JP2005216825A - Square battery and its manufacturing method - Google Patents

Square battery and its manufacturing method Download PDF

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JP2005216825A
JP2005216825A JP2004025756A JP2004025756A JP2005216825A JP 2005216825 A JP2005216825 A JP 2005216825A JP 2004025756 A JP2004025756 A JP 2004025756A JP 2004025756 A JP2004025756 A JP 2004025756A JP 2005216825 A JP2005216825 A JP 2005216825A
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plate
electrode plate
joining
coated
portions
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JP4588331B2 (en
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Yukio Harima
幸男 播磨
Tatsuya Hashimoto
達也 橋本
Seiichi Uemoto
誠一 上本
Kiyomi Kouzuki
きよみ 神月
Hiroaki Ichinose
浩明 一ノ瀬
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Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a square battery wherein a current carrying path from each part of the coated portion of an electrode plate to a collector can be shortened and connection resistance can be lessened to obtain a high output, and which can be structured so as to have high volume density and a compact size while having high productivity so that its cost can be reduced. <P>SOLUTION: This square battery 1 contains a group of electrodes 4, in which a beltlike positive electrode plate is superposed over a beltlike negative electrode plate through a separator and they are wound, and from which the non-coated portions 6 of the positive electrode plate and the negative electrode plate are protruded at both end parts in the direction of their winding axis, and an electrolyte in a square battery case 1A. A fitting end part 8a having a V-shaped cross-section and a collector 8 having a pair of bonding plate parts 8b continuously connected to it are fitted in the winding center part of the non-coated portions 6 wound in a multiple ellipse shape, and both bonding plate parts 8b are bonded to the group of the non-coated portions 6 in its outside. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、横断面形状が長方形や隅丸長方形ないし長円形を呈する角形電池とその製造方法に関するものである。   The present invention relates to a prismatic battery having a cross-sectional shape of a rectangle, a rounded rectangle, or an oval, and a method of manufacturing the same.

従来から、円筒型電池に比してより高い体積密度が得られる電池として、角形の電池筐体内に、帯状の正極板と負極板をセパレータを介して重ねて巻回して成る極板群と電解液を収容して成る角形電池が知られている。また、この種の角形電池において、極板群の巻回軸方向の両端部にそれぞれ正極板と負極板の非塗工部を突出させ、かつ突出された非塗工部を電極端子又は集電体に接続することで、コンパクトな構成にて、電極板の塗工部の各部位から電極端子又は集電体に至る通電経路を短く、かつ接続抵抗を小さくして高出力が得られるように工夫したものが種々提案されている。   Conventionally, as a battery that can obtain a higher volume density than a cylindrical battery, an electrode plate group formed by winding a strip-like positive electrode plate and a negative electrode plate with a separator interposed in a rectangular battery case and electrolysis A square battery containing a liquid is known. Further, in this type of prismatic battery, the non-coated portions of the positive electrode plate and the negative electrode plate are protruded from both ends in the winding axis direction of the electrode plate group, respectively, and the protruded non-coated portions are electrode terminals or current collectors. By connecting to the body, it is possible to obtain a high output in a compact configuration by shortening the current path from each part of the coated part of the electrode plate to the electrode terminal or current collector and reducing the connection resistance. Various ideas have been proposed.

例えば、極板群から突出させた非塗工部上に電極端子の軸部を配置し、軸部の両側縁に突出させた複数の突起部を加熱溶融させ、その溶融液を積層した非塗工部の界面に供給して形成した架橋部にて非塗工部と電極端子の軸部を接合したものが知られている(例えば、特許文献1参照。)。   For example, the shaft portion of the electrode terminal is disposed on the non-coated portion that protrudes from the electrode plate group, and a plurality of protrusions that protrude from both side edges of the shaft portion are heated and melted, and the melt is laminated. There is known one in which a non-coated portion and a shaft portion of an electrode terminal are joined at a bridging portion formed by supplying to the interface of the working portion (see, for example, Patent Document 1).

また、極板群から突出している積層状態の電極板の非塗工部を所要数毎に収束させ、電極端子が接続固定される集電体に、断面が逆V字状で頂点にスリットを設けた狭窄部を所要数連続して形成し、各狭窄部に上記収束した非塗工部を差し込み、スリットから非塗工部の先端を突き出させてレーザー溶接したものが知られている(例えば、特許文献2参照。)。   In addition, the uncoated portions of the stacked electrode plates protruding from the electrode plate group are converged for each required number, and the current collector to which the electrode terminals are connected and fixed has a reverse V-shaped cross section and a slit at the apex. It is known that the required number of stenosis portions are continuously formed, the converged non-coating portions are inserted into each stenosis portion, the tip of the non-coating portion is protruded from the slit, and laser welding is performed (for example, , See Patent Document 2).

また、極板群から突出している積層状態の電極板の非塗工部を所要数毎に収束させ、電極端子が接続固定される集電体に、断面が略逆V字状で頂部が逆U字状の溝部を所要数連続して形成し、各溝部に収束した非塗工部を差し込み、集電体の溝部と非塗工部の差し込み部を超音波溶接や抵抗溶接などで溶接、若しくはリベット等で機械的に結合したものも知られている(例えば、特許文献3参照。)。   Further, the uncoated portions of the laminated electrode plates protruding from the electrode plate group are converged for each required number, and the current collector is connected and fixed to the current collector. Form the required number of U-shaped grooves continuously, insert the non-coated part converged in each groove part, weld the groove part of the current collector and the inserted part of the non-coated part by ultrasonic welding or resistance welding, Or what was mechanically couple | bonded with the rivet etc. is known (for example, refer patent document 3).

さらに、極板群から突出している積層状態の電極板の非塗工部を、複数の山形歯を有する治具などを用いて複数に振り分け、電極端子が接続固定された集電体に、非塗工部上に配置される集電部を設けるとともに、この集電部に平板部を介して連結されている複数の挟持部を設け、各挟持部に振り分けられた非塗工部をそれぞれ挿入し、挟持部をかしめるとともに超音波溶接によって接続固定したものも知られている(例えば、特許文献4参照。)。   Further, the non-coated portion of the laminated electrode plate protruding from the electrode plate group is divided into a plurality of pieces using a jig having a plurality of angle teeth, and the non-coated portion is connected to the current collector to which the electrode terminals are connected and fixed. A current collector is provided on the coating part, and a plurality of clamping parts connected to the current collecting part via a flat plate part are provided, and a non-coating part distributed to each clamping part is inserted. And what clamped the clamping part and was connected and fixed by ultrasonic welding is also known (for example, refer patent document 4).

