JP2002313811A5 - - Google Patents

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JP2002313811A5
JP2002313811A5 JP2002020801A JP2002020801A JP2002313811A5 JP 2002313811 A5 JP2002313811 A5 JP 2002313811A5 JP 2002020801 A JP2002020801 A JP 2002020801A JP 2002020801 A JP2002020801 A JP 2002020801A JP 2002313811 A5 JP2002313811 A5 JP 2002313811A5
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semiconductor film
semiconductor
semiconductor device
manufacturing
barrier layer
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絶縁表面上に結晶構造を有する半導体膜が形成さ、前記半導体膜に含まれる酸素の濃度は5×1018/cm3以下であり、前記半導体膜の内部において、希ガス元素が1×1013〜1×1020/cm3の濃度で含まれている領域を有することを特徴とする半導体装置。A semiconductor film having a crystalline structure on an insulating surface is formed, the concentration of oxygen contained in the semiconductor film is 5 × 10 18 / cm 3 and less, Oite the inner portion of the semiconductor film, a rare gas element is A semiconductor device having a region included at a concentration of 1 × 10 13 to 1 × 10 20 / cm 3 . 絶縁表面上に結晶構造を有する半導体膜が形成さ、前記半導体膜は細い棒状又は細い扁平棒状結晶であり、前記半導体膜に含まれる酸素の濃度は5×1018/cm3以下であり、前記半導体膜の内部において、希ガス元素が1×1013〜1×1020/cm3の濃度で含まれている領域を有することを特徴とする半導体装置。A semiconductor film having a crystalline structure on an insulating surface is formed, the semiconductor film is a thin rod-like or thin flat rod-shaped crystals, the concentration of oxygen contained in said semiconductor film is 5 × 10 18 / cm 3 and less, the Oite the inner portion of the semiconductor film, a semiconductor device characterized by having a region that contains a concentration of the rare gas element is 1 × 10 13 ~1 × 10 20 / cm 3. 絶縁表面上に結晶構造を有する半導体膜と、ゲート絶縁膜と、ゲート電極とを有、前記半導体膜は、前記ゲート電極と重なる領域において、酸素を5×1018/cm3以下の濃度で含み、かつ、前記半導体膜の内部において、希ガス元素が1×1013〜1×1020/cm3の濃度で含まれている領域を有することを特徴とする半導体装置。A semiconductor film having a crystalline structure on an insulating surface, possess a gate insulating film, a gate electrode, the semiconductor film in a region overlapping with the gate electrode, oxygen at a concentration of 5 × 10 18 / cm 3 or less wherein, and a semiconductor device which comprises said Oite the inner portion of the semiconductor film, the region rare gas element is contained at a concentration of 1 × 10 13 ~1 × 10 20 / cm 3. 絶縁表面上に結晶構造を有する半導体膜と、ゲート絶縁膜と、ゲート電極とを有、前記半導体膜は、細い棒状又は細い扁平棒状結晶であり、前記ゲート電極と重なる領域において、酸素を5×1018/cm3以下の濃度で含み、かつ、前記半導体膜の内部において、希ガス元素が1×1013〜1×1020/cm3の濃度で含まれている領域を有することを特徴とする半導体装置。A semiconductor film having a crystalline structure on an insulating surface, possess a gate insulating film, a gate electrode, said semiconductor film is a thin rod-like or thin flattened rod-like crystals in a region overlapping with the gate electrode, oxygen 5 × includes 10 18 / cm 3 at a concentration, and has a region Oite the internal, rare gas element is contained at a concentration of 1 × 10 13 ~1 × 10 20 / cm 3 of the semiconductor film A semiconductor device. 請求項1乃至4のいずれか一において、前記希ガス元素はHe、Ne、Ar、Kr、Xeから選ばれた一種または複数種であることを特徴とする半導体装置。In any one of claims 1乃optimum 4, wherein the rare gas element is a semiconductor device comprising He, Ne, Ar, Kr, that is one or more kinds selected from Xe. 絶縁表面を有する基板上にシリコンを主成分とし非晶質構造を有する第1の半導体膜を形成
前記第1の半導体膜にシリコンの結晶化を助長する触媒元素を添加して、第1の加熱処理により結晶構造を有する第1の半導体膜を形成
前記結晶構造を有する第1の半導体膜の表面にバリア層を形成
前記バリア層上に第2の半導体膜を成膜
前記第2の半導体膜に希ガス元素を前記成膜と同時又はその後に添加して、第2の加熱処理によりゲッタリングを行い前記触媒元素を前記第2の半導体膜に移動さ
前記第2の半導体膜を除去
前記バリア層を除去することを特徴とする半導体装置の作製方法。
As a main component silicon over a substrate having an insulating surface to form a first semiconductor film having an amorphous structure,
By adding a catalyst element for promoting crystallization of silicon in the first semiconductor film, a first semiconductor film having a crystalline structure is formed by the first heat treatment,
Forming a barrier layer on the surface of the first semiconductor film having the crystal structure;
The second semiconductor film is formed on the barrier layer,
Was added a rare gas element in the second semiconductor layer on the deposition and simultaneously or thereafter, the catalyst element carried gettering is moved to the second semiconductor film by the second heat treatment,
Removing the second semiconductor layer,
The method for manufacturing a semiconductor device comprising the Turkey to remove the barrier layer.
