adhesive layer is preferable in this range, and when it heat-seals other than this range, the low-temperature heat sealing function of an adhesive bond layer In addition, there is a problem that the function of suppressing adhesion of small electronic components may be deteriorated and cost merit is lost. Furthermore, the thickness of the support is also a necessary condition, and the thickness of the support is not constant depending on the material. The antistatic layer is also related to the size and volume of the small electronic component, but is not necessarily restricted by certain conditions. It is not a thing.

本発明に係るボトムカバーテープの一部を拡大して示す模式断面図である。It is a schematic cross section which expands and shows a part of bottom cover tape which concerns on this invention.

符号の説明Explanation of symbols

1 ボトムカバーテープ
2 支持体層
3 接着剤層
4 帯電防止層
1 Bottom cover tape 2 Support layer 3 Adhesive layer 4 Antistatic layer

Claims (3)

支持体に接着剤層と帯電防止層の積層物であり、接着剤層が、(A)ベースポリマーとしてポリオレフィン系樹脂90〜50重量%と(B)10〜50重量%のモノマー含量5重量%以上のエチレンエチルアクリレート共重合樹脂、エチレンメチルメタアクリレート共重合樹脂、エチレンエチルメタクリレート共重合樹脂のいずれか1種か、またはそれらの混合物である共重合樹脂からなり、帯電防止層がアルキルジメチルエチルアンモニウムエトサルフェートからなることを特徴とする小型電子部品搬送体用ボトムカバーテープ。   It is a laminate of an adhesive layer and an antistatic layer on a support, and the adhesive layer comprises (A) a polyolefin resin 90 to 50% by weight as a base polymer and (B) a monomer content 5% by weight of 10 to 50% by weight. It consists of a copolymer resin that is one of the above-mentioned ethylene ethyl acrylate copolymer resin, ethylene methyl methacrylate copolymer resin, ethylene ethyl methacrylate copolymer resin, or a mixture thereof, and the antistatic layer is alkyldimethylethyl ammonium. A bottom cover tape for a small electronic component carrier characterized by comprising ethosulfate. 接着剤層の厚みが10〜50μmであることを特徴とする請求項1記載の小型電子部品搬送体用ボトムカバーテープ。   The thickness of an adhesive bond layer is 10-50 micrometers, The bottom cover tape for small electronic component conveyance bodies of Claim 1 characterized by the above-mentioned. 帯電防止層の厚みが有効成分換算で0.01〜0.001μmであり、表面抵抗率において低湿度下(20%程度)でも10〜1012Ω/□の性能を保持することができる請求項1又は2記載の小型電子部品搬送体用ボトムカバーテープ。 The thickness of the antistatic layer is 0.01 to 0.001 μm in terms of active ingredient, and the surface resistivity can maintain the performance of 10 8 to 10 12 Ω / □ even at low humidity (about 20%). Item 3. The bottom cover tape for a small electronic component carrier according to Item 1 or 2.
JP2005131940A 2005-04-28 2005-04-28 Bottom cover tape for small electronic part carrier Withdrawn JP2006307032A (en)

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JP2005131940A JP2006307032A (en) 2005-04-28 2005-04-28 Bottom cover tape for small electronic part carrier

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013133110A (en) * 2011-12-26 2013-07-08 Showa Denko Packaging Co Ltd Dust-free packaging bag excellent in automatic packaging aptitude
JP2013136405A (en) * 2011-12-28 2013-07-11 Showa Denko Packaging Co Ltd Clean packaging bag excellent in automatic packaging aptitude
JP2015047817A (en) * 2013-09-03 2015-03-16 日本マタイ株式会社 Bottom cover tape for conveyance of electronic part
CN106010322A (en) * 2015-03-25 2016-10-12 藤森工业株式会社 Antistatic surface protective film
CN106010323A (en) * 2015-03-25 2016-10-12 藤森工业株式会社 Antistatic surface protective film and optical part with same
JP2019199496A (en) * 2018-05-14 2019-11-21 東ソー株式会社 Easily peelable film and lid material

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013133110A (en) * 2011-12-26 2013-07-08 Showa Denko Packaging Co Ltd Dust-free packaging bag excellent in automatic packaging aptitude
JP2013136405A (en) * 2011-12-28 2013-07-11 Showa Denko Packaging Co Ltd Clean packaging bag excellent in automatic packaging aptitude
JP2015047817A (en) * 2013-09-03 2015-03-16 日本マタイ株式会社 Bottom cover tape for conveyance of electronic part
CN106010322A (en) * 2015-03-25 2016-10-12 藤森工业株式会社 Antistatic surface protective film
CN106010323A (en) * 2015-03-25 2016-10-12 藤森工业株式会社 Antistatic surface protective film and optical part with same
CN106010323B (en) * 2015-03-25 2020-09-18 藤森工业株式会社 Antistatic surface protective film and optical component with the same
JP2019199496A (en) * 2018-05-14 2019-11-21 東ソー株式会社 Easily peelable film and lid material
JP7095392B2 (en) 2018-05-14 2022-07-05 東ソー株式会社 Easy-to-peel film and lid material

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