なお、アルミ板の間にアルミ箔の積層体をサンドイッチした状態で摩擦攪拌接合(FSW:Friction Stir Welding)法にて接合する技術も知られている(例えば、非特許文献1参照。)。
特開2002−100340号公報 特開平10−261441号公報 特開平10−270048号公報 特開2000−82486号公報 青田欣也、「摩擦攪拌接合法のマイクロ接合への応用」、溶接 学会誌、(社)溶接学会、平成15年4月、第72巻、第3号、 P25−28
In addition, the technique of joining by the friction stir welding (FSW: Friction Stir Welding) method in the state which sandwiched the laminated body of the aluminum foil between the aluminum plates is also known (for example, refer nonpatent literature 1).
JP 2002-100340 A JP-A-10-261441 JP-A-10-270048 JP 2000-82486 A Aoya Shinya, “Application of Friction Stir Welding to Microjoining”, Journal of the Japan Welding Society, Japan Welding Society, April 2003, Vol. 72, No. 3, P25-28

ところが、特許文献1や特許文献2に開示されているように、極板群から突出させた電極板の非塗工部と集電体を、その一部を加熱溶融させて接合する方法では、電極板の間の介装されているセパレータが熱影響を受けてその機能に障害を与えたり、場合によって短絡を生じさせる恐れがある。それを防止するためには、極板群からの非塗工部の突出量を大きくしたり、冷却を行うなどの対策が必要となり、電池としての体積効率が悪化したり、接合工程が煩雑になったり、設備コストが高くなったりして生産性低下やコストアップの原因になるという問題がある。   However, as disclosed in Patent Document 1 and Patent Document 2, in the method of joining the non-coated portion and the current collector of the electrode plate protruding from the electrode plate group by heating and melting a part thereof, There is a possibility that the separator interposed between the electrode plates may be affected by heat, impede its function, and possibly cause a short circuit. In order to prevent this, it is necessary to take measures such as increasing the amount of protrusion of the non-coated part from the electrode plate group, cooling, etc., reducing the volume efficiency of the battery, and complicating the joining process. There is a problem in that the cost of the equipment increases and the cost of the equipment increases, resulting in a decrease in productivity and an increase in cost.

また、特許文献2や特許文献3に開示されているように、非塗工部を所要数毎に収束させ、逆V字状の狭窄部や溝部に非塗工部を差し込んで超音波溶接等で接合する構成では、非塗工部を所要数毎に収束させるという煩雑な工数が必要となり、生産性が低く、コスト高になるという問題があり、また狭窄部や溝部の間にV字状の突出部が形成され、この突出部が収束させた非塗工部間に嵌入するため、この突出部の先端が逆極性の電極板に接触して短絡を発生する恐れがあり、それを防止するためには非塗工部の突出量を大きくする必要があり、やはり体積効率が悪化するという問題がある。   Moreover, as disclosed in Patent Document 2 and Patent Document 3, the non-coated portion is converged for each required number, and the non-coated portion is inserted into an inverted V-shaped narrowed portion or groove portion, and ultrasonic welding or the like. In the structure to be joined with, it requires a complicated man-hour for converging the non-coated parts for each required number, resulting in low productivity and high cost, and V-shaped between the narrowed part and the groove part. This protrusion is inserted between the non-coated parts where the protrusion converges, so there is a risk that the tip of this protrusion will come into contact with the reverse polarity electrode plate, causing a short circuit and preventing it. In order to do this, it is necessary to increase the amount of protrusion of the non-coated portion, and there is a problem that volume efficiency is deteriorated.

また、特許文献4に開示された構造では、挟持部間に平面部を設けていることで上記V字状の突出部による問題はある程度解消されるが、複数の山形歯を有する治具などを用いて非塗工部を複数に振り分ける工程が必要となり、生産性が低く、コスト高になるという問題がある。   In addition, in the structure disclosed in Patent Document 4, the problem due to the V-shaped protrusion is solved to some extent by providing a flat portion between the sandwiching portions. However, a jig having a plurality of chevron teeth is used. There is a problem that the process of using and distributing the non-coated part into a plurality of steps is required, resulting in low productivity and high cost.

本発明は、上記従来の問題点に鑑み、電極板の塗工部の各部位から集電体に至る通電経路を短くかつ接続抵抗を小さくできて高出力が得られ、しかも体積密度が高くコンパクトに構成できかつ生産性が高くコスト低下を図ることができる角形電池とその製造方法を提供することを課題とする。   In view of the above-mentioned conventional problems, the present invention can shorten the energization path from each part of the coated portion of the electrode plate to the current collector, reduce the connection resistance, obtain a high output, and have a high volume density and a compact size. It is an object of the present invention to provide a prismatic battery that can be configured as described above, that is highly productive, and that can reduce costs, and a method for manufacturing the prismatic battery.

本発明の角形電池は、角形の電池筐体内に、帯状の正極板と負極板をセパレータを介して重ねて巻回して成りかつ巻回軸方向の両端部にそれぞれ正極板と負極板の非塗工部が突出されている極板群と電解液とを収容して成る角形電池であって、少なくとも前記両端部のうちの一端部は、断面略V字状の嵌入端部とそれに連続する一対の接合板部を有する集電体を、多重長円形に巻回されている非塗工部の巻回中心部に嵌入させ、両接合板部とその外側の非塗工部とを接合したものである。なお、接合には、熱影響の少ない、超音波接合、抵抗溶接、摩擦攪拌接合(FSW)などが好適である。   The prismatic battery of the present invention is formed by winding a strip-shaped positive electrode plate and a negative electrode plate with a separator interposed therebetween in a rectangular battery casing, and the positive electrode plate and the negative electrode plate are not coated on both ends in the winding axis direction, respectively. A prismatic battery comprising an electrode plate group from which a work part is projected and an electrolyte solution, wherein at least one end portion of the both end portions is a fitting end portion having a substantially V-shaped cross section and a pair continuous thereto. A current collector having a joining plate part is inserted into the winding center part of the non-coated part wound in a multi-oval shape, and both the joining plate parts and the non-coated part outside thereof are joined. It is. For joining, ultrasonic joining, resistance welding, friction stir welding (FSW), or the like, which has little thermal influence, is suitable.

