JP2001323299A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
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- JP2001323299A JP2001323299A JP2000141823A JP2000141823A JP2001323299A JP 2001323299 A JP2001323299 A JP 2001323299A JP 2000141823 A JP2000141823 A JP 2000141823A JP 2000141823 A JP2000141823 A JP 2000141823A JP 2001323299 A JP2001323299 A JP 2001323299A
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- weight
- liquid detergent
- detergent composition
- present
- alkali metal
- Prior art date
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Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、液体洗浄剤組成物
に関するものである。詳しくは、変性油汚れ等に対する
優れた洗浄力、アルミニウム等の軽金属の腐食防止効
果、および長期保存安定性を有する液体洗浄剤組成物に
関するものである。[0001] The present invention relates to a liquid detergent composition. More specifically, the present invention relates to a liquid detergent composition having an excellent detergency against denatured oil stains, an effect of preventing corrosion of light metals such as aluminum, and a long-term storage stability.
【０００２】[0002]
【従来の技術】従来から、熱、光、酸化等により変性し
た油汚れに対する洗浄剤には、洗浄成分としてアルカリ
剤、アニオンあるいはノニオン界面活性剤、グリコール
系溶剤が配合され（特開昭６２−３４９９８号公報
等）、台所、調理場等の流し台、ガスレンジ、グリル、
オーブン周辺等の硬質表面に使用されているアルミニウ
ム等の軽金属に対しての洗浄剤には、腐食防止成分とし
て珪酸アルカリ金属塩が配合された洗浄剤が主に用いら
れてきた（特開平６−２６４０９７号公報等）。しか
し、従来の洗浄剤は、洗浄力と軽金属に対する腐食防止
効果は備えているが、長期保存中に沈殿が生じる問題が
あった。この沈殿は、界面活性剤や溶剤により珪酸アル
カリ金属塩の溶解度が減少することに起因し、とくに殺
菌効果の付与を目的に配合されるカチオン界面活性剤の
存在下ではより顕著となり多量の沈殿を生成する。この
沈殿は、洗浄剤をスプレーで使用した際に、目詰まりや
被洗浄物への付着残留といった問題の原因となる。2. Description of the Related Art Conventionally, an alkaline agent, an anionic or nonionic surfactant, and a glycol-based solvent have been blended as a cleaning component in a cleaning agent for oil stains modified by heat, light, oxidation, etc. No. 34998), kitchens, kitchens, sinks, gas ranges, grills,
As a cleaning agent for a light metal such as aluminum used for a hard surface such as around an oven, a cleaning agent containing an alkali metal silicate as a corrosion inhibitor has been mainly used (Japanese Patent Laid-Open No. Hei 6-1994). No. 264097). However, although the conventional cleaning agent has a detergency and an effect of preventing corrosion of light metals, it has a problem that precipitation occurs during long-term storage. This precipitation is caused by a decrease in the solubility of the alkali metal silicate due to the surfactant and the solvent, and is particularly remarkable in the presence of a cationic surfactant incorporated for the purpose of imparting a bactericidal effect. Generate. This precipitation causes problems such as clogging and residual adhesion to an object to be cleaned when the cleaning agent is used by spraying.
【０００３】[0003]
【発明が解決しようとする課題】したがって、本発明の
目的は、変性油汚れ等に対する優れた洗浄力、アルミニ
ウム等の軽金属の腐食防止効果、および長期保存安定性
を有する液体洗浄剤組成物を提供することにある。SUMMARY OF THE INVENTION Accordingly, an object of the present invention is to provide a liquid detergent composition having excellent detergency against modified oil stains, an effect of preventing corrosion of light metals such as aluminum, and long-term storage stability. Is to do.
