JP2006219794A - Thread-winding body for artificial hair - Google Patents
Thread-winding body for artificial hair Download PDFInfo
- Publication number
- JP2006219794A JP2006219794A JP2005035900A JP2005035900A JP2006219794A JP 2006219794 A JP2006219794 A JP 2006219794A JP 2005035900 A JP2005035900 A JP 2005035900A JP 2005035900 A JP2005035900 A JP 2005035900A JP 2006219794 A JP2006219794 A JP 2006219794A
- Authority
- JP
- Japan
- Prior art keywords
- artificial hair
- fiber
- synthetic fiber
- wound
- wound body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 210000004209 hair Anatomy 0.000 title claims abstract description 34
- 238000004804 winding Methods 0.000 title abstract description 6
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 25
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 25
- 239000000835 fiber Substances 0.000 claims description 33
- 229920000728 polyester Polymers 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 description 13
- -1 polyethylene terephthalate Polymers 0.000 description 9
- 238000004043 dyeing Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 208000016261 weight loss Diseases 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000013585 weight reducing agent Substances 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- DOZGRCMRCPSZHG-UHFFFAOYSA-N 2-(4-benzoyl-3-hydroxyphenoxy)ethyl 2-methylprop-2-enoate Chemical compound OC1=CC(OCCOC(=O)C(=C)C)=CC=C1C(=O)C1=CC=CC=C1 DOZGRCMRCPSZHG-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- DCBNMBIOGUANTC-UHFFFAOYSA-N [5-[(5-benzoyl-4-hydroxy-2-methoxyphenyl)methyl]-2-hydroxy-4-methoxyphenyl]-phenylmethanone Chemical compound COC1=CC(O)=C(C(=O)C=2C=CC=CC=2)C=C1CC(C(=CC=1O)OC)=CC=1C(=O)C1=CC=CC=C1 DCBNMBIOGUANTC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 238000011946 reduction process Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- IMJYRYAZVATGLW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2,2-dimethylpropyl)phenol Chemical compound CC(C)(C)CC1=CC(CC(C)(C)C)=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IMJYRYAZVATGLW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- SCMSRHIBVBIECI-UHFFFAOYSA-N [2-hydroxy-4-(2-hydroxyethoxy)phenyl]-phenylmethanone Chemical compound OC1=CC(OCCO)=CC=C1C(=O)C1=CC=CC=C1 SCMSRHIBVBIECI-UHFFFAOYSA-N 0.000 description 1
- CHBCHAGCVIMDKI-UHFFFAOYSA-N [F].C=C Chemical compound [F].C=C CHBCHAGCVIMDKI-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 239000012796 inorganic flame retardant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012192 staining solution Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229920006312 vinyl chloride fiber Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
本願発明はかつら製造の機械化に好適な人工毛髪用巻き糸体に関するものであり、とくに全自動かつら製造機用に好適な人工毛髪用巻き糸体に関する。 The present invention relates to a wound body for artificial hair suitable for mechanization of wig production, and particularly to a wound body for artificial hair suitable for a fully automatic wig manufacturing machine.
従来、かつらの製造は立体形状に成形された厚手の母材にトウ条の植毛部材から所望の長さの人工毛髪または人毛を2本(2つ折りすると1本が2本になる)又は数本づつ束の状態で母材(一般的にはネット状物)に2つ折りにして一つ一つ人手により縫い付けまたは結ぶことにより植毛部材を植えつけていた。これらに用いる人工毛髪用繊維は、例えば特開昭63−12716号公報(特許文献1)に記載されているように104デニール程度の繊維束として取り扱うのが一般的である。 Conventionally, wigs have been manufactured by using two thick artificial hairs or human hairs of a desired length from a tow-shaped flocked member on a thick base material formed into a three-dimensional shape. In a state of being bundled one by one, the flocked member was planted by folding it into a base material (generally a net-like material) and sewing or tying it one by one by hand. The fiber for artificial hair used for these is generally handled as a fiber bundle of about 10 4 denier as described in, for example, JP-A-63-12716 (Patent Document 1).
しかし、このような手植え作業では例えば2万本の人口毛髪を2〜3週間位かかって植付けるのがせいぜいであり、作業効率が極端に悪いという欠点があった。またコスト高を避けるために人件費の安い海外で生産すると、不良品が多く発生し歩留まりが悪いという欠点があった。 However, in such a hand planting operation, for example, it is at most to plant 20,000 artificial hairs in about 2 to 3 weeks, and there is a disadvantage that the work efficiency is extremely poor. In addition, when manufacturing overseas where labor costs are low in order to avoid high costs, there are disadvantages that many defective products occur and the yield is poor.