この構成によると、多重長円形に巻回されている非塗工部の巻回中心部には、非塗工部の多重積層部に比して大きな隙間が形成されているため、集電体の断面略V字状の嵌入端部を容易に嵌入させることができ、かつ外側から溶接作業を行うことができるので、高い作業能率で接続することができ、生産性が高くコスト低下を図ることができる。また、極板群の一端側では、集電体を接続する極性と同じ極性の最内周の電極板の非塗工部の間に嵌入端部を嵌入させることになるため、また極板群の他端側では、集電体を接続する極性と逆極性の最内周の電極板の端縁の周囲を取り囲むようにセパレータが存在し、その周囲を集電体を接続する極性と同じ極性の電極板の非塗工部が取り囲んでいるため、セパレータを内側に折り込んで逆極性の極板群の端縁上に重ねて覆った状態で同じ極性の電極板の非塗工部の間の隙間に嵌入端部を嵌入させることによって、非塗工部の突出長が短くても集電体の先端の嵌入端部が逆極性の電極板と短絡を起こす恐れがなく、体積密度を高く、コンパクトに構成することができる。また、多重長円形に巻回されている非塗工部がその周方向2箇所で集電体と接合されるので、電極板の塗工部の各部位から集電体に至る通電経路を短くかつ接続抵抗を小さくできて高出力を得ることができる。   According to this configuration, since a large gap is formed in the winding center portion of the non-coated portion wound in the multiple oval shape as compared with the multiple laminated portion of the non-coated portion, the current collector Since the insertion end portion having a substantially V-shaped cross section can be easily inserted and welding work can be performed from the outside, it is possible to connect with high work efficiency, high productivity, and cost reduction. Can do. In addition, on one end side of the electrode plate group, since the insertion end portion is inserted between the non-coated portions of the innermost electrode plate having the same polarity as that of the current collector, the electrode plate group On the other side of the separator, there is a separator surrounding the edge of the innermost electrode plate with the opposite polarity to the polarity to which the current collector is connected, and the same polarity as the polarity to which the current collector is connected. Since the non-coated part of the electrode plate is surrounded, the separator is folded inward and overlapped on the edge of the opposite polarity electrode plate group so as to cover the non-coated part of the electrode plate of the same polarity. By inserting the insertion end into the gap, the insertion end at the tip of the current collector does not cause a short circuit with the opposite polarity electrode plate even if the projection length of the non-coated part is short, and the volume density is high. It can be configured compactly. In addition, since the non-coating portion wound in a multi-oval shape is joined to the current collector at two locations in the circumferential direction, the energization path from each part of the coating portion of the electrode plate to the current collector is shortened. In addition, the connection resistance can be reduced and high output can be obtained.

また、極板群が、巻き始めにセパレータのみを1又は複数回巻回したものであると、最内周がセパレータとなっているため、極板群の両端側ともにセパレータの間に集電体の嵌入端部を嵌入させることになり、集電体の嵌入端部が逆極性の電極板と短絡を起こす恐れをより簡単かつ確実に無くすことができる。   Moreover, since the innermost circumference is a separator when the electrode plate group is formed by winding only the separator one or more times at the beginning of winding, a current collector is provided between the separators at both ends of the electrode plate group. Therefore, the risk of causing a short circuit between the inserted end of the current collector and the electrode plate having the opposite polarity can be eliminated more easily and reliably.

また、両接合板部と当て板との間に非塗工部を挟持した状態で接合すると、接合時に非塗工部における接合工具の当接部が局部的に破断したり、溶損したりすることなく、信頼性の高い接合状態を確保することができる。   In addition, when bonding is performed with the non-coated portion sandwiched between both the bonded plate portions and the contact plate, the contact portion of the bonding tool in the non-coated portion is locally broken or melted during bonding. Therefore, a highly reliable joining state can be ensured.

また、両接合板部と当て板を連結片を介して一体連結し、集電体の断面方向の形状を略M字状とすると、集電体と当て板を一体部品として取扱うことができるので、部品コスト及び生産能率を向上できるとともに、連結片のみで連結しているため接合板部と当て板の連結部の剛性が小さく、それらの間で非塗工部を容易に挟持することができ、また超音波接合時に当て板の振動を阻害したり、抵抗溶接時に短絡電流が大きく溶接不可能になるというような不具合を生じる恐れがない。   In addition, if both the joining plate portions and the contact plate are integrally connected via a connecting piece, and the shape of the current collector in the cross-sectional direction is substantially M-shaped, the current collector and the contact plate can be handled as an integral part. In addition to improving the component cost and production efficiency, since the connection is made only with the connecting pieces, the rigidity of the connecting portion of the joining plate portion and the backing plate is small, and the non-coated portion can be easily sandwiched between them. In addition, there is no possibility of causing problems such as inhibiting the vibration of the contact plate at the time of ultrasonic bonding, or causing a short circuit current to become large and impossible to weld at the time of resistance welding.

また、本発明の角形電池の製造方法は、角形の電池筐体内に、帯状の正極板と負極板をセパレータを介して重ねて巻回して成りかつ巻回軸方向の両端部にそれぞれ正極板と負極板の非塗工部が突出されている極板群と電解液とを収容して成る角形電池の製造方法であって、巻回形成した極板群の両端における多重長円形に巻回されている非塗工部の巻回中心部に、断面略V字状の嵌入端部とそれに連続する一対の接合板部を有する集電体を嵌入させる工程と、両接合板部とその外側の非塗工部を接合する工程と、両極性の集電体をそれぞれ外部接続端子に接続し、極板群を電池筐体内に収容する工程とを有するものである。   In addition, the method for manufacturing a prismatic battery according to the present invention includes a strip-shaped positive electrode plate and a negative electrode plate stacked in a rectangular battery casing with a separator interposed therebetween, and each of the positive electrode plate and the positive electrode plate at both ends in the winding axis direction. A method for manufacturing a prismatic battery comprising an electrode plate group in which a non-coated portion of a negative electrode plate protrudes and an electrolyte solution, wherein the electrode plate group is wound in multiple oval shapes at both ends of the wound electrode plate group. A step of fitting a current collector having a fitting end portion having a substantially V-shaped cross section and a pair of joining plate portions continuous thereto into the winding center portion of the non-coated portion; There are a step of joining the non-coated portion, and a step of connecting the bipolar current collectors to the external connection terminals, respectively, and housing the electrode plate group in the battery casing.

この構成によると、上記のように体積密度が高くコンパクトな構成で、かつ電極板の塗工部の各部位から集電体に至る通電経路が短くかつ接続抵抗が小さくて高出力の角形電池を容易に生産性良く製造することができる。   According to this configuration, a high-power rectangular battery having a high volume density and a compact configuration as described above, a short energization path from each part of the coating portion of the electrode plate to the current collector, and a low connection resistance. It can be easily manufactured with good productivity.

また、非塗工部を接合板部と当て板で挟持した状態で、接合板部をアンビルで受け、当て板に超音波ホーンを当てて超音波接合すると、各非塗工部に破れ等を生じることなく超音波接合によって接合することができ、生産性良く信頼性の高い接合状態を得ることができる。   In addition, when the non-coated part is sandwiched between the joining plate part and the backing plate, the joining plate part is received by the anvil, and when the ultrasonic horn is applied to the backing plate and ultrasonic joining is performed, each uncoated part is torn. Bonding can be performed by ultrasonic bonding without occurrence, and a highly reliable bonding state with high productivity can be obtained.

