JP2004025670A - Method for forming groove part for opening container - Google Patents

Method for forming groove part for opening container Download PDF

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Publication number
JP2004025670A
JP2004025670A JP2002186433A JP2002186433A JP2004025670A JP 2004025670 A JP2004025670 A JP 2004025670A JP 2002186433 A JP2002186433 A JP 2002186433A JP 2002186433 A JP2002186433 A JP 2002186433A JP 2004025670 A JP2004025670 A JP 2004025670A
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JP
Japan
Prior art keywords
groove
container
laser
forming
flow path
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
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JP2002186433A
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Japanese (ja)
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JP4226281B2 (en
Inventor
Koji Takada
高田 康治
Yukiko Kanehata
金端 有紀子
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Fujimori Kogyo Co Ltd
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Fujimori Kogyo Co Ltd
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Priority to JP2002186433A priority Critical patent/JP4226281B2/en
Publication of JP2004025670A publication Critical patent/JP2004025670A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To form an easily opening groove part always having a proper depth to the surface of the expanded sheet made of a resin of a container, which is equipped with a flow channel between two bonded resin sheets by expanding at least one resin sheet from the surface of the resin sheet, without stopping the feed of the container. <P>SOLUTION: In the method for forming the groove part for opening the container, the surfaces of the resin sheets 1a and 1b are irradiated with a laser L for forming the groove part and the forming range of the groove part along the irradiation direction is larger than the expanded quantity of the resin sheets 1a and 1b in the forming region of the flow channel 2. <P>COPYRIGHT: (C)2004,JPO

Description

【0001】
【発明の属する技術分野】
本発明は、貼り合わされた二枚の樹脂製シート間に、これら樹脂製シートのうち少なくとも一方をその表面からを膨出させることにより形成された流路を備える容器の、膨出した上記樹脂製シートの表面に、易開封用の溝部を形成する方法に関する。
【0002】
【従来の技術】
易開封用の溝部が形成された密閉容器の例を図2に示す。符号1は容器で、容器1は、その側面を構成する前後二枚の矩形状をなす樹脂製のシート1a,1bと、底面を構成する樹脂製のシート1cとを、それらの縁部に形成されたシール部1d,1eにて貼り合わせることにより、内部にシート1a,1b,1cに囲まれた空間Sを有し、かつシート1cを底面として自立可能に形成されている。
【0003】
符号2は、容器1の上端に形成された、シート1a,1bを張り合わせてなる一対の角部のうち、一方(図中左側)の角部に形成された流路である。流路2は、個々のシート1a,1bを、その表面から膨出させてなるもので、空間S部の上端から、上記一方の角部に向け延設されるとともに、その周囲はシール部1dにより囲まれている。
