JP2006088708A - Printed matter - Google Patents

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JP2006088708A
JP2006088708A JP2005323020A JP2005323020A JP2006088708A JP 2006088708 A JP2006088708 A JP 2006088708A JP 2005323020 A JP2005323020 A JP 2005323020A JP 2005323020 A JP2005323020 A JP 2005323020A JP 2006088708 A JP2006088708 A JP 2006088708A
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printed matter
paper
gold foil
printing
adhesive layer
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JP4122023B2 (en
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Yasuhito Suzuki
康仁 鈴木
Takao Koyama
隆雄 小山
Mika Toyohara
美加 豊原
Akio Sasaki
章雄 佐々木
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Dai Nippon Printing Co Ltd
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Dai Nippon Printing Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide, cost effectively with reasonable prices and with short working hours, the printed matters as the duplication (including the restoration) of richly gilt and colored paintings and its production method which enables the duplication and/or the reproduction most faithful to the original paintings. <P>SOLUTION: The printed matter (the duplicated or the restored paintings) is characterized to be the one which has the gold leaf pasted on one side surface of the paper substrate through adhesive layer and has printing pattern layer formed on top of this gold leaf. It is characterized also to be the one which has the gold leaf pasted partially through adhesive layer thus forming the gold leaf domain and non-gold leaf domain and has the pattern printing layer formed at least in the above-mentioned non-gold leaf domain. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

本発明は、金箔を貼り付けた印刷物に関し、さらに詳しくは、襖や屏風、あるいは、壁面や天井面等に描かれた日本絵画等の金箔を貼り付けた絵画を複製した印刷物に関する。   The present invention relates to a printed material on which a gold foil is pasted, and more specifically, relates to a printed material on which a painting on which a gold leaf such as a Japanese painting drawn on a wall or ceiling surface or a painting is pasted is reproduced.

襖や屏風、あるいは、壁面や天井面等に金箔を貼り付けると共に極彩色に描かれた日本絵画等の文化遺産は、温度や湿度、あるいは、太陽光等の自然界の影響を長い年月受けると共に、大気汚染等の影響を受けて老朽化が年々進むなかで、これを如何にして後世に残していくか深刻な状況下にある。   Cultural heritage such as Japanese paintings painted with gold leaf on the walls and ceilings, or on the walls and ceilings, have been affected by the natural environment such as temperature, humidity or sunlight for many years. However, as aging progresses year by year due to the effects of air pollution and the like, it is in a serious situation how this will be passed on to future generations.

そこで、老朽化した文化遺産の修復を進める一方、他方においては老朽化した実物を収蔵庫等に大切に保管すると共に、老朽化した実物を複製物に置き換えていく方向の動きが活発化してきている。   Therefore, while the restoration of the aged cultural heritage is being promoted, on the other hand, the aging actual thing is carefully stored in a storage etc., and the movement to replace the aged real thing with a replica has been activated. Yes.

ところで、実物の複製物は、通常、現状(現物)模写ないし再現模写が今までの主流であったが、模写は一つ一つ手書きであるために製作日数が極端に長く、また、製作費用も莫大であると共に、模写する画家の解釈や主観が入った複製物となり、実物を描いた作者が実物に込めた意図が表現できない場合がある。特に、現状(現物)模写は、現在見られる箔足の微妙な汚れや変色を忠実に再現することは極めて難しいという問題がある。   By the way, the actual reproduction (in-kind) copying or reproduction copying has been the mainstream until now, but since the copying is handwritten one by one, the production days are extremely long and the production cost is also high. In addition to the enormous size, it may be a reproduction that includes the interpretation and subjectivity of the painter to be copied, and may not be able to express the intention of the real artist. In particular, the current (actual) replication has the problem that it is extremely difficult to faithfully reproduce the subtle stains and discoloration of the foil feet currently seen.

また、模写による複製物は、地震、台風等の自然災害や火災、人的毀損等の人的災害に対して無防備であり、一度被害が発生すると実物から再度模写する必要があり、上記で説明した模写の問題が再度発生する。また、この場合には、実物が収蔵庫等に大切に保管されているとはいっても、老朽化は更に進んでおり、現状(現物)模写ないし再現模写のいずれで模写をするにしても最初の模写と比べて、さらに困難な模写となる。   In addition, duplicates by copying are defenseless against natural disasters such as earthquakes, typhoons, and human disasters such as fires and human damage, and once damage occurs, it is necessary to copy from the real thing again. The replication problem that occurred again occurs. Also, in this case, even though the real thing is carefully stored in the storage, etc., the aging is further progressing, and it is the first to copy either the current (actual) copy or the reproduction copy. This is even more difficult than the copy of

そこで本発明は、上記問題を解決するためになされたものであって、襖や屏風、あるいは、壁面や天井面等に金箔を貼り付けると共に極彩色に描かれた日本絵画等の絵画の複製物として、模写に比べてより忠実に実物を表現すると共に模写に比べて製作日数が短く、製作費用も安価な印刷物を提供することにある。さらには、災害等により複製した印刷物が損傷あるいは消滅しても、再生が容易な印刷物を提供することにある。   Therefore, the present invention has been made to solve the above-mentioned problems, and is a reproduction of a painting such as a Japanese painting drawn in a brilliant color while sticking a gold leaf on a folding screen, folding screen, wall surface, ceiling surface, etc. It is to provide a printed material that more faithfully represents the actual object than copying and has a shorter production time and lower manufacturing cost than copying. It is another object of the present invention to provide a printed material that can be easily reproduced even if the printed material is damaged or disappears due to a disaster or the like.

