JP2003155541A - High strength hot rolled steel sheet having excellent corrosion resistance and stretch-flanging property, and production method therefor - Google Patents

High strength hot rolled steel sheet having excellent corrosion resistance and stretch-flanging property, and production method therefor

Info

Publication number
JP2003155541A
JP2003155541A JP2001352334A JP2001352334A JP2003155541A JP 2003155541 A JP2003155541 A JP 2003155541A JP 2001352334 A JP2001352334 A JP 2001352334A JP 2001352334 A JP2001352334 A JP 2001352334A JP 2003155541 A JP2003155541 A JP 2003155541A
Authority
JP
Japan
Prior art keywords
steel sheet
stretch
corrosion resistance
rolled steel
strength hot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2001352334A
Other languages
Japanese (ja)
Other versions
JP3728239B2 (en
Inventor
Hiroyuki Tanahashi
浩之 棚橋
Manabu Takahashi
学 高橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP2001352334A priority Critical patent/JP3728239B2/en
Publication of JP2003155541A publication Critical patent/JP2003155541A/en
Application granted granted Critical
Publication of JP3728239B2 publication Critical patent/JP3728239B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide a high strength hot rolled steel sheet which has excellent corrosion resistance and stretch-flanging properties. SOLUTION: The hot rolled steel sheet has a composition containing, by mass, 0.03 to 0.10% C, 0.05 to 1.2% Si, 1.0 to 2.0% Mn, <=0.05% P, <=0.01% S, <=0.005% N and 0.01 to 0.05% Al, and, if required, containing either or both selected from Ti and Nb so as to satisfy -0.05<= Ti+(48/93)×Nb-(48/12)×C-(48/14)×N-(48/32)×S}<=0.2, and, if required, containing Cu, Ni and Ca, and the balance Fe. The thickness of an oxide film containing Fe2 SiO4 on the surface is <5 μm, and the area ratio of a bainitic ferrite phase in the cross-sectional structure is >=80%. In the method of producing the hot rolled steel sheet, the steel is heated to >=1,150 deg.C, is rough-rolled, is thereafter coiled at <=1,150 deg.C, is subjected to finish rolling as-uncoiled so as to be completed at an Ar3 point or higher, is subjected to high speed cooling to <=500 deg.C, and is they coiled at 300 to 500 deg.C.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】本発明は、耐食性と伸びフラ
ンジ性に優れた高強度熱延鋼板、およびその製造方法に
関するものである。
TECHNICAL FIELD The present invention relates to a high-strength hot-rolled steel sheet having excellent corrosion resistance and stretch flangeability, and a method for producing the same.

【0002】[0002]

【従来の技術】自動車部品、特に、足回り部品と呼ばれ
るメンバー類やアーム類などには高強度熱延鋼板が広く
用いられている。これらの部品に要求される鋼板の特性
としては、強度、延性の他に穴広げ試験で評価される伸
びフランジ性がある。これは、こうした部品が他の部品
とボルト接合などの方法で組み合わされることが多く、
その際のボルト穴が、打ち抜き穴のせり出し加工(穴広
げ加工)によって形成されるのが一般的であるからであ
る。
2. Description of the Related Art High-strength hot-rolled steel sheets are widely used for automobile parts, particularly members and arms called suspension parts. The characteristics of the steel sheet required for these parts include strength and ductility as well as stretch-flangeability evaluated by a hole expanding test. This is because these parts are often combined with other parts by methods such as bolting,
This is because the bolt holes at that time are generally formed by the protrusion processing (hole expansion processing) of the punched holes.

【0003】更に具体的に述べれば、打ち抜き穴のせり
出し加工時に、鋼板断面を貫通する亀裂が発生しないこ
とが必要とされ、貫通亀裂を発生させることなく、より
大きく穴径を広げられることがその優劣の指標となる。
More specifically, it is required that cracks that penetrate the steel sheet cross section do not occur during the extrusion processing of the punched hole, and that the hole diameter can be expanded to a larger extent without causing through cracks. It is an indicator of superiority or inferiority.

【0004】伸びフランジ性に優れる鋼板については多
くの提案がなされている。例えば特開平6−17292
4号公報、同7−11382号公報、および、同7−7
0696号公報などがそれである。これらは、鋼板の化
学成分や製造方法の検討を通して、強度と伸びフランジ
性を両立させる方法を見出したものであり、穴広げ加工
時の亀裂の基点となり得る介在物を抑制するとともに、
ベーナイト組織、あるいはベイニティック・フェライト
組織を主相とする鋼板の提案を要旨とするものである。
Many proposals have been made for steel sheets having excellent stretch flangeability. For example, JP-A-6-17292
4, gazette 7-11382, and gazette 7-7.
That is the 0696 publication. These are the ones that have found a method for achieving both strength and stretch-flangeability through the examination of the chemical composition and manufacturing method of the steel sheet, while suppressing the inclusions that can be the base points of cracks during hole expanding,
The gist is the proposal of a steel sheet having a bainite structure or a bainitic ferrite structure as the main phase.

【0005】本発明者らも伸びフランジ性に優れた高強
度熱延鋼板の研究開発に取り組み、上記提案と同様に、
介在物制御と鋼板組織のベーナイト相化、あるいはベイ
ニティック・フェライト相化が基本的には優れた鋼板を
得る手段であるとの結論に達し、さらに改良を試みてい
るところであった。
The inventors of the present invention also worked on research and development of a high-strength hot-rolled steel sheet excellent in stretch-flangeability, and in the same manner as the above proposal,
It was concluded that the inclusion control and the bainitic phase of the steel sheet structure, or the bainitic ferrite phase is basically the means to obtain an excellent steel sheet, and we were trying to improve it further.

【0006】中でも当該組織の鋼板を得るのに最も重要
である圧延後の冷却条件の制御に腐心を払い、通常の圧
延方法では冷却条件が不安定と成り易い、鋼板の先端部
と後端部の、鋼板が仕上圧延機を出てから巻き取られる
までの部分も含めた材質作りこみのためにエンドレス圧
延法の適用検討も進めていた。なお、ここで言うエンド
レス圧延法とは、粗圧延した熱延材(以下、粗バーと言
う)を仕上圧延前に次々と接合して複数の粗バーを連続
的に仕上圧延し、適宜切断して熱延コイルを製造する方
法のことである。
Above all, the control of cooling conditions after rolling, which is the most important for obtaining a steel sheet having the structure, is devised, and the cooling conditions are likely to become unstable in the ordinary rolling method. However, we were also studying the application of the endless rolling method in order to create the material including the part from the exit of the finish rolling mill to the winding of the steel sheet. The endless rolling method referred to here means that rough rolled hot rolled materials (hereinafter referred to as rough bars) are joined one after another before finish rolling to continuously finish roll a plurality of rough bars and appropriately cut them. It is a method of manufacturing a hot rolled coil.

【0007】[0007]

【発明が解決しようとする課題】一方、最近、自動車の
平均的な使用期間が長くなる傾向が明確になり、それに
合わせて自動車メーカーも従来以上に高耐久性を各部材
に求めるようになった。足回り部品についても例外では
なく、従来それほど厳しく求められていなかった耐食性
が求められるようになった。
On the other hand, recently, it has become clear that the average usage period of automobiles becomes longer, and in response to this, automobile manufacturers have come to demand higher durability for each member than ever before. . Suspension parts are no exception, and corrosion resistance, which has not been so strictly demanded in the past, is now required.