【0004】
また、一方の角部の表面には、流路2を横断する方向に沿って線状の溝部2aがそれぞれ形成され、この溝部2aに沿って流路2を切断することにより、容器1を容易に開口し、空間Sに貯留された物品を、流路2を介して注出可能となっている。また、符号2bは、溝部2aの両端に、シール部1dを流路2側に窪ませることによりそれぞれ形成された凹部である。これら凹部2bの存在により、上記一方の端部をひねって流路2を切断しようとした際に容器1が受ける力が凹部2bを介して溝部2aに集中し、容器1の開口容易性が更に向上する。
【0005】
【発明が解決しようとする課題】
ところで、近年、溝部2aの形成に際しては、溝部2aの形成部位に、レーザを、容器1の表面及び裏面側から、その焦点が上記形成部位に合致するようそれぞれ照射し、シート1a,1bの表面を構成する樹脂をレーザのエネルギを用いて昇華させることにより、溝部2aを形成する方法が採用されている。しかしながら、例えば図2に示すように、流路2が、シート1a,1bを前後に膨出させてなる立体をなす場合には、レーザの出力及び焦点を、溝部2aの形成部位のうち、レーザの出力部に最も接近する点(流路2の形成部位の外周端。図2に矢印Aで示す点)に適正な深さの溝部2aが形成される程度に設定すると、上記出力部から相対的に離れている他の部位では、十分なエネルギが得られず、その結果、溝部2aが形成されにくくなり、容器1の開口容易性が低下するという問題が生じる。
【0006】
逆に、レーザの出力及び焦点を、シール部1dの表面(図2に矢印Bで示す範囲)に適正な深さの溝部2aが形成される程度に設定すると、流路2の形成部位では、上記出力部と相対的に接近しているため、印加されるエネルギが過大となり、その結果、溝部2aが深くなり過ぎてシート1a,1bの強度が低下し、シート1a,1bが不要に裂ける等の問題が生じる。そこで、従来では、レーザの出力部を溝部2aの形成部位の表面形状に沿って移動させることにより、上記出力部と溝部2aの形成部位との距離を一定に維持している。しかしながら、この方法は、上記出力部を上記表面形状に沿って移動させるための移動機構が必要となる他、上記出力部の移動に時間を要するため、溝部2aの形成に際し、容器1を上記出力部に対し停止させる必要があるという問題を有している。
【0007】
【課題を解決するための手段】
本発明は、上記の問題を解決するためになされたもので、貼り合わされた二枚の樹脂製シート間に、これら樹脂製シートのうち少なくとも一方をその表面から膨出させることにより形成された流路を備える容器の、膨出した上記樹脂製シートの表面に、上記流路を横断する方向に沿って溝部を設け、上記容器を容易に開口可能とするための容器開口用溝部の形成方法であって、膨出した上記樹脂製シートの表面に向け、上記溝部形成用のレーザを照射し、かつ上記レーザの照射による、その照射方向に沿った上記溝部の形成範囲が、上記流路の形成部位における上記樹脂製シートの膨出量より大きいことを特徴としている。
【0008】
更に、上記レーザの照射による、上記溝部の延設方向に沿った上記溝部の形成範囲が、上記溝部の全長以上であることが望ましい。
【0009】
また、上記レーザには、例えば、ガルバノ偏光レンズを介して出力されるレーザが使用可能である。
【0010】
上記溝部を、上記容器の搬送中に、上記容器の搬送を停止することなく、個々の上記樹脂製シートの表面に向け上記レーザを照射することにより形成することも可能である。
【0011】
【発明の実施の形態】
以下、図面に基づき、本発明の実施形態について説明する。ここで、図1は、本発明の実施形態を説明するためのもので、流路2近傍の、溝部2aの形成方向に沿った断面図である。また、以下の記載中、上記図2に示す部材と同様の構成を有する部材については、図2と同一の符号を付して、その説明を省略する。
【0012】
本発明は、容器1のうち、溝部2aの形成部位に、レーザを、容器1の表面及び裏面側から、その焦点が上記形成部位に合致するようそれぞれ照射し、シート1a,1bの表面を構成する樹脂をレーザのエネルギを用いて昇華させることにより、溝部2aを形成する点では、上記従来の溝部形成方法と同様である。
【0013】
一方、本発明に係る溝部2aの形成方法では、図1に示すように、レーザLの照射による、その照射方向に沿った溝部2aの形成範囲Cを、流路2の形成部位におけるシート1a,1bの膨出量Dより大きくなるよう設定する。更に、本発明では、レーザLの照射による、溝部2aの延設方向に沿った溝部2aの形成範囲Eを、溝部2aの全長F以上に設定する。
【0014】
ここで、上記のような設定条件を満たすレーザLには、例えば、ガルバノ偏光レンズを介して出力されるレーザが使用可能である。このレーザLでは、レーザ発振器から発振される、例えば炭酸ガスレーザのようなレーザを、ガルバノ偏光レンズを介して出力することにより、出力されるレーザLの焦点深度(溝部2aの形成範囲Cに相当)に、その照射方向に沿って、例えば±5mm程度のばらつきを持たせたものである。通常、流路2の形成部位におけるシート1a,1bの膨出量Dは1〜6mm程度であるため、レーザLの焦点深度に±5mm程度のばらつきがあれば、一度の照射で、流路2の形成部位及びシール部1dの表面に、適正な深さの溝部2aを、同時に形成することができる。
【0015】
