JP2004049941A - Treatment method and apparatus for combined sewage under rainy weather - Google Patents

Treatment method and apparatus for combined sewage under rainy weather Download PDF

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Publication number
JP2004049941A
JP2004049941A JP2002207107A JP2002207107A JP2004049941A JP 2004049941 A JP2004049941 A JP 2004049941A JP 2002207107 A JP2002207107 A JP 2002207107A JP 2002207107 A JP2002207107 A JP 2002207107A JP 2004049941 A JP2004049941 A JP 2004049941A
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Japan
Prior art keywords
sludge
sewage
rainy weather
biological
separated
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JP2002207107A
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JP3700938B2 (en
Inventor
Katsuyuki Kataoka
片岡 克之
Toshihiro Tanaka
田中 俊博
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Ebara Corp
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Ebara Corp
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  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Treatment Of Sludge (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To effectively utilize solid-liquid separated sludge discharged from a solid-liquid separator for sewage under rainy weather to improve the effect of biological dephosphorization and denitrification treatment of the sewage. <P>SOLUTION: The treatment method comprises coagulating and separating at least part of the sewage under rainy weather and feeding the coagulated and separated sludge to an anaerobic section or a biological denitrification section of a biological dephosphorization step of a sewage treatment facility. After the coagulated and separated sludge is subjected to acid fermentation, the sludge is fed to the anaerobic section or biological denitrification section of the biological dephosphorization step of the sewage treatment facility. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、有機性の懸濁粒子を含有する合流式下水道の雨天時越流水(CSOと略称される)、又は下水処理施設に流入する増量した下水の浄化、脱窒素処理装置に関する。
【0002】
【従来の技術】
最近合流式下水道における雨天時越流水(CSO)の公共用水域への汚濁負荷が大きな問題になっている。合流式下水道の雨天時越流水(CSO)は短時間に膨大な水量が発生するので、高速度で固液分離でき、SSが除去された処理水を公共用水域に放流する技術が適用される。
【0003】
また、下水処理施設に流入する雨天時下水は、水量が晴天時よりも大きく増加するので、図2を借りて説明すると、雨天時下水1の一部である晴天時下水の量に相当する部分が最初沈殿池2で沈殿分離されたのち、活性汚泥処理工程4で活性汚泥処理され、残りの下水1aはそのまま公共用水域に放流水として放流されていたが、最近図2に示すように、残りの下水1aについてこれを凝集分離工程16で凝集分離して分離水17を放流する方式が検討されている。なお、図2は残りの下水1aについて凝集分離を行う最近の雨天時下水方式を示したブロック図であり、6は最終沈殿池である。
しかし、最近のいずれの方式も凝集分離汚泥の処理処分法は、凝集分離汚泥18を下水処理場の最初沈殿池2に流入させ、沈殿分離し、沈殿汚泥を汚泥処理するという方法が適用され、凝集分離汚泥の有効利用が検討されていなかった。
【0004】
【発明が解決しようとする課題】
本発明は、このような実情に鑑みてなされたものであり、雨天時下水の凝集分離装置から排出される凝集分離汚泥を、下水の生物学的脱リン、脱窒素処理効果を向上させるのに有効利用できる新概念を提供することを課題とする。
