JP2002321303A - Deodorizing humidity conditioning sheet material - Google Patents

Deodorizing humidity conditioning sheet material

Info

Publication number
JP2002321303A
JP2002321303A JP2001163452A JP2001163452A JP2002321303A JP 2002321303 A JP2002321303 A JP 2002321303A JP 2001163452 A JP2001163452 A JP 2001163452A JP 2001163452 A JP2001163452 A JP 2001163452A JP 2002321303 A JP2002321303 A JP 2002321303A
Authority
JP
Japan
Prior art keywords
deodorizing
volume
humidity
humidity control
zeolite powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001163452A
Other languages
Japanese (ja)
Inventor
Toshio Nishizawa
敏雄 西澤
Kazunori Kageyama
和則 影山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NAGAI KIKAI CHUZO CO Ltd
Original Assignee
NAGAI KIKAI CHUZO CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NAGAI KIKAI CHUZO CO Ltd filed Critical NAGAI KIKAI CHUZO CO Ltd
Priority to JP2001163452A priority Critical patent/JP2002321303A/en
Publication of JP2002321303A publication Critical patent/JP2002321303A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5085Calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00267Materials permeable to vapours or gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Drying Of Gases (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Building Environments (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Laminated Bodies (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a deodorizing humidity conditioning sheet material by which an odorous gas, a volatile solvent gas, volatile organic compound or the like is actively absorbed, decomposed and eliminated to be deodorized, and humidity conditioning property in which extra humidity is absorbed and emitted at drying is displayed by using a ceiling material, a wall material and the like of building space to realize safe, hygienic and comfortable building space. SOLUTION: The deodorizing humidity conditioning layer is applied and adhered on one side face or both side faces of a base material composed of an inorganic porous material having gas permeability or both side faces of a base material composed of a fabric substance or a knitting substance. The layer comprises the following compositions of the following percentage; an artificial zeolite powder of 55 to 90% volume which is 30 μm or less in average particle size and at least 70 m<2> /g or more in its specific surface area, and is 200 mg or more in base substitution volume (mg/100 g); a fixing agent of 7 to 25% volume composed of cement or dolomite plaster, and an adhesive agent of 7 to 20% volume composed of a cellulose derivative or sodium salt alginate.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本発明は施設建物や住居建物空間
等の天井や壁に使用することにより、該建物空間内に発
生滞留する臭気ガスや揮散溶剤ガス等の吸着分解消去と
適性な湿度に調湿せしめ、以って安全で衛生的且快適な
建物空間を提供しえる消臭調湿材に関する。
BACKGROUND OF THE INVENTION The present invention is applied to ceilings and walls of facility buildings and residential buildings to absorb and decompose and remove odorous gas and volatile solvent gases generated and retained in the building space and to obtain appropriate humidity. The present invention relates to a deodorant humidity control material which can provide a safe, hygienic and comfortable building space by controlling the humidity.

【0002】[0002]

【従来技術】近年においては極度に都市集中化が進んで
いることから、都市部においては土地の有効利用のため
店舗や事務所等の施設建物或いは住居用建物等も躯体構
造を重構造となし且高層化が図られつつあり、更には一
般戸建住宅においても多様なデザインに加え耐震性や耐
火性に優れ且コスト的にも安価なプレハブ工法やプレカ
ット工法による住居建物が積極的に採用されつつある。
加えてこれら建物にはアルミサッシュや新建材等寸法精
度の高い建材が使用されることとも相俟って、これら建
物空間の密閉性が著しく高まっている。
2. Description of the Related Art In recent years, urban centers have been extremely concentrated, and in urban areas, facilities such as stores and offices or residential buildings are not made to have a heavy frame structure for effective use of land. In addition to the increasing number of high-rise buildings, residential buildings using prefabricated construction methods and pre-cut construction methods, which are excellent in earthquake resistance and fire resistance and inexpensive in addition to various designs, are also actively employed in general detached houses. It is getting.
In addition, due to the use of high-dimensional building materials such as aluminum sash and new building materials for these buildings, the hermeticity of these building spaces is significantly increased.

【0003】これがため特別な換気や清浄設備が完備さ
れていない店舗集合建物においては特定店舗や販売コー
ナー等より発生する臭気が店舗集合建物内に滞留充満し
て建物空間全体が不快な環境におかれ、更に事務所建物
においても近年の就業者の食生活の変化所謂中食化に伴
い多種多様な弁当類や惣菜類を持ち込み食取するため、
これらから発生する臭気が拡散滞留し、特に居住用建物
においては常時居住者が生活することから、食品類や食
事に伴う臭気を初め居住者の汗、皮膚、体液等の変性や
腐敗臭、化粧品や浴用剤或いは喫煙臭等に加え、居住用
建物は密閉性の高まりから年間を通して温暖なうえ風通
しが不十分で、而も水回り設備による多湿性とともに食
物残滓等細菌や黴菌の恰好の繁殖条件を具備するため、
これら細菌や黴菌の繁殖に伴う繁殖臭等とが相俟って生
活臭気化し、これらが居住建物内に滞留充満しているば
かりか、建材や内装材或いは家具調度品等にまで付着浸
透し、特に外来者には著しく不快感を与えている。
[0003] For this reason, in a store complex where special ventilation and cleaning facilities are not fully equipped, the odor generated from a specific store or a sales corner is accumulated in the store complex and the entire building space is uncomfortable. In addition, in the office building, in addition to the recent changes in the eating habits of employees, so-called home meals, various kinds of lunches and prepared dishes are brought in and eaten,
Odors generated from these substances are diffused and retained, especially in residential buildings, where residents always live.Therefore, odors associated with foods and meals, as well as denaturation of perspiration, skin, body fluids, etc., decay odor, cosmetics, etc. Residential buildings are warm and inadequately ventilated throughout the year due to the increase in airtightness, as well as odors, bath additives and smoking odors. In order to have
Living odors are combined with the propagation odor associated with the propagation of these bacteria and fungi, and these odors not only fill up the living buildings, but also penetrate and penetrate into building materials, interior materials, furniture furniture, etc. In particular, it is extremely uncomfortable for foreigners.

【0004】加えて細菌や黴菌類は極めて短時間に急激
な繁殖をなすばかりか、これらの繁殖に伴って分泌され
る分泌液により建物躯体の劣化や内装材、家具調度品に
至るまで変色や汚損が招来され、而もこれら細菌や黴菌
の死骸がアレルゲンとなりアトピー性疾患を誘発し、且
これら菌類の死骸を餌料としてダニを初めとする不快害
虫が蝟集する等、建物空間内が著しく非衛生的な状態に
おかれている。そして現状においてはこれら細菌や黴菌
の繁殖防止のため化学殺黴剤を噴射させたり、防虫のた
めの化学防虫剤ガスを拡散充満させている実態は、他方
において内装材等より発生する揮散有機化合物(VO
C)や揮散有機溶剤等により惹起されるシックハウス症
候群以上に強力且危険を孕んでいる。
In addition, bacteria and fungi not only rapidly propagate in a very short period of time, but also cause deterioration of the building frame and discoloration of interior materials and furniture furniture due to secretions secreted by the propagation. The inside of the building space is extremely unsanitary, such as fouling, and the dead bodies of these bacteria and fungi become allergens and induce atopic diseases, and the dead bodies of these fungi feed together with mite and other unpleasant pests. Is in a state of being. At present, chemical fungicides are sprayed to prevent the propagation of these bacteria and fungi, and chemical insecticide gas for insect control is diffused and filled, on the other hand, volatile organic compounds generated from interior materials etc. (VO
It is stronger and more dangerous than sick house syndrome caused by C) or volatile organic solvents.