なお、ガルバノ偏光レンズを介して出力されるレーザLでは、焦点深度のばらつきに伴い、照射部位にてシート1a,1bに付与されるエネルギが、上記従来の溝部形成方法に使用されるレーザに比して相対的に低下するため、レーザLの出力を、上記従来の溝部形成方法に使用されるレーザより大きく設定する必要がある。例えば、ガルバノ偏光レンズを介して出力されるレーザLにおいて、一度の照射で、膨出量Dが1〜6mm程度である流路2の形成部位及びシール部1dの表面に、適正な深さの溝部2aを形成するためには、5〜30ワット程度の出力が必要となる。
【0016】
また、本発明に係る溝部2aの形成方法では、一度の照射で、溝部2aの形成部位(流路2の形成部位及びシール部1dの表面)に、適正な深さの溝部2aを、同時に形成することができるため、レーザLの出力部を流路2の表面形状に沿って移動させるための移動機構が不要となる。しかも、レーザLの照射時間が極めて短時間で済むため、溝部2aの形成に際し、容器1を上記出力部に対し停止させる必要もない。従って、本発明に係る溝部2aの形成方法では、例えば容器1の製造工程中等における容器1の搬送中に、ロータリーエンコーダ等を用いて容器1の移動速度を正確に測定し、その移動速度に応じた時間間隔で樹脂製シート1a,1bの表裏にそれぞれレーザLを照射することにより、容器1の搬送を停止することなく、個々の容器1における溝部2aの形成部位に、適正な深さの溝部2aを形成することができる。
【0017】
なお、本発明は上記実施形態に限定されるものではなく、具体的な使用環境等に応じ、本発明の趣旨を逸脱しない範囲で、任意に変更可能であることは言うまでもない。例えば、本発明に使用可能なレーザLは、ガルバノ偏光レンズを介して出力される炭酸ガスレーザに限られず、一度の照射で、溝部2aの形成部位に、適正な深さの溝部2aを、同時に形成可能なものであればよい。また、レーザによる溝部2a形成設備を有さない容器1の製造装置に、本発明に係る溝部2aの形成方法が実施可能な溝部2a形成設備を追加設置したり、レーザによる溝部2a形成設備を有さない製造装置で予め容器1を製造しておき、後の工程(例えば仕上げ工程や検品工程等)にて、移動中の容器1に対し、本発明に係る方法により、容器1を停止することなく、溝部2aを形成することも可能である。
【0018】
また、本発明に係る溝部2aの形成方法では、レーザLの照射による、その照射方向に沿った溝部2aの形成範囲Cが、流路2の形成部位におけるシート1a,1bの膨出量Dより大きいため、シート1a,1b自身に、図1中上下方向に沿った若干の凹凸があった場合でも、常時適正な深さの溝部2aが形成可能であるが、レーザLの照射範囲近傍に、樹脂製シート1a,1bの表面を押さえるための部材(スタビライザ)3を、レーザLの照射範囲と重ならないよう設け、シート1a,1b自身の凹凸や、図1中上下方向に沿った不要な移動を防止してもよい。
【0019】
また、上記実施形態では、本発明の方法を、個々のシート1a,1bの双方を膨出させることにより流路2が形成された容器1に対して適用したが、本発明の方法は、シート1a,1bの一方を表面から膨出させることにより流路が形成された容器に対しても適用可能であることはいうまでもない。
【0020】
【発明の効果】
以上説明した通り、本発明に係る容器開口用溝部の形成方法によれば、容器の所定位置に、常時適正な深さの溝部を形成することができる。また、溝部の形成に際し、容器の搬送を停止する必要もない。
【図面の簡単な説明】
【図1】本発明の実施形態を説明するための、流路近傍の、溝部の形成方向に沿った断面図である。
【図2】本発明が適用可能な容器の構造の例を示す、容器の上方斜視図である。
【符号の説明】
1 容器
1a,1b (樹脂製)シート
2 流路
2a (容器開口用)溝部
2b 凹部
C 個々のレーザの照射による、その照射方向に沿った溝部の形成範囲
D 流路を形成する個々の樹脂製シートの膨出量
E レーザの照射による、溝部の延設方向に沿った溝部の形成範囲
F 溝部の全長
L レーザ
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention provides a container having a flow path formed by swelling at least one of these resin sheets from the surface between two bonded resin sheets. The present invention relates to a method for forming a groove for easy opening on a surface of a sheet.
[0002]
[Prior art]
FIG. 2 shows an example of a closed container in which a groove for easy opening is formed. Reference numeral 1 denotes a container, and the container 1 is formed at its edges with two front and rear rectangular resin sheets 1a and 1b forming side surfaces and a resin sheet 1c forming a bottom surface. By laminating at the sealed portions 1d and 1e, a space S surrounded by the sheets 1a, 1b and 1c is provided inside, and the sheet 1c is formed to be self-supporting with the bottom as the bottom.