【０００４】[0004]
【課題を解決するための手段】本発明者らは、鋭意研究
を重ねた結果、上記の課題を解決することができた。す
なわち本発明は、組成物中で（ａ）アルカリ剤０．１〜
３０重量％、（ｂ）珪酸アルカリ金属塩０．１〜３０重
量％、（ｃ）イミダゾリニウムベタイン型界面活性剤
０．１〜３０重量％、および（ｄ）溶剤０．１〜３０重
量％を含有することを特徴とする液体洗浄剤組成物を提
供するものである。Means for Solving the Problems As a result of intensive studies, the present inventors have solved the above-mentioned problems. That is, the present invention relates to a composition in which
30% by weight, (b) 0.1 to 30% by weight of an alkali metal silicate, (c) 0.1 to 30% by weight of an imidazolinium betaine type surfactant, and (d) 0.1 to 30% by weight of a solvent The present invention provides a liquid detergent composition comprising:
【０００５】また本発明は、さらに（ｅ）カチオン界面
活性剤０．１〜３０重量％を含有することを特徴とする
前記の液体洗浄剤組成物を提供するものである。Further, the present invention provides the above-mentioned liquid detergent composition, further comprising (e) 0.1 to 30% by weight of a cationic surfactant.
【０００６】また本発明は、硬質表面用洗浄剤である前
記の液体洗浄剤組成物を提供するものである。The present invention also provides the above-mentioned liquid detergent composition which is a detergent for hard surfaces.
【０００７】[0007]
【発明の実施の形態】（ａ）アルカリ剤 本発明に使用される（ａ）アルカリ剤としては、例えば
水酸化ナトリウム、水酸化カリウム等のアルカリ金属水
酸化物；モノエタノールアミン、ジエタノールアミン、
トリエタノールアミン等のアルカノールアミン類；アン
モニア等が挙げられ、これらの１種を用いることも、２
種以上を混合して用いることもできる。なかでも水酸化
ナトリウムが好適である。（ａ）アルカリ剤の配合量
は、本発明の組成物中で０．１〜３０重量％である。好
ましくは、１．０〜１０重量％であり、さらに好ましく
は、１．０〜５．０重量％である。０．１重量％未満で
は十分な洗浄力が得られず、３０重量％を超えてもそれ
以上洗浄力が向上しない。BEST MODE FOR CARRYING OUT THE INVENTION (a) Alkali agent The (a) alkali agent used in the present invention includes, for example, alkali metal hydroxides such as sodium hydroxide and potassium hydroxide; monoethanolamine, diethanolamine,
Alkanolamines such as triethanolamine; ammonia and the like.
Mixtures of more than one species can be used. Of these, sodium hydroxide is preferred. (A) The compounding amount of the alkali agent is 0.1 to 30% by weight in the composition of the present invention. Preferably, it is 1.0 to 10% by weight, more preferably 1.0 to 5.0% by weight. If the amount is less than 0.1% by weight, sufficient detergency cannot be obtained, and if it exceeds 30% by weight, the detergency will not be further improved.
【０００８】（ｂ）珪酸アルカリ金属塩 本発明に使用される（ｂ）珪酸アルカリ金属塩は、とく
に限定されるものではないが具体例としては、下記一般
式（Ｉ）で示されるものが好適である。 (B) Alkali Metal Silicate Salt The (b) alkali metal silicate salt used in the present invention is not particularly limited, but specific examples include those represented by the following general formula (I). It is.
【０００９】[0009]
【化１】ｘＭ2Ｏ・ｙＳｉＯ2・ｚＨ2Ｏ （Ｉ）Embedded image xM 2 O.ySiO 2 .zH 2 O (I)
【００１０】（式中、ｘ、ｙ、ｚは付加モル数であり、
ｚは０〜９の整数、ｘ：ｙ＝２：１〜１：４、Ｍはカリ
ウムまたはナトリウムである）(Where x, y, and z are the number of moles added,
z is an integer of 0 to 9, x: y = 2: 1 to 1: 4, and M is potassium or sodium)
【００１１】上記一般式（Ｉ）で表される（ｂ）珪酸ア
ルカリ金属塩の具体例としては、無水メタ珪酸ナトリウ
ム、ジ珪酸ナトリウム等が挙げられ、これらの１種を用
いることも、２種以上を混合して用いることもできる。
（ｂ）珪酸アルカリ金属塩の配合量は、本発明の組成物
中で０．１〜３０重量％であり、配合性や経済性の面か
ら０．１〜１０重量％が好ましく、さらに好ましくは、
１．０〜５．０重量％である。０．１重量％未満では十
分な腐食防止効果が得られず、３０重量％を超えてもそ
れ以上腐敗防止効果が向上しない。Specific examples of the alkali metal silicate (b) represented by the above general formula (I) include anhydrous sodium metasilicate, sodium disilicate and the like. A mixture of the above can be used.