本発明者は、上記目的を達成するために研究を重ねた結果、請求項1記載の発明の印刷物は、紙基材の一方の面に接着剤層を介して金箔を貼着し、該金箔上に印刷絵柄層を形成したことを特徴とするものである。   As a result of the inventor's studies to achieve the above object, the printed matter according to claim 1 has a gold foil attached to one surface of a paper substrate via an adhesive layer, and the gold foil. A printed pattern layer is formed thereon.

また、請求項2記載の発明の印刷物は、紙基材の一方の面に、部分的に接着剤層を介して金箔を貼着することにより金箔領域と非金箔領域とを形成し、少なくとも前記非金箔領域に絵柄印刷層を形成したことを特徴とするものである。   Moreover, the printed matter of the invention according to claim 2 forms a gold foil region and a non-gold leaf region by sticking a gold foil partially on one surface of a paper base material via an adhesive layer, and at least the above-mentioned The pattern printing layer is formed in the non-gold leaf region.

また、請求項3記載の発明は、請求項2記載の印刷物において、前記金箔領域に絵柄印刷層が形成されていることを特徴とするものである。   The invention according to claim 3 is the printed matter according to claim 2, wherein a pattern printing layer is formed in the gold foil region.

上記請求項1〜3記載の構成とすることにより、現状の実物を忠実に再現した印刷物、あるいは、実物が描かれた当時の状態を忠実に再現した印刷物とすることができる。   By adopting the configuration according to the first to third aspects, a printed matter that faithfully reproduces the current actual product or a printed matter that faithfully reproduces the state at the time when the actual product was drawn can be obtained.

また、請求項4記載の発明は、請求項1〜3のいずれかに記載の印刷物において、前記接着剤層、および、前記絵柄印刷層が紫外線硬化型樹脂からなる印刷インキで形成されていることを特徴とするものである。   The invention according to claim 4 is the printed matter according to any one of claims 1 to 3, wherein the adhesive layer and the pattern printing layer are formed of a printing ink made of an ultraviolet curable resin. It is characterized by.

また、請求項5記載の発明は、請求項4記載の印刷物において、前記紫外線硬化型樹脂が紫外線硬化型エポキシアクリレート樹脂であることを特徴とするものである。   The invention according to claim 5 is the printed matter according to claim 4, wherein the ultraviolet curable resin is an ultraviolet curable epoxy acrylate resin.

上記請求項4、5記載の構成、取分け、請求項5記載の構成とすることにより、紙基材と金箔とを強固に接着することができる接着剤層とすることができると共に、金箔や紙基材に対して接着性(密着性)に優れ、また、耐磨耗性や耐擦傷性に優れた絵柄印刷層とすることができる。   By adopting the configuration according to claims 4 and 5, particularly the configuration according to claim 5, it is possible to provide an adhesive layer capable of firmly bonding the paper substrate and the gold foil, and to obtain the gold foil or paper. It is possible to obtain a pattern printing layer that is excellent in adhesion (adhesion) to the substrate and excellent in abrasion resistance and scratch resistance.

また、請求項6記載の発明は、請求項1〜5のいずれかに記載の印刷物において、前記接着剤層、および、前記絵柄印刷層がオフセット印刷により形成されていることを特徴とするものである。このように構成することにより、10数色印刷しても見当精度の良い印刷物とすることができる。   The invention according to claim 6 is characterized in that, in the printed matter according to any one of claims 1 to 5, the adhesive layer and the pattern printing layer are formed by offset printing. is there. By configuring in this way, it is possible to obtain a printed matter with high registration accuracy even when printing ten or more colors.

また、請求項7記載の発明は、請求項1、2のいずれかに記載の印刷物において、前記紙基材が和紙であることを特徴とするものである。このように構成することにより、実物が和紙に描かれているものは、より実物に忠実な印刷物とすることができる。   The invention according to claim 7 is the printed matter according to any one of claims 1 and 2, wherein the paper base is Japanese paper. With this configuration, what is actually drawn on Japanese paper can be a printed matter that is more faithful to the real thing.

また、請求項8記載の発明は、請求項7記載の印刷物において、前記和紙が雁皮繊維と三椏繊維の2種類で構成された繊維により抄紙されたものであることを特徴とするものである。このように構成することにより、オフセット印刷により絵柄印刷層等を形成する場合に湿し水による影響(和紙の伸縮)を受けにくい和紙とすることができる。   The invention according to claim 8 is characterized in that, in the printed matter according to claim 7, the Japanese paper is made of paper composed of two types of cocoon fibers and trifilament fibers. With this configuration, it is possible to obtain a Japanese paper that is less susceptible to the influence of the fountain solution (expansion and contraction of the Japanese paper) when the pattern printing layer or the like is formed by offset printing.

