JP2002030363A - Wear resistant parts and method for producing the same - Google Patents

Wear resistant parts and method for producing the same

Info

Publication number
JP2002030363A
JP2002030363A JP2000221056A JP2000221056A JP2002030363A JP 2002030363 A JP2002030363 A JP 2002030363A JP 2000221056 A JP2000221056 A JP 2000221056A JP 2000221056 A JP2000221056 A JP 2000221056A JP 2002030363 A JP2002030363 A JP 2002030363A
Authority
JP
Japan
Prior art keywords
alloy
wear
sintered body
sphere
producing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000221056A
Other languages
Japanese (ja)
Inventor
Kunihiro Tanaka
邦弘 田中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tanaka Kikinzoku Kogyo KK
Original Assignee
Tanaka Kikinzoku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tanaka Kikinzoku Kogyo KK filed Critical Tanaka Kikinzoku Kogyo KK
Priority to JP2000221056A priority Critical patent/JP2002030363A/en
Publication of JP2002030363A publication Critical patent/JP2002030363A/en
Pending legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To obtain wear resistant parts capable of withstanding use even in the severe environment of an high temperature-oxidizing atmosphere. SOLUTION: A metallic body, an alloy body or a sintered body having an almost columnar shape is formed of Ir, Rh or their alloy, next, this alloy or sintered body is melted while being rotated in an inert gas, and the molten metal drops scattered by centrifugal force are cooled and solidified into a spherical body.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、ボールベアリング
のボール等に代表される耐摩耗部品、特に高温下、酸化
性雰囲気下での使用に耐え得る耐摩耗部品及びその製造
方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wear-resistant part typified by a ball of a ball bearing and the like, and more particularly to a wear-resistant part capable of withstanding use at high temperatures and in an oxidizing atmosphere, and a method of manufacturing the same.

【0002】[0002]

【従来の技術】従来より耐摩耗部品であるボールベアリ
ングのボールには主として鉄系材料、真ちゅう等が用い
られている。その理由は、材料が安価で且つ加工が比較
的容易であることによる。しかし、これらの材料は酸化
性雰囲気下での使用においては、腐食の進展が早い。ま
た、腐食しにくいステンレス系材料を用いたボールで
も、高温下では腐食が激しいので、使用できなかった。
特に原子力関係の施設においては、高温、酸化性雰囲気
下の環境が多く、このような過激な環境でも使用し得る
ような好ましい耐摩耗部品は見当たらない。
2. Description of the Related Art Conventionally, iron-based materials, brass and the like are mainly used for balls of ball bearings, which are wear-resistant parts. The reason is that the material is inexpensive and the processing is relatively easy. However, when these materials are used in an oxidizing atmosphere, corrosion progresses rapidly. Further, even a ball made of a stainless steel material which is hard to corrode could not be used because of high corrosion at high temperature.
Particularly in nuclear facilities, there are many environments in a high temperature and oxidizing atmosphere, and there is no preferable wear-resistant part that can be used even in such a severe environment.

【0003】[0003]

【発明が解決しようとする課題】そこで本発明は、高
温、酸化性雰囲気下といった過激な環境でも使用に耐え
得る耐摩耗部品及びその製造方法を提供しようとするも
のである。
SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a wear-resistant part which can withstand use even in a severe environment such as a high temperature and an oxidizing atmosphere, and a method of manufacturing the same.

【0004】[0004]

【課題を解決するための手段】上記課題を解決するため
の本発明の耐摩耗部品は、Ir、Rh、Ru又はそれら
の合金の球体より成るものである。
According to the present invention, there is provided a wear-resistant component comprising a sphere made of Ir, Rh, Ru, or an alloy thereof.

【0005】上記の耐摩耗部品を作る本発明の製造方法
は、Ir、Rh、Ru又はそれらの合金により略円柱形
状の金属体、合金体又は焼結体を作り、次にこの金属
体、合金体又は焼結体を不活性ガス中で回転させつつ溶
融し、遠心力により飛散する溶融金属を冷却させて凝固
し、球体にすることを特徴とするものである。
[0005] The manufacturing method of the present invention for producing the above wear-resistant parts comprises producing a substantially cylindrical metal body, alloy body or sintered body from Ir, Rh, Ru or an alloy thereof, and then forming the metal body, alloy body or alloy body. The method is characterized in that a body or a sintered body is melted while rotating in an inert gas, and the molten metal scattered by centrifugal force is cooled and solidified to form a sphere.