【0005】発明者等はかかる実情に鑑み鋭意研究を重
ねた結果臭気分子を含む臭気ガスや揮散溶剤ガス或いは
揮散有機化合物等は、大きな吸着容量所謂実質的な比表
面積において少なくとも50m/g以上の多孔性物質
には積極的に吸着されること、並びに該多孔性物質に高
い塩基置換性即ちその実質的塩基置換容量(meg/1
00g)が少なくとも120乃至150mg以上の塩基
置換性を保持する場合には吸着された臭気分子や揮散有
機化合物分子が分解消去され消臭化が実現できるばかり
か、吸着量の飽和がなくなり吸着性及び分解消去性が長
期に亘って保持されること、更には該多孔性物質として
アルミノ珪酸塩鉱物を用いることにより多湿時における
吸湿と、且乾燥時における放湿所謂調湿性が発揮される
ことを究明した。
The present inventors have conducted intensive studies in view of such circumstances, and as a result, the odor gas containing odor molecules, the volatile solvent gas or the volatile organic compound has a large adsorption capacity of at least 50 m 2 / g in a substantial specific surface area. Is positively adsorbed on the porous material, and the base material has high base substitution property, that is, its substantial base substitution capacity (meg / 1
00g) retains a base substitution property of at least 120 to 150 mg or more, not only can the adsorbed odor molecules and volatile organic compound molecules be decomposed and eliminated to achieve deodorization, but also the adsorption amount becomes saturated and the adsorbability and Determined that the decomposability was maintained for a long period of time, and furthermore, by using an aluminosilicate mineral as the porous substance, it was possible to exhibit moisture absorption in humid conditions and moisture release during drying, so-called humidity control. did.

【0006】これがため発明者等は、先願発明として開
示されてなる特開平11−19922号、特開平11−
302012号、特開2000−026488号或いは
特開2000−143234号発明者の協力のもと、原
材料として鋳造廃砂を用いてアルミノ珪酸塩鉱物たる人
工ゼオライトの製造を試みた結果、その嵩比重が0.5
6、粒子径5乃至10μm、細孔径5乃至10A、比表
面積70乃至100m/g、及び塩基置換容量(me
g/100g)200乃至400mg、溶出pH値5乃
至11、吸湿能力20乃至50%の人工ゼオライトの製
造が確認されたことにより本発明に至った。
For this reason, the inventors have disclosed in Japanese Patent Application Laid-Open No. 11-19922 and Japanese Patent Application Laid-Open No.
302012, JP-A-2000-26488 or JP-A-2000-143234 With the cooperation of the inventor, an attempt was made to produce an artificial zeolite, which is an aluminosilicate mineral, using casting waste sand as a raw material. 0.5
6, particle diameter 5 to 10 μm, pore diameter 5 to 10 A, specific surface area 70 to 100 m 2 / g, and base substitution capacity (me
g / 100 g) 200 to 400 mg, an elution pH value of 5 to 11, production of an artificial zeolite having a moisture absorption capacity of 20 to 50% was confirmed, and the present invention was reached.

【0007】[0007]

【発明が解決しようとする課題】即ち本発明は建物空間
を形成する天井材や壁材として使用し、若しくは区画壁
として使用することにより、臭気ガスや揮散溶剤ガス若
しくは揮散有機化合物の積極的な吸着且分解消去と調湿
を図り、以って安全で衛生的且快適な建物空間を実現し
える消臭調湿板材を提供することにある。
That is, the present invention can be used as a ceiling material or a wall material for forming a building space, or as a partition wall, so that an odor gas, a volatile solvent gas or a volatile organic compound can be actively used. It is an object of the present invention to provide a deodorizing and humidity controlling plate material capable of realizing a safe, hygienic and comfortable building space by absorbing and decomposing and eliminating and controlling humidity.

【0008】[0008]

【課題を解決するための手段】上述の課題を解決するた
めに本発明が用いた技術的手段は、天井材や壁材として
要請される強靭性を初め、耐火性、耐水性、軽量性、加
工性に加えて臭気ガスや揮散溶剤ガス或いは揮散有機化
合物等を十分に且多量に吸着させ、更に湿度の吸放湿の
促進をも図るうえから、通気性を有する無機質多孔性素
材からなる基材を用いるとともに、該基材の一側面若し
くは両側面に臭気ガスや揮散溶剤ガス、或いは揮散有機
化合物を積極的に且効率良く吸着し而も分解消去させる
うえから、平均粒径が30μm以下の吸着表面積率が大
きく且比表面積が少なくとも70m/g以上と大きな
吸着容量を有し、更には吸着した臭気ガス分子や揮散溶
剤ガス分子或いは揮散有機化合物分子等を分解促進させ
て消去せしむるため、その塩基置換容量(meg/10
0g)が少なくとも200mg以上の人工ゼオライト粉
体が55乃至90%容量、並びに塗着形成される消臭調
湿層の固着性及び塗着性を高めるため、セメント若しく
はドロマイトプラスターからなる固着材が7乃至25%
容量、及び塗着形成される消臭調湿層に強靭性と保形性
を付与さしめ、且基材との強固な塗着を図るうえからセ
ルロース誘導体若しくはアルギン酸ナトリウム塩からな
る接着剤が3乃至20%容量割合の組成からなる消臭調
湿層が塗着形成された構成に存する。
The technical means used by the present invention to solve the above-mentioned problems include fire resistance, water resistance, light weight, toughness required for ceiling materials and wall materials. In addition to processability, it is possible to absorb a sufficient and large amount of odor gas, volatile solvent gas or volatile organic compound, and to promote the absorption and release of humidity. In addition to the use of a material, an odor gas, a volatile solvent gas, or a volatile organic compound is positively and efficiently adsorbed on one side or both sides of the base material to be decomposed and eliminated, and the average particle size is 30 μm or less. It has a large adsorption surface area ratio and a large adsorption capacity with a specific surface area of at least 70 m 2 / g. Further, it promotes the decomposition of adsorbed odor gas molecules, volatile solvent gas molecules, volatile organic compound molecules, etc. to be eliminated. Was The base substitution capacity (meg / 10
0 g) of at least 200 mg or more of artificial zeolite powder in a volume of 55 to 90%, and a cement or cement made of dolomite plaster in order to enhance the fixability and coatability of the deodorant humidity control layer formed by coating. ~ 25%
An adhesive made of a cellulose derivative or sodium alginate is used to impart toughness and shape retention to the capacity and the deodorizing humidity control layer formed by coating, and to achieve firm coating with the substrate. A deodorant humidity control layer having a composition of about 20% by volume is formed by coating.