また、非塗工部を接合板部と当て板で挟持した状態で、接合板部と当て板に電極を当てて抵抗溶接すると、各非塗工部に破れや局部的な溶損などを生じることなく、信頼性の高い溶接接合状態を生産性良く得ることができる。   In addition, when resistance welding is performed by applying an electrode to the joining plate portion and the contact plate in a state where the uncoated portion is sandwiched between the joining plate portion and the contact plate, each uncoated portion is broken or locally melted. Therefore, a highly reliable welded joint state can be obtained with high productivity.

また、非塗工部を接合板部と当て板で挟持した状態で、摩擦攪拌接合法にて接合すると、熱影響を受けず、振動等による電極板の活物質の脱落の恐れも無く、任意の板厚の集電板と非塗工部との接合も高い信頼性をもって実現できて集電体とリードを一体化でき、部品点数及び接続箇所数を低減できるので、内部抵抗の低減及びコストの大幅な低廉化を図ることができる。   In addition, when the non-coated part is sandwiched between the joining plate part and the contact plate and joined by the friction stir welding method, it is not affected by heat and there is no risk of the active material of the electrode plate falling off due to vibration or the like. The current collector plate with a thickness of 5 mm and non-coated parts can be joined with high reliability, and the current collector and leads can be integrated, reducing the number of parts and the number of connections, reducing internal resistance and cost Can be significantly reduced.

本発明の角形電池とその製造方法によれば、非塗工部の巻回中心部に集電体を容易に嵌入させて外側から接合することで高い作業能率で接続でき、生産性を向上してコスト低下を図れ、また非塗工部の突出長が短くても集電体の先端の嵌入端部が逆極性の電極板と短絡を起こす恐れがないので、体積密度を高くコンパクトに構成でき、また電極板の塗工部の各部位から集電体に至る通電経路も短くかつ接続抵抗を小さくできて高出力を得ることができる。   According to the prismatic battery of the present invention and the manufacturing method thereof, the current collector can be easily inserted into the winding center of the non-coated portion and joined from the outside to be connected with high work efficiency, thereby improving productivity. The cost can be reduced, and even if the protruding length of the non-coated part is short, the insertion end of the current collector does not cause a short circuit with the electrode plate with the opposite polarity. In addition, the energization path from each part of the coating portion of the electrode plate to the current collector can be short, the connection resistance can be reduced, and high output can be obtained.

以下、本発明の角形電池とその製造方法の一実施形態について、図1〜図6を参照して説明する。   Hereinafter, an embodiment of a prismatic battery and a manufacturing method thereof according to the present invention will be described with reference to FIGS.

図1〜図4において、1はリチウムイオン電池から成る角形電池であり、横断面形状が扁平な長方形、若しくは隅丸長方形ないし長円形の有底角筒状のケース2の一端開口に封口板3を密封溶接して電池筐体1Aが構成され、この電池筐体1A内に発電要素としての極板群4を電解液とともに収容して構成されている。本実施形態では、ケース2及び封口板3は鋼板にて構成されている。   1 to 4, reference numeral 1 denotes a prismatic battery made of a lithium ion battery. A sealing plate 3 is provided at one end opening of a case 2 having a flat rectangular shape or a rounded rectangular or oval bottomed rectangular tube shape. Is sealed and welded to form a battery housing 1A, and an electrode plate group 4 as a power generation element is housed in the battery housing 1A together with an electrolyte. In the present embodiment, the case 2 and the sealing plate 3 are made of steel plates.

極板群4は、帯状の正極板とセパレータと負極板とセパレータを順次重ねた状態で薄板状の巻芯材の外周に巻回し、巻回終了後に巻芯材を引き抜いて扁平に圧縮することで構成されており、図6に示すように、正極板4aと負極板4bがそれらの間にセパレータcを介装した状態で積層された構成となっている。特に、本実施形態では巻き始めに1又は複数回セパレータ4cのみを巻回したのち、負極板4bとセパレータ4cと正極板aとセパレータ4cを順に重ねて巻回しており、最内周に1又は複数層のセパレータ4cが配設されている。また、極板群4の最外周も必要に応じて短絡防止のためにセパレータ4cが1又は複数層巻回されている。   The electrode plate group 4 is wound around the outer periphery of a thin plate-shaped core material in a state in which a belt-like positive electrode plate, a separator, a negative electrode plate, and a separator are sequentially stacked, and after completion of the winding, the core material is pulled out and compressed into a flat shape. As shown in FIG. 6, the positive electrode plate 4a and the negative electrode plate 4b are laminated with a separator c interposed therebetween. In particular, in the present embodiment, after winding only the separator 4c one or more times at the beginning of winding, the negative electrode plate 4b, the separator 4c, the positive electrode plate a, and the separator 4c are wound one on top of the other in order. Multiple layers of separators 4c are provided. Further, the outermost periphery of the electrode plate group 4 is also wound with one or more layers of separators 4c to prevent a short circuit if necessary.

正極板4aはアルミ箔から成る芯材に正極合剤を塗着・乾燥して構成されており、かつその一側には正極合剤を塗工しない芯材のみから成る正極の非塗工部5が形成されている。また、負極板4bは銅箔から成る芯材に負極合剤を塗着・乾燥して構成されており、かつその他側には負極合材を塗工しない芯材のみから成る負極の非塗工部6が形成されている。セパレータ4cは微多孔性ポリプロピレンフィルムなどにて構成されている。そして、極板群4において、正極の非塗工部5と負極の非塗工部6が互いに反対側に突出されている。   The positive electrode plate 4a is configured by applying and drying a positive electrode mixture on a core material made of aluminum foil, and on one side of the positive electrode plate 4a, a non-coated portion of the positive electrode consisting only of a core material not coated with the positive electrode mixture 5 is formed. The negative electrode plate 4b is formed by applying and drying a negative electrode mixture on a core material made of copper foil, and the other side is not coated with a negative electrode consisting only of a core material to which no negative electrode mixture is applied. Part 6 is formed. The separator 4c is made of a microporous polypropylene film or the like. In the electrode plate group 4, the non-coated portion 5 of the positive electrode and the non-coated portion 6 of the negative electrode protrude on the opposite sides.

