JP2002535421A5 - - Google Patents
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- JP2002535421A5 JP2002535421A5 JP2000594580A JP2000594580A JP2002535421A5 JP 2002535421 A5 JP2002535421 A5 JP 2002535421A5 JP 2000594580 A JP2000594580 A JP 2000594580A JP 2000594580 A JP2000594580 A JP 2000594580A JP 2002535421 A5 JP2002535421 A5 JP 2002535421A5
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- phenolic resin
- acid
- modifier
- aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000853 adhesive Substances 0.000 description 99
- 230000001070 adhesive effect Effects 0.000 description 70
- 239000000203 mixture Substances 0.000 description 70
- 239000003607 modifier Substances 0.000 description 56
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 54
- 229910052751 metal Inorganic materials 0.000 description 54
- 239000002184 metal Substances 0.000 description 54
- 239000005011 phenolic resin Substances 0.000 description 54
- 229920001568 phenolic resin Polymers 0.000 description 52
- 239000002243 precursor Substances 0.000 description 45
- -1 IsoPlen Chemical compound 0.000 description 42
- 125000003118 aryl group Chemical group 0.000 description 42
- 239000006185 dispersion Substances 0.000 description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 37
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- 239000000758 substrate Substances 0.000 description 31
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- 239000000178 monomer Substances 0.000 description 29
- 229920003986 novolac Polymers 0.000 description 29
- 238000000034 method Methods 0.000 description 27
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 25
- 239000002253 acid Substances 0.000 description 24
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- 239000004816 latex Substances 0.000 description 24
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 22
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 22
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- 150000001875 compounds Chemical class 0.000 description 21
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- 125000001424 substituent group Chemical group 0.000 description 17
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- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000011248 coating agent Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 13
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 12
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 12
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- 238000012360 testing method Methods 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 11
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- 125000002877 alkyl aryl group Chemical group 0.000 description 10
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 10
- 150000002500 ions Chemical class 0.000 description 10
- 150000002989 phenols Chemical class 0.000 description 10
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- 239000011541 reaction mixture Substances 0.000 description 10
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 9
- 239000007795 chemical reaction product Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
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- 239000000376 reactant Substances 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 238000009835 boiling Methods 0.000 description 8
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- 238000005304 joining Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 8
- 159000000000 sodium salts Chemical class 0.000 description 8
- 229910052717 sulfur Inorganic materials 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 238000007720 emulsion polymerization reaction Methods 0.000 description 7
- 125000003010 ionic group Chemical group 0.000 description 7
- 150000002832 nitroso derivatives Chemical class 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 238000009833 condensation Methods 0.000 description 6
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 150000002828 nitro derivatives Chemical class 0.000 description 6
- 229920000098 polyolefin Polymers 0.000 description 6
