JP2002302697A - Detergent composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a detergent composition having a good foaming property and foaming quality, without stiff and creaking feelings when rinsing, and without generating sticking and stiff feelings even in a continuous use for a long term. SOLUTION: The detergent composition contains (A) an extract from an unrefined sugar and (B) one or two or more selected from the group consisting of a siloxane compound, a cationic polymer and a peptide derivative.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a detergent composition, and more particularly, to foaming, good foam quality, no squeezing or squeaky feeling during rinsing, and a feeling of stickiness and stiffness even after long-term continuous use. The present invention relates to a detergent composition which does not produce odor.

[0002]

2. Description of the Related Art Various cleaning compositions using a surfactant as a cleaning base have been proposed for the purpose of cleaning skin and hair. In these detergent compositions, a texture control agent for relaxing a feeling of tightness and squeaking, a cationic polymer such as cationized cellulose as a foam quality modifier for improving foam quality, a siloxane compound, a peptide derivative, Oils and the like are widely used. However, some of these may inhibit foaming properties or give a slimy feeling when rinsing, and when used alone for a long period of time, they may accumulate on the skin and hair and become sticky. There were drawbacks such as a feeling of feeling and stiffness.

[0003]

In the above circumstances, there has been a demand for a technique for solving the above-mentioned disadvantages. That is, an object of the present invention is to provide a detergent composition which is foamed, has good foam quality, does not have a tight feeling or squeaky feeling during rinsing, and has no sticky feeling or stiffness even after long-term continuous use. is there.

[0004]

That is, claim 1 of the present invention relates to (1) an extract from unpurified sugar and (B) a compound selected from the group consisting of a siloxane compound, a cationic polymer, and a peptide derivative. A cleaning composition comprising a seed or two or more kinds. Claim 2 of the present invention relates to (C) one or two kinds selected from the group consisting of a black pigment component obtained by extraction from unpurified sugar, and (B) a siloxane compound, a cationic polymer, and a peptide derivative. A cleaning composition comprising: Claim 3 of the present invention is the cleaning composition according to claim 1 or claim 2, wherein the unrefined sugar is brown sugar or molasses obtained from sugarcane.

[0005]

BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in detail.

The extract from unrefined sugar used as the component (A) of the present invention is obtained from unrefined sugar such as sugar or molasses obtained from sugar raw materials such as sugarcane and sugar beet, lower alcohol such as ethanol, glycerin, It is obtained by extraction with a polyhydric alcohol such as 1,3-butylene glycol or a mixture thereof. For example, "Black Sugar Extract", "Black Sugar Extract ( 2) ". Among these, it is desirable to contain a black pigment component, and in particular, a black pigment component obtained from sugarcane is separated,
A concentrated extract is desirable. Commercially available desirable extracts include "Coctoligo" manufactured by Osaka Pharmaceutical Research Institute.

[0007] The amount of the extract from these unpurified sugars is preferably 0.00% by dry weight in the composition of the present invention.
The content is from 0.01 to 5% by mass (hereinafter abbreviated as%), and more preferably from 0.0005 to 1%. If it is less than 0.0001%,
In some cases, the effects of the present invention may not be achieved.
The coloring of the product may be remarkable, which may be undesirable in appearance.

The siloxane compound of the component (B) used in the present invention is not particularly limited as long as it has a siloxane structure. Examples thereof include dimethylpolysiloxane, methylphenylpolysiloxane, amino-modified silicone, and fatty acid-modified silicone. Silicone, alcohol-modified silicone, aliphatic alcohol-modified silicone, polyether-modified silicone, epoxy-modified silicone, fluorine-containing modified silicone, cyclic silicone, alkyl-modified silicone, betaine group-containing modified silicone
Siloxane compounds obtained according to the method described in Japanese Patent No. 30294) or co-modified silicones thereof. In order to impart a further excellent conditioning effect and a finished feeling, among these siloxane compounds, nonvolatile ones, especially dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, alkyl-modified silicone,
Desirable are a fluoroalkyl group-containing modified silicone and an alkoxy-modified silicone, among which fluoroalkyl polyoxyalkylene co-modified silicone or 25
Viscosity at 1000 ° C. is 1000 to 1,000,000 mm ² / s
Is more desirable. Also,
These siloxane compounds may be emulsion-polymerized.