【0008】足回り部品は、外板パネルなどに比べては
るかに厚肉であること、また、ステンレス鋼などとは異
なり、局部的な激しい腐食の心配は少ないことから、さ
び代を考慮して部品設計を行うことによって耐食性を確
保することが行われて来たが、車体の軽量化に対する要
求が一段と強まる中にあっては、こうした思想も変更を
余儀なくされてきており、耐食性に対する要求も回避で
きないものとなった。
Since the underbody parts are much thicker than the outer panel, etc., and unlike stainless steel, there is little concern about local severe corrosion. Although it has been attempted to ensure corrosion resistance by designing parts, as the demand for weight reduction of vehicle bodies has increased, these ideas have been forced to change, and the requirement for corrosion resistance has been avoided. It became impossible.

【0009】こうした情勢から、従来の足回り用高強度
熱延鋼板が有していた強度、延性、伸びフランジ性に加
えて耐食性が求められることとなったが、こうした視点
に立った鋼板に関する提案は皆無に近い。
Under these circumstances, corrosion resistance was required in addition to the strength, ductility and stretch flangeability that conventional high strength hot rolled steel sheets for underbody have had, but proposals for steel sheets from this viewpoint Is almost empty.

【0010】一般的に、Si含有量の高い鋼板では、塗
料密着性確保の目的で行われる化成皮膜の形成が難し
く、耐食性確保の観点からは望ましくないとの指摘があ
るが、Siは伸びフランジ性を劣化させることなく強度
を高めるのに有効な元素であるからむやみに少なくする
ことは好ましくない。そこでSi量の抑制に頼ることな
く優れた化成処理性、ひいては耐食性を確保し、併せて
伸びフランジ性にも優れた高強度熱延鋼板を提供するこ
とが、本発明が解決しようとする課題である。
In general, it is pointed out that it is difficult to form a chemical conversion film for the purpose of ensuring paint adhesion on a steel sheet having a high Si content, which is not desirable from the viewpoint of ensuring corrosion resistance, but Si is a stretch flange. Since it is an element effective for increasing the strength without deteriorating the property, it is not preferable to reduce it unnecessarily. Therefore, it is an object of the present invention to provide a high-strength hot-rolled steel sheet that secures excellent chemical conversion treatability without failing to suppress the amount of Si, by extension, corrosion resistance, and also has excellent stretch flangeability. is there.

【0011】[0011]

【課題を解決するための手段】既に述べたように、本発
明者らは、目標とする鋼板の製造方法にエンドレス圧延
を適用すべく検討を進めていた。この方法を用いること
によって従来にはない特性を更に付加出来ないか研究を
行っていた。本発明はこのような過程で見出だされ、詳
細な検討を経て完成されたものであり、その要旨は、 (1)質量%にて、 C :0.03〜0.10%、 Si:0.05〜1.2%、 Mn:1.0 〜2.0%、 P :0.05%以下、 S :0.0 1%以下、 N :0.005%以下、 Al:0.01〜0.05%を含有し、更にTi,Nb
の一方あるいは双方を -0.05≦{Ti+(48/93)×Nb-(48/1
2)×C -(48/14)×N-(48/32)×S}≦0.2 となるように含
有し、残部がFeおよび不可避不純物からなり、表面の
Fe2 SiO4 を含む酸化膜の厚さが5μm未満であ
り、かつ断面組織におけるベイニティック・フェライト
相の面積率が80〜100%であることを特徴とする耐
食性と伸びフランジ性に優れた高強度熱延鋼板。
As described above, the present inventors have been studying to apply endless rolling to a target steel sheet manufacturing method. We have been studying whether or not it is possible to add more characteristics that were not available in the past by using this method. The present invention was discovered in such a process, and completed through a detailed study, and the gist thereof is (1)% by mass, C: 0.03 to 0.10%, Si: 0.05 to 1.2%, Mn: 1.0 to 2.0%, P: 0.05% or less, S: 0.01% or less, N: 0.005% or less, Al: 0.01 .About.0.05%, Ti, Nb
-0.05 ≤ (Ti + (48/93) × Nb- (48/1
2) × C − (48/14) × N− (48/32) × S} ≦ 0.2, the balance is Fe and unavoidable impurities, and the surface of the oxide film containing Fe 2 SiO 4 is formed. A high-strength hot-rolled steel sheet having excellent corrosion resistance and stretch-flangeability, which has a thickness of less than 5 μm and an area ratio of bainitic ferrite phase in the cross-sectional structure of 80 to 100%.

【0012】(2)更に、質量%で、 Cu:0.5〜1.5%、 Ni:0.2〜0.7% を含有することを特徴とする上記(1)記載の耐食性と
伸びフランジ性に優れた高強度熱延鋼板。
(2) Further, in terms of mass%, Cu: 0.5 to 1.5% and Ni: 0.2 to 0.7% are contained, and the corrosion resistance and elongation described in (1) above. High strength hot rolled steel sheet with excellent flangeability.

【0013】(3)更に、質量%で、Ca:0.000
5〜0.0025%を含有することを特徴とする上記
(1)または(2)に記載の耐食性と伸びフランジ性に
優れた高強度熱延鋼板。
(3) Further, in mass%, Ca: 0.000
The high-strength hot-rolled steel sheet having excellent corrosion resistance and stretch flangeability according to the above (1) or (2), characterized by containing 5 to 0.0025%.

【0014】(4)上記(1)〜(3)の何れか1項に
記載の鋼板を製造する方法であって、上記(1)〜
(3)の何れか1項に記載の化学成分を有する鋼材を1
150〜1250℃に加熱して粗圧延した後、1150
℃以下の温度においてコイル状に巻取り、巻戻しつつA
r3 点〜Ar3 点+100℃で仕上圧延を完了し、更に
40℃/秒以上の平均冷却速度で300〜500℃まで
冷却し、300〜500℃で巻き取ることを特徴とする
耐食性と伸びフランジ性に優れた高強度熱延鋼板の製造
方法。である。
(4) A method for producing the steel sheet according to any one of (1) to (3) above, which comprises (1) to
The steel material having the chemical composition according to any one of (3) is 1
After heating to 150 to 1250 ° C. and rough rolling, 1150
At a temperature below ℃
Finishing rolling is completed at r3 point to Ar3 point + 100 ° C., further cooled to 300 to 500 ° C. at an average cooling rate of 40 ° C./sec or more, and wound at 300 to 500 ° C., corrosion resistance and stretch flangeability. A method for producing a high-strength hot-rolled steel sheet which is excellent in Is.

【0015】[0015]

【発明の実施の形態】まず、本発明を完成するに至った
実験について以下に説明する。本発明者らはまず、鋼板
のSi含有量と化成処理性について研究を行った。Si
含有量の異なる鋼を常法(エンドレス圧延ではない熱延
方法)によって熱延、酸洗し、次いで同一条件で化成処
理を施した。それらの単位面積当たりの化成皮膜形成量
(質量)を調べたところ、鋼板のSi含有量が増えるに
つれて化成皮膜形成量が減少する傾向が認められた。
BEST MODE FOR CARRYING OUT THE INVENTION First, the experiments that have led to the completion of the present invention will be described below. The present inventors first conducted research on the Si content and chemical conversion treatability of the steel sheet. Si
Steels having different contents were hot rolled and pickled by a conventional method (hot rolling method other than endless rolling), and then subjected to chemical conversion treatment under the same conditions. When the amount (mass) of forming the chemical conversion film per unit area was examined, it was found that the amount of forming the chemical conversion film decreased as the Si content of the steel sheet increased.

