JP2006148500A - Manufacturing method of inner shielding material - Google Patents

Manufacturing method of inner shielding material Download PDF

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JP2006148500A
JP2006148500A JP2004335214A JP2004335214A JP2006148500A JP 2006148500 A JP2006148500 A JP 2006148500A JP 2004335214 A JP2004335214 A JP 2004335214A JP 2004335214 A JP2004335214 A JP 2004335214A JP 2006148500 A JP2006148500 A JP 2006148500A
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steel strip
temper rolling
steel
rolling
steepness
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Kazuhiro Matsumoto
一洋 松本
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JFE Steel Corp
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JFE Steel Corp
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<P>PROBLEM TO BE SOLVED: To provide an inner shielding material manufacturing method preventing troubles in passing a material sheet through a plating line, and uniformizing plating quality without damaging its magnetic property as an inner shielding material. <P>SOLUTION: In the manufacturing method for inner shielding material which is plated on its surface and is used for magnetic shielding for cathode-ray tubes, a steel tape of low carbon steel or ultra low carbon steel is cold rolled, the steepness of this steel tape is adjusted to 0.3% or less by temper rolling after that, then continuous annealing is carried out, and subsequently this steel tape is plated on its surface. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は表面にメッキが施されたTVインナーシールド材の製造方法に関する。   The present invention relates to a method for manufacturing a TV inner shield material whose surface is plated.

TVの陰極線管に用いられるインナーシールド材は、地磁気ドリフトを防止するための磁気シールド材として用いられ、その特性として非履歴透磁率が高い必要がある。そのため、TVインナーシールド材は、焼鈍により十分に再結晶させる必要がある。また、防錆のため、表面にはCr、Ni等のメッキが施される。このようなTVインナーシールド材を製造する際、再結晶焼鈍は、バッチ式の箱焼鈍あるいは連続焼鈍により行われている。   An inner shield material used for a TV cathode ray tube is used as a magnetic shield material for preventing geomagnetic drift, and as its characteristics, it needs to have a high non-historical permeability. Therefore, the TV inner shield material needs to be sufficiently recrystallized by annealing. Moreover, Cr, Ni, etc. are plated on the surface for rust prevention. When manufacturing such a TV inner shield material, recrystallization annealing is performed by batch type box annealing or continuous annealing.

箱焼鈍の場合は、TVインナーシールド材は板厚が薄いため、焼鈍中に鋼板同士の焼付き、いわゆる密着が発生する場合がある。そこで、特開平6−36702号公報(特許文献1)には、箱焼鈍における密着防止のため、鋼板の表面粗さを所定の範囲内に調整して焼鈍を行うという技術が提案されている。一方、連続焼鈍の場合は、焼鈍中の鋼板の密着は原理的に起こらないので、表面粗さを所定範囲に調整する必要はない。   In the case of box annealing, the TV inner shield material has a thin plate thickness, so that seizure of the steel plates during annealing, so-called adhesion may occur. In view of this, Japanese Patent Laid-Open No. 6-36702 (Patent Document 1) proposes a technique of performing annealing by adjusting the surface roughness of a steel sheet within a predetermined range in order to prevent adhesion in box annealing. On the other hand, in the case of continuous annealing, there is no need for adjusting the surface roughness to a predetermined range because the adhesion of the steel sheet during annealing does not occur in principle.

一般の冷延鋼板の製造では、焼鈍後に通常、伸張率1.0〜2.0%程度の調質圧延が施される。しかし、TVインナーシールド材の製造では、磁気特性については焼鈍後に調質圧延を施すと歪が入るため透磁率が低下してしまう。そこで、TVインナーシールド材では、焼鈍を行ったままで、即ち調質圧延を行うことなく、製品としている。   In the production of a general cold-rolled steel sheet, temper rolling with an elongation of about 1.0 to 2.0% is usually performed after annealing. However, in the manufacture of the TV inner shield material, the magnetic properties are reduced when the temper rolling is performed after annealing, so that the magnetic permeability decreases. Therefore, the TV inner shield material is a product that is annealed, that is, not subjected to temper rolling.

