JP2003259842A - Method for producing food material in which active ingredient of tangle weed, undaria pinnatifida and hizikia fusiforme are retained - Google Patents

Method for producing food material in which active ingredient of tangle weed, undaria pinnatifida and hizikia fusiforme are retained

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Publication number
JP2003259842A
JP2003259842A JP2002066352A JP2002066352A JP2003259842A JP 2003259842 A JP2003259842 A JP 2003259842A JP 2002066352 A JP2002066352 A JP 2002066352A JP 2002066352 A JP2002066352 A JP 2002066352A JP 2003259842 A JP2003259842 A JP 2003259842A
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JP
Japan
Prior art keywords
hijiki
heating
seaweed
wakame
food material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
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JP2002066352A
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Japanese (ja)
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JP3721431B2 (en
Inventor
Nobuo Yamada
信夫 山田
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ARUGA KK
MINATO PHARMACEUTICAL CO Ltd
Original Assignee
ARUGA KK
MINATO PHARMACEUTICAL CO Ltd
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Priority to JP2002066352A priority Critical patent/JP3721431B2/en
Publication of JP2003259842A publication Critical patent/JP2003259842A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing a food material in which active ingredients of tangle weed, Undaria pinnatifida and Hizikia fusiforme are retained. <P>SOLUTION: The food material is produced by controlling water-adding amount, heating temperature and heating time without wholly using a chemical such as an acid or an alkali so that breakage of mucopolysaccharides such as alginic acid and fucoidan and minerals, vitamins, vegetable fibers, etc., is minimized. <P>COPYRIGHT: (C)2003,JPO

Description

【発明の詳細な説明】 【0001】 【発明の属する技術分野】本発明は、理化学的に異なる
性状を有するこんぶ、わかめおよびひじきの有効成分を
保持した食品素材の製造方法に関するものである。 【0002】 【従来の技術】従来、こんぶ等の海藻を原料とした海藻
ジュース、あるいは海藻飲料の原料とするため、海藻を
粉末化する方法が公知である。例えば、藻体を軟化させ
るために加熱時間と関係なく軟化するまで加熱したり、
搾汁機を用いてエキス成分を搾り出したり、あるいはア
ルカリ等の薬品類を使用したり、更には酵素を用いて原
料海藻を軟化させたりして、粉末化する方法が公知であ
る。 【0003】 【発明が解決しようとする課題】しかしながら、前記従
来の粉末化方法では、海藻特有の有効成分、例えば粘質
多糖類、ミネラル、ビタミン等を意識しての製造方法は
全く存在せず、従って従来の粉末化方法で得られた海藻
の粉末には有効成分がほとんど含まれておらず、食品素
材として使用しても栄養食品としての効果がないという
課題があった。 【0004】本発明は、前記課題を解決すべくなされた
ものであって、粘質多糖類、ミネラル、ビタミン等のよ
うな有効成分を喪失することのないこんぶ、わかめおよ
びひじきの有効成分を保持した食品素材の製造方法を提
供しようとするものである。 【0005】 【課題を解決するための手段】本発明は、こんぶ、わか
めおよびひじきを荒く破砕して、これに3倍量程度の水
を加え3分程度脱塩して、塩分を含んだ水分を水切りし
て除去する脱塩工程と、前記脱塩工程を経たこんぶ、わ
かめおよびひじきに2倍量程度の水を加え、室温から約
50〜60℃/hの昇温速度で1時間加熱し、1時間後
に70℃になるよう加熱した後、直ちに加熱を停止する
加熱工程と、前記加熱工程で加熱されたこんぶ、わかめ
およびひじきを、60〜80℃で16〜18時間程度乾
燥させる乾燥工程と、前記乾燥工程で乾燥したこんぶ、
わかめおよびひじきを粉砕機で粗粉砕して粗粉末とする
粗粉砕工程と、前記粗粉砕工程によって得られたこん
ぶ、わかめおよびひじきの粗粉末を蒸気滅菌する殺菌工
程と、前記殺菌工程を経たこんぶ、わかめおよびひじき
の粗粉末を粉砕機で微粉末に粉砕する微粉末工程とによ
り製造するという手段を採用することにより、上記課題
を解決した。 【0006】 【発明の実施の形態】飽食時代といわれている現在、ア
ンバランスな食生活によって、生活習慣病である高血圧
症、動脈硬化、糖尿病などが若年層にまで及んできてい
る。これらの生活習慣病は、毎日の食生活を適切に保て
ば防ぐことのできることも知られている。 【0007】その一つとして、海藻類を毎日摂ることに
より予防できるともいわれている。海藻類は、地球上に
