JP2003071858A - Method for manufacturing composite optical element - Google Patents
Method for manufacturing composite optical elementInfo
- Publication number
- JP2003071858A JP2003071858A JP2001266105A JP2001266105A JP2003071858A JP 2003071858 A JP2003071858 A JP 2003071858A JP 2001266105 A JP2001266105 A JP 2001266105A JP 2001266105 A JP2001266105 A JP 2001266105A JP 2003071858 A JP2003071858 A JP 2003071858A
- Authority
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- Japan
- Prior art keywords
- mold
- optical element
- resin layer
- resin
- base material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、紫外線硬化型樹脂
を使用して製造される複合型光学素子の製造方法に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a composite optical element manufactured by using an ultraviolet curable resin.
【0002】[0002]
【従来の技術】複合型光学素子の製造は、所望の樹脂層
を形成するための光学面を有する金型及び基材のいずれ
かに紫外線硬化型樹脂を供給し、金型と基材とを相対的
に接近させて紫外線硬化型樹脂を押圧して広げることに
より金型と基材との間に所望の樹脂層を形成した後、紫
外線の照射により樹脂層を硬化し、硬化した樹脂層から
金型を剥離することにより行われている。2. Description of the Related Art A composite optical element is manufactured by supplying an ultraviolet curable resin to either a mold having an optical surface for forming a desired resin layer or a base material so that the mold and the base material are separated from each other. After forming a desired resin layer between the mold and the base material by pressing and spreading the UV curable resin relatively close to each other, the resin layer is cured by irradiation of ultraviolet rays, and the cured resin layer is removed. This is done by peeling the mold.
【0003】このような製造における紫外線照射により
樹脂層を硬化する場合、紫外線硬化型樹脂の硬化率は1
00%ではなく、100mW/cm2、40secの条
件下で70%程度である。硬化率が低い場合、耐熱試験
において、未硬化成分が析出することにより、樹脂面の
コート膜との密着性の低下、樹脂層の形状が変化する問
題が生じる。When the resin layer is cured by irradiation of ultraviolet rays in such production, the curing rate of the ultraviolet curable resin is 1
Instead of 00%, it is about 70% under the condition of 100 mW / cm 2 and 40 sec. When the curing rate is low, in the heat resistance test, precipitation of uncured components causes a problem that the adhesion of the resin surface to the coating film is lowered and the shape of the resin layer is changed.
【0004】この問題を解決するために、特開昭64−
35401号公報には、紫外線硬化型樹脂と熱硬化型樹
脂とを混合した樹脂を用い、紫外線照射の後に加熱する
方法が提案されている。To solve this problem, Japanese Patent Laid-Open No. 64-64-
Japanese Patent No. 35401 proposes a method in which a resin obtained by mixing an ultraviolet curable resin and a thermosetting resin is used, and heating is performed after ultraviolet irradiation.
【0005】[0005]
【発明が解決しようとする課題】しかしながら、紫外線
硬化型樹脂と熱硬化型樹脂とを混合した樹脂を用いる場
合には、紫外線の照射して仮硬化を行い、仮硬化の後
に、樹脂を金型と共に加熱して本硬化させる必要があ
る。このため、金型から剥離するまでの時間が長くな
り、量産性に劣ると共に、金型の熱容量を含めた分の熱
量が必要であり、大きな加熱エネルギーを要している。
また、特殊な樹脂を用いるため、材料費が高価になって
いる。However, when a resin in which an ultraviolet curable resin and a thermosetting resin are mixed is used, the resin is irradiated with ultraviolet rays for temporary curing, and after the temporary curing, the resin is molded into a mold. At the same time, it is necessary to heat the material to fully cure it. For this reason, it takes a long time to peel from the mold, which is inferior in mass productivity and requires a large amount of heat including the heat capacity of the mold, which requires a large amount of heating energy.
Further, since a special resin is used, the material cost is high.
【0006】本発明は、このような従来の問題点を考慮
してなされたものであり、紫外線硬化型樹脂及び熱硬化
型樹脂を用いることなく、硬化不足による耐熱性の低
下、コート膜の密着性低下を防止することができると共
に、量産性に優れた複合型光学素子の製造方法を提供す
ることを目的とする。The present invention has been made in consideration of such conventional problems, and the heat resistance is lowered due to insufficient curing and the adhesion of the coating film is eliminated without using an ultraviolet curable resin and a thermosetting resin. It is an object of the present invention to provide a method for manufacturing a composite-type optical element, which is capable of preventing the deterioration of properties and is excellent in mass productivity.