そこで、かつら製造の機械化の方策が特開2003−105616号公報(特許文献2)などに示されている。しかし、人工毛髪を供給するボビンに関してはなんら記載がないのが実情である。 Therefore, a mechanization measure for manufacturing a wig is disclosed in Japanese Patent Laid-Open No. 2003-105616 (Patent Document 2). However, there is no description about bobbins for supplying artificial hair.
本願発明は上記背景のもとになされたもので、その目的とするところは、かつら製造の機械化のために好適な人工毛髪用巻き糸体を提供することにある。 The present invention has been made based on the above background, and an object thereof is to provide a wound body for artificial hair suitable for mechanization of wig production.
本発明者らは上記目的を達成するために鋭意検討した結果、ボビンまたは筒状体に合成繊維糸条が巻き付けられてなる巻き糸体であって、該合成繊維の巻き付け本数が5本以下である人工毛髪用巻き条体を用いることにより、かつら製造の機械化が可能となることを見出し、本発明に到達したものである。 As a result of intensive studies to achieve the above object, the inventors of the present invention are wound bodies in which a synthetic fiber yarn is wound around a bobbin or a tubular body, and the number of the synthetic fibers wound is 5 or less. It has been found that by using a certain wound body for artificial hair, mechanization of wig production becomes possible, and the present invention has been achieved.
本発明の人工毛髪用巻き糸体は5本以下の糸条がボビンまたは筒状物に連続的に巻かれているため、かつら製造用機械に供給することが可能であり、そうすることによって、初めて、自動的することが可能となり、かつら製造の大幅なコストダウンが可能となる。 Since the wound body for artificial hair of the present invention has 5 or less yarns continuously wound around a bobbin or a cylindrical object, it can be supplied to a wig manufacturing machine, and by doing so, For the first time, it is possible to automate, and the cost of manufacturing a wig can be greatly reduced.
本発明の合成繊維はポリエステル繊維、ナイロン繊維、アクリロニトリル系繊維、塩化ビニル繊維、塩化ビニリデン繊維、ポリオレフィン系繊維等、糸条が連続された合成繊維である必要がある。なかでも、取扱性、耐熱性の点から、ポリエステル繊維が好ましい。 The synthetic fiber of the present invention needs to be a synthetic fiber having continuous yarns such as polyester fiber, nylon fiber, acrylonitrile fiber, vinyl chloride fiber, vinylidene chloride fiber, and polyolefin fiber. Of these, polyester fibers are preferred from the viewpoints of handleability and heat resistance.
ポリエステルは、テレフタル酸を主たる二官能性カルボン酸とし、エチレングリコール、1,3-プロパンジオールまたは1,4-ブタンジオールを主たるグリコール成分とするポリエステル、具体的にはポリエチレンテレフタレート、ポリプロピレンテレフタレートまたはポリブチレンテレフタレートが好ましい。 Polyester is a polyester having terephthalic acid as the main difunctional carboxylic acid and ethylene glycol, 1,3-propanediol or 1,4-butanediol as the main glycol component, specifically polyethylene terephthalate, polypropylene terephthalate or polybutylene. Terephthalate is preferred.
これらのポリエステルには、本発明の目的を阻害しない範囲内、具体的には全酸成分に対して15モル%以下、好ましくは10モル%以下、特に好ましくは5モル%以下の共重合成分が共重合されていてもよい。好ましく用いられる共重合成分としては、2,6-ナフタレンジカルボン酸、4,4´-ジカルボキシフェノキシメタン、イソフタル酸、リン酸、ホスホン酸などの酸成分、ジエチレングリコール、ビスフェノール-AのEO付加物などのジオール成分を例示することができる。なかでも、難燃性の点から、リン酸、ホスホン酸などのリン化合物が好ましい。また、少量であればトリメシン酸、トリメリット酸、硼酸、グリセリン、トリメチロールプロパンなどの三官能性化合物を共重合したものであってもよい。 These polyesters have a copolymer component of 15 mol% or less, preferably 10 mol% or less, particularly preferably 5 mol% or less, based on the total acid component, within a range not impairing the object of the present invention. It may be copolymerized. Preferred copolymerization components include 2,6-naphthalenedicarboxylic acid, 4,4′-dicarboxyphenoxymethane, acid components such as isophthalic acid, phosphoric acid and phosphonic acid, diethylene glycol, EO addition product of bisphenol-A, etc. The diol component can be exemplified. Among these, phosphorus compounds such as phosphoric acid and phosphonic acid are preferable from the viewpoint of flame retardancy. Further, as long as the amount is small, a trifunctional compound such as trimesic acid, trimellitic acid, boric acid, glycerin, trimethylolpropane and the like may be copolymerized.