【0016】更に詳細に調査したところ、Si含有量の
少ない鋼板の化成処理皮膜は緻密なリン酸塩の結晶で構
成されているのに対して、Si含有量の多い鋼板ではリ
ン酸塩の結晶が粗大であるばかりでなく、皮膜が全く形
成されていない箇所すらあることがわかった。またこう
した場所にはFe2 SiO4 を主要成分とする物質(以
下、Fe−Si系スピネルという)が鋼板表面と平行に
厚く存在していることも明らかとなった。このことか
ら、何らかの方法でFe−Si系スピネル層の厚さを抑
制できればSi含有量に関わらず優れた化成処理性が確
保できるものと考えて更に検討を進めた。
A more detailed examination revealed that the chemical conversion treatment film of the steel sheet having a low Si content was composed of dense phosphate crystals, whereas the steel sheet having a high Si content had phosphate crystals. It was found that not only was it coarse, but there were even places where no film was formed. It was also clarified that a substance containing Fe 2 SiO 4 as a main component (hereinafter referred to as Fe—Si spinel) was thickly present in such a place in parallel with the surface of the steel sheet. From this, it was thought that if the thickness of the Fe-Si based spinel layer could be suppressed by some method, excellent chemical conversion treatability could be secured regardless of the Si content, and further studies were conducted.

【0017】なお、単にFe−Si系スピネル層を薄く
すること(完全に無くすことも含む)を目的とするので
あれば、熱延後の酸洗時間を長くする、酸洗液中の酸の
濃度を高くする、酸洗液の温度を高くする、あるいは、
研削などの方法で機械的に除去することなどの選択も考
えられるが、そうした方法は製造コストを押し上げ、熱
延鋼板本来のコストパフォーマンスを損ねるだけである
ので本発明者らは、熱延スケールの除去は一般的な酸洗
(例えば、80℃の5%HClに30秒程度浸漬する)
によって行うことを前提にした。
For the purpose of simply thinning the Fe-Si spinel layer (including completely eliminating it), the pickling time after hot rolling should be lengthened. Increase the concentration, increase the temperature of the pickling solution, or
Although it may be possible to select such as mechanically removing by a method such as grinding, since the method only raises the manufacturing cost and impairs the original cost performance of the hot-rolled steel sheet, the present inventors have For removal, general pickling (for example, soaking in 5% HCl at 80 ° C for 30 seconds)
It was supposed to be done by.

【0018】一方、エンドレス圧延法適用検討の一環と
して、粗バーに粗圧延後のコイル巻取りを模擬した加工
を施した試験片を仕上圧延、酸洗後、化成処理したとこ
ろ、同じSi含有量であるにも関わらず、仕上圧延前に
該加工を施した鋼板の化成処理性は該加工を行っていな
いものより優れていることを見出した。また、そうした
相違が鋼板表面のFe−Si系スピネル層の厚さの違い
によってもたらされていることも見出した。
On the other hand, as a part of studying the application of the endless rolling method, a test piece obtained by subjecting a rough bar to a work simulating coil winding after rough rolling was finish-rolled, pickled, and subjected to chemical conversion treatment. However, it has been found that the chemical conversion treatability of the steel sheet subjected to the working before finish rolling is superior to that of the steel sheet not subjected to the working. It was also found that such a difference is caused by the difference in the thickness of the Fe-Si based spinel layer on the surface of the steel sheet.

【0019】本発明者らは、この発見に立脚した研究を
推し進め、強度、延性、伸びフランジ性に加えて耐食性
にも優れる熱延鋼板を得るための化学成分、および製造
条件を明らかとして本発明を完成させるに至った。
The present inventors promoted research based on this discovery, and made clear the chemical composition and manufacturing conditions for obtaining a hot-rolled steel sheet having excellent corrosion resistance in addition to strength, ductility, stretch flangeability, and the present invention. Has been completed.

【0020】以下に本発明の限定理由を述べる。まず化
学成分について述べる。成分の含有率は質量%である。 C:0.03〜0.10%。Cは鋼板の強度を確保する
ために必須の元素であり、高強度鋼板を得るためには少
なくとも0.03%が必要である。しかし、過剰に含ま
れると、TiやNbによる炭化物生成や、冷却条件を駆
使しても、伸びフランジ性に好ましくないセメンタイト
相の生成が避けられなくなるので0.1%以下とする。
The reasons for limiting the present invention will be described below. First, the chemical components will be described. The content rate of the component is mass%. C: 0.03 to 0.10%. C is an essential element for ensuring the strength of the steel sheet, and at least 0.03% is necessary to obtain a high-strength steel sheet. However, if it is contained in excess, it becomes unavoidable to generate carbides due to Ti or Nb and generation of a cementite phase unfavorable for stretch flangeability even if the cooling conditions are fully utilized, so the content is made 0.1% or less.

【0021】Si:0.05〜1.2%。Siは伸びフ
ランジ性を劣化させることなく強度を確保するのに有効
な元素であるが、過剰に含まれると伸びフランジ性に好
ましくないポリゴナル・フェライト相を生成しやすくな
る。また、本発明の製造方法を用いても耐食性の劣化を
抑制できなくなるのでその上限は1.2%とする。
Si: 0.05 to 1.2%. Si is an element effective for ensuring the strength without deteriorating the stretch-flangeability, but if it is contained in excess, it tends to generate a polygonal ferrite phase which is unfavorable for the stretch-flangeability. Further, even if the manufacturing method of the present invention is used, deterioration of corrosion resistance cannot be suppressed, so the upper limit is made 1.2%.

【0022】Mn:1.0〜2.0%。MnはC,Si
とともに鋼板の高強度化に有効な元素であり、1.0%
以上は含有させるべきであるが、2.0%を越えて含有
させるとエンドレス圧延のための粗バー接合性に悪影響
を及ぼすので上限を2.0%とする。
Mn: 1.0 to 2.0%. Mn is C, Si
Along with 1.0%, it is an element effective in strengthening steel sheets.
The above should be contained, but if it exceeds 2.0%, it adversely affects the rough bar bondability for endless rolling, so the upper limit is made 2.0%.

【0023】P:0.05%以下。Pは固溶強化元素と
して有効であるが、偏析による加工性の劣化やMnと同
様粗バーの接合性に悪影響を及ぼすので0.05%以下
にする必要がある。
P: 0.05% or less. P is effective as a solid solution strengthening element, but since it deteriorates the workability due to segregation and adversely affects the bondability of the rough bar like Mn, it must be made 0.05% or less.

【0024】S:0.01%以下。SはMnSなどの介
在物を形成して伸びフランジ性を劣化させる他、Cを炭
化物とする目的で含有させるTiと結合してその歩留り
を低下させるなどの有害な作用をする。従って出来るだ
け抑制すべきであるが0.01%以下であれば許容され
る。
S: 0.01% or less. S forms an inclusion such as MnS to deteriorate the stretch flangeability, and also has a harmful effect such as a decrease in the yield by combining with Ti contained for the purpose of making C a carbide. Therefore, the amount should be suppressed as much as possible, but 0.01% or less is acceptable.

【0025】N:0.005%以下。NはAlNなどの
介在物を形成してのびフランジ性を劣化させる他、Cを
炭化物とする目的で含有させるTiと結合してその歩留
りを低下させる。従って出来るだけ抑制すべきであるが
0.005%以下であれば許容される。
N: 0.005% or less. N forms inclusions such as AlN and deteriorates the spreadability, and also binds with Ti contained for the purpose of converting C into a carbide to reduce the yield. Therefore, it should be suppressed as much as possible, but 0.005% or less is acceptable.

【0026】Al:0.01〜0.05%。Alは溶鋼
脱酸のために0.01%以上添加する必要があるが、
0.05%を超えて含有すると生成物が凝集粗大化して
連続鋳造ノズルの目詰まりを引き起こしたり、穴広げ加
工時の割れ発生の起点となったりし易いので0.01〜
0.05%の範囲とする。
Al: 0.01 to 0.05%. Al needs to be added in an amount of 0.01% or more for deoxidation of molten steel,
If the content is more than 0.05%, the product tends to aggregate and coarsen to cause clogging of the continuous casting nozzle or to become a starting point of cracking during hole expansion processing.
The range is 0.05%.