(B) The compounding amount of the alkali metal silicate is 0.1 to 30% by weight in the composition of the present invention, preferably 0.1 to 10% by weight, more preferably 0.1 to 10% by weight, from the viewpoint of mixability and economy. ,
It is 1.0 to 5.0% by weight. If it is less than 0.1% by weight, a sufficient corrosion preventing effect cannot be obtained, and if it exceeds 30% by weight, the rot preventing effect cannot be further improved.
【００１２】（ｃ）イミダゾリニウムベタイン型界面活
性剤 本発明に使用される（ｃ）イミダゾリニウムベタイン型
界面活性剤は、とくに限定されるものではないが具体例
としては、下記一般式（II）で示されるものが好適であ
る。 (C) imidazolinium betaine-type surfactant
The imidazolinium betaine type surfactant (c) used in the present invention is not particularly limited, but specific examples include those represented by the following general formula (II).
【００１３】[0013]
【化２】 Embedded image
【００１４】（式中、Ｒは炭素数５〜２１の直鎖もしく
は分岐鎖のアルキルまたはアルケニル基を示し、なかで
も炭素数１０〜１８の飽和アルキル基が好ましい。Ｒ’
は水酸基で置換されていてもよい炭素数１〜５のアルキ
ルまたはアルケニル基を示し、なかでもメチル基、エチ
ル基またはヒドロキシエチル基が好ましい。ｔは１〜５
の整数を示し、なかでも１または２が好ましい。）(In the formula, R represents a linear or branched alkyl or alkenyl group having 5 to 21 carbon atoms, and among them, a saturated alkyl group having 10 to 18 carbon atoms is preferable.
Represents an alkyl or alkenyl group having 1 to 5 carbon atoms which may be substituted with a hydroxyl group, and among them, a methyl group, an ethyl group or a hydroxyethyl group is preferable. t is 1 to 5
And an integer of 1 or 2 is preferable. )
【００１５】上記一般式（II）で表される（ｃ）イミダ
ゾリニウムベタイン型界面活性剤は、とくに限定される
ものではないが、具体例としては、１−ヤシアルキル−
２−ヒドロキシエチル−２−カルボキシメチルイミダゾ
リニウムベタイン、１−ドデシル−２−ヒドロキシエチ
ル−２−カルボキシメチルイミダゾリニウムベタイン等
が挙げられ、これらの１種を用いることも、２種以上を
混合して用いることもできる。 （ｃ）イミダゾリニウムベタイン型界面活性剤の配合量
は、本発明の組成物中で０．１〜３０重量％であり、好
ましくは０．５〜１０重量％であり、さらに好ましく
は、１．０〜５．０重量％である。０．１重量％未満で
は十分な洗浄力と沈殿防止効果が得られず、３０重量％
を超えてもそれ以上効果が向上しない。The imidazolinium betaine-type surfactant (c) represented by the general formula (II) is not particularly limited, but specific examples thereof include 1-cocoalkyl-
2-hydroxyethyl-2-carboxymethylimidazolinium betaine, 1-dodecyl-2-hydroxyethyl-2-carboxymethylimidazolinium betaine, and the like. One of these can be used, or two or more can be used. It can also be used. (C) The compounding amount of the imidazolinium betaine type surfactant is 0.1 to 30% by weight, preferably 0.5 to 10% by weight, more preferably 1 to 10% by weight in the composition of the present invention. 0.0 to 5.0% by weight. If the amount is less than 0.1% by weight, sufficient detergency and the effect of preventing precipitation cannot be obtained.
Even if it exceeds, the effect does not improve any more.
【００１６】（ｄ）溶剤 本発明に使用される（ｄ）溶剤は、とくに限定されるも
のではないが具体例としては、下記一般式（III）で表
されるものが好適である。 (D) Solvent The solvent (d) used in the present invention is not particularly limited, but specific examples include those represented by the following general formula (III).