【0007】[0007]
【課題を解決するための手段】上記目的を達成するた
め、請求項1の発明の複合型光学素子の製造方法は、所
望の樹脂層を形成するための光学面を有する金型と基材
のいずれかに紫外線硬化型樹脂を供給し、金型と基材と
を相対的に接近させて紫外線硬化型樹脂を押し広げて金
型と基材との間に所望の樹脂層を形成した後、紫外線の
照射により樹脂層を硬化させ、硬化した樹脂層から金型
を剥離する複合型光学素子の製造方法において、光学素
子を金型から剥離した後、熱処理を施すことを特徴とす
る。In order to achieve the above object, the method for producing a composite optical element according to the invention of claim 1 is a method for producing a desired resin layer, comprising a mold and a substrate having an optical surface for forming a desired resin layer. After supplying the ultraviolet curable resin to any one, after forming a desired resin layer between the mold and the substrate by spreading the ultraviolet curable resin by making the mold and the base material relatively close to each other, In the method for producing a composite optical element in which a resin layer is cured by irradiation with ultraviolet rays, and a mold is peeled from the cured resin layer, a heat treatment is performed after the optical element is peeled from the mold.
【0008】この発明では、樹脂層が硬化した光学素子
を金型から剥離した後、バッチ処理により熱処理して未
硬化成分を析出させるため、硬化不足による耐熱性の低
下、コート膜の密着性低下を防止することができ、しか
も大きな熱量が不要で、量産性に優れたものとなる。In this invention, after the optical element having the resin layer cured is peeled from the mold, the uncured component is deposited by heat treatment by batch processing, so that the heat resistance is lowered due to insufficient curing and the adhesion of the coating film is reduced. Can be prevented, and a large amount of heat is not required, resulting in excellent mass productivity.
【0009】請求項2の発明は、請求項1記載の複合型
光学素子の製造方法であって、前記熱処理の前に、紫外
線を光学素子に再度照射することを特徴とする。According to a second aspect of the present invention, there is provided the method for manufacturing the composite optical element according to the first aspect, wherein the optical element is irradiated again with ultraviolet rays before the heat treatment.
【0010】このように熱処理の前に、紫外線を再照射
することにより、紫外線硬化型樹脂の硬化率を高めるこ
とができる。By thus reirradiating with ultraviolet rays before the heat treatment, the curing rate of the ultraviolet curable resin can be increased.
【0011】請求項3の発明は、請求項1または2記載
の複合型光学素子の製造方法であって、前記熱処理は、
紫外線硬化型樹脂のガラス転移点未満の温度で行うこと
を特徴とする。A third aspect of the present invention is the method for manufacturing the composite optical element according to the first or second aspect, wherein the heat treatment is
It is characterized in that it is carried out at a temperature lower than the glass transition point of the ultraviolet curable resin.
【0012】ガラス転移点未満の温度であっても、未硬
化成分を析出させることができるため、小さな熱量で処
理することが可能となる。Even at a temperature below the glass transition point, the uncured component can be deposited, so that the treatment can be performed with a small amount of heat.
【0013】[0013]
【発明の実施の形態】(実施の形態1)図1〜図4は本
発明の実施の形態1を工程順に示しており、図1に示す
ように、金型1及び基材2を備えて複合型光学素子の成
形を行う。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS (Embodiment 1) FIGS. 1 to 4 show Embodiment 1 of the present invention in the order of steps. As shown in FIG. 1, a mold 1 and a base material 2 are provided. The composite type optical element is molded.
【0014】金型1は湾曲凸状の光学面1aを有する直
径18mmの円柱状に成形されている。基材2はガラス
からなり、直径20mm、曲率半径50mmの凹面から
なる成形面2aが金型1との対向面に形成されている。
反対側の非成形面2bは、直径が22mm、曲率半径1
00mmの凸面となっている。基材2はヤトイ3上に把
持部材4によって固定されている。また、金型1の中心
軸と基材2の中心軸は10μm以内の距離で一致してお
り、金型1は上下動自在に保持されている。The mold 1 is formed into a cylindrical shape having a curved convex optical surface 1a and a diameter of 18 mm. The base material 2 is made of glass, and a molding surface 2a, which is a concave surface having a diameter of 20 mm and a radius of curvature of 50 mm, is formed on the surface facing the mold 1.