【0005】
【課題を解決するための手段】
本発明は、以下の手段により上記課題を解決することができた。
(1)雨天時下水の少なくとも一部を凝集分離し、該凝集分離汚泥を、下水処理施設の生物脱リン工程の嫌気部、又は生物学的脱窒素部に供給することを特徴とする合流式下水の処理方法。
(2)前記凝集分離汚泥を酸発酵させたのち、下水処理施設の生物脱リン工程の嫌気部、または生物学的脱窒素部に供給することを特徴とする前記(1)記載の下水処理方法。
【0006】
(3)雨天時の増量した合流式下水を浄化するための処理装置において、雨天時に増量した流入下水の少なくとも一部を導入して分離水と凝集分離汚泥に分離する凝集分離装置と、前記分離水を放流する配管と、前記流入下水の一部を導入して分離水と沈殿汚泥に分離する最初沈殿池と、前記最初沈殿池からの分離水と該凝集分離装置からの凝集沈殿汚泥とを導入して脱リンする嫌気部、脱窒部、又は好気部を有する嫌気好気式生物脱リン設備と、前記脱リン設備からの汚泥を含有する被脱リン水を導入して処理水と沈殿汚泥に分離する最終沈殿池とを有することを特徴とする雨天時の合流式下水の処理装置。
(4)前記凝集分離装置からの凝集分離汚泥を酸発酵槽に導入し、前記酸発酵槽からの酸発酵汚泥を嫌気好気式生物脱リン設備の嫌気部に送る配管を設けたことを特徴とする前記(3)記載の雨天時の合流式下水の処理装置。
【0007】
【発明の実施の形態】
以下、本発明の実施の形態を図面に基づいて説明する。
図1は、本発明の雨天時の合流式下水の処理装置の一実施態様を示すブロック図である。
図2で示した部分と同一機能を有する部分は同一符号を用いて示す。
【0008】
雨天時下水1の一部1aに凝集剤(無機凝集剤、高分子凝集剤、これらの併用)を添加して、凝集分離工程18で凝集分離する。凝集分離法としては、たとえば凝集沈殿、凝集浮上分離、疎ろ材による凝集ろ過などのいずれかを適用する。凝集分離工程18では、雨天時下水1aのSS、リン、SS性BOD、CODが除去された分離水19と下水中の有機物を豊富に取り込んだ凝集分離汚泥20とが分離される。
一方、雨天時下水1の残りは、最初沈殿池2で、SSがある程度沈殿分離され、分離水が生物脱リン工程(方法の意味で「生物脱リンプロセス」ともいう)12又は生物学的硝化脱窒素工程(方法の意味で「生物学的硝化脱窒素プロセス」ともいう)13によって活性汚泥処理されたのち、活性汚泥混合液6から活性汚泥が最終沈殿池7で沈殿分離されて処理水8となる。
【0009】
しかし、雨天時には、生物脱リンプロセス12又は生物学的硝化脱窒素プロセス13に供給される有機物が雨水によって希釈され、有機物濃度が減少するため、生物脱リン菌からのリン吐き出しが不十分になり、リン除去効果が悪化する問題があった。また脱窒素菌のための有機炭素源が不足するため、脱窒素反応が充分進まないという問題が起きていた。
【0010】
本発明のポイントは、前記凝集分離汚泥20を、生物脱リンプロセス12の嫌気部14、又は生物学的硝化脱窒素プロセス13の脱窒素部15に供給し、凝集分離汚泥20中の豊富な有機物を、生物脱リンプロセス12などにおける生物脱リン菌のリン吐き出し促進又は脱窒素菌の水素供与体として活用する点、及び凝集分離汚泥20中の水酸化鉄、水酸化アルミニウムがリン吸着能力を残存しているため、これを生物脱リンプロセス12などの中の生物処理工程に流入する下水1中のリン除去に活用する点である。
この技術によって、雨天時の場合でも、生物脱リン工程の嫌気部14、または生物学的脱窒素部15における有機物が不足することが無くなり、効果的に生物脱リン、脱窒素反応を進ませることができるようになったのである。
【0011】
他の好ましい実施態様として、凝集分離汚泥20を、酸発酵部21で常温又は加温条件下(温度30〜40℃程度)で、嫌気的に滞留させ生物学的に酸発酵させたのち、酸発酵汚泥22を生物脱リン工程の嫌気部14、または生物学的脱窒素部15に供給すると、さらにリン吐き出し促進、もしくは脱窒素促進に効果的である。
なお、図1において、11は余剰汚泥、3は最初沈殿池2からの初沈汚泥である。
【0012】
【実施例】
以下、本発明を実施例により具体的に説明するが、本発明はこれらの実施例により何等制限されるものではない。
【0013】
(実施例1)
雨天時に下水処理場に流入するSS120mg/リットル、BOD80mg/リットル、リン3.6mg/リットルの下水に対して本発明を適用する試験を行った。
先ず流入下水の水量の2/3を分岐し、これに塩化第2鉄を40mg/リットル添加し、1分撹拌したのちアニオン系ポリマ(エバグロースA151;荏原製作所製品)を3mg/リットル添加して1分間撹拌した結果、粒径1cm程度の大粒径フロックが生成し、沈降速度350mm/minで凝集沈殿された。凝集沈殿分離工程から出る分離水のSSは3.6mg/リットル、リンは0.3mg/リットルと少なく、下水中のSS、リンが高度に除去された。
次に流入下水の水量の1/3(この量は晴天時の下水処理量に当たる:設計量)を最初沈殿池に流入させ、沈殿越流水と前記凝集沈殿汚泥を嫌気好気式(AO法)生物脱リン設備に流入させた。この結果、処理水のリンは雨天継続時にも安定して0.1mg/リットル以下であった。
【0014】
(比較例1)
比較のため、凝集沈殿汚泥を最初沈殿池に流入させて沈殿し、最初沈殿池越流水を生物学的脱リン工程の嫌気部に流入させる方法を試験した結果、処理水リンは平均1.6mg/リットルと悪化した。
【0015】
【発明の効果】
本発明によれば、下記の優れた効果が得られる。
(1)雨天時でも生物脱リン、生物学的脱窒素設備の処理水質が悪化しない。
(2)雨天時下水を効果的に浄化でき、雨天時に無処理下水によって公共水域が汚染されない。
(3)雨天時下水の凝集分離汚泥を単に処分するのではなく、下水の浄化に有効利用できる。
【図面の簡単な説明】
【図1】本発明の雨天時の合流式下水の処理装置の一実施態様を示すブロック図である。
【図2】従来の雨天時の合流式下水の処理装置の一実施態様を示すブロック図である。
【符号の説明】
1 雨天時下水
1a 雨天時下水の一部
2 最初沈殿池
3 初沈汚泥
