JP2003040745A - Hair-dyeing composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a hair-dyeing composition which has an excellent hair- dyeing property, an excellent level dyeing property and an excellent color- retaining property, moderates the damages of the hair, and gives sufficiently excellent touch such as hand touch after used. SOLUTION: This hair-dyeing composition is characterized by comprising (A) sea mud and (B) a vegetable protein hydrolysate and/or a fish-originated water-soluble collagen.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a hair dyeing composition for dyeing or bleaching hair, and more specifically, it has excellent hair dyeing properties, level dyeing properties, and color retention properties, and further reduces damage to hair. The present invention relates to a composition for hair dyeing, which is sufficiently excellent in feeling after use such as touch.

[0002]

2. Description of the Related Art Conventionally, as a hair dye, a two-pack type oxidative hair dye comprising a first agent containing an oxidative dye intermediate and a second agent containing an oxidant has been widely used. This hair dye penetrates the colorless low molecular weight oxidation dye intermediate into the hair,
The pigment is generated and dyed by performing oxidative polymerization in the hair. These oxidative hair dyes can dye hair in various color tones as desired. Further, the hair dye without the oxidation dye intermediate is used as a decolorizing agent.

[0003]

However, the conventional oxidative hair dyes are excellent in hair dyeing property, level dyeing property, and color retention, but are sufficiently satisfactory in feeling after use such as damage to hair or touch. Was not obtained. That is, an object of the present invention is to provide a composition for hair dyeing, which is excellent in hair dyeing property, level dyeing property, and long-lasting property, and further softens damage to hair and is sufficiently excellent in touch after use such as touch. is there.

[0004]

[Means for Solving the Problems] The inventors of the present invention have conducted intensive studies in view of the above circumstances, and as a result, blended sea mud and vegetable protein hydrolyzate and / or fish-derived water-soluble collagen into a hair dyeing composition. According to the present invention, it has been found that a composition for hair dyeing which is excellent in hair dyeing property, level dyeing property, and color retention, further softens damage to hair, and is sufficiently excellent in touch after use such as touch is obtained. Has been completed. That is, the present invention is
Components (A) and (B); (A) Sea mud (B) A vegetable protein hydrolyzate and / or a fish-derived water-soluble collagen, which is a composition for hair dyeing.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below. In the present invention, the hair dye composition includes a hair dye, a hair dye and a decolorizing agent.

The sea mud as the component (A) to be blended in the present invention is a natural inorganic substance of marine origin, and is a corrosive mud mainly composed of sulfur-containing aluminum silicate containing sulfur and containing various minerals. The mined sea mud can be used after being subjected to treatments such as drying and crushing, if necessary. As a commercially available product, MIRONECTON (manufactured by Dainippon Kasei)
Etc.

[0007] The mironectone (trade name) contains various mineral components in a well-balanced manner, so that it has a mineral component replenishing action and can impart excellent conditioning effects to hair.

The content of sea mud is not particularly limited, but is preferably 0.1 to 5 mass%. In this range,
It has an extremely excellent effect on the feel after use.

On the other hand, the vegetable protein hydrolyzate of the component (B) used in the present invention is, for example, hydrolyzed wheat protein solution, hydrolyzed wheat powder, soy protein hydrolyzate, soy protein hydrolyzate (2). , Water-soluble collagen (1), water-soluble collagen (2), water-soluble collagen (3) and the like can be used. In addition, these protein hydrolysates are "mixed component standard by cosmetic variety" (supervised by the Ministry of Health and Welfare Pharmacy Bureau Examination Division, Yakuji Nippo Ltd. 1997 issue), "Supplementary ingredient standard by makeup variety II" (Ministry of Health and Welfare Pharmacy Bureau Examination Division) Supervised, published by Yakuji Nipposha 11th year).

The amount of protein hydrolyzate is not particularly limited, but is preferably 0.01 to 3% by mass. In this range, it has an extremely excellent effect on the feel after use.

The components incorporated in the first agent will be described below.

Oxidative Dye When the hair dye composition of the present invention is a so-called hair dye,
It usually contains an oxidative dye. The oxidizing dye is not particularly limited, and known dyes can be widely used.
More specifically, the following can be exemplified.