存在するすべての元素を含む海水中で生育するため、そ
の藻体内にミネラル、ビタミン類を多く含んでいること
は勿論、特に褐藻類中、こんぶ、わかめおよびひじきに
は、これらにしか存在しないアルギン酸やフコイダンな
どの粘質多糖類を豊富に含有している。また、これらの
粘質多糖類は、水溶性の食物繊維としても働き、不溶性
の食物繊維とともに人間の体内で様々な健康的な働きを
することが知られている。 【0008】そして、前記のことから、本発明は、前記
こんぶ、わかめおよびひじきの持つ物理化学的性状と栄
養的価値を可能な限り破壊しないようにして有効成分を
保持し、然も、多くの有効成分が水に溶けやすい粉末状
の食品素材を得ることを目的としている。 【0009】本発明の原材料としては、前記のように海
藻類の中で褐藻類にしか含まれていない粘質多糖類のア
ルギン酸とフコイダンを有効に利用するため、褐藻類
中、こんぶ、わかめおよびひじきの3種類を採用した。 【0010】本発明は、こんぶ、わかめおよびひじきに
含まれているアルギン酸やフコイダン等の粘質多糖類や
ミネラル、ビタミン類、食物繊維等を可能な限り破壊し
ないように、酸やアルカリ等の薬品類を一切使用するこ
となく、加水量と加熱温度並びに加熱時間をコントロー
ルすることによって製造する方法に関する。以下更に本
発明方法につき詳細に説明する。 【0011】本発明における前記各原材料の配合比率
は、特に限定する必要はないが、好ましくは、わかめ2
0〜70重量%、こんぶ20〜70重量%、ひじき10
〜20重量%、特に好ましくは、わかめ50重量%、こ
んぶ35重量%、ひじき15重量%とすることが推奨さ
れる。 【0012】本発明では、前記のように褐藻類であるこ
んぶ、わかめおよびひじきの粘質多糖類の有効利用を図
ることを主眼としているので、ある程度の粘度を維持し
て、粘質多糖類が分解しない製品とする必要がある。そ
のため、先ず加熱の前後によるその物性の変化を粘度の
測定によって行うこととし、オストワルド粘度計によっ
て粘度の測定を行った。なお、後述の図2において、粘
度は見掛けの値を示したが、真の値に換算できる。 【0013】本発明方法における原材料である、こん
ぶ、わかめおよびひじきは、そのまま利用するには多す
ぎる塩分が含まれている。そのため脱塩が必要となるの
で、後述する本発明方法で粉末化した製品の粘度と脱塩
水の粘度から適切な脱塩時間を調べた。その結果、図1
に示したように、脱塩時間が10分以上になると、その
製品の粘度が大きく低下するので、脱塩時間は3分以内
で行う必要がある。脱塩水の粘度は、時間の経過と共に
増加するが、これはこんぶ、わかめおよびひじきに含ま
れる冷水可溶性物質が溶出するためで、比較的低分子の
アルギン酸やフコイダンなども含まれているものと考え
られる。また、脱塩水の量は、多いほど脱塩効率は良い
と思われるが、原料重量の3倍程度が適切である。 【0014】脱塩後の加熱温度と加熱時間を決定するた
めの予備的な実験として、こんぶ、わかめおよびひじき
を予め200〜250μmに粉末化したものを、オート
クレープを用いて120℃に温度を上昇させてから、加
熱時間と粘度との関係について調査したところ図2のよ
うな結果が得られた。すなわち、加熱時間が長くなると
粘度の低下が見られた。これは、高温、長時間の加熱に
より、粘質多糖類が分解されるためであると推定され
た。 【0015】次に、加熱時の加水量については、脱塩
後、脱水してから加熱のためにニーダーに原料を移し、
原料に対して2倍量の水を加える。前記原料重量と水量
との適切な比率はいくつかの実験の結果得られたもので
ある。前記比率であると、その後の工程のオープン型乾
燥機に移すときと、移した後に、最も重要視している粘
質多糖類がほとんど滴下せず、本発明の目的に合致する
からである。すなわち、前記水量よりも少ないと、いわ
ゆるこげたような状態になり、水量が多いと粘質成分を
含む有効成分が流出してしまうのである。 【0016】更に、加熱温度と加熱時間との関係につい
ては、前記のように120℃よりも低い温度で処理する
ことの必要性が考えられたので、前記こんぶ、わかめお
よびひじきを予め200〜250μmに粉末化したもの
を、80〜100℃で加熱して粘度との関係を調べたと
ころ、図3のように、加温する温度が高くなればその分
粘度が低下するという結果が得られた。このような結果
と、食物繊維の熱による変化などの実験結果などから7
0℃以下で加熱することが望ましいと考えられる。 【0017】次に、前記こんぶ、わかめおよびひじきを
予め200〜250μmに粉末化したものを、70℃で
加熱した場合の加熱時間と粘度との関係を見たのが図4
である。図4に示すように、70℃になってから5分程
度で粘度は急激に低下するという結果が得られた。この
ことから、70℃にまで温度が上昇したら、速やかに加
熱を止め、自然冷却することが必要である。 【0018】前記のように、本発明方法においては、水
を加えて原料を加熱するが、そのときの加熱時間は55
〜60分が粘度の変化などからみて良い。すなわち、図
5のように、徐々に温度を上昇させ、70℃程度で加熱
を停止することが望ましい。 【0019】前記図1〜図5に示すテストの結果、本発
明方法は以下の工程により構成される。第1工程とし
て、こんぶ、わかめおよびひじきを2cm程度に荒く破
砕したものに、3倍量程度の水を加えて3分程度脱塩し
た後、脱塩した後の塩分を含んだ水分を水切りして除去
して脱塩工程を完了する。 【0020】第2工程として、前記脱塩工程を経た後、
前記脱塩後のこんぶ、わかめおよびひじきに2倍量程度
の水を加えて加熱する加熱工程に入る。この加熱工程
は、室温から約50〜60℃/hの昇温速度で1時間加
熱し、1時間後に70℃になるよう加熱して、この70
℃になった状態で直ちに加熱を停止する。 【0021】次に、第3工程として、前記加熱工程で加
熱されたこんぶ、わかめおよびひじきを熱風乾燥させる
乾燥工程に入る。この乾燥工程は、前記原料を60〜8
0℃で16〜18時間程度乾燥させる。 【0022】そして第4工程として、前記乾燥工程によ
り乾燥したこんぶ、わかめおよびひじきを粉砕機で粗粉
砕する粗粉砕工程に入る。この粗粉砕工程により、前記
こんぶ、わかめおよびひじきを5mm〜8mm程度の粗
粉末とする。 【0023】第5工程として、前記粗粉砕工程により粗
粉末に粉砕されたこんぶ、わかめおよびひじきの粗粉末
を蒸気滅菌する殺菌工程に入る。 【0024】そして、最後に第6工程として前記殺菌工
程を経たこんぶ、わかめおよびひじきの粗粉末を、粉砕
機で100メッシュ程度に微粉砕する微粉砕工程により
微粉末として、こんぶ、わかめおよびひじきの有効成分
を保持した粉末状の食品素材を製造するのである。 【0025】前記工程によって製造された食品素材は、
粉末のまま野菜ジュース等の飲料物に適宜添加混入し
て、所謂健康飲料として飲用に供することもできる。 【0026】更に、前記工程によって製造された粉末状
の食品素材に還元麦芽糖、または澱粉等を加えて製造