【００１７】[0017]
【化３】 Ｒ1−Ｏ−（Ｃ2Ｈ4Ｏ）m−（Ｃ3Ｈ6Ｏ）n−Ｈ （III）Embedded image R 1 —O— (C 2 H 4 O) m — (C 3 H 6 O) n —H (III)
【００１８】（式中、Ｒ1は炭素数１〜６の直鎖または
分岐状のアルキル基であり、ｍとｎは０〜１０の整数で
あり同時に０ではない）(Wherein, R 1 is a linear or branched alkyl group having 1 to 6 carbon atoms, m and n are integers of 0 to 10 and not simultaneously 0)
【００１９】上記一般式（III）で表される（ｄ）溶剤
の具体例としては、ジエチレングリコールモノエチルエ
ーテル、ジエチレングリコールモノブチルエーテル、プ
ロピレングリコールモノエチルエーテル、プロピレング
リコールモノブチルエーテル等が挙げられ、これらの１
種を用いることも、２種以上を混合して用いることもで
きる。（ｄ）溶剤の配合量は、本発明の組成物中で０．
１〜３０重量％である。好ましくは、５．０〜２０重量
％であり、さらに好ましくは、５．０〜１０．０重量％
である。０．１重量％未満では十分な洗浄力が得られ
ず、３０重量％を超えてもそれ以上洗浄力が向上しな
い。Specific examples of the solvent (d) represented by the general formula (III) include diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monoethyl ether, and propylene glycol monobutyl ether.
Seeds may be used, or two or more kinds may be used in combination. (D) The compounding amount of the solvent is 0.1% in the composition of the present invention.
1 to 30% by weight. Preferably, it is 5.0 to 20% by weight, more preferably 5.0 to 10.0% by weight.
It is. If the amount is less than 0.1% by weight, sufficient detergency cannot be obtained, and if it exceeds 30% by weight, the detergency will not be further improved.
【００２０】（ｅ）カチオン界面活性剤 本発明の液体洗浄剤組成物には、殺菌成分として、上記
（ａ）〜（ｄ）成分以外に（ｅ）カチオン界面活性剤を
配合することができる。（ｅ）カチオン界面活性剤は、
（ｂ）珪酸アルカリ金属塩の溶解度に悪影響を及ぼし、
（ｅ）カチオン界面活性剤未配合時より多くの沈殿を生
成するが、本発明では、（ｃ）イミダゾリニウムベタイ
ン型界面活性剤の配合によりこの点も解消できることを
見出した。（ｅ）カチオン界面活性剤の具体例として
は、ラウリルジメチルベンジルアンモニウムクロライ
ド、ジデシルジメチルアンモニウムクロライド等が挙げ
られ、これらの１種を用いることも、２種以上を混合し
て用いることもできる。（ｅ）カチオン界面活性剤の配
合量は、本発明の組成物中で０．１〜３０重量％であ
り、好ましくは０．５〜１０重量％であり、さらに好ま
しくは、１．０〜５．０重量％である。０．１重量％未
満では十分な殺菌力が得られず、３０重量％を超えても
それ以上殺菌力が向上しない。 (E) Cationic Surfactant The liquid detergent composition of the present invention may contain (e) a cationic surfactant as a bactericidal component in addition to the components (a) to (d). (E) a cationic surfactant,
(B) adversely affects the solubility of the alkali metal silicate,
(E) More precipitates are formed than when no cationic surfactant is blended. In the present invention, it has been found that this point can be solved by blending (c) imidazolinium betaine type surfactant. (E) Specific examples of the cationic surfactant include lauryl dimethyl benzyl ammonium chloride, didecyl dimethyl ammonium chloride, and the like. One of these can be used, or two or more can be used in combination. (E) The compounding amount of the cationic surfactant is 0.1 to 30% by weight, preferably 0.5 to 10% by weight, more preferably 1.0 to 5% by weight in the composition of the present invention. 0.0% by weight. If the amount is less than 0.1% by weight, sufficient bactericidal power cannot be obtained, and if it exceeds 30% by weight, the bactericidal power cannot be further improved.
【００２１】本発明の液体洗浄剤組成物には、必要に応
じて本発明の効果を損なわない範囲内で、任意成分とし
て、各種界面活性剤、殺菌剤、有機キレート剤、粘度調
整剤（粘土鉱物、アクリル系ポリマー、無水マレイン酸
系ポリマー、カルボキシメチルセルロース等）、香料、
色素、酸化防止剤、可溶化剤、その他添加剤を配合でき
る。The liquid detergent composition of the present invention may optionally contain various surfactants, bactericides, organic chelating agents, viscosity modifiers (clays) as long as the effects of the present invention are not impaired. Minerals, acrylic polymers, maleic anhydride polymers, carboxymethyl cellulose, etc.), fragrances,
Dyes, antioxidants, solubilizers, and other additives can be added.