本発明の印刷物は、襖や屏風、あるいは、壁面や天井面等に金箔を貼り付けると共に極彩色に描かれた日本絵画等の絵画の複製物として、模写に比べてより忠実に実物を表現した印刷物とすることができる。また、本印刷物を製造する過程において、実物の画像情報をデジタルデータとして取り込むために、災害等により複製した印刷物が損傷あるいは消滅しても、容易に再生することができる。さらに、本発明の印刷物は、模写に比べて製作日数が短く、製作費用も安価なものとすることができる。   The printed matter of the present invention faithfully represents the real thing as a reproduction of a painting such as a Japanese painting drawn in a colorful color with a gold leaf pasted on a wall or ceiling, or on a wall surface or ceiling surface, etc. Can be printed. In addition, since the actual image information is captured as digital data in the process of manufacturing the printed material, it can be easily reproduced even if the printed material is damaged or disappears due to a disaster or the like. Furthermore, the printed matter of the present invention can be manufactured in a shorter number of days and less expensive than copying.

上記の本発明について、図面等を用いて以下に詳述する。
図1は本発明にかかる印刷物の一実施例を示す正面図、図2は図1のI−I線の断面図、図3は本発明にかかる印刷物の製造方法の説明図であり、図中の1は印刷物、2は紙基材、3,3’は金箔、4,4’は絵柄印刷層、10は接着剤層、20は台紙、30は耐熱耐紫外線テープ、40,41は印刷用台紙をそれぞれ示す。
The above-described present invention will be described in detail below with reference to the drawings.
1 is a front view showing an embodiment of a printed material according to the present invention, FIG. 2 is a cross-sectional view taken along line I-I in FIG. 1, and FIG. 3 is an explanatory view of the method for producing a printed material according to the present invention. 1 is a printed material, 2 is a paper substrate, 3, 3 'is a gold foil, 4, 4' is a pattern printing layer, 10 is an adhesive layer, 20 is a mount, 30 is a heat and UV resistant tape, and 40 and 41 are for printing. Each mount is shown.

図1は本発明にかかる印刷物の一実施例を示す正面図、図2は図1のI−I線の断面図であって、印刷物1は紙基材2からなり、図1の左側半面には接着剤層10(図2参照)を介して金箔3が貼着されると共に右側半面には接着剤層10(図2参照)を介して「F」の形状に金箔3’が貼着されている。そして、金箔3、3’を形成した以外の前記紙基材2上に絵柄印刷層4が設けられる共に該絵柄印刷層4は前記金箔3、3’との境界においては毛抜き状態で設けられている(通常、絵柄印刷層4は花鳥風月などが極彩色で描かれている)。さらに、左側半面の金箔3上に「A」の形状の絵柄印刷層4’が設けられている。この絵柄印刷層4’は、「A」の如き単色からなる文字や記号であってもよいし、また、極彩色で花鳥風月などを描いたものであってもよいし、また、長い年月の間に金箔に付着した汚れやシミを表現したものであってもよい。   FIG. 1 is a front view showing an embodiment of a printed material according to the present invention, FIG. 2 is a cross-sectional view taken along the line II of FIG. 1, and the printed material 1 comprises a paper base material 2 on the left half surface of FIG. The gold foil 3 is attached via the adhesive layer 10 (see FIG. 2), and the gold foil 3 ′ is attached to the right half surface in the shape of “F” via the adhesive layer 10 (see FIG. 2). ing. And the pattern printing layer 4 is provided on the paper base material 2 other than the gold foils 3 and 3 'formed, and the pattern printing layer 4 is provided in a tweezer state at the boundary with the gold foils 3 and 3'. (Normally, the pattern print layer 4 is drawn with a gorgeous color such as Katori Kazuki). Further, a pattern printing layer 4 ′ having a shape of “A” is provided on the gold foil 3 on the left half surface. The pattern print layer 4 ′ may be a single color letter or symbol such as “A”, or may be a colorful color depicting a flower-bird-like moon, etc. It may be a representation of dirt and spots adhering to the gold leaf between the two.

