JP2004047400A5 - - Google Patents

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Publication number
JP2004047400A5
JP2004047400A5 JP2002236726A JP2002236726A JP2004047400A5 JP 2004047400 A5 JP2004047400 A5 JP 2004047400A5 JP 2002236726 A JP2002236726 A JP 2002236726A JP 2002236726 A JP2002236726 A JP 2002236726A JP 2004047400 A5 JP2004047400 A5 JP 2004047400A5
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Japan
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cation
group
monomer
ionic
arso
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JP2002236726A
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Japanese (ja)
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JP2004047400A (en
JP4538183B2 (en
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Priority to JP2002236726A priority Critical patent/JP4538183B2/en
Priority claimed from JP2002236726A external-priority patent/JP4538183B2/en
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Publication of JP2004047400A5 publication Critical patent/JP2004047400A5/ja
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Claims (2)

下記Ｉ群から選ばれた少なくとも１つのアンモニウムカチオンと下記ＩＩ群から選ばれた少なくとも１つのアニオンから成る塩構造を含有する化合物を（Ａ），Ａと共通のカチオン構造又は／およびアニオン構造を有し，且つ重合性官能基を含有する単量体を（Ｂ）とするとき，Ａ／Ｂ（重量比）＝９９．９／０．１〜０／１００からなるイオン性化合物が含浸されているシート状樹脂成形物中および表面の単量体Ｂを重合させて得られることを特徴とするイオン性樹脂シート。
（Ｉ群）ピロリウムカチオン，イミダゾリウムカチオン，ピラゾリウムカチオン，ベンズイミダゾリウムカチオン，ビリジニウムカチオン，インドリウムカチオン，カルバゾリウムカチオン，キノリニウムカチオン，ピペリジニウムカチオン，ピペラジニウムカチオン、アルキルアンモニウムカチオン（但し，炭素数１〜３０のアルキル）
（いずれも，Ｎおよび／又は環が炭素数１〜１０の炭化水素基で置換されているものを含む）
（ＩＩ群）ＢＦ４，ＰＦ６，ＣｎＦ２ｎ＋１ＣＯ２（但しｎは１〜４の整数），ＣｎＦ２ｎ＋１ＳＯ３（但しｎは１〜４の整数），（ＦＳＯ２）２Ｎ（ＣＦ３ＳＯ２）２Ｎ，（Ｃ２Ｆ５ＳＯ２）２Ｎ，（ＣＦ３ＳＯ２）３Ｃ，ＣＦ３ＳＯ２−Ｎ−ＣＯＣＦ３，ＲＳＯ３（Ｒは脂肪族基），ＡｒＳＯ３（Ａｒは芳香族基），Ｒ−ＳＯ２−Ｎ−ＳＯ２ＣＦ３（Ｒは脂肪族基），ＡｒＳＯ２−Ｎ−ＳＯ２ＣＦ３（Ａｒは芳香族基）A compound having a salt structure consisting of at least one ammonium cation selected from the following group I and at least one anion selected from the following group II has (A) and a cation structure common to A and / or an anion structure. When the monomer containing a polymerizable functional group is (B), an ionic compound comprising A / B (weight ratio) = 99.9 / 0.1-0 / 100 is impregnated. An ionic resin sheet obtained by polymerizing monomer B in and on a sheet-like resin molded product.
(Group I) pyrrolium cation, imidazolium cation, pyrazolium cation, benzimidazolium cation, biridinium cation, indolium cation, carbazolium cation, quinolinium cation, piperidinium cation, piperazinium cation , Alkyl ammonium cation (however, alkyl having 1 to 30 carbon atoms)
(All include N and / or ring substituted with a hydrocarbon group having 1 to 10 carbon atoms)
(Group II) BF 4 , PF 6 , C n F 2n + 1 CO 2 (where n is an integer of 1 to 4), C n F 2n + 1 SO 3 (where n is an integer of 1 to 4), (FSO 2 ) 2 N (CF 3 SO 2) 2 N , (C 2 F 5 SO 2) 2 N, (CF 3 SO 2) 3 C, CF 3 SO 2 -N-COCF 3, RSO 3 (R is an aliphatic group), ArSO 3 (Ar is an aromatic group), R—SO 2 —N—SO 2 CF 3 (R is an aliphatic group) , ArSO 2 —N—SO 2 CF 3 (Ar is an aromatic group) イオン性化合物において、更に単量体（Ｂ）と共重合可能な重合性官能基を２個以上有する単量体（Ｃ）を単量体（Ｂ）に対して０．５モル％以上含有することを特徴とする請求項１記載のイオン性樹脂シート。 In the ionic compound, the monomer (C) having at least two polymerizable functional groups copolymerizable with the monomer (B) is contained in an amount of 0.5 mol% or more based on the monomer (B). The ionic resin sheet according to claim 1 .
JP2002236726A 2002-07-10 2002-07-10 Ionic resin sheet Expired - Fee Related JP4538183B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2002236726A JP4538183B2 (en) 2002-07-10 2002-07-10 Ionic resin sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2002236726A JP4538183B2 (en) 2002-07-10 2002-07-10 Ionic resin sheet