5-aminoorthocresol, 5-aminoorthocresol sulfate, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 1-amino-4-methylaminoanthraquinone, 3,3'-imino Diphenol, 2,4-diaminophenol hydrochloride, toluene-2,5-diamine hydrochloride, nitroparaphenylenediamine hydrochloride, paraphenylenediamine hydrochloride, N-phenylparaphenylenediamine hydrochloride, metaphenylenediamine hydrochloride, orthoaminophenol, catechol, Acetic acid N
-Phenylparaphenylenediamine, 1,4-diaminoanthraquinone, 2,6-diaminopyridine, sulfuric acid 2,
6-diaminopyridine, 1,5-dihydroxynaphthalene, diphenylamine, toluene-2,5-diamine,
Toluene-3,4-diamine, α-naphthol, nitroparaphenylenediamine, paraaminophenylsulfamic acid, paraaminophenol, paranitroorthophenylenediamine, paraphenylenediamine, paramethylaminophenol, picramic acid, sodium picramate, picric acid, 2-hydroxy-5-nitro-
Sodium 2 ', 4'-diaminoazobenzene-5-sulfonate, hydroquinone, pyrogallol, N-phenylparaphenylenediamine, phloroglucin, hematein, gallic acid, metaaminophenol, metaphenylenediamine, sulfuric acid 2-amino-5-nitrophenol , Orthoaminophenol sulfate, orthochloroparaphenylenediamine sulfate, 4,4′-diaminodiphenylamine sulfate, toluene-2,5-diamine sulfate, nitroparaphenylenediamine sulfate, paraaminophenol sulfate, paranitroorthophenylenediamine sulfate, para sulfate Nitrometaphenylenediamine, paraphenylenediamine sulfate, paramethylaminophenol sulfate, metaaminophenol sulfate, metaphenylenediamine sulfate, etc.

The above dyes may be used alone or in admixture of two or more. The blending amount of the oxidation dye is appropriately selected depending on the type of the oxidation dye, the desired degree of dyeing, etc., and can be blended in any amount.

Alkaline agent In the present invention, the alkaline agent for making the first agent alkaline is not particularly limited, and known ones may be widely used.

Specifically, for example, ammonia, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-1-propanol,
2-amino-2-methyl-1,3-propanediol,
Examples include amine-based alkaline agents such as tetrakis (2-hydroxyisopropyl) ethylenediamine. You may use the said alkaline agent 1 type or in mixture of 2 or more types.

The components contained in the second agent will be described below.

Oxidizing agent The oxidizing agent to be added to the second agent is not particularly limited, and widely known agents can be used. In particular,
Examples thereof include hydrogen peroxide and peroxides, which release oxygen by contacting with water.

More specifically, hydrogen peroxide (usually 10
Used as an aqueous solution of ˜35% by mass. ), Sodium perborate, ammonium perborate, potassium perborate,
Examples thereof include sodium percarbonate and sodium bromate (these are added as an aqueous solution or a stock solution). You may use the said oxidizing agent 1 type or in mixture of 2 or more types.

The above components are essential components when the hair dye composition of the present invention is used as a hair dye. However, in addition to the above components, the following components may be added, if necessary. good.
Hereinafter, these components will be described.

The presence of metal ions in the hair-sealant composition of the metal sequestering agent accelerates the color development of the oxidative dye contained in the first part of the hair-dyeing agent, or a part of the surfactant contained in the composition. Since it produces soap and insoluble substance, it is possible to add a sequestering agent to prevent this.

The metal sequestering agent is not particularly limited and widely known ones can be used. Specific examples include edetic acid, disodium edetate, tetrasodium edetate, sodium citrate, sodium metaphosphate, and sodium polyphosphate. These sequestering agents may be used alone or in combination of two or more.

Oil agent An oil agent may be added to the hair dye composition. The oil agent is not particularly limited, and widely known oil agents conventionally used in hair dye compositions can be widely used. Specifically, for example, olive oil, sesame oil, castor oil, coconut oil, jojoba oil, liquid paraffin, petrolatum, oleyl alcohol, oleic acid, hexyldecanol, isopropyl myristate, cetanol, stearyl alcohol, behenyl alcohol, cetostearyl alcohol and the like. To be Also, highly polymerized methyl polysiloxane,
Dimethyl siloxane, methyl (polyoxyethylene) siloxane copolymer, methylphenyl polysiloxane, amino-modified silicone and the like can also be used.

