JP2002309329A - Al-Mg-Si ALLOY EXTRUSION SHAPE MATERIAL HAVING EXCELLENT HEAT CONDUCTIVITY - Google Patents
Al-Mg-Si ALLOY EXTRUSION SHAPE MATERIAL HAVING EXCELLENT HEAT CONDUCTIVITYInfo
- Publication number
- JP2002309329A JP2002309329A JP2001110722A JP2001110722A JP2002309329A JP 2002309329 A JP2002309329 A JP 2002309329A JP 2001110722 A JP2001110722 A JP 2001110722A JP 2001110722 A JP2001110722 A JP 2001110722A JP 2002309329 A JP2002309329 A JP 2002309329A
- Authority
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- Prior art keywords
- aluminum alloy
- extruded
- less
- alloy
- thermal conductivity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Extrusion Of Metal (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、例えばコンピュー
タの電子機器装置に用いられる発熱体冷却用のヒートシ
ンク等に使用される熱伝導性に優れたAl−Mg−Si
系アルミニウム合金押出形材に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to Al--Mg--Si having excellent thermal conductivity, for example, used as a heat sink for cooling a heating element used in electronic equipment of a computer.
The present invention relates to an extruded aluminum alloy.
【0002】[0002]
【従来の技術】一般にコンピュータなどの電子機器装置
に用いられる発熱体冷却用のヒートシンク等において
は、Al−Mg−Si系、即ち6000系アルミニウム
合金押出形材が用いられている。特に6000系アルミ
ニウム合金の中では熱伝導性に優れ、良好な押出加工性
を有し、更に熱処理を施すことにより適度な強度となり
切断や孔あけ等の切削加工を容易にできるA6063合
金(JIS)が広く使用されており、例えば特開平11
−74428号公報には、A6063S−T5材からな
るヒートシンクが記載されている。2. Description of the Related Art In general, a heat sink for cooling a heating element used in electronic equipment such as a computer uses an Al-Mg-Si type, that is, 6000 type aluminum alloy extruded material. In particular, among the 6000 series aluminum alloys, A6063 alloy (JIS) which has excellent heat conductivity, has good extrudability, and has appropriate strength by heat treatment, and can facilitate cutting such as cutting and drilling (JIS). Are widely used.
JP-A-744428 describes a heat sink made of A6063S-T5 material.
【0003】[0003]
【発明が解決しようとする課題】しかしながら、近年の
コンピュータなどの電子機器装置は軽量・小型化の方向
にあると共に、内部のCPU(中央演算処理装置)など
の高性能化に伴い発熱量も多くなる傾向にあるため、発
熱体冷却用のヒートシンク等の放熱性能の向上が望まれ
ているが、従来のA6063合金では、放熱性能を十分
に満足することができない恐れがある。However, in recent years, electronic devices such as computers have become lighter and smaller, and the amount of heat generated has increased due to higher performance of an internal CPU (central processing unit) and the like. Therefore, it is desired to improve the heat radiation performance of a heat sink for cooling a heating element. However, the conventional A6063 alloy may not be able to sufficiently satisfy the heat radiation performance.
【0004】また、熱伝導性の良い1000系アルミニ
ウム合金で薄肉部を形成すると強度が低く、切削加工時
に不具合が生じたり、組み付け時や使用時に振動や衝撃
で破損したりする問題がある。[0004] Further, when a thin-walled portion is formed of a 1000-series aluminum alloy having good thermal conductivity, the strength is low, and there is a problem in that a problem occurs during cutting, and a breakage occurs due to vibration or impact during assembly or use.
【0005】それゆえ、本発明は、強度を低下させるこ
となく放熱性能が向上可能なAl−Mg−Si系アルミ
ニウム合金押出形材を提供することを、その技術的課題
とする。[0005] Therefore, an object of the present invention is to provide an extruded Al-Mg-Si-based aluminum alloy material capable of improving heat radiation performance without reducing strength.
【0006】[0006]
【課題を解決するための手段】上記した技術的課題を解
決するために講じた本発明による熱伝導性に優れたAl
−Mg−Si系アルミニウム合金押出形材は、Mg:
0.4〜0.6%、Si:0.2〜0.5%、Ti:
0.003〜0.01%、Fe:0.1%以下、V:
0.005%以下を含み、残部Al及び不可避不純物で
あるアルミニウム合金からなることを特徴とする。Means for Solving the Problems An Al having excellent thermal conductivity according to the present invention, which has been taken in order to solve the above technical problems.