ところで、図1に示す印刷物1を得る印刷方法としては、紙基材2に金箔3、3’を貼着するために設ける前記接着剤層10、あるいは、前記絵柄印刷層4,4’など10数色を印刷見当を合わせ印刷する必要があり、印刷見当精度を考慮するとシルクスクリーン印刷法ないしオフセット印刷法、あるいは、この両者の印刷法を組み合わせた印刷法等を挙げることができるが、シルクスクリーン印刷法はスクリーンメッシュを通して紙基材2にインキを転移させるため、印刷表面にスクリーンメッシュの跡が残り、極彩色や古色の色調再現性に障害となるという点で問題があり、また、シルクスクリーン印刷法とオフセット印刷法との組み合わせは、印刷見当精度の点で問題があり、オフセット印刷法が適当である。また、本発明の印刷物1をオフセット印刷法で印刷する場合に用いるオフセット印刷版は、多色印刷する際に生じるモアレやロゼット模様(通称で花目という)を防止するために、FM(Frequency Modulation)スクリーンで網点を形成するのが好ましい。   By the way, as a printing method for obtaining the printed matter 1 shown in FIG. 1, the adhesive layer 10 provided for sticking the gold foils 3, 3 ′ to the paper substrate 2, or the pattern printing layers 4, 4 ′ 10, etc. It is necessary to print several colors together with the printing register. Considering the printing register accuracy, the silk screen printing method or the offset printing method, or the printing method that combines these two printing methods can be mentioned. Since the printing method transfers ink to the paper substrate 2 through the screen mesh, there is a problem in that the trace of the screen mesh remains on the printing surface, which hinders the reproducibility of color tone and old color, and silk screen The combination of the printing method and the offset printing method has a problem in terms of printing registration accuracy, and the offset printing method is appropriate. In addition, the offset printing plate used when the printed matter 1 of the present invention is printed by the offset printing method is designed to prevent FM (Frequency Modulation) in order to prevent moiré and rosette patterns (commonly referred to as flower patterns) that occur during multicolor printing. ) Preferably, halftone dots are formed on the screen.

また、前記紙基材2としては、印刷可能なものであれば洋紙、和紙いずれの紙でもよいのであって特に制限はなく、実物を最も忠実に表現できる紙を適宜選択して用いることができる。しかし、実物が和紙に描かれた絵画であって、この絵画の複製物をオフセット印刷法で作製する場合にあっては、オフセット印刷法で用いる湿し水の影響をできる限り受け難い和紙(水による伸縮の少ない和紙)を用いる必要があり、これに適合する和紙として雁皮繊維と三椏繊維との混合繊維により抄紙されたものが適当である。特に、この雁皮繊維と三椏繊維との混合比は雁皮繊維が50〜70重量%、三椏繊維が50〜30重量%の範囲で抄紙された和紙が好ましく、なかでも雁皮繊維が60重量%、三椏繊維が40重量%からなる越前和紙の鳥の子特漉2号紙が特に好適である。また、一般に、和紙には楮繊維もよく用いられるが、楮繊維は繊維長さが長く湿し水による伸縮が激しいために本発明の印刷物1に用いる和紙としては不適である。   The paper base 2 may be either Western paper or Japanese paper as long as it is printable, and is not particularly limited. Paper that can represent the real thing most faithfully can be appropriately selected and used. . However, if the actual thing is a picture drawn on Japanese paper and a copy of this picture is produced by the offset printing method, the Japanese paper (water It is necessary to use a Japanese paper with less expansion and contraction, and a paper made with a mixed fiber of scabbard fibers and trifilar fibers is suitable as a compatible Japanese paper. In particular, the mixing ratio between the cocoon fiber and the cocoon fiber is preferably 50% to 70% by weight of the cocoon fiber and 50% to 30% by weight of the cocoon fiber. The Echizen Japanese paper Torinoko No. 2 paper with 40% by weight fiber is particularly suitable. In general, cocoon fibers are often used for Japanese paper, but the cocoon fibers are unsuitable as the Japanese paper used for the printed matter 1 of the present invention because of their long fiber length and intense expansion and contraction by dampening water.

また、前記接着剤層10を形成する印刷インキとしては、金箔3、3’を紙基材2に貼着するために用いるものであり、具体的には砂子糊、布海苔、姫糊、膠などが金箔3、3’を貼着するまでの間、適当な粘性を一定時間保持することなどから一般的に用いられているが、オフセット印刷法で印刷可能であることを考慮すると、紫外線硬化型樹脂(紫外線を照射することにより硬化させるまでは未硬化の粘性を保持した状態が持続する)からなる印刷インキが上記要求に合致する点で好ましい。   Moreover, as printing ink which forms the said adhesive bond layer 10, it is used in order to stick the gold | metal foils 3 and 3 'to the paper base material 2, Specifically, sand paste, cloth nori, hime glue, glue, etc. Is generally used because it maintains a suitable viscosity for a certain period of time until the gold foils 3 and 3 'are adhered, but considering that printing can be performed by an offset printing method, an ultraviolet curable type is used. A printing ink made of a resin (a state in which an uncured viscosity is maintained until cured by irradiation with ultraviolet rays) is preferable in that it meets the above requirements.