例えば、特開平10−168551号公報(特許文献2)に記載の技術では、連続焼鈍により平均結晶粒径を3〜20μmに再結晶させた後、調質圧延を施すことなくCr又はNiメッキを施して製品とする技術が提案されている。
特開平6−36702号公報 特開平10−168551号公報
For example, in the technique described in JP-A-10-168551 (Patent Document 2), after recrystallizing the average crystal grain size to 3 to 20 μm by continuous annealing, Cr or Ni plating is performed without temper rolling. Techniques that are applied to produce products have been proposed.
JP-A-6-36702 Japanese Patent Laid-Open No. 10-168551

前記特許文献2に記載の発明が対象とするインナーシールド材は、メッキを施して製品とするものである。一般にメッキラインに通板される鋼帯は、焼鈍および調質圧延が施されており、通板の際の形状も良好である。従って、メッキラインは、通板される鋼帯の形状が良好であることを前提として設計されている。   The inner shield material targeted by the invention described in Patent Document 2 is a product obtained by plating. Generally, a steel strip passed through a plating line is annealed and temper-rolled, and the shape at the time of passing is good. Therefore, the plating line is designed on the assumption that the shape of the steel strip to be passed is good.

しかし、前記特許文献2に記載の技術では、調質圧延を省略しているため、メッキラインへ通板する鋼帯の形状は冷間圧延されたままであり、鋼帯の形状は必ずしも良くない場合がある。そのため、鋼帯をメッキラインに通板する際、鋼帯の形状不良により通板トラブルが発生しやすくなり、さらにメッキ品質の均一性が低下することとなる。   However, in the technique described in Patent Document 2, since temper rolling is omitted, the shape of the steel strip that passes through the plating line remains cold-rolled, and the shape of the steel strip is not necessarily good. There is. For this reason, when the steel strip is passed through the plating line, a trouble in passing the steel strip is liable to occur due to the defective shape of the steel strip, and the uniformity of the plating quality is further reduced.

また、インナーシールド材は、高い圧下率に加えて、高い板厚精度を要求され、板厚を均一にする必要がある。しかし高圧下率かつ板厚を均一化しようとすると、その反面、冷間圧延後の鋼帯の形状は一般に悪化する。そのため、メッキラインで通板トラブルが発生し易くなる。更に、能率面から連続焼鈍ラインにおける高速通板が要請される場合、走行が不安定となり、炉内での鋼帯の絞りの発生、さらには破断等の事故に繋がる場合もある。   Further, the inner shield material is required to have a high plate thickness accuracy in addition to a high rolling reduction, and it is necessary to make the plate thickness uniform. However, when trying to equalize the plateau thickness and plate thickness, the shape of the steel strip after cold rolling generally deteriorates. For this reason, it is easy for trouble to pass through the plating line. Furthermore, when high-speed threading in a continuous annealing line is required from the viewpoint of efficiency, running may become unstable, leading to the occurrence of steel strip drawing in the furnace, and even accidents such as fracture.

これらの問題に対しては、冷間圧延時の板の形状改善等の対策が必要であるが、それについては、前記特許文献2の従来技術には開示されていない。   For these problems, measures such as improvement of the shape of the plate at the time of cold rolling are required, but this is not disclosed in the prior art of Patent Document 2.

また、前記特許文献1に記載の技術は、表面粗さの制御については説明されているが、鋼板の形状については、焼鈍後の形状についてのみ触れられているに過ぎない。この技術では、焼鈍後にメッキラインに通板すると軟質であるため形状が悪くなるということから、焼鈍前にメッキラインに通板している。従って、この技術を、焼鈍後にメッキラインに通板する製造方法に適用することはできない。   Moreover, although the technique of the said patent document 1 is demonstrated about control of surface roughness, about the shape of a steel plate, only the shape after annealing is touched. In this technique, if the plate is passed through the plating line after annealing, the shape is deteriorated because it is soft, so the plate is passed through the plating line before annealing. Therefore, this technique cannot be applied to a manufacturing method of passing through a plating line after annealing.