し、顆粒状とすることにより、健康食品として食するこ
ともできる。 【0027】 【発明の効果】本発明は上述のようであるから、こん
ぶ、わかめおよびひじきの有効成分であるアルギン酸や
フコイダン等の粘質多糖類やミネラル、ビタミン類、食
物繊維等を可能な限り破壊することなく製造され、且つ
有効成分が水に溶けやすいので、健康飲料あるいは健康
食品素材として極めて有用である。
Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a food material containing active ingredients of kelp, seaweed and hijiki having different physicochemical properties. 2. Description of the Related Art Conventionally, a method of pulverizing seaweed in order to use it as a seaweed juice or seaweed beverage starting from seaweed such as konbu is known. For example, to soften algae, heating until softening regardless of the heating time,
There are known methods of extracting an extract component using a juicer, using chemicals such as alkali, and softening the raw seaweed using an enzyme to powder. [0003] However, in the above-mentioned conventional pulverization method, there is no production method conscious of the active ingredients peculiar to seaweed, for example, viscous polysaccharides, minerals and vitamins. Therefore, there is a problem that the seaweed powder obtained by the conventional powdering method hardly contains an active ingredient, and there is no effect as a nutritional food even when used as a food material. [0004] The present invention has been made to solve the above-mentioned problems, and has an active ingredient of konbu, wakame and hijiki which does not lose an active ingredient such as a viscous polysaccharide, a mineral and a vitamin. It is an object of the present invention to provide a method for producing a food material. SUMMARY OF THE INVENTION [0005] The present invention provides a method of crushing kelp, seaweed and seaweed roughly, adding about three times the amount of water thereto, desalinating for about three minutes, and removing water containing salt. And then adding about twice the amount of water to the konbu, wakame and hijiki that have passed through the desalting step, and heating the mixture at room temperature for about 1 hour at a heating rate of about 50-60 ° C./h. A heating step of heating the mixture to 70 ° C. after one hour and then immediately stopping the heating; and a drying step of drying the konbu, wakame and hijiki heated in the heating step at 60 to 80 ° C. for about 16 to 18 hours. And the konbu dried in the drying step,
A coarse pulverizing step of coarsely pulverizing wakame and hijiki with a pulverizer to obtain a coarse powder, a konbu obtained by the coarse pulverizing step, a sterilizing step of steam sterilizing the coarse powder of wakame and hijiki, and a konbu which has passed through the sterilizing step The above problem was solved by adopting a means for producing by a fine powder step of pulverizing coarse powder of wakame and hijiki into fine powder with a pulverizer. DESCRIPTION OF THE PREFERRED EMBODIMENTS At the present time, which is said to be the period of satiety, unbalanced eating habits have led to lifestyle-related diseases such as hypertension, arteriosclerosis, diabetes and the like reaching even younger people. It is also known that