中でも、前記接着剤層10を形成する印刷インキに用いる紫外線硬化型樹脂としては、金箔3、3’との接着強度を従来の砂子糊、布海苔、姫糊、膠等の接着剤より見劣りしないものとするためには、紫外線硬化型エポキシアクリレート樹脂が好適である。紫外線硬化型エポキシアクリレート樹脂とは、ポリエステルアクリレート系紫外線硬化型樹脂にエポキシアクリレート樹脂(ビスフェノールAにエピクロルヒドリンを作用させて得たエポキシ樹脂をアクリル変性した樹脂)を加えたものである。前記接着剤層10を形成する印刷インキとしては、金箔3、3’を紙基材2に貼着するためのエポキシアクリレート樹脂の前記ポリエステルアクリレート系紫外線硬化型樹脂に対する添加割合は15〜35重量%、より好ましくは20〜30重量%である。添加割合が15重量%より少ないと紙基材2へ樹脂が浸透して金箔3、3’を貼り合わせるための粘着性が得られず、また、紫外線を照射して樹脂を硬化させても金箔3、3’との接着強度を得ることができない。また、添加割合が35重量%より多いと疎水性を要求するオフセット用印刷インキとして不適当となる(これは、オフセット印刷では「湿し水」を使用するので水によりインキが乳化するのを嫌うためである)。   Among them, as the ultraviolet curable resin used for the printing ink for forming the adhesive layer 10, the adhesive strength with the gold foils 3, 3 ′ is not inferior to that of conventional adhesives such as sand paste, cloth laver, princess paste, glue, etc. In order to achieve this, an ultraviolet curable epoxy acrylate resin is suitable. The ultraviolet curable epoxy acrylate resin is obtained by adding an epoxy acrylate resin (a resin obtained by acrylic-modifying an epoxy resin obtained by causing epichlorohydrin to act on bisphenol A) to a polyester acrylate ultraviolet curable resin. As the printing ink for forming the adhesive layer 10, the addition ratio of the epoxy acrylate resin for adhering the gold foil 3, 3 ′ to the paper substrate 2 is 15 to 35 wt% with respect to the polyester acrylate UV curable resin. More preferably, it is 20 to 30% by weight. If the addition ratio is less than 15% by weight, the resin penetrates into the paper substrate 2 and the adhesiveness for bonding the gold foils 3 and 3 'cannot be obtained. Even if the resin is cured by irradiating ultraviolet rays, the gold foil The adhesive strength with 3, 3 ′ cannot be obtained. Further, if the addition ratio is more than 35% by weight, it becomes unsuitable as offset printing ink that requires hydrophobicity (this is because “fountain solution” is used in offset printing, so that the ink is not emulsified with water. For).

前記接着剤層10を形成する前記紫外線硬化型樹脂からなる印刷インキは、前記紫外線硬化型エポキシアクリレート樹脂の他に印刷適性を保持するために沈降性硫酸バリウム、炭酸カルシウム等のフィラーと光重合開始剤、重合禁止剤、および、粘度調整用アクリレートモノマー成分からなるものであって、紫外線硬化型エポキシアクリレート樹脂としては、たとえば、リポキシSP−1519M〔昭和高分子(株)製〕、エベクリル3700〔ダイセルUCB(株)製〕等を挙げることができる。このように構成した印刷インキで形成した前記接着剤層10を紫外線を照射して硬化させることにより得られた金箔3、3’の貼着部は剛性を備え、耐薬品性、耐熱性に優れ、接着強度においても経時的(年単位)に低下することがないものとすることができる。   The printing ink made of the ultraviolet curable resin for forming the adhesive layer 10 starts photopolymerization with fillers such as precipitated barium sulfate and calcium carbonate in addition to the ultraviolet curable epoxy acrylate resin to maintain printability. The UV curable epoxy acrylate resin includes, for example, Lipoxy SP-1519M (manufactured by Showa Polymer Co., Ltd.), Evecryl 3700 [Daicel] UCB Co., Ltd.]. The adhesion part of the gold foils 3 and 3 ′ obtained by irradiating and curing the adhesive layer 10 formed with the printing ink thus configured has rigidity, and is excellent in chemical resistance and heat resistance. Also, the adhesive strength can be prevented from decreasing with time (yearly unit).

また、前記絵柄印刷層4,4’を形成する紫外線硬化型樹脂からなる印刷インキとしては、前記接着剤層10で説明した紫外線硬化型樹脂からなる印刷インキと同じものを用いることができる。   Further, as the printing ink made of the ultraviolet curable resin for forming the pattern printing layers 4 and 4 ′, the same printing ink as the ultraviolet curable resin described in the adhesive layer 10 can be used.