これらのポリエステルには、改質の目的で他の熱可塑性合成樹脂、例えばナイロン6、ナイロン6・6などのポリアミド類、ポリエチレン、ポリプロピレンなどのポリオレフィン類、ポリテトラフルオロエチレン、ポリフッ化ビニリデン、エチレン・テトラフルオロエチレンコポリマーなどの含フッ素ポリマー類などを、0.5〜50重量%の範囲で混合していてもよい。 These polyesters include other thermoplastic synthetic resins for modification purposes, such as polyamides such as nylon 6 and nylon 6/6, polyolefins such as polyethylene and polypropylene, polytetrafluoroethylene, polyvinylidene fluoride, ethylene Fluorine-containing polymers such as tetrafluoroethylene copolymer may be mixed in the range of 0.5 to 50% by weight.
さらに上記のポリエステル中には、使用中の人工毛髪の変褪色を防止する目的で公知の紫外線吸収剤を含有させてもよい。好ましく使用される紫外線吸収剤としては、例えば2,2-メチレンビス〔4-(1,1,3,3-テトラメチルブチル)-6-(2H-ベンゾトリアゾール-2-イル)フェノール、2-〔2-ヒドロキシ-3,5-ビス(α,α-ジメチルベンジル)フェニル〕-2H-ベンゾトリアゾール、2-(5-メチル-2-ヒドロキシフェニル)ベンゾトリアゾール、2-〔3,5-ビス(2,2-ジメチルプロピル)-2-ヒドロキシフェニル〕ベンゾトリアゾール、2-(3-ターシャリーブチル-5-メチル-2-ヒドロキシフェニル)-5-クロロベンゾトリアゾール、2-(3,5-ターシャリーブチル-2-ヒドロキシフェニル)-5-クロロベンゾトリアゾール、2-〔2-ヒドロキシ-3,5-ビス(α,α-ジメチルベンジル)フェニル〕-2H-ベンゾトリアゾールなどのベンゾトリアゾール系紫外線吸収剤、2-ヒドロキシ-4-(メタクリロイルオキシエトキシ)ベンゾフェノン30〜50モル%とメタクリル酸メチル70〜30モル%とのランダムコポリマー、2,4-ジヒドロキシベンゾフェノン、2,2’,4,4’-テトラヒドロキシベンゾフェノン、2-ヒドロキシ-4-(β-ヒドロキシエトキシ)-ベンゾフェノン、ビス(5-ベンゾイル-4-ヒドロキシ-2-メトキシフェニル)メタンなどのベンゾフェノン系紫外線吸収剤、酸化鉄微粒子などを例示することができる。なかでも、ビス(5-ベンゾイル-4-ヒドロキシ-2-メトキシフェニル)メタン、2,2-メチレンビス〔4-(1,1,3,3-テトラメチルブチル)-6-(2H-ベンゾトリアゾール-2-イル)フェノール、2-〔2-ヒドロキシ-3,5-ビス(α,α-ジメチルベンジル)フェニル〕-2H-ベンゾトリアゾール、酸化鉄微粒子などは、溶融状態のポリエステルに添加・混合する際の耐熱性が良好で高い耐光性が得られるので好ましい。また、2-ヒドロキシ-4-(メタクリロイルオキシエトキシ)ベンゾフェノン30〜50モル%とメタクリル酸メチル70〜30モル%とのランダムコポリマーは、高分子量なのでポリエステル繊維中からのブリードアウトが少なく、安定した耐光性が得られるので好ましい。なお、これらの各種紫外線吸収剤の2種以上を組み合わせて用いてもよい。 Further, the above polyester may contain a known ultraviolet absorber for the purpose of preventing discoloration of the artificial hair being used. As an ultraviolet absorber preferably used, for example, 2,2-methylenebis [4- (1,1,3,3-tetramethylbutyl) -6- (2H-benzotriazol-2-yl) phenol, 2- [ 2-hydroxy-3,5-bis (α, α-dimethylbenzyl) phenyl] -2H-benzotriazole, 2- (5-methyl-2-hydroxyphenyl) benzotriazole, 2- [3,5-bis (2 , 2-Dimethylpropyl) -2-hydroxyphenyl] benzotriazole, 2- (3-tertiarybutyl-5-methyl-2-hydroxyphenyl) -5-chlorobenzotriazole, 2- (3,5-tertiarybutyl) Benzotriazol such as 2-hydroxyphenyl) -5-chlorobenzotriazole, 2- [2-hydroxy-3,5-bis (α, α-dimethylbenzyl) phenyl] -2H-benzotriazole UV absorber, 2-hydroxy-4- (methacryloyloxyethoxy) benzophenone 30-50 mol% and methyl methacrylate 70-30 mol% random copolymer, 2,4-dihydroxybenzophenone, 2,2 ', 4 Benzophenone UV absorbers such as 4'-tetrahydroxybenzophenone, 2-hydroxy-4- (β-hydroxyethoxy) -benzophenone, bis (5-benzoyl-4-hydroxy-2-methoxyphenyl) methane, iron oxide fine particles, etc. Can be illustrated. Among them, bis (5-benzoyl-4-hydroxy-2-methoxyphenyl) methane, 2,2-methylenebis [4- (1,1,3,3-tetramethylbutyl) -6- (2H-benzotriazole- When 2-yl) phenol, 2- [2-hydroxy-3,5-bis (α, α-dimethylbenzyl) phenyl] -2H-benzotriazole, iron oxide fine particles, etc. are added to and