One or more of the above oil agents may be blended, and the blending amount of the oil agent is not particularly limited as long as it is a blending amount which is usually blended.

Surfactant A surfactant may be added to the hair dye composition.
The surfactant is not particularly limited and widely known ones can be used. Specific examples include nonionic surfactants, anionic surfactants, amphoteric surfactants, and cationic surfactants. More specifically, it is as follows.

Nonionic surfactant Polyoxyethylene isostearyl ether, polyoxyethylene isocetyl ether, polyoxyethylene octyldodecyl ether, polyoxyethylene oleyl ether, polyoxyethylene oleyl cetyl ether, polyoxyethylene stearyl ether, polyoxy Ethylene cetyl ether, polyoxyethylene cetostearyl ether, polyoxyethylene tridecyl ether, polyoxybutyl ether, polyoxyethylene behenyl ether, polyoxyethylene myristyl ether, polyoxyethylene lauryl ether, polyoxyethylene octylphenyl ether, polyoxyethylene Examples thereof include dinonyl phenyl ether and polyoxyethylene nonyl phenyl ether.

Anionic surfactant N-acyl-L-glutamate diethanolamine, N
-Acyl-L-glutamic acid triethanolamine, N
-Sodium acyl-L-glutamate, sodium isethionate, disodium undecylenoylamide ethyl sulfosuccinate, sodium octylphenoxydiethoxyethyl sulfonate, oleoyl sarcosine, sodium oleoylmethyl taurine, carboxylated polyoxyethylene tridecyl ether , L-glutamic acid triethanolamine hardened tallow fatty acid amide, L-glutamate hardened tallow fatty acid amide, L-glutamic acid sodium coconut oil fatty acid amide, hardened coconut oil fatty acid sodium glyceryl sulfate, diundecylenoyl amide ethyl sulfosuccinate, N- Stearoyl-
L-Glutamate sodium, Stearoyl-L-glutamate disodium salt, Stearoylmethyl taurine sodium salt, Dioctyl sodium sulfosuccinate, Disodium polyoxyethylene lauroyl ethanolamide ester sulfosuccinate, Disodium lauryl sulfosuccinate, Diethanolamine cetylsulfate, Sodium cetyl sulfate, Set Sodium stearyl sulphate, sodium dextran sulphate, sodium tetradecene sulphonate, triethanolamine dodecylbenzene sulphonate, triethanolamine tridecyl sulphate, ditriethanolamine N-palmitoyl aspartate, sodium polyoxyethylene undecyl ether sulphate, polyoxyethylene octyl Sodium phenyl ether sulfate, polyoxye Ammonium renoleyl ether sulfate, disodium lauryl polyoxyethylene sulfosuccinate, sodium polyoxyethylene nonylphenyl ether sulfate, sodium polyoxyethylene pentadecyl ether sulfate, triethanolamine polyoxyethylene myristyl ether sulfate, sodium polyoxyethylene myristyl ether sulfate, Polyoxyethylene lauryl ether sulfate triethanolamine, polyoxyethylene lauryl ether sulfate sodium, myristyl sulfate diethanolamine, sodium myristyl sulfate, N-myristoyl-L-glutamate sodium,
Sodium myristoylmethylaminoacetate, Sodium myristoylmethyl taurine, Potassium coconut oil fatty acid,
Coconut oil fatty acid / beef tallow fatty acid-L-glutamic acid sodium amide, N-coconut oil fatty acid-L-glutamic acid triethanolamine, N-coconut oil fatty acid-L-glutamic acid sodium salt, coconut oil fatty acid sarcosine, coconut oil fatty acid sarcosine triethanolamine, Palm oil fatty acid sarcosine sodium, Palm oil fatty acid triethanolamine, Palm oil fatty acid sodium, Palm oil fatty acid methyl alanine sodium, Palm oil fatty acid methyl taurine potassium, Palm oil fatty acid methyl taurine sodium, Sodium lauryl aminodipropionate, Sodium lauryl sulfoacetate , Sodium lauryl benzene sulfonate, lauryl sulfate, ammonium lauryl sulfate, ethanolamine lauryl sulfate potassium lauryl sulfate, diethanolamine lauryl sulfate, LA Lil sulfate triethanolamine, sodium lauryl sulfate, magnesium lauryl sulfate, lauroyl -L- glutamic acid triethanolamine, N
-Sodium lauroyl-L-glutamate, lauroyl sarcosine, potassium lauroyl sarcosine, sodium lauroyl sarcosine, sodium lauroyl methyl β-alanine solution, sodium lauroyl methyl taurine, sodium lauroyl methyl taurine solution and the like can be mentioned.