さらに、前記特許文献2に記載の技術では、主として結晶粒径の調整方法について説明されており、鋼板の形状については一切触れられていない。そのため、この技術に基づき、メッキラインの通板トラブルやCAL高速通板時の走行不安定の問題に対処することは、困難である。   Furthermore, in the technique described in Patent Document 2, a method for adjusting the crystal grain size is mainly described, and the shape of the steel sheet is not mentioned at all. Therefore, based on this technology, it is difficult to cope with the trouble of passing through the plating line and the problem of unstable running at the time of CAL high-speed passing.

また、一般に、冷間圧延後の鋼帯には、圧延油ムラ(鋼板表面の圧延油の残存ピット模様)や酸洗不良等によるスケール残りの痕などが発生する。このような冷間圧延時に発生する特に模様状の鋼板の表面性状不良は、その後に調質圧延を行うことにより軽減されるが、調質圧延を行わないこれらの技術ではこのような問題が避けられない。   Further, in general, in the steel strip after the cold rolling, rolling oil unevenness (remaining pit pattern of the rolling oil on the surface of the steel plate), traces of residual scale due to pickling failure, and the like are generated. Such poor surface properties of the steel sheet with a particular pattern that occur during cold rolling are alleviated by subsequent temper rolling, but these techniques that do not perform temper rolling avoid such problems. I can't.

そこで、本発明は、インナーシールド材としての磁気特性を損なうことなく、且つ、メッキラインにおける通板トラブルの発生を防止し、メッキ品質を均一化することが可能なインナーシールド材の製造方法を提供することを目的とする。   Accordingly, the present invention provides a method for manufacturing an inner shield material that can prevent the occurrence of plate-passing troubles in the plating line and make the plating quality uniform without impairing the magnetic properties of the inner shield material. The purpose is to do.

上記の課題は次の発明により解決される。
[1]陰極線管の磁気シールドに使用される表面にメッキが施されたインナーシールド材の製造方法において、低炭素鋼または極低炭素鋼の鋼帯を冷間圧延した後、調質圧延によりこの鋼帯の急峻度を0.3%以下に調整し、次いで連続焼鈍を行い、その後この鋼帯の表面にメッキを施すことを特徴とするインナーシールド材の製造方法。
The above problems are solved by the following invention.
[1] In a method for producing an inner shield material having a plated surface used for a magnetic shield of a cathode ray tube, a steel strip of low carbon steel or ultra low carbon steel is cold-rolled and then subjected to temper rolling. A method for producing an inner shield material, characterized in that the steepness of a steel strip is adjusted to 0.3% or less, followed by continuous annealing, and then plating the surface of the steel strip.

この発明は、冷間圧延後の鋼帯を調質圧延により急峻度を調整することを特徴とする。このように、鋼帯の形状である急峻度を所定の範囲内に調整することにより、通板トラブルを起こすことなくメッキラインに通板することが可能となる。また、急峻度の調整を連続焼鈍の前に行うことにより、インナーシールド材としての磁気特性を損なうことなく、鋼帯の形状を改善できる。   The present invention is characterized in that the steepness of the steel strip after cold rolling is adjusted by temper rolling. In this way, by adjusting the steepness, which is the shape of the steel strip, within a predetermined range, it is possible to pass through the plating line without causing a plate passing trouble. Moreover, by adjusting the steepness before the continuous annealing, the shape of the steel strip can be improved without impairing the magnetic properties as the inner shield material.

図1にメッキラインにおける通板鋼帯の急峻度とライン張力との関係における板絞り発生状況の一例を示す。ここで、前記板絞りとは、通板鋼帯の形状不良(中伸・耳波)がある場合に、ライン張力によりその形状不良部が座屈し、鋼帯にシワやワレが発生する状況をいう。   FIG. 1 shows an example of the state of occurrence of plate drawing in the relationship between the steepness of the sheet steel strip in the plating line and the line tension. Here, the plate diaphragm refers to a situation in which, when there is a shape defect (medium extension / ear wave) of a sheet steel strip, the shape defect portion buckles due to line tension, and the steel strip is wrinkled or cracked. Say.