【0027】Ti,Nbの一方あるいは双方: -0.05≦{Ti+(48/93)×Nb-(48/12)×C-(48/14)×N-(48/3
2)×S}≦0.2 TiおよびNbはC,SおよびNを析出物として固定す
ることによって鋼板の加工性を向上させる(いわゆるsc
avenging効果)働きをする。一方、必要以上に添加され
た場合には、それらは固溶Tiや固溶Nbとして鋼中に
存在し、再結晶を温度を上昇させ熱間加工組織が残存し
易くなり延性を損ねる。そしてその最適な添加量の範囲
は、実施例の中で示すように、各元素の化学当量を用い
て記述される上記式の中辺を指標として用いると適切に
表すことができる。すなわち、その値が−0.05未満
では延性、穴広げ性が劣り、また0.2を超えると延性
が劣化する。以上の理由から上記の式を満たすように限
定されなければならない。
One or both of Ti and Nb: -0.05≤ {Ti + (48/93) × Nb- (48/12) × C- (48/14) × N- (48/3
2) × S} ≦ 0.2 Ti and Nb improve workability of steel sheet by fixing C, S and N as precipitates (so-called sc
avenging effect) work. On the other hand, if added more than necessary, they are present in the steel as solid solution Ti or solid solution Nb and raise the temperature of recrystallization, tending to leave a hot work structure and impairing ductility. Then, the optimum range of the addition amount can be appropriately expressed by using the middle side of the above formula described using the chemical equivalent of each element as an index, as shown in Examples. That is, if the value is less than -0.05, the ductility and hole expandability are poor, and if it exceeds 0.2, the ductility is deteriorated. For the above reasons, it must be limited to satisfy the above formula.

【0028】Cu:0.5〜1.5%。Cuは、固溶強
化元素または析出強化元素として鋼板の高強度化に利用
できる。しかし、0.5%以上を添加しないとその効果
は少ない。一方、1.5%を越えて含有されていると熱
延中の鋼板表面性状を悪化させるので1.5%を上限と
する。
Cu: 0.5-1.5%. Cu can be used as a solid solution strengthening element or a precipitation strengthening element for increasing the strength of the steel sheet. However, the effect is small unless 0.5% or more is added. On the other hand, if the content exceeds 1.5%, the surface properties of the steel sheet during hot rolling deteriorate, so the upper limit is 1.5%.

【0029】Ni:0.2〜0.7%。Niは上記Cu
による熱延表面性状悪化を緩和する効果があり、Cuの
約半分である0.2%以上を添加することが望ましい。
一方、0.7%を超えて添加してもその効果は飽和し、
鋼材の価格を上げるだけなので、0.7%を上限とす
る。
Ni: 0.2 to 0.7%. Ni is the above Cu
It has the effect of alleviating the deterioration of the hot rolled surface quality due to, and it is desirable to add 0.2% or more which is about half of Cu.
On the other hand, even if added over 0.7%, the effect is saturated,
Since it only raises the price of steel materials, the upper limit is 0.7%.

【0030】Ca:0.0005〜0.0025%。C
aは0.0005%以上含有すると、生成される介在物
を低融点化することによって球状化し、穴広げ時の割れ
の起点になるのを抑制する作用を有する。その作用は
0.0025%でほぼ飽和するのでそれ以下の添加でよ
い。
Ca: 0.0005 to 0.0025%. C
When a is contained in an amount of 0.0005% or more, it has an action of suppressing the formation of inclusions into a spherical shape by lowering the melting point thereof and becoming a starting point of cracks at the time of hole expansion. The effect is almost saturated at 0.0025%, so addition of less than that is sufficient.

【0031】なお、本発明において上記以外の成分はF
eとなるが、スクラップなどの溶解原料から混入する不
可避的不純物は許容される。
In the present invention, the components other than the above are F
However, inevitable impurities that are mixed in from melted raw materials such as scrap are allowed.

【0032】次に加熱、圧延、冷却、および、巻取りの
各条件について述べる。 加熱温度:1150〜1250℃。TiCやNbCなど
を固溶させるためには加熱温度を1150℃以上とする
ことが必要である。これらを固溶させておくことによ
り、圧延後の冷却過程でポリゴナルなフェライトの生成
が抑制され、伸びフランジ性にとって好ましいベイニテ
ィック・フェライト相を主体とする組織が得られる。一
方、加熱温度が1250℃を超えるとスラブ表面の酸化
が著しくなり、特に粒界が選択的に酸化されたことに起
因すると思われる楔状の表面欠陥がデスケーリング後に
残り、それが圧延後の表面品位を損ねるので上限を12
50℃とする。
Next, heating, rolling, cooling, and winding conditions will be described. Heating temperature: 1150 to 1250 ° C. In order to form a solid solution of TiC, NbC, etc., it is necessary to set the heating temperature to 1150 ° C or higher. By forming a solid solution of these, the formation of polygonal ferrite is suppressed in the cooling process after rolling, and a structure mainly composed of a bainitic ferrite phase for stretch flangeability can be obtained. On the other hand, when the heating temperature exceeds 1250 ° C, the slab surface is significantly oxidized, and in particular, wedge-shaped surface defects that are considered to be caused by selective oxidation of grain boundaries remain after descaling, which is the surface after rolling. The upper limit is 12 because it impairs quality.
Set to 50 ° C.

【0033】粗バーをコイル状に巻き取る温度:115
0℃以下。本温度は本発明中最も重要な条件の一つであ
る。実施例の中で後述するように、1150℃以下にお
いて粗バーを巻取ると、化成処理性が著しく向上する。
そのメカニズムは必ずしも明らかではないが、恐らく、
適切な温度の範囲で粗バーを巻取ると、鋼板中のSi
の、(粗圧延中に形成された熱延スケール直下の)地鉄
表層への濃化が抑制され、その結果、仕上圧延中、およ
び仕上圧延後に形成される熱延スケール下部(地鉄直
上)にFe−Si系スピネルが生成しにくくなり、続く
酸洗工程でそれらは完全に除去されるか、極めて少なく
なるため、そのことが化成処理性の向上に関係している
ものと思われる。
Temperature at which the coarse bar is wound into a coil: 115
0 ° C or less. This temperature is one of the most important conditions in the present invention. As will be described later in Examples, when a rough bar is wound at 1150 ° C. or lower, chemical conversion treatability is remarkably improved.
The mechanism is not always clear, but probably
When the rough bar is wound in the appropriate temperature range, Si in the steel plate
Of the hot-rolled scale (immediately below the hot-rolled scale formed during rough rolling) is suppressed, and as a result, the hot-rolled scale lower portion (directly above the hot-rolled steel) formed during finish rolling and after finish rolling. Fe-Si-based spinels are less likely to be generated, and they are completely removed or extremely reduced in the subsequent pickling step, which seems to be related to the improvement of chemical conversion treatability.

【0034】また、粗バーを巻取る温度の下限は、圧延
中の温度低下や加工発熱などを考慮して仕上圧延完了温
度がAr3 点〜Ar3 点+100℃となるように設定さ
れればよく、概ね950℃好ましくは980℃である。
なお本発明は、エンドレス圧延によって目的とする鋼板
を提供することを前提としているが、粗バーをコイル状
に巻取るものの、他の粗バーと接合せず、単に巻戻して
仕上圧延に供する圧延方法も当然のことながら含まれ
る。
Further, the lower limit of the temperature at which the rough bar is wound may be set so that the finish rolling completion temperature is Ar3 to Ar3 + 100 ° C. in consideration of the temperature decrease during rolling and heat generation during processing. The temperature is approximately 950 ° C., preferably 980 ° C.
Note that the present invention is premised on providing a target steel sheet by endless rolling, but although the rough bar is wound in a coil shape, it is not joined with other rough bars, but simply rolled back for finish rolling. Methods are of course included.