Amphoteric surfactants 2-alkyl-N-carboxymethyl-N-hydroxyethyl imidazolinium betaine, undecinoyl-carboxylmethoxyethyl carboxymethyl imidazolinium betaine sodium, undecyl hydroxyethyl imidazolinium betaine sodium, undecyl-
N-hydroxyethyl-N-carboxymethylimidazolinium betaine, alkyldiaminoethylglycine hydrochloride solution, stearyldihydroxyethylbetaine, stearyldimethylbetaine sodium, stearylbetaine, bis (stearyl-N-hydroxyethylimidazoline) chloroacetic acid complex coconut oil alkyl -N-carboxyethyl-N-hydroxyethyl imidazolinium betaine sodium, coconut oil alkyl betaine, coconut oil fatty acid amidopropyl betaine, coconut oil fatty acid-N-carboxymethoxyethyl-N-carboxyethyl imidazolinium betaine sodium, coconut oil Fatty acid-N-carboxymethoxyethyl-N-carboxymethylimidazolinium disodium lauryl sulfate, lauryl dimethylaminoacetic acid betaine, β Sodium lauryl aminopropionic acid, lauryl aminopropionic acid triethanolamine, lauryl di aminoethyl sodium glycine and the like.

Cationic surfactants Ethanol lanolin sulfate fatty acid aminopropylethyldimethylammonium chloride, alkyltrimethylammonium chloride, octadecylammonium chloride, octyldihydroxyethylmethylammonium chloride, dialkyl (12-15) dimethylammonium chloride, dialkyl (14-18) Dimethylammonium, dicocoyldimethylammonium chloride, distearyldimethylammonium chloride, dicetyldimethylammonium chloride solution, di (polyoxyethylene) oleylmethylammonium chloride, stearyldihydroxyethylbetaine sodium chloride, stearyldimethylbenzylammonium chloride,
Stearyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, cetyl pyridinium chloride, benzalkonium chloride, benzalkonium chloride solution, benzathonium chloride, benzathonium chloride solution, polyoxyethylene (1) polyoxypropylene (25) diethylmethyl ammonium chloride, Myristyl dimethyl benzyl ammonium, methyl benzethonium chloride, lauryl trimethyl ammonium chloride, lauryl pyridinium chloride solution, alkylisoquinolium bromide solution, stearyl trimethyl ammonium bromide, cetyl trimethyl ammonium bromide, lauryl trimethyl ammonium bromide, stearyl trimethyl ammonium saccharin, Cetyl trimethyl ammonium saccharin etc. are mentioned.

The above-mentioned surfactants may be used alone or in admixture of two or more.

Antioxidant When the composition for hair dyeing of the present invention is a so-called hair dye, an antioxidant is used for the purpose of suppressing oxidation of the oxidative dye before use and unnecessary color development. It can be blended.

The antioxidant is not particularly limited and widely known ones can be used. Specifically, for example, thioglycolic acid, calcium thioglycolate,
Ammonium thioglycolate, sodium sulfite, ascorbic acid, sodium ascorbate, ammonium ascorbate, propyl gallate, tocophenol, L-cystine, homocystine, N-acetyl-
L-cystine and the like can be mentioned. These antioxidants,
One kind or two or more kinds can be blended.