極板群4の上端側に突出している正極の非塗工部5にはアルミ板から成る正極の集電体7が接合されている。詳しくは、図2に詳細に示すように、極板群3の上端部で多重長円形に巻回されている非塗工部5の巻回中心部に、断面略V字状の嵌入端部7aとそれに連続してV字状に開いた一対の接合板部7bを有する集電体7を嵌入させ、その両接合板部7bの外面に非塗工部5の積層群を押し当て、さらにその外側に当て板9を配置し、接合板部7bと当て板9の間に非塗工部5の積層群を挟持した状態で超音波溶接や抵抗溶接やFSW法などで接合されている。   A positive electrode current collector 7 made of an aluminum plate is joined to a positive electrode non-coating portion 5 protruding to the upper end side of the electrode plate group 4. Specifically, as shown in detail in FIG. 2, an insertion end portion having a substantially V-shaped cross section at the winding center portion of the non-coated portion 5 wound in a multiple oval shape at the upper end portion of the electrode plate group 3. 7a and a current collector 7 having a pair of joint plate portions 7b that are continuously opened in a V shape are fitted, and the laminated group of the non-coated portions 5 is pressed against the outer surface of both joint plate portions 7b. The contact plate 9 is disposed outside thereof, and is joined by ultrasonic welding, resistance welding, FSW method, or the like in a state where the laminated group of the non-coated portions 5 is sandwiched between the joining plate portion 7 b and the contact plate 9.

また、極板群3の下端側に突出している負極の非塗工部6には銅板若しくはその表面にニッケルメッキを施した負極の集電体8が接合されている。詳しくは、図3に詳細に示すように、極板群3の下端部で多重長円形に巻回されている非塗工部6の巻回中心部に、断面略V字状の嵌入端部8aとそれに連続して平行に立ち上げ形成された一対の接合板部8bを有する集電体8を嵌入させ、その両接合板部8bの外面に非塗工部6の積層群を押し当て、さらにその外側に当て板10を配置し、接合板部8bと当て板10の間に非塗工部6の積層群を挟持した状態で超音波溶接や抵抗溶接やFSW法などで接合されている。   Further, a negative electrode non-coating portion 6 protruding to the lower end side of the electrode plate group 3 is joined to a copper plate or a negative electrode current collector 8 having a nickel plating on the surface thereof. Specifically, as shown in detail in FIG. 3, an insertion end portion having a substantially V-shaped cross section at the winding center portion of the non-coated portion 6 wound in a multiple oval shape at the lower end portion of the electrode plate group 3. 8a and a current collector 8 having a pair of joining plate portions 8b formed so as to be continuously raised in parallel therewith, and the laminated group of the non-coated portions 6 is pressed against the outer surfaces of both the joining plate portions 8b. Further, the backing plate 10 is arranged outside thereof, and is joined by ultrasonic welding, resistance welding, FSW method or the like with the laminated group of the non-coated portions 6 sandwiched between the joining plate portion 8b and the backing plate 10. .

正極の集電体7は、図2と図4に示すように、一方の接合板部7bの一端部から接続片7cが立ち上げ形成され、この接続片7cが封口板3の内面に絶縁部材12を介して配設されたリード板13の一端部から垂下された接続片13aにスポット溶接にて接合されている。封口板3には、正極の外部接続端子11を貫通させる端子貫通穴15が形成れており、外部接続端子11は上記絶縁部材12及び端子貫通穴15の内周と封口板3の上面との間に介装される絶縁部材14を介して絶縁状態で装着固定されている。外部接続端子11は、フィルタ11a内にインナーガスケット11bを介して安全弁機構11cとキャップ11dを収容配置して構成されており、フィルタ11aの下端部をかしめることで封口板3にリード板13とともに装着固定されている。   As shown in FIGS. 2 and 4, the positive electrode current collector 7 is formed with a connection piece 7 c raised from one end of one joining plate portion 7 b, and this connection piece 7 c is formed on the inner surface of the sealing plate 3. 12 is joined to a connecting piece 13a suspended from one end of a lead plate 13 disposed via 12 by spot welding. The sealing plate 3 is formed with a terminal through hole 15 that allows the positive external connection terminal 11 to pass through. The external connection terminal 11 is formed between the inner periphery of the insulating member 12 and the terminal through hole 15 and the upper surface of the sealing plate 3. It is mounted and fixed in an insulated state via an insulating member 14 interposed therebetween. The external connection terminal 11 is configured by accommodating and arranging a safety valve mechanism 11c and a cap 11d in the filter 11a via an inner gasket 11b, and caulking the lower end of the filter 11a together with the sealing plate 3 and the lead plate 13. It is fixed.

負極の集電体8は、図3と図4に示すように、一方の接合板部8bの一端部から他方の接合板部8bに向けて折曲されるとともに一端外方に向けて長く延びる接続片8cが突出形成され、この接続片8cがリード板16に接続されている。リード板16は、通電抵抗を小さくするため、断面積の大きい導電性板材にて構成されており、図1及び図4に示すように、ケース2の一側の短壁内面に沿って配設され、その上下端からL字状に接続部16a、16bが折り曲げ形成され、上端の接続部16aが封口板3にスポット溶接等にて接合され、下端の接続部16bが接続片8cにスポット溶接等にて接合されている。かくして、負極の外部接続端子は封口板3、若しくはそれに固着された端子部材にて構成される。   As shown in FIGS. 3 and 4, the negative electrode current collector 8 is bent from one end portion of one joining plate portion 8 b toward the other joining plate portion 8 b and extends long outward toward one end. A connection piece 8 c is formed so as to protrude, and this connection piece 8 c is connected to the lead plate 16. The lead plate 16 is composed of a conductive plate material having a large cross-sectional area in order to reduce current resistance, and is disposed along the inner surface of the short wall on one side of the case 2 as shown in FIGS. The connecting portions 16a and 16b are bent in an L shape from the upper and lower ends, the upper connecting portion 16a is joined to the sealing plate 3 by spot welding or the like, and the lower connecting portion 16b is spot welded to the connecting piece 8c. Etc. are joined. Thus, the negative external connection terminal is constituted by the sealing plate 3 or a terminal member fixed thereto.

