JP2001298126A - Wiring substrate and electronic component using the same - Google Patents

Wiring substrate and electronic component using the same

Info

Publication number
JP2001298126A
JP2001298126A JP2000114314A JP2000114314A JP2001298126A JP 2001298126 A JP2001298126 A JP 2001298126A JP 2000114314 A JP2000114314 A JP 2000114314A JP 2000114314 A JP2000114314 A JP 2000114314A JP 2001298126 A JP2001298126 A JP 2001298126A
Authority
JP
Japan
Prior art keywords
insulating layer
insulating
powder
organic material
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000114314A
Other languages
Japanese (ja)
Inventor
Tadashi Nagasawa
忠 長澤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyocera Corp
Original Assignee
Kyocera Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyocera Corp filed Critical Kyocera Corp
Priority to JP2000114314A priority Critical patent/JP2001298126A/en
Publication of JP2001298126A publication Critical patent/JP2001298126A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48225Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • H01L2224/48227Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation connecting the wire to a bond pad of the item

Landscapes

  • Parts Printed On Printed Circuit Boards (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Production Of Multi-Layered Print Wiring Board (AREA)

Abstract

PROBLEM TO BE SOLVED: To solve problems of low impact resistance and cracks since an insulation base constituting an electronic component consists of ceramics, and of low dielectric constant and that an electronic component cannot be miniaturized. SOLUTION: A wiring substrate 4 is formed by laminating a plurality of insulation layers 1a, 1b, 1c, 1d, 1e up and down which consist of inorganic insulation powder of 10 to 70 wt.% and organic material of 30 to 90 wt.% and are formed by binding inorganic insulation powder by organic material, and applying a wiring conductor 2 among the insulation layers 1a, 1b, 1c, 1d, 1e and/or to exposed insulation layers 1a, 1b, 1c, 1d, 1e surfaces. At least one layer of the insulating layers 1a, 1b, 1c, 1d, 1e has permittivity in upper and lower surface direction of 30 or more and at least a pair of counter electrode 3 are disposed between the upper and lower surfaces. Since the insulation base 1 is formed by binding inorganic insulation powder by organic material which is excellent in tenacity, cracks or the like are not generated in the insulation base 1 even if the wiring substrate 4 collide hard against each other.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、各種AV機器や家
電機器・通信機器・コンピュータとその周辺機器等の電
子機器に使用される配線基板ならびに電子部品に関する
ものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a wiring board and electronic components used for electronic devices such as various AV devices, home appliances, communication devices, computers, and peripheral devices thereof.

【0002】[0002]

【従来の技術】一般に、現在の電子部品は、移動体通信
機器に代表されるように小型・軽量・薄型・高性能・高
機能・高品質・高信頼性が要求されており、このような
電子部品に用いられる配線基板も小型化が要求されるよ
うになってきている。
2. Description of the Related Art Generally, current electronic components are required to be small, light, thin, high-performance, high-performance, high-quality, and high-reliable, as represented by mobile communication devices. Wiring boards used for electronic components have also been required to be reduced in size.

【0003】このような配線基板、例えば、半導体素子
を収容する半導体素子収納用パッケージに使用される配
線基板は、酸化アルミニウム質焼結体等のセラミックス
から成る絶縁層が複数層積層されているとともにその上
面中央部に半導体素子を収容する凹部を有する絶縁基体
と、絶縁基体の凹部周辺から下面にかけて導出されたタ
ングステン・モリブデン等の高融点金属から成る配線導
体とから構成されており、絶縁基体の凹部底面に半導体
素子をガラス・樹脂・ロウ材等の接着剤を介して接着固
定するとともに半導体素子の各電極(電源電極・接地電
極・信号電極)を例えばボンディングワイヤ等の電気的
接続手段を介して配線導体に電気的に接続し、しかる
後、絶縁基体の上面に、金属やセラミックス等から成る
蓋体を絶縁基体の凹部を塞ぐようにしてガラス・樹脂・
ロウ材等の封止材を介して接合させ、絶縁基体の凹部内
に半導体素子を気密に収容することによって製品として
の半導体装置と成り、配線導体の絶縁基体下面に導出し
た部位を外部電気回路基板の配線導体に接続することに
よって半導体素子の各電極が外部電気回路基板に電気的
に接続されることと成る。
Such a wiring board, for example, a wiring board used for a package for housing a semiconductor element for housing a semiconductor element has a plurality of insulating layers made of ceramics such as a sintered body of aluminum oxide. An insulating substrate having a concave portion for accommodating a semiconductor element in the center of the upper surface, and a wiring conductor made of a high melting point metal such as tungsten and molybdenum led out from the periphery of the concave portion to the lower surface of the insulating substrate. The semiconductor element is bonded and fixed to the bottom surface of the concave portion with an adhesive such as glass, resin, brazing material, etc., and each electrode (power supply electrode, ground electrode, signal electrode) of the semiconductor element is connected via an electrical connection means such as a bonding wire. To electrically connect to the wiring conductor, and then, on the upper surface of the insulating base, place a lid made of metal, ceramics, etc. on the upper surface of the insulating base. A block way, glass, resin,
A semiconductor device as a product is formed by joining a semiconductor element in a concave portion of the insulating base in an airtight manner by joining through a sealing material such as a brazing material, and a portion of the wiring conductor led out to the lower surface of the insulating base is an external electric circuit. Each electrode of the semiconductor element is electrically connected to the external electric circuit board by connecting to the wiring conductor of the board.

【0004】また、この従来の配線基板では、半導体素
子に接続される電源電圧および接地電源の変動によって
半導体素子に誤動作が生じないようにする目的で、絶縁
基体内部に絶縁基体を構成する絶縁層の一つを挟んで互
いに対向するタングステン・モリブデン等の高融点金属
粉末から成る広面積の一対の対向電極を配設することに
より、一対の対向電極間に静電容量素子を形成し、対向
電極の一方を半導体素子の電源電極に、他方を半導体素
子の接地電極に電気的に接続することにより半導体素子
に接続される電源電圧の変動を抑制するようになってい
る。
Further, in this conventional wiring board, an insulating layer constituting an insulating base inside the insulating base is provided in order to prevent a malfunction of the semiconductor element due to a fluctuation of a power supply voltage and a ground power supply connected to the semiconductor element. By disposing a pair of wide-area opposed electrodes made of a high melting point metal powder such as tungsten and molybdenum opposed to each other with one of them sandwiched, a capacitance element is formed between the pair of opposed electrodes, One is electrically connected to the power supply electrode of the semiconductor element and the other is electrically connected to the ground electrode of the semiconductor element, so that the fluctuation of the power supply voltage connected to the semiconductor element is suppressed.