【００２２】本発明の液体洗浄剤組成物は、上記（ａ）
〜（ｄ）成分および任意成分を混合し、水溶液として調
製する。水溶液のｐＨは、１１以上が好ましい。The liquid detergent composition of the present invention comprises the above (a)
(D) Component and optional component are mixed to prepare an aqueous solution. The pH of the aqueous solution is preferably 11 or more.
【００２３】本発明の液体洗浄剤組成物は、とくに硬質
表面の洗浄に適している。硬質表面とは、例えば、台
所、調理場等の壁面や床面、流し台、ガスレンジ、グリ
ル、オーブン等の表面および内面が挙げられ、その材質
としては、アルミニウム、ステンレス等の軽金属が挙げ
られる。The liquid detergent composition of the present invention is particularly suitable for cleaning hard surfaces. The hard surface includes, for example, walls and floors of kitchens, kitchens, and the like, surfaces and inner surfaces of sinks, gas ranges, grills, ovens, and the like, and examples of the material include light metals such as aluminum and stainless steel.
【００２４】[0024]
【実施例】以下、本発明を実施例により具体的に説明す
るが、本発明はこれらに限定されるものではない。表１
（実施例１〜９）および表２（比較例１〜９）に示す配
合組成の液体洗浄剤組成物を調製した。得られた各組成
物について、洗浄性、アルミ腐食防止性、および保存安
定性を、それぞれ下記の測定法に従い評価した。結果は
表１、２に示した。EXAMPLES Hereinafter, the present invention will be described in more detail with reference to Examples, but the present invention is not limited thereto. Table 1
Liquid detergent compositions having the composition shown in (Examples 1 to 9) and Table 2 (Comparative Examples 1 to 9) were prepared. For each of the obtained compositions, the detergency, the aluminum corrosion inhibitory property, and the storage stability were evaluated according to the following measurement methods. The results are shown in Tables 1 and 2.
【００２５】（液体洗浄剤組成物の調製）実施例１ 水に、水酸化ナトリウム、トリエタノールアミン、無水
メタ珪酸ナトリウム、１−ヤシアルキル−２−ヒドロキ
シエチル−２−カルボキシメチルイミダゾリニウムベタ
イン、ジエチレングリコールモノブチルエーテルを順に
加え、常温下でマグネットスターラーを用い攪拌しなが
ら液体洗浄剤組成物を調製した。実施例２〜９および比
較例１〜９も上記と同様に、水に、表１または２に示す
配合成分を加え、常温下で攪拌しながら各液体洗浄剤組
成物を調製した。(Preparation of Liquid Detergent Composition) Example 1 In water, sodium hydroxide, triethanolamine, anhydrous sodium metasilicate, 1-cocoalkyl-2-hydroxyethyl-2-carboxymethylimidazolinium betaine, diethylene glycol Monobutyl ether was added in order, and a liquid detergent composition was prepared at room temperature with stirring using a magnetic stirrer. In the same manner as in Examples 2 to 9 and Comparative Examples 1 to 9, the components shown in Table 1 or 2 were added to water, and each liquid detergent composition was prepared while stirring at room temperature.
