JP2005306854A - Water-in-oil type cosmetic for eyelashes - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a water-in-oil type cosmetic for eyelashes that has excellent cosmetic effect that the eyelashes are allowed to see longer and the eyes are made strikingly beautiful and shows high effect durability, easy make-up properties, easy removability and temporal stability, particularly provide a water-in-oil type cosmetic for eyelashes having excellent cosmetic film uniformity, the film transparency and the film gloss, and volume feeling. <P>SOLUTION: Specific amounts of inulin and/or fatty acid ester obtained by hydrolysis of inulin and wax are combined with candelilla wax whereby the amount of the wax can be reduced and the transparency is increased and excellent usability is acquired. Thus, a water-in-oil type cosmetic for eyelashes is obtained that gives cosmetic film having excellent volume effect, uniformity and gloss. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention is a water-in-oil type cosmetic for cosmetics, which has a cosmetic effect that makes the eyelids look longer and makes the eyes stand out, its durability, ease of makeup, ease of removal with a remover, and stability over time. In particular, the present invention relates to a cosmetic for water-in-oil type with excellent uniformity of the decorative film, transparency of the decorative film, gloss of the decorative film, and excellent volume.

Cosmetics for eyelids have a cosmetic effect that makes the eyes clear by curling the eyelids upward and making the eyelids thicker and longer.
Conventionally, these vaginal cosmetics are mainly composed of solid oils such as waxes, powders, film forming agents, water-soluble polymers and fibers, and have various usability and functions required for cosmetics. In order to have the properties, various dosage forms and mixing of raw materials have been studied.
For example, there are emulsified types such as oil-in-water type and water-in-oil type, and oily type vaginal cosmetics. However, in the Japanese market, it is underwater due to ease of makeup and removal with a remover. Oil-type cosmetics for salmon are the mainstream, and oil-based technology development that pursues ease of removal has been mainly done. (For example, refer nonpatent literature 1). However, compared with the past, it has become common to use spears and the quality requirements have become more diverse, so that water-in-oil type technical studies have been made. For example, by containing an oil-soluble resin in the outer phase and a coloring material in the inner phase, the coloring material is prevented from being lost due to physical irritation, and the makeup is improved (see, for example, Patent Document 1). In addition, there is a technique (for example, see Patent Document 2) in which wearability and soap and water removability are improved by combining a water-soluble polymer substance in a water-based emulsion and a specific surfactant.
In addition, in the examination of the blending of raw materials, since the target is salmon, a quality different from that of skin cosmetics is required, and these are often studied independently. For example, for the purpose of improving the uniformity and flexibility of the decorative film, a technique combining fructooligosaccharide fatty acid ester and a film-forming polymer emulsion (for example, see Patent Document 3), or a technique replacing conventional waxes and resins. There is a technique for blending a candelilla resin (see, for example, Patent Document 4).
While technologies for improving the quality of products as described above are being developed, technologies for changing the texture of the surface of the cocoon are also being studied. Examples include a mat that has no surface gloss, and a mat that emphasizes gloss (see, for example, Patent Document 5).

Takeo Mitsui, “New Cosmetics”, 1st edition, P.I. 402-404, Publisher: Nanzando Co., Ltd., published in 1993 Japanese Patent Laid-Open No. 6-211629 Japanese National Patent Publication No. 11-505544 JP 7-196450 A JP 2002-338436 A Special table 2003-521489 gazette

  However, many of the technologies up to now are related to volume effect, long rush effect, usability, and their keeping power, and good results have been obtained for these, but those with qualitative changes have not been studied much. The current situation is not. Recently, in addition to the above effects, it has been desired that the wrinkles look healthy and supple. In order to realize this, a technique obtained by configuring with a glossy effect substance as described above has been studied. However, although gloss is obtained, there has been no technology that can embody the healthy, supple appearance that consumers demand.