These siloxane compounds can be used alone or in admixture of two or more. A sufficient conditioning effect, finished feeling, and the like can be obtained without impairing usability.
In order to provide foam quality, 0.01 to 2
It is desirable to mix 5%.

The cationic polymer of the component (B) used in the present invention includes, for example, a cationized cellulose derivative (trade name: Polymer JR-400 [manufactured by UCC]);
LEOGARD G [manufactured by Lion Corporation], Kachinal HC-20
0 (manufactured by Toho Chemical Industry Co., Ltd.), cationized guar gum derivatives (trade names: Jaguar C-17 and C-13-S (manufactured by Celanese), etc.), and quaternized polyvinylpyrrolidone derivatives (trade names: GAFQUAT734 and 755) [ISP
Dimethyl diallyl ammonium chloride derivative (trade name: MERQUAT100, 550 and 3)
330 [manufactured by Calgon], polyglycol polyamine condensate (trade name: Polycoat NH [manufactured by Henkel])
Etc.), cationized starch, cationized polypeptide and the like.

These cationic polymers can be used singly or as a mixture of two or more kinds, and have a sufficient conditioning effect, finished feeling, and so forth as long as the usability is not impaired.
In order to provide a foam quality, the detergent composition of the present invention should have a concentration of 0.1%.
01 to 10% is preferable, and 0.01 to 5 is more preferable.
%.

The peptide derivative of the component (B) used in the present invention includes natural peptides, synthetic peptides, protein hydrolysates obtained by partially hydrolyzing proteins (proteins) with acids, alkalis or enzymes. In addition, derivatives such as cationized products, acylated products, alkyl esterified products, and siliconized products of these peptides can also be used. Examples of natural peptides include glutathione,
Examples include bacitracin A, insulin, glucagon, oxytocin, vasopressin, and the like, and examples of synthetic peptides include polyglycine, polylysine, polyglutamic acid, and polyserine.

[0013] Examples of the protein serving as a source of the protein hydrolyzate include those derived from animals such as collagen, gelatin, keratin, silk fibroin, sericin, casein, conchiolin, elastin, egg yolk protein and egg white protein of chicken and the like. And soybeans, almonds, wheat, beer lees, corn, rice, plant-derived proteins such as potatoes, as well as yeasts of the genera Saccharomyces, Candita, Endomycopsis, brewer's yeast, sake yeast Examples include yeast proteins isolated from bacteria, those derived from microorganisms such as mushrooms (basidiomycetes), and proteins isolated from chlorella.

Among these peptide derivatives, collagen, conchiolin, silk fibroin, and the like obtained from animals or plants are particularly desirable in order to provide a sufficient conditioning effect, finished feeling, and foam quality within a range not to impair the usability as a detergent. Wheat protein, protein hydrolyzate such as soy protein is desirable, the molecular weight is not particularly limited, but the average molecular weight is preferably 50 to 50,000,
Further, the average molecular weight is preferably from 200 to 10,000. Also,
The compounding amount of these peptide derivatives is preferably 0.0001 to 5%, more preferably 0.001 to 1% by dry weight in the composition of the present invention. If the amount is less than 0.0001%, the effect of the present invention may not be exhibited even if it is added, and if it exceeds 5%, it may not be preferable in the production process of the product.

The cleaning composition of the present invention usually contains a surfactant as a cleaning base. The surfactant used in the present invention may be any of nonionic, anionic, cationic, amphoteric, and semipolar. Particularly, anionic surfactant, amphoteric surfactant, semipolar surfactant, and sugar-based nonionic Surfactants, fatty acid alkanolamide type nonionic surfactants, and the like are preferable from the viewpoint of detergency and foamability.

Specific examples of preferred surfactants include, as anionic surfactants, fatty acid soaps, alkyl sulfate surfactants, alkyl ether sulfate surfactants, olefin sulfonate surfactants, phosphorus surfactants, and the like. Acid ester type surfactant, alkyl ether carboxylate type surfactant, amino acid salt type surfactant (sarcosine salt type,
β-alanine salt type, glutamate type, aspartate type, etc.), sulfosuccinate type surfactant, taurine type surfactant, etc., as amphoteric surfactants, sulfobetaine type surfactants, alkyl betaine type surfactants Surfactants, amidopropyl betaine surfactants, imidazolinium betaine surfactants, etc., semipolar surfactants, amine oxide surfactants, sugar nonionic surfactants, alkyl glucosides, sugar fatty acid esters As a fatty acid alkanolamide type nonionic surfactant,
Fatty acid diethanolamide, fatty acid monoethanolamide, fatty acid diisopropanolamide and the like can be mentioned.
The lipophilic group of these surfactants may be linear or branched, or may be partially modified with another functional group, and may be an acyl group or an alkyl group. Usually, a linear or branched one having an average carbon number of 8 to 22 is preferably used. Further, these surfactants may have an alkylene oxide structure, an amide structure, a hydroxyl group and the like in the molecule.