-Extruded Mg-Si based aluminum alloy material is Mg:
0.4-0.6%, Si: 0.2-0.5%, Ti:
0.003 to 0.01%, Fe: 0.1% or less, V:
0.005% or less, and the balance is made of Al and an unavoidable impurity of an aluminum alloy.
【0007】ここで、好ましくは、前記アルミニウム合
金を、押出加工した後に人工時効処理を施すことによ
り、ビッカース硬さが60HV以上であることが望まし
い。Here, it is preferable that the aluminum alloy is subjected to an artificial aging treatment after the extrusion, so that the Vickers hardness is 60 HV or more.
【0008】[0008]
【発明の実施の形態】以下、本発明によるAl−Mg−
Si系アルミニウム合金押出形材における添加元素の意
義及び合金組成の限定理由について説明する。BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, Al-Mg-
The significance of the additional elements in the extruded Si-based aluminum alloy and the reasons for limiting the alloy composition will be described.
【0009】(Mg、Si)MgとSiは、Mg2Si
を形成し強度を向上させる。Mg添加量が0.4%未
満、あるいはSi添加量0.2%未満では、Mg2Si
が少なくなり十分な強度を得ることができない。一方、
Mg添加量が0.6%を超える、あるいはSi添加量が
0.5%を超えると、熱伝導性が低下する。更に押出加
工性も考慮すると、Mg添加量の上限値は0.5%、S
i添加量の上限値は0.4%が好ましい。(Mg, Si) Mg and Si are Mg 2 Si
To improve the strength. If the added amount of Mg is less than 0.4% or the added amount of Si is less than 0.2%, Mg 2 Si
And sufficient strength cannot be obtained. on the other hand,
If the added amount of Mg exceeds 0.6% or the added amount of Si exceeds 0.5%, the thermal conductivity decreases. In consideration of the extrudability, the upper limit of the amount of added Mg is 0.5%,
The upper limit of the amount of i added is preferably 0.4%.
【0010】(Ti)Tiは、鋳塊組織の微細化のため
に添加されるが、0.01%を超えると熱伝導性が低下
し、0.003%未満だと合金鋳造時に鋳造割れが発生
する原因となる。そのため、添加量は0.003〜0.
01が望ましい。更に望ましい添加量は、0.003〜
0.008%である。[0010] (Ti) Ti is added for refining the ingot structure, but if it exceeds 0.01%, the thermal conductivity is reduced, and if it is less than 0.003%, casting cracks occur during alloy casting. Cause it to occur. Therefore, the amount of addition is 0.003-0.
01 is desirable. A more desirable addition amount is 0.003 to
0.008%.
【0011】(Fe)Feは、アルミニウムの精錬・鋳
造過程にて不純物として最も多く混入される元素である
が、熱伝導性を大きく低下させるため、0.1%以下が
望ましい。更に望ましくは、0.05%以下が好まし
い。(Fe) Fe is the element which is most often mixed as an impurity in the process of refining and casting aluminum, but is preferably 0.1% or less because it greatly reduces the thermal conductivity. More preferably, the content is 0.05% or less.
【0012】(V)Vは、Feと同様に不純物として混
入される元素であるが、微量でも著しく熱伝導性を低下
させる。従って、添加量は0.005%以下が望まし
い。(V) V is an element mixed as an impurity like Fe, but even a minute amount significantly lowers the thermal conductivity. Therefore, the addition amount is desirably 0.005% or less.
【0013】上記以外の元素については、不可避不純物
として個々に0.05%以下、合計で0.15%以下で
あれば合金の特性にほとんど影響を及ぼさない。但し、
Cu、Mn、Cr、Zn、Zrは、熱伝導性を低下させ
るため、それぞれ0.03%以下に制限するのが好まし
い。The elements other than those described above have little effect on the properties of the alloy if they are individually 0.05% or less as unavoidable impurities and 0.15% or less in total. However,
Cu, Mn, Cr, Zn, and Zr are each preferably limited to 0.03% or less in order to reduce thermal conductivity.
【0014】以上の合金組成にて調整されたアルミニウ
ム合金を用いて、常法により製造しても十分に熱伝導性
に優れたアルミニウム合金押出形材が得られるが、本発
明によるアルミニウム合金押出材の特性を最も発揮させ
るには、以下に述べる製造条件が望ましい。Although an aluminum alloy extruded material having excellent thermal conductivity can be obtained by using an aluminum alloy adjusted by the above alloy composition by a conventional method, the aluminum alloy extruded material according to the present invention can be obtained. In order to make the most of the characteristics described above, the following manufacturing conditions are desirable.