また、負極の非塗工部6に負極の集電体8を超音波接合する場合には、図5に示すように、接合板部8b、8b間にアンビル21を挿入して支持し、当て板10の外面側に超音波ホーン22を押し付けて超音波振動エネルギーを付与することで、超音波接合することができる。また、抵抗溶接にて接合する場合には、アンビル21と超音波ホーン22に代えて溶接電極を用い、溶接電流を流すことで溶接することができる。さらに、FSW法にて接合する場合は、アンビル21にて接合板部8b、8bを支持した状態で、当て板10の外側から大径のショルダと小径のピンを有する工具を高速で回転させながら押し付け、摩擦攪拌しながら走査することで任意長の接合部を形成することができる。このFSW法はセパレータ等に与える熱影響が少なく、抵抗溶接等によるスパッタやヒュームやチリなどを発生せず、超音波接合の場合のように振動による活物質の剥離の恐れもなく、さらに任意の肉厚の集電体でも適正に接合できるので、リード板16と一体化して部品点数の低減も図れるなどの利点があって好適である。なお、図5の例では負極の集電体8と負極の非塗工部6との接合の例を図示して説明したが、正極の集電体6と正極の非塗工部5との接合においても当然適用することができる。   Further, when the negative electrode current collector 8 is ultrasonically bonded to the negative electrode non-coated portion 6, as shown in FIG. 5, an anvil 21 is inserted and supported between the bonding plate portions 8b and 8b. Ultrasonic bonding can be performed by pressing the ultrasonic horn 22 against the outer surface side of the plate 10 and applying ultrasonic vibration energy. Moreover, when joining by resistance welding, it can replace by using the welding electrode instead of the anvil 21 and the ultrasonic horn 22, and can be welded by sending a welding current. Further, when joining by the FSW method, while the joining plate portions 8b and 8b are supported by the anvil 21, a tool having a large diameter shoulder and a small diameter pin is rotated at high speed from the outside of the backing plate 10. An arbitrary-length joint can be formed by scanning while pressing and friction stirring. This FSW method has little thermal effect on the separator, etc., does not generate spatter, fume, dust, etc. due to resistance welding, etc., and there is no fear of peeling of the active material due to vibration as in the case of ultrasonic bonding. Even a thick current collector can be appropriately joined, which is advantageous in that it can be integrated with the lead plate 16 to reduce the number of parts. In the example of FIG. 5, the example of joining of the negative electrode current collector 8 and the negative electrode non-coated portion 6 is illustrated and described. However, the positive electrode current collector 6 and the positive electrode non-coated portion 5 Of course, it can also be applied to bonding.

次に、以上の構成の角形電池1の製造工程の一例を、図4を参照して説明する。帯状の正極板と負極板をセパレータを介して重ねて巻回して極板群4を製造した後、極板群4の両端に突出させた非塗工部5、6の巻回中心部に、断面略V字状の嵌入端部7a、8aとそれに連続する一対の接合板部7b、8bを有する集電体7、8をそれぞれ嵌入させ、非塗工部5、6の外面に当て板9、10を当てた状態で、これら集電体7、8と非塗工部5、6を超音波接合、抵抗溶接、FSW法などで接合する。   Next, an example of the manufacturing process of the prismatic battery 1 having the above configuration will be described with reference to FIG. After producing the electrode plate group 4 by stacking and winding the belt-like positive electrode plate and the negative electrode plate with a separator interposed between them, the winding center portions of the non-coated parts 5 and 6 projected from both ends of the electrode plate group 4 are Current collectors 7 and 8 having fitting end portions 7a and 8a having a substantially V-shaped cross section and a pair of joining plate portions 7b and 8b continuous thereto are fitted, respectively, and a contact plate 9 is placed on the outer surface of the non-coated portions 5 and 6. 10 are applied, and the current collectors 7 and 8 and the non-coated portions 5 and 6 are joined by ultrasonic joining, resistance welding, FSW method, or the like.

また、封口板3に対して外部接続端子11とリード板13を装着固定し、負極の集電体8の接続片8cに対してリード板16の下端の接続部16bを溶接接合する。次に、正極の集電体7の接続片7cをリード板13の接続片13aに溶接接合するとともに、リード板16の上端の接続部16aを封口板3に溶接接合する。その後、この極板群4と封口板3を一体化したものをケース2内に挿入し、封口板3の外周に立ち上げ形成された立ち上げ部3aの端縁とケース2の開口端縁とをレーザ溶接し、形成された溶接部23にて密封接合する。その後、封口板3に形成された注液口24から電解液を注液し、封栓25にて密封することで角形電池1が完成する。   Further, the external connection terminal 11 and the lead plate 13 are attached and fixed to the sealing plate 3, and the connection portion 16 b at the lower end of the lead plate 16 is welded to the connection piece 8 c of the negative electrode current collector 8. Next, the connecting piece 7 c of the positive electrode current collector 7 is welded to the connecting piece 13 a of the lead plate 13, and the connecting portion 16 a at the upper end of the lead plate 16 is welded to the sealing plate 3. Thereafter, the electrode plate group 4 and the sealing plate 3 integrated with each other are inserted into the case 2, and the edge of the rising portion 3 a formed on the outer periphery of the sealing plate 3 and the opening edge of the case 2 are Are welded in a sealed manner at the formed weld 23. Thereafter, the electrolytic solution is injected from the injection port 24 formed in the sealing plate 3 and sealed with the sealing plug 25, thereby completing the rectangular battery 1.

以上の本実施形態によれば、極板群4の両端で多重長円形に巻回されて突出している非塗工部5、6の巻回中心部には、非塗工部5、6の多重積層部に比して大きな隙間が形成されているため、集電体7、8の断面略V字状の嵌入端部7a、8aを容易に嵌入させることができ、その後外側から集電体7、8に対して非塗工部5、6の接合を行うことができるので、高い作業能率で接合することができる。したがって、生産性が高くコスト低下を図ることができる。   According to the present embodiment described above, the winding center portions of the non-coated portions 5 and 6 that are wound in a multi-oval shape at both ends of the electrode plate group 4 and project are provided at the winding center portions of the non-coated portions 5 and 6. Since a large gap is formed as compared to the multi-layered portion, the fitting end portions 7a and 8a having a substantially V-shaped cross section of the current collectors 7 and 8 can be easily fitted, and then the current collector from the outside. Since the non-coated portions 5 and 6 can be joined to 7 and 8, they can be joined with high work efficiency. Therefore, productivity is high and cost reduction can be achieved.

また、上記接合に際して、集電体7、8の両接合板部7b、8bと当て板9、10との間に非塗工部5、6群を挟持した状態で接合しているので、非塗工部5、6における超音波ホーン22や電極などの溶接工具の当接部が局部的に破断したり、溶損したりすることなく、信頼性の高い接合状態を確保することができる。   In addition, since the non-coating portions 5 and 6 are sandwiched between the joining plate portions 7b and 8b of the current collectors 7 and 8 and the contact plates 9 and 10 during the joining, The contact part of welding tools, such as the ultrasonic horn 22 and an electrode in the coating parts 5 and 6, does not fracture | rupture locally or melt | dissolve, but can ensure a reliable joining state.

また、多重長円形に巻回されている非塗工部5、6がその周方向2箇所で集電体7、8と溶接にて接続されるので、電極板の塗工部の各部位から集電体7、8に至る通電経路を短くかつ接続抵抗を小さくできて高出力を得ることができる。   In addition, since the non-coated portions 5 and 6 wound in a multi-oval shape are connected to the current collectors 7 and 8 by welding at two locations in the circumferential direction, from each portion of the coated portion of the electrode plate The energization path leading to the current collectors 7 and 8 can be shortened, the connection resistance can be reduced, and a high output can be obtained.