この絵柄印刷層4,4’を形成する印刷インキに用いる顔料としては、印刷物1が通常の一般家屋の屋内に置かれた状態下で経時的(年単位)な変色や褪色が極めて少ないものを用いる必要がある。これに適合する顔料としては、高級有機顔料、および、無機顔料を挙げることができる。高級有機顔料としては、たとえば、黄系に用いる顔料としてイソインドリノン系、ベンズイミダゾロン系、スレン系、モノアゾ系、縮合アゾ系等を挙げることができ、紅および赤系に用いる顔料としてキナクリドン系、モノアゾ系、縮合アゾ系、ペリレン系等を挙げることができ、橙系顔料としてイソインドリノン系、ベリノン系等を挙げることができ、青、藍および緑系顔料としてフタロシアニン系等を挙げることができ、紫系顔料としてジオキサジン系、キナクリドン系等を挙げることができる。また、無機顔料としては、たとえば、黄系顔料として黄鉛、黄色酸化鉄、カドミウムイエロー等を挙げることができ、赤系顔料として弁殻、カドミウムレッド等を挙げることができ、青および紫系顔料として群青、紺青、酸化クロム、コバルトブルー、コバルトグリーン、マンガンバイオレット等を挙げることができ、墨系顔料としてカーボンブラック、白系顔料として酸化チタンを挙げることができる。また、この他に、アルミニウム粉、ブロンズ粉等の金属粉、あるいは、炭酸カルシウム、硫酸バリウム、アルミナホワイト、シリカ等の体質顔料を挙げることができる。なお、前記接着剤層10を形成する紫外線硬化型樹脂からなる印刷インキについても、必要に応じて上記顔料を添加しても構わない。   The pigment used in the printing ink for forming the pattern printing layers 4 and 4 'is one that has very little discoloration or discoloration over time (yearly) when the printed material 1 is placed indoors in a normal ordinary house. It is necessary to use it. Examples of the pigment suitable for this include higher organic pigments and inorganic pigments. Examples of higher organic pigments include, for example, isoindolinone-based, benzimidazolone-based, selenium-based, monoazo-based, and condensed azo-based pigments for yellow, and quinacridone-based pigments for red and red. , Monoazo, condensed azo, perylene, etc., orange pigments such as isoindolinone, and verinone pigments, and blue, indigo and green pigments such as phthalocyanine pigments. Examples of purple pigments include dioxazine and quinacridone. Examples of the inorganic pigment include yellow lead, yellow iron oxide, cadmium yellow and the like as yellow pigments, and red shells such as valve shell and cadmium red, and blue and purple pigments. Examples include ultramarine blue, bitumen, chromium oxide, cobalt blue, cobalt green, and manganese violet. Carbon black is used as a black pigment, and titanium oxide is used as a white pigment. In addition, metal powders such as aluminum powder and bronze powder, or extender pigments such as calcium carbonate, barium sulfate, alumina white, and silica can be used. Note that the above-described pigment may be added to the printing ink made of an ultraviolet curable resin for forming the adhesive layer 10 as necessary.

以上のような紫外線硬化型樹脂からなる印刷インキ、および、紫外線硬化型樹脂に顔料等を添加した印刷インキを用いて前記接着剤層10および前記絵柄印刷層4,4’を形成した構成とすることにより、少なくとも30年、より好ましくは50年間、通常の一般家屋の屋内に置かれた状態下で接着強度が低下することなく、また、変色や褪色が極めて少ない印刷物とすることができる。   The adhesive layer 10 and the pattern printing layers 4 and 4 ′ are formed using a printing ink made of the ultraviolet curable resin as described above and a printing ink obtained by adding a pigment or the like to the ultraviolet curable resin. As a result, it is possible to obtain a printed material that does not deteriorate the adhesive strength and is extremely little discolored or discolored when placed in a normal ordinary house for at least 30 years, more preferably 50 years.

次に、図1、図2に示す本発明の印刷物1の製造方法について説明する。
まず、紙基材2に金箔が貼着されると共に絵筆と絵具を用いて極彩色に描かれた実物(図示せず)を写真等により画像として取り込み、取り込んだ画像をスキャナーで4色(キ、アカ、アイ、スミ)に色分解して基準版を作製すると共に色分解した4色の基準版で表現できない色を特色として必要な色数だけ特色版を作製すると共に、金箔を貼着するための接着剤層10を形成する接着剤版と接着剤層10の位置を示すアタリ罫線版を作製しておく。
Next, the manufacturing method of the printed matter 1 of this invention shown in FIG. 1, FIG. 2 is demonstrated.
First, a gold foil is affixed to the paper base 2 and a real object (not shown) drawn in a brilliant color using a paintbrush and paint is captured as an image by a photograph or the like. (Aka, Ai, Sumi) to make a reference plate by color separation, and make a special color plate of the required number of colors with a color that cannot be expressed by the four-color reference plate that has been color-separated, and affix a gold foil An adhesive plate for forming the adhesive layer 10 and an atlas ruled line plate indicating the position of the adhesive layer 10 are prepared.

