JP2002317367A - Nonwoven fabric suitable for rug - Google Patents
Nonwoven fabric suitable for rugInfo
- Publication number
- JP2002317367A JP2002317367A JP2001123340A JP2001123340A JP2002317367A JP 2002317367 A JP2002317367 A JP 2002317367A JP 2001123340 A JP2001123340 A JP 2001123340A JP 2001123340 A JP2001123340 A JP 2001123340A JP 2002317367 A JP2002317367 A JP 2002317367A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- nonwoven fabric
- melting point
- component
- fabric according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Carpets (AREA)
- Biological Depolymerization Polymers (AREA)
- Nonwoven Fabrics (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、耐摩耗性及びクッ
ション性に優れ、敷物として実用化できる不織布に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a nonwoven fabric which is excellent in abrasion resistance and cushioning property and can be put to practical use as a rug.
【0002】[0002]
【従来の技術】従来から、リサイクル可能なカーペット
として、熱融着繊維を使用し、ニードルパンチした不織
布を使用することが知られている(特開平6−1731
49号公報及び特開平5−115347号公報)。しか
し、これらの公報に記載されるような不織布は、熱融着
繊維を、ただ単に溶融してバインダーとして用いるだけ
であるため、摩耗による抜け毛等の問題があった。ま
た、全体的に均質な板状となるため、カーペットとして
の感触に欠け、実用性に乏しいものであった。2. Description of the Related Art Conventionally, it has been known to use a heat-bonded fiber and a needle-punched non-woven fabric as a recyclable carpet (Japanese Patent Laid-Open No. 6-1731).
49 and JP-A-5-115347). However, in the nonwoven fabrics described in these publications, the heat-fused fibers are simply melted and used as a binder. In addition, since it has a uniform plate shape as a whole, it lacks the feel of a carpet and is not practical.
【0003】[0003]
【発明が解決しようとする課題】本発明では、熱融着繊
維を使用した不織布であって、摩耗による抜け毛等の問
題がなく、敷物に好適な不織布、及び表裏で表情が異な
り、カーペットとして感触よく使用できる不織布を提供
することを課題とする。SUMMARY OF THE INVENTION The present invention relates to a non-woven fabric using heat-fusible fibers, which has no problem of hair loss due to abrasion, is suitable for a rug, and has a different expression on both sides, and has a touch as a carpet. It is an object to provide a nonwoven fabric that can be used well.
【0004】[0004]
【課題を解決するための手段】本発明では、熱融着繊維
を使用し、ニードルパンチした不織布において、使用す
る繊維の組み合わせを工夫し、スパイラル状に捲縮した
繊維を表面側に存在させることにより上記課題を解決し
た。SUMMARY OF THE INVENTION In the present invention, in a nonwoven fabric which has been subjected to needle punching using heat-fused fibers, a combination of fibers to be used is devised so that fibers crimped in a spiral form are present on the surface side. Solved the above problem.
【0005】本発明の不織布は、融点の異なる2種の熱
可塑性樹脂成分からなる複合繊維Aと、前記熱可塑性成
分の低融点成分より高い融点を有する繊維Bとからな
り、前記複合繊維Aの低融点成分の溶融により一体化さ
れた短繊維不織布であって、前記複合繊維Aが前記繊維
Bに比して繊度が小さく、かつ前記複合繊維Aの少なく
とも一部がスパイラル状に捲縮していることを特徴とす
る。[0005] The nonwoven fabric of the present invention comprises a composite fiber A comprising two kinds of thermoplastic resin components having different melting points, and a fiber B having a higher melting point than the low melting point component of the thermoplastic component. A short-fiber nonwoven fabric integrated by melting a low-melting-point component, wherein the composite fiber A has a smaller fineness than the fiber B, and at least a part of the composite fiber A is crimped in a spiral shape. It is characterized by being.
【0006】かかる不織布に用いられる複合繊維Aとし
ては、いわゆる貼り合わせ構造(サイド・バイ・サイド
型)及び芯鞘構造があり、芯鞘構造の場合には鞘を低融
点成分とする。このうち、芯鞘構造のものの方が、ニー
ドルパンチによる繊維の割れの問題が生じにくいため好
ましく、中でも偏心型の芯鞘構造からなるものを使用す
るのが好ましい。偏心型であると、熱処理後の捲縮率が
高く、容易にスパイラル状となるからである。As the composite fiber A used for such a nonwoven fabric, there are a so-called bonded structure (side-by-side type) and a core-sheath structure. In the case of the core-sheath structure, the sheath is a low melting point component. Among them, the core-sheath structure is preferable because the problem of fiber breakage due to the needle punch hardly occurs, and among them, the one having the eccentric core-sheath structure is preferable. This is because the eccentric type has a high crimp ratio after heat treatment and easily becomes a spiral shape.