【0009】更に本発明においては基材が金属繊維、合
成繊維若しくは天然繊維を織成若しくは編成してなる織
物地若しくは編物地からなり、且該基材の両側面に消臭
調湿層が塗着形成された構成、及び消臭調湿層に無機繊
維からなり、その分径が0.03mm以下で適宜長さに
切断されたチョップドストランドが3乃至10%容量割
合で配合されてなる構成、及び全体重量の軽量化と透気
透湿のための通気空隙を形成せしめて臭気ガス等の吸着
性及び吸湿性を高めるため、人工ゼオライト粉体中にパ
ーライト、シラスバルーン、フライアッシュバルーンか
らなる無機発泡材が10乃至30%容量割合で配合され
た構成に存する。
Further, in the present invention, the base material is made of a woven or knitted fabric obtained by weaving or knitting a metal fiber, a synthetic fiber or a natural fiber, and a deodorizing humidity control layer is applied to both sides of the base material. A configuration in which chopped strands formed of inorganic fibers, and having a diameter of 0.03 mm or less and appropriately cut into lengths, are blended in an amount of 3 to 10% by volume, In order to increase the adsorbability and hygroscopicity of odor gas etc. by forming ventilation holes for lightening of the overall weight and air permeability and moisture, inorganic zeolite powder consisting of perlite, shirasu balloon, fly ash balloon in artificial zeolite powder A foam material is present in a composition of 10 to 30% by volume.

【0010】[0010]

【作用】本発明はかかる構成よりなるため、次のような
作用を有する。即ち基材が通気性を有する無機質多孔性
素材で形成され、且その一側面若しくは両側面には所要
の性能を有する人工ゼオライト粉体が55乃至90%容
量にセメント若しくはドロマイトプラスターからなる固
着材が7乃至25%容量、及びセルロース誘導体若しく
はアルギン酸ナトリウム塩からなる接着剤が3乃至20
%容量割合の組成の消臭調湿層が塗着形成されてなるた
め、建物空間内で発生拡散する臭気ガスや揮散溶剤ガス
或いは揮散有機化合物等が、消臭調湿層より孔径の比較
的大きな多孔性の基材内に透通し易く、この透通に伴い
臭気ガスや揮散溶剤ガス或いは揮散有機化合物が、その
吸着表面積率が大きく且吸着容量の大きな所謂比表面積
の大きな人工ゼオライト粉体に積極的に吸着されるとと
もに、保持する高い塩素置換性で分解消去されるため吸
着性が長期に維持され更には過剰湿度についても積極的
に吸湿されたうえ保湿がなされる。
Since the present invention has the above-described structure, the present invention has the following functions. That is, the base material is formed of an inorganic porous material having air permeability, and on one or both sides thereof, an artificial zeolite powder having a required performance is provided with a fixing material made of cement or dolomite plaster in a volume of 55 to 90%. 7 to 25% by volume, and 3 to 20 adhesives composed of a cellulose derivative or sodium alginate.
% By volume, the odor gas, the volatile solvent gas, and the volatile organic compounds generated and diffused in the building space have a relatively smaller pore size than the deodorant humidity control layer. It is easy to penetrate into a large porous base material. With this penetration, odor gas, volatile solvent gas or volatile organic compound is converted into artificial zeolite powder having a large adsorption surface area ratio and a large adsorption capacity, so-called large specific surface area. While being positively adsorbed, it is decomposed and eliminated due to the high chlorine-substituting property that is retained, so that the adsorbing property is maintained for a long time, and excess moisture is also actively absorbed and retained.

【0011】そして消臭調湿層には7乃至25%容量割
合のセメント若しくはドロマイトプラスターからなる固
着材が配合されてなるため、塗着形成される消臭調湿層
が強固に固着形成されるとともに,透気性や透湿性が保
持され且基材との塗着も良好になしえる。加えて該消臭
調湿層にはセルロース誘導体若しくはアルギン酸ナトリ
ウム塩からなる接着剤が3乃至20%容量割合で配合さ
れてなるため、塗着形成される消臭調湿層が強靭化さ
れ、特に肉薄に形成された場合にもクラックの発生が防
止されるとともに、基材の素材如何にかかわらず強力な
塗着がなされる。
[0011] Since the deodorizing and humidity controlling layer contains a cement or a dolomite plaster in a volume ratio of 7 to 25% by volume, the deodorizing and humidity controlling layer to be applied is firmly formed. At the same time, air permeability and moisture permeability are maintained, and coating with the base material can be performed well. In addition, since the deodorant humidity control layer contains an adhesive composed of a cellulose derivative or sodium alginate at a volume ratio of 3 to 20%, the deodorant humidity control layer formed by coating is toughened. Even when formed thin, cracks are prevented from being generated, and strong coating is performed irrespective of the material of the base material.

【0012】更に本発明における消臭調湿層に無機繊維
からなりその分径が0.03mm以下で且適宜長さに切
断されたチョップドストランドが3乃至10%容量割合
で配合されることにより、該チョップドストランドが固
着材や接着剤と十分に固着や接着がなされるため、特に
薄肉で形成される消臭調湿層でも乾燥時におけるクラッ
ク発生が阻止されるとともに、該消臭調湿層を形成する
人工ゼオライト粉体中に無機発泡材を10乃至30%容
量割合で配合されることにより、塗着形成される消臭調
湿層に比較的孔径の大きな通気空隙が多数形成され軽量
化とともに臭気ガス類や湿度の吸着吸湿性が著しく高め
られる。而も本発明基材に金属繊維や合成繊維或いは天
然繊維を織成若しくは編成した織物地や編物地を用い該
基材の両側面に消臭調湿層を塗着挟持させた構成では全
体が該基材により補強され且保形性も高められるととも
に、人工ゼオライト粉体の組成割合が著しく増大し、そ
の大きな表面積率及び比表面積により臭気ガスや揮散溶
剤ガス若しくは揮散有機化合物の吸着並びに分解消去
性、或いは湿気の吸放湿性が著しく高められる。
Further, chopped strands composed of inorganic fibers and having a diameter of 0.03 mm or less and appropriately cut into lengths are blended in the deodorizing humidity control layer of the present invention in a proportion of 3 to 10% by volume. Since the chopped strands are sufficiently fixed and adhered to the fixing material and the adhesive, cracks during drying can be prevented even in the deodorant humidity control layer formed particularly in a thin wall, and the deodorant humidity control layer is formed. By blending the inorganic foaming material in the artificial zeolite powder to be formed at a volume ratio of 10 to 30%, a large number of relatively large pores are formed in the deodorizing humidity control layer formed by coating, thereby reducing the weight. Adsorption and absorption of odorous gases and humidity are significantly improved. Also, in a configuration in which a woven or knitted fabric obtained by weaving or knitting a metal fiber, a synthetic fiber, or a natural fiber on the base material of the present invention and a deodorizing humidity control layer is applied and sandwiched on both sides of the base material as a whole, The base material is reinforced and the shape retention is enhanced, and the composition ratio of the artificial zeolite powder is remarkably increased. Due to its large surface area ratio and specific surface area, adsorption and decomposition and elimination of odor gas, volatile solvent gas or volatile organic compound are eliminated. Properties or moisture absorption / release properties are significantly enhanced.