Therefore, as a result of intensive studies to solve the above problems, the present inventors have not only applied a substance that gives a gloss, but also increased the gloss by creating a uniform film on the eyelashes. In the cosmetics for water-in-oil vaginal cosmetics, inulin and / or By containing a specific amount of hydrolyzed inulin fatty acid ester and wax and candelilla resin, the amount of wax is reduced, transparency is improved and excellent usability is obtained, and candelilla resin has a volume effect. And the present invention was completed. In addition, it has been found that by containing fibers, the adhesion of the fibers is improved and the long rush is further improved, and the present invention has been completed.
That is, the following components (A) to (C);
(A) Fatty acid ester of inulin and / or hydrolyzed inulin (B) Wax (C) Candelilla resin, content of component (B) is 0.5-8 mass% (hereinafter simply referred to as “%”) The present invention relates to a water-in-oil type salmon cosmetic characterized by

  The water-in-oil cosmetic for cosmetics of the present invention has a cosmetic effect that makes the eyelids look longer and makes the eyes stand out, its durability and ease of makeup, ease of removal with a remover, and good stability over time This is a water-in-oil cosmetic for cosmetics, and in particular, it is a water-in-oil cosmetic for cosmetics that is excellent in the uniformity of the cosmetic film, the transparency of the cosmetic film, the gloss of the cosmetic film, and the volume feeling.

Hereinafter, the present invention will be described in detail.
The inulin and / or hydrolyzed inulin fatty acid ester of the component (A) used in the water-in-oil vaginal cosmetics of the present invention has the effect of gelling an oil agent and imparting viscosity in a wide range, thereby maintaining makeup. And stability over time can be improved. Component (A) Fatty acid ester of inulin and / or hydrolyzed inulin is an ester of inulin, which is a kind of polysaccharide, and / or hydrolyzed inulin, which is a hydrolyzate thereof, and a fatty acid or a fatty acid derivative. The thing described in Kai 2002-284620 gazette is mentioned. Examples of commercially available products include Leo Pearl ISK (manufactured by Chiba Flour Mills).
It is preferable that the fatty acid ester of inulin and / or hydrolyzed inulin as the component (A) has an oil agent having a high gelling ability when the fatty acid substitution degree per monosaccharide unit is 2.2 or more. The fatty acid substitution degree shown here indicates the average number of moles obtained by esterifying three hydroxyl groups in a monosaccharide unit with a fatty acid. In the acyl group of the ester, 60 mol% or more of the total acyl group is preferably an acyl group having a straight chain hydrocarbon skeleton having 16 to 22 carbon atoms, specifically, a hexadecanoyl group or an octadecanoyl group. , Eicosanoyl group and docosanoyl group. With regard to the carbon chain length of the acyl group, an acyl group having a carbon number smaller than that of the hexadecanoyl group does not provide sufficient solubility or gel structure with the oil component, and conversely, an acyl group having a larger number of carbon atoms than the docosanoyl group. Then, it may be accompanied by a heavy feel during use or may precipitate over time.
Moreover, less than 40 mol% of the total acyl groups may be substituted with other acyl groups. Examples of other acyl groups include acetyl group, propionyl group, butyryl group, isobutyryl group, valeryl group, isovaleryl group, pivaloyl group, hexanoyl group, octanoyl group, decanoyl group, dodecanoyl group, tetradecanoyl group, tetracosanoyl group Hexacosanoyl group, octacosanoyl group, triacontanoyl group, oleoyl group, benzoyl group, naphthoyl group, isostearoyl group, isohexadecanoyl group, isodecanoyl group, isooctanoyl group and the like.

  Although content of a component (A) is not specifically limited, Preferably it is 1 to 5%, More preferably, it is 1.5 to 4%. Within this range, more excellent cosmetic effects and stability over time can be obtained.

  The wax of the component (B) used in the water-in-oil vaginal cosmetics of the present invention can improve the effect of making the vaginal thick, the makeup persistence, and the stability over time. Specific examples include paraffin wax, ceresin wax, microcrystalline wax, polyethylene wax, ethylene / propylene copolymer, montan wax, Fischer-Tropsch wax, beeswax, carnauba wax, candelilla wax, gay wax, and mole. Two or more species can be used.

  Content of a component (B) is 0.5 to 8%, Preferably it is 2 to 7%. If it is less than 0.5%, the makeup effect that makes wrinkles appear thick and the temporal stability are poor, and if it exceeds 8%, it is not good in terms of usability, gloss of the cosmetic film, and transparency.

