JP2002540263A5 - - Google Patents
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- Publication number
- JP2002540263A5 JP2002540263A5 JP2000608664A JP2000608664A JP2002540263A5 JP 2002540263 A5 JP2002540263 A5 JP 2002540263A5 JP 2000608664 A JP2000608664 A JP 2000608664A JP 2000608664 A JP2000608664 A JP 2000608664A JP 2002540263 A5 JP2002540263 A5 JP 2002540263A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- ether
- transition metal
- olefin
- olefins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 58
- 238000000034 method Methods 0.000 description 55
- 150000001336 alkenes Chemical class 0.000 description 26
- 238000006116 polymerization reaction Methods 0.000 description 24
- 229910052723 transition metal Inorganic materials 0.000 description 15
- 150000003624 transition metals Chemical class 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 14
- 239000002184 metal Substances 0.000 description 14
- 239000012968 metallocene catalyst Substances 0.000 description 14
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- 150000008282 halocarbons Chemical class 0.000 description 8
- 230000000737 periodic effect Effects 0.000 description 8
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 229910052726 zirconium Inorganic materials 0.000 description 6
- NKJOXAZJBOMXID-UHFFFAOYSA-N 1,1'-Oxybisoctane Chemical compound CCCCCCCCOCCCCCCCC NKJOXAZJBOMXID-UHFFFAOYSA-N 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- 125000003367 polycyclic group Chemical group 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 2
- XWCDCDSDNJVCLO-UHFFFAOYSA-N Chlorofluoromethane Chemical compound FCCl XWCDCDSDNJVCLO-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- AFYPFACVUDMOHA-UHFFFAOYSA-N chlorotrifluoromethane Chemical compound FC(F)(F)Cl AFYPFACVUDMOHA-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 2
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 2
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12696299P | 1999-03-30 | 1999-03-30 | |
| US09/387,600 | 1999-08-31 | ||
| US09/387,600 US6288181B1 (en) | 1999-03-30 | 1999-08-31 | Process for producing polyolefins |
| US60/126,962 | 1999-08-31 | ||
| PCT/US1999/023897 WO2000058372A1 (en) | 1999-03-30 | 1999-10-14 | Process for producing polyolefins |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010222301A Division JP5823678B2 (ja) | 1999-03-30 | 2010-09-30 | ポリオレフィンの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002540263A JP2002540263A (ja) | 2002-11-26 |
| JP2002540263A5 true JP2002540263A5 (https=) | 2006-11-30 |
Family
ID=26825201
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000608664A Withdrawn JP2002540263A (ja) | 1999-03-30 | 1999-10-14 | ポリオレフィンの製造方法 |
| JP2010222301A Expired - Lifetime JP5823678B2 (ja) | 1999-03-30 | 2010-09-30 | ポリオレフィンの製造方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010222301A Expired - Lifetime JP5823678B2 (ja) | 1999-03-30 | 2010-09-30 | ポリオレフィンの製造方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6288181B1 (https=) |
| EP (1) | EP1171485B1 (https=) |
| JP (2) | JP2002540263A (https=) |
| CN (1) | CN1161387C (https=) |
| BR (1) | BR9917239B1 (https=) |
| CA (1) | CA2368403A1 (https=) |
| DE (1) | DE69934258T2 (https=) |
| MX (1) | MXPA01009835A (https=) |
| WO (1) | WO2000058372A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7401525B2 (en) * | 2005-03-23 | 2008-07-22 | Honeywell International Inc. | Micro-machined pressure sensor with polymer diaphragm |
| US8087412B2 (en) | 2008-05-01 | 2012-01-03 | Ansell Healthcare Products Llc | Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks |
| DE102013002483B4 (de) | 2013-02-14 | 2019-02-21 | Vdm Metals International Gmbh | Nickel-Kobalt-Legierung |
| US10662269B2 (en) | 2017-08-31 | 2020-05-26 | Lifestyles Healthcare Pte. Ltd. | Ziegler-Natta catalyzed polyisoprene articles |
| JP2022159145A (ja) * | 2021-03-31 | 2022-10-17 | 三井化学株式会社 | オレフィン重合体の製造方法 |
Family Cites Families (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4076698A (en) | 1956-03-01 | 1978-02-28 | E. I. Du Pont De Nemours And Company | Hydrocarbon interpolymer compositions |
| US4003712A (en) | 1970-07-29 | 1977-01-18 | Union Carbide Corporation | Fluidized bed reactor |
| NO136797C (no) | 1970-09-25 | 1977-11-09 | Union Carbide Corp | Fremgangsm}te for polymerisering av etylen med modifisert katalysator |
| US4012573A (en) | 1970-10-09 | 1977-03-15 | Basf Aktiengesellschaft | Method of removing heat from polymerization reactions of monomers in the gas phase |
| US3709853A (en) | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
| US4011382A (en) | 1975-03-10 | 1977-03-08 | Union Carbide Corporation | Preparation of low and medium density ethylene polymer in fluid bed reactor |
| US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
| US4792592A (en) | 1981-03-26 | 1988-12-20 | Union Carbide Corporation | Process for reducing sheeting during polymerization of alpha-olefins |
| US4876320A (en) * | 1981-03-26 | 1989-10-24 | Union Carbide Chemicals And Plastics Company Inc. | Process for reducing sheeting during polymerization of alpha-olefins |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4564647A (en) | 1983-11-14 | 1986-01-14 | Idemitsu Kosan Company Limited | Process for the production of polyethylene compositions |
| CA1235543A (en) | 1984-09-12 | 1988-04-19 | Norio Kashiwa | Process for producing propylene block copolymer |
| US4752597A (en) | 1985-12-12 | 1988-06-21 | Exxon Chemical Patents Inc. | New polymerization catalyst |
| US4855370A (en) | 1986-10-01 | 1989-08-08 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| US5026795A (en) | 1987-02-24 | 1991-06-25 | Phillips Petroleum Co | Process for preventing fouling in a gas phase polymerization reactor |
| FR2618786B1 (fr) | 1987-07-31 | 1989-12-01 | Bp Chimie Sa | Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US4803251A (en) | 1987-11-04 | 1989-02-07 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| FR2646426B2 (fr) | 1988-09-13 | 1991-08-16 | Bp Chemicals Sa | Procede et appareillage de polymerisation d'alpha-olefine en phase gazeuse en presence d'un agent ralentisseur d'activite |
| US5227440A (en) | 1989-09-13 | 1993-07-13 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| FR2656314B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines. |
| FR2656315B1 (fr) | 1989-12-22 | 1992-04-17 | Bp Chemicals Snc | Procede de preparation d'un catalyseur a base de zirconium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines. |
| US5177042A (en) * | 1989-12-29 | 1993-01-05 | Union Carbide Chemicals And Plastics Technology Corporation | High activity vanadium-based catalyst |
| FR2660926B1 (fr) | 1990-04-11 | 1992-07-31 | Bp Chemicals Snc | Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere. |
| US5162463A (en) | 1990-12-10 | 1992-11-10 | Union Carbide Chemicals & Plastics Technology Corporation | Method for producing sticky polymers |
| US5200477A (en) | 1991-02-22 | 1993-04-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing sticky polymers |
| DE69219668T2 (de) | 1991-03-29 | 1997-09-11 | Chevron Usa Inc | Cyclopentadienylgruppe enthaltende Alpha-Olefin-Polymerisationskatalysatoren auf Basis eines Metals der 6B-Gruppe und Verfahren zur Polymerisation von Alpha-Olefinen |