【0013】[0013]

【実施例】以下に本発明実施例を図とともに説明すれ
ば、図1は本発明の断面説明図、図2は人工ゼオライト
粉体の拡大説明図であって本発明は建物空間内で発生拡
散する臭気ガスを初め揮散溶剤ガス若しくは揮散有機化
合物等の吸着並びに分解消去による消臭と吸着能力の維
持、及び多湿時における吸湿と乾燥時における放湿所謂
調湿をなすことにより、安全で衛生的且快適な建物空間
を実現することにあり、これがためには本発明を天井材
や壁材若しくは区画壁材として張設する必要上より通常
においては平板状に成形された板材として使用される。
これがため基材1としては通気性望ましくはその通気孔
径1Aが比較的大きく且その比表面積も大きなものが好
適であることから、具体的にはその通気孔径1Aが略5
0乃至500μm程度のコンクリート連続気泡板や粘土
焼成板、珪藻土板、セラミックス連続気泡板或いは頁岩
や粘土に石炭粉や木粉等を分散混合のうえ焼成し、該石
炭粉や木粉等を焼失せしめた無機質多孔性板材が使用さ
れる。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a sectional explanatory view of the present invention, and FIG. 2 is an enlarged explanatory view of an artificial zeolite powder. It is safe and hygienic by absorbing deodorizing solvent gas or volatile organic compounds, etc., and maintaining deodorizing and adsorbing ability by decomposing and elimination, and absorbing moisture in humid conditions and releasing moisture in drying conditions. In order to realize a comfortable building space, the present invention is usually used as a plate material formed into a flat plate because the present invention needs to be stretched as a ceiling material, a wall material, or a partition wall material.
For this reason, the substrate 1 is preferably air-permeable and preferably has a relatively large air hole diameter 1A and a large specific surface area.
Disperse and mix coal powder or wood powder etc. into concrete open-cell board, clay fired board, diatomaceous earth board, ceramic open-cell board or shale or clay of about 0 to 500 μm, and fire to burn off the coal powder or wood powder. An inorganic porous plate material is used.

【0014】かくして選択された基材1の一側面若しく
は両側面には建物空間内で発生拡散する臭気ガスや揮散
溶剤ガス若しくは揮散有機化合物を積極的に吸着し且分
解消去せしめて消臭と吸着能力を維持せしめ、更には多
湿時における吸湿と且乾燥時における放湿所謂調湿性を
発揮せしむるために消臭調湿層2が所要の厚さを以って
塗着形成されている。この消臭調湿層2における臭気ガ
ス等の吸着並びに分解消去や湿度の吸湿並びに放湿作用
は専ら人工ゼオライト粉体2Aに依拠するものであっ
て、該人工ゼオライト粉体2Aの臭気ガス等の吸着性は
該臭気ガス等との接触表面積率及び吸着容量が関与する
とともに、吸湿並びに放湿作用も接触表面積率及び吸着
容量が大きく関与するものである。
Odor gas, volatile solvent gas or volatile organic compound generated and diffused in the building space is positively adsorbed on one or both side surfaces of the selected substrate 1 and decomposed and eliminated to deodorize and adsorb. The deodorizing and humidity-controlling layer 2 is formed with a required thickness so as to maintain the performance and to exhibit moisture absorption during high humidity and moisture release during drying, so-called humidity control. The adsorption, decomposition and elimination of the odor gas in the deodorizing humidity control layer 2 and the humidifying and desorbing action of the humidity depend exclusively on the artificial zeolite powder 2A. The adsorptivity depends on the contact surface area ratio and the adsorption capacity with the odorous gas and the like, and the contact area ratio and the adsorption capacity greatly influence moisture absorption and desorption.

【0015】そして本発明は実用使用上板材として用い
られるため平板状に成形する手段が必要となるが、一般
的な焼成手段では塩基置換性が熱的に破壊されて分解消
去作用も減失するため、固着材2Bや接着剤2Cによる
成形手段、所謂乾燥固化手段を採用せざるを得ぬもの
の、該乾燥固化手段では人工ゼオライト粉体2Aが固着
材2Bや接着剤2Cに包被閉塞されて臭気ガス等の吸着
や湿度の吸湿が阻害される危険があるため、仮令透気性
や透湿性を保持する固着材2Bや接着剤2Cが選択使用
されても最大30乃至40%程度の包被閉塞がなされた
場合にも、十分に吸着性や吸湿性を発揮しえる人工ゼオ
ライト粉体2Aの選択が肝要となる。かかる事由により
消臭調湿層2の形成のための人工ゼオライト粉体2Aと
しては、図2の如く接触表面積が大きく形成されるよう
その平均粒径が30μm以下で、且微細で膨大数の細孔
20Aを有する吸着容量の大きなものが好適であるた
め、その比表面積が少なくとも70m/g以上で而も
吸着した臭気ガス等を分解消去せしめて消臭を図るうえ
から、その塩基置換容量(meg/100g)が200
mg以上のものが選択されることとなる。
Since the present invention is used as a sheet material for practical use, a means for forming the sheet into a flat plate is required. However, in a general firing means, the base substitution property is thermally destroyed and the decomposing / erasing action is also reduced. For this reason, it is inevitable to employ a forming means using the fixing material 2B or the adhesive 2C, that is, a so-called dry solidifying means. However, in the dry solidifying means, the artificial zeolite powder 2A is covered with the fixing material 2B or the adhesive 2C. Since there is a risk that adsorption of odor gas and the like and absorption of humidity may be hindered, even if the fixing material 2B or the adhesive 2C that retains the provisional air permeability or moisture permeability is selected and used, the encapsulation of up to about 30 to 40% is blocked. It is important to select an artificial zeolite powder 2A that can sufficiently exhibit adsorptivity and hygroscopicity. Due to this reason, the artificial zeolite powder 2A for forming the deodorizing humidity control layer 2 has an average particle size of 30 μm or less, and a large number of fine particles so that a large contact surface area is formed as shown in FIG. Since those having a large adsorption capacity having the pores 20A are preferable, the specific surface area is at least 70 m 2 / g or more. meg / 100g) is 200
mg or more will be selected.

【0016】而して基材1の一側面若しくは両側面に塗
着形成される消臭調湿層2は、かくして選択された人工
ゼオライト粉体2Aが55乃至90%容量割合と、該人
工ゼオライト粉体2Aを所要の厚さの塗着層として固着
させ且保形性を付与せしめるとともに基材1との塗着を
図るうえから、セメント若しくはドロマイトプラスター
からなる固着材2Bが7乃至25%容量割合で、及び消
臭調湿層2に十分な強靭性を付与せしめ且多様な基材1
とも強固な接着を図るうえから、セルロース誘導体若し
くはアルギン酸ナトリウム塩からなる接着剤2Cが3乃
至20%容量割合の組成を以って形成されている。かか
る場合において、固着材にセメントやドロマイトプラス
ターを用いると固着に伴い微細な通気空隙20Bが多数
形成されること、及び人工ゼオライト粉体2Aとのポゾ
ラン作用による固着性が高まることによるものであり、
接着剤2Cにセルロース誘導体若しくはアルギン酸ナト
リウム塩が選択される理由は、人工ゼオライト粉体2A
が該接着剤2Cに包被された場合にも比較的透気性や透
湿性が発揮されて吸着性や吸放湿性が阻害されにくくな
ることによるもので、セルロース誘導体の具体的なもの
としてはエチルセルロース、メチルセルロース、カルボ
キシメチルセルロース或いはアセチルセルロース等が挙
げられる。尚アルギン酸ナトリウム塩に代えてポリビニ
ルアルコールを用いても実用性能が保持される。
The deodorant humidity control layer 2 formed on one or both sides of the base material 1 comprises 55 to 90% by volume of the artificial zeolite powder 2A thus selected and the artificial zeolite. In order to fix the powder 2A as a coating layer of a required thickness, to impart shape retention, and to apply the powder to the substrate 1, the bonding material 2B made of cement or dolomite plaster has a 7 to 25% capacity. To give sufficient toughness to the deodorizing and humidity controlling layer 2 and to obtain various base materials 1
In order to achieve strong adhesion, the adhesive 2C made of a cellulose derivative or sodium alginate is formed with a composition of 3 to 20% by volume. In such a case, when cement or dolomite plaster is used as the fixing material, a large number of fine ventilation voids 20B are formed due to the fixing, and the fixing property by the pozzolanic action with the artificial zeolite powder 2A is increased.
The reason why the cellulose derivative or sodium alginate is selected as the adhesive 2C is that the artificial zeolite powder 2A is used.
This is because even when it is wrapped in the adhesive 2C, relatively air permeability and moisture permeability are exhibited, and adsorption and moisture absorption / desorption properties are hardly inhibited. , Methylcellulose, carboxymethylcellulose or acetylcellulose. Practical performance is maintained even when polyvinyl alcohol is used in place of sodium alginate.