絶縁表面を有する基板上にシリコンを主成分とし非晶質構造を有する第1の半導体膜を形成
前記第1の半導体膜にシリコンの結晶化を助長する触媒元素を添加して、第1の加熱処理により結晶構造を有する第1の半導体膜を形成
前記結晶構造を有する第1の半導体膜レーザー光を照射
前記結晶構造を有する第1の半導体膜の表面にバリア層を形成
前記バリア層上に第2の半導体膜を成膜
前記第2の半導体膜に希ガス元素を前記成膜と同時又はその後に添加して、第2の加熱処理によりゲッタリングを行い前記触媒元素を前記第2の半導体膜に移動さ
前記第2の半導体膜を除去
前記バリア層を除去することを特徴とする半導体装置の作製方法。
As a main component silicon over a substrate having an insulating surface to form a first semiconductor film having an amorphous structure,
By adding a catalyst element for promoting crystallization of silicon in the first semiconductor film, a first semiconductor film having a crystalline structure is formed by the first heat treatment,
Irradiating the first semiconductor film laser beam having a crystal structure,
Forming a barrier layer on the surface of the first semiconductor film having the crystal structure;
The second semiconductor film is formed on the barrier layer,
Was added a rare gas element in the second semiconductor layer on the deposition and simultaneously or thereafter, the catalyst element carried gettering is moved to the second semiconductor film by the second heat treatment,
Removing the second semiconductor layer,
The method for manufacturing a semiconductor device comprising the Turkey to remove the barrier layer.
絶縁表面を有する基板上にシリコンを主成分とし非晶質構造を有する第1の半導体膜を形成し、Forming a first semiconductor film containing silicon as a main component and having an amorphous structure over a substrate having an insulating surface;
前記第1の半導体膜にシリコンの結晶化を助長する触媒元素を添加して、第1の加熱処理により結晶構造を有する第1の半導体膜を形成し、Adding a catalyst element for promoting crystallization of silicon to the first semiconductor film, and forming a first semiconductor film having a crystal structure by a first heat treatment;
前記結晶構造を有する第1の半導体膜の表面にバリア層を形成し、Forming a barrier layer on the surface of the first semiconductor film having the crystal structure;
前記バリア層上に第2の半導体膜を成膜し、Forming a second semiconductor film on the barrier layer;
前記第2の半導体膜に希ガス元素を前記成膜と同時又はその後に添加して、第2の加熱処理によりゲッタリングを行い前記触媒元素を前記第2の半導体膜に移動させ、A rare gas element is added to the second semiconductor film simultaneously with or after the film formation, and gettering is performed by a second heat treatment to move the catalyst element to the second semiconductor film,
前記第2の半導体膜を除去し、Removing the second semiconductor film;
前記バリア層を除去し、Removing the barrier layer;
前記結晶構造を有する第1の半導体膜にレーザー光を照射することを特徴とする半導体装置の作製方法。A method for manufacturing a semiconductor device, wherein the first semiconductor film having the crystal structure is irradiated with laser light.