mixed with molten polyester The heat resistance is favorable and high light resistance is obtained, which is preferable. In addition, a random copolymer of 2-hydroxy-4- (methacryloyloxyethoxy) benzophenone 30-50 mol% and methyl methacrylate 70-30 mol% has a high molecular weight, so there is little bleed out from the polyester fiber and stable light resistance. It is preferable because of its property. Two or more of these various ultraviolet absorbers may be used in combination.
また、使用中の火災による危険から人体を守るため、合成繊維中に燐系、ハロゲン系、三酸化アンチモンなどの公知の有機または無機質の難燃剤を含ませてもよい。また、繊維の帯電によるまとわり付きや絡まり、あるいは埃の付着を防止する目的で、合成繊維自体を変性しても良く、あるいは帯電防止剤を合成繊維中に配合してもよい。 Moreover, in order to protect a human body from the danger by the fire in use, you may include well-known organic or inorganic flame retardants, such as phosphorus type | system | group, halogen type | system | group, and antimony trioxide, in synthetic fiber. Further, the synthetic fiber itself may be modified or an antistatic agent may be blended in the synthetic fiber for the purpose of preventing clinging or entanglement due to charging of the fiber or adhesion of dust.
次に、本発明にかかるポリエステル繊維は、その繊維表面に凹部を有していることが好ましい。該凹部の形状は特に限定する必要はなく任意であるが、開口部の最大長(長手方向の径)は2〜20μmの範囲、特に5〜15μmの範囲である凹部が糸表面積100平方μm当たり10〜30個、特に10〜20個存在することが好ましい。 Next, it is preferable that the polyester fiber concerning this invention has a recessed part in the fiber surface. The shape of the recess is not particularly limited and is arbitrary, but the maximum length (diameter in the longitudinal direction) of the opening is in the range of 2 to 20 μm, particularly in the range of 5 to 15 μm. It is preferable that 10-30, especially 10-20 are present.
ここで、開口部の最大長および単位面積当たりの存在個数は、走査電子顕微鏡を用い、該繊維表面を1000倍の倍率で10視野撮影した写真から計測した値の平均値である。繊維表面に存在する凹部の数が100平方μm当たり10〜30個であっても、凹部を形成する開口部の最大長が2μm未満の場合には艶消し効果が低下する傾向にあり、逆に30μmを越える場合には繊維表面のざらつきが肉眼で分かるようになるだけでなく、糸物性も低下する場合がある。一方、凹部の開口部最大長が2〜30μmの範囲にあっても、該凹部の数が100平方μm当たり10個より少ない場合には艶消し効果が減少し、逆に30個を越える場合にはと艶がなくなりすぎて死毛調となりやすい。 Here, the maximum length of the opening and the number of existence per unit area are average values of values measured from photographs obtained by photographing 10 fields of the fiber surface at a magnification of 1000 using a scanning electron microscope. Even if the number of recesses present on the fiber surface is 10 to 30 per 100 square μm, the matte effect tends to be reduced when the maximum length of the opening forming the recess is less than 2 μm. When it exceeds 30 μm, not only the roughness of the fiber surface can be seen with the naked eye, but also the physical properties of the yarn may be lowered. On the other hand, even if the maximum length of the opening of the recess is in the range of 2 to 30 μm, the matting effect is reduced when the number of the recesses is less than 10 per 100 square μm, and conversely when the number exceeds 30. The luster is too thin and it tends to be dead.