【0017】基材1に消臭調湿層2を塗着形成させる手
段としては該消臭調湿層2を形成する人材ゼオライト粉
体2A、固着材2B及び接着剤2Cを適宜割合で配合
し、この全体量に対して水を略30乃至55%容量割合
で添加し十分に混練し粘性塗着原料となしたうえ、適宜
の塗着装置若しくは手作業により所要の厚さに塗着し乾
燥させることで本発明消臭調湿板材3が作成される。そ
してかかる消臭調湿板材3は天井材や壁材或いは区画壁
材として使用されるもので、天井材としては略9乃至1
5mm程度の厚さで、更に壁材や区画壁材としては略1
5乃至30mm程度が通常使用されてなるから、実質的
消臭調湿層2の厚さとしては天井材の場合では略1.8
乃至4.2mm程度に壁材の場合では略3乃至6mm程
度の厚さに塗着形成されることが望ましい。加えて人工
ゼオライト粉体2Aはアルカリ性の珪酸鉱物であること
から、固着材2Bのセメントが配合され水との混練によ
りポゾラン作用が強く働き過剰に固着する恐れもあるの
で、セメントを使用する場合にはせいぜい7乃至12%
容量程度に留めることが望まれる。
As means for applying the deodorizing and humidity controlling layer 2 on the substrate 1, a zeolite powder 2A for forming the deodorizing and humidity controlling layer 2, a fixing material 2B and an adhesive 2C are blended in an appropriate ratio. Water is added at a volume ratio of about 30 to 55% with respect to the total amount, kneaded well to form a viscous coating material, and then applied to a required thickness by an appropriate coating device or manually, and dried. By doing so, the deodorant humidity control plate material 3 of the present invention is created. The deodorant humidity control plate material 3 is used as a ceiling material, a wall material, or a partition wall material.
It is about 5mm thick, and it is almost 1 as wall material or partition wall material.
Since a thickness of about 5 to 30 mm is usually used, the thickness of the substantially deodorizing and humidity controlling layer 2 is approximately 1.8 in the case of a ceiling material.
In the case of a wall material having a thickness of about 3 to 4.2 mm, it is desirable that the wall material is applied and formed to have a thickness of about 3 to 6 mm. In addition, since the artificial zeolite powder 2A is an alkaline silicate mineral, the cement of the fixing material 2B is blended, and the kneading with water may cause a strong pozzolanic effect, which may cause excessive fixation. At most 7-12%
It is desirable to keep the capacity to about the same.

【0018】更に消臭調湿層2が薄く形成される場合で
は乾燥固化に伴うクラックの発生が危惧され、或いは外
部衝撃が付加され易い壁材としての使用等では、該外部
衝撃の付加による割れやクラック発生の危険を孕んでい
る。従ってかかる問題への対処として図3に示すよう
に、塗着形成される消臭調湿層2に無機繊維からなり、
その分径が0.03mm以下で且適宜の長さに切断され
てなるチョップドストランド2Dを3乃至10%容量割
合で配合させることが提案されるものであって、分径が
0.03mm以下に制限される理由は微粒状の人工ゼオ
ライト粉体2Aの塗着形成時に十分に馴染む柔軟性が要
請されることによるもので、且該チョップドストランド
2Dの長さは塗着原料の粘性や塗着形成厚さ等により適
宜に決定されるが、概ね塗着形成される厚さに相当する
長さから、最大でも該長さの3倍程度が目安となる。無
論無機繊維の具体的なものとしてはガラス繊維やロック
ウール等が挙げられる。
Further, when the deodorizing humidity control layer 2 is formed thin, there is a concern that cracks may be generated due to drying and solidification, or when it is used as a wall material to which an external impact is likely to be applied, cracks due to the application of the external impact may occur. And the danger of cracks. Therefore, as a countermeasure against such a problem, as shown in FIG.
It is proposed that the chopped strands 2D having a diameter of 0.03 mm or less and cut into appropriate lengths be mixed at a volume ratio of 3 to 10%. The reason for the limitation is that a sufficient flexibility is required at the time of coating the fine artificial zeolite powder 2A, and the length of the chopped strand 2D depends on the viscosity of the coating raw material and the coating formation. The thickness is appropriately determined depending on the thickness and the like, but a length roughly corresponding to the thickness to be formed by coating is at most about three times the length. Of course, specific examples of the inorganic fiber include glass fiber and rock wool.

【0019】而して臭気ガスや揮散溶剤ガス若しくは揮
散有機化合物等を吸着し且分解消去せしめて、より大き
な消臭性を実現し或いは過剰な湿気を吸湿し且乾燥時に
放湿し、以ってより快適な建物空間の実現を図るうえか
らは、図4に示す如く基材1として通気性を有する網目
合を以って金属繊維、合成繊維若しくは天然繊維を織成
或いは編成してなる織物地若しくは編物地10を用い、
且該織物地若しくは編物地10の両側面より所要の厚さ
を以って消臭調湿層2が塗着形成された構成のものが提
案される。かかる場合の織物地若しくは編物地10は該
織物地若しくは編物地10を挟んで両側面より塗着形成
される相互の消臭調湿層2.2が一体的に接着しえるよ
うな網目合が望まれるもので、具体的網目合としては
2.5mm平方程度から最大で25mm平方程度のもの
が好適であり、且塗着され形成される本発明消臭調湿板
材3の厚さが9mm以下の薄いものの場合には、使用す
る織物地若しくは編物地10としては金属繊維や少なく
とも1000デニール以上の太織度の合成繊維モノフィ
ラメント等を用いて十分に剛性を付与せしめたものが保
形性のうえから求められる。
By adsorbing and decomposing and eliminating odorous gas, volatile solvent gas or volatile organic compound, etc., a greater deodorizing property is realized, or excess moisture is absorbed and moisture is released during drying. In order to realize a more comfortable building space, as shown in FIG. 4, a woven fabric obtained by weaving or knitting a metal fiber, a synthetic fiber or a natural fiber with a breathable mesh as the base material 1 Using the ground or knitted fabric 10,
In addition, a configuration is proposed in which the deodorant humidity control layer 2 is formed by applying a required thickness from both sides of the woven or knitted fabric 10. In such a case, the woven fabric or knitted fabric 10 has such a mesh that the mutual deodorant humidity control layers 2.2 formed by coating from both sides with the woven fabric or knitted fabric 10 interposed therebetween can be integrally bonded. It is desirable that the mesh size is from about 2.5 mm square to a maximum of about 25 mm square, and the thickness of the deodorant humidity control plate material 3 of the present invention formed by coating is 9 mm or less. In the case of a thin fabric, the fabric or knitted fabric 10 to be used is made of a metal fiber or a synthetic fiber monofilament having a weaving degree of at least 1000 denier or the like and sufficiently imparted rigidity to improve the shape retention. Required from.