一般にメッキラインにおけるライン張力は単位面積当りで1.0〜2.0kg/mm程度である。この場合、図1より通板する鋼帯の急峻度を0.3%以下とすれば板絞りの発生を防止できることがわかる。 Generally, the line tension in the plating line is about 1.0 to 2.0 kg / mm 2 per unit area. In this case, it can be seen from FIG. 1 that the occurrence of plate drawing can be prevented if the steepness of the steel strip passing through is set to 0.3% or less.

ここで、調質圧延により鋼帯に歪みが発生するが、それは連続焼鈍で再結晶化させることにより解消することができる。また、冷間圧延の際に発生した表面欠陥も、調質圧延を行うことにより軽減することができる。その結果、メッキラインにおける通板トラブルの発生が防止され、メッキ品質を均一化することが可能となる。   Here, although the steel strip is distorted by temper rolling, it can be eliminated by recrystallization by continuous annealing. Moreover, the surface defect which generate | occur | produced in the case of cold rolling can also be reduced by performing temper rolling. As a result, it is possible to prevent the occurrence of plate troubles in the plating line and make the plating quality uniform.

なお、上記低炭素鋼または極低炭素鋼とは、Cを質量%で0.001〜0.08%含有するものを指す。   In addition, the said low carbon steel or extremely low carbon steel refers to what contains 0.001 to 0.08% of C by mass%.

本発明によれば、インナーシールド材の冷間圧延後の鋼帯を調質圧延して急峻度を調整することにより、通板トラブルを起こすことなくメッキラインに通板することができる。また、連続焼鈍の前に調質圧延を施しているので、インナーシールド材としての磁気特性を損なうことなく、鋼帯の形状を改善できる。   According to the present invention, the steel strip after the cold rolling of the inner shield material is temper-rolled and the steepness is adjusted, so that the plate can be passed through the plating line without causing troubles. Further, since the temper rolling is performed before the continuous annealing, the shape of the steel strip can be improved without impairing the magnetic properties as the inner shield material.

発明の実施に当たっては、冷間圧延まではインナーシールド材の通常の製造方法と同様の条件で製造することができる。   In carrying out the invention, it can be manufactured under the same conditions as in the normal manufacturing method of the inner shield material until cold rolling.

通常の冷間圧延後の鋼帯は、急峻度λが1%前後あるいはそれ以上の場合があり、このままではメッキラインの通板トラブルが発生する恐れがある。そこで、上記のように急峻度を0.3%以内となるよう調質圧延を実施する。   A steel strip after normal cold rolling may have a steepness λ of about 1% or more, and there is a risk that a plate line trouble may occur in this state. Therefore, temper rolling is performed so that the steepness is within 0.3% as described above.

急峻度を上記範囲内に抑える場合、調質圧延の条件は通常の焼鈍後の鋼帯(以下、「焼鈍板」という。)の条件とは異なり、伸張率、圧延荷重およびライン張力は焼鈍板よりかなり低目(圧延荷重0.5T/mm以下、張力15kg/mm以下)で十分となる。 When the steepness is kept within the above range, the conditions for temper rolling are different from the conditions for steel strip after normal annealing (hereinafter referred to as “annealed plate”), and the elongation, rolling load and line tension are annealed. A considerably lower level (rolling load of 0.5 T / mm or less, tension of 15 kg / mm 2 or less) is sufficient.

調質圧延は通常の焼鈍板の処理が可能な設備であれば、本発明に係るインナーシールド材の処理は可能であるが、調質圧延の条件は大幅に変更する必要がある。調質圧延の条件に関しては、通常は、目標の伸張率、転写率を得るために、荷重、張力を調整するが、本発明では、荷重、張力の調整を急峻度の調整のために行う。そのため、伸張率の値については特に限定されず、形状を矯正できればよい。この場合、伸張率は、通常の目標伸張率が1〜3%程度であるのに対して、本発明においては0.3〜0.5%程度でよい。それ以上の伸張率にするのは、冷間圧延後の鋼帯は硬質なため困難を伴い、またその必要もない。   If the temper rolling is a facility capable of processing a normal annealed sheet, the inner shield material according to the present invention can be processed, but the condition of the temper rolling needs to be significantly changed. Regarding the condition of temper rolling, the load and tension are usually adjusted to obtain the target elongation rate and transfer rate, but in the present invention, the load and tension are adjusted to adjust the steepness. Therefore, the value of the expansion rate is not particularly limited as long as the shape can be corrected. In this case, the expansion rate may be about 0.3 to 0.5% in the present invention, while the normal target expansion rate is about 1 to 3%. It is difficult to make the elongation ratio higher than that, because the steel strip after cold rolling is hard and difficult.