The component (C) candelilla resin used in the water-in-oil vaginal cosmetics of the present invention is a resin obtained by fractional extraction of candelilla wax with an organic solvent, and is a resin compared to other resins. Not only is the odor less, but it has adhesion and can improve the volume.
In the present invention, the resin content in the candelilla resin preferably contains 65% or more of the resin content, and more preferably contains 85% or more of the resin content. As a method of the fractional extraction, for example, ethanol is added to candelilla wax and the candelilla wax is dissolved by heating on a water bath or the like. Next, this is cooled to room temperature to precipitate wax crystals, which are filtered to separate them into crystals and filtrate. Since the resin component is dissolved in the filtrate, the resin component can be obtained by distilling and recovering ethanol in the filtrate. Further, the softening point of the candelilla resin is preferably 35 to 55 ° C., and examples thereof include candelilla wax extract under the INCI name (International Nomenclature Cosmetic Labeling Names). As a method for measuring the softening point, a sample amount, 0.5 g, a heating rate of 0.2 ° C./min, 12 mmφ, 10 g of lead sphere is used according to the cosmetic raw material standard general test method softening point measuring method.

  Although content of a component (C) is not specifically limited, Preferably it is 0.1 to 30%, More preferably, it is 1 to 20%. Within this range, a more excellent cosmetic effect can be obtained.

  Since this invention is a water-in-oil type, it contains water, but the content is preferably 1 to 40%, particularly preferably 5 to 30%. If it is this range, the thing superior in the point of the sustainability of a cosmetic effect, usability, and the ease of removal with a remover will be obtained.

The vaginal cosmetic intended to obtain a long rush effect further contains the fiber of the component (D), and by combining with the components (A) to (C), the adhesion of the fiber to the wrinkle is further improved. Therefore, an excellent long rush effect can be obtained. The fiber of component (D) is not particularly limited as long as it is generally used in cosmetics, synthetic fibers such as nylon and polyester, artificial fibers such as rayon, natural fibers such as cellulose, and semi-synthetic materials such as acetate silk. Examples thereof include fibers. Among these, a polypropylene fiber, which is a synthetic fiber in which a propylene polymer is made into a fiber shape, is more preferable in terms of a cosmetic effect that makes wrinkles appear longer and makes the eyes stand out. Moreover, these fiber can use 1 type (s) or 2 or more types as needed.
The fiber of component (D) is used after being subjected to a surface treatment as necessary. Surface treatment agents include fluorine compounds, silicone oils, powders, oils, gelling agents, emulsion polymers, surfactants, etc. Among them, fluorine compounds show wrinkles thick and long and make eyes stand out. From the viewpoint of the makeup effect and the sustainability of the makeup effect. The fluorine compound for treating these surfaces is not particularly limited as long as the fiber can be treated to obtain water repellency and oil repellency. In particular, perfluoroalkyl group-containing esters, perfluoroalkylsilanes, perfluoropolyethers. A polymer having a perfluoroalkyl group is most preferable in terms of water repellency and oil repellency.

  The content of the component (D) fiber is preferably 0.1 to 10%, and more preferably 1 to 6% from the viewpoint of a cosmetic effect such as making the wrinkles look thicker and longer and make the eyes stand out.

The water-in-oil cosmetic for cosmetics of the present invention can further improve makeup sustainability and further improve ease of makeup by further containing the film-forming emulsion polymer of component (E). Can do.
The film-forming emulsion polymer is not particularly limited as long as it is generally used in cosmetics, and any of them can be used. Conventional alkyl acrylate, alkyl methacrylate polymer, copolymer, and acrylic A partially cross-linked acid polymer can also be suitably used. For example, (meth) acrylic acid alkyl polymer emulsion, (meth) alkyl acrylate copolymer emulsion, (meth) acrylic acid / (meth) alkyl acrylate copolymer emulsion, (meth) alkyl acrylate / styrene copolymer Examples include a coalescence emulsion, a vinyl acetate polymer emulsion, a vinyl acetate-containing copolymer emulsion, a vinylpyrrolidone / styrene copolymer emulsion, a silicone-containing polymer emulsion, and a silicone-containing copolymer emulsion. Moreover, these film-forming emulsion polymers can use 1 type (s) or 2 or more types as needed.

  The content of the film-forming emulsion polymer of component (E) is preferably 0.1 to 15% in terms of solid content of the polymer, and more preferably 1 to 10% in terms of makeup sustainability and ease of makeup. preferable.

  In addition to the above-mentioned components (A) to (E), the cosmetics for glazes of the present invention are usually used in cosmetics, for example, oily components as emollient components, and powders for touch adjustment and coloring. Ingredients, base materials, moisture retention, water-soluble ingredients as powder dispersants, surfactants for powder dispersion, UV absorbers, moisturizers, antioxidants, beauty ingredients, anti-inflammatory agents, antiseptics, fragrances, etc. Can be appropriately blended within a range not impairing the effects of the present invention.