【0020】加えて考慮すべきは消臭調湿層2を形成す
る人工ゼオライト粉体2Aの保持する細孔20Aは極め
て微細であるから、該細孔20Aに接触する臭気ガスや
揮散溶剤ガス或いは揮散有機化合物の吸着或いは湿度の
吸湿が十分になされるものの、建物空間内で発生拡散す
る臭気ガスや揮散溶剤ガス或いは揮散有機化合物の吸着
や湿度の吸湿を積極的になすためには、該消臭調湿層2
内に容易に透通、透湿させることが肝要で、これがため
には通気空隙20Bを可成く多く形成させることが望ま
れるため、図5に示す如く消臭調湿層2の形成のために
使用する人工ゼオライト粉体2Aの使用量の10乃至3
0%容量割合をパーライト、シラスバルーン若しくはフ
ライアッシュバルーンからなる無機発泡材2Eを配合使
用することが好適であって、該無機発泡材2Eの粒径に
ついては特段に制約は無いが、あまり粒径の大きなもの
では塗着形成される消臭調湿層2の外形仕上がり状態が
悪くなるため、最大でも1.5乃至3.0mm以下のも
のが望ましい。
It should be additionally considered that the pores 20A held by the artificial zeolite powder 2A forming the deodorizing humidity control layer 2 are extremely fine, so that the odor gas, the volatile solvent gas, Although the adsorption of volatile organic compounds or the absorption of humidity is sufficiently performed, in order to positively absorb and absorb the odor gas and the volatile solvent gas or the volatile organic compounds generated and diffused in the building space and the moisture absorption, Odor control moisture layer 2
It is important to easily allow the water to pass therethrough and to allow moisture to pass therethrough. Since it is desired to form as many ventilation gaps 20B as possible, as shown in FIG. 10 to 3 of the amount of artificial zeolite powder 2A used for
It is preferable to mix and use 0% by volume of an inorganic foam 2E made of perlite, shirasu balloon or fly ash balloon. The particle size of the inorganic foam 2E is not particularly limited, but is very small. When the thickness is large, the finished finish of the deodorant humidity control layer 2 formed by coating deteriorates, so that the thickness is preferably 1.5 to 3.0 mm or less at the maximum.

【0021】本発明はかかる如き構成によるものである
が、以下に本発明による消臭性及び調湿性についての実
験結果を報告すれば、実験に用いた消臭調湿板材は基材
に線径0.3mmのステンレス線条を用い、その網目合
が2.5mm平方に平織してなるステンレス織物地を用
い、この基材の両側面に塗着原料として平均粒径が10
μmでその比表面積が80m/g、及び塩基置換容量
(meg/100g)が260mg、pH値11.0の
人工ゼオライト粉体68%容量、ポルトランドセメント
7.0%容量、ドロマイトプラスター11.0%容量、
メチルセルロース12%容量、及びガラス織維チョップ
ドストランド2.0%容量を撹拌混合のうえ、この全体
量に対して水38%容量を加えて混練したものを用い
た。而してこの塗着原料を基材の両側面よりそれぞれ3
mmの厚さで塗着させ、実質的厚さが6mmの消臭調湿
板材となしたものを用いた。消臭性実験は1mの密閉
型槽の上部に供給栓下部に排気栓を設けるとともに該密
閉型槽内に消臭調湿板材1mを立設させたうえ、供給
栓より所要濃度の臭気ガスを注入充満させたうえ、経過
時間とともに該槽内の残留臭気ガス濃度を北川式ガス検
知管で測定したもので、且該槽内には臭気ガスが消臭調
湿板材に接触しえるよう小型ファンで緩かに流動させた
もので、使用臭気ガスとしてアンモニア、メチルメルカ
プタン、硫化水素、酢酸、一酸化炭素、及び塩素の6種
類について行ったもので測定結果は表1の通りである。
The present invention is based on such a configuration. The following is a description of the results of experiments on the deodorizing properties and humidity control properties of the present invention. A stainless steel fabric having a mesh of 2.5 mm square and a mesh size of 2.5 mm square is used.
μm, the specific surface area is 80 m 2 / g, the base substitution capacity (meg / 100 g) is 260 mg, the artificial zeolite powder having a pH value of 11.0 is 68%, the Portland cement is 7.0%, the dolomite plaster is 11.0. %capacity,
12% by volume of methylcellulose and 2.0% by volume of glass woven chopped strand were mixed with stirring, and then kneaded by adding 38% by volume of water to the total amount. Then, the coating material was applied to both sides of the
A deodorant humidity control plate having a thickness of 6 mm and a substantial thickness of 6 mm was used. In the deodorization test, an exhaust plug was provided at the lower part of the supply plug at the upper part of the closed type tank of 1 m 3 , and a deodorant humidity control plate 1 m 2 was erected in the closed type tank. After the gas was filled and filled, the residual odor gas concentration in the tank was measured with a Kitagawa gas detector tube with the lapse of time, and the odor gas was allowed to come into contact with the deodorizing and controlling wet plate material in the tank. The gas was gently flown with a small fan, and the measurements were performed on six kinds of odor gases, such as ammonia, methyl mercaptan, hydrogen sulfide, acetic acid, carbon monoxide, and chlorine.

【0022】[0022]

【表1】 [Table 1]

【0023】更に調湿性試験については、同様の密閉型
槽を用い該槽内に消臭調湿板材1mを適宜に配したう
え供給栓より湿度98%の加湿空気を注入充満させ経過
時間とともに湿度変化を測定して吸湿性を判定し、然る
後槽内に湿度35%の乾燥空気を注入充満させたうえ経
過時間とともに槽内の湿度上昇変化を測定することによ
り放湿性を判定したもので結果は表2の通りである。
Further, in the humidity control test, 1 m 2 of a deodorant humidity control plate material was appropriately disposed in the same closed type tank, and humidified air having a humidity of 98% was injected and filled from the supply plug, followed by the elapsed time. Measure the change in humidity to determine the hygroscopicity, and then inject into the tank 35% humidity dry air, fill and then measure the change in humidity rise in the tank with elapsed time to determine the moisture release Table 2 shows the results.