また、本実施形態によれば、極板群4の巻き始めにセパレータ4cのみを1又は複数回巻回しているので、図6に示すように、極板群4の最内周がセパレータとなっており、そのためセパレータ4c、4cの間に集電体8の嵌入端部8aを嵌入させることになり、集電体8の嵌入端部8aが逆極性の正極板4aと短絡を起こす恐れをより簡単かつ確実に無くすことができる。また、図示していないが、正極の集電体7と正極の非塗工部5の場合も同様であるが、特に正極の集電体7の場合には、最内側の電極板である逆極性の負極板4bとの短絡を起こす恐れを確実に無くすことができるので、特に効果的である。   Further, according to the present embodiment, since only the separator 4c is wound one or more times at the beginning of winding of the electrode plate group 4, as shown in FIG. 6, the innermost periphery of the electrode plate group 4 is a separator. Therefore, the insertion end portion 8a of the current collector 8 is inserted between the separators 4c and 4c, and the insertion end portion 8a of the current collector 8 is more likely to cause a short circuit with the positive electrode plate 4a having the reverse polarity. It can be easily and reliably eliminated. Although not shown, the same applies to the positive electrode current collector 7 and the positive electrode non-coated portion 5, but in the case of the positive electrode current collector 7, the reverse of the innermost electrode plate. This is particularly effective because the possibility of causing a short circuit with the polar negative electrode plate 4b can be reliably eliminated.

なお、極板群4の最内周がセパレータ4cとなっていない場合でも、通常極板群4では最内周は負極板4bとされるので、負極の集電体8の嵌入端部8aは最内周の負極板4bの非塗工部6の間に嵌入させることになるため、非塗工部6の突出長が短くても集電体8の先端の嵌入端部8aが逆極性の正極板4aと短絡を起こす恐れがない。また、正極の集電体7側では、集電体7の極性とは逆極性の最内周の負極板4bの端縁の周囲を取り囲むようにセパレータ4cが存在し、その周囲を正極板4aの非塗工部5が取り囲んでいるため、セパレータ4cを内側に折り込んで負極板4bの端縁上に重ねて覆った状態で、集電体7の嵌入端部7aを正極板4aの非塗工部5の間の隙間に嵌入させることによって、非塗工部5の突出長が短くても集電体7の先端の嵌入端部7aが負極板4bと短絡を起こす恐れを無くすことができる。かくして、体積密度を高く、コンパクトに構成することができる。   Even when the innermost periphery of the electrode plate group 4 is not the separator 4c, the innermost periphery is usually the negative electrode plate 4b in the electrode plate group 4, so that the insertion end 8a of the negative electrode current collector 8 is Since it is inserted between the non-coated portions 6 of the innermost negative electrode plate 4b, the insertion end portion 8a at the tip of the current collector 8 has a reverse polarity even if the protruding length of the non-coated portion 6 is short. There is no risk of short circuit with the positive electrode plate 4a. On the current collector 7 side of the positive electrode, a separator 4c exists so as to surround the periphery of the innermost negative electrode plate 4b having a polarity opposite to the polarity of the current collector 7, and the periphery of the separator 4c surrounds the positive electrode plate 4a. Since the separator 4c is folded inward and overlaid on the edge of the negative electrode plate 4b, the insertion end portion 7a of the current collector 7 is covered with the non-coated portion of the positive electrode plate 4a. By fitting in the gaps between the working parts 5, it is possible to eliminate the possibility that the fitting end part 7a at the tip of the current collector 7 will cause a short circuit with the negative electrode plate 4b even if the protruding length of the non-coated part 5 is short. . Thus, the volume density can be increased and the configuration can be made compact.

以上の実施形態の集電体7、8においては、別部材の当て板9、10を用いたが、図7に示すように、V字状の嵌入端部18aと両接合板部18bを有する集電部18と当て板19の両端間を1又は複数の連結片20を介して一体連結して、断面方向の形状を略M字状とした集電体17を用いることもできる。このような集電体17を用いると、集電部18と当て板19を一体部品として取扱うことができるので、部品コスト及び生産能率を向上できるとともに、連結片20のみで連結しているため接合板部18bと当て板19の連結部の剛性が小さく、それらの間で非塗工部6、若しくは非塗工部5を容易に挟持することができ、また超音波接合時に当て板19の振動を阻害したり、抵抗溶接時に短絡電流が大きく溶接不可能になるというような不具合を生じる恐れがない。   In the current collectors 7 and 8 of the above embodiment, the contact plates 9 and 10 which are separate members are used. However, as shown in FIG. 7, the current collectors 7 and 8 have a V-shaped fitting end portion 18 a and both joint plate portions 18 b. It is also possible to use a current collector 17 in which the ends of the current collector 18 and the contact plate 19 are integrally connected via one or a plurality of connecting pieces 20 so that the cross-sectional shape is substantially M-shaped. When such a current collector 17 is used, the current collector 18 and the contact plate 19 can be handled as an integral part, so that the parts cost and production efficiency can be improved, and since the connection is made only by the connection piece 20, the connection is achieved. The connecting portion between the plate portion 18b and the contact plate 19 has a small rigidity, and the non-coated portion 6 or the non-coated portion 5 can be easily sandwiched between them. There is no possibility of causing a problem that the short circuit current is large at the time of resistance welding and welding becomes impossible.

本発明の角形電池は、非塗工部の巻回中心部に集電体を容易に嵌入させて外側から接合することで高い作業能率で接続でき、生産性を向上してコスト低下を図れ、また非塗工部の突出長が短くても集電体の先端の嵌入端部が逆極性の電極板と短絡を起こす恐れがないので、体積密度を高くコンパクトに構成でき、また電極板の塗工部の各部位から集電体に至る通電経路も短くかつ接続抵抗を小さくできて高出力を得ることができ、リチウムイオン電池、ニッケル水素電池などの各種角形電池に有用である。   The prismatic battery of the present invention can be connected with high work efficiency by easily fitting the current collector into the winding center of the non-coated part and joining from the outside, improving productivity and reducing cost, In addition, even if the protruding length of the non-coated part is short, there is no possibility that the insertion end at the tip of the current collector will cause a short circuit with the electrode plate having the opposite polarity, so that the volume density can be increased and the structure can be made compact. The energization path from each part of the working part to the current collector is also short, the connection resistance can be reduced, and high output can be obtained, which is useful for various rectangular batteries such as lithium ion batteries and nickel metal hydride batteries.