[0003]
Reference numeral 2 denotes a flow path formed at one (left side in the figure) of the pair of corners formed at the upper end of the container 1 and formed by laminating the sheets 1a and 1b. The flow path 2 is formed by swelling the individual sheets 1a and 1b from the surface thereof. The flow path 2 extends from the upper end of the space S toward the one corner, and the periphery thereof is a seal 1d. Surrounded by
[0004]
Further, a linear groove 2a is formed on the surface of one corner along the direction crossing the flow path 2, and by cutting the flow path 2 along the groove 2a, the container 1 can be easily manufactured. And the articles stored in the space S can be poured out through the flow path 2. Reference numerals 2b denote recesses respectively formed at both ends of the groove 2a by recessing the seal portion 1d toward the flow path 2. Due to the presence of these recesses 2b, when the one end is twisted to cut the flow path 2, the force received by the container 1 is concentrated on the groove 2a via the recess 2b, and the ease of opening of the container 1 is further improved. improves.
[0005]
[Problems to be solved by the invention]
By the way, in recent years, when forming the groove 2a, a laser is applied to the formation portion of the groove 2a from the front and back sides of the container 1 so that the focal point matches the formation portion, and the surface of the sheet 1a, 1b is irradiated. Is formed by sublimating the resin constituting the groove 2a using laser energy. However, for example, as shown in FIG. 2, when the flow path 2 forms a three-dimensional shape in which the sheets 1 a and 1 b are swelled back and forth, the laser output and the focal point are controlled by the laser out of the portion where the groove 2 a is formed. Is set to such an extent that a groove 2a having an appropriate depth is formed at the point closest to the output portion (the outer peripheral end of the portion where the flow path 2 is formed; the point indicated by arrow A in FIG. 2). Sufficient energy cannot be obtained in other parts that are far apart from each other, and as a result, it is difficult to form the groove 2a, and there is a problem that the ease of opening the container 1 is reduced.
[0006]
Conversely, if the output and focus of the laser are set to such an extent that the groove 2a having an appropriate depth is formed on the surface of the seal portion 1d (the range indicated by the arrow B in FIG. 2), Since it is relatively close to the output section, the applied energy becomes excessive, and as a result, the groove 2a becomes too deep, the strength of the sheets 1a and 1b decreases, and the sheets 1a and 1b are unnecessarily torn. Problem arises. Therefore, conventionally, the distance between the output portion and the portion where the groove 2a is formed is kept constant by moving the output portion of the laser along the surface shape of the portion where the groove 2a is formed. However, this method requires a moving mechanism for moving the output section along the surface shape, and requires time to move the output section. There is a problem that it is necessary to stop some parts.
[0007]
[Means for Solving the Problems]
The present invention has been made to solve the above-described problem, and a flow formed between two bonded resin sheets by causing at least one of the resin sheets to swell from the surface thereof. A method of forming a container opening groove for providing a groove along a direction crossing the flow path on the surface of the swelled resin sheet of a container provided with a path, so that the container can be easily opened. Thereupon, the laser for forming the groove portion is irradiated toward the surface of the resin sheet that has swelled, and the range of formation of the groove portion along the irradiation direction by the laser irradiation is such that the flow path is formed. It is characterized in that it is larger than the swelling amount of the resin sheet at the site.
[0008]
Furthermore, it is desirable that the range of formation of the groove along the direction in which the groove is extended by the laser irradiation is equal to or longer than the entire length of the groove.
[0009]
Further, as the laser, for example, a laser output through a galvano-polarizing lens can be used.
[0010]
The groove may be formed by irradiating the surface of each of the resin sheets with the laser beam without stopping the conveyance of the container during the conveyance of the container.
[0011]
BEST MODE FOR CARRYING OUT THE INVENTION
Hereinafter, embodiments of the present invention will be described with reference to the drawings. Here, FIG. 1 is for explaining the embodiment of the present invention, and is a cross-sectional view of the vicinity of the flow path 2 along the forming direction of the groove 2a. Further, in the following description, members having the same configuration as the members shown in FIG. 2 are denoted by the same reference numerals as those in FIG.