【0024】[0024]

【表2】 [Table 2]

【0025】[0025]

【発明の効果】本発明は以上のように、通気性を有する
無機質多孔性素材からなる基材の一側面若しくは両側面
に、或いは織物地若しくは編物地からなる基材の両側面
に消臭調湿層が塗着形成されてなり且該消臭調湿層が臭
気ガス等の吸着に係る接触表面積率の極めて大きな平均
粒径30μm以下で、且極めて大きな吸着容量を保持さ
せるうえからその比表面積が少なくとも70m/g以
上で、而も吸着された臭気ガス分子を初め揮散溶剤ガス
分子或いは揮散有機化合物分子をその塩基置換性により
分解し消去せしめる塩基置換容量(meg/100g)
が200mg以上の人工ゼオライト粉体が55乃至90
%容量割合で配合され、更には消臭調湿層に固着性と保
形性を付与せしむるためにセメント若しくはドロマイト
プラスターからなる固着材が7乃至25%容量割合で配
合され、加えて該消臭調湿層に強靭性と広範な被着面と
の接着性を保持せしむるうえで、セルロース誘導体若し
くはアルギン酸ナトリウム塩からなる接着剤が3乃至2
0%容量割合で配合された組成からなるから、該消臭調
湿層に接触した臭気ガスや揮散溶剤ガス或いは揮散有機
化合物等は効率良く吸着され、若しくは接触した過剰湿
度に係る湿気も効率良く吸湿され、而も固着材の乾燥固
化に際しては水分蒸散に伴う多数の通気空隙が創出さ
れ、且セルロース誘導体やアルギン酸ナトリウム塩から
なる接着剤による包被接着がなされても透気性や透湿性
を有するため人工ゼオライト粉体の吸着性や吸湿性が損
なわれぬため、臭気ガスや揮散溶剤ガス或いは揮散有機
化合物が該消臭調湿層から基材にまで亘って透過される
ため積極的にこれらが吸着吸湿されることとなり、且吸
着された臭気ガス分子等は分解消去されるため長期に亘
って消臭性が維持される。そして吸湿された湿気水分は
人工ゼオライト粉体の立体構造間隙内に保水されるとと
もに乾燥度合に応じて放湿されるため、建物空間内の湿
度が安定して保持される所謂調湿性が発揮されるため、
結露の発生防止とともに細菌や黴菌の繁殖も抑制され、
且連鎖されるダニ等不快害虫の蝟集も抑制され、衛生的
快適な建物空間が実現される。加えて本発明は膨大量の
細孔を有する人工ゼオライト粉体を主組成とする消臭調
湿層が無機質多孔性素材からなる基材に塗着形成される
ため、優れた断熱性はもとより遮音性をも発揮すること
等が相俟って本発明は広範なシックハウス症候群を解決
するには極めて好適な消臭調湿板材である。
As described above, the present invention can be applied to one side or both sides of a base made of an inorganic porous material having air permeability, or to both sides of a base made of a woven or knitted fabric. A wet layer is formed by coating, and the deodorizing and humidity controlling layer has an extremely large average particle diameter of 30 μm or less in contact surface area ratio for adsorption of odorous gas and the like, and has a specific surface area in order to maintain an extremely large adsorption capacity. Is at least 70 m 2 / g, and a base substitution capacity (meg / 100 g) for decomposing and eliminating adsorbed odor gas molecules and volatile solvent gas molecules or volatile organic compound molecules by their base substitution properties.
Of artificial zeolite powder of 200 mg or more is 55 to 90
% In order to provide the deodorant humidity control layer with fixation and shape retention, and a fixing material composed of cement or dolomite plaster is added in a proportion of 7 to 25% by volume. In order to maintain toughness and adhesion to a wide range of adherends on the deodorizing humidity control layer, an adhesive composed of a cellulose derivative or sodium alginate is used in an amount of 3 to 2%.
Since it has a composition of 0% by volume, the odor gas, the volatile solvent gas or the volatile organic compound that has come into contact with the deodorizing humidity control layer is efficiently adsorbed, or the humidity that comes into contact with the excess humidity is efficiently taken away. Moisture is absorbed, and when the solidifying material is dried and solidified, a large number of ventilation voids are created due to the evaporation of moisture, and the material has air permeability and moisture permeability even when wrapped and adhered with an adhesive composed of a cellulose derivative or sodium alginate. Because the adsorptive property and hygroscopic property of the artificial zeolite powder are not impaired, the odor gas, the volatile solvent gas or the volatile organic compound is permeated from the deodorizing humidity control layer to the base material, so that these are positively affected. Odor gas molecules are absorbed and absorbed, and the adsorbed odor gas molecules and the like are decomposed and eliminated, so that the deodorizing property is maintained for a long period of time. The absorbed moisture is retained in the three-dimensional structure gap of the artificial zeolite powder and released according to the degree of drying, so that the humidity in the building space is stably maintained, so-called humidity control. To
As well as preventing the formation of condensation, the growth of bacteria and fungi is also suppressed,
In addition, the aggregation of unpleasant pests such as chain mites is suppressed, and a sanitary and comfortable building space is realized. In addition, the present invention has a deodorizing and humidity controlling layer mainly composed of an artificial zeolite powder having an enormous number of pores formed on a substrate made of an inorganic porous material, so that not only excellent heat insulating properties but also sound insulation is achieved. The present invention is an extremely suitable deodorizing and controlling wet plate material for solving a wide range of sick house syndromes.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の断面説明図である。FIG. 1 is an explanatory cross-sectional view of the present invention.

【図2】人工ゼオライト粉体の拡大説明図である。FIG. 2 is an enlarged explanatory view of an artificial zeolite powder.

【図3】チョップドストランドが配合された消臭調湿層
の断面説明図である。
FIG. 3 is an explanatory cross-sectional view of a deodorant humidity control layer in which chopped strands are blended.

【図4】織物地を基材に用いた本発明の断面説明図であ
る。
FIG. 4 is an explanatory sectional view of the present invention using a woven fabric as a base material.

【図5】無機発泡材が配合された消臭調湿層の断面説明
図である。
FIG. 5 is an explanatory cross-sectional view of a deodorant humidity control layer in which an inorganic foaming material is blended.

【符号の説明】[Explanation of symbols]

1 基材 1A 通気孔径 10 織物地若しくは編物地 2 消臭調湿層 2A 人工ゼオライト粉体 2B 固着材 2C 接着剤 2D チョップドストランド 2E 無機発泡材 20A 人工ゼオライト粉体の細孔 20B 通気空隙 3 本発明 REFERENCE SIGNS LIST 1 base material 1A vent hole diameter 10 woven fabric or knitted fabric 2 deodorant humidity control layer 2A artificial zeolite powder 2B fixing material 2C adhesive 2D chopped strand 2E inorganic foam material 20A pores of artificial zeolite powder 20B ventilation gap 3 present invention