【0007】スパイラル状に捲縮した複合繊維Aの平均
捲縮数は、少なくとも20ケ/25.4mmであるのが
好ましく、更に40ケ/25.4mm以上、特に80ケ
/25.4mm以上であるのがよい。捲縮数が多いほ
ど、敷物として用いた際の耐摩耗性及びクッション性に
優れるからである。The average number of crimps of the spirally crimped conjugate fiber A is preferably at least 20 / 25.4 mm, more preferably 40 / 25.4 mm or more, particularly 80 / 25.4 mm or more. There should be. This is because the greater the number of crimps, the better the abrasion resistance and cushioning properties when used as a rug.
【0008】スパイラル状に捲縮した複合繊維Aの数
は、少なくとも不織布の一方の表面において、25ケ/
cm2 以上の割合で存在していることが好ましい。捲縮
繊維の割合が多いほど、敷物として用いた際の耐摩耗性
及びクッション性に優れるからである。この捲縮した繊
維の個数は、電子顕微鏡観察により測定することができ
る。[0008] The number of the composite fibers A crimped in a spiral shape is at least 25
It is preferably present in a proportion of at least cm 2 . This is because the greater the proportion of crimped fibers, the better the abrasion resistance and cushioning properties when used as a rug. The number of the crimped fibers can be measured by observation with an electron microscope.
【0009】なお、この捲縮の発現(スパイラル化)
は、複合繊維Aの熱処理温度(低融点成分を溶融するた
めの温度)を、複合繊維Aの高融点成分の融点近くまで
上げることによって、特に効果的に得られるものであ
る。具体的には、低融点成分の融点を(a)℃、高融点
成分の融点を(b)℃とした場合に、熱処理温度(x)
℃を下記式を満たすものとするのが好ましい。 . (a)+10≦(x)<(b)[0009] Expression of this crimp (spiralization)
Can be obtained particularly effectively by increasing the heat treatment temperature (temperature for melting the low melting point component) of the conjugate fiber A to near the melting point of the high melting point component of the conjugate fiber A. Specifically, when the melting point of the low melting point component is (a) ° C. and the melting point of the high melting point component is (b) ° C., the heat treatment temperature (x)
It is preferred that the temperature satisfies the following equation. . (A) + 10 ≦ (x) <(b)
【0010】複合繊維Aとして、繊維Bに比して小さい
繊度を有するものを用い、ニードルによりウエッブを貫
く上下運動のうち、敷物の表面となる側に向かって貫く
回数を、逆向きの回数より多くすることで、不織布の一
方の側(敷物の表側)で、繊度が小さい複合繊維Aの密
度が高まり、そこで複合繊維Aを繊維Bに点接着させた
状態で、強く捲縮させることができるため、不織布の敷
物の表側となる面は実質的に平坦であるが、その反対側
は、毛羽立つ感触を有するものとなる。As the composite fiber A, a fiber having a fineness smaller than that of the fiber B is used, and the number of times that the needle penetrates toward the surface of the rug in the up-and-down motion of penetrating the web is determined by the number of times of the reverse direction. By doing so, the density of the composite fiber A having a small fineness increases on one side of the nonwoven fabric (the front side of the rug), and the composite fiber A can be strongly crimped in a state where the composite fiber A is point-bonded to the fiber B. Therefore, the surface on the front side of the nonwoven rug is substantially flat, but the opposite side has a fluffy feel.
【0011】本発明の不織布を構成する糸の材質は特に
限定されないが、車両用又は催物会場用等の各種敷物と
して使用し、使用後、環境問題を生ずることなく廃物処
理するためには、全体に同一素材からなるものとするの
が好ましい。The material of the yarn constituting the nonwoven fabric of the present invention is not particularly limited. However, in order to use it as various rugs for vehicles or entertainment venues and to treat waste without causing environmental problems after use, It is preferable to use the same material.