【0005】さらに、この配線基板では、一対の対向電
極の間に挟まれる絶縁層にタングステン・モリブデン等
の高融点金属粉末を分散させ、絶縁層の誘電率を高いも
のとすることにより一対の対向電極間に形成される容量
素子に大きな静電容量を付与する工夫もなされている。
Further, in this wiring board, a high melting point metal powder such as tungsten and molybdenum is dispersed in an insulating layer sandwiched between a pair of opposing electrodes, thereby increasing the dielectric constant of the insulating layer to form a pair of opposing electrodes. A device for providing a large capacitance to a capacitor formed between electrodes has also been devised.

【0006】なお、従来の配線基板は、セラミックグリ
ーンシート積層法によって製作され、具体的には、酸化
アルミニウム・酸化珪素・酸化マグネシウム・酸化カル
シウム等のセラミック原料粉末に適当な有機バインダ・
溶剤等を添加混合して泥漿状となすとともにこれを従来
周知のドクタブレード法を採用してシート状とすること
によって複数のセラミックグリーンシートを得、しかる
後、セラミックグリーンシートに適当な打抜き加工を施
すとともに配線導体および対向電極と成る金属ぺースト
を所定パターンに印刷塗布し、最後にセラミックグリー
ンシートを所定の順に積層して生セラミック成型体とな
すとともに生セラミック成型体を還元雰囲気中約1600℃
の高温で焼成することによって製作される。
A conventional wiring board is manufactured by a ceramic green sheet laminating method. Specifically, an organic binder suitable for a ceramic raw material powder such as aluminum oxide, silicon oxide, magnesium oxide, and calcium oxide is used.
A plurality of ceramic green sheets are obtained by adding and mixing a solvent or the like to form a slurry and forming the sheet into a sheet shape by employing a conventionally known doctor blade method. Thereafter, an appropriate punching process is performed on the ceramic green sheet. Apply and paste the metal paste that will be the wiring conductor and the counter electrode in a predetermined pattern, and finally laminate the ceramic green sheets in a predetermined order to form a green ceramic molded body and place the green ceramic molded body in a reducing atmosphere at about 1600 ° C.
It is manufactured by firing at a high temperature.

【0007】[0007]

【発明が解決しようとする課題】しかしながら、この従
来の配線基板は、絶縁基体を構成する酸化アルミニウム
質焼結体等のセラミックスが硬くて脆い性質を有するた
め、搬送工程や半導体装置製作の自動ライン等において
配線基板同士が、あるいは配線基板と半導体装置製作自
動ラインの一部とが激しく衝突すると絶縁基体に欠けや
割れ・クラック等が発生し、その結果、半導体素子を気
密に収容することができず、半導体素子を長期間にわた
り正常、かつ安定に作動させることができなくなるとい
う欠点を有していた。
However, in this conventional wiring board, since the ceramics such as the aluminum oxide sintered body constituting the insulating base have a hard and brittle property, the automatic wiring of the transfer process and the semiconductor device manufacturing is difficult. When the wiring boards collide with each other or the wiring board and a part of the semiconductor device manufacturing automatic line violently collide with each other, chips, cracks, cracks, etc. occur in the insulating base, and as a result, the semiconductor element can be housed in an airtight manner. In addition, the semiconductor device cannot operate normally and stably for a long period of time.

【0008】また、この従来の配線基板は、絶縁基体を
構成する酸化アルミニウム質焼結体等の比誘電率がせい
ぜい10程度と低いため、絶縁基体内部に絶縁基体を構成
する絶縁層を挟んで一対の対向電極を対向させることに
より形成される容量素子に大きな静電容量を付与するこ
とが困難であり、その結果、大きな静電容量を得るため
には対向電極の面積を大きなものとする必要があり、配
線基板を小型化することが困難であるという問題点を有
していた。
Further, in this conventional wiring board, since the relative dielectric constant of an aluminum oxide sintered body or the like constituting the insulating base is as low as about 10 at most, the insulating layer constituting the insulating base is sandwiched inside the insulating base. It is difficult to provide a large capacitance to a capacitor formed by facing a pair of counter electrodes, and as a result, the area of the counter electrode needs to be large in order to obtain a large capacitance. There is a problem that it is difficult to reduce the size of the wiring board.

【0009】なお、一対の対向電極の間に挟まれる絶縁
層にタングステン・モリブデン等の高融点金属粉末を分
散させて絶縁層の誘電率を大きなものとした場合でも、
分散させる高融点金属粉末の量を増加させることによ
り、絶縁層の比誘電率を徐々に大きなものとすることが
できるものの、絶縁層内で高融点金属粉末同士が接触し
て対向電極間に電気的短絡が発生したり、あるいは容量
素子の耐電圧性が低下してしまい半導体素子を正常、か
つ安定に作動させることができないという問題点を有し
ていた。
[0009] Even when a high melting point metal powder such as tungsten and molybdenum is dispersed in an insulating layer sandwiched between a pair of opposing electrodes to increase the dielectric constant of the insulating layer,
By increasing the amount of the refractory metal powder to be dispersed, the relative dielectric constant of the insulating layer can be gradually increased, but the refractory metal powders in the insulating layer come into contact with each other and the electric power is applied between the opposing electrodes. There is a problem that a short circuit occurs or the withstand voltage of the capacitance element is reduced, so that the semiconductor element cannot be operated normally and stably.