【００２６】＜洗浄性試験方法＞大豆油０．１ｇをステ
ンレス板（ＳＵＳ３０４）に塗布し、２００℃で３時間
の焼付けを行った。このステンレス板を表１および２に
示す種々の液体洗浄剤組成物２５ｍｌに浸漬し、１０分
間放置した。この洗浄率をステンレス板の洗浄前後の重
量変化により算出し、次の尺度で表１および２に示し
た。 （重量変化） ◎：１００〜８０％ ○： ８０〜６０％ △： ６０〜４０％ ×： ４０〜 ０％<Method for Testing Detergency> 0.1 g of soybean oil was applied to a stainless steel plate (SUS304) and baked at 200 ° C. for 3 hours. This stainless steel plate was immersed in 25 ml of various liquid detergent compositions shown in Tables 1 and 2, and left for 10 minutes. This cleaning rate was calculated from the change in weight of the stainless steel plate before and after cleaning, and is shown in Tables 1 and 2 on the following scale. (Weight change) ：: 100 to 80% ：: 80 to 60% Δ: 60 to 40% ×: 40 to 0%
【００２７】＜アルミ腐食防止性試験方法＞表１および
２に示す種々の液体洗浄剤組成物の１０重量％水溶液中
に、清浄なアルミニウム板（Ａ５０５２Ｐ）を浸漬し、
１時間後引き上げ、すすぎ、乾燥した。この操作を３回
繰り返し、アルミニウム板の状態変化より評価し、次の
尺度で表１および２に示した。 （状態変化） ◎：浸漬３回まで変化無し ○：浸漬１回まで変化無し ×：浸漬１回で表面が変色<Aluminum Corrosion Inhibition Test Method> A clean aluminum plate (A5052P) was immersed in a 10% by weight aqueous solution of various liquid detergent compositions shown in Tables 1 and 2.
After 1 hour, it was pulled up, rinsed and dried. This operation was repeated three times and evaluated based on the change in the state of the aluminum plate. The results are shown in Tables 1 and 2 on the following scale. (State change) ：: No change up to 3 dippings ○: No change up to 1 dipping ×: Surface discoloration after 1 dipping
【００２８】＜保存安定性試験方法＞表１および２に示
す種々の液体洗浄剤組成物をポリプロピレン製の容器に
入れ、室温および４０℃に保存した。この保存中におけ
る液体の状態変化により評価し、次の尺度で表１および
２に示した。 （状態変化） ◎：１ヶ月以上、沈殿物無し △：１ヶ月間以内に、沈殿が生成した ×：１週間以内に、沈殿が生成した<Storage stability test method> Various liquid detergent compositions shown in Tables 1 and 2 were placed in polypropylene containers and stored at room temperature and 40 ° C. Evaluations were made based on changes in the state of the liquid during storage, and are shown in Tables 1 and 2 on the following scale. (State change) ： １: 1 month or more, no precipitate △: Within 1 month, precipitate was formed ×: Within 1 week, precipitate was formed
【００２９】[0029]
【表１】 [Table 1]
【００３０】[0030]
【表２】 [Table 2]
【００３１】[0031]
【発明の効果】本発明によれば、変性油汚れ等に対する
優れた洗浄力、アルミニウム等の軽金属の腐食防止効
果、および長期保存安定性を有する液体洗浄剤組成物が
提供される。According to the present invention, there is provided a liquid detergent composition having excellent detergency against denatured oil stains, an effect of preventing corrosion of light metals such as aluminum, and long-term storage stability.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 ＦＩ テーマコート゛(参考） Ｃ１１Ｄ 3/43 Ｃ１１Ｄ 3/43 17/08 17/08 (72)発明者 小根 仁 東京都荒川区東尾久７丁目２番35号 株式 会社アデカクリーンエイド内 Ｆターム(参考） 4H003 AC08 AC15 AD04 AD05 AE05 BA12 DA05 EA15 EA21 EB14 ED02 ED29 FA15 FA16 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI theme coat ゛ (Reference) C11D 3/43 C11D 3/43 17/08 17/08 (72) Inventor Jin Jin Higashi Oku, Arakawa-ku, Tokyo 7-2-35 Fade term in Adeka Clean Aid Co., Ltd. (Reference) 4H003 AC08 AC15 AD04 AD05 AE05 BA12 DA05 EA15 EA21 EB14 ED02 ED29 FA15 FA16
Claims (3)
０重量％、（ｂ）珪酸アルカリ金属塩０．１〜３０重量
％、（ｃ）イミダゾリニウムベタイン型界面活性剤０．
１〜３０重量％、および（ｄ）溶剤０．１〜３０重量％
を含有することを特徴とする液体洗浄剤組成物。1. The composition according to claim 1, wherein (a) the alkali agent is 0.1 to 3;
0% by weight, (b) 0.1 to 30% by weight of an alkali metal silicate, (c) imidazolinium betaine surfactant.
1 to 30% by weight, and (d) 0.1 to 30% by weight of the solvent
A liquid detergent composition comprising:
〜３０重量％を含有することを特徴とする請求項１に記
載の液体洗浄剤組成物。2. The method according to claim 1, further comprising (e) a cationic surfactant 0.1.