【0015】上記に示す組成のアルミニウム合金ビレッ
トを溶製し、540〜590℃で2〜10時間の均質化
処理を施す。次いで、450〜520℃に加熱した後に
押出加工し、そのまま空冷にて冷却した後に、180〜
220℃で1〜5時間の人工時効処理を施すことによ
り、ビッカース硬さが60HV以上であることが好まし
い。An aluminum alloy billet having the above composition is melted and homogenized at 540 to 590 ° C. for 2 to 10 hours. Then, after being heated to 450 to 520 ° C., it was extruded, and was cooled by air cooling as it was.
The Vickers hardness is preferably 60 HV or more by performing artificial aging treatment at 220 ° C. for 1 to 5 hours.
【0016】ここで、ビッカース硬さを測定するのは、
一般にビッカース硬さが、本発明によるアルミニウム合
金押出形材も含め6000系アルミニウム合金における
熱処理後の機械的性質、特に引張強さの代用値としても
扱われているからであるが、ビッカース硬さが60HV
未満だと強度が十分でなく、切断及び孔加工時に塑性変
形やバリの発生等の不具合が生じたり、薄肉部を有した
アルミニウム合金押出形材においては組み付け時や使用
時に破損したりするため、不適当である。Here, the Vickers hardness is measured by:
This is because Vickers hardness is generally treated as a substitute for mechanical properties, particularly tensile strength, after heat treatment in a 6000 series aluminum alloy including the extruded aluminum alloy material according to the present invention. 60HV
If it is less than the strength, it will not be strong enough, and problems such as plastic deformation and burr will occur during cutting and drilling, and in the case of extruded aluminum alloy material with a thin part, it will be damaged during assembly and use, Improper.
【0017】[0017]
【実施例】次に、本発明の実施例について、比較例と対
比して具体的に説明する。Next, examples of the present invention will be specifically described in comparison with comparative examples.
【0018】表1に示す各組成のアルミニウム合金ビレ
ット(直径φ204mm)を常法により溶製し、570
℃で5時間の均質化処理を施した。次いで、押出温度
(ビレット加熱温度)を500℃、押出速度を10m/
minで押出加工し、そのまま空冷にて冷却した後に、
200℃で3時間の人工時効処理を施し、図1に示すよ
うに複数の薄肉部を有した断面のアルミニウム合金押出
形材を製造した。Aluminum alloy billets (diameter φ204 mm) of each composition shown in Table 1 were melted by a conventional method, and 570
A homogenization treatment was performed at 5 ° C. for 5 hours. Next, the extrusion temperature (billet heating temperature) was set to 500 ° C., and the extrusion speed was set to 10 m /
Extrusion in min, and after cooling by air cooling as it is,
An artificial aging treatment was performed at 200 ° C. for 3 hours to produce an aluminum alloy extruded shape having a cross section having a plurality of thin portions as shown in FIG.
【0019】[0019]
【表1】 [Table 1]
【0020】これらのアルミニウム合金押出形材を、押
出方向長さを50mmに切断し、孔あけ加工を行った。
この切削及び孔あけ加工時に切削加工性の評価を行い、
押出形材が塑性変形したり、バリが発生したものは×、
塑性変形やバリが認められず良好に切削加工されたもの
を○と判定した。These extruded aluminum alloy members were cut to a length of 50 mm in the extrusion direction and punched.
Evaluate the cutting workability during this cutting and drilling,
If the extruded shape is plastically deformed or burrs are generated,
A sample that was well cut without any plastic deformation or burrs was judged to be good.
【0021】熱伝導性の評価は、一般に金属材料は熱伝
導率と導電率との間に比例関係があり、導電率によって
熱伝導性の良否を判断できるので、20℃にて導電率を
測定した。導電率は、従来のA6063合金における代
表値が54〜55%IACSであるので、55%IAC
S以下のものを×、55%IACSを超えるものを○と
した。In the evaluation of thermal conductivity, a metal material generally has a proportional relationship between the thermal conductivity and the electrical conductivity, and the quality of the thermal conductivity can be determined based on the electrical conductivity. did. Since the representative value of the conventional A6063 alloy is 54 to 55% IACS, the conductivity is 55% IAC.