【0010】また、一対の対向電極間に挟まれる絶縁層
を、例えばチタン酸バリウム磁器等の高誘電体材料で形
成し、対向電極間の電気的絶縁を保ちつつ対向電極間に
形成される容量素子の静電容量を大きなものとすること
も考えられるが、この場合、チタン酸バリウム等の高誘
電体材料は、その焼成温度や焼成雰囲気、あるいは焼成
収縮率が酸化アルミニウム質焼結体やタングステン・モ
リブデン等の高融点金属粉末の焼成温度や焼成雰囲気、
あるいは焼成収縮率と大きく異なることから、酸化アル
ミニウム質焼結体やタングステン・モリブデン等の高融
点金属粉末との同時焼成が困難であり、所定の配線基板
を得ることができないという問題点を有していた。
The insulating layer sandwiched between the pair of counter electrodes is formed of a high dielectric material such as barium titanate porcelain, and a capacitor formed between the counter electrodes while maintaining electrical insulation between the counter electrodes. It is conceivable to increase the capacitance of the element. In this case, however, a high-dielectric material such as barium titanate has a firing temperature, a firing atmosphere, or a firing shrinkage rate of an aluminum oxide sintered body or tungsten.・ Firing temperature and firing atmosphere of high melting point metal powder such as molybdenum,
Alternatively, since it is significantly different from the firing shrinkage, it is difficult to fire simultaneously with a high melting point metal powder such as an aluminum oxide-based sintered body or tungsten / molybdenum, so that a predetermined wiring board cannot be obtained. I was

【0011】このような問題点を解決するために、無機
誘電体粉末を有機樹脂で結合して成る高誘電率の複合材
料が提案されている(特開平11−68322号公報)。しか
しながら、この複合材料においてもその比誘電率は20程
度と低いものであり、含有する誘電体粉末の比誘電率を
十分に発現させることができず、その結果、大きな静電
容量を得るために対向電極の面積を大きくする必要があ
り、小型の配線基板を得ることができないという問題点
を有していた。
In order to solve such a problem, there has been proposed a composite material having a high dielectric constant obtained by binding an inorganic dielectric powder with an organic resin (Japanese Patent Laid-Open No. 11-68322). However, the relative permittivity of this composite material is as low as about 20, and the relative permittivity of the dielectric powder contained therein cannot be sufficiently exhibited. As a result, in order to obtain a large capacitance, There is a problem that the area of the counter electrode needs to be increased, and a small-sized wiring board cannot be obtained.

【0012】本発明は、かかる従来技術の問題点に鑑み
案出されたものであり、その目的は、高誘電率の配線基
板を用いた耐衝撃性に優れた小型の電子部品を提供する
ことにある。
The present invention has been devised in view of the problems of the prior art, and has as its object to provide a small-sized electronic component excellent in impact resistance using a wiring board having a high dielectric constant. It is in.

【0013】[0013]

【課題を解決するための手段】本発明の配線基板は、10
〜70重量%の無機絶縁粉末と30〜90重量%の有機材料と
から成り、無機絶縁粉末を有機材料により結合して成る
絶縁層を複数層、上下に積層させるとともに絶縁層間お
よび/または露出する絶縁層表面に配線導体を被着して
成る配線基板であって、絶縁層は少なくとも一層の上下
面方向の比誘電率が30以上であり、かつその上下面間に
少なくとも一対の対向電極が配設されていることを特徴
とするものである。
According to the present invention, there is provided a wiring board comprising:
Up to 70% by weight of an inorganic insulating powder and 30 to 90% by weight of an organic material, wherein a plurality of insulating layers are formed by combining the inorganic insulating powder with an organic material, and a plurality of insulating layers are laminated one above another, and the insulating layers are exposed and / or exposed. What is claimed is: 1. A wiring board comprising a wiring conductor provided on a surface of an insulating layer, wherein the insulating layer has a relative dielectric constant of at least one of upper and lower surfaces of 30 or more, and at least one pair of opposing electrodes disposed between upper and lower surfaces. It is characterized by being provided.

【0014】また、本発明の配線基板は、上下面方向の
比誘電率が30以上の絶縁層が10〜70重量%の誘電体粉末
と30〜90重量%の異方誘電性を有する有機材料とから成
り、その比誘電率の最大と成る方向の比誘電率が誘電体
粉末の比誘電率の1/100〜1/2であることを特徴と
するものである。
Further, the wiring board of the present invention is characterized in that an insulating layer having a relative dielectric constant of 30 or more in the vertical direction has a dielectric powder of 10 to 70% by weight and an organic material having an anisotropic dielectric of 30 to 90% by weight. Wherein the relative permittivity in the direction in which the relative permittivity is maximum is 1/100 to 1/2 of the relative permittivity of the dielectric powder.

【0015】さらに、本発明の電子部品は、上記配線基
板と、配線基板に搭載され、配線導体と電気的に接続さ
れた電子素子とから成ることを特徴とするものである。
Further, an electronic component according to the present invention is characterized by comprising the above-mentioned wiring board and an electronic element mounted on the wiring board and electrically connected to a wiring conductor.

【0016】本発明の配線基板によれば、絶縁基体が無
機絶縁粉末や誘電体粉末を靭性に優れる有機材料で結合
することによって形成されていることから、配線基板同
士あるいは配線基板と半導体装置製作自動ラインの一部
とが激しく衝突しても絶縁基体に欠けや割れ・クラック
等が発生することはなく、また、比誘電率が30以上の絶
縁層の上下面間に少なくとも一対の対向電極を配設させ
たことから、その一対の対向電極間に静電容量の大きな
容量素子を得ることができる。
According to the wiring substrate of the present invention, since the insulating base is formed by bonding inorganic insulating powder or dielectric powder with an organic material having excellent toughness, the wiring substrates or the wiring substrate and the semiconductor device are manufactured. Even if a part of the automatic line collides violently, the insulating substrate does not chip, crack, crack, etc. With this arrangement, a capacitor having a large capacitance can be obtained between the pair of opposed electrodes.

【0017】また、本発明の電子部品によれば、大きな
静電容量を得るために対向電極の面積を必要以上に大き
くする必要はなく、小型の電子部品とすることができ
る。
Further, according to the electronic component of the present invention, it is not necessary to increase the area of the counter electrode more than necessary in order to obtain a large capacitance, and a small electronic component can be obtained.

【0018】[0018]

【発明の実施の形態】次に、本発明の配線基板ならびに
電子部品を添付の図面に基づき詳細に説明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, a wiring board and an electronic component according to the present invention will be described in detail with reference to the accompanying drawings.

【0019】図1は本発明の配線基板に、電子素子とし
て半導体素子を搭載した場合の電子部品の一例を示す断
面図である。この図において、1は絶縁基体、2は配線
導体、3は対向電極であり、主にこれらで配線基板4が
構成される。また、5は半導体素子であり、主に配線基
板4と半導体素子5とで本発明の電子部品6が構成され
る。
FIG. 1 is a sectional view showing an example of an electronic component when a semiconductor element is mounted as an electronic element on the wiring board of the present invention. In this figure, 1 is an insulating base, 2 is a wiring conductor, 3 is a counter electrode, and the wiring board 4 is mainly composed of these. Reference numeral 5 denotes a semiconductor element, and the electronic component 6 of the present invention mainly includes the wiring board 4 and the semiconductor element 5.