【0006】上記の耐摩耗部品の製造方法において、金
属体、合金体又は焼結体の溶融は、該金属体、合金体又
は焼結体の対向位置に電極を設置し、金属体、合金体又
は焼結体を陽極とし、前記電極を陰極として、アーク放
電により溶融するものであることが好ましい。
[0006] In the above method for producing a wear-resistant part, the metal body, the alloy body or the sintered body is melted by disposing an electrode at a position facing the metal body, the alloy body or the sintered body. Alternatively, it is preferable that the sintered body be used as an anode and the electrode be used as a cathode and be melted by arc discharge.

【0007】[0007]

【作用】上記のように本発明の耐摩耗部品は、Ir、R
h、Ru又はそれらの合金の球体より成るので、非常に
硬く、またIr、Rh、Ru等は耐薬品性にもすぐれる
ので、高温、酸化性不雰囲気下でも非常に腐食しにく
く、過激な環境でも使用に耐え得る。
As described above, the wear-resistant parts of the present invention are Ir, R
h, Ru, or their alloys, they are very hard, and Ir, Rh, Ru, etc. are also excellent in chemical resistance. It can be used in the environment.

【0008】また、上記のような本発明の耐摩耗部品の
製造方法は、従来の機械加工では真球に近い球体に加工
することが困難であったIr、Rh、Ru又はそれらの
合金より成る略円柱形状の金属体、合金体又は焼結体
を、不活性ガス中で回転させつつ溶融し、遠心力により
連続的に飛散する溶融金属を冷却させて凝固し、球体に
するので、Ir、Rh、Ru又はそれらの合金の球体を
短時間に容易に且つ安価に大量に製造できて、生産性が
向上する。また、溶融、冷却を不活性ガス中で行うの
で、Ir、Rh、Ru又はそれらの合金の酸化を抑制す
ることができ、清浄な品質の良い球体を製造できる。さ
らに、本発明の耐摩耗部品の製造方法においては、回転
させる略円柱形状の金属体、合金体又は焼結体の径(回
転半径)及び回転数を変化させることで、製造される球
体の大きさ(径)を調整することができる。尚、回転さ
せる金属体、合金体又は焼結体を略円柱形状とするの
は、製造される球体の大きさをできるだけ均一にするた
めである。
Further, the method for producing a wear-resistant part of the present invention as described above comprises Ir, Rh, Ru or an alloy thereof, which has been difficult to be processed into a sphere close to a true sphere by conventional machining. Since a substantially cylindrical metal body, alloy body or sintered body is melted while rotating in an inert gas, and the molten metal continuously scattered by centrifugal force is cooled and solidified to form a sphere, Ir, Rh, Ru or their alloy spheres can be easily and inexpensively mass-produced in a short time, and productivity is improved. In addition, since melting and cooling are performed in an inert gas, the oxidation of Ir, Rh, Ru, or an alloy thereof can be suppressed, and a clean and high-quality sphere can be manufactured. Furthermore, in the method for manufacturing a wear-resistant part of the present invention, the diameter (rotation radius) and the number of rotations of a substantially cylindrical metal body, alloy body or sintered body to be rotated are changed, so that the size of the sphere to be manufactured is changed. The diameter can be adjusted. The reason why the metal body, alloy body or sintered body to be rotated has a substantially columnar shape is to make the size of the manufactured sphere as uniform as possible.

【0009】然して、本発明の耐摩耗部品の製造方法に
おいて、金属体、合金体又は焼結体の溶融を、該金属
体、合金体又は焼結体を陽極とし、これに対向設置した
電極を陽極して、アーク放電により溶融する方法を採っ
ているので、装置構成が簡便であり、瞬時に金属体、合
金体又は焼結体を溶融できて、効率がよい。
Therefore, in the method for manufacturing a wear-resistant part of the present invention, the melting of the metal body, the alloy body or the sintered body is performed by using the metal body, the alloy body or the sintered body as an anode, and mounting the electrode opposed to the anode. Since the method in which the anode is used and melting is performed by arc discharge is employed, the apparatus configuration is simple, and the metal body, alloy body, or sintered body can be melted instantaneously, and the efficiency is high.