次に、少なくとも二辺が直交する(オフセット印刷時に一辺が咬側、他の一辺が針側となる)台紙20〔三菱製紙(株)製:N−パールDX(290g/m2)〕上に紙基材2を載置すると共に前記台紙の一辺側(オフセット印刷時の咬側)で紙基材2を耐熱耐紫外線テープ30でテープ止めして固定した図3(a)に示すような印刷用台紙40を作製する。この印刷用台紙40を用いて、まず紙基材2に紫外線硬化型樹脂からなる印刷インキで金箔を貼着するための位置を示すグレー色のアタリ罫線印刷(図示せず)を前記アタリ罫線版で印刷すると共に、前記アタリ罫線印刷(図示せず)と見当を合わせて金箔を貼着するための接着剤層10(図示せず)を紫外線硬化型エポキシアクリレート樹脂に黄色顔料と赤色顔料で略金色に着色した紫外線硬化型樹脂からなる印刷インキで前記接着剤版を用いて印刷し、前記接着剤層10(図示せず)上に金箔を貼り付けると共にバレンで押さえて後に金箔の重なり部分あるいは不要な部分を除去し、その後金箔面に上記台紙のような厚紙を当てて加圧することにより金箔を完全に密着させ、厚紙を除去してから前記印刷用台紙に紫外線を照射して前記紫外線硬化型樹脂からなる印刷インキを完全に硬化させて、図3(b)に示す金箔3、3’が紙基材2に貼着された印刷用台紙41を得る。その後、金箔面に礬砂(どうさ)液を塗布すると共に自然乾燥して金箔の剥離防止を行い、その後上記した基準版および特色版で前記金箔3上と前記紙基材2の非金箔面とに「A」という形状の絵柄印刷層4’(図1参照)と絵柄印刷層4(図1参照)とを紫外線硬化型樹脂からなる印刷インキで印刷すると共に、紫外線を照射して前記絵柄印刷層4,4’(図1参照)を完全に硬化させて後に、紙基材2を台紙30から取り外し、四辺をトリミング〔図3(b)に示す一点鎖線でトリミング〕して図1に示す本発明の印刷物1を得る。 Next, on mount 20 [Mitsubishi Paper Co., Ltd .: N-Pearl DX (290 g / m 2 )] where at least two sides are orthogonal (one side is the occlusion side and the other side is the needle side during offset printing) Printing as shown in FIG. 3A in which the paper base 2 is placed and the paper base 2 is fixed with a heat-resistant and ultraviolet-resistant tape 30 on one side of the mount (the bite side during offset printing). A mount 40 is produced. Using this printing mount 40, first, the gray ruled line printing (not shown) indicating the position for sticking the gold foil to the paper base material 2 with the printing ink made of an ultraviolet curable resin is used. In addition, the adhesive layer 10 (not shown) for adhering the gold foil in register with the attried ruled line printing (not shown) is abbreviated with a yellow pigment and a red pigment on an ultraviolet curable epoxy acrylate resin. Printing is performed using a printing ink made of an ultraviolet curable resin colored in gold, using the adhesive plate, and a gold foil is pasted on the adhesive layer 10 (not shown) and pressed with valen, or an overlapping portion of the gold foil or Unnecessary parts are removed, and then the gold foil is applied to the gold foil surface by applying pressure to the gold foil surface so that the gold foil is completely adhered, and after removing the thick paper, the printing substrate is irradiated with ultraviolet rays to radiate the purple. The printing ink comprising a line-curable resin is completely cured to give a printed carrier sheet 41 gilt 3,3 'is adhered to paper substrate 2 shown in FIG. 3 (b). After that, a cinnabar liquid is applied to the gold foil surface and air-dried to prevent the peeling of the gold foil, and then the above-described reference plate and special plate on the gold foil 3 and the non-gold leaf surface of the paper base 2 In addition, the pattern printing layer 4 ′ (see FIG. 1) and the pattern printing layer 4 (see FIG. 1) having a shape of “A” are printed with printing ink made of an ultraviolet curable resin, and the pattern is irradiated with ultraviolet rays. After the printed layers 4 and 4 '(see FIG. 1) are completely cured, the paper base 2 is removed from the mount 30, and the four sides are trimmed [trimmed by the alternate long and short dashed lines shown in FIG. The print 1 of the present invention shown is obtained.

ところで、前記紙基材2として和紙、たとえば、鳥の子特漉2号紙を用いた場合に、金箔面に礬砂(どうさ)液を塗布して自然乾燥すると鳥の子特漉2号紙に反りが生じる。この場合は、反りを取り除く(フラットにする)手段を施す必要がある。この手段としては、たとえば、鳥の子特漉2号紙に水分を均一に与えて平面が平滑な金属板で挟んで加圧することにより反りを取り除くことができる。さらに、和紙、たとえば、鳥の子特漉2号紙を用いた場合、複製した印刷物の風合いを実物通りに表現するために、和紙の繊維が毛羽立った裏面を印刷面とすることが望ましい。   By the way, when using Japanese paper as the paper base material 2, for example, Torinoko Tokugo No. 2 paper, if the sand is applied to the gold leaf surface and dried naturally, the Torinoko Tokugo No. 2 paper warps. Arise. In this case, it is necessary to provide means for removing the warp (making it flat). As this means, for example, the warp can be removed by uniformly applying water to Torikoshi No. 2 paper, sandwiching it with a smooth metal plate and pressing it. Furthermore, when Japanese paper, for example, Torinoko Tokugo No. 2 paper is used, it is desirable to use the back side on which the fibers of the Japanese paper are fuzzy as the printed surface in order to express the texture of the printed material as it is.