PH Adjusting Agent A pH adjusting agent may be added in order to adjust the pH. Specific examples include organic acids such as tartaric acid, acetic acid, citric acid, lactic acid, succinic acid and oxalic acid, and inorganic acids such as phosphoric acid and hydrochloric acid. These pH adjusters can be blended in one kind or two or more kinds.

In addition, known hair protecting agents, fragrances such as geraniol, solubilizers such as lower alcohols, polymer compounds, dyes, ultraviolet absorbers, fragrances, stabilizers, penetrants, wetting agents, hair nourishing agents, etc. It may be added appropriately as long as the performance of the hair dyeing composition is not impaired.

The composition for hair dyeing of the present invention can be prepared by a conventional method, and its dosage form can be emulsion, cream, gel, paste or the like. Among these, creamy ones are preferable in terms of good stability.

When the hair dye composition of the present invention does not contain the above dye, it can be used as a decolorizing agent.

[0037]

EXAMPLES The present invention will be described below with reference to examples and comparative examples, but the present invention is not limited to these examples and comparative examples.

Evaluation Criteria With respect to the evaluation method, each item was evaluated by the method shown below. The following formulation was used as the oxidizing agent. Hydrogen peroxide water (35%) 17.0% by mass Cetanol 1.6 Sodium cetyl sulfate 0.2 Tetrasodium edetate 0.2 Phenacetin 0.1 Tartaric acid 0.1 Purified water 100% by mass.

1. Sensory test (touch feeling) 30 g of hair dye prepared based on the formulations of Examples and Comparative Examples
Then, 30 g of an oxidizer was added and mixed, and the mixed solution was applied to a human hair bundle of 30 g, left at room temperature for 30 minutes, washed, and dried. The feel of the dyed human hair bundle was evaluated by sensory evaluation by 20 subjects according to the following criteria. ⊚: 16 or more subjects who answered that they had a good feeling of touch ◯: 12 or more and less than 16 subjects who answered that they had a good feeling of touch Δ: Eight or more and less than 12 subjects answered that they had a good feel. X: Less than 8 subjects answered that the feeling of touch was good.

2. Hair dyeing test (dyeability) To 30 g of the hair dye prepared according to the examples and comparative examples, 30 g of an oxidizing agent was added and mixed, and the mixed solution was applied to 30 g of white human hair and left at room temperature for 30 minutes. Then washed and dried. The dyed state of the dyed white human hair was visually observed by a subject and evaluated according to the following criteria. ⊚: 16 or more subjects who answered that the dyeing condition was good ◯: 12 or more and less than 16 subjects who answered that the dyeing condition was good. Δ: 8 or more and less than 12 subjects answered that the dyeing condition was good. X: Less than 8 subjects answered that the dyeing condition was good.

The creamy oxidative hair dyes of Examples 1 to 11 and Comparative Examples 1 to 6 were each prepared according to a conventional method, and the above tests were carried out. Tables 1 and 2 show the respective compositions and the results of various tests.

[0042]

[Table 1]

[0043]

[Table 2]

From the results shown in Tables 1 and 2, when sea mud and vegetable protein hydrolyzate and / or water-soluble collagen derived from fish are used in combination, hair dyeing and leveling properties are obtained at any mixing ratio. It was revealed that it is excellent, and further, the damage to the hair is softened, and the feeling after use such as touch is sufficiently excellent.

Further, from Table 1, sea mud is effective in the feeling of touch even when the concentration in the first agent is 0.1% by mass, and if it exceeds 5% by mass, the effect is not significant. Although it was observed, no significant effect was observed, and a significant improvement in the effect was observed at a blending ratio of 1 to 3% by mass.

Similarly, the decolorizing agent will be described with reference to Examples and Comparative Examples.

As for the evaluation method, the sensory test (feeling to the touch), the hair dyeing test (dyeability) shown above, and the method shown below were carried out.

3. Hair dyeing test (decolorization) To 30 g of the sample prepared according to the examples and comparative examples, 30 g of an oxidizing agent was added and mixed, and the mixed solution was applied to 30 g of black hair and left at room temperature for 30 minutes. Washed and dried. The dyed black human hair was visually observed by a subject for a decolorized state, and evaluated according to the following criteria. ⊚: 16 or more subjects who answered that the decolorization state was good ◯: 12 or more and less than 16 subjects who answered that the decolorization state was good Δ: 8 or more and less than 12 subjects answered that the decolorization state was good. X: Less than 8 subjects answered that the decolorization state was good.