【0012】本発明では、特に、不織布を構成する繊
維、すなわち前記複合繊維A及び繊維B共に、ポリ乳酸
系繊維からなるものとすることにより、生分解性を有す
る不織布として、廃物処理の問題なく、広く敷物類に使
用できる製品を得ることが可能となる。ここに、ポリ乳
酸系繊維とは、乳酸モノマー単独からなるポリ乳酸繊維
だけでなく、生分解性を阻害しない範囲で、他の成分を
ブレンドまたは共重合して得た繊維も含まれる。In the present invention, in particular, the fibers constituting the nonwoven fabric, that is, the composite fibers A and B are both made of polylactic acid-based fibers, so that the biodegradable nonwoven fabric can be processed without waste. Thus, it is possible to obtain products that can be widely used for rugs. Here, the polylactic acid-based fiber includes not only a polylactic acid fiber composed solely of a lactic acid monomer, but also a fiber obtained by blending or copolymerizing other components as long as biodegradability is not impaired.
【0013】従来、ポリ乳酸系繊維は、たとえばポリエ
チレンテレフタレート系繊維に比べて、脆く繊維が切れ
やすく、捲縮弾性率が低く、嵩が出難く、クッション性
に乏しいので、敷物類に適用できるとは考えられていな
かったが、本発明では、たとえば芯及び鞘共にポリ乳酸
系成分からなる芯鞘構造の複合繊維Aと、その芯成分と
ほぼ同一の融点を有するポリ乳酸系の繊維Bを組み合わ
せて使用し、しかも複合繊維Aをサイド・バイ・サイド
に近いような偏心型の芯鞘構造とし、不織布製造におけ
る熱処理温度を、複合繊維Aの芯成分の融点近くまで
(芯成分の融点との差が5〜15℃、特に7〜13℃程
度となるまで)高めることによって、複合繊維Aを繊維
Bに点接着させた状態で、強く捲縮させることができ、
その結果全体にポリ乳酸系繊維からなる不織布でありな
がら、実用性ある耐摩耗性とクッション性を有する敷物
に適した製品となることを可能とした。[0013] Conventionally, polylactic acid-based fibers are brittle and tend to break fibers, have low crimp elasticity, are hardly bulky, and have poor cushioning properties, compared to, for example, polyethylene terephthalate-based fibers. However, in the present invention, for example, a composite fiber A having a core-sheath structure composed of a polylactic acid-based component in both the core and the sheath, and a polylactic acid-based fiber B having a melting point substantially equal to that of the core component are combined. The composite fiber A has an eccentric core-sheath structure in which the composite fiber A is close to side-by-side, and the heat treatment temperature in the production of the nonwoven fabric is set close to the melting point of the core component of the composite fiber A (with the melting point of the core component). By increasing the difference (until the difference is about 5 to 15 ° C., particularly about 7 to 13 ° C.), the composite fiber A can be strongly crimped in a state where the composite fiber A is adhered to the fiber B,
As a result, it has become possible to provide a practically suitable product for a rug having abrasion resistance and cushioning properties even though it is a nonwoven fabric made entirely of polylactic acid-based fibers.
【0014】この場合、複合繊維Aと繊維Bの混合率は
特に限定されないが、重量比率で、10〜50:90〜
50であるのが好ましく、特に、20〜30:80〜7
0程度であるのが好ましい。In this case, the mixing ratio of the conjugate fiber A and the fiber B is not particularly limited, but is 10 to 50:90 by weight.
Preferably, it is 50, especially 20-30: 80-7.
It is preferably about 0.
【0015】本発明の不織布は、ゴム硬度計で測定した
際、不織布の平均表面硬度が、表裏で異なることが好ま
しく、例えば、後述の測定方法による硬度差が2.0以
上であるのが好ましく、更に好ましくは3.0以上、特
に好ましくは4.0以上である。In the nonwoven fabric of the present invention, when measured with a rubber hardness tester, the average surface hardness of the nonwoven fabric is preferably different between the front and back sides. For example, the difference in hardness by a measurement method described later is preferably 2.0 or more. , More preferably 3.0 or more, and particularly preferably 4.0 or more.
【0016】また、複合繊維Aと繊維Bの繊度は、前者
が後者の1/2〜1/6程度であるのが好ましく、特
に、複合繊維Aの単糸繊度が2〜4dtexであるのが
好ましい。The fineness of the conjugate fiber A and the fiber B is preferably about 1/2 to 1/6 of the former, and particularly, the single fiber fineness of the conjugate fiber A is 2 to 4 dtex. preferable.
【0017】[0017]
【発明の実施の形態】本発明の実施例を次に示す。な
お、実施例において%とあるのは、特に断らない限り、
重量%を示す。また、実施例に先だって、実施例で製造
した不織布の物性の測定・評価方法を以下に記載する。DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiments of the present invention will be described below. In Examples, “%” means “%” unless otherwise specified.