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C04B 28/02 C04B 28/02 4G019 28/12 28/12 4G028 38/00 301 38/00 301Z 303 303Z 41/50 41/50 41/68 41/68 41/85 41/85 C E04B 1/64 E04B 1/64 D //(C04B 28/02 C04B 14:04 Z 14:04 14:02 B 14:02 14:38 Z 14:38 24:38 B 24:38) 111:40 111:40 Fターム(参考) 2E001 DB01 DB03 DB04 DH21 FA06 FA14 GA06 GA12 GA27 GA29 GA42 GA82 GA84 HA28 HC11 JA01 JA20 JA21 JB07 JC08 KA01 4C080 AA05 BB02 BB10 CC01 CC12 HH05 JJ03 KK08 LL02 LL10 MM04 NN01 NN22 NN23 NN24 4D052 AA10 CA02 CA09 HA00 HA03 HA39 4F100 AA00A AA00B AA00C AB01A AC04B AC04C AE01B AE01C AE20B AE20C AH08B AH08C AJ01A AJ04B AJ04C AK01A AT00A BA02 BA03 BA06 BA10B BA10C BA13 CB00B CB00C DE01B DE01C DG01A DG01B DG01C DG12A DG13A DJ00A EH46B EH46C GB08 JA20B JA20C JC00 JC00B JC00C JD02A JD14 JD15B JD15C YY00B YY00C 4G012 PA03 PA06 PA07 PA15 PA17 PA19 PA22 PA24 PA27 PB39 PB40 PC01 PC11 PD01 PD03 PE02 PE04 4G019 DA04 FA01 FA03 FA11 4G028 DB01 DB06 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C04B 28/02 C04B 28/02 4G019 28/12 28/12 4G028 38/00 301 38/00 301Z 303 303Z 41 / 50 41/50 41/68 41/68 41/85 41/85 C E04B 1/64 E04B 1/64 D // (C04B 28/02 C04B 14:04 Z 14:04 14:02 14:02 B 14:02 14 : 38 Z 14:38 24:38 B 24:38) 111: 40 111: 40 F term (reference) 2E001 DB01 DB03 DB04 DH21 FA06 FA14 GA06 GA12 GA27 GA29 GA42 GA82 GA84 HA28 HC11 JA01 JA20 JA21 JB07 JC08 KA01 4C080 AA05 BB02 BB10 CC01 CC12 HH05 JJ03 KK08 LL02 LL10 MM04 NN01 NN22 NN23 NN24 4D052 AA10 CA02 CA09 HA00 HA03 HA39 4F100 AA00A AA00B AA00C AB01A AC04B AC04C AE01B AE01C AE20B A04A01A01A04A04A01A01 DE01C DG01A DG01B DG01C DG12A DG13A DJ00A EH46B EH46C GB08 JA20B JA20C JC00 JC00B JC00C JD02A JD14 JD15B JD15C YY00B YY00C 4G012 PA03 PA06 PA07 PA15 PA17 PA01 FA01 PD02 FA03

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 通気性を有し且無機質多孔性素材からな
る基材の一側面若しくは両側面に、平均粒径が30μm
以下で少なくともその比表面積が70m/g以上及び
塩基置換容量(meg/100g)が200mg以上の
人工ゼオライト粉体が55乃至90%容量、セメント若
しくはドロマイトプラスターからなる固着材が7乃至2
5%容量、及びセルロース誘導体若しくはアルギン酸ナ
トリウム塩からなる接着剤が3乃至20%容量割合の組
成よりなる消臭調湿層が塗着形成されてなる消臭調湿板
材。
An average particle size of 30 μm on one side or both sides of a base material having air permeability and made of an inorganic porous material.
In the following, an artificial zeolite powder having a specific surface area of at least 70 m 2 / g and a base substitution capacity (meg / 100 g) of 200 mg or more has a capacity of 55 to 90%, and a cement or dolomite plaster has a fixing material of 7 to 2%.
A deodorizing and humidifying plate material formed by applying a deodorizing and humidity controlling layer having a composition of 5 to 20% by volume and an adhesive comprising a cellulose derivative or sodium alginate in a proportion of 3 to 20% by volume.
【請求項2】 基材が金属繊維、合成繊維、若しくは天
然繊維を織成若しくは編成させた織物地或いは編物地よ
りなり、且該基材が両側面に塗着形成される消臭調湿層
で挟持されてなる消臭調湿板材。
2. A deodorizing humidity control layer in which a base material is made of a woven or knitted fabric woven or knitted with metal fibers, synthetic fibers, or natural fibers, and the base material is coated on both sides. A deodorant humidity board material sandwiched between.
【請求項3】 消臭調湿層に無機繊維からなりその分径
が0.03mm以下で且適宜長さに切断されたチョップ
ドストランドが3乃至10%容量配合されてなる請求項
1若しくは請求項2記載の消臭調湿板材。
3. A chopped strand composed of inorganic fibers having a diameter of 0.03 mm or less and appropriately cut into lengths, wherein 3 to 10% by volume of the deodorizing humidity control layer is blended. 2. The deodorizing and adjusting wet plate material according to 2.
【請求項4】 人工ゼオライト粉体中にパーライト、シ
ラスバルーン、フライアッシュバルーンからなる無機発
泡材が10乃至30%容量割合で配合されてなる、請求
項1乃至請求項3記載の消臭調湿材。
4. The deodorizing and humidity controlling method according to claim 1, wherein the artificial zeolite powder is mixed with an inorganic foaming material composed of pearlite, shirasu balloon and fly ash balloon in a volume ratio of 10 to 30%. Wood.
JP2001163452A 2001-04-23 2001-04-23 Deodorizing humidity conditioning sheet material Pending JP2002321303A (en)

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Cited By (9)

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JP2004330095A (en) * 2003-05-08 2004-11-25 Matsushita Electric Ind Co Ltd Method for forming moisture absorbent layer
JP2009537703A (en) * 2006-05-18 2009-10-29 ハク リー、ジョン Earthen wallpaper
CN102093020A (en) * 2010-12-03 2011-06-15 吉林省志惠防腐保温工程有限公司 Special light-weight fireproof waterproof thermal-insulation slurry for polyurethane (PU)
JP2013014941A (en) * 2011-07-04 2013-01-24 Ishikawa:Kk Interior finishing board and construction method for the same
CN104857819A (en) * 2015-05-14 2015-08-26 汪培杰 Diatomite purification package
CN108191456A (en) * 2018-03-16 2018-06-22 江苏汉旭建材科技有限公司 A kind of building flooring sound insulation heat preservation board and preparation method thereof
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004330095A (en) * 2003-05-08 2004-11-25 Matsushita Electric Ind Co Ltd Method for forming moisture absorbent layer
JP2009537703A (en) * 2006-05-18 2009-10-29 ハク リー、ジョン Earthen wallpaper
CN102093020A (en) * 2010-12-03 2011-06-15 吉林省志惠防腐保温工程有限公司 Special light-weight fireproof waterproof thermal-insulation slurry for polyurethane (PU)
JP2013014941A (en) * 2011-07-04 2013-01-24 Ishikawa:Kk Interior finishing board and construction method for the same
CN104857819A (en) * 2015-05-14 2015-08-26 汪培杰 Diatomite purification package
JP2018121748A (en) * 2017-01-30 2018-08-09 吉澤石灰工業株式会社 Antibacterial deodorization agent and antibacterial deodorization method
CN108191456A (en) * 2018-03-16 2018-06-22 江苏汉旭建材科技有限公司 A kind of building flooring sound insulation heat preservation board and preparation method thereof
CN109650811A (en) * 2019-01-11 2019-04-19 济南大学 A kind of cement ceiling board of adjusting humidity and preparation method thereof
CN109650811B (en) * 2019-01-11 2021-04-09 济南大学 Humidity-adjustable cement ceiling board and preparation method thereof
CN112026310A (en) * 2019-08-09 2020-12-04 乐清市川嘉电气科技有限公司 Processing technology of impervious bentonite waterproof blanket

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