本発明の一実施形態の角形電池の全体構成を示し、(a)は縦断正面図、(b)は縦断側面図である。BRIEF DESCRIPTION OF THE DRAWINGS The whole structure of the square battery of one Embodiment of this invention is shown, (a) is a vertical front view, (b) is a vertical side view. 同実施形態の角形電池における正極の集電体の周辺部の拡大詳細断面図である。It is an expanded detailed sectional view of the peripheral part of the current collector of the positive electrode in the prismatic battery of the same embodiment. 同実施形態の角形電池における負極の集電体の周辺部の拡大詳細断面図である。FIG. 3 is an enlarged detailed cross-sectional view of a peripheral portion of a negative electrode current collector in the rectangular battery of the same embodiment. 同実施形態の角形電池のケースを省略して示した概略分解斜視図である。It is the general | schematic disassembled perspective view which abbreviate | omitted and showed the case of the square battery of the embodiment. 同実施形態における集電体と非塗工部の接合工程の説明図である。It is explanatory drawing of the joining process of the electrical power collector in the same embodiment, and a non-coating part. 同実施形態において集電体の嵌入端部を嵌入させた状態を示す拡大断面図である。It is an expanded sectional view showing the state where the insertion end of the current collector was inserted in the embodiment. 本発明の他の実施形態の角形電池における集電体と非塗工部の接合工程の説明図である。It is explanatory drawing of the joining process of the electrical power collector and non-coating part in the square battery of other embodiment of this invention.

符号の説明Explanation of symbols

1 角形電池
1A 電池筐体
4 極板群
4a 正極板
4b 負極板
4c セパレータ
5 正極の非塗工部
6 負極の非塗工部
7 正極の集電体
7a 嵌入端部
7b 接合板部
8 負極の集電体
8a 嵌入端部
8b 接合板部
9 当て板
10 当て板
17 集電体
18b 接合板部
19 当て板
20 連結片
21 アンビル
22 超音波ホーン
DESCRIPTION OF SYMBOLS 1 Square battery 1A Battery housing 4 Electrode plate group 4a Positive electrode plate 4b Negative electrode plate 4c Separator 5 Positive electrode non-coating part 6 Negative electrode non-coating part 7 Positive electrode collector 7a Insertion end part 7b Bonding plate part 8 Current collector 8a Insertion end portion 8b Joint plate portion 9 Contact plate 10 Contact plate 17 Current collector 18b Joint plate portion 19 Contact plate 20 Connecting piece 21 Anvil 22 Ultrasonic horn

Claims (8)

角形の電池筐体内に、帯状の正極板と負極板をセパレータを介して重ねて巻回して成りかつ巻回軸方向の両端部にそれぞれ正極板と負極板の非塗工部が突出されている極板群と電解液とを収容して成る角形電池であって、少なくとも前記両端部のうちの一端部は、断面略V字状の嵌入端部とそれに連続する一対の接合板部を有する集電体を、多重長円形に巻回されている非塗工部の巻回中心部に嵌入させ、両接合板部とその外側の非塗工部とを接合したことを特徴とする角形電池。   In a rectangular battery casing, a belt-like positive electrode plate and a negative electrode plate are overlapped and wound with a separator interposed therebetween, and uncoated portions of the positive electrode plate and the negative electrode plate protrude from both ends in the winding axis direction, respectively. A prismatic battery containing an electrode plate group and an electrolyte solution, wherein at least one end portion of the both end portions has a fitting end portion having a substantially V-shaped cross section and a pair of joining plate portions continuous thereto. A prismatic battery characterized in that an electric body is fitted into a winding center portion of a non-coated portion wound in a multi-oval shape, and both the joining plate portions and the non-coated portion outside thereof are joined. 極板群は、巻き始めにセパレータのみを1又は複数回巻回したものであることを特徴とする請求項1記載の角形電池。   The prismatic battery according to claim 1, wherein the electrode plate group is formed by winding only the separator one or more times at the beginning of winding. 両接合板部と当て板との間に非塗工部を挟持した状態で接合したことを特徴とする請求項1又は2記載の角形電池。   The prismatic battery according to claim 1 or 2, wherein the non-coating portion is sandwiched between both the joining plate portions and the contact plate. 両接合板部と当て板を連結片を介して一体連結し、集電体の断面方向の形状を略M字状としたことを特徴とする請求項3記載の角形電池。   4. The prismatic battery according to claim 3, wherein both the joining plate portion and the contact plate are integrally connected through a connecting piece, and the shape of the current collector in the cross-sectional direction is substantially M-shaped. 角形の電池筐体内に、帯状の正極板と負極板をセパレータを介して重ねて巻回して成りかつ巻回軸方向の両端部にそれぞれ正極板と負極板の非塗工部が突出されている極板群と電解液とを収容して成る角形電池の製造方法であって、巻回形成した極板群の両端における多重長円形に巻回されている非塗工部の巻回中心部に、断面略V字状の嵌入端部とそれに連続する一対の接合板部を有する集電体を嵌入させる工程と、両接合板部とその外側の非塗工部を接合する工程と、両極性の集電体をそれぞれ外部接続端子に接続し、極板群を電池筐体内に収容する工程とを有することを特徴とする角形電池の製造方法。   In a rectangular battery casing, a belt-like positive electrode plate and a negative electrode plate are overlapped and wound with a separator interposed therebetween, and uncoated portions of the positive electrode plate and the negative electrode plate protrude from both ends in the winding axis direction, respectively. A method of manufacturing a prismatic battery containing an electrode plate group and an electrolyte solution, wherein a winding center portion of a non-coated portion wound in a multiple oval shape is wound at both ends of the wound electrode plate group. , A step of inserting a current collector having a fitting end portion having a substantially V-shaped cross section and a pair of joining plate portions continuous thereto, a step of joining both the joining plate portions and the non-coating portion outside thereof, and bipolar And a step of housing the electrode plate group in a battery casing. 非塗工部を接合板部と当て板で挟持した状態で、接合板部をアンビルで受け、当て板に超音波ホーンを当てて超音波接合することを特徴とする請求項5記載の角形電池の製造方法。   6. The prismatic battery according to claim 5, wherein the non-coated portion is sandwiched between the joining plate portion and the contact plate, the joining plate portion is received by an anvil, and an ultrasonic horn is applied to the contact plate for ultrasonic joining. Manufacturing method. 非塗工部を接合板部と当て板で挟持した状態で、接合板部と当て板に電極を当てて抵抗溶接することを特徴とする請求項5記載の角形電池の製造方法。   6. The method for manufacturing a prismatic battery according to claim 5, wherein the non-coated portion is sandwiched between the joining plate portion and the contact plate, and resistance welding is performed by applying an electrode to the joining plate portion and the contact plate. 非塗工部を接合板部と当て板で挟持した状態で、摩擦攪拌接合法にて接合することを特徴とする請求項5記載の角形電池の製造方法。
6. The method for manufacturing a prismatic battery according to claim 5, wherein the non-coated portion is joined by a friction stir welding method in a state where the non-coated portion is sandwiched between the joining plate portion and the contact plate.
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