【0035】仕上圧延完了温度:Ar3 点〜Ar3 点+
100℃。伸びフランジ性にとって好ましいベイニティ
ック・フェライト相を主体とする組織を得るためには、
γ域で圧延を行い冷却する必要がある。従って仕上圧延
完了温度はAr3 点以上とする。一方、仕上げ温度がA
r3 点+100℃を超えるとポリゴナル・フェライト相
が生成し易くなるので、上限をAr3 点+100℃とす
る。
Finishing rolling completion temperature: Ar3 point to Ar3 point +
100 ° C. In order to obtain a structure mainly composed of bainitic ferrite phase which is preferable for stretch flangeability,
It is necessary to perform rolling and cooling in the γ range. Therefore, the finish rolling completion temperature is set to Ar3 point or higher. On the other hand, the finishing temperature is A
If the temperature exceeds r3 point + 100 ° C, a polygonal ferrite phase is easily generated, so the upper limit is made Ar3 point + 100 ° C.

【0036】冷却:平均冷却速度40℃/秒以上で30
0〜500℃まで。伸びフランジ性に優れた鋼板を得る
ためには、ポリゴナル・フェライト相の生成を抑制する
必要がある。そのためには40℃/秒以上の平均冷却速
度で300〜500℃まで冷却する必要がある。一方、
組織制御の上では冷却速度に上限を設ける必要はない
が、余りに速い冷却速度は鋼板の冷却を不均一にする恐
れがあり、またそうした冷却を可能にするような設備の
製造には多額の費用が必要になり、そのことで鋼板の価
格の上昇を招くことが考えられる。そうした観点から冷
却速度の上限は100℃/秒とするのが好ましい。ま
た、冷却停止温度が300℃より低くなると伸びフラン
ジ性に好ましくないマルテンサイト相が生成されるの
で、下限を300℃とする。
Cooling: 30 at an average cooling rate of 40 ° C./sec or more
From 0 to 500 ° C. In order to obtain a steel sheet having excellent stretch flangeability, it is necessary to suppress the formation of polygonal ferrite phase. For that purpose, it is necessary to cool to 300 to 500 ° C. at an average cooling rate of 40 ° C./second or more. on the other hand,
Although it is not necessary to set an upper limit on the cooling rate for structural control, too high a cooling rate may cause uneven cooling of the steel sheet, and it is expensive to manufacture equipment that enables such cooling. Is required, which may lead to an increase in steel plate price. From such a viewpoint, the upper limit of the cooling rate is preferably 100 ° C./second. Further, when the cooling stop temperature is lower than 300 ° C., a martensite phase which is unfavorable for stretch flangeability is generated, so the lower limit is set to 300 ° C.

【0037】巻取り温度:300〜500℃。300℃
を下回る温度まで急冷されるとマルテンサイト相が生成
され伸びフランジ性を極端に悪化させる。そこで巻取り
温度は300℃以上とする必要がある。一方、ポリゴナ
ル・フェライト相の生成抑制には500℃以下とする必
要がある。また500℃以下で巻き取ることにより、そ
の後の冷却過程でTiCやNbCが析出し、フェライト
相中の固溶C量を大幅に減少させ、伸びフランジ性の向
上をもたらす。
Winding temperature: 300 to 500 ° C. 300 ° C
When it is rapidly cooled to a temperature below 1, the martensite phase is formed and stretch flangeability is extremely deteriorated. Therefore, the winding temperature needs to be 300 ° C. or higher. On the other hand, it is necessary to set the temperature to 500 ° C. or lower in order to suppress the formation of the polygonal ferrite phase. Further, by winding at 500 ° C. or lower, TiC and NbC are precipitated in the subsequent cooling process, and the amount of solid solution C in the ferrite phase is significantly reduced, and the stretch flangeability is improved.

【0038】次に、鋼板の表面と組織について説明す
る。 Fe2 SiO4 を含む酸化膜の厚さ:5μm未満(0を
含む)。本発明者らは塩酸を用いて熱延スケールを除去
した鋼板の表面を詳細に調査した。希薄塩酸水溶液中へ
の浸漬時間を少しずつ変えた試験片を用意し、エリプソ
メトリーによる酸化膜厚さの測定と透過電子顕微鏡によ
るレプリカ観察による酸化物の同定を行った。
Next, the surface and structure of the steel sheet will be described. Thickness of oxide film containing Fe 2 SiO 4 is less than 5 μm (including 0). The present inventors investigated in detail the surface of the steel sheet from which the hot rolled scale was removed using hydrochloric acid. A test piece prepared by gradually changing the immersion time in a dilute hydrochloric acid aqueous solution was prepared, and the oxide film thickness was measured by ellipsometry and the oxide was identified by replica observation by a transmission electron microscope.

【0039】その結果、地鉄上にはSiO2 を主に含む
層、Fe2 SiO4 を主に含む層、Fe34 とFe2
3 を主に含む層がこの順に積層して酸化膜を形成して
おり、Fe34 とFe23 を主に含む層は通常の熱
延スケール除去酸洗でほぼ除去可能であること、SiO
2 を主に含む層は化成処理性にほとんど影響しないこ
と、および、Fe2 SiO4 を主に含む層は酸洗除去さ
れにくく、かつその厚さが5μm以上であると化成処理
性を著しく損ねることを見出した。Fe2 SiO 4 を含
む酸化膜の厚さを5μm未満と限定したのはこのためで
あり、薄いほど好ましく、この酸化膜はないことが好ま
しい。
As a result, SiO is formed on the base metal.2 Mainly includes
Layer, Fe2 SiOFour A layer mainly containing Fe3 OFour And Fe2 
O3 Is mainly laminated in this order to form an oxide film.
Cage, Fe3 OFour And Fe2 O3 Layer containing mainly is normal heat
Almost removable by pickling scale
2 The layer mainly containing is not affected by chemical conversion treatability.
And, and Fe2 SiOFour The layer mainly containing is removed by pickling
It is difficult to get rid of, and if the thickness is 5 μm or more, chemical conversion treatment
It was found that the property significantly deteriorates. Fe2 SiO Four Including
This is the reason why the thickness of the oxide film is limited to less than 5 μm.
Yes, thinner is preferable, and it is preferable that this oxide film is not present.
Good

【0040】なお、「Fe2 SiO4 を含む酸化膜の厚
さ」とは地鉄上のSiO2 を主に含む層とFe2 SiO
4 を主に含む層を合わせた厚さのことであり、また、熱
延コイルのトップ、ミドル、ボトムから各々3個採取し
た鋼片について測定し、それらを平均した値を該膜厚と
した。SiO2 を主に含む層とはSiO2 の含有量が5
0%以上であり、Fe2 SiO4 を主に含む層とはFe
2 SiO4 の含有量が50%以上であり、Fe34
Fe23 を主に含む層とはこれら2つの酸化物の含有
量の合計が50%以上であることと定義する。
The "thickness of the oxide film containing Fe 2 SiO 4 " means the layer containing mainly SiO 2 on the base metal and Fe 2 SiO 4.
It is the total thickness of the layers mainly containing 4, and was measured for each of three steel strips taken from the top, middle, and bottom of the hot rolled coil, and the averaged value was taken as the film thickness. . The content of SiO 2 is a layer containing SiO 2 mainly 5
A layer containing 0% or more and mainly containing Fe 2 SiO 4 is Fe.
The content of 2 SiO 4 is 50% or more, and the layer mainly containing Fe 3 O 4 and Fe 2 O 3 is defined as the total content of these two oxides being 50% or more.

【0041】一方、Fe2 SiO4 を含む酸化膜の厚さ
が薄ければ薄いほど化成処理性は向上するのでFe2
iO4 を含む酸化膜が存在しない状態(これを「Fe2
SiO4 を含む酸化膜の厚さが0(零)」と呼ぶ)も本
発明に含まれる。
On the other hand, since the thinner chemical conversion treatability if the thickness is thin oxide film improves containing Fe 2 SiO 4 Fe 2 S
A state in which an oxide film containing iO 4 does not exist (this is referred to as “Fe 2
The thickness of the oxide film containing SiO 4 is referred to as "0 (zero)") is also included in the present invention.