  Oil components include hydrocarbons, fats and oils, ester oils, fatty acids, higher alcohols, silicone oils, regardless of their origin, such as animal oils, vegetable oils, synthetic oils, and semi-solid oils, liquid oils, etc. Fluorinated oils, lanolin derivatives, oily gelling agents and the like. Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, polybutene, oils and fats such as olive oil, castor oil, mink oil, macadamian nut oil, jojoba oil, diisostearyl malate, cetyl isooctanoate, Isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N-lauroyl-L-glutamic acid di ( Esters such as cholesteryl, behenyl, octyldodecyl), fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, stearyl Higher alcohols such as coal, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, low polymerization dimethylpolysiloxane, high polymerization dimethylpolysiloxane, methylphenylpolysiloxane, alkoxy-modified polysiloxane, cross-linked organopoly Silicones such as siloxane and fluorine-modified organopolysiloxane, fluorine oils such as perfluorodecane, perfluorooctane and perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin fatty acid ester , Sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid, aluminum isostearate, calcium stearate Oily gelling agents etc. and the like.

  The powder component is not particularly limited by the shape of a plate, spindle, needle, etc., particle size, particle structure such as porous, non-porous, etc., inorganic powders, glitter powders, organic Examples thereof include powders, pigment powders, and composite powders. Specifically, conger, ultramarine, bengara, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, aluminum oxide, cerium magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, carbon Inorganic powders such as black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, synthetic sericite, sericite, talc, kaolin, silicon carbide, barium sulfate, boron nitride, bismuth oxychloride, Mica titanium, iron oxide coated mica, iron oxide mica titanium, organic pigment-treated mica titanium, aluminum powder and other glittering powders, magnesium stearate, zinc stearate, N-acyl lysine, nylon and other organic powders, organic Tar pigments and organic dyes Pigment powders such as pigments, fine particle titanium oxide-coated mica titanium, fine particle zinc oxide-coated mica titanium, barium sulfate-coated mica titanium, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, and the like, polyethylene terephthalate, aluminum, Examples include epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, and the like, and one or more of them can be used. In addition, these powders may be used alone or in combination of two or more, and are known using fluorine compounds, silicone oils, metal soaps, waxes, surfactants, fats and oils, etc. It may be subjected to a surface treatment by a method.

  The water-soluble component may be any component that is soluble in water, for example, alcohols such as ethyl alcohol and isopropyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and polyethylene glycol. Glycerols such as glycerin, diglycerin, polyglycerin, saccharides such as sorbitol, maltitol, sucrose, starch sugar, lactitol, guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan, methylcellulose, Highly water-soluble components such as hydroxyethylcellulose, carboxymethylcellulose, carboxyvinyl polymer, polyvinyl alcohol, polyvinylpyrrolidone, sodium polyacrylate , Sodium chloride, magnesium chloride, salts such as sodium lactate, aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, plant extracts such as rose, and the like.

  Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., antiseptics such as paraoxybenzoic acid esters, phenoxyethanol, etc. Can be mentioned.

As the surfactant, any surfactant that is generally used in cosmetics can be used. Nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, and the like can be used. Can be mentioned. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sucrose fatty acid ester, polyoxyethylene hydrogenated castor oil, polyether-modified organopolysiloxane , Polyoxyalkylene / alkylmethylpolysiloxane / methylpolysiloxane copolymer, lecithin and the like.
However, the water-in-oil glaze cosmetic of the present invention is not an emulsion obtained by orienting a surfactant at the interface as an emulsifier, but the component (A) or other hydrophilic substance is mixed with an aqueous component. The non-emulsifying type dispersed in the oil phase is desirable. The non-emulsifying type is advantageous in that film formation is fast and removal with a remover is easy.

  Examples of the form of the water-in-oil type cosmetics of the present invention include creams, gels, liquids, etc. Among them, gels are preferable, and the appearance is transparent, translucent, and opaque. can do. As a vaginal cosmetic, it can be applied to mascara, mascara base and mascara overcoat.

Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

Invention products 1 to 5 and comparative products 1 to 6 Mascara Mascara having the formulation shown in Table 1 was prepared by the following production method, and the cosmetic effect, usability, and stability were evaluated. The cosmetic effect is the items of the gloss of the cosmetic film (including the uniformity of the cosmetic film), the transparency of the cosmetic film, and the volume feeling, and the usability is evaluated for ease of makeup. These results are also shown in Table 1. Shown in Further, although the results were not listed in the table as evaluation items, the ease of removal was also evaluated at the same time when only the product of the present invention was used and removed by a remover.

* 1: Leopard ISK (Chiba Flour Mills)
* 2: Leopard KL (Chiba Flour Mills)
* 3: Candelilla resin E-1 (Nippon Natural Products)
* 4: Benton 38 (manufactured by ELEMENTIS)
* 5: AEROSIL 380S (Nippon Aerosil Co., Ltd.)
* 6: 2% perfluoroalkyl phosphate diethanolamine salt treatment * 7: Plexitol B-500 (manufactured by Polymer Latex)
* 8: Vinibrand 1080 (manufactured by Nissin Chemical Industry Co., Ltd.)
* 9: Perfluoroalkyl phosphate diethanolamine 5% treated fiber (6D-2mm)

(Manufacturing method)
Invention products 1-5 and comparative products 1-6
A. Ingredients (1) to (13) are uniformly heated and mixed to about 80 ° C.
B. Ingredients (14)-(21) are mixed uniformly and brought to about 80 ° C.
C. Add B to A and mix evenly.
D. Fill the container with C to make a product.

(Evaluation methods)
Using 10 sensory test panels, each sample was evaluated in 7 levels using the absolute evaluation criteria for the following a to d, and the average score of each sample was (2) using the 4-step criteria. Judged.
For evaluation item e, the glass bottle was filled with mascara, stored in a thermostatic bath at 50 ° C., the state after one week was observed, and (3) the determination was made according to a four-step criterion.
Moreover, about the ease of removal of a remover, about 1 g of remover of the following prescription was taken up in cotton, and after applying to a use site for about 5 seconds, it was evaluated whether it was easy to wipe off a cosmetic film.

(Evaluation item)
a. Gloss of cosmetic film b. Transparency of decorative film c. Volume feeling d. Ease of makeup e. Stability over time (1) Absolute evaluation criteria (score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (2) Four-step criteria (average score): (Decision)
More than 5 points: Very good: ◎
3 points to 5 points or less: Good: ○
Over 2 points and under 3 points: Somewhat bad: △
2 points or less: Defect: ×
(3) There is no separation at all in four-step criteria: ◎
There is some separation, but there is no problem in use: ○
There is some separation, and there is a problem during use: △
Separation is remarkable: ×

Remover formula for evaluation (component) (%)
(1) Light liquid isoparaffin 10
(2) Carboxymethylcellulose 0.5
(3) Sodium hydroxide 0.1
(4) Purified water remaining amount (5) Preservative 0.1
(Manufacturing method)
A. Components (2) to (5) are mixed and dissolved, and (1) is added to emulsify.
B. A is filled in a container to obtain an evaluation remover.

As is clear from the results in Table 1, the mascara of the inventive products 1 to 5 are more uniform and glossy than the mascara of the comparative products 1 to 6, are excellent in transparency of the cosmetic film, and have a sense of volume. Therefore, it gave a healthy and supple impression. In addition, it can be seen that it has far superior characteristics in all aspects of ease of makeup and stability over time. Furthermore, it was easy to remove with a remover.
On the other hand, the comparative product 1 containing no component (A) has a decorative film transparency, volume and stability over time, and the comparative product 2 containing no component (B) has a cosmetic film transparency and volume. In comparison product 3 which does not contain component (C) in terms of stability over time, it does not contain component (A) in terms of glossiness, transparency and volume of the cosmetic film, but instead contains dextrin fatty acid ester. In the comparative product 4, the cosmetic film is transparent, voluminous, and stable over time, and in the comparative product 5 containing a large amount of the component (B), the cosmetic film has a glossy transparency and ease of makeup. In comparison, the comparative product 6 containing a large amount of the component (B) and containing polyvinyl alcohol as a film-forming agent is satisfactory in terms of gloss of the decorative film, a sense of transparency, a sense of volume, and ease of makeup. Was not obtained.