Indicate weight%. Prior to the examples, methods for measuring and evaluating physical properties of the nonwoven fabric produced in the examples are described below.
【0018】(耐摩耗性試験方法) JIS L1023−9 回転数1000回(Abrasion resistance test method) JIS L1023-9 1000 rotations
【0019】(不織布の厚さ) JIS L1021−7.2.1 1.96kPa,加圧子10cm2 (Thickness of non-woven fabric) JIS L1021-7.2.1 1.96 kPa, pressurizer 10 cm 2
【0020】(不織布の目付) JIS L1021−7.3.1(The basis weight of the nonwoven fabric) JIS L1021-7.3.1
【0021】(平均表面硬度)アスカーゴム硬度計(高
分子計器)F型を用い、測定する。(Average surface hardness) Measured using an Asker rubber hardness meter (polymer meter), type F.
【0022】(防炎性)消防法施行規則S36.4.1
自治省令第6号 第4条の3(5)(Flameproof) Fire Service Law Enforcement Regulation S36.4.1
Ministry of Home Affairs Ordinance No. 6 Article 4-3 (5)
【0023】実施例1 融点130℃のポリ乳酸を鞘成分とし、融点170℃の
ポリ乳酸を芯成分とした単糸繊度が3.3dtex、繊
維長が51mmである芯鞘構造の複合繊維Aと、融点1
70℃のポリ乳酸系繊維で単糸繊度が11dtex、繊
維長が64mmである繊維Bを、重量比率で20:80
の割合で混綿し、カード機、クロスレイヤー処理し、裏
面側からニードルパンチした。そして、得られたシート
を160℃で3分熱処理して、目付400g/m2 、厚
さ3.5mmの不織布を得た。この不織布は、一方の面
(敷物とした際の表面)が平坦で、耐摩耗性試験におけ
る減量が18mgで、敷物としての実用の基準である5
0mg以下という条件を充分にクリアするものであっ
た。また、他面(敷物とした際の裏面)側には、毛羽立
ちが認められ、外観及びクッション性のよいカーペット
として使用できるものとなった。Example 1 A composite fiber A having a core-sheath structure having a single-filament fineness of 3.3 dtex and a fiber length of 51 mm using polylactic acid having a melting point of 130 ° C. as a sheath component and polylactic acid having a melting point of 170 ° C. as a core component was used. , Melting point 1
A fiber B having a polylactic acid-based fiber of 70 ° C. and a single fiber fineness of 11 dtex and a fiber length of 64 mm was used in a weight ratio of 20:80.
, Mixed with a card machine, cross-layered, and needle-punched from the back side. The obtained sheet was heat-treated at 160 ° C. for 3 minutes to obtain a nonwoven fabric having a basis weight of 400 g / m 2 and a thickness of 3.5 mm. This nonwoven fabric has a flat surface on one side (a surface when used as a rug), a weight loss of 18 mg in an abrasion resistance test, which is a standard for practical use as a rug.
The condition of 0 mg or less was sufficiently cleared. On the other side (the back side of the rug), fluffing was observed, and the carpet could be used as a carpet having good appearance and cushioning properties.
【0024】この不織布の平均表面硬度は、表側が7
8.0、裏側が71.8であり、この硬度差は、6.2
であった。The average surface hardness of this nonwoven fabric was 7 on the front side.
8.0, the back side is 71.8, and this hardness difference is 6.2.
Met.
【0025】また、この製品は、消防法の防炎基準を満
たし、インテリア床材防炎性に優れるものであった。This product also meets the fire protection standards of the Fire Service Law and has excellent fire resistance to interior flooring materials.
【0026】更に、この製品は、全体に生分解性に優れ
たポリ乳酸系繊維からなるため、使用後の処理も、環境
汚染を心配することなく実施できるので、催物会場のカ
ーペット等として非常に有用である。Furthermore, since this product is entirely made of polylactic acid-based fiber having excellent biodegradability, the treatment after use can be carried out without worrying about environmental pollution. Useful.