[0012]
According to the present invention, a laser is applied to the formation part of the groove 2a in the container 1 from the front and back sides of the container 1 so that the focal point matches the formation part, thereby forming the surfaces of the sheets 1a and 1b. The groove 2a is formed by sublimating the resin to be formed by using the energy of the laser, which is the same as the above-described conventional groove forming method.
[0013]
On the other hand, in the method of forming the groove 2a according to the present invention, as shown in FIG. 1, the formation range C of the groove 2a along the irradiation direction by the irradiation of the laser L is changed to the sheet 1a, It is set to be larger than the bulge amount D of 1b. Further, in the present invention, the formation range E of the groove 2a along the extending direction of the groove 2a by the irradiation of the laser L is set to be equal to or longer than the total length F of the groove 2a.
[0014]
Here, as the laser L that satisfies the above setting conditions, for example, a laser output via a galvano-polarizing lens can be used. In this laser L, a laser oscillated from a laser oscillator, such as a carbon dioxide gas laser, is output through a galvano polarizing lens, so that the focal depth of the output laser L (corresponding to the formation range C of the groove 2a). In addition, for example, a variation of about ± 5 mm is provided along the irradiation direction. Normally, the swelling amount D of the sheets 1a and 1b at the portion where the flow path 2 is formed is about 1 to 6 mm. Therefore, if the focal depth of the laser L fluctuates about ± 5 mm, the irradiation of the The groove 2a having an appropriate depth can be formed at the same time at the formation site of the groove and the surface of the seal portion 1d.
[0015]
In the laser L output through the galvano polarizing lens, the energy applied to the sheets 1a and 1b at the irradiation site due to the variation in the depth of focus is smaller than that of the laser used in the conventional groove forming method. Therefore, it is necessary to set the output of the laser L higher than that of the laser used in the conventional groove forming method. For example, in a laser L output via a galvano polarizing lens, a single irradiation is performed so that the bulging amount D is about 1 to 6 mm at the formation portion of the flow path 2 and the surface of the seal portion 1d with an appropriate depth. In order to form the groove 2a, an output of about 5 to 30 watts is required.
[0016]
In the method of forming the groove 2a according to the present invention, the groove 2a having an appropriate depth is simultaneously formed in the formation part of the groove 2a (the formation part of the flow path 2 and the surface of the seal part 1d) by one irradiation. Therefore, a moving mechanism for moving the output portion of the laser L along the surface shape of the flow path 2 is not required. In addition, since the irradiation time of the laser L is extremely short, there is no need to stop the container 1 with respect to the output unit when forming the groove 2a. Therefore, in the method of forming the groove 2a according to the present invention, for example, during the transportation of the container 1 during the manufacturing process of the container 1, the moving speed of the container 1 is accurately measured using a rotary encoder or the like, and the moving speed is determined in accordance with the moving speed. By irradiating the laser L to the front and back of the resin sheets 1a and 1b respectively at the time intervals, without stopping the conveyance of the containers 1, the grooves 2a having the appropriate depth are formed at the portions where the grooves 2a are formed in the individual containers 1. 2a can be formed.
[0017]
It should be noted that the present invention is not limited to the above embodiment, and it is needless to say that the present invention can be arbitrarily changed according to a specific use environment or the like without departing from the gist of the present invention. For example, the laser L that can be used in the present invention is not limited to a carbon dioxide laser that is output through a galvano-polarizing lens, and a single irradiation simultaneously forms a groove 2a having an appropriate depth in a formation portion of the groove 2a. Whatever is possible is possible. Further, a groove 2a forming equipment capable of performing the method of forming the groove 2a according to the present invention is additionally installed in the manufacturing apparatus of the container 1 having no laser groove 2a forming equipment, or a laser groove 2a forming equipment is provided. The container 1 is manufactured in advance using a manufacturing apparatus, and the container 1 is stopped by a method according to the present invention with respect to the moving container 1 in a later step (for example, a finishing step or an inspection step). Instead, it is also possible to form the groove 2a.