these lifestyle-related diseases can be prevented if the daily diet is properly maintained. [0007] As one of them, it is said that it can be prevented by taking seaweed every day. Since seaweeds grow in seawater containing all the elements present on the earth, they not only contain a large amount of minerals and vitamins in their alga bodies, but especially in brown algae, kombu, wakame and hijiki. It is rich in mucous polysaccharides such as alginic acid and fucoidan which are only present in these. Further, it is known that these mucous polysaccharides also function as water-soluble dietary fiber, and have various healthy functions in the human body together with insoluble dietary fiber. From the foregoing, it can be seen that the present invention retains the active ingredient in such a manner that the physicochemical properties and nutritional value of the konbu, wakame and hijiki are preserved as little as possible. It is intended to obtain a powdery food material in which the active ingredient is easily soluble in water. As the raw materials of the present invention, alginic acid and fucoidan, which are the only viscous polysaccharides contained only in brown algae among sea algae as described above, are used. Three types of hijiki were adopted. [0010] The present invention relates to chemicals such as acids and alkalis, which are used to prevent as much as possible destruction of viscous polysaccharides such as alginic acid and fucoidan, minerals, vitamins and dietary fiber contained in konbu, wakame and hijiki. The present invention relates to a method for producing by controlling the amount of water, the heating temperature, and the heating time without using any kind of phenol. Hereinafter, the method of the present invention will be described in detail. The mixing ratio of each raw material in the present invention is not particularly limited, but is preferably 2
0-70% by weight, Konbu 20-70% by weight, Hijiki 10
-20% by weight, particularly preferably 50% by weight of wakame, 35% by weight of konbu, and 15% by weight of hijiki. In the present invention, as described above, the main purpose is to effectively utilize the viscous polysaccharides of kelp, seaweed and hijiki, which are brown algae. Therefore, the viscosity of the viscous polysaccharide is maintained while maintaining a certain degree of viscosity. It must be a product that does not decompose. Therefore, the change in physical properties before and after heating was determined by measuring the viscosity, and the viscosity was measured by an Ostwald viscometer. In addition, in FIG. 2 described later, the viscosity shows an apparent value, but can be converted to a true value. The raw materials used in the method of the present invention, konbu, wakame and hijiki, contain too much salt to be used as they are. Therefore, desalting is required. Therefore, an appropriate desalting time was determined from the viscosity of the product powdered by the method of the present invention described later and the viscosity of deionized water. As a result, FIG.