ポリエステル繊維表面にこのような形状の凹部を形成する方法は特に限定されず、従来公知のブラスト加工、アルカリ減量加工法など任意の方法を採用することができる。なかでもポリエステル中に微細孔形成剤を含有させた繊維をアルカリ減量処理することにより、繊維表面に微細孔を形成させる方法が好ましい。 The method for forming the concave portion having such a shape on the surface of the polyester fiber is not particularly limited, and any known method such as a conventionally known blasting method or alkali weight reduction processing method can be employed. In particular, a method of forming fine pores on the fiber surface by subjecting a fiber containing a fine pore forming agent in polyester to an alkali weight reduction treatment is preferable.
微細孔形成剤としては、シリカゾル、酸化アルミニウムを含有する乾式法シリカ、粒子表面のシラノール基を封鎖した乾式法シリカ、アルミナゾル、微粒子状アルミナ、極微粒子状酸化チタン、微粒子状炭酸カルシウム、有機スルホン酸化合物などを例示することができ、これらの平均粒径、添加量、アルカリ減量処理条件を適宜選択することにより凹部の形状を制御することができる。なかでも、微細孔形成剤が金属を含有する化合物である場合には、アルカリ減量処理により良好な形状の凹部が形成できるので特に好ましい。 Fine pore forming agents include silica sol, dry silica containing aluminum oxide, dry silica with silanol groups blocked on the particle surface, alumina sol, fine alumina, ultrafine titanium oxide, fine calcium carbonate, organic sulfonic acid A compound etc. can be illustrated, The shape of a recessed part can be controlled by selecting these average particle diameters, addition amount, and alkali weight reduction process conditions suitably. Especially, when a micropore formation agent is a compound containing a metal, since the recessed part of a favorable shape can be formed by an alkali weight reduction process, it is especially preferable.
人工毛髪用合成繊維の繊度は特に規定する必要はないが、20〜110dtex、好ましくは30〜90dtexの範囲であることが、天然様の効果を発現させる点から望ましい。 The fineness of the synthetic fiber for artificial hair does not need to be specified in particular, but is preferably in the range of 20 to 110 dtex, preferably 30 to 90 dtex from the viewpoint of expressing a natural-like effect.
なお、本発明の人工毛髪用繊維の繊維横断面形状はいかなるものでもよく、例えば丸、楕円、3角、T、Y、H、+、5葉、6葉、7葉、8葉などの多葉形状、正方形、長方形、菱形、繭型、馬蹄型などを挙げることができ、さらには、これらの形状を一部変更したものであってもよい。なかでも、扁平断面形状であってクビレ度が1.5以上であるものは、櫛通り性や光沢の点からより好ましい。ここでクビレ度とは扁平断面形状において、最太部長さ/最狭部長さで表した値である。また、使用に当たっては、複数の断面形状の繊維を適宜組み合わせて用いることもできる。 In addition, the fiber cross-sectional shape of the fiber for artificial hair of the present invention may be any shape, for example, many such as circle, ellipse, triangle, T, Y, H, +5 leaves, 6 leaves, 7 leaves, 8 leaves, etc. A leaf shape, a square shape, a rectangular shape, a rhombus shape, a saddle shape, a horseshoe shape, and the like can be given. Furthermore, these shapes may be partially changed. Among these, those having a flat cross-sectional shape and a necking degree of 1.5 or more are more preferable from the viewpoint of combability and gloss. Here, the degree of necking is a value expressed by the length of the thickest part / the length of the narrowest part in the flat cross-sectional shape. In use, a plurality of cross-sectional fibers can be used in appropriate combination.
