JP2004315457A5 - - Google Patents
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- Publication number
- JP2004315457A5 JP2004315457A5 JP2003113215A JP2003113215A JP2004315457A5 JP 2004315457 A5 JP2004315457 A5 JP 2004315457A5 JP 2003113215 A JP2003113215 A JP 2003113215A JP 2003113215 A JP2003113215 A JP 2003113215A JP 2004315457 A5 JP2004315457 A5 JP 2004315457A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- carbon atoms
- palladium
- general formula
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 125000004432 carbon atom Chemical group C* 0.000 description 29
- 125000000217 alkyl group Chemical group 0.000 description 14
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 11
- 229910052763 palladium Inorganic materials 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- -1 phosphine compound Chemical class 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 125000003277 amino group Chemical group 0.000 description 4
- 125000004093 cyano group Chemical group *C#N 0.000 description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 4
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 3
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 3
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 150000002941 palladium compounds Chemical class 0.000 description 3
- 0 CC(*)(*)C(*)N Chemical compound CC(*)(*)C(*)N 0.000 description 2
- 125000004414 alkyl thio group Chemical group 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 150000001543 aryl boronic acids Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000002933 cyclohexyloxy group Chemical group C1(CCCCC1)O* 0.000 description 1
- YFXCNIVBAVFOBX-UHFFFAOYSA-N ethenylboronic acid Chemical compound OB(O)C=C YFXCNIVBAVFOBX-UHFFFAOYSA-N 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000006678 phenoxycarbonyl group Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003113215A JP4338426B2 (ja) | 2003-04-17 | 2003-04-17 | パラジウム錯体触媒を利用した電子吸引性基置換化合物の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003113215A JP4338426B2 (ja) | 2003-04-17 | 2003-04-17 | パラジウム錯体触媒を利用した電子吸引性基置換化合物の製造方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004315457A JP2004315457A (ja) | 2004-11-11 |
| JP2004315457A5 true JP2004315457A5 (enExample) | 2006-06-08 |
| JP4338426B2 JP4338426B2 (ja) | 2009-10-07 |
Family
ID=33473212
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003113215A Expired - Fee Related JP4338426B2 (ja) | 2003-04-17 | 2003-04-17 | パラジウム錯体触媒を利用した電子吸引性基置換化合物の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4338426B2 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1854802A4 (en) * | 2005-02-17 | 2008-06-25 | Japan Science & Tech Agency | A CATALYST FOR ASYMMETRIC SYNTHESIS, LIGAND FOR THE USE THEREOF, AND METHOD FOR PRODUCING OPTICALLY ACTIVE CONNECTION BY AN ASYMMETRIC SYNTHESIS ACTION USING THE SAME |
| JP5021248B2 (ja) * | 2006-07-19 | 2012-09-05 | 国立大学法人北海道大学 | 光学活性化合物の製造方法 |
| DE102009055183B3 (de) * | 2009-12-22 | 2011-12-08 | Chiroblock Gmbh | Verfahren zur Herstellung arylsubstituierter Nitroalkanderivate |
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2003
- 2003-04-17 JP JP2003113215A patent/JP4338426B2/ja not_active Expired - Fee Related