4 分離水
5 活性汚泥処理工程(装置)
6 活性汚泥混合液
7 最終沈殿池
8 処理水
9 分離汚泥
10 返送汚泥
11 余剰汚泥
12 生物学的脱リン工程
13 生物学的硝化脱窒工程
14 嫌気部
15 脱窒素部(生物学的硝化脱窒素工程)
16 好気部(生物学的硝化脱窒素工程)
17 循環液
18 凝集分離工程(装置)
19 分離水
20 凝集分離汚泥
21 酸発酵部
22 酸発酵液
[0001]
TECHNICAL FIELD OF THE INVENTION
TECHNICAL FIELD The present invention relates to a purification and denitrification treatment apparatus for rainwater overflow (abbreviated as CSO) of a combined sewer system containing organic suspended particles, or an increased amount of sewage flowing into a sewage treatment facility.
[0002]
[Prior art]
Recently, the pollution load of public water bodies due to rainfall overflow (CSO) in a combined sewer has become a major problem. Since the stormwater overflow (CSO) of the combined sewer system generates an enormous amount of water in a short time, solid-liquid separation can be performed at a high speed, and a technology of discharging treated water from which SS has been removed to a public water area is applied. .
[0003]
In addition, since the amount of sewage during rainy weather that flows into the sewage treatment facility increases more than that during fine weather, a portion corresponding to the amount of sewage during fine weather, which is a part of the sewage 1 during rainy weather, will be described with reference to FIG. Was first settled and separated in the sedimentation basin 2 and then activated sludge treatment in the activated sludge treatment step 4, and the remaining sewage 1a was discharged as it is to the public water area as effluent water, but recently, as shown in FIG. A method of coagulating and separating the remaining sewage 1a in the coagulation / separation step 16 and discharging the separated water 17 is being studied. FIG. 2 is a block diagram showing a recent rainy sewage system in which coagulation and separation are performed on the remaining sewage 1a, and reference numeral 6 denotes a final sedimentation basin.
However, any of the recent methods for treating and coagulating and separating sludge is applied to a method in which the coagulated and separated sludge 18 flows into the first sedimentation basin 2 of the sewage treatment plant, is separated and separated, and the sludge is treated. Effective utilization of coagulated and separated sludge has not been studied.
[0004]
[Problems to be solved by the invention]
The present invention has been made in view of such circumstances, and is intended to improve the biological dephosphorization and denitrification treatment effects of coagulated and separated sludge discharged from a coagulation and separation device for sewage in rainy weather. The task is to provide new concepts that can be used effectively.