S and below were evaluated as x, and those exceeding 55% IACS were evaluated as ○.
【0022】ビッカース硬さは、常温でJIS Z 22
44に従い5点平均により測定した。これらの評価結果
を表2に併せて示す。Vickers hardness is JIS Z 22 at room temperature.
The measurement was carried out by averaging the five points according to 44. These evaluation results are also shown in Table 2.
【0023】[0023]
【表2】 [Table 2]
【0024】表2に示すように、本発明によるアルミニ
ウム合金押出形材である実施例1〜2は、切削加工性と
導電率が共に良好であった。特に、1000系アルミニ
ウム合金における導電率の代表値が60〜62%IAC
Sであることを考慮すると、6000系アルミニウム合
金において58〜59%IACSという値は、優れた熱
伝導性をそなえていることがわかる。As shown in Table 2, Examples 1 and 2, which are the extruded aluminum alloy material according to the present invention, exhibited both good machinability and electrical conductivity. In particular, the typical value of the conductivity of a 1000 series aluminum alloy is 60 to 62% IAC.
Considering that S is the value, it can be seen that the value of 58 to 59% IACS in the 6000 series aluminum alloy has excellent thermal conductivity.
【0025】それに対して、ビッカース硬さが60HV
未満である比較例3、5は、切断及び孔あけ加工時に押
出形材の変形やバリが発生し、比較例4、7は、切削加
工性は良好であるものの導電率が低く、熱伝導性が劣る
ものとなった。On the other hand, the Vickers hardness is 60 HV
In Comparative Examples 3 and 5, which are less than the above, deformation and burrs of the extruded material occur during cutting and drilling, and Comparative Examples 4 and 7 have good machinability but low electrical conductivity and thermal conductivity. Became inferior.
【0026】[0026]
【発明の効果】以上の如く、本発明によれば、強度や切
削加工性を満足しながら優れた熱伝導性を有し、例えば
発熱体冷却用のヒートシンク等の材料として好適なアル
ミニウム合金押出形材を得ることができる。As described above, according to the present invention, an extruded aluminum alloy having excellent heat conductivity while satisfying strength and machinability and suitable as a material for a heat sink for cooling a heating element, for example. Material can be obtained.
【図面の簡単な説明】[Brief description of the drawings]
【図1】実施例に用いた押出形材を示す断面図である。FIG. 1 is a cross-sectional view showing an extruded profile used in an example.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C22F 1/00 630 C22F 1/00 630C 630J 650 650F 1/05 1/05 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int. Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C22F 1/00 630 C22F 1/00 630C 630J 650 650F 1/05 1/05
Claims (2)
同じ)、Si:0.2〜0.5%、Ti:0.003〜
0.01%、Fe:0.1%以下、V:0.005%以
下を含み、残部Al及び不可避不純物であるアルミニウ
ム合金からなることを特徴とする熱伝導性に優れたAl
−Mg−Si系アルミニウム合金押出形材。1. Mg: 0.4 to 0.6% (mass%, the same applies hereinafter), Si: 0.2 to 0.5%, Ti: 0.003 to
Al having excellent thermal conductivity, comprising 0.01%, Fe: 0.1% or less, V: 0.005% or less, the balance being Al and an aluminum alloy which is an unavoidable impurity.
-Extruded Mg-Si aluminum alloy material.