【0020】絶縁基体1は、本例では5層の絶縁層1a、
1b、1c、1d、1eが積層されて成り、その上面中央部に半
導体素子5を収容するための段状の凹部Aを有してお
り、凹部A底面には半導体素子5が樹脂等の接着剤を介
して接着固定される。
In this embodiment, the insulating substrate 1 has five insulating layers 1a,
1b, 1c, 1d and 1e are laminated, and a stepped recess A for accommodating the semiconductor element 5 is provided in the center of the upper surface thereof. It is adhesively fixed via an agent.

【0021】また、絶縁基体1を構成する絶縁層1a、1
b、1c、1d、1eのうち少なくとも1層(この図の例では
絶縁層1d)は、その上下面方向の比誘電率が30以上の絶
縁層から成り、後述するように絶縁層1dの上下面に一対
の対向電極3を配設し、対向電極3間に容量素子を形成
した場合、容量素子の静電容量は絶縁層1dの上下面方向
の比誘電率が30以上と高いことから極めて大きなものと
なすことができる。
The insulating layers 1a, 1a constituting the insulating base 1 are
At least one of the layers b, 1c, 1d, and 1e (the insulating layer 1d in the example of this figure) is formed of an insulating layer having a relative dielectric constant of 30 or more in the upper and lower surface directions. When a pair of opposing electrodes 3 are provided on the lower surface and a capacitance element is formed between the opposing electrodes 3, the capacitance of the capacitance element is extremely high because the relative permittivity in the upper and lower direction of the insulating layer 1d is as high as 30 or more. It can be big.

【0022】また、絶縁層1dに含有される誘電体粉末
は、電気を通さないことから、絶縁層1dを挟んで対向す
る対向電極3間に電気的短絡や耐電圧性の低下が起こる
ことは一切ない。
Since the dielectric powder contained in the insulating layer 1d does not conduct electricity, there is no possibility that an electric short circuit or a decrease in withstand voltage occurs between the opposing electrodes 3 opposed to each other with the insulating layer 1d interposed therebetween. Not at all.

【0023】絶縁基体1を構成する絶縁層1a、1b、1c、
1eは、酸化アルミニウム・窒化珪素・窒化アルミニウム
・炭化珪素・酸化チタン・酸化バリウム・酸化ストロン
チウム・酸化ジルコニウム・酸化カルシウム・ゼオライ
ト等の無機絶縁粉末を、エポキシ樹脂・フェノール樹脂
・ポリイミド樹脂・ビスマレイミド樹脂・熱硬化性ポリ
フェニレンエーテル樹脂等の熱硬化性樹脂や液晶ポリエ
ステル・ポリフェニレンエーテル系樹脂等の熱可塑性樹
脂により結合することによって形成されており、後述す
る絶縁層1dとともにその各々が無機絶縁粉末を靭性に優
れる熱硬化性樹脂や熱可塑性樹脂等の有機材料で結合す
ることによって形成されていることから、絶縁基体1に
外力が印加されても外力により絶縁基体1に欠けや割れ
・クラックが発生することはない。
The insulating layers 1a, 1b, 1c,
1e is an inorganic insulating powder of aluminum oxide, silicon nitride, aluminum nitride, silicon carbide, titanium oxide, barium oxide, strontium oxide, zirconium oxide, calcium oxide, zeolite, etc., epoxy resin, phenol resin, polyimide resin, bismaleimide resin It is formed by bonding with a thermosetting resin such as a thermosetting polyphenylene ether resin or a thermoplastic resin such as a liquid crystal polyester / polyphenylene ether-based resin, and each of them, together with an insulating layer 1d described below, is made of inorganic toughness powder. Is formed by bonding with an organic material such as a thermosetting resin or a thermoplastic resin, which is excellent in heat resistance, so that even if an external force is applied to the insulating base 1, the insulating base 1 may be chipped, cracked, or cracked by the external force. Never.

【0024】絶縁基体1は、例えば粒径が0.1〜15μm
程度の酸化アルミニウム・窒化珪素・窒化アルミニウム
・炭化珪素・酸化チタン・酸化バリウム・酸化ストロン
チウム・酸化ジルコニウム・酸化カルシウム等の無機絶
縁粉末に、エポキシ樹脂・フェノール樹脂・ポリイミド
樹脂・ビスマレイミド樹脂・熱硬化性ポリフェニレンエ
ーテル樹脂等の熱硬化性樹脂または液晶ポリエステル・
ポリフェニレンエーテル系樹脂等の熱可塑性樹脂と溶剤
・可塑剤・分散剤等を添加して得たペーストを従来周知
のドクタブレード法等のシート成型法を採用してシート
状となすことによって絶縁基体1における絶縁層1a、1
b、1c、1eとなる複数の前駆体シートを得るとともにこ
の絶縁層1a、1b、1c、1eとなる前駆体シートと後述する
絶縁層1dとなる前駆体シートの各々に必要に応じて適当
な打抜き加工を従来周知のパンチング法を採用して施
し、これらの打抜き加工が施された絶縁層1a、1b、1c、
1d、1eを所定の順に積層圧着し、最後に、積層圧着され
た絶縁層1a、1b、1c、1d、1eを約 100〜300℃の温度・
0.4〜10MPaの圧力で30分〜24時間ホットプレスし
て、これを熱硬化させることによって製作される。
The insulating substrate 1 has, for example, a particle size of 0.1 to 15 μm.
Inorganic insulating powder such as aluminum oxide, silicon nitride, aluminum nitride, silicon carbide, titanium oxide, barium oxide, strontium oxide, zirconium oxide, calcium oxide, epoxy resin, phenol resin, polyimide resin, bismaleimide resin, and thermosetting Thermosetting resin such as reactive polyphenylene ether resin or liquid crystal polyester
A paste obtained by adding a thermoplastic resin such as a polyphenylene ether-based resin and a solvent, a plasticizer, a dispersant, and the like is formed into a sheet by employing a conventionally known sheet forming method such as a doctor blade method. Insulating layers 1a, 1 in
b, 1c, and a plurality of precursor sheets to be used as the insulating layers 1a, 1b, 1c, and 1e, and a precursor sheet to be the insulating layer 1d as described below. The punching process is performed by using a conventionally known punching method, and the insulating layers 1a, 1b, 1c,
1d and 1e are laminated and crimped in a predetermined order, and finally, the laminated and crimped insulating layers 1a, 1b, 1c, 1d and 1e are heated at a temperature of about 100 to 300 ° C.
It is manufactured by hot-pressing at a pressure of 0.4 to 10 MPa for 30 minutes to 24 hours and thermally curing the same.