The non-molding surface 2b on the opposite side has a diameter of 22 mm and a radius of curvature of 1
It has a convex surface of 00 mm. The base material 2 is fixed on the toy 3 by a gripping member 4. Further, the center axis of the mold 1 and the center axis of the base material 2 coincide with each other within a distance of 10 μm, and the mold 1 is held so as to be vertically movable.
【0015】複合型光学素子の成形は、まず、基材2の
成形面2a上に樹脂層5を形成するための樹脂6を供給
する。樹脂6の材質としては紫外線硬化型樹脂が使用さ
れる。紫外線硬化型樹脂としては、例えば、ガラス転移
点(Tg点)が( )℃の( )あるいは
Tg点が( )℃の( )を選択することが
できる。In the molding of the composite type optical element, first, the resin 6 for forming the resin layer 5 on the molding surface 2a of the base material 2 is supplied. An ultraviolet curable resin is used as the material of the resin 6. As the ultraviolet curable resin, for example, () having a glass transition point (Tg point) of () ° C. or () having a Tg point of () ° C. can be selected.
【0016】次に、金型1を下降する。この下降によっ
て、まず金型1の光学面1aと樹脂6とが接触する。そ
して、さらに金型1の下降を継続すると、基材2上の樹
脂6は図2に示すように、金型1と基材2に挟まれて押
し広げられる。Next, the mold 1 is lowered. By this descending, first, the optical surface 1a of the mold 1 and the resin 6 come into contact with each other. Then, when the mold 1 is further continued to descend, the resin 6 on the base material 2 is sandwiched between the mold 1 and the base material 2 and spread out, as shown in FIG.
【0017】所定の位置まで金型1を降下した後、樹脂
6を硬化することにより金型1、樹脂層5、基材2の密
着体が形成される。硬化は基材2側から紫外線を照射す
ることにより行う。照射する紫外線照度は80mW/c
m2、時間は40secである。After the mold 1 is lowered to a predetermined position, the resin 6 is cured to form a close contact body of the mold 1, the resin layer 5 and the substrate 2. Curing is performed by irradiating ultraviolet rays from the base material 2 side. The irradiation intensity of ultraviolet rays is 80 mW / c
m 2 , time is 40 sec.
【0018】樹脂層5の硬化後は図3に示すように、把
持部材4を開放し、密着体を上昇させる。この上昇によ
って、予め基材2の上方に設けられていた剥離用部材7
が基材2の外周面と接触し、樹脂層5と金型1とが剥離
する。金型1と樹脂層5とが剥離した後、図4に示すよ
うに把持部材4により基材2を再び保持し、金型1を高
速で上昇させる。After the resin layer 5 is cured, as shown in FIG. 3, the gripping member 4 is opened to raise the contact member. Due to this rise, the peeling member 7 previously provided above the substrate 2
Comes into contact with the outer peripheral surface of the substrate 2, and the resin layer 5 and the mold 1 are separated. After the mold 1 and the resin layer 5 are separated from each other, the base member 2 is held again by the gripping member 4 as shown in FIG. 4, and the mold 1 is elevated at a high speed.
【0019】このように得られた基材2と樹脂層5の密
着体は100個を1ロットとして、所定のパレットに集
められる。集められた密着体を加熱炉に入れ、紫外線硬
化型樹脂のTg点以下の温度である100℃で4hr加
熱する。加熱されることにより、樹脂に含まれる未硬化
成分は析出、揮発する。また、樹脂の種類によっては液
体成分が残留することがあるが、この場合はIPA等の
アルコールによって洗浄することにより除去することが
できる。100 pieces of the adhered body of the base material 2 and the resin layer 5 thus obtained are collected in a predetermined pallet with 100 pieces as one lot. The collected adhered bodies are placed in a heating furnace and heated at 100 ° C., which is a temperature below the Tg point of the ultraviolet curable resin, for 4 hours. By being heated, the uncured component contained in the resin is precipitated and volatilized. Further, depending on the type of resin, a liquid component may remain, but in this case, it can be removed by washing with alcohol such as IPA.