本発明にかかる合成繊維は、着色していなくても構わないが、必要に応じて染色処理を行なう。染料としては分散染料であっても構わないが、使用中の人工毛髪の変褪色の点から、耐光堅牢度が5級以上の染料を使用することが好ましい。染色の方法としては、公知の染色キャリヤー剤を併用してもよいが、染色キャリヤー剤を必要としない高圧染色法がより好ましい。なお、染色前の合成繊維中にはカーボンブラックなどの各種顔料が添加されていてもよく、この場合には染色時の染料が節約できるばかりでなく、用途によっては染色を行なう必要がなくなるので好ましい。 The synthetic fiber according to the present invention may not be colored, but is dyed as necessary. Although a disperse dye may be used as the dye, it is preferable to use a dye having a light fastness of 5 or higher from the viewpoint of discoloration of the artificial hair being used. As a dyeing method, a known dyeing carrier agent may be used in combination, but a high-pressure dyeing method that does not require a dyeing carrier agent is more preferable. In addition, various pigments such as carbon black may be added to the synthetic fiber before dyeing. In this case, not only can the dye at the time of dyeing be saved, but it is preferable because it is not necessary to dye depending on the use. .
次に、本発明にかかる合成繊維は5本以下の糸条がボビンまたは筒状体に巻き付けられている必要がある。従来、人毛が一定の限りのある長さであるものしか得ることが出来ないために、人工毛髪に用いる合成繊維も限りある長さで供給されており、これらのものでは、かつら製造用の機械に供給することは出来ない。 Next, the synthetic fiber according to the present invention needs to have five or less yarns wound around a bobbin or a cylindrical body. Conventionally, since only a certain length of human hair can be obtained, synthetic fibers used for artificial hair are also supplied in a limited length. It cannot be supplied to the machine.
一方、一般的に合成繊維を衣料用や産業資材用に用いる時の糸条本数は10本以上が一般的である。しかしかつら製造用の機械に用いる場合には、5本より多いと縫いつけ部が嵩張り、かつらにした時に不自然さを生じるために好ましくない。特に2本または3本の場合がより好ましい。 On the other hand, generally, the number of yarns when synthetic fibers are used for clothing or industrial materials is generally 10 or more. However, when it is used in a machine for manufacturing a wig, when the number is more than 5, it is not preferable because the sewn portion is bulky and unnatural when it is made into a wig. In particular, the case of 2 or 3 is more preferable.
また、本発明の合成繊維の糸長は、長ければ長い程、巻き糸体の交換頻度が少なくなり生産性が向上するが、その一方で、糸長が長くなると巻き糸体の重量が重くなり、取扱性がわるくなる。好ましくは、1km以上、特に好ましくは3〜20kmの範囲である。 In addition, the longer the yarn length of the synthetic fiber of the present invention, the less frequently the winding body is replaced and the productivity is improved. On the other hand, the longer the yarn length, the heavier the winding body weight. , Handling becomes difficult. Preferably, it is in the range of 1 km or more, particularly preferably 3 to 20 km.
以上に説明した本発明の人工毛髪用繊維は、ボビンまたは筒状物に5本以下の合成繊維糸条が巻き付けられている巻き糸体であるため、長時間安定してかつら製造することができる。 Since the artificial hair fiber of the present invention described above is a wound body in which 5 or less synthetic fiber yarns are wound around a bobbin or a cylindrical body, the wig can be manufactured stably for a long time. .
以下、実施例をあげて本発明をさらに具体的に説明する。
[実施例1]
ベンゼンスルホン酸ナトリウム-3,5-ジ(カルボン酸Mg1/2)をポリマー中に0.5%重量(テレフタル酸成分に対して0.34モル%)分散せしめた極限粘度(フェノールとテトラクロルエタン1:1の混合溶剤中25℃で測定)0.64のポリエチレンテレフタレートチップを真空下160℃で8時間乾燥した。該チップを、290℃でエクストルーダ型混練機、計量ギヤポンプおよび50メッシュのガラスビーズと150メッシュの金網よりなる濾過層を有する紡糸機を用い、孔径0.3mmの紡出孔を30ホール有する紡糸口金より溶融吐出し、紡糸口金下20cmの所で40℃温水で冷却後巻き取り紡糸原糸を得た。
Hereinafter, the present invention will be described more specifically with reference to examples.