【0042】ベイニティック・フェライト相の面積率:
80〜100%。優れた伸びフランジ性を得るにはベイ
ニティック・フェライトを主相とする組織にすることが
必要であり、その面積率は実施例にて示すように80%
以上、好ましくは90%以上であることが望ましい。ま
た残部はベイナイト相、およびポリゴナル・フェライト
相を20%以下含有することができ、マルテンサイト相
が含まれることは極力避けることが望ましい。
Area ratio of bainitic ferrite phase:
80-100%. In order to obtain excellent stretch flangeability, it is necessary to make the structure mainly composed of bainitic ferrite, and the area ratio thereof is 80% as shown in the examples.
Or more, preferably 90% or more. Further, the balance can contain 20% or less of bainite phase and polygonal ferrite phase, and it is desirable to avoid inclusion of martensite phase as much as possible.

【0043】[0043]

【実施例】以下、本発明の実施例を比較例とともに説明
する。 (実施例1)表1に化学成分を示す鋼のスラブを複数製
造した。これらのスラブを、同じ鋼を2本一組として用
い、1250℃に再加熱後、粗圧延しエンドレス圧延に
供した。粗バーはコイルボックスと呼ばれる装置にて巻
き取られ、その後巻き戻され、先行粗バーの後端と後行
粗バーの先端を剪断調整し、付き合わされた剪断面同士
を入熱5.2kJ/cmのレーザーで接合し、仕上圧延機に
供給した。仕上圧延機を出た鋼板は冷却帯で冷却され、
巻取り機直前の剪断装置で粗バー接合部の前後を取り除
くように切断され2本の熱延コイルとして巻き取られ
た。粗バー巻き取り温度、仕上圧延完了温度、仕上圧延
後の冷却速度、および巻取り温度を表2に示す。
EXAMPLES Examples of the present invention will be described below together with comparative examples. (Example 1) A plurality of steel slabs having the chemical compositions shown in Table 1 were manufactured. These slabs were made of two sets of the same steel, reheated to 1250 ° C., rough-rolled, and subjected to endless rolling. The rough bar is wound up by a device called a coil box, then rewound, and the rear ends of the leading coarse bar and the leading ends of the trailing rough bars are shear-adjusted, and heat is applied to the abutted sheared surfaces at 5.2 kJ / It was joined with a cm laser and supplied to a finish rolling mill. The steel plate exiting the finishing rolling mill is cooled in the cooling zone,
It was cut by a shearing device immediately before the winder so as to remove the front and rear of the rough bar joint, and wound into two hot rolled coils. Table 2 shows the rough bar winding temperature, finish rolling completion temperature, cooling rate after finish rolling, and winding temperature.

【0044】このようにして得られた鋼板の強度、延
性、穴広げ性、化成処理性、および断面組織を調べた。
その結果を鋼と条件の組み合わせ毎に表3に示す。これ
らは同じ鋼の2本のコイルについて行った試験結果を平
均したものである。強度と延性は、圧延方向と平行に採
取したJIS5号試験片の引張試験により求めた。穴広
げ性は、150×150mmの鋼板の中央に開けた直径1
0mmの打ち抜き穴を60°の円錐パンチで押し広げ、板
厚貫通亀裂が生じた時点での穴径D(mm)を測定し、λ
=(D−10)/10で求めたλで評価した。また、化
成処理性は、鋼板表面に形成させることの出来たリン酸
塩皮膜量W(g/m2)で評価した。なお、化成処理は、
酸洗、脱脂、水洗した鋼板に懸濁液をスプレーし、余剰
分を絞りロールで除去して付着量を一定にした後、ドラ
イヤーで乾燥させる方法で行った。
The strength, ductility, hole expandability, chemical conversion treatability, and cross-sectional structure of the steel sheet thus obtained were examined.
The results are shown in Table 3 for each combination of steel and conditions. These are the averages of the test results performed on two coils of the same steel. The strength and ductility were determined by a tensile test of JIS No. 5 test pieces taken parallel to the rolling direction. The hole expandability is a diameter of 1 in the center of a 150 × 150 mm steel plate.
A 0 mm punched hole is spread with a 60 ° conical punch and the hole diameter D (mm) at the time when a through-thickness crack occurs is measured.
= (D-10) / 10 was evaluated by λ. The chemical conversion treatability was evaluated by the phosphate film amount W (g / m 2 ) that could be formed on the surface of the steel sheet. The chemical conversion treatment is
The suspension was sprayed on a steel sheet that had been pickled, degreased, and washed with water, and the excess was removed by a squeezing roll to make the adhered amount constant, and then dried by a dryer.

【0045】表3から明らかなように、本発明の方法を
用いれば、強度、延性、穴広げ性、および化成処理性に
優れた鋼板を得ることができる。
As is clear from Table 3, by using the method of the present invention, it is possible to obtain a steel sheet excellent in strength, ductility, hole expandability and chemical conversion treatability.

【0046】[0046]

【表1】 [Table 1]

【0047】[0047]

【表2】 [Table 2]

【0048】[0048]

【表3】 [Table 3]

【0049】(実施例2)質量%で、C:0.05%、
Si:0.51%、Mn:1.50%、P:0.021
%、S:0.0009%、N:0.0008%、Al:
0.03%、Ti:0.3%、Nb:0.03%、C
u:0.94%、Ni:0.51%、Ca:0.002
1%を含み、残部がFeおよび不可避的不純物であるス
ラブを複数製造した。これらのスラブを1250℃に再
加熱後、粗圧延してコイルボックスに供給した。その
際、直前までのデスケーリング装置を活用して粗バーを
冷却し、粗バー巻取り温度を980〜1200℃の範囲
で変化させた。巻取った粗バーを巻戻しつつ仕上圧延機
に通した。また比較のために、同様に冷却した後、コイ
ルボックスで巻き取ることなく仕上圧延機に通す圧延も
行った。仕上圧延終了温度は、850℃、冷却速度は5
0℃/秒、巻取り温度は450℃とした。
(Example 2) In mass%, C: 0.05%,
Si: 0.51%, Mn: 1.50%, P: 0.021
%, S: 0.0009%, N: 0.0008%, Al:
0.03%, Ti: 0.3%, Nb: 0.03%, C
u: 0.94%, Ni: 0.51%, Ca: 0.002
Multiple slabs containing 1% with the balance Fe and unavoidable impurities were produced. After reheating these slabs to 1250 ° C., they were roughly rolled and supplied to a coil box. At that time, the coarse bar was cooled by using the descaling device until immediately before, and the coarse bar winding temperature was changed in the range of 980 to 1200 ° C. The wound coarse bar was unwound and passed through a finish rolling mill. For comparison, after cooling in the same manner, rolling was also performed by passing through a finish rolling mill without winding in a coil box. Finishing rolling finish temperature is 850 ° C, cooling rate is 5
The coiling temperature was 0 ° C / sec and the coiling temperature was 450 ° C.