【0020】この実施の形態で得られた複合型光学素子
は、−30℃〜90℃の耐熱試験において、樹脂層5の
形状変化は0.5μm以下であり、しかもコート膜との
密着性にも優れていた。In the composite optical element obtained in this embodiment, the shape change of the resin layer 5 was 0.5 μm or less in the heat resistance test at −30 ° C. to 90 ° C., and moreover, the adhesiveness to the coat film was high. Was also excellent.
【0021】(実施の形態2)図5〜図8は本発明の実
施の形態2を工程順に示している。図5に示すように、
金型11は連続した凹凸状の光学面11aを有する直径
20mmの円柱状となっている。基材12はガラスから
なり、直径22mm、曲率半径100mmの凹面からな
る成形面12aを金型11側に有し、非成形面12bの
曲率半径200mm、直径22mmの凹面からなる被成
形面12bを反対側に有している。基材12はヤトイ1
3上に把持部材14によって固定されている。金型11
の中心軸と基材12の中心軸は10μm以内の距離で一
致しており、金型11は上下動自在に保持されている。(Embodiment 2) FIGS. 5 to 8 show Embodiment 2 of the present invention in the order of steps. As shown in FIG.
The mold 11 is in the form of a cylinder having a diameter of 20 mm and having a continuous concave-convex optical surface 11a. The base material 12 is made of glass and has a molding surface 12a having a concave surface with a diameter of 22 mm and a radius of curvature of 100 mm on the mold 11 side, and a non-molding surface 12b having a curvature radius of 200 mm and a concave surface 12b having a diameter of 22 mm. Have on the other side. Substrate 12 is a toy 1
It is fixed on the upper part 3 by a gripping member 14. Mold 11
And the central axis of the base material 12 coincide with each other within a distance of 10 μm, and the mold 11 is held so as to be vertically movable.
【0022】複合型光学素子の成形は、まず、基材12
に樹脂層15を形成するための樹脂16を供給する。樹
脂16としては紫外線硬化型樹脂が使用される。紫外線
硬化型樹脂としては、例えば、ガラス転移点(Tg点)
が( )℃の()あるいはTg点が( )℃の(
)を選択することができる。In the molding of the composite type optical element, first, the base material 12 is formed.
Then, a resin 16 for forming the resin layer 15 is supplied. An ultraviolet curable resin is used as the resin 16. Examples of the ultraviolet curable resin include a glass transition point (Tg point)
Is () ° C () or Tg point is () ° C (
) Can be selected.
【0023】次に、金型11を下降する。この下降によ
って、まず金型11の光学面11aと樹脂16とが接触
する。そして、さらに金型11の下降を継続すると、基
材12上の樹脂16は図6に示すように、金型11と基
材12に挟まれて押し広げられる。Next, the mold 11 is lowered. By this descending, first, the optical surface 11a of the mold 11 and the resin 16 come into contact with each other. Then, when the die 11 is further continued to descend, the resin 16 on the base material 12 is sandwiched between the die 11 and the base material 12 and spread out, as shown in FIG.
【0024】所定の位置まで金型11を降下した後、樹
脂16を硬化することにより金型11、樹脂層15、基
材12の密着体が形成される。硬化は基材2側から紫外
線を照射することにより行う。照射する紫外線照度は1
50mW/cm2、時間は10secである。After the mold 11 is lowered to a predetermined position, the resin 16 is cured to form a close contact body of the mold 11, the resin layer 15 and the base material 12. Curing is performed by irradiating ultraviolet rays from the base material 2 side. The illuminance of ultraviolet light is 1
It is 50 mW / cm 2 and the time is 10 sec.
【0025】樹脂層15の硬化後は図7に示すように、
把持部材14を開放し、密着体を上昇させる。この上昇
によって、予め基材12の上方に設けられていた剥離用
部材17が基材12の外周面と接触し、樹脂層15と金
型11とが剥離する。金型11と樹脂層15とが剥離し
た後、図8に示すように把持部材14により基材12を
再び保持し、金型11を高速で上昇させる。After the resin layer 15 is cured, as shown in FIG.