請求項6乃至8いずれか一において、前記第1の加熱処理は、ハロゲンランプ、メタルハライドランプ、キセノンアークランプ、カーボンアークランプ、高圧ナトリウムランプ、高圧水銀ランプから選ばれた一種または複数種からの輻射により行うことを特徴とする半導体装置の作製方法。9. The heat treatment according to claim 6 , wherein the first heat treatment includes radiation from one or more kinds selected from a halogen lamp, a metal halide lamp, a xenon arc lamp, a carbon arc lamp, a high pressure sodium lamp, and a high pressure mercury lamp. A method for manufacturing a semiconductor device, characterized in that: 請求項6乃至8いずれか一において、前記第1の加熱処理は、電熱炉を用いたファーネスアニール法により行うことを特徴とする半導体装置の作製方法。9. The method for manufacturing a semiconductor device according to claim 6 , wherein the first heat treatment is performed by a furnace annealing method using an electric furnace. 請求項6乃至10いずれか一において、前記第2の加熱処理は、ハロゲンランプ、メタルハライドランプ、キセノンアークランプ、カーボンアークランプ、高圧ナトリウムランプ、高圧水銀ランプから選ばれた一種または複数種からの輻射により行うことを特徴とする半導体装置の作製方法。11. The heat treatment according to claim 6 , wherein the second heat treatment includes radiation from one or more kinds selected from a halogen lamp, a metal halide lamp, a xenon arc lamp, a carbon arc lamp, a high pressure sodium lamp, and a high pressure mercury lamp. A method for manufacturing a semiconductor device, characterized in that: 請求項6乃至10いずれか一において、前記第2の加熱処理は、電熱炉を用いたファーネスアニール法により行うことを特徴とする半導体装置の作製方法。11. The method for manufacturing a semiconductor device according to claim 6 , wherein the second heat treatment is performed by a furnace annealing method using an electric furnace. 絶縁表面を有する基板にシリコンを主成分とし非晶質構造を有する第1の半導体膜を形成し、Forming a first semiconductor film containing silicon as a main component and having an amorphous structure over a substrate having an insulating surface;
前記非晶質構造を有する第1の半導体膜にシリコンの結晶化を助長する触媒元素を添加し、Adding a catalyst element for promoting crystallization of silicon to the first semiconductor film having the amorphous structure;
前記非晶質構造を有する第1の半導体膜の表面にバリア層を形成し、Forming a barrier layer on the surface of the first semiconductor film having the amorphous structure;
前記バリア層上に第2の半導体膜を成膜し、Forming a second semiconductor film on the barrier layer;
前記第2の半導体膜に希ガス元素を前記成膜と同時又はその後に添加し、Adding a rare gas element to the second semiconductor film simultaneously with or after the film formation;
加熱処理により、前記非晶質構造を有する第1の半導体膜を結晶化させ結晶構造を有する第1の半導体膜を形成すると共に前記触媒元素を前記第2の半導体膜に移動させ、By heat treatment, the first semiconductor film having an amorphous structure is crystallized to form a first semiconductor film having a crystalline structure, and the catalytic element is moved to the second semiconductor film,
前記第2の半導体膜を除去し、Removing the second semiconductor film;
前記バリア層を除去し、Removing the barrier layer;
前記結晶構造を有する第1の半導体膜にレーザー光を照射することを特徴とする半導体装置の作製方法。A method for manufacturing a semiconductor device, wherein the first semiconductor film having the crystal structure is irradiated with laser light.
絶縁表面上にシリコンの結晶化を助長する触媒元素を添加し、Add a catalytic element to promote crystallization of silicon on the insulating surface,
前記絶縁表面を有する基板にシリコンを主成分とし非晶質構造を有する第1の半導体膜を形成し、Forming a first semiconductor film containing silicon as a main component and having an amorphous structure on the substrate having an insulating surface;
前記非晶質構造を有する第1の半導体膜の表面にバリア層を形成し、Forming a barrier layer on the surface of the first semiconductor film having the amorphous structure;
前記非晶質構造を有する第1の半導体膜上に第2の半導体膜を成膜し、Forming a second semiconductor film on the first semiconductor film having the amorphous structure;
前記第2の半導体膜に希ガス元素を前記成膜と同時又はその後に添加し、Adding a rare gas element to the second semiconductor film simultaneously with or after the film formation;
加熱処理により、前記非晶質構造を有する第1の半導体膜を結晶化させ結晶構造を有する第1の半導体膜を形成すると共に前記触媒元素を前記第2の半導体膜に移動させ、By heat treatment, the first semiconductor film having an amorphous structure is crystallized to form a first semiconductor film having a crystalline structure, and the catalytic element is moved to the second semiconductor film,
前記第2の半導体膜を除去し、Removing the second semiconductor film;
前記バリア層を除去し、Removing the barrier layer;
前記結晶構造を有する第1の半導体膜にレーザー光を照射することを特徴とする半導体装置の作製方法。A method for manufacturing a semiconductor device, wherein the first semiconductor film having the crystal structure is irradiated with laser light.