【0050】このようにして得られた鋼板の強度、延
性、穴広げ性、および化成処理性を調べた。評価方法は
実施例1と同じである。その結果、ベイニティック・フ
ェライト相の面積率は何れも80%以上であり、強度、
延性、および穴広げ性は粗バー巻取り温度の影響をほと
んど受けなかったが、化成処理性は強く影響を受けた。
その結果を、粗バー巻取り温度を横軸に取ってFe2
iO4 を含む酸化膜の厚さとともに図1に示す。図に示
すように、粗バー巻取り温度が1150℃を上回る場合
には粗バーの巻取り、巻戻しを行っても表面のFe2
iO4 を含む酸化膜の厚さが5μm以上であり、化成処
理性を改善する効果は認められない。
The steel sheet thus obtained was examined for strength, ductility, hole expandability, and chemical conversion treatability. The evaluation method is the same as in Example 1. As a result, the area ratio of the bainitic ferrite phase is 80% or more, the strength,
The ductility and hole expandability were hardly affected by the rough bar winding temperature, but the chemical conversion treatability was strongly affected.
The results, taking the rough bar coiling temperature on the horizontal axis Fe 2 S
It is shown in FIG. 1 together with the thickness of the oxide film containing iO 4 . As shown in the figure, when the winding temperature of the coarse bar exceeds 1150 ° C, the Fe 2 S on the surface is not removed even if the coarse bar is wound and unwound.
Since the oxide film containing iO 4 has a thickness of 5 μm or more, the effect of improving the chemical conversion treatability is not recognized.

【0051】[0051]

【発明の効果】本発明の方法によれば、化成処理性、ひ
いては耐食性と、伸びフランジ性に優れた高強度熱延鋼
板を得ることができる。
According to the method of the present invention, it is possible to obtain a high-strength hot-rolled steel sheet which is excellent in chemical conversion treatment property, eventually corrosion resistance, and stretch flangeability.

【図面の簡単な説明】[Brief description of drawings]

【図1】粗バーの巻取り温度と化成処理性、およびFe
2 SiO4 を含む酸化膜の厚さの関係を示すグラフであ
る。粗バーの巻取りを行わずに仕上圧延を行った場合に
は粗バーがコイルボックス位置を通過する際の温度でプ
ロットした。
FIG. 1 Winding temperature of coarse bar and chemical conversion treatability, and Fe
2 is a graph showing the relationship of the thickness of an oxide film containing 2 SiO 4 . When finish rolling was performed without winding the rough bar, the temperature was plotted as the temperature at which the rough bar passed the coil box position.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C22C 38/16 C22C 38/16 Fターム(参考) 4E002 AA07 AD04 BC05 BC07 BD07 CB01 4K037 EA01 EA05 EA09 EA13 EA15 EA18 EA20 EA23 EA25 EA27 EA28 EB05 EB07 EB08 EB09 FA02 FA03 FB10 FC03 FC04 FC07 FD04 FE01 GA02 HA02─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) C22C 38/16 C22C 38/16 F term (reference) 4E002 AA07 AD04 BC05 BC07 BD07 CB01 4K037 EA01 EA05 EA09 EA13 EA15 EA18 EA20 EA23 EA25 EA27 EA28 EB05 EB07 EB08 EB09 FA02 FA03 FB10 FC03 FC04 FC07 FD04 FE01 GA02 HA02

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 質量%にて、 C :0.03〜0.10%、 Si:0.05〜1.2%、 Mn:1.0〜2.0%、 P :0.05%以下、 S :0.01%以下、 N :0.005 %以下、 Al:0.01〜0.05%を含有し、更にTi,Nb
の一方あるいは双方を -0.05≦{Ti+(48/93)×Nb-(48/12)×C-(48/14)×N-(48/3
2)×S}≦0.2 となるように含有し、残部がFeおよび不可避不純物か
らなり、表面のFe2 SiO4 を含む酸化膜の厚さが5
μm未満であり、かつ断面組織におけるベイニティック
・フェライト相の面積率が80〜100%であることを
特徴とする耐食性と伸びフランジ性に優れた高強度熱延
鋼板。
1. In mass%, C: 0.03 to 0.10%, Si: 0.05 to 1.2%, Mn: 1.0 to 2.0%, P: 0.05% or less , S: 0.01% or less, N: 0.005% or less, Al: 0.01 to 0.05%, and Ti, Nb.
-0.05 ≤ (Ti + (48/93) x Nb- (48/12) x C- (48/14) x N- (48/3
2) × S} ≦ 0.2 is contained, the balance is Fe and unavoidable impurities, and the thickness of the oxide film containing Fe 2 SiO 4 on the surface is 5
A high-strength hot-rolled steel sheet excellent in corrosion resistance and stretch-flangeability, characterized in that the area ratio of bainitic ferrite phase in the cross-sectional structure is 80 to 100%.
【請求項2】 更に、質量%で、 Cu:0.5〜1.5%、 Ni:0.2〜0.7%を含有することを特徴とする請
求項1記載の耐食性と伸びフランジ性に優れた高強度熱
延鋼板。
2. Corrosion resistance and stretch flangeability according to claim 1, further comprising Cu: 0.5 to 1.5% and Ni: 0.2 to 0.7% in mass%. Excellent high strength hot rolled steel sheet.
【請求項3】 更に、質量%で、 Ca:0.0005〜0.0025%を含有することを
特徴とする請求項1または2に記載の耐食性と伸びフラ
ンジ性に優れた高強度熱延鋼板。
3. A high-strength hot-rolled steel sheet excellent in corrosion resistance and stretch-flangeability according to claim 1 or 2, further containing Ca: 0.0005 to 0.0025% by mass. .
【請求項4】 請求項1〜3の何れか1項に記載の鋼板
を製造する方法であって、請求項1〜3の何れか1項に
記載の化学成分を有する鋼材を1150〜1250℃に
加熱して粗圧延した後、1150℃以下の温度において
コイル状に巻取り、巻戻しつつAr3 点〜Ar3 点+1
00℃で仕上圧延を完了し、更に40℃/秒以上の平均
冷却速度で300〜500℃まで冷却し、300〜50
0℃で巻き取ることを特徴とする耐食性と伸びフランジ
性に優れた高強度熱延鋼板の製造方法。
4. A method for manufacturing the steel sheet according to any one of claims 1 to 3, wherein a steel material having the chemical composition according to any one of claims 1 to 3 is used at 1150 to 1250 ° C. After heating and rough rolling, it is wound into a coil at a temperature of 1150 ° C or lower, and while being rewound, Ar3 point to Ar3 point + 1
Finishing rolling is completed at 00 ° C., and further cooled to 300 to 500 ° C. at an average cooling rate of 40 ° C./sec or more, 300 to 50 ° C.
A method for producing a high-strength hot-rolled steel sheet excellent in corrosion resistance and stretch-flangeability, which comprises winding at 0 ° C.
JP2001352334A 2001-11-16 2001-11-16 High-strength hot-rolled steel sheet excellent in corrosion resistance and stretch flangeability, and method for producing the same Expired - Fee Related JP3728239B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001352334A JP3728239B2 (en) 2001-11-16 2001-11-16 High-strength hot-rolled steel sheet excellent in corrosion resistance and stretch flangeability, and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001352334A JP3728239B2 (en) 2001-11-16 2001-11-16 High-strength hot-rolled steel sheet excellent in corrosion resistance and stretch flangeability, and method for producing the same

Publications (2)

Publication Number Publication Date
JP2003155541A true JP2003155541A (en) 2003-05-30
JP3728239B2 JP3728239B2 (en) 2005-12-21

Family

ID=19164527

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001352334A Expired - Fee Related JP3728239B2 (en) 2001-11-16 2001-11-16 High-strength hot-rolled steel sheet excellent in corrosion resistance and stretch flangeability, and method for producing the same

Country Status (1)