【0027】[0027]
【発明の効果】本発明の不織布には、繊度の小さい熱接
着性複合繊維Aがスパイラル状に捲縮したものが存在す
る。そのため、本発明の不織布は、耐摩耗性に優れた、
敷物に適した不織布となる。また、捲縮した繊維を、表
側に偏らせた場合には、当該面は平坦となるため、他の
素材と接着したりすることも容易であり、しかも、表側
には、繊度の小さい複合繊維Aがスパイラル状に捲縮し
たものが存在するため、薄い不織布であっても、特に、
反撥性(クッション性)のある製品となる。特に、不織
布全体を生分解性あるポリ乳酸系繊維からなるものとす
ることも可能で、この場合には、後処理の心配がないの
で、使い捨ての敷物として広く実用化できるので、屋内
の敷物だけでなく、農業用シートや植生シート等として
使用することも可能である。The nonwoven fabric of the present invention includes a thermoadhesive conjugate fiber A having a small fineness which is crimped in a spiral shape. Therefore, the nonwoven fabric of the present invention has excellent abrasion resistance,
It becomes a nonwoven fabric suitable for rugs. In addition, when the crimped fiber is biased to the front side, the surface becomes flat, so that it is easy to adhere to other materials, and the front side is a composite fiber having a small fineness. Since A has a crimped spiral shape, even a thin nonwoven fabric,
The product has repulsion (cushioning properties). In particular, the entire nonwoven fabric can be made of biodegradable polylactic acid-based fiber. In this case, since there is no need to worry about post-treatment, it can be widely used as a disposable rug. Instead, it can be used as an agricultural sheet or a vegetation sheet.
───────────────────────────────────────────────────── フロントページの続き (72)発明者 大野 守彦 岐阜県海津郡南濃町津屋1511番地 サンケ ミカル株式会社内 (72)発明者 古河 陽一 岐阜県海津郡南濃町津屋1511番地 サンケ ミカル株式会社内 Fターム(参考) 3B120 AA14 EB11 EB18 4L047 AA21 AA27 AA28 AB02 AB07 AB09 BA03 BA09 BA24 BB09 CA13 CB01 CB05 CC10 ──────────────────────────────────────────────────続 き Continuing from the front page (72) Inventor Morihiko Ono 1511 Tsuya, Minanomachi, Kaizu-gun, Gifu Prefecture (72) Inventor Yoichi Furukawa 1511 Tsuya, Minanomachi, Kazu-gun, Gifu Prefecture F within Sanke Mical Corporation Terms (reference) 3B120 AA14 EB11 EB18 4L047 AA21 AA27 AA28 AB02 AB07 AB09 BA03 BA09 BA24 BB09 CA13 CB01 CB05 CC10
Claims (11)
らなる複合繊維Aと、前記熱可塑性成分の低融点成分よ
り高い融点を有する繊維Bとからなり、前記複合繊維A
の低融点成分の溶融により一体化された短繊維不織布で
あって、前記複合繊維Aが前記繊維Bに比して繊度が小
さく、かつ前記複合繊維Aの少なくとも一部がスパイラ
ル状に捲縮していることを特徴とする不織布。1. A composite fiber A comprising a composite fiber A comprising two kinds of thermoplastic resin components having different melting points, and a fiber B having a melting point higher than a low melting point component of the thermoplastic component.
Is a short fiber non-woven fabric integrated by melting of the low melting point component, wherein the composite fiber A has a smaller fineness than the fiber B, and at least a part of the composite fiber A is crimped in a spiral shape. Nonwoven fabric characterized by having.
均捲縮数が、少なくとも20ケ/25.4mmであるこ
とを特徴とする請求項1の不織布。2. The nonwoven fabric according to claim 1, wherein the average number of crimps of the spirally crimped conjugate fiber A is at least 20 / 25.4 mm.
少なくとも一方の表面において、25ケ/cm2 以上の
割合で存在していることを特徴とする請求項1または2
の不織布。3. The conjugate fiber A spirally crimped,
3. The composition according to claim 1, wherein at least one surface is present at a rate of 25 pcs / cm 2 or more.
Nonwoven.
であることを特徴とする請求項1〜3いずれか1項の不
織布。4. The nonwoven fabric according to claim 1, wherein the conjugate fiber A has a core-sheath structure.
も、ポリ乳酸系繊維からなるものであることを特徴とす
る請求項1〜4いずれか1項の不織布。5. The nonwoven fabric according to claim 1, wherein both the conjugate fiber A and the fiber B are made of a polylactic acid-based fiber.
比率で、10〜50:90〜50であることを特徴とす
る請求項1〜5いずれか1項の不織布。6. The nonwoven fabric according to claim 1, wherein a mixing ratio of the conjugate fiber A and the fiber B is 10 to 50:90 to 50 by weight.