The gripping member 14 is opened to raise the contact body. Due to this rise, the peeling member 17 previously provided above the base material 12 comes into contact with the outer peripheral surface of the base material 12, and the resin layer 15 and the mold 11 are separated. After the mold 11 and the resin layer 15 are separated from each other, the base member 12 is held again by the gripping member 14 as shown in FIG. 8, and the mold 11 is elevated at a high speed.
【0026】このように得られた基材12と樹脂層15
の密着体は100個を1ロットとして、所定のパレット
に集められる。集められた密着体を紫外線炉に入れ、紫
外線が照射される。照射される紫外線照度は100mW
/cm2、時間は10minである。紫外線照射によ
り、樹脂の硬化率が90%まで上昇する。The base material 12 and the resin layer 15 thus obtained
One hundred lots of the adherents of 1 are collected in a predetermined pallet. The collected adhered bodies are put in an ultraviolet oven and irradiated with ultraviolet rays. Irradiated UV illuminance is 100mW
/ Cm 2 , and the time is 10 min. The ultraviolet curing increases the curing rate of the resin to 90%.
【0027】紫外線を照射した後、密着体を加熱炉に入
れ、紫外線硬化型樹脂のTg点以下の温度である100
℃で2hr加熱する。加熱されることにより、樹脂に含
まれる未硬化成分は析出、揮発する。After irradiating with ultraviolet rays, the adhered body was put in a heating furnace and the temperature was 100 or lower, which was a temperature below the Tg point of the ultraviolet curable resin.
Heat for 2 hours at ° C. By being heated, the uncured component contained in the resin is precipitated and volatilized.
【0028】この実施の形態で得られた複合型光学素子
は、−30℃〜90℃の耐熱試験において、樹脂層5の
形状変化がなく、しかもコート膜との密着性にも優れて
いた。The composite optical element obtained in this embodiment had no change in the shape of the resin layer 5 in the heat resistance test at -30 ° C. to 90 ° C. and was also excellent in adhesion to the coating film.
【0029】本発明は、以上の実施の形態に限定される
ことなく種々変形が可能である。例えば、紫外線硬化型
樹脂を金型の光学面に供給し、金型または基材を相対的
に接近させて押し広げても良い。The present invention can be variously modified without being limited to the above embodiments. For example, an ultraviolet curable resin may be supplied to the optical surface of the mold, and the mold or the base material may be brought relatively close to each other and spread.
【0030】[0030]
【発明の効果】請求項1の発明のよれば、樹脂層が硬化
した光学素子を金型から剥離した後、バッチ処理により
熱処理して未硬化成分を析出させるため、硬化不足によ
る耐熱性の低下、コート膜の密着性低下を防止すること
ができ、しかも大きな熱量が不要で、量産性に優れたも
のとなる。According to the first aspect of the invention, the optical element having the resin layer cured is peeled from the mold and then heat-treated by batch treatment to precipitate the uncured component, so that the heat resistance is deteriorated due to insufficient curing. In addition, it is possible to prevent the adhesiveness of the coat film from being lowered, and further, a large amount of heat is not required, which is excellent in mass productivity.
【0031】請求項2の発明によれば、請求項1の発明
の硬化を有するのに加えて、紫外線硬化型樹脂の硬化率
を高めることができる。According to the invention of claim 2, in addition to having the curing of the invention of claim 1, the curing rate of the ultraviolet curable resin can be increased.
【0032】請求項3の発明によれば、請求項1及び2
の発明の効果を有するのに加えて、小さな熱量で処理す
ることが可能となる。According to the invention of claim 3, claims 1 and 2
In addition to having the effects of the invention described above, it becomes possible to process with a small amount of heat.
【図1】実施の形態1における樹脂供給工程の断面図で
ある。FIG. 1 is a cross-sectional view of a resin supply process according to the first embodiment.
【図2】実施の形態1における樹脂の硬化工程の断面図
である。FIG. 2 is a cross-sectional view of a resin curing step in the first embodiment.
【図3】実施の形態1における密着体上昇工程の断面図
である。FIG. 3 is a cross-sectional view of a contact body raising step in the first embodiment.
【図4】実施の形態1における離型工程の断面図であ
る。FIG. 4 is a cross-sectional view of a mold release process in the first embodiment.
【図5】実施の形態2における樹脂供給工程の断面図で
ある。FIG. 5 is a cross-sectional view of a resin supply step in the second embodiment.