[0005]
[Means for Solving the Problems]
The present invention has solved the above problem by the following means.
(1) A combined type wherein at least a part of sewage in rainy weather is coagulated and separated, and the coagulated separated sludge is supplied to an anaerobic part or a biological denitrification part in a biological dephosphorization step of a sewage treatment facility. Sewage treatment method.
(2) The sewage treatment method according to (1), wherein after the coagulated and separated sludge is subjected to acid fermentation, the sludge is supplied to an anaerobic part or a biological denitrification part in a biological dephosphorization step of a sewage treatment facility. .
[0006]
(3) A treatment apparatus for purifying an increased combined sewage in rainy weather, wherein the coagulation / separation apparatus introduces at least a part of the increased inflow sewage in rainy weather and separates it into separated water and coagulated / separated sludge; A pipe for discharging water, a first sedimentation basin for introducing a part of the inflow sewage and separating it into separated water and sedimentation sludge, and a separated water from the first sedimentation basin and a coagulated sedimentation sludge from the coagulation separation device. Anaerobic part to introduce and dephosphorize, denitrification part, or anaerobic aerobic biological dephosphorization equipment having an aerobic part, and treated water by introducing dephosphorized water containing sludge from the dephosphorization equipment A combined sewage treatment apparatus for rainy weather, comprising: a final sedimentation tank that separates into sedimentation sludge.
(4) The coagulation / separation sludge from the coagulation / separation apparatus is introduced into an acid fermentation tank, and a pipe is provided to send the acid fermentation sludge from the acid fermentation tank to an anaerobic section of an anaerobic-aerobic biological dephosphorization facility. (3) The combined sewage treatment apparatus for rainy weather according to (3).
[0007]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
FIG. 1 is a block diagram showing an embodiment of the combined sewage treatment apparatus in rainy weather of the present invention.
Portions having the same functions as those shown in FIG. 2 are denoted by the same reference numerals.
[0008]
A coagulant (an inorganic coagulant, a polymer coagulant, or a combination thereof) is added to a part 1a of the sewage 1 in rainy weather, and coagulated and separated in the coagulation separation step 18. As the coagulation separation method, for example, any of coagulation sedimentation, coagulation flotation separation, coagulation filtration using a sparse filter, and the like are applied. In the coagulation separation step 18, the separation water 19 from which SS, phosphorus, SS BOD and COD of the sewage 1a during rainy weather have been removed is separated from the coagulation separation sludge 20 which is rich in organic matter in the sewage.
On the other hand, the remainder of the sewage during rainy weather 1 is initially settled in a sedimentation basin 2 and SS is separated to some extent. After activated sludge treatment by a denitrification step (also referred to as “biological nitrification denitrification process” in the sense of a method) 13, activated sludge is precipitated and separated from the activated sludge mixture 6 in a final sedimentation tank 7 and treated water 8 It becomes.
[0009]
However, in rainy weather, the organic matter supplied to the biological dephosphorization process 12 or the biological nitrification denitrification process 13 is diluted by rainwater, and the concentration of the organic matter decreases. However, there is a problem that the phosphorus removing effect is deteriorated. In addition, there is a problem that the denitrification reaction does not sufficiently proceed due to a shortage of an organic carbon source for the denitrifying bacteria.
[0010]
The point of the present invention is that the coagulated and separated sludge 20 is supplied to the anaerobic section 14 of the biological dephosphorization process 12 or the denitrification section 15 of the biological nitrification and denitrification process 13, and the abundant organic matter in the coagulated and separated sludge 20 is supplied. Is used as a phosphorus release promoting biodephosphorus bacterium or a hydrogen donor of denitrifying bacterium in the biodephosphorization process 12 and the like, and iron hydroxide and aluminum hydroxide in the coagulated / separated sludge 20 retain the phosphorus adsorption ability. Therefore, this is used for removing phosphorus from the sewage 1 flowing into the biological treatment step in the biological dephosphorization process 12 or the like.
By this technology, even in the case of rainy weather, the anaerobic part 14 in the biological dephosphorization step or the organic matter in the biological denitrification part 15 does not run short, and the biological dephosphorization and denitrification reactions are effectively advanced. Now you can do it.