As shown in (1), when the desalting time is 10 minutes or more, the viscosity of the product is greatly reduced. Therefore, the desalting time must be performed within 3 minutes. The viscosity of the demineralized water increases with time, but this is due to the elution of cold water soluble substances contained in konbu, seaweed and hijiki, and it is thought that relatively low-molecular alginic acid and fucoidan are also contained. Can be Also, it is considered that the desalination efficiency increases as the amount of the desalinated water increases, but it is appropriate that the amount is about three times the weight of the raw material. As a preliminary experiment for determining the heating temperature and heating time after desalination, konbu, wakame and hijiki were previously powdered to 200 to 250 μm, and the temperature was adjusted to 120 ° C. using an autoclave. When the relationship between the heating time and the viscosity was investigated after the temperature was raised, the result as shown in FIG. 2 was obtained. That is, a decrease in viscosity was observed as the heating time increased. This was presumed to be due to the decomposition of the mucous polysaccharide by heating at a high temperature for a long time. Next, regarding the amount of water during heating, after desalting, dewatering and then transferring the raw materials to a kneader for heating,
Add twice the amount of water to the raw material. The appropriate ratio of raw material weight to water amount has been obtained from several experiments. This is because when the ratio is the above, the mucous polysaccharide, which is regarded as the most important, hardly drops when transferring to the open-type dryer in the subsequent step, and after the transfer, which meets the object of the present invention. That is, if the amount of water is smaller than the above-mentioned amount, a so-called burnt state is obtained, and if the amount of water is large, an effective ingredient including a viscous component flows out. Further, regarding the relationship between the heating temperature and the heating time, it was considered necessary to carry out the treatment at a temperature lower than 120 ° C. as described above, so that the konbu, wakame and hijiki were previously set at 200 to 250 μm. Heating the powdered material at 80 to 100 ° C. and examining the relationship with the viscosity revealed that, as shown in FIG. 3, the higher the heating temperature, the lower the viscosity. . From these results and experimental results such as changes in dietary fiber due to heat, etc.
It is considered desirable to heat at 0 ° C. or lower. Next, FIG. 4 shows the relationship between the heating time and the viscosity when the konbu, wakame and hijiki were previously powdered to 200 to 250 μm and heated at 70 ° C.
It is. As shown in FIG. 4, a result was obtained in which the viscosity sharply decreased in about 5 minutes after the temperature reached 70 ° C. For this reason, when the temperature rises to 70 ° C., it is necessary to stop heating immediately and cool naturally. As described above, in the method of the present invention, the raw material is heated by adding water.
Up to 60 minutes is good in view of the change in viscosity. That is, as shown in FIG. 5, it is desirable to gradually increase the temperature and stop the heating at about 70 ° C. As a result of the tests shown in FIGS. 1 to 5, the method of the present invention comprises the following steps. In the first step, kelp, seaweed and hijiki are roughly crushed to about 2 cm, and about 3 minutes of water is added to desalinate for about 3 minutes. Then, water containing salt is drained after desalination. To complete the desalting process. As a second step, after the desalting step,
A heating step of adding about twice the amount of water to the konbu, wakame and hijiki after the desalting and heating the mixture is started. In this heating step, heating is performed for 1 hour at a heating rate of about 50 to 60 ° C./h from room temperature, and after 1 hour, heating is performed to 70 ° C.
Stop heating immediately when the temperature reaches ° C. Next, as a third step, a drying step of drying the konbu, wakame and hijiki heated in the heating step with hot air is started. In this drying step, the raw materials are
Dry at 0 ° C. for about 16-18 hours. Then, as a fourth step, a coarse pulverizing step of coarsely pulverizing the dried kelp, wakame and hijiki in the drying step with a pulverizer is performed. By this coarse pulverizing step, the konbu, wakame and hijiki are turned into coarse powder of about 5 mm to 8 mm. As a fifth step, a sterilization step of steam-sterilizing the kelp, wakame and hijiki coarse powder pulverized into the coarse powder by the coarse pulverization step is started. Finally, as a sixth step, the coarse powder of konbu, wakame and hijiki which has passed through the sterilization step is finely pulverized to about 100 mesh with a pulverizer to obtain fine powder of konbu, wakame and hijiki. It produces a powdered food material containing the active ingredient. The food material produced by the above process is
The powder can also be added as needed to beverages such as vegetable juices and mixed, and used as a so-called health drink. Furthermore, reduced maltose, starch or the like is added to the powdery food material produced by the above-mentioned process to produce granules, which can be eaten as health foods. Since the present invention is as described above, viscous polysaccharides such as alginic acid and fucoidan, minerals, vitamins, dietary fiber and the like, which are the active ingredients of konbu, seaweed and hijiki, are used as much as possible. Since it is manufactured without breaking and the active ingredient is easily soluble in water, it is extremely useful as a health drink or health food material.