【0010】[0010]

【発明の実施の形態】本発明の実施形態を説明すると、
先ずIr200gをアーク溶解し、次に1300℃にて
熱間鍛造、さらに1300℃の溝ロールにて直径10mm
の棒状とし、長さ50mmに切断しIrの円柱状体を得
た。次に図1に示す回転装置1を用いて前記Ir円柱体
からIrの球体の製造を行った。即ち、スピンドル2の
先端にIr円柱体3を取付けた後、図示せぬモーターを
駆動し、駆動ベルト4を介してスピンドル2を6000
rpm で回転させた。そして、Ir円柱体3を陽極とし、
Ir円柱体3の対向位置に予め設置したタングステン電
極5を陰極として40vの電圧をかけ、アーク放電を生
じさせてIr円柱体3を溶融した。溶融したIr滴6は
回転による遠心力で飛散するが、予めドラム7内に充満
したヘリウガスにより冷却されて凝固し、球体として下
部に落下する。こうして製造したIr球体8をドラム7
の下部捕集口9から捕集し、これを分級したところ、粒
径0.3〜1.6mmのIr球体8を得た。このIr球体
8は、外観上表面が滑らかで金属光沢を有し、また、電
子顕微鏡で表面を観察したところ、明確な結晶粒界が観
察され、良好な品質のIr球体8を得ることができたこ
とが確認された。このIr球体8の硬度を測定したとこ
ろ300HV程度と非常に高かった。また、長時間におよ
ぶ高温、酸化性雰囲気への放置においても、殆んど腐食
が見られなかった。
DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described.
First, 200 g of Ir was melted by an arc, then hot forged at 1300 ° C., and further 10 mm in diameter with a groove roll at 1300 ° C.
And cut into a length of 50 mm to obtain an Ir columnar body. Next, an Ir sphere was manufactured from the Ir cylinder using the rotating device 1 shown in FIG. That is, after attaching the Ir columnar body 3 to the tip of the spindle 2, a motor (not shown) is driven, and the spindle 2 is moved to 6000 through the drive belt 4.
Rotated at rpm. Then, the Ir cylinder 3 is used as an anode,
A voltage of 40 V was applied using the tungsten electrode 5 previously installed at a position facing the Ir cylinder 3 as a cathode to generate an arc discharge, thereby melting the Ir cylinder 3. The molten Ir droplet 6 is scattered by centrifugal force due to rotation, but is cooled and solidified by helium gas previously filled in the drum 7 and falls as a sphere. The Ir sphere 8 produced in this way is
Was collected from the lower collecting port 9 and classified, to obtain Ir spheres 8 having a particle size of 0.3 to 1.6 mm. The Ir spheres 8 have a smooth surface and a metallic luster in appearance, and when the surface is observed with an electron microscope, clear crystal grain boundaries are observed, so that Ir spheres 8 of good quality can be obtained. It was confirmed that. When the hardness of the Ir sphere 8 was measured, it was as high as about 300 HV. In addition, almost no corrosion was observed even when left in a high-temperature, oxidizing atmosphere for a long time.

【0011】[0011]

【発明の効果】以上の説明で判るように本発明の耐摩耗
部品は、非常に硬く、高温、酸化性雰囲気下でも非常に
腐食しにくい球体であるので、原子力関係の施設の過激
な環境でも使用し得る耐摩耗部品となる。
As can be understood from the above description, the wear-resistant part of the present invention is a sphere which is very hard and hard to corrode even in a high-temperature, oxidizing atmosphere. It becomes a wear-resistant part that can be used.