[0011]
In another preferred embodiment, the coagulated and separated sludge 20 is anaerobically retained in the acid fermentation section 21 at room temperature or under warming conditions (temperature of about 30 to 40 ° C.), and is subjected to acid fermentation. When the fermented sludge 22 is supplied to the anaerobic section 14 or the biological denitrification section 15 in the biological dephosphorization step, it is more effective for promoting phosphorus discharge or denitrification.
In FIG. 1, reference numeral 11 denotes excess sludge, and reference numeral 3 denotes initial sludge from the first settling tank 2.
[0012]
【Example】
Hereinafter, the present invention will be described specifically with reference to examples, but the present invention is not limited to these examples.
[0013]
(Example 1)
A test for applying the present invention to sewage of 120 mg / liter, BOD of 80 mg / liter, and phosphorus of 3.6 mg / liter flowing into a sewage treatment plant during rainy weather was conducted.
First, 2/3 of the amount of inflow sewage is branched, and ferric chloride is added thereto at 40 mg / l. After stirring for 1 minute, 3 mg / l of anionic polymer (Ebagrose A151; product of Ebara Corporation) is added. As a result of stirring for minutes, a floc having a large particle diameter of about 1 cm was formed and coagulated and precipitated at a sedimentation speed of 350 mm / min. The SS of the separated water from the coagulation / sedimentation separation step was as small as 3.6 mg / L and the phosphorus was as small as 0.3 mg / L, and SS and phosphorus in the sewage were highly removed.
Next, 1/3 of the amount of inflowed sewage (this amount corresponds to the amount of sewage treatment in fine weather: designed amount) is first flowed into the sedimentation basin, and the settling overflow and the coagulated sediment sludge are anaerobically aerobic (AO method). Flowed into the biological dephosphorization facility. As a result, the phosphorus in the treated water was stable at 0.1 mg / liter or less even when rain continued.
[0014]
(Comparative Example 1)
For comparison, a method was examined in which the coagulated sediment sludge was first caused to flow into the sedimentation basin to settle, and the overflow of the first sedimentation basin was caused to flow into the anaerobic part of the biological dephosphorization step. As a result, 1.6 mg of treated water phosphorus was averaged. Per liter.
[0015]
【The invention's effect】
According to the present invention, the following excellent effects can be obtained.
(1) The treated water quality of the biological dephosphorization and biological denitrification facilities does not deteriorate even in rainy weather.
(2) Sewage in rainy weather can be effectively purified, and public water bodies are not polluted by untreated sewage in rainy weather.
(3) It is possible to effectively use sewage purification instead of simply disposing of the segregated sludge from sewage in rainy weather.
[Brief description of the drawings]
FIG. 1 is a block diagram showing an embodiment of a combined sewage treatment apparatus for rainy weather according to the present invention.
FIG. 2 is a block diagram showing one embodiment of a conventional combined-type sewage treatment apparatus in rainy weather.
[Explanation of symbols]
1 rainy sewage 1a part of sewage in rainy weather 2 first settling basin 3 first settling sludge 4 separated water 5 activated sludge treatment process (equipment)
6 Activated sludge mixture 7 Final sedimentation basin 8 Treated water 9 Separated sludge 10 Returned sludge 11 Excess sludge 12 Biological dephosphorization step 13 Biological nitrification denitrification step 14 Anaerobic part 15 Denitrification part (Biological nitrification denitrification) Process)
16 aerobic part (biological nitrification denitrification process)
17 Circulating fluid 18 Coagulation separation process (equipment)
19 Separated water 20 Coagulated separated sludge 21 Acid fermentation section 22 Acid fermentation liquid

Claims (4)