【図面の簡単な説明】 【図1】原材料の脱塩時間と脱塩水並びに本発明方法に
よる製品の粘度との関係図である。 【図2】こんぶ、わかめおよびひじき粉末の加熱時間と
粘度との関係図である。 【図3】こんぶ、わかめおよびひじき粉末の加熱温度と
粘度との関係図である。 【図4】こんぶ、わかめおよびひじき粉末の70℃での
加熱時間と粘度との関係図である。 【図5】原材料の加熱時間と水温との関係図である。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a diagram showing the relationship between the desalting time of raw materials, the desalinated water and the viscosity of the product according to the method of the present invention. FIG. 2 is a graph showing the relationship between heating time and viscosity of konbu, wakame, and hijiki powder. FIG. 3 is a graph showing the relationship between heating temperature and viscosity of konbu, wakame, and hijiki powder. FIG. 4 is a graph showing the relationship between viscosity and heating time at 70 ° C. for kombu, wakame and hijiki powder. FIG. 5 is a diagram showing a relationship between a heating time of raw materials and a water temperature.

Claims (1)

【特許請求の範囲】 【請求項1】こんぶ、わかめおよびひじきを荒く破砕し
て、これに3倍量程度の水を加え3分程度脱塩して、塩
分を含んだ水分を水切りして除去する脱塩工程と、 前記脱塩工程を経たこんぶ、わかめおよびひじきに2倍
量程度の水を加え、室温から約50〜60℃/hの昇温
速度で1時間加熱し、1時間後に70℃になるよう加熱
した後、直ちに加熱を停止する加熱工程と、 前記加熱工程で加熱されたこんぶ、わかめおよびひじき
を、60〜80℃で16〜18時間程度乾燥させる乾燥
工程と、 前記乾燥工程で乾燥したこんぶ、わかめおよびひじきを
粉砕機で粗粉砕して粗粉末とする粗粉砕工程と、 前記粗粉砕工程によって得られたこんぶ、わかめおよび
ひじきの粗粉末を蒸気滅菌する殺菌工程と、 前記殺菌工程を経たこんぶ、わかめおよびひじきの粗粉
末を粉砕機で微粉末に粉砕する微粉末工程とにより製造
することを特徴とするこんぶ、わかめおよびひじきの有
効成分を保持した食品素材の製造方法。
[Claim 1] Kombu, seaweed and seaweed are roughly crushed, to which about 3 times the amount of water is added, desalted for about 3 minutes, and water containing salt is drained off. And about 2 times the amount of water added to the konbu, wakame and hijiki that have passed through the desalting step, and heated from room temperature at a heating rate of about 50 to 60 ° C./h for 1 hour. ° C, heating immediately after stopping the heating, a drying step of drying the kelp, wakame and hijiki heated in the heating step at 60 to 80 ° C for about 16 to 18 hours, and a drying step. A coarse crushing step of coarsely pulverizing the dried kelp, seaweed and hijiki with a crusher to obtain a coarse powder; Through the sterilization process Kelp, seaweed and kelp a coarse powder of seaweed, characterized in that produced by the powder process of grinding to a fine powder with a grinder, seaweed and manufacturing method of the food material which holds the active ingredients of hijiki.
JP2002066352A 2002-03-12 2002-03-12 Method for producing food material having active ingredients of kombu, seaweed and hijiki Expired - Fee Related JP3721431B2 (en)

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JP2002066352A JP3721431B2 (en) 2002-03-12 2002-03-12 Method for producing food material having active ingredients of kombu, seaweed and hijiki

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JP2003259842A true JP2003259842A (en) 2003-09-16
JP3721431B2 JP3721431B2 (en) 2005-11-30

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