[Example 1]
Intrinsic viscosity (phenol and tetrachloro) in which sodium benzenesulfonate-3,5-di (carboxylic acid Mg 1/2 ) is dispersed in a polymer by 0.5% by weight (0.34 mol% based on the terephthalic acid component) (Measured in a mixed solvent of ethane 1: 1 at 25 ° C.) A 0.64 polyethylene terephthalate chip was dried at 160 ° C. for 8 hours under vacuum. A spinneret having 30 holes of 0.3 mm diameter spinning holes using the tip at 290 ° C. using an extruder-type kneader, a metering gear pump, and a spinning machine having a filtration layer made of 50 mesh glass beads and 150 mesh wire mesh. It was further melted and discharged, and after being cooled with 40 ° C. hot water at a position 20 cm below the spinneret, a wound spinning yarn was obtained.
次いで70℃の温水中で4.0倍に延伸し、さらに8%のリラックス処理を施した後に600dtex/12filの延伸糸として巻取った。得られた延伸糸にN処理(NaOH50g/リットル水溶液中98℃下30分間処理)を加え、減量率10重量%のポリエステル繊維を得た。 Subsequently, the film was stretched 4.0 times in warm water at 70 ° C., further subjected to a relaxation treatment of 8%, and wound as a 600 dtex / 12 fil stretched yarn. N treatment (treatment at 98 ° C. for 30 minutes in a 50 g / liter aqueous solution of NaOH) was added to the obtained drawn yarn to obtain a polyester fiber having a weight loss rate of 10% by weight.
得られたポリエステル繊維の表面には、開口部の最大長が2μm以上、20μm以下の凹部が繊維表面積100平方μm当たり16個存在していた。また、繊維強度は3.36cN/dtex、単繊維繊度は58dtexであった。 On the surface of the obtained polyester fiber, there were 16 recesses having a maximum length of 2 μm or more and 20 μm or less per 100 square μm of fiber surface area. The fiber strength was 3.36 cN / dtex, and the single fiber fineness was 58 dtex.
この繊維を高圧スミス染色機を用い、下記に示す染色液にて浴比20:1、130℃で60分間の条件で染色を行ない、次いでハイドロサルファイト1.5g/リットル、苛性ソ-ダ1g/リットル、アミラジン1g/リットルを含む水溶液中、浴比20:1にて80℃下20分間還元洗浄を行なった。
(染色液)
Sumikasen Brown 2.5% owf
Miketon Polyster Black 0.3% owf
Dianix Fast Yellow 1.5% owf
Dianix Fast Dark Green 1.0% owf
This fiber was dyed with a dyeing solution shown below using a high-pressure Smith dyeing machine at a bath ratio of 20: 1 at 130 ° C. for 60 minutes, followed by hydrosulfite 1.5 g / liter, caustic soda 1 g. Reductive washing was carried out at 80 ° C. for 20 minutes in a bath ratio of 20: 1 in an aqueous solution containing 1 g / liter of amylazine / liter.
(Staining solution)
Sumikasen Brown 2.5% owf
Miketon Polyster Black 0.3% owf
Dianix Fast Yellow 1.5% owf
Dianix Fast Dark Green 1.0% owf
得られた人工毛髪用繊維を2糸条づつ両つば型のボビンに糸長5kmの長さで巻き取り、人工毛髪用巻き糸体を得た。
得られたボビンを特開2003−105616号公報記載のかつら製造用自動植毛機に設置し、かつらを10時間連続運転で製作した。糸切れによる低台もなく、非常に良好な状態であった。
The obtained artificial hair fiber was wound around a double-bottle bobbin with a length of 5 km by two yarns to obtain a wound body for artificial hair.
The obtained bobbin was installed in an automatic hair transplanter for manufacturing a wig described in JP-A-2003-105616, and the wig was produced by continuous operation for 10 hours. It was in a very good state with no low ground due to yarn breakage.
[比較例1]
得られた人工毛髪用繊維を6糸条づつ両つば型ボビンに糸長1.6kmの長さで巻き取り、人工毛髪巻き条体を得た。得られたボビンを実施例1と同様にかつら製造用自動植毛機に設置し運転した。運転可能時間は3時間20分しかなく、連続生産が出来ない状態であった。また、得られたかつらも均一性がなく、商品価値の非常に悪いものしか、出来なかった。
[Comparative Example 1]
The obtained fiber for artificial hair was wound around a double-bottle bobbin by 6 yarns at a length of 1.6 km to obtain an artificial hair wound body. The obtained bobbin was installed and operated in an automatic hair transplanter for wig production in the same manner as in Example 1. The operating time was only 3 hours and 20 minutes, and continuous production was not possible. Moreover, the obtained wig was not uniform and only a product having a very bad commercial value could be obtained.