請求項13又は請求項14において、前記加熱処理は、ハロゲンランプ、メタルハライドランプ、キセノンアークランプ、カーボンアークランプ、高圧ナトリウムランプ、高圧水銀ランプから選ばれた一種または複数種からの輻射により行うことを特徴とする半導体装置の作製方法。In Claim 13 or Claim 14, the heat treatment is performed by radiation from one or more kinds selected from a halogen lamp, a metal halide lamp, a xenon arc lamp, a carbon arc lamp, a high pressure sodium lamp, and a high pressure mercury lamp. A method for manufacturing a semiconductor device. 請求項13又は請求項14において、前記加熱処理は、電熱炉を用いたファーネスアニール法により行うことを特徴とする半導体装置の作製方法。15. The method for manufacturing a semiconductor device according to claim 13, wherein the heat treatment is performed by a furnace annealing method using an electric heating furnace. 請求項6乃至16いずれか一において、前記バリア層はオゾン水により形成することを特徴とする半導体装置の作製方法。The method for manufacturing a semiconductor device according to claim 6 , wherein the barrier layer is formed using ozone water. 請求項6乃至16いずれか一において、前記バリア層はプラズマ処理により表面を酸化して形成することを特徴とする半導体装置の作製方法。The method for manufacturing a semiconductor device according to claim 6 , wherein the barrier layer is formed by oxidizing a surface by plasma treatment. 請求項6乃至16いずれか一において、前記バリア層は酸素を含む雰囲気中で紫外線を照射してオゾンを発生させ表面を酸化して形成することを特徴とする半導体装置の作製方法。17. The method for manufacturing a semiconductor device according to claim 6 , wherein the barrier layer is formed by irradiating ultraviolet rays in an atmosphere containing oxygen to generate ozone to oxidize the surface. 請求項6乃至19いずれか一において、前記希ガス元素はHe、Ne、Ar、Kr、Xeから選ばれた一種または複数種であることを特徴とする半導体装置の作製方法。20. The method for manufacturing a semiconductor device according to claim 6 , wherein the rare gas element is one or a plurality selected from He, Ne, Ar, Kr, and Xe. 請求項6乃至20いずれか一において、前記希ガス元素はイオン注入法又はイオンドープ法で添加することを特徴とする半導体装置の作製方法。21. The method for manufacturing a semiconductor device according to claim 6 , wherein the rare gas element is added by an ion implantation method or an ion doping method. 請求項6乃至21いずれか一いずれか一において、前記触媒元素はFe、Ni、Co、Ru、Rh、Pd、Os、Ir、Pt、Cu、Auから選ばれた一種または複数種であることを特徴とする半導体装置の作製方法。 22. The catalyst element according to claim 6 , wherein the catalyst element is one or more selected from Fe, Ni, Co, Ru, Rh, Pd, Os, Ir, Pt, Cu, and Au. A method for manufacturing a semiconductor device.
JP2002020801A 2001-01-29 2002-01-29 Method for manufacturing semiconductor device Expired - Fee Related JP4071005B2 (en)

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US6933527B2 (en) 2001-12-28 2005-08-23 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and semiconductor device production system
US6841797B2 (en) 2002-01-17 2005-01-11 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device formed over a surface with a drepession portion and a projection portion
TW200302511A (en) 2002-01-28 2003-08-01 Semiconductor Energy Lab Semiconductor device and method of manufacturing the same
TWI261358B (en) 2002-01-28 2006-09-01 Semiconductor Energy Lab Semiconductor device and method of manufacturing the same
US7749818B2 (en) 2002-01-28 2010-07-06 Semiconductor Energy Laboratory Co., Ltd. Semiconductor device and method of manufacturing the same
CN101217150B (en) 2002-03-05 2011-04-06 株式会社半导体能源研究所 Semiconductor element and semiconductor device using the same
US6847050B2 (en) 2002-03-15 2005-01-25 Semiconductor Energy Laboratory Co., Ltd. Semiconductor element and semiconductor device comprising the same
US6930326B2 (en) 2002-03-26 2005-08-16 Semiconductor Energy Laboratory Co., Ltd. Semiconductor circuit and method of fabricating the same
JP4115252B2 (en) * 2002-11-08 2008-07-09 シャープ株式会社 Semiconductor film and manufacturing method thereof, and semiconductor device and manufacturing method thereof
JP5046464B2 (en) * 2002-12-18 2012-10-10 株式会社半導体エネルギー研究所 Method for manufacturing semiconductor memory element
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