The decolorizing agents of Examples 12 to 14 and Comparative Examples 7 to 9 were prepared according to a conventional method, and the above tests were carried out. Table 3 shows the respective compositions and the results of various tests.

[0050]

[Table 3]

From the results shown in Table 3, also in the decolorizing agent, when sea mud was used in combination with the vegetable protein hydrolyzate and / or water-soluble collagen derived from fish, hair dyeing properties and level dyeing were obtained at any mixing ratio. It has been revealed that the composition has excellent properties, further reduces damage to hair, and has a sufficiently excellent feeling after use such as touch.

[0052] Example 15 First agent mass% −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Sea mud (Mironecton R; made by Dainippon Kasei) 1.0 Hydrolyzed wheat powder (Promois WG; Seiwa Kasei Co., Ltd.) 0.3 Water-soluble collagen (Marine collagen NK; manufactured by Ichimaru Falcos) 0.1 Cetanol 9.0 1,3-butylene glycol 5.0 Liquid paraffin 3.0 Polyoxyethylene cetyl ether (5.5 EO) 5.0 Sodium lauryl sulfate 1.0 Jojoba oil 0.3 Dimethyldiallylammonium chloride / acrylic acid copolymer liquid 1.0 Sodium sulfite 1.0 Tetrasodium edetate 0.2 Toluene 2,5-diamine 1.0 Resorcin 0.8 Hydrochloric acid 2,4-diaminophenoxyethanol 0.2 Meta aminophenol 0.1 Monoethanolamine 5.0 Hydrolyzed silk * 4 0.3 Soaproot extract * 4 0.3 Sage extract * 4 0.3 Carrot extract * 4 0.3 Seaweed extract * 4 0.3 Mixed plant extract (1) * 4 0.3 Mixed plant extract (3) * 4 0.3 Mixed plant extract (6) * 4 0.3 Fragrance 0.5 Purified water balance Second agent −−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−−− Hydrogen peroxide water (35%) 17.0 Cetanol 6.0 Cetyl sulfate sodium 1.0 Hydroxyethanediphosphonic acid 0.2 Disodium edetate 0.1 Purified water balance   * 4; "Standards for Quasi-drug Ingredients" Supervised by the Examination Division, Pharmaceutical Affairs Bureau, Ministry of Health and Welfare, Pharmaceutical Affairs Daily 1991 Issued June 15, 2012) Use the one that matches

A hair dye composition having the above composition was prepared by a conventional method. Mix the first agent / second agent in a ratio of 1/2,
When it was used, it was excellent in hair dyeability, level dyeing property, and color retention, and further, the degree of hair damage was low, and the feel after use such as touch was excellent.

In the above-mentioned prescription examples, it is more preferable to use a fragrance having the following prescription because the odor of ammonia and the like can be reduced.

[0055]

[Table 4]

[0056]

EFFECTS OF THE INVENTION As described above, the hair dyeing composition of the present invention is used in combination with sea mud and a vegetable protein hydrolyzate and / or fish-derived water-soluble collagen to obtain hair dyeing properties and leveling properties. It has excellent dyeability and color retention, and also softens hair damage.
It is possible to impart a sufficiently excellent effect to the feeling after use such as touch.

Continued front page    F term (reference) 4C083 AA112 AA122 AA161 AA162                       AB412 AC022 AC032 AC072                       AC122 AC172 AC182 AC302                       AC532 AC542 AC552 AC642                       AC772 AC782 AC792 AC892                       AD092 AD242 AD411 AD412                       AD431 AD432 AD452 CC36                       DD31 EE06 EE26 EE27 EE29

Claims (2)

[Claims] 1. A hair dye comprising the following components (A) and (B); (A) sea mud (B) vegetable protein hydrolyzate and / or fish-derived water-soluble collagen. Composition. 2. The hair dye according to claim 1, wherein the content of the component (A) is 0.1 to 5 mass% and the content of the component (B) is 0.01 to 3 mass%. Composition.