These surfactants can be used alone or as a mixture of two or more kinds. Usually, it is preferable to add 0.1 to 50% to the detergent composition.

[0018] The cleaning composition of the present invention may optionally contain components commonly incorporated in cleaning agents, for example, higher alcohols,
Oil components such as lanolin derivatives and fatty acid esters of polyethylene glycol, moisturizing components such as propylene glycol, glycerin and polyethylene glycol, pearlescent agents such as fatty acid ethylene glycol, and water-soluble polymer compounds (nonionic, anionic, amphoteric, etc.) ), Extracts from animals and plants, sequestering agents, preservatives, pH adjusters,
An ultraviolet absorber, an antioxidant, a dye, a fragrance and the like can be appropriately compounded.

The detergent composition of the present invention can be preferably applied to the body such as body shampoo, hand soap, face wash, hair shampoo and the like, and can be used for powders such as solids, liquids, aerosol foams, mist, etc. It can be used for various dosage forms.

[0020]

Next, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto. still,
The perfume formulation used in the following detergent formulation is as follows.

[0021]

[Table 1]

Prior to the examples, test methods and evaluation methods employed in each example and comparative example will be described.

Finish feeling test method after use A panel (30 persons) applied a body shampoo having the following composition as a control to the left foot and the left hand, and applied a sample to the right foot and the right hand, respectively. The quality, the feeling of tightness during rinsing, and the feeling of stickiness after drying were sensory evaluated for each of the left and right limbs. Further, washing was performed once a day in the same manner as above, and the sticky feeling after drying after continuous use for 30 days was subjected to a sensory evaluation according to the above items.

Control (%) • Potassium coconut oil fatty acid 30.0 • Cationized cellulose derivative (trade name: Polymer JR-400 [manufactured by UCC]) 0.5 • Purified water residue

The evaluation criteria were set as follows. <Foaming / foam quality> ◎ ・ ・ ・ 19 or more people answered as good ○ ・ ・ ・ 16 to 18 people answered as good △ ・ ・ ・ 8 to 15 people answered as good × ・ ・・ No more than 7 people answered good

<Tightness at the time of rinsing and stickiness after drying> ・ ・ ・: More than 19 people answered better than control コ ン ト ロ ー ル: 16 to 1 people answered better than control
8 people △ ・ ・ ・ The number of people who answered better than the control was 8-15
Name ×: 7 or less people who answered better than control

Examples 1 to 6 and Comparative Examples 1 to 6 Table 2 shows the evaluation results of each composition.

[0028]

[Table 2]

A body shampoo having the composition shown in Table 2 was prepared by a conventional method, and was continuously used for 30 days. The foaming, the foam quality, the tightness upon rinsing, and the stickiness after drying were sensory evaluated. As shown in the above, all of the body shampoos of Examples 1 to 6 using the components of the present invention showed excellent performance.

Example 7 Body shampoo (%) Potassium coconut oil fatty acid 15.0 Sodium lauryl sulfate 5.0 Triethanolamine lauryl phosphate 2.0 Isopropanolamide laurate 1.0 POP (1) Coconut fatty acid monoisopropanol Amide 2.0 Ethylene glycol distearate 1.0 Seaweed extract (trade name: Kaisou extract [Maruzen Pharmaceutical Co., Ltd.]) 0.5 Polymer silicone aqueous emulsion (trade name: BY22-029 2.0 [Toray) -Dow Corning Silicone Co., Ltd.)) Silylated peptide derivative 0.2 (trade name: Promois WS-HSIG [Seiwa Kasei Co., Ltd.]) Glycerin 3.0 L-Serine 0.05 D-Panthenol 0.1 Black Sugar extract 0.2 (trade name: Coctoligo [Osaka Pharmaceutical Laboratory Co., Ltd.]) EDTA 0.2 Chiruparaben 0.2 Dye Appropriate amount Perfume Appropriate amount Purified water Balance

A body shampoo having the above composition was prepared by a conventional method, and continuously used for 30 days, and foaming, foam quality, a feeling of firmness upon rinsing, and a feeling of stickiness after drying were evaluated. And obtained good results.