調質圧延時の荷重は、急峻度の観点から設定されるので、通常の焼鈍板の調質圧延時の荷重に比べて低くてよい。また、形状改善の観点からも、荷重を低目とした方が形状調整がしやすいという利点を有する。   Since the load during temper rolling is set from the viewpoint of steepness, it may be lower than the load during temper rolling of a normal annealed sheet. Also, from the viewpoint of shape improvement, it is advantageous that shape adjustment is easier when the load is low.

なお、表面粗さの転写率については荷重に大きく依存し、荷重を低目とすることにより転写率は低目となる。従って、それを考慮に入れて、ロールの表面粗さを設定しておくことが望ましい。   Note that the transfer rate of the surface roughness greatly depends on the load, and the transfer rate becomes low by reducing the load. Therefore, it is desirable to set the surface roughness of the roll taking this into consideration.

このように、インナーシールド材の冷間圧延後の調質圧延は、形状矯正を目的とする。その結果、通常の焼鈍板より荷重や張力等の観点から見て、比較的軽い調質圧延で済み、設備の小型化が可能である。また、設備が同一であれば、ライン速度が高速化できるので、連続焼鈍ラインの通板速度に合わせて制御することが可能であり、高能率化を図ることが可能となる。   Thus, the temper rolling after the cold rolling of the inner shield material aims at shape correction. As a result, temper rolling is comparatively lighter from the viewpoint of load, tension and the like than a normal annealing plate, and the equipment can be downsized. Further, if the facilities are the same, the line speed can be increased, so that it can be controlled in accordance with the sheet passing speed of the continuous annealing line, and high efficiency can be achieved.

質量%で、C:0.01〜0.06%、Si:0.03%以下、Mn:0.10〜0.05%、P:0.02%以下、S:0.01〜0.025%、N:0.0035%以下を含有し、冷間圧延後の鋼帯の形状が急峻度λ=1.0%の薄鋼板に対し、焼鈍前に調質圧延を施し、その後に焼鈍を行った。調質圧延は2スタンドの調質圧延機を用いて実施した。調質圧延の条件を表1に示す。なお、比較例1として、焼鈍後に調質圧延を施した通常のブリキ材の場合を示す。   In mass%, C: 0.01 to 0.06%, Si: 0.03% or less, Mn: 0.10 to 0.05%, P: 0.02% or less, S: 0.01 to 0.00. 025%, N: 0.0035% or less, thin steel plate with a steepness of λ = 1.0% after cold rolling is subjected to temper rolling before annealing, and then annealed Went. The temper rolling was carried out using a two-stand temper rolling mill. Table 1 shows the conditions for temper rolling. In addition, as a comparative example 1, the case of the normal tinplate which gave temper rolling after annealing is shown.

Figure 2006148500
Figure 2006148500

調質圧延後の薄鋼板について、急峻度の測定を行った。測定結果を表1に併せて示す。なお、メッキラインの装入に必要な形状は、急峻度λ≦0.3%である。   The steepness of the thin steel plate after temper rolling was measured. The measurement results are also shown in Table 1. The shape necessary for charging the plating line has a steepness λ ≦ 0.3%.