【0025】上下面方向の比誘電率が30以上の絶縁層1d
は、10〜70重量%の誘電体粉末と30〜90重量%の異方誘
電性を有する有機材料とから成り、誘電体粉末が10重量
%より少ないと比誘電率が30よりも小さなものと成る傾
向があり、また、70重量%を超えると有機樹脂の量が少
なくなり複合部材の強度が低下してしまう傾向がある。
したがって、誘電体粉末と有機材料の配合比を誘電体粉
末10〜70重量%・有機材料30〜90重量%とすることが好
ましい。
An insulating layer 1d having a relative dielectric constant of 30 or more in the vertical direction.
Is composed of 10 to 70% by weight of a dielectric powder and 30 to 90% by weight of an organic material having anisotropic dielectric property. When the dielectric powder is less than 10% by weight, the relative dielectric constant is smaller than 30. When the content exceeds 70% by weight, the amount of the organic resin decreases, and the strength of the composite member tends to decrease.
Therefore, it is preferable that the compounding ratio between the dielectric powder and the organic material be 10 to 70% by weight of the dielectric powder and 30 to 90% by weight of the organic material.

【0026】なお、絶縁基体1を構成する絶縁層1a、1
b、1c、1eは、含有される無機絶縁粉末の含有量を絶縁
層1dに含有される誘電体粉末の含有量と略一致させるこ
とが好ましい。無機絶縁粉末の含有量と誘電体粉末の含
有量とが大きく異なると、絶縁層1dと他の絶縁層1a、1
b、1c、1eの熱膨張係数が大きく異なってしまい、半導
体素子4が作動時に発熱し、この熱が絶縁層1dと他の
絶縁層1a、1b、1c、1eの両者に印加されると、両者間に
両者の熱膨張係数の相違に起因する大きな応力が発生
し、この応力によって両者間で剥離したり、絶縁層1dや
絶縁層1a、1b、1c、1eに割れや欠けが発生してしまう傾
向がある。したがって、絶縁層1a、1b、1c、1eに含有さ
れる無機絶縁粉末の量は、絶縁層1dに含有される誘電体
材料の含有量と略一致させることが好ましい。
The insulating layers 1a, 1a constituting the insulating base 1
As for b, 1c, and 1e, it is preferable that the content of the inorganic insulating powder contained is made substantially the same as the content of the dielectric powder contained in the insulating layer 1d. If the content of the inorganic insulating powder and the content of the dielectric powder are significantly different, the insulating layer 1d and the other insulating layers 1a, 1
When the thermal expansion coefficients of b, 1c, and 1e are significantly different, the semiconductor element 4 generates heat during operation, and when this heat is applied to both the insulating layer 1d and the other insulating layers 1a, 1b, 1c, and 1e, A large stress is generated between the two due to the difference in the coefficient of thermal expansion between them, and this stress causes separation between the two or cracks or chips occur in the insulating layer 1d or the insulating layers 1a, 1b, 1c, 1e. There is a tendency. Therefore, it is preferable that the amount of the inorganic insulating powder contained in the insulating layers 1a, 1b, 1c, and 1e substantially coincides with the content of the dielectric material contained in the insulating layer 1d.

【0027】絶縁層1dは、比誘電率が100〜5000程度の
酸化チタン・酸化バリウム・酸化ストロンチウム・酸化
ジルコニウム・酸化カルシウム等の無機系誘電体粉末や
これらの化合物・混合物、チタン酸カリウムウィスカ・
ホウ酸アルミニウムウィスカ・針状酸化チタン・シリカ
アルミナ繊維・アルミナ繊維等の繊維状高誘電体粉末、
チタン酸バリウム・チタン酸カルシウム・スズ酸バリウ
ム・ジルコン酸バリウム・ジルコン酸ストロンチウム等
の高誘電体粉末を、異方誘電性を有するとともに分子中
に配向性部位を有し、かつ分子の主軸方向の比誘電率ε
Pと主軸方向と直交する方向の比誘電率εVの比εP/εV
が1.2〜10である有機材料により結合することによって
形成されている。
The insulating layer 1d is made of an inorganic dielectric powder such as titanium oxide, barium oxide, strontium oxide, zirconium oxide, calcium oxide or the like having a relative dielectric constant of about 100 to 5,000, or a compound or mixture thereof, or a potassium titanate whisker.
Fibrous high dielectric powder such as aluminum borate whisker, acicular titanium oxide, silica alumina fiber, alumina fiber, etc.
High dielectric powders such as barium titanate, calcium titanate, barium stannate, barium zirconate, and strontium zirconate have anisotropic dielectric properties, have orientational sites in the molecule, and have the principal axis direction of the molecule. Relative permittivity ε
The ratio ε P / ε V of P and the relative permittivity ε V in the direction orthogonal to the main axis direction
Are formed by bonding with an organic material of 1.2 to 10.

【0028】絶縁層1dに使用される誘電体粉末は、誘電
体粉末の比誘電率が 100未満であると、絶縁層1dの比誘
電率が30よりも小さなものとなる傾向があり、また、50
00を超えると絶縁層1dの誘電損失が大きなものとなって
しまう傾向がある。したがって、誘電体粉末の比誘電率
は100〜5000の範囲であることが好ましい。
When the dielectric powder used for the insulating layer 1d has a relative dielectric constant of less than 100, the relative dielectric constant of the insulating layer 1d tends to be smaller than 30. 50
If it exceeds 00, the dielectric loss of the insulating layer 1d tends to be large. Therefore, the relative permittivity of the dielectric powder is preferably in the range of 100 to 5,000.