The liquid detergent composition according to claim 1, wherein the composition comprises about 30% by weight.
２に記載の液体洗浄剤組成物。3. The liquid detergent composition according to claim 1, which is a hard surface detergent.
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| JP2000141823A JP4488458B2 (en) | 2000-05-15 | 2000-05-15 | Liquid detergent composition |
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|---|---|---|---|
| JP2000141823A JP4488458B2 (en) | 2000-05-15 | 2000-05-15 | Liquid detergent composition |
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| JP4488458B2 JP4488458B2 (en) | 2010-06-23 |
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|---|---|---|---|
| JP2000141823A Expired - Fee Related JP4488458B2 (en) | 2000-05-15 | 2000-05-15 | Liquid detergent composition |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003253298A (en) * | 2002-02-27 | 2003-09-10 | Nicca Chemical Co Ltd | Method for striping and washing magnetic card |
| JP2004149677A (en) * | 2002-10-30 | 2004-05-27 | Sanyo Chem Ind Ltd | Liquid bleaching detergent composition |
| JP2004189874A (en) * | 2002-12-11 | 2004-07-08 | Kao Corp | Germicidal detergent composition |
| US20080207893A1 (en) * | 2005-05-12 | 2008-08-28 | Lars Erik Berglund | Process For Grinding Cellulose Ether |
| JP2009114156A (en) * | 2007-11-09 | 2009-05-28 | Kao Corp | Liquid cleanser composition |
| JP2011026532A (en) * | 2009-06-26 | 2011-02-10 | Unitika Ltd | Cleaning liquid for polyamide resin molded article and cleaning method to use the same |
| JP2015048418A (en) * | 2013-09-02 | 2015-03-16 | トヨタ自動車株式会社 | Engine cleaning composition and engine cleaning method |
| JP2018002907A (en) * | 2016-07-04 | 2018-01-11 | 油化産業株式会社 | Detergent composition |
| JP2020070389A (en) * | 2018-11-01 | 2020-05-07 | 花王株式会社 | Detergent composition for aluminum based metallic articles |
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| JPH11181475A (en) * | 1997-12-17 | 1999-07-06 | Kao Corp | Detergent composition for automatic dishwasher |
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| JPH01312090A (en) * | 1988-06-13 | 1989-12-15 | Dai Ichi Kogyo Seiyaku Co Ltd | Detergent for metal stock for working and deterging method |
| JPH10219283A (en) * | 1997-02-13 | 1998-08-18 | Lion Corp | Detergent composition for wire drawing |
| JPH11181475A (en) * | 1997-12-17 | 1999-07-06 | Kao Corp | Detergent composition for automatic dishwasher |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003253298A (en) * | 2002-02-27 | 2003-09-10 | Nicca Chemical Co Ltd | Method for striping and washing magnetic card |
| JP2004149677A (en) * | 2002-10-30 | 2004-05-27 | Sanyo Chem Ind Ltd | Liquid bleaching detergent composition |
| JP2004189874A (en) * | 2002-12-11 | 2004-07-08 | Kao Corp | Germicidal detergent composition |
| US20080207893A1 (en) * | 2005-05-12 | 2008-08-28 | Lars Erik Berglund | Process For Grinding Cellulose Ether |
| US9523014B2 (en) * | 2005-05-12 | 2016-12-20 | Akzo Nobel N.V. | Process for grinding cellulose ether |
| JP2009114156A (en) * | 2007-11-09 | 2009-05-28 | Kao Corp | Liquid cleanser composition |
| JP2011026532A (en) * | 2009-06-26 | 2011-02-10 | Unitika Ltd | Cleaning liquid for polyamide resin molded article and cleaning method to use the same |
| JP2015048418A (en) * | 2013-09-02 | 2015-03-16 | トヨタ自動車株式会社 | Engine cleaning composition and engine cleaning method |
| JP2018002907A (en) * | 2016-07-04 | 2018-01-11 | 油化産業株式会社 | Detergent composition |
| JP2020070389A (en) * | 2018-11-01 | 2020-05-07 | 花王株式会社 | Detergent composition for aluminum based metallic articles |
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