Mascara (ingredient) (%)
(1) Candelilla resin * 10 10
(2) Trimethylsiloxysilicic acid 10
(3) Decamethylcyclopentasiloxane Residual amount (4) Fatty acid ester of inulin and / or hydrolyzed inulin * 11 1.5
(5) Carnauba wax 1
(6) Organically modified clay mineral * 4 5
(7) Titanium / titanium oxide sintered product 10
(8) Bengala-coated mica titanium 5
(9) Purified water 10
(10) Alkyl acrylate / styrene copolymer emulsion (solid content 45%) * 12 2
(11) Natural vitamin E 0.5
(12) Soybean phospholipid 0.3
(13) Polyvinyl alcohol 0.1
(14) Polypropylene fiber 1.5D-1mm 6
* 10: The composition of the candelilla resin is 90% resin, 5% free alcohol, 2% free fatty acid, 2% ester, 1% hydrocarbon, and the softening point is 47 to 48 ° C.
* 11: Hydrolyzed inulin (palmitic acid / 2-ethylhexanoic acid) ester (average fatty acid substitution degree is 2.5)
* 12: Yodzole GH41 (made by NSC Japan)
(Manufacturing method)
A. Components (1) to (8) are uniformly heated and mixed, and components (9) to (14) are added and mixed uniformly.
B. A is filled into a container to obtain a product.
The mascara of the present invention has a uniform and excellent gloss film, an excellent transparency of the decorative film, and a voluminous feel, so it gives a healthy and supple impression. Moreover, the ease of makeup and stability over time were good, and it was easy to remove with a remover.

Mascara base (component) (%)
(1) Candelilla resin * 3 5
(2) Inulin and / or hydrolyzed inulin fatty acid ester * 13 3
(3) Beeswax 4
(4) Polyethylene wax 3
(5) Light liquid isoparaffin remaining amount (6) Mica 5
(7) Mica titanium 2
(8) Purified water 30
(9) Polyvinyl acetate emulsion (solid content 45%) * 8 20
(10) Soybean phospholipid 0.5
(11) Ethanol 2
* 13: Hydrolyzed inulin stearic acid / isostearic acid ester (average fatty acid substitution degree is 2.3)
(Manufacturing method)
A. Components (1) to (7) are heated and mixed uniformly, and components (8) to (11) are added and mixed uniformly.
B. A is filled into a container to obtain a product.
The mascara base of the present invention is easy to make and stable over time, and is easy to remove with a remover. When a commercially available mascara is applied from above, the makeup film is uniform and excellent in gloss, It was excellent in transparency of the film, gave a sense of volume, and gave a healthy and supple impression.

Mascara top coat (ingredient) (%)
(1) Candelilla resin * 3 22
(2) Fatty acid ester of inulin and / or hydrolyzed inulin * 14 4.5
(3) Beeswax 0.5
(4) Carnauba wax 0.5
(5) Light liquid isoparaffin remaining amount (6) Purified water 10
(7) Soybean phospholipid 0.5
(8) (Vinylpyrrolidone-vinyl acetate) copolymer * 15 3
(9) Ethanol 2
(10) Colored nylon fiber * 16 0.5
* 14: Hydrolyzed inulin stearic acid / isostearic acid ester (average fatty acid substitution degree is 1.8)
* 15: PVP / VAE-735 (50% ethanol solution) (manufactured by ISP Van Dyke)
* 16: 6D-2mm (Blue No. 1)
(Manufacturing method)
A. Components (1) to (5) are heated and mixed uniformly, and components (6) to (10) are added and mixed uniformly.
B. A is filled into a container to obtain a product.
The mascara top coat of the present invention is easy to make up, stable over time, and easy to remove with a remover.When applied on a commercially available mascara, the makeup film is uniform and excellent in gloss, The decorative film was excellent in transparency, voluminous, and energetic and healthy.

Claims (5)

The following components (A) to (C);
(A) Fatty acid ester of inulin and / or hydrolyzed inulin (B) Wax (C) Candelilla resin, component (B) content is 0.5-8 mass% Medium-water type cosmetic for salmon.   The content of the component (A) is 1 to 5% by mass, and the content of the component (C) is 0.1 to 30% by mass. . Furthermore, a fiber is contained as a component (D), The cosmetics for water-in-oil type | molds of Claim 1 or 2 characterized by the above-mentioned.
The cosmetic for water-in-oil type according to claim 1, wherein   Furthermore, film-forming emulsion polymer is contained as a component (E), The cosmetics for water-in-oil type | molds in any one of Claims 1-3 characterized by the above-mentioned.   The cosmetic for water-in-oil type according to any one of claims 1 to 4, which is substantially non-emulsified.