なお、上記説明において、「F」の形状に設けた金箔3’は、金箔に替えて金粉を振りかけて形成することもできる。また、必要に応じて、金箔が酸化し金色の褪色を防止する目的で、また、耐磨耗性や耐擦傷性を向上指せる目的で、あるいは、絵柄印刷層4、4’の艶を消す(マット調とする)目的でOPニス等により保護層(図示せず)を絵柄印刷層4、4’上ないし全面に設けても構わない。   In the above description, the gold foil 3 ′ provided in the shape of “F” can be formed by sprinkling gold powder instead of the gold foil. If necessary, the gloss of the pattern printed layers 4 and 4 ′ is erased for the purpose of preventing the gold foil from being oxidized and preventing the discoloration of the gold color, to improve the wear resistance and the scratch resistance, or ( For the purpose of matting), a protective layer (not shown) may be provided on the pattern printing layers 4 and 4 ′ or on the entire surface with OP varnish or the like.

本発明にかかる印刷物の一実施例を示す正面図である。It is a front view which shows one Example of the printed matter concerning this invention. 図1のI−I線の断面図である。It is sectional drawing of the II line | wire of FIG. 本発明にかかる印刷物の製造方法の説明図である。It is explanatory drawing of the manufacturing method of the printed matter concerning this invention.

符号の説明Explanation of symbols

1 印刷物
2 紙基材
3,3’ 金箔
4,4’ 絵柄印刷層
10 接着剤層
20 台紙
30 耐熱耐紫外線テープ
40,41 印刷用台紙

DESCRIPTION OF SYMBOLS 1 Printed matter 2 Paper base material 3,3 'Gold foil 4,4' Picture print layer 10 Adhesive layer 20 Mount 30 Heat-resistant ultraviolet-resistant tape 40,41 Print mount

Claims (8)

紙基材の一方の面に接着剤層を介して金箔を貼着し、該金箔上に印刷絵柄層を形成したことを特徴とする印刷物。 A printed matter, wherein a gold foil is attached to one surface of a paper substrate via an adhesive layer, and a printed pattern layer is formed on the gold foil. 紙基材の一方の面に、部分的に接着剤層を介して金箔を貼着することにより金箔領域と非金箔領域とを形成し、少なくとも前記非金箔領域に絵柄印刷層を形成したことを特徴とする印刷物。 Forming a gold foil region and a non-gold foil region by partially sticking a gold foil on one side of a paper substrate through an adhesive layer, and forming a pattern printing layer at least in the non-gold foil region Characteristic printed matter. 前記金箔領域に絵柄印刷層が形成されていることを特徴とする請求項2記載の印刷物。 The printed matter according to claim 2, wherein a pattern printing layer is formed in the gold foil region. 前記接着剤層、および、前記絵柄印刷層が紫外線硬化型樹脂からなる印刷インキで形成されていることを特徴とする請求項1〜3のいずれかに記載の印刷物。 The printed matter according to any one of claims 1 to 3, wherein the adhesive layer and the pattern printing layer are formed of a printing ink made of an ultraviolet curable resin. 前記紫外線硬化型樹脂が紫外線硬化型エポキシアクリレート樹脂であることを特徴とする請求項4記載の印刷物。 The printed matter according to claim 4, wherein the ultraviolet curable resin is an ultraviolet curable epoxy acrylate resin. 前記接着剤層、および、前記絵柄印刷層がオフセット印刷により形成されていることを特徴とする請求項1〜5のいずれかに記載の印刷物。 The printed matter according to any one of claims 1 to 5, wherein the adhesive layer and the pattern printing layer are formed by offset printing. 前記紙基材が和紙であることを特徴とする請求項1、2のいずれかに記載の印刷物。 The printed material according to claim 1, wherein the paper base is Japanese paper. 前記和紙が雁皮繊維と三椏繊維の2種類で構成された繊維により抄紙されたものであることを特徴とする請求項7記載の印刷物。

8. The printed matter according to claim 7, wherein the Japanese paper is paper-made with fibers composed of two types of cocoon fibers and trifilament fibers.

JP2005323020A 2005-11-08 2005-11-08 Printed matter Expired - Fee Related JP4122023B2 (en)

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Cited By (2)

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JP2009132165A (en) * 2009-03-26 2009-06-18 Yumeraku Co Ltd Laminated body of wearable gold leaf for attachment
JP2010269182A (en) * 2010-09-06 2010-12-02 Yumeraku Co Ltd Gold foil face-packing method, laminate of gold foil for face packing used for the method

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JP5287982B2 (en) 2009-04-13 2013-09-11 株式会社Sumco Manufacturing method of silicon epitaxial wafer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009132165A (en) * 2009-03-26 2009-06-18 Yumeraku Co Ltd Laminated body of wearable gold leaf for attachment
JP2010269182A (en) * 2010-09-06 2010-12-02 Yumeraku Co Ltd Gold foil face-packing method, laminate of gold foil for face packing used for the method

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