【0029】なお、誘電体粉末の平均粒子径は、絶縁層
1dの耐熱性の観点からは0.1μm以上であることが、ま
た、絶縁層1d表面の平滑性の観点からは15μm以下であ
ることが好ましく、好適には0.3〜10μmの範囲である
ことが好ましい。
The average particle size of the dielectric powder is determined by the thickness of the insulating layer.
It is preferably 0.1 μm or more from the viewpoint of the heat resistance of 1d, and preferably 15 μm or less, and more preferably 0.3 to 10 μm, from the viewpoint of the smoothness of the surface of the insulating layer 1d. .

【0030】また、異方誘電性を有する有機材料として
は、フェノール樹脂・エポキシ系樹脂・ポリイミド樹脂
・不飽和ポリエステル系樹脂・ビスマレイミド−トリア
ジン樹脂等のトリアジン系樹脂・熱硬化変成を施したポ
リフェニレンエーテル系樹脂等の熱硬化性樹脂や、ポリ
エチレン・ポリスチレン・ポリカーボネート・ポリエチ
レンテレフタレート・ポリアミド・ポリスチレンサルフ
ァイド・ポリエチレンナフタレート・ポリアリルサルホ
ン・ポリアリルエーテルケトン・液晶ポリエステル・ポ
リフェニレンエーテル系樹脂等の熱可塑性樹脂が用いら
れ、耐湿性や寸法精度の観点からは液晶ポリエステルに
代表される液晶ポリマーが好ましい。
Examples of the organic material having anisotropic dielectric properties include phenol resin, epoxy resin, polyimide resin, unsaturated polyester resin, triazine resin such as bismaleimide-triazine resin, and polyphenylene subjected to thermosetting denaturation. Thermosetting resins such as ether resins, and thermoplastics such as polyethylene, polystyrene, polycarbonate, polyethylene terephthalate, polyamide, polystyrene sulfide, polyethylene naphthalate, polyallyl sulfone, polyallyl ether ketone, liquid crystal polyester, and polyphenylene ether resins A resin is used, and a liquid crystal polymer represented by a liquid crystal polyester is preferable from the viewpoint of moisture resistance and dimensional accuracy.

【0031】絶縁層1dは、例えば、平均粒子径が0.1〜1
5μm低度のチタン酸バリウムやチタン酸カルシウム・
スズ酸バリウム・ジルコン酸バリウム・ジルコン酸スト
ロンチウム等の誘電体粉末に、エポキシ樹脂・フェノー
ル樹脂・ポリイミド樹脂・ビスマレイミド樹脂・熱硬化
性ポリフェニレンエーテル樹脂等の熱硬化性樹脂あるい
は液晶ポリエステル・ポリフェニレンエーテル系樹脂等
の熱可塑性樹脂と、適当な溶剤・可塑剤・分散剤等を添
加して得たペーストを従来周知のドクタブレード法等の
シート成型法を採用してシート状となすとともに、60〜
100℃の温度で5分〜3時間加熱して絶縁基体1の絶縁
層1dとなる半硬化状の前駆体シートを得、さらに半硬化
状の前駆体シートの上下面にめっき法や金属箔を転写す
る転写法等を採用して金属電極を被着させ、この金属電
極間に60〜100℃の温度で1〜20KV/mmの直流電圧
を30分〜24時間印加することにより有機材料の分子を直
流電圧を印加した方向に配向させ、最後に、金属電極を
エッチングやラッピングにより取り除くことにより、上
下面方向の誘電率が30以上の絶縁基体1の絶縁層1dと成
る前駆体シートが製作される。
The insulating layer 1d has, for example, an average particle diameter of 0.1 to 1
5μm low barium titanate or calcium titanate
Thermosetting resins such as epoxy resin, phenolic resin, polyimide resin, bismaleimide resin, thermosetting polyphenylene ether resin, or liquid crystal polyester / polyphenylene ether based dielectric powder such as barium stannate / barium zirconate / strontium zirconate A thermoplastic resin such as a resin, and a paste obtained by adding an appropriate solvent, plasticizer, dispersant, and the like are formed into a sheet by employing a conventionally known sheet forming method such as a doctor blade method.
By heating at a temperature of 100 ° C. for 5 minutes to 3 hours, a semi-cured precursor sheet to be the insulating layer 1d of the insulating substrate 1 is obtained, and a plating method or a metal foil is applied to the upper and lower surfaces of the semi-cured precursor sheet. A metal electrode is adhered by using a transfer method for transferring, and a DC voltage of 1 to 20 KV / mm is applied between the metal electrodes at a temperature of 60 to 100 ° C. for 30 minutes to 24 hours, thereby forming molecules of the organic material. Is oriented in the direction to which a DC voltage is applied, and finally, the metal electrode is removed by etching or lapping, whereby a precursor sheet serving as the insulating layer 1d of the insulating substrate 1 having a dielectric constant of 30 or more in the vertical direction is manufactured. You.

【0032】一般に、有機材料の分子は棒状の形状を有
するとともに双極子モーメントを有しており、有機材料
の分子に外部より直流の高電圧を印加して双極子モーメ
ントの方向を略同一方向に揃えて配向させた場合、分子
の配向した方向において大きな比誘電率を示すようにな
る。さらに、このような有機樹脂の分子が配向した状態
の絶縁層1d中に含有される誘電体粉末は、その双極子モ
ーメントの方向も容易に同じ方向に揃う傾向があり、そ
の結果、有機材料の分子の双極子モーメントの方向が揃
った方向における絶縁層1dの比誘電率を誘電体粉末の比
誘電率の1/100〜1/2とすることができる。絶縁層1
dの比誘電率が誘電体粉末の比誘電率の1/100未満であ
ると、30以上の高い比誘電率を得ることが困難と成る傾
向があり、また、1/2を超えると誘電損失が大きなも
のとなってしまう傾向がある。したがって、有機材料の
分子の双極子モーメントの方向が揃った方向における絶
縁層1dの比誘電率は誘電体粉末の比誘電率の1/100〜
1/2であることが好ましい。
In general, molecules of an organic material have a rod-like shape and have a dipole moment. When a high DC voltage is applied to the molecules of the organic material from the outside, the direction of the dipole moment is substantially the same. When aligned and aligned, a large relative dielectric constant is exhibited in the direction in which the molecules are aligned. Furthermore, the dielectric powder contained in the insulating layer 1d in such a state that the molecules of the organic resin are oriented tends to easily align the dipole moment in the same direction. The relative dielectric constant of the insulating layer 1d in the direction in which the dipole moments of the molecules are aligned can be set to 1/100 to 1/2 of the relative dielectric constant of the dielectric powder. Insulation layer 1
If the relative permittivity of d is less than 1/100 of the relative permittivity of the dielectric powder, it tends to be difficult to obtain a high relative permittivity of 30 or more. Tend to be large. Therefore, the relative dielectric constant of the insulating layer 1d in the direction in which the dipole moment directions of the molecules of the organic material are aligned is 1/100 to the relative dielectric constant of the dielectric powder.
Preferably it is 1/2.