この表より、本発明例では、比較例1と比べて、1/2〜1/3の圧延荷重で、0.3%以下の急峻度λが得られることがわかる。また、ミル出側張力も1/2以下で済み、調質圧延機の荷重、出側設備の張力等、通常のブリキ材の調質圧延設備に比べて、半分以下の設備能力でよいことがわかる。さらに、焼鈍後に調質圧延を施した比較例1は所望の磁気特性が得られなかったのに対し、発明例では良好な磁気特性が得られたことがわかる。   From this table, it can be seen that, in the example of the present invention, a steepness λ of 0.3% or less is obtained at a rolling load of 1/2 to 1/3 as compared with Comparative Example 1. Moreover, the mill exit side tension may be less than 1/2, and the load capacity of the temper rolling mill, the tension of the exit side equipment, etc., may be less than half of the equipment capacity compared to normal tin temper rolling equipment. Recognize. Furthermore, it can be seen that Comparative Example 1 in which temper rolling was performed after annealing did not obtain the desired magnetic properties, whereas the inventive examples obtained good magnetic properties.

次に、このようにして得られた薄鋼板を、メッキラインに通板した。その際のメッキラインにおける通板速度を表2に示す。なお、比較例2として、調質圧延を行わない場合を併せて示す。なお、調質圧延を行わない場合の急峻度λは約1.0%であった。   Next, the thin steel plate thus obtained was passed through a plating line. Table 2 shows the plate passing speed in the plating line at that time. In addition, as the comparative example 2, the case where temper rolling is not performed is also shown. Note that the steepness λ when the temper rolling was not performed was about 1.0%.

Figure 2006148500
Figure 2006148500

この表より、調質圧延を行わない比較例2と比べて、本発明例では、形状が良好なために、通板トラブルを防止することができ、メッキラインの通板速度を3倍以上高速にすることができたことがわかる。さらに、調質圧延を行わない比較例2は、冷間圧延時に発生する模様状の表面欠陥がメッキ後にも見られたが、本発明例では表面性状も良好であった。   From this table, compared with Comparative Example 2 in which temper rolling is not performed, in the present invention example, the shape is good, so that it is possible to prevent the trouble of threading, and the speed of threading of the plating line is three times faster. You can see that Further, in Comparative Example 2 in which temper rolling was not performed, pattern-like surface defects generated during cold rolling were observed after plating, but in the present invention example, the surface properties were also good.

メッキラインにおける通板鋼帯の急峻度とライン張力との関係における板絞り発生状況の一例を示す図である。It is a figure which shows an example of the sheet | seat drawing generation | occurrence | production situation in the relationship between the steepness of the sheet steel strip in a plating line, and line tension.

Claims (1)

陰極線管の磁気シールドに使用される表面にメッキが施されたインナーシールド材の製造方法において、低炭素鋼または極低炭素鋼の鋼帯を冷間圧延した後、調質圧延によりこの鋼帯の急峻度を0.3%以下に調整し、次いで連続焼鈍を行い、その後この鋼帯の表面にメッキを施すことを特徴とするインナーシールド材の製造方法。   In a method for producing an inner shield material with a plated surface used for a magnetic shield of a cathode ray tube, after cold rolling a steel strip of low carbon steel or extremely low carbon steel, the steel strip is subjected to temper rolling. A method for producing an inner shield material, characterized in that the steepness is adjusted to 0.3% or less, followed by continuous annealing, and then plating the surface of the steel strip.
JP2004335214A 2004-11-19 2004-11-19 Manufacturing method of inner shielding material Pending JP2006148500A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009209382A (en) * 2008-02-29 2009-09-17 Jfe Steel Corp Cold rolled steel sheet having excellent surface quality after molding, and method for producing the same
JP2014208894A (en) * 2013-03-28 2014-11-06 Jfeスチール株式会社 Steel sheet for can excellent in processability and surface roughing resistance and manufacturing method therefor
JP2017179558A (en) * 2016-03-31 2017-10-05 古河電気工業株式会社 Metallic material for thin film plating and method for producing the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009209382A (en) * 2008-02-29 2009-09-17 Jfe Steel Corp Cold rolled steel sheet having excellent surface quality after molding, and method for producing the same
JP2014208894A (en) * 2013-03-28 2014-11-06 Jfeスチール株式会社 Steel sheet for can excellent in processability and surface roughing resistance and manufacturing method therefor
JP2017179558A (en) * 2016-03-31 2017-10-05 古河電気工業株式会社 Metallic material for thin film plating and method for producing the same

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