[0018]
In the method of forming the groove 2a according to the present invention, the formation range C of the groove 2a along the irradiation direction by the irradiation of the laser L is determined by the swelling amount D of the sheets 1a and 1b in the formation part of the flow path 2. Due to the large size, even when the sheets 1a and 1b themselves have slight irregularities in the vertical direction in FIG. 1, the groove 2a having an appropriate depth can always be formed. A member (stabilizer) 3 for holding down the surfaces of the resin sheets 1a and 1b is provided so as not to overlap with the irradiation range of the laser L, and unnecessary movement along the unevenness of the sheets 1a and 1b and the vertical direction in FIG. May be prevented.
[0019]
Further, in the above embodiment, the method of the present invention is applied to the container 1 in which the flow path 2 is formed by expanding both of the individual sheets 1a and 1b. It goes without saying that the present invention is also applicable to a container in which a flow path is formed by bulging one of 1a and 1b from the surface.
[0020]
【The invention's effect】
As described above, according to the method for forming a container opening groove according to the present invention, a groove having an appropriate depth can always be formed at a predetermined position of a container. Further, it is not necessary to stop the transport of the container when forming the groove.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a vicinity of a flow path, taken along a direction in which a groove is formed, for describing an embodiment of the present invention.
FIG. 2 is a top perspective view of a container showing an example of the structure of the container to which the present invention can be applied.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 Container 1a, 1b (made of resin) sheet 2 Flow path 2a Groove part 2b (for container opening) Recess C Forming area D of groove part along the irradiation direction by irradiation of each laser D made of individual resin forming flow path Sheet swelling amount E Range of groove formation F along the direction in which grooves are extended by laser irradiation F Total length L of grooves Laser

Claims (4)

貼り合わされた二枚の樹脂製シート間に、これら樹脂製シートのうち少なくとも一方をその表面から膨出させることにより形成された流路を備える容器の、膨出した上記樹脂製シートの表面に、上記流路を横断する方向に沿って溝部を設け、上記容器を容易に開口可能とするための容器開口用溝部の形成方法であって、
膨出した上記樹脂製シートの表面に向け、上記溝部形成用のレーザを照射し、かつ上記レーザの照射による、その照射方向に沿った上記溝部の形成範囲が、上記流路の形成部位における上記樹脂製シートの膨出量より大きいことを特徴とする、容器開口用溝部の形成方法。
Between the two bonded resin sheets, at least one of these resin sheets is a container having a channel formed by expanding from the surface of the container, on the surface of the expanded resin sheet, A method for forming a container opening groove for allowing the container to be easily opened by providing a groove along a direction crossing the flow path,
Irradiating the laser for forming the groove toward the surface of the swelled resin sheet, and irradiating the laser, the formation range of the groove along the irradiation direction is the same as that of the flow path at the portion where the flow path is formed. A method of forming a groove for opening a container, wherein the groove is larger than a swelling amount of a resin sheet.
上記レーザの照射による、上記溝部の延設方向に沿った上記溝部の形成範囲が、上記溝部の全長以上であることを特徴とする、請求項1に記載の容器開口用溝部の形成方法。The method for forming a groove for opening a container according to claim 1, wherein the range of formation of the groove along the direction in which the groove is extended by the laser irradiation is equal to or longer than the entire length of the groove. 上記レーザが、ガルバノ偏光レンズを介して上記樹脂製シートの表面を照射することを特徴とする、請求項1または2に記載の容器開口用溝部の形成方法。The method of forming a groove for opening a container according to claim 1, wherein the laser irradiates the surface of the resin sheet via a galvano-polarizing lens. 上記溝部が、上記容器の搬送中に、上記容器の搬送を停止することなく、個々の上記樹脂製シートの表面に向け上記レーザを照射することにより形成されることを特徴とする、請求項1,2または3に記載の容器開口用溝部の形成方法。The said groove part is formed by irradiating the said laser toward the surface of each said resin-made sheet, without stopping conveyance of the said container during conveyance of the said container, The characterized by the above-mentioned. 4. The method for forming a groove for opening a container according to any one of claims 1, 2 and 3.
JP2002186433A 2002-06-26 2002-06-26 Method for forming container opening groove Expired - Fee Related JP4226281B2 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008290762A (en) * 2007-05-28 2008-12-04 Daiwa Can Co Ltd Production method of easily breakable/openable polyester resin container

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008290762A (en) * 2007-05-28 2008-12-04 Daiwa Can Co Ltd Production method of easily breakable/openable polyester resin container

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