【図6】実施の形態2における樹脂の硬化工程の断面図
である。FIG. 6 is a cross-sectional view of a resin curing step in the second embodiment.
【図7】実施の形態2における密着体上昇工程の断面図
である。FIG. 7 is a cross-sectional view of a contact body raising step in the second embodiment.
【図8】実施の形態2における離型工程の断面図であ
る。FIG. 8 is a cross-sectional view of a mold releasing process according to the second embodiment.
1,11 金型 1a,11a 光学面 2,12 基材 5,15 樹脂層 6,16 紫外線硬化型樹脂 1,11 mold 1a, 11a Optical surface 2,12 base material 5,15 Resin layer 6,16 UV curable resin
フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) B29L 11:00 B29L 11:00 Continuation of front page (51) Int.Cl. 7 Identification code FI theme code (reference) B29L 11:00 B29L 11:00
Claims (3)
有する金型と基材のいずれかに紫外線硬化型樹脂を供給
し、金型と基材とを相対的に接近させて紫外線硬化型樹
脂を押し広げて金型と基材との間に所望の樹脂層を形成
した後、紫外線の照射により樹脂層を硬化させ、硬化し
た樹脂層から金型を剥離する複合型光学素子の製造方法
において、光学素子を金型から剥離した後、熱処理を施
すことを特徴とする複合型光学素子の製造方法。1. A UV-curable resin is supplied to either a mold having an optical surface for forming a desired resin layer or a base material, and the mold and the base material are brought relatively close to each other to be UV-cured. Manufacture of a composite optical element in which a mold resin is spread to form a desired resin layer between a mold and a base material, the resin layer is cured by irradiation of ultraviolet rays, and the mold is separated from the cured resin layer. In the method, a method for producing a composite optical element is characterized in that after the optical element is separated from the mold, heat treatment is performed.
再度照射することを特徴とする請求項1記載の複合型光
学素子の製造方法。2. The method for producing a composite optical element according to claim 1, wherein the optical element is irradiated again with ultraviolet rays before the heat treatment.
ス転移点未満の温度で行うことを特徴とする請求項1ま
たは2記載の複合型光学素子の製造方法。3. The method for producing a composite optical element according to claim 1, wherein the heat treatment is performed at a temperature lower than the glass transition point of the ultraviolet curable resin.
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JP2001266105A JP2003071858A (en) | 2001-09-03 | 2001-09-03 | Method for manufacturing composite optical element |
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JP2003071858A true JP2003071858A (en) | 2003-03-12 |
JP2003071858A5 JP2003071858A5 (en) | 2008-10-16 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102922755A (en) * | 2011-08-08 | 2013-02-13 | 上海聚恒太阳能有限公司 | Manufacturing method of Fresnel condenser lens |
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JPS63158501A (en) * | 1986-12-23 | 1988-07-01 | Dainippon Ink & Chem Inc | Production of substrate for optical disc |
JPH0354501A (en) * | 1989-07-24 | 1991-03-08 | Mitsubishi Rayon Co Ltd | Production of modified fly eye lens |
JPH0971439A (en) * | 1995-09-06 | 1997-03-18 | Ricoh Co Ltd | Aspheric optical element and its production |
WO2001007938A1 (en) * | 1999-07-23 | 2001-02-01 | Nikon Corporation | Resin-bond type optical element, production method therefor and optical article |
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2001
- 2001-09-03 JP JP2001266105A patent/JP2003071858A/en active Pending
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JPS63158501A (en) * | 1986-12-23 | 1988-07-01 | Dainippon Ink & Chem Inc | Production of substrate for optical disc |
JPH0354501A (en) * | 1989-07-24 | 1991-03-08 | Mitsubishi Rayon Co Ltd | Production of modified fly eye lens |
JPH0971439A (en) * | 1995-09-06 | 1997-03-18 | Ricoh Co Ltd | Aspheric optical element and its production |
WO2001007938A1 (en) * | 1999-07-23 | 2001-02-01 | Nikon Corporation | Resin-bond type optical element, production method therefor and optical article |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102922755A (en) * | 2011-08-08 | 2013-02-13 | 上海聚恒太阳能有限公司 | Manufacturing method of Fresnel condenser lens |
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