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 150000003871 sulfonates Chemical class 0.000 description 6
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 description 5
- 239000004971 Cross linker Substances 0.000 description 5
- 230000000712 assembly Effects 0.000 description 5
- 238000000429 assembly Methods 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 229920001084 poly(chloroprene) Polymers 0.000 description 5
- 239000012855 volatile organic compound Substances 0.000 description 5
- PDKAXHLOFWCWIH-UHFFFAOYSA-N 1,1-dichlorobuta-1,3-diene Chemical compound ClC(Cl)=CC=C PDKAXHLOFWCWIH-UHFFFAOYSA-N 0.000 description 4
- LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 description 4
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- DKJVSIITPZVTRO-UHFFFAOYSA-N 6,7-dihydroxynaphthalene-2-sulfonic acid Chemical compound C1=C(S(O)(=O)=O)C=C2C=C(O)C(O)=CC2=C1 DKJVSIITPZVTRO-UHFFFAOYSA-N 0.000 description 4
- 244000043261 Hevea brasiliensis Species 0.000 description 4
- RWNKSTSCBHKHTB-UHFFFAOYSA-N Hexachloro-1,3-butadiene Chemical compound ClC(Cl)=C(Cl)C(Cl)=C(Cl)Cl RWNKSTSCBHKHTB-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 238000000748 compression moulding Methods 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical group C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 229920003052 natural elastomer Polymers 0.000 description 4
- 229920001194 natural rubber Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- SHHKMWMIKILKQW-UHFFFAOYSA-N 2-formylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1C=O SHHKMWMIKILKQW-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 150000004982 aromatic amines Chemical group 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 150000008378 aryl ethers Chemical class 0.000 description 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 3
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- 238000006482 condensation reaction Methods 0.000 description 3
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- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- OXNIZHLAWKMVMX-UHFFFAOYSA-N picric acid Chemical compound OC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O OXNIZHLAWKMVMX-UHFFFAOYSA-N 0.000 description 3
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 230000008569 process Effects 0.000 description 3
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- 229910052708 sodium Inorganic materials 0.000 description 3
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- 229950002929 trinitrophenol Drugs 0.000 description 3
- ZFBGKBGUMMBBMY-UHFFFAOYSA-N 1,1,2-trichlorobuta-1,3-diene Chemical compound ClC(Cl)=C(Cl)C=C ZFBGKBGUMMBBMY-UHFFFAOYSA-N 0.000 description 2
- IZUKQUVSCNEFMJ-UHFFFAOYSA-N 1,2-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1[N+]([O-])=O IZUKQUVSCNEFMJ-UHFFFAOYSA-N 0.000 description 2
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- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
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- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- DCHPLLIYQOESOZ-UHFFFAOYSA-N 6,7-dihydroxynaphthalene-1-sulfonic acid Chemical compound C1=CC(S(O)(=O)=O)=C2C=C(O)C(O)=CC2=C1 DCHPLLIYQOESOZ-UHFFFAOYSA-N 0.000 description 2
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N N-methylaminoacetic acid Natural products C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 108010077895 Sarcosine Proteins 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
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- CTIQLGJVGNGFEW-UHFFFAOYSA-L naphthol yellow S Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C([O-])=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 CTIQLGJVGNGFEW-UHFFFAOYSA-L 0.000 description 2
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical class [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
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- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
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- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