| US5466766A (en) | 1991-05-09 | 1995-11-14 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
| EP0515132B2 (en) | 1991-05-20 | 2003-08-27 | Mitsui Chemicals, Inc. | Olefin polymerization catalyst and olefin polymerization |
| DE69224600T2 (de) | 1991-11-12 | 1998-08-27 | Nippon Oil Co Ltd | Katalysatorbestandteile für Olefinpolymerisation |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| EP0578838A1 (en) | 1992-04-29 | 1994-01-19 | Hoechst Aktiengesellschaft | Olefin polymerization catalyst, process for its preparation, and its use |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| US5194526A (en) | 1992-07-30 | 1993-03-16 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing sticky polymers |
| JP3202349B2 (ja) | 1992-09-22 | 2001-08-27 | 三菱化学株式会社 | 触媒組成物およびそれを用いるオレフィンの重合法 |
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| EP0630910A1 (en) | 1993-06-28 | 1994-12-28 | Union Carbide Chemicals & Plastics Technology Corporation | Use of Lewis Bases for activity reduction in metallocene catalyzed olefin polymerization reactions |
| WO1996000245A1 (en) | 1994-06-24 | 1996-01-04 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US5625012A (en) | 1994-06-29 | 1997-04-29 | Union Carbide Chemicals & Plastics Technology Corporation | Process for reducing polymer build-up in recycle lines and heat exchangers during polymerization of alpha olefins |
| US5468702A (en) | 1994-07-07 | 1995-11-21 | Exxon Chemical Patents Inc. | Method for making a catalyst system |
| US5948972A (en) | 1994-12-22 | 1999-09-07 | Kla-Tencor Corporation | Dual stage instrument for scanning a specimen |
| JP3517471B2 (ja) | 1994-12-28 | 2004-04-12 | 三井化学株式会社 | 環状オレフィン共重合体の製造方法 |
| FR2729393B1 (fr) * | 1995-01-18 | 1997-03-21 | Bp Chemicals Snc | Procede de polymerisation d'olefine |
| US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
| CN1061994C (zh) * | 1995-07-14 | 2001-02-14 | 中国石油化工总公司 | 间规选择性复合金属茂催化剂、其制备及应用 |
| JP3529921B2 (ja) * | 1995-12-05 | 2004-05-24 | 三井化学株式会社 | オレフィン重合用固体触媒およびオレフィン重合用予備重合触媒 |
| WO1998020045A1 (en) | 1996-11-01 | 1998-05-14 | Union Carbide Chemicals & Plastics Technology Corporation | Reduction of fouling in olefin polymerization systems |
| DE19709486A1 (de) | 1997-03-07 | 1998-09-10 | Studiengesellschaft Kohle Mbh | Verfahren und Katalysatoren zur stereospezifischen Polymerisation von Olefinen mit chiralen Halbsandwich-Metallocen-Katalysatoren |
| US5777120A (en) | 1997-03-14 | 1998-07-07 | University Of Iowa Research Foundation | Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts |
| JP3813299B2 (ja) * | 1997-06-02 | 2006-08-23 | 三井化学株式会社 | オレフィン気相重合における重合開始方法 |
-
1999
- 1999-08-31 US US09/387,600 patent/US6288181B1/en not_active Expired - Lifetime
- 1999-10-14 WO PCT/US1999/023897 patent/WO2000058372A1/en not_active Ceased
- 1999-10-14 CA CA002368403A patent/CA2368403A1/en not_active Abandoned
- 1999-10-14 BR BRPI9917239-9A patent/BR9917239B1/pt not_active IP Right Cessation
- 1999-10-14 EP EP99954898A patent/EP1171485B1/en not_active Expired - Lifetime
- 1999-10-14 CN CNB998166758A patent/CN1161387C/zh not_active Expired - Lifetime
- 1999-10-14 JP JP2000608664A patent/JP2002540263A/ja not_active Withdrawn
- 1999-10-14 MX MXPA01009835A patent/MXPA01009835A/es unknown
- 1999-10-14 DE DE69934258T patent/DE69934258T2/de not_active Expired - Lifetime
-
2010
- 2010-09-30 JP JP2010222301A patent/JP5823678B2/ja not_active Expired - Lifetime
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