Example 8 Body shampoo (%) Coconut fatty acid acylglycine potassium 20.0 Lauroylglycine triethanolamine 10.0 Sodium laurylaminodiacetate 5.0 Labetaylaminoacetate betaine 5.0 POP (1) Coconut fatty acid Monoisopropanolamide 5.0 Myristic acid 0.5 Glycerin 2.0 Brown sugar extract 0.2 (trade name: Coctoligo [manufactured by Osaka Pharmaceutical Laboratory Co., Ltd.]) Sodium chloride 2.0 Citric acid 0.2 Knapweed extract 0 3 (trade name: “Kelso extract extract BG” [manufactured by Maruzen Pharmaceutical Co., Ltd.]) Japanese sagebrush extract 0.1 (trade name: “Inchinko Extract BG” [manufactured by Maruzen Pharmaceutical Co., Ltd.)) Sakinoki extract 0.1 (trade name) : "Yukinosita extract BG" [Maruzen Pharmaceutical Co., Ltd.]) EDTA 0.2 methylparabe 0.2 Perfume Appropriate amount Purified water Balance

A body shampoo having the above composition was prepared by a conventional method, and was continuously used for 30 days. Foaming, foam quality, firmness upon rinsing, and stickiness after drying were evaluated organoleptically. And obtained good results.

Example 9 Body Shampoo (%) POE (3) Sodium Lauryl Ether Sulfate 10.0 Triethanolamine Lauryl Sulfate 8.0 Amidopropyl Betaine Laurate 2.0 Sodium Laurylaminodiacetate 2.0 Monoisopropanol Laurate Amide 1.0 1,3-butylene glycol 2.5 Glycerin 1.0 Dimethyldiallylammonium chloride / acrylamide 2.0 copolymer (trade name: Marcoat 550 (manufactured by Calgon)) Panax ginseng extract 0.1 (trade name: carrot Extract BG [Maruzen Pharmaceutical Co., Ltd.]) Silk Extract 0.05 (trade name: SilkGen G Soluble [Ichimaru Falcos Co., Ltd.]) Brown Sugar Extract 0.05 (trade name: Coctoligo [Osaka Pharmaceutical Research Laboratories]) EDTA 0.2 methyl para Down 0.2 salicylic 0.2 Perfume Appropriate amount Purified water Balance

A body shampoo having the above composition was prepared by a conventional method, and was continuously used for 30 days. Foaming, foam quality, firmness upon rinsing, and stickiness after drying were organoleptically evaluated. And obtained good results.

Example 10 Face Wash (%) Lauric acid 5.0 Myristic acid 10.0 Palmitic acid 10.0 Stearic acid 10.0 Potassium hydroxide 6.0 Lauric acid monoethanolamide 1.0 Dimethylpolysiloxane 0.0 1 (50,000 mm ² / s; 25 ° C.) Ethylene glycol dibehenate 2.0 Brown sugar extract 0.2 (trade name: Coctoligo [manufactured by Osaka Pharmaceutical Research Institute]) EDTA 0.2 Methyl paraben 0.2 Dye Appropriate amount Perfume Appropriate Volume Purified water Residue

A face wash having the above composition is prepared by a conventional method.
After continuous use for 0 days, the foaming, the foam quality, the tightness upon rinsing, and the stickiness after drying were organoleptically evaluated. As a result, all of the characteristics were excellent and good results were obtained.