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- CMHHITPYCHHOGT-UHFFFAOYSA-N tributylborane Chemical compound CCCCB(CCCC)CCCC CMHHITPYCHHOGT-UHFFFAOYSA-N 0.000 description 1
- KQBSGRWMSNFIPG-UHFFFAOYSA-N trioxane Chemical compound C1COOOC1 KQBSGRWMSNFIPG-UHFFFAOYSA-N 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 150000003739 xylenols Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11676799P | 1999-01-22 | 1999-01-22 | |
| US60/116,767 | 1999-01-22 | ||
| PCT/US2000/001417 WO2000043131A2 (en) | 1999-01-22 | 2000-01-20 | Autodepositable adhesive |
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| Publication Number | Publication Date |
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| JP2002535421A JP2002535421A (ja) | 2002-10-22 |
| JP2002535421A5 true JP2002535421A5 (enExample) | 2014-02-27 |
| JP5496438B2 JP5496438B2 (ja) | 2014-05-21 |
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|---|---|---|---|
| JP2000594580A Expired - Fee Related JP5496438B2 (ja) | 1999-01-22 | 2000-01-20 | 自動付着性接着剤 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6521687B2 (enExample) |
| EP (1) | EP1144535B1 (enExample) |
| JP (1) | JP5496438B2 (enExample) |
| AT (1) | ATE281500T1 (enExample) |
| AU (1) | AU2854400A (enExample) |
| BR (1) | BR0008184B1 (enExample) |
| CA (1) | CA2359054C (enExample) |
| DE (1) | DE60015497T2 (enExample) |
| ES (1) | ES2226789T3 (enExample) |
| WO (1) | WO2000043131A2 (enExample) |
Families Citing this family (21)
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|---|---|---|---|---|
| WO2000043131A2 (en) * | 1999-01-22 | 2000-07-27 | Lord Corporation | Autodepositable adhesive |
| AU2001243188A1 (en) * | 2000-02-18 | 2001-08-27 | Henkel Kommanditgesellschaft Auf Aktien | Rubber-metal composites |
| US20040033374A1 (en) * | 2002-08-16 | 2004-02-19 | Mowrey Douglas H. | Phenolic adhesives for bonding peroxide-cured elastomers |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| BR0315341B1 (pt) | 2002-10-15 | 2014-02-18 | Adesivos compreendendo poliolefina. | |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| DE10327452A1 (de) * | 2003-06-18 | 2005-01-05 | Bayer Materialscience Ag | Klebstoffe |
| WO2005000480A2 (en) * | 2003-06-27 | 2005-01-06 | Lord Corporation | Improved coating process utilizing automated systems |
| US20050074567A1 (en) * | 2003-09-24 | 2005-04-07 | Corbett Bradford G. | Protective coating compositions and techniques for fluid piping systems |
| US20070244247A1 (en) * | 2006-04-13 | 2007-10-18 | Mowrey Douglas H | Aqueous adhesive for rubber to metal bonding |
| US20070243372A1 (en) * | 2006-04-13 | 2007-10-18 | Mowrey Douglas H | Aqueous adhesive |
| US8288447B2 (en) | 2006-06-07 | 2012-10-16 | Henkel Ag & Co. Kgaa | Foamable compositions based on epoxy resins and polyesters |
| CA2663920C (en) | 2006-09-18 | 2015-11-24 | Henkel Ag & Co. Kgaa | Off-white and gray autodeposition coatings |
| DE102009003082A1 (de) | 2009-05-13 | 2010-11-18 | Henkel Ag & Co. Kgaa | Anionische Netzmittel zur Stabilisierung selbstabscheidender Zusammensetzungen enthaltend oxidische Pigmente |
| JP5603156B2 (ja) * | 2010-07-12 | 2014-10-08 | ダンロップスポーツ株式会社 | ゴルフボール |
| US9916555B2 (en) | 2012-04-10 | 2018-03-13 | Geoforce, Inc. | Location tracking with integrated identification of cargo carrier contents and related system and method |
| US9133295B2 (en) * | 2012-11-29 | 2015-09-15 | Georgia-Pacific Chemicals Llc | Preparation of phenol-formaldehyde resin beads using suspension or emulsion polymerization |
| JP2018522954A (ja) | 2015-05-01 | 2018-08-16 | ロード コーポレイション | ゴム接合用接着剤 |
| EP3957986B1 (en) | 2015-11-30 | 2024-09-18 | Intabio, Llc | Methods for sample characterization |
| WO2019148198A1 (en) | 2018-01-29 | 2019-08-01 | Intabio, Inc. | Devices, methods and kits for sample characterization |
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| US3258388A (en) * | 1962-08-31 | 1966-06-28 | Lord Corp | Adhesive composition for bonding rubber to metal |
| US3920600A (en) * | 1974-01-08 | 1975-11-18 | Du Pont | Adhesive compositions |