Country Link
JP (1) JP3728239B2 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005045084A1 (en) * 2003-11-05 2005-05-19 Nippon Steel Corporation Hot-rolled steel plate excellent in chemical treatment characteristics and method for production thereof
JP2005248240A (en) * 2004-03-03 2005-09-15 Nippon Steel Corp High burring hot rolled steel sheet with bake hardenability, and its manufacturing method
WO2006103991A1 (en) * 2005-03-28 2006-10-05 Kabushiki Kaisha Kobe Seiko Sho High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof
KR100723200B1 (en) 2005-12-16 2007-05-29 주식회사 포스코 A method for manufacturing high strenth hot rolled steel sheet having excellent balance of elongation-stretch flangeability and stretch flangeability-fatigue property
WO2007122910A1 (en) * 2006-03-24 2007-11-01 Kabushiki Kaisha Kobe Seiko Sho High-strength hot rolled steel sheet having excellent composite moldability
KR20110097526A (en) * 2010-02-25 2011-08-31 현대제철 주식회사 High strength hot-rolled steel with excellent strength and ductility and method of manufacturing the high strength hot-rolled steel
WO2012036309A1 (en) * 2010-09-17 2012-03-22 Jfeスチール株式会社 High-strength hot-rolled steel sheet having excellent bending workability and method for producing same
JP2016041833A (en) * 2014-08-14 2016-03-31 Jfeスチール株式会社 Si-CONTAINING HOT ROLLED STEEL SHEET WITH EXCELLENT CHEMICAL CONVERSION TREATMENT PROPERTY AND MANUFACTURING METHOD OF THE SAME
WO2016095616A1 (en) * 2014-12-19 2016-06-23 宝山钢铁股份有限公司 Good fatigue- and crack growth-resistant steel plate and manufacturing method therefor
WO2020130417A3 (en) * 2018-12-19 2020-09-03 주식회사 포스코 Ultra-thick structural steel having excellent brittle crack initiation resistance, and manufacturing method therefor

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108342646B (en) * 2018-02-28 2019-12-27 马钢(集团)控股有限公司 Axle steel added with rare earth elements for railway vehicles and production method thereof

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005045084A1 (en) * 2003-11-05 2005-05-19 Nippon Steel Corporation Hot-rolled steel plate excellent in chemical treatment characteristics and method for production thereof
KR100819218B1 (en) * 2003-11-05 2008-04-02 신닛뽄세이테쯔 카부시키카이샤 Hot-rolled steel plate excellent in chemical treatment characteristics and method for production thereof
US7820099B2 (en) 2003-11-05 2010-10-26 Nippon Steel Corporation Hot rolled steel sheet excellent in chemical convertibility and method of production of the same
JP2005248240A (en) * 2004-03-03 2005-09-15 Nippon Steel Corp High burring hot rolled steel sheet with bake hardenability, and its manufacturing method
US8038809B2 (en) 2005-03-28 2011-10-18 Kobe Steel, Ltd. High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof
WO2006103991A1 (en) * 2005-03-28 2006-10-05 Kabushiki Kaisha Kobe Seiko Sho High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof
US8486205B2 (en) 2005-03-28 2013-07-16 Kobe Steel, Ltd. High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof
KR100723200B1 (en) 2005-12-16 2007-05-29 주식회사 포스코 A method for manufacturing high strenth hot rolled steel sheet having excellent balance of elongation-stretch flangeability and stretch flangeability-fatigue property
WO2007122910A1 (en) * 2006-03-24 2007-11-01 Kabushiki Kaisha Kobe Seiko Sho High-strength hot rolled steel sheet having excellent composite moldability
US8529829B2 (en) 2006-03-24 2013-09-10 Kobe Steel, Ltd. High-strength hot-rolled steel sheet with excellent combined formability
KR20110097526A (en) * 2010-02-25 2011-08-31 현대제철 주식회사 High strength hot-rolled steel with excellent strength and ductility and method of manufacturing the high strength hot-rolled steel
WO2012036309A1 (en) * 2010-09-17 2012-03-22 Jfeスチール株式会社 High-strength hot-rolled steel sheet having excellent bending workability and method for producing same
JP2012062558A (en) * 2010-09-17 2012-03-29 Jfe Steel Corp High-strength hot-rolled steel sheet having excellent bending workability and method for producing the same
US9200344B2 (en) 2010-09-17 2015-12-01 Jfe Steel Corporation High strength hot rolled steel sheet having excellent bendability and method for manufacturing the same
JP2016041833A (en) * 2014-08-14 2016-03-31 Jfeスチール株式会社 Si-CONTAINING HOT ROLLED STEEL SHEET WITH EXCELLENT CHEMICAL CONVERSION TREATMENT PROPERTY AND MANUFACTURING METHOD OF THE SAME
WO2016095616A1 (en) * 2014-12-19 2016-06-23 宝山钢铁股份有限公司 Good fatigue- and crack growth-resistant steel plate and manufacturing method therefor
US10920298B2 (en) 2014-12-19 2021-02-16 Baoshan Iron & Steel Co., Ltd. Good fatigue- and crack growth-resistant steel plate and manufacturing method therefor
WO2020130417A3 (en) * 2018-12-19 2020-09-03 주식회사 포스코 Ultra-thick structural steel having excellent brittle crack initiation resistance, and manufacturing method therefor

Also Published As

Publication number Publication date
JP3728239B2 (en) 2005-12-21

Similar Documents

Publication Publication Date Title
JP5283504B2 (en) Method for producing high-strength steel sheet having excellent ductility and steel sheet produced thereby
DK2924140T3 (en) Process for producing a flat high-strength steel product
JP5228062B2 (en) High strength thin steel sheet with excellent weldability and method for producing the same
JP3858146B2 (en) Manufacturing method of high-strength cold-rolled steel sheet and high-strength hot-dip galvanized steel sheet
JP2000109951A (en) High strength hot rolled steel sheet excellent in stretch-flanging property and its production
CN103249847B (en) Method for manufacturing high-strength cold-rolled/hot-rolled trip steel having a tensile strength of 590 mpa grade, superior workability, and low mechanical-property deviation
KR20200106195A (en) High-strength steel sheet and its manufacturing method
JP2001335890A (en) High tensile steel sheet excellent in bendability, and its production method
JP2003155541A (en) High strength hot rolled steel sheet having excellent corrosion resistance and stretch-flanging property, and production method therefor
JPH05140652A (en) Manufacture of low yield ratio cold rolled high tensile strength steel sheet excellent in corrosion resistance
JPH06240356A (en) Production of high strength hot rolled steel plate excellent in workability
JP4980253B2 (en) High-strength hot-rolled steel sheet with excellent strength-ductility balance and punchability and method for producing the same
JPH09118952A (en) Member made of high-strength hot rolled steel sheet having lower yield ratio
JP2001247918A (en) Method for producing high strength thin steel sheet
JP3954411B2 (en) Manufacturing method of high-strength hot-rolled steel sheet with excellent material uniformity and hole expandability
JPH09184045A (en) Extremely thin hot rolled steel sheet excellent in impact resistance and its production
JPH1081919A (en) Production of steel sheet for two-piece can, excellent in non-earing characteristic and surface roughing resistance
JP4781563B2 (en) High strength hot-rolled steel sheet with excellent bake hardenability and method for producing the same
JP3616472B2 (en) Method for producing high-strength hot-dip galvanized steel sheet with excellent workability
JPH1036939A (en) Hot rolled steel and production of hot rolled steel sheet
JPS6369923A (en) Production of cold rolled steel sheet for deep drawing having excellent baking hardenability
JPH11193419A (en) Production of galvannealed high strength cold rolled steel sheet excellent in formability
JP2003089847A (en) Hot rolled steel sheet having excellent stretch flanging workability, galvanized steel sheet, and their production method
JP2000087142A (en) Production of high tensile hot rolled steel strip having ferritic and bainitic structure
JP3678018B2 (en) Manufacturing method of high workability high tensile hot rolled steel sheet with excellent material uniformity

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20041130

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20041221

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20050927

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20050930

R151 Written notification of patent or utility model registration

Ref document number: 3728239

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091007

Year of fee payment: 4

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101007

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101007

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111007

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111007

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121007

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121007

Year of fee payment: 7

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131007

Year of fee payment: 8

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131007

Year of fee payment: 8

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131007

Year of fee payment: 8

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

LAPS Cancellation because of no payment of annual fees