Publications (3)

Publication Number Publication Date
JP2004047400A JP2004047400A (en) 2004-02-12
JP2004047400A5 true JP2004047400A5 (en) 2005-10-27
JP4538183B2 JP4538183B2 (en) 2010-09-08

Family

ID=31712049

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2002236726A Expired - Fee Related JP4538183B2 (en) 2002-07-10 2002-07-10 Ionic resin sheet

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JP (1) JP4538183B2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4389454B2 (en) * 2003-03-13 2009-12-24 住友ベークライト株式会社 Polymer solid electrolyte
JP4300954B2 (en) * 2003-09-26 2009-07-22 住友ベークライト株式会社 Polymer solid electrolyte
JP4820535B2 (en) * 2004-02-24 2011-11-24 弘幸 大野 New imidazolium compounds
KR101197115B1 (en) * 2004-02-24 2012-11-07 히로유키 오노 Novel imidazolium compound
US7419623B2 (en) * 2004-08-03 2008-09-02 Air Products And Chemicals, Inc. Proton conducting mediums for electrochemical devices and electrochemical devices comprising the same
JP4709518B2 (en) 2004-09-29 2011-06-22 株式会社東芝 Proton conducting membrane and fuel cell
JP4718827B2 (en) 2004-12-24 2011-07-06 株式会社東芝 Fuel cell
JP4830314B2 (en) * 2005-02-28 2011-12-07 住友ベークライト株式会社 Composition for ion conductive electrolyte, ion conductive electrolyte, and secondary battery using the ion conductive electrolyte
JP5205692B2 (en) * 2005-10-12 2013-06-05 住友ベークライト株式会社 Electrolyte resin composition, ion conductive electrolyte, and secondary battery using the same
JP4857789B2 (en) * 2006-02-01 2012-01-18 株式会社日立製作所 Fuel cell, polymer electrolyte and ion-exchange resin used therefor
JP2007258081A (en) * 2006-03-24 2007-10-04 Sumitomo Bakelite Co Ltd Electrolyte composition, ionic conductive electrolyte, and secondary battery using it
JP4444355B2 (en) 2008-09-03 2010-03-31 株式会社東芝 Fuel cell
WO2010064386A1 (en) * 2008-12-04 2010-06-10 国立大学法人大阪大学 Pattern-forming method
JP5439009B2 (en) * 2009-03-31 2014-03-12 大塚化学株式会社 Imidazolium salts, electrolytes and electrochemical devices

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3817045B2 (en) * 1997-09-12 2006-08-30 四国化成工業株式会社 Molten salt type polymer electrolyte

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