| JPS5153590A (en) * | 1974-11-06 | 1976-05-12 | Toyo Soda Mfg Co Ltd | Kuroropurenno jugoho |
| US4119587A (en) * | 1977-02-25 | 1978-10-10 | Lord Corporation | Adhesive compositions comprising (a) halogenated polyolefin (b) aromatic nitroso compound and (c) lead salts |
| US4414350A (en) * | 1979-09-27 | 1983-11-08 | Amchem Products, Inc. | Ferrous complexing agent for autodeposition |
| US4994521A (en) * | 1979-12-12 | 1991-02-19 | Amchem Corporation | Persulfate activated autodepositing composition |
| US5912297A (en) * | 1983-07-25 | 1999-06-15 | Henkel Corporation | Internally stabilized vinylidene chloride resin in autodeposition |
| US4647480A (en) * | 1983-07-25 | 1987-03-03 | Amchem Products, Inc. | Use of additive in aqueous cure of autodeposited coatings |
| US4855001A (en) * | 1987-02-10 | 1989-08-08 | Lord Corporation | Structural adhesive formulations and bonding method employing same |
| AU617726B2 (en) * | 1987-12-18 | 1991-12-05 | Lord Corporation | Adhesive composition, methods for the production and use thereof, and articles produced thereby |
| FR2627499B1 (fr) * | 1988-02-24 | 1990-08-03 | Hoechst France | Dispersion aqueuse de polymeres du type styrene-acrylique et son application pour l'obtention de compositions adhesives resistant a l'eau convenant notamment dans le domaine du carrelage |
| US4920176A (en) * | 1988-12-05 | 1990-04-24 | The B. F. Goodrich Company | Nitrile emulsion polymers having improved adhesion properties |
| WO1991005023A1 (en) * | 1989-10-02 | 1991-04-18 | Henkel Corporation | Composition and process for and article with improved autodeposited surface coating based on epoxy resin |
| US4968741A (en) * | 1989-10-06 | 1990-11-06 | The Goodyear Tire & Rubber Company | Latex for coatings having reduced blushing characteristics |
| US5122566A (en) * | 1989-10-06 | 1992-06-16 | The Goodyear Tire & Rubber Company | Latex for coatings having reduced blushing characteristics |
| US5061523A (en) * | 1990-09-24 | 1991-10-29 | Henkel Corporation | Autodeposition process with low volatile organic chemical emissions |
| US5200459A (en) * | 1991-05-31 | 1993-04-06 | Lord Corporation | Stable butadiene heteropolymer latices |
| US5300555A (en) * | 1991-05-31 | 1994-04-05 | Lord Corporation | Stable butadiene homopolymers latices |
| US5200455A (en) | 1992-01-30 | 1993-04-06 | Lord Corporation | Aqueous adhesive compositions containing stabilized phenolic resins |
| US5646211A (en) * | 1992-01-31 | 1997-07-08 | Henkel Corporation | Autodeposition coating composition |
| US5427863A (en) * | 1992-09-23 | 1995-06-27 | Henkel Corporation | Polymer blends for autodeposited coating |
| JP3484743B2 (ja) * | 1993-02-26 | 2004-01-06 | Ｎｏｋ株式会社 | 接着剤組成物 |
| US5367010A (en) * | 1993-03-22 | 1994-11-22 | Lord Corporation | Adhesive compositions based on chlorinated ethylene/vinyl acetate copolymers |
| US5372853A (en) * | 1993-08-05 | 1994-12-13 | Henkel Corporation | Treatment to improve corrosion resistance of autodeposited coatings of metallic surfaces |
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| JP4005311B2 (ja) | 1998-01-27 | 2007-11-07 | ロード コーポレーション | 水性フェノ−ル樹脂分散液 |
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-
2000
- 2000-01-20 WO PCT/US2000/001417 patent/WO2000043131A2/en not_active Ceased
- 2000-01-20 ES ES00906970T patent/ES2226789T3/es not_active Expired - Lifetime
- 2000-01-20 AU AU28544/00A patent/AU2854400A/en not_active Abandoned
- 2000-01-20 EP EP00906970A patent/EP1144535B1/en not_active Expired - Lifetime
- 2000-01-20 US US09/488,716 patent/US6521687B2/en not_active Expired - Lifetime
- 2000-01-20 CA CA2359054A patent/CA2359054C/en not_active Expired - Fee Related
- 2000-01-20 DE DE60015497T patent/DE60015497T2/de not_active Expired - Lifetime
- 2000-01-20 AT AT00906970T patent/ATE281500T1/de not_active IP Right Cessation
- 2000-01-20 JP JP2000594580A patent/JP5496438B2/ja not_active Expired - Fee Related
- 2000-01-20 BR BRPI0008184-1A patent/BR0008184B1/pt not_active IP Right Cessation
-
2002
- 2002-11-26 US US10/304,219 patent/US7109265B2/en not_active Expired - Fee Related
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