雨天時下水の少なくとも一部を凝集分離し、該凝集分離汚泥を、下水処理施設の生物脱リン工程の嫌気部、又は生物学的脱窒素部に供給することを特徴とする合流式下水の処理方法。Combined sewage treatment characterized by coagulating and separating at least a part of sewage in rainy weather, and supplying the coagulated and separated sludge to an anaerobic part or a biological denitrifying part in a biological dephosphorization step of a sewage treatment facility. Method. 前記凝集分離汚泥を酸発酵させたのち、下水処理施設の生物脱リン工程の嫌気部、または生物学的脱窒素部に供給することを特徴とする請求項1記載の下水処理方法。The sewage treatment method according to claim 1, wherein after the coagulated and separated sludge is subjected to acid fermentation, the sludge is supplied to an anaerobic part or a biological denitrification part in a biological dephosphorization step of a sewage treatment facility. 雨天時の増量した合流式下水を浄化するための処理装置において、雨天時に増量した流入下水の少なくとも一部を導入して分離水と凝集分離汚泥に分離する凝集分離装置と、前記分離水を放流する配管と、前記流入下水の一部を導入して分離水と沈殿汚泥に分離する最初沈殿池と、前記最初沈殿池からの分離水と該凝集分離装置からの凝集沈殿汚泥とを導入して脱リンする嫌気部、脱窒部、又は好気部を有する嫌気好気式生物脱リン設備と、前記脱リン設備からの汚泥を含有する被脱リン水を導入して処理水と沈殿汚泥に分離する最終沈殿池とを有することを特徴とする雨天時の合流式下水の処理装置。In a treatment device for purifying increased combined sewage in rainy weather, a coagulation separation device for introducing at least a part of increased inflow sewage in rainy weather and separating it into separated water and coagulated separated sludge, and discharging the separated water And a first settling tank for introducing a part of the inflow sewage to separate into separated water and settled sludge, and introducing separated water from the first settled tank and coagulated settled sludge from the coagulation / separation apparatus. An anaerobic aerobic biological dephosphorization facility having an anaerobic part, a denitrification part, or an aerobic part for dephosphorization, and introducing dephosphorized water containing sludge from the dephosphorization facility into treated water and settled sludge. A combined sewer system for rainy weather, comprising a final sedimentation basin for separation. 前記凝集分離装置からの凝集分離汚泥を酸発酵槽に導入し、前記酸発酵槽からの酸発酵汚泥を嫌気好気式生物脱リン設備の嫌気部に送る配管を設けたことを特徴とする請求項3記載の雨天時の合流式下水の処理装置。The coagulation / separation sludge from the coagulation / separation device is introduced into an acid fermentation tank, and a pipe is provided to send the acid fermentation sludge from the acid fermentation tank to an anaerobic part of an anaerobic aerobic biological dephosphorization facility. Item 3. The combined sewage treatment apparatus in rainy weather according to Item 3.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006043511A (en) * 2004-07-30 2006-02-16 Sumitomo Heavy Ind Ltd Organic acid producing method, organic acid producing device and wastewater treatment apparatus
KR100635485B1 (en) 2004-09-21 2006-10-17 한국건설기술연구원 Apparatus and method for all-weather treatment of sewage and wastewater by efficient combination of treatment functions
JP2007253003A (en) * 2006-03-22 2007-10-04 Tokyo Metropolis Method for estimating quality of inflow sewage by eluting phosphorus from activated sludge, nutritional source addition unit in advanced sewage treatment system and advanced sewage treatment system
WO2014034827A1 (en) * 2012-08-31 2014-03-06 東レ株式会社 Fresh water generation method
JP2016002541A (en) * 2014-06-19 2016-01-12 日本下水道事業団 Membrane separation activated sludge treatment apparatus and method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006043511A (en) * 2004-07-30 2006-02-16 Sumitomo Heavy Ind Ltd Organic acid producing method, organic acid producing device and wastewater treatment apparatus
KR100635485B1 (en) 2004-09-21 2006-10-17 한국건설기술연구원 Apparatus and method for all-weather treatment of sewage and wastewater by efficient combination of treatment functions
JP2007253003A (en) * 2006-03-22 2007-10-04 Tokyo Metropolis Method for estimating quality of inflow sewage by eluting phosphorus from activated sludge, nutritional source addition unit in advanced sewage treatment system and advanced sewage treatment system
WO2014034827A1 (en) * 2012-08-31 2014-03-06 東レ株式会社 Fresh water generation method
JPWO2014034827A1 (en) * 2012-08-31 2016-08-08 東レ株式会社 Fresh water generation method
JP2016002541A (en) * 2014-06-19 2016-01-12 日本下水道事業団 Membrane separation activated sludge treatment apparatus and method

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