本発明によれば、ボビンまたは筒状物に5本以下の合成繊維糸条が連続的に巻き付けられてなる、かつら製造の機械化のために好適な人工毛髪用巻き糸体が提供されるので、かつら製造の機械化、自動化が可能となる。 According to the present invention, there is provided a wound body for artificial hair suitable for mechanization of wig production, in which 5 or less synthetic fiber yarns are continuously wound around a bobbin or a cylindrical object. The mechanization and automation of wig production becomes possible.
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005035900A JP2006219794A (en) | 2005-02-14 | 2005-02-14 | Thread-winding body for artificial hair |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005035900A JP2006219794A (en) | 2005-02-14 | 2005-02-14 | Thread-winding body for artificial hair |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2006219794A true JP2006219794A (en) | 2006-08-24 |
Family
ID=36982301
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005035900A Pending JP2006219794A (en) | 2005-02-14 | 2005-02-14 | Thread-winding body for artificial hair |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2006219794A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06316802A (en) * | 1993-04-30 | 1994-11-15 | Teijin Ltd | Artificial hair |
JP2003105616A (en) * | 2001-09-28 | 2003-04-09 | Hochi Hiroshi | Automatic hair transplanter for producing wig and method for producing wig |
-
2005
- 2005-02-14 JP JP2005035900A patent/JP2006219794A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH06316802A (en) * | 1993-04-30 | 1994-11-15 | Teijin Ltd | Artificial hair |
JP2003105616A (en) * | 2001-09-28 | 2003-04-09 | Hochi Hiroshi | Automatic hair transplanter for producing wig and method for producing wig |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5813747B2 (en) | Cationic dyeable polyester fiber and composite fiber | |
EP3428328B1 (en) | Dyeable polyolefin fiber and fibrous structure comprising same | |
JP7332693B2 (en) | Conductive composite fiber and fiber structure using the same | |
KR20190067763A (en) | The polymeric fiber and the fiber structure made thereof | |
JP2018197403A (en) | Water-repellent woven/knitted fabric | |
JP2007146306A (en) | Artificial-hair fiber | |
JP3134421B2 (en) | Polyester monofilament bundle for artificial hair | |
JP6356976B2 (en) | Sea-island type composite fiber | |
JP2019094593A (en) | Core-in-sheath type composite fiber | |
JP5735844B2 (en) | Cationic dyeable polyester fibers and fiber aggregates with excellent dyeability | |
JP6129608B2 (en) | Polyester core-sheath type composite fiber excellent in permeation resistance and method for producing the same | |
JP6882942B2 (en) | Polyester-based composite fibers and fiber aggregates | |
JP5327411B1 (en) | Fiber, production method thereof, and water-repellent fabric | |
JP5065576B2 (en) | Artificial hair fiber | |
JP2006219794A (en) | Thread-winding body for artificial hair | |
JP2009299209A (en) | Sheath-core conjugate filament | |
JP4922668B2 (en) | Permeability woven and knitted fabric, production method thereof and textile | |
JP3175222B2 (en) | Artificial hair | |
JP5815450B2 (en) | Polyester latently crimped multifilament yarn and method for producing the same, dark-dyed fabric and method for producing the same | |
JP2011157647A (en) | Wiping cloth | |
JP2017078245A (en) | Synthetic fiber for artificial hair | |
JP5324360B2 (en) | Fabrics and textile products including core-sheath type composite false twisted yarn | |
JP2015121007A (en) | Polymethylpentene-based side-by-side-type composite fiber | |
JP2015067917A (en) | Photochromic polyvinyl alcohol fiber | |
JP2019090135A (en) | Nanovoid conjugate polyester fiber |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20071128 |
|
A977 | Report on retrieval |
Effective date: 20100929 Free format text: JAPANESE INTERMEDIATE CODE: A971007 |
|
A131 | Notification of reasons for refusal |
Effective date: 20101207 Free format text: JAPANESE INTERMEDIATE CODE: A131 |
|
A02 | Decision of refusal |
Effective date: 20110405 Free format text: JAPANESE INTERMEDIATE CODE: A02 |