【0012】また、本発明の耐摩耗部品の製造方法は、
回転電極と不活性ガス中のアーク放電とにより球体を作
るのであるから上記の優れた耐摩耗部品を短時間に容易
に且つ安価に大量に製造できて生産性が向上する。ま
た、清浄な品質の球体の耐摩耗部品を得ることができ、
その上回転電極の大きさと回転数の調整することにより
所要の大きさの球体の耐摩耗部品を容易に得ることがで
きる。
Further, the method for producing a wear-resistant part according to the present invention comprises:
Since the sphere is formed by the rotating electrode and the arc discharge in the inert gas, the above-mentioned excellent wear-resistant parts can be easily and inexpensively mass-produced in a short time, and the productivity is improved. Also, it is possible to obtain clean quality spherical wear-resistant parts,
In addition, by adjusting the size of the rotating electrode and the number of rotations, a spherical wear-resistant part having a required size can be easily obtained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の耐摩耗部品の製造方法を実施するため
の装置の概略図である。
FIG. 1 is a schematic view of an apparatus for carrying out a method of manufacturing a wear-resistant part according to the present invention.

【符号の説明】[Explanation of symbols]

1 回転装置 2 スピンドル 3 Ir円柱体 4 駆動ベルト 5 タングステン電極 6 Ir滴 7 ドラム 8 Ir球体 9 下部捕集口 DESCRIPTION OF SYMBOLS 1 Rotating device 2 Spindle 3 Ir cylinder 4 Drive belt 5 Tungsten electrode 6 Ir drop 7 Drum 8 Ir sphere 9 Lower collection port

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 Ir、Rh、Ru又はそれらの合金の球
体より成る耐摩耗部品。
1. A wear-resistant part comprising a sphere made of Ir, Rh, Ru or an alloy thereof.
【請求項2】 Ir、Rh、Ru又はそれらの合金によ
り略円柱形状の金属体、合金体又は焼結体を作り、次に
この金属体、合金体又は焼結体を不活性ガス中で回転さ
せつつ溶融し、遠心力により飛散する溶融金属を冷却さ
せて凝固し、球体にすることを特徴とする耐摩耗部品の
製造方法。
2. A substantially cylindrical metal body, alloy body or sintered body is made of Ir, Rh, Ru or an alloy thereof, and then the metal body, alloy body or sintered body is rotated in an inert gas. A method for producing a wear-resistant part, wherein the molten metal is melted while being cooled, and the molten metal scattered by centrifugal force is cooled and solidified to form a sphere.
【請求項3】 請求項2記載の耐摩耗部品の製造方法に
おいて、金属体、合金体又は焼結体の溶融は、該金属
体、合金体又は焼結体の対向位置に電極を設置し、金属
体、合金体又は焼結体を陽極とし、前記電極を陰極とし
て、アーク放電により溶融するものであることを特徴と
する耐摩耗部品の製造方法。
3. The method for manufacturing a wear-resistant part according to claim 2, wherein the metal body, the alloy body or the sintered body is melted by disposing an electrode at a position facing the metal body, the alloy body or the sintered body; A method for producing a wear-resistant part, wherein a metal body, an alloy body, or a sintered body is used as an anode and the electrode is used as a cathode and is melted by arc discharge.
JP2000221056A 2000-07-17 2000-07-17 Wear resistant parts and method for producing the same Pending JP2002030363A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000221056A JP2002030363A (en) 2000-07-17 2000-07-17 Wear resistant parts and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000221056A JP2002030363A (en) 2000-07-17 2000-07-17 Wear resistant parts and method for producing the same

Publications (1)

Publication Number Publication Date
JP2002030363A true JP2002030363A (en) 2002-01-31

Family

ID=18715548

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000221056A Pending JP2002030363A (en) 2000-07-17 2000-07-17 Wear resistant parts and method for producing the same

Country Status (1)

Country Link
JP (1) JP2002030363A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008062785A1 (en) * 2006-11-21 2008-05-29 Furuya Metal Co., Ltd. Method for recovering ruthenium
JP2016065264A (en) * 2014-09-08 2016-04-28 石福金属興業株式会社 Method for manufacturing platinum group metal or platinum group alloy

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008062785A1 (en) * 2006-11-21 2008-05-29 Furuya Metal Co., Ltd. Method for recovering ruthenium
JP2008127629A (en) * 2006-11-21 2008-06-05 Furuya Kinzoku:Kk Method for recovering ruthenium
US8454914B2 (en) 2006-11-21 2013-06-04 Furuya Metal Co., Ltd. Method for recovering ruthenium
JP2016065264A (en) * 2014-09-08 2016-04-28 石福金属興業株式会社 Method for manufacturing platinum group metal or platinum group alloy

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