Example 11 Hand Soap (%) Coconut Fatty Acid Potassium 15.0 Ammonium Lauryl Sulfate 5.0 Coconut Fatty Acid Acylglutamate Triethanolamine 5.0 Monoisopropanolamide Laurate 2.0 Ethylene Glycol Distearate 2.0 Black Sugar extract 0.001 (trade name: Coctoligo [manufactured by Osaka Pharmaceutical Laboratory Co., Ltd.]) Collagen hydrolyzate 0.2 (trade name: Promois W-52 [manufactured by Seiwa Kasei Co., Ltd.]) Dimethyl diallyl ammonium chloride / acrylamide 0 Copolymer (trade name: Mercoat 550 [manufactured by Calgon]) Cationized cellulose derivative 0.2 (trade name: Catinal HC-200 [manufactured by Toho Chemical Industry Co., Ltd.]) Dipropylene glycol 2.0 EDTA 0.2 methyl paraben 2 Appropriate amount of fragrance Purified water residue

A face wash having the above composition is prepared by a conventional method.
After continuous use for 0 days, the foaming, the foam quality, the tightness upon rinsing, and the stickiness after drying were organoleptically evaluated. As a result, all of the characteristics were excellent and good results were obtained.

Example 12 Shampoo (%) POE (3) Sodium Lauryl Ether Sulfate 10.0 Lauroyl-N-methyl-β-alanine Sodium 4.0 Amidopropyl Betaine Laurate 5.0 Monoisopropanolamide Laurate 1.5 Ethylene glycol distearate 2.0 linden extract 0.5 (trade name: linden extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) aqueous polymer silicone emulsion (trade name: BY22-029 2.0 [Toray Dow Corning -Silicone Co., Ltd.) Cationized cellulose derivative 0.5 (trade name: Catinal HC-200 [Toho Chemical Industry Co., Ltd.]) Brown sugar extract 0.1 (trade name: Coctoligo [Osaka Pharmaceutical Laboratory Co., Ltd.]) L -Serine 0.01 EDTA 0.2 Methyl paraben 0.2 Sodium benzoate 0 2 Perfume Appropriate amount Purified water Balance

A shampoo having the above composition was prepared according to a conventional method and used continuously for 30 days. The shampoo was evaluated for foaming, foam quality, tightness upon rinsing, and stickiness after drying. With good results.

Example 13 Foam Shampoo (Undiluted Solution) (%) POE (3) Sodium Lauric Amide Ether Sulfate 8.0 Lauryl Amidopropyldimethylaminoacetic Acid Betaine 5.0 Coconut Fatty Acid Sodium Methyl Taurine 5.0 Coconut Fatty Acid Sucrose ester 3.0 POP (1) Mono-isopropanolamide of coconut acid 3.0 Amino-modified silicone aqueous emulsion (trade name: SM8702C 1.0 [manufactured by Dow Corning Toray Silicone Co., Ltd.]) Ethanol 2.0 brown sugar Extract 0.1 (trade name: Coctoligo [manufactured by Osaka Pharmaceutical Laboratory Co., Ltd.]) EDTA 0.2 methyl paraben 0.2 dye appropriate amount perfume appropriate amount purified water residue (propellant) liquefied petroleum gas 7.0

A foam shampoo having the above composition is prepared by a conventional method, and is continuously used for 30 days.
When the sensory evaluation was performed on the feeling of tightness after rinsing and the feeling of stickiness after drying, all properties were excellent, and good results were obtained.

[0044]

As described above, according to the present invention, a detergent composition which is excellent in foaming and foam quality, does not have a feeling of squeezing or squeaking during rinsing, and does not produce a sticky feeling and a stiff feeling even after long-term continuous use. Things can be provided.

──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. ⁷ Identification symbol FI theme coat ゛ (reference) C11D 3/382 C11D 3/382 3/40 3/40 F term (reference) 4C083 AA11 AC12 AC24 AC30 AC39 AC47 AC48 AC53 AC54 AC58 AC64 AC66 AC69 AC71 AC78 AD09 AD13 AD15 AD16 AD21 AD41 AD45 BB34 BB41 CC23 CC38 EE06 4H003 AB03 AB09 AB27 AB31 AB38 AC13 AD04 BA01 BA09 BA12 BA15 DA02 EB05 EB09 EB13 EB16 EB30 EB37 EB41 FA42 EB43 FA17

Claims (3)

[Claims] 1. An extract from (A) an unpurified sugar, and (B)
A cleaning composition comprising one or more selected from the group consisting of a siloxane compound, a cationic polymer, and a peptide derivative. 2. It comprises (C) a black pigment component obtained by extraction from unpurified sugar, and (B) one or more selected from the group consisting of siloxane compounds, cationic polymers and peptide derivatives. A cleaning composition comprising: 3. The cleaning composition according to claim 1, wherein the unpurified sugar is brown sugar or molasses obtained from sugarcane.