【0033】なお、ここで配向性部位とは、主に剛直性
のP置換の芳香族環や直線性のビフェニル、シクロヘキ
シル系・置換ナフチル系の芳香族環から成るものであ
り、分子中にこれらの配向性部位を有することにより、
分子は細長い棒状あるいは平板状の形状となり良好な配
向性を有することとなる。
The term "orientation site" here mainly means a rigid P-substituted aromatic ring or a linear biphenyl, cyclohexyl- or substituted naphthyl-based aromatic ring. By having an orientation site of
The molecules have an elongated rod-like or plate-like shape and have good orientation.

【0034】また、絶縁層1dに使用される有機材料は、
その分子中に配向性部位を有するとともに分子の主軸方
向の比誘電率εPと主軸方向と直交する方向の比誘電率
εVの比εP/εVが1.2〜10であることが好ましい。
The organic material used for the insulating layer 1d is as follows:
It is preferable that the molecule has an oriented site and that the ratio ε P / ε V of the relative dielectric constant ε P in the principal axis direction of the molecule and the relative dielectric constant ε V in the direction orthogonal to the principal axis direction be 1.2 to 10.

【0035】有機樹脂が配向性部位を有しない場合、有
機樹脂を良好に配向させることが困難と成り、30以上の
高い比誘電率を得ることが困難と成る傾向がある。した
がって、絶縁層1dに使用される有機材料は、その分子中
に配向性部位を有することが好ましい。また、有機材料
の分子の主軸方向における比誘電率εPと主軸方向と直
交する方向における比誘電率εVの比εP/εVが1.2未満
であると、有機材料が良好に配向することが困難と成
り、その結果、30以上の高い比誘電率を得ることが困難
と成る傾向があり、10を超えると有機材料の分子の配向
の程度が大きなものとなりすぎ、温度サイクル試験等の
信頼性試験の際の絶縁層1dの熱膨張・熱収縮の際に発生
する応力によって、有機樹脂の分子が配向した方向に沿
ってクラックが発生したり破断したりし易くなる傾向が
ある。したがって、分子の主軸方向の比誘電率εPと主
軸方向と直交する方向の比誘電率εVの比εP/εVを1.2
〜10の範囲とすることが好ましい。
When the organic resin does not have an oriented portion, it becomes difficult to orient the organic resin satisfactorily, and it tends to be difficult to obtain a high relative dielectric constant of 30 or more. Therefore, the organic material used for the insulating layer 1d preferably has an oriented site in the molecule. In addition, when the ratio ε P / ε V of the relative permittivity ε P of the molecules of the organic material in the main axis direction and the relative permittivity ε V in the direction orthogonal to the main axis direction is less than 1.2, the organic material is well oriented. Tends to be difficult, and as a result, it is difficult to obtain a high relative dielectric constant of 30 or more, and if it exceeds 10, the degree of orientation of the molecules of the organic material becomes too large, and the reliability of the temperature cycle test etc. There is a tendency that cracks are generated or broken along the direction in which the molecules of the organic resin are oriented due to the stress generated at the time of thermal expansion and thermal contraction of the insulating layer 1d in the performance test. Therefore, the ratio ε P / ε V of the relative permittivity ε P of the molecule in the principal axis direction to the relative permittivity ε V in the direction orthogonal to the principal axis direction is 1.2.
It is preferably in the range of 10 to 10.

【0036】なお、分子の主軸方向とは、分子の比誘電
率が一番高く発現される方向であり、通常は分子中の原
子が一番長く連なっている主鎖方向である。さらに、分
子の直交する方向とは直交する全ての方向を示す。
The term "major axis direction of a molecule" refers to a direction in which the relative dielectric constant of the molecule is the highest, and is usually the direction of the main chain in which atoms in the molecule are the longest. Further, the direction orthogonal to the molecule indicates all directions orthogonal to each other.

【0037】また、絶縁基体1を構成する絶縁層1a、1
b、1c、1d、1eでは、有機材料と無機絶縁粉末の親和性
を高め、これらの接合性向上と絶縁基体1の機械的強度
を高める目的で、絶縁基体1と成る絶縁層1a、1b、1c、
1d、1eにシラン系カップリング剤やチタネート系カップ
リング剤等のカップリング剤を1種類以上添加してもよ
い。
The insulating layers 1a, 1a constituting the insulating base 1
In b, 1c, 1d, and 1e, the insulating layers 1a, 1b, and 1b serving as the insulating base 1 are provided for the purpose of increasing the affinity between the organic material and the inorganic insulating powder, improving the bonding properties thereof, and increasing the mechanical strength of the insulating base 1. 1c,
One or more coupling agents such as a silane coupling agent and a titanate coupling agent may be added to 1d and 1e.

【0038】なお、絶縁層1a、1b、1c、1eと成る前駆体
シートを形成する樹脂および硬化剤を絶縁層1dと成る前
駆体シートを形成する樹脂および硬化剤と同じ樹脂およ
び硬化剤を使用することにより、絶縁層1dと成る前駆体
シートと絶縁層1a、1b、1c、1eと成る前駆体シートとを
同じ硬化条件で同時に熱硬化させることが可能と成り、
これにより容量素子を構成するための対向電極3の間に
挟まれる絶縁層1dを特別な困難を伴うことなく絶縁基体
1中に一体に形成することができる。
The same resin and hardener as the resin and hardener forming the precursor sheet forming the insulating layer 1d are used as the resin forming the precursor sheet forming the insulating layers 1a, 1b, 1c and 1e. By doing so, it becomes possible to simultaneously heat-cure the precursor sheet to be the insulating layer 1d and the precursor sheet to be the insulating layers 1a, 1b, 1c, and 1e under the same curing conditions,
Thus, the insulating layer 1d sandwiched between the opposing electrodes 3 for forming the capacitive element can be integrally formed in the insulating base 1 without any special difficulty.