表面には毛羽立ちが認められることを特徴とする請求項
1〜6いずれか1項の不織布。7. The nonwoven fabric according to claim 1, wherein one surface is substantially smooth and the other surface is fuzzed.
表面硬度が、表裏で異なることを特徴とする請求項1〜
7いずれか1項の不織布。8. The non-woven fabric according to claim 1, wherein the average surface hardness of the nonwoven fabric is different between the front and back sides when measured with a rubber hardness tester.
7. The nonwoven fabric according to any one of 7.
らなることを特徴とする敷物。9. A rug comprising the nonwoven fabric according to any one of claims 1 to 8.
からなる複合繊維Aと、前記熱可塑性成分の低融点成分
より高い融点を有する繊維Bとからなるウエッブをニー
ドルパンチし、その後、前記低融点成分の融点以上の温
度で熱処理して短繊維不織布を製造する方法において、
前記熱可塑性成分の低融点成分の融点を(a)℃、高融
点成分の融点を(b)℃とした場合に、前記不織布の熱
処理温度(x)℃を下記式を満たすものとすることを特
徴とする、不織布の製造方法。 . (a)+10≦(x)<(b)10. A web made of a composite fiber A comprising two kinds of thermoplastic resin components having different melting points and a fiber B having a melting point higher than a low melting point component of the thermoplastic component is needle-punched. In a method of producing a short fiber nonwoven fabric by heat treatment at a temperature equal to or higher than the melting point of the melting point component,
When the melting point of the low melting point component of the thermoplastic component is (a) ° C. and the melting point of the high melting point component is (b) ° C., the heat treatment temperature (x) ° C. of the nonwoven fabric should satisfy the following formula. A method for producing a nonwoven fabric, which is characterized by the following. . (A) + 10 ≦ (x) <(b)
からなる複合繊維Aと、前記熱可塑性成分の低融点成分
より高い融点を有する繊維Bとからなるウエッブをニー
ドルパンチし、その後、前記低融点成分の融点以上の温
度で熱処理して短繊維不織布を製造する方法において、
前記複合繊維Aとして、前記繊維Bに比して小さい繊度
を有するものを使用し、ニードルによりウエッブを貫く
上下運動のうち、敷物の表面となる側に向かって貫く回
数を、逆向きの回数より多くすることを特徴とする、請
求項10の不織布の製造方法。11. A web comprising a composite fiber A comprising two kinds of thermoplastic resin components having different melting points and a fiber B having a melting point higher than a low melting point component of the thermoplastic component is needle-punched. In a method of producing a short fiber nonwoven fabric by heat treatment at a temperature equal to or higher than the melting point of the melting point component,
As the conjugate fiber A, a fiber having a fineness smaller than that of the fiber B is used, and the number of times the needle moves through the web toward the surface serving as the surface of the rug in the up and down movement of the needle is smaller than the number of times of the reverse direction. The method for producing a nonwoven fabric according to claim 10, wherein the number is increased.
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JP2001123340A JP4711033B2 (en) | 2001-04-20 | 2001-04-20 | Nonwoven fabric suitable for rugs |
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JP2001123340A JP4711033B2 (en) | 2001-04-20 | 2001-04-20 | Nonwoven fabric suitable for rugs |
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JP2002317367A true JP2002317367A (en) | 2002-10-31 |
JP4711033B2 JP4711033B2 (en) | 2011-06-29 |
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JP2001123340A Expired - Fee Related JP4711033B2 (en) | 2001-04-20 | 2001-04-20 | Nonwoven fabric suitable for rugs |
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US8850719B2 (en) | 2009-02-06 | 2014-10-07 | Nike, Inc. | Layered thermoplastic non-woven textile elements |
US8906275B2 (en) | 2012-05-29 | 2014-12-09 | Nike, Inc. | Textured elements incorporating non-woven textile materials and methods for manufacturing the textured elements |
US9227363B2 (en) | 2009-02-06 | 2016-01-05 | Nike, Inc. | Thermoplastic non-woven textile elements |
US9579848B2 (en) | 2009-02-06 | 2017-02-28 | Nike, Inc. | Methods of joining textiles and other elements incorporating a thermoplastic polymer material |
US11779071B2 (en) | 2012-04-03 | 2023-10-10 | Nike, Inc. | Apparel and other products incorporating a thermoplastic polymer material |
Families Citing this family (1)
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US10982363B2 (en) | 2009-02-06 | 2021-04-20 | Nike, Inc. | Thermoplastic non-woven textile elements |
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