後に人工時効処理を施すことにより、ビッカース硬さが
60HV以上であることを特徴とする請求項1に記載の
熱伝導性に優れたAl−Mg−Si系アルミニウム合金
押出形材。2. The heat conductive Al-Mg according to claim 1, wherein the aluminum alloy is subjected to an artificial aging treatment after being extruded to have a Vickers hardness of 60 HV or more. -Extruded Si-based aluminum alloy.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP2001110722A JP2002309329A (en) | 2001-04-10 | 2001-04-10 | Al-Mg-Si ALLOY EXTRUSION SHAPE MATERIAL HAVING EXCELLENT HEAT CONDUCTIVITY |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2001110722A JP2002309329A (en) | 2001-04-10 | 2001-04-10 | Al-Mg-Si ALLOY EXTRUSION SHAPE MATERIAL HAVING EXCELLENT HEAT CONDUCTIVITY |
Publications (2)
Publication Number | Publication Date |
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JP2002309329A true JP2002309329A (en) | 2002-10-23 |
JP2002309329A5 JP2002309329A5 (en) | 2008-03-21 |
Family
ID=18962429
Family Applications (1)
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JP2001110722A Pending JP2002309329A (en) | 2001-04-10 | 2001-04-10 | Al-Mg-Si ALLOY EXTRUSION SHAPE MATERIAL HAVING EXCELLENT HEAT CONDUCTIVITY |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012172164A (en) * | 2011-02-18 | 2012-09-10 | Sankyo Material Inc | Aluminum alloy extrusion formed material and manufacturing method thereof |
JP2016079475A (en) * | 2014-10-20 | 2016-05-16 | 昭和電工株式会社 | Method for producing thermally conductive and electrically conductive member |
CN115595478A (en) * | 2022-10-25 | 2023-01-13 | 江苏中福铝镁科技有限公司(Cn) | Conductive sheet profile and preparation method thereof |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6296639A (en) * | 1985-09-30 | 1987-05-06 | アルカン・インタ−ナシヨナル・リミテツド | Extrusion ingot of al-mg-si alloy and its production |
JPH02200750A (en) * | 1989-01-31 | 1990-08-09 | Sumitomo Light Metal Ind Ltd | Aluminum alloy stock excellent in electric conductivity and its production |
JPH0456744A (en) * | 1990-06-26 | 1992-02-24 | Sumitomo Light Metal Ind Ltd | High conductivity al-mg-si alloy tube and its manufacture |
JPH08104934A (en) * | 1994-10-06 | 1996-04-23 | Furukawa Electric Co Ltd:The | Aluminum alloy fin material |
JPH09137242A (en) * | 1995-11-08 | 1997-05-27 | Nippon Light Metal Co Ltd | Aluminum alloy thin sheet for cross fin and its production |
JPH10298687A (en) * | 1992-08-20 | 1998-11-10 | Furukawa Electric Co Ltd:The | Aluminum alloy high thermal conductivity fin material |
JPH10310834A (en) * | 1997-05-08 | 1998-11-24 | Nippon Light Metal Co Ltd | Aluminum alloy thin sheet for cross fin and its production |
JPH1174428A (en) * | 1997-08-27 | 1999-03-16 | Gunma Alum Kk | Heat sink and its manufacture |
JP2000226628A (en) * | 1999-02-04 | 2000-08-15 | Showa Alum Corp | Aluminum radiating member and its production |
-
2001
- 2001-04-10 JP JP2001110722A patent/JP2002309329A/en active Pending
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6296639A (en) * | 1985-09-30 | 1987-05-06 | アルカン・インタ−ナシヨナル・リミテツド | Extrusion ingot of al-mg-si alloy and its production |
JPH02200750A (en) * | 1989-01-31 | 1990-08-09 | Sumitomo Light Metal Ind Ltd | Aluminum alloy stock excellent in electric conductivity and its production |
JPH0456744A (en) * | 1990-06-26 | 1992-02-24 | Sumitomo Light Metal Ind Ltd | High conductivity al-mg-si alloy tube and its manufacture |
JPH10298687A (en) * | 1992-08-20 | 1998-11-10 | Furukawa Electric Co Ltd:The | Aluminum alloy high thermal conductivity fin material |
JPH08104934A (en) * | 1994-10-06 | 1996-04-23 | Furukawa Electric Co Ltd:The | Aluminum alloy fin material |
JPH09137242A (en) * | 1995-11-08 | 1997-05-27 | Nippon Light Metal Co Ltd | Aluminum alloy thin sheet for cross fin and its production |
JPH10310834A (en) * | 1997-05-08 | 1998-11-24 | Nippon Light Metal Co Ltd | Aluminum alloy thin sheet for cross fin and its production |
JPH1174428A (en) * | 1997-08-27 | 1999-03-16 | Gunma Alum Kk | Heat sink and its manufacture |
JP2000226628A (en) * | 1999-02-04 | 2000-08-15 | Showa Alum Corp | Aluminum radiating member and its production |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012172164A (en) * | 2011-02-18 | 2012-09-10 | Sankyo Material Inc | Aluminum alloy extrusion formed material and manufacturing method thereof |
JP2016079475A (en) * | 2014-10-20 | 2016-05-16 | 昭和電工株式会社 | Method for producing thermally conductive and electrically conductive member |
CN115595478A (en) * | 2022-10-25 | 2023-01-13 | 江苏中福铝镁科技有限公司(Cn) | Conductive sheet profile and preparation method thereof |
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