【0039】このような絶縁基体1には、絶縁層1b上面
で凹部Aの段上から絶縁層1b、1c、1d、1eを貫通して絶
縁層1eの下面に導出する、銅、銀、金等の金属粉末を
エポキシ樹脂等の熱硬化性樹脂やポリフェニレンエーテ
ル系樹脂等の熱可塑性樹脂等の有機材料により結合した
配線導体2が被着形成されている。
Such an insulating substrate 1 includes copper, silver, and gold that pass through the insulating layers 1b, 1c, 1d, and 1e from the upper surface of the insulating layer 1b and pass through the insulating layers 1b, 1c, 1d, and 1e to the lower surface of the insulating layer 1e. A wiring conductor 2 is formed by bonding a metal powder such as an epoxy resin or the like with an organic material such as a thermosetting resin such as an epoxy resin or a thermoplastic resin such as a polyphenylene ether-based resin.

【0040】配線導体2は、内部に収容する半導体素子
4を外部電気回路に電気的に接続する作用をなし、配線
導体2で凹部Aの段上部位には半導体素子5の電極(電
源電極・接地電極・信号電極)がボンディングワイヤ7
を介して電気的に接続され、絶縁層1eの下面に導出する
部位は外部電気回路基板の配線導体に電気的に接続され
る。
The wiring conductor 2 serves to electrically connect the semiconductor element 4 housed therein to an external electric circuit, and the electrode of the semiconductor element 5 (power supply electrode Ground electrode / signal electrode) is bonding wire 7
Are electrically connected to each other, and a portion extending to the lower surface of the insulating layer 1e is electrically connected to a wiring conductor of an external electric circuit board.

【0041】配線導体2に含有される金属粉末は、配線
導体2に導電性を付与する作用をなし、配線導体2にお
ける含有量が70重量%未満では配線導体2の導電性が低
下する傾向にあり、また含有量が95重量%を超えると金
属粉末を熱硬化性樹脂や熱可塑性樹脂で強固に結合する
ことが困難となる傾向がある。したがって、配線導体2
に含有される金属粉末は、70〜95重量%の範囲が好まし
い。
The metal powder contained in the wiring conductor 2 has an effect of imparting conductivity to the wiring conductor 2, and when the content in the wiring conductor 2 is less than 70% by weight, the conductivity of the wiring conductor 2 tends to decrease. If the content exceeds 95% by weight, it tends to be difficult to firmly bond the metal powder with a thermosetting resin or a thermoplastic resin. Therefore, the wiring conductor 2
Is preferably in the range of 70 to 95% by weight.

【0042】また、配線導体2は、その含有する熱硬化
性樹脂や熱可塑性樹脂として絶縁層1a、1b、1c、1d、1e
に含有される熱硬化性樹脂や熱可塑性樹脂と同様な樹脂
を使用することにより、絶縁層1a、1b、1c、1d、1eに良
好に被着形成される。
The wiring conductor 2 is made of insulating layers 1a, 1b, 1c, 1d, 1e as thermosetting resin or thermoplastic resin contained therein.
By using the same resin as the thermosetting resin or the thermoplastic resin contained in the insulating layer, the insulating layers 1a, 1b, 1c, 1d, and 1e can be satisfactorily adhered and formed.

【0043】さらに、配線導体2は、その露出する表面
にニッケル・金等の耐蝕性に優れ、かつ良導電性の金属
をめっき法により1.0〜20μmの厚みに被着させておく
と配線導体2の酸化腐蝕を有効に防止することができる
とともに配線導体2とボンディングワイヤ7とを強固に
電気的に接続させることができる。したがって、配線導
体2の露出する表面には、ニッケルや金等の耐蝕性に優
れ、かつ良導電性の金属をめっき法により1.0〜20μm
の厚みに被着させておくことが好ましい。
Further, the wiring conductor 2 may be provided with a metal having excellent corrosion resistance, such as nickel or gold, and a good conductivity by a plating method to a thickness of 1.0 to 20 μm on the exposed surface. Can be effectively prevented, and the wiring conductor 2 and the bonding wire 7 can be firmly electrically connected. Therefore, on the exposed surface of the wiring conductor 2, a metal having excellent corrosion resistance and good conductivity, such as nickel or gold, is applied by plating to a thickness of 1.0 to 20 μm.
It is preferable that the film is adhered to a thickness of 10 mm.

【0044】なお、配線導体2は、例えば配線導体2に
含有される金属粉末が銅で、有機材料がエポキシ樹脂か
ら成る場合、粒径が0.1〜10μm程度の銅粉末にエポキ
シ樹脂およびアミン系硬化剤等の硬化剤を添加混合しぺ
ースト状となすとともにぺーストを絶縁基体1となる半
硬化状シートに従来周知のスクリーン印刷法等を採用し
て所定パターンに印刷し、これを絶縁基体1となる半硬
化状シートともに熱硬化させることにより絶縁基体1の
所定位置に被着形成される。
When the metal powder contained in the wiring conductor 2 is copper and the organic material is an epoxy resin, for example, the copper powder having a particle size of about 0.1 to 10 μm is added to the wiring resin 2 by epoxy resin and amine curing. A paste is added to a semi-cured sheet serving as the insulating base 1 in a predetermined pattern by using a well-known screen printing method or the like. The semi-cured sheet is heat-cured together with the semi-cured sheet to be formed at a predetermined position on the insulating substrate 1.

【0045】さらに、絶縁基体1内部には、絶縁層1dを
挟んで一対の対向電極3が配設されており、一対の対向
電極3の一方は配線導体2のうち半導体素子5の電源電
極に接続される配線導体2に、他方は配線導体2のうち
半導体素子5の接地電極に接続される配線導体2に電気
的に接続されている。
Further, a pair of opposing electrodes 3 are disposed inside the insulating base 1 with the insulating layer 1 d interposed therebetween, and one of the pair of opposing electrodes 3 is connected to the power supply electrode of the semiconductor element 5 of the wiring conductor 2. The other end of the wiring conductor 2 is electrically connected to the wiring conductor 2 connected to the ground electrode of the semiconductor element 5.

【0046】一対の対向電極3は、例えば、銅、銀、金
等の金属粉末を熱硬化性樹脂や熱可塑性樹脂等により結
合して成り、対向電極3間に、絶縁層1dの誘電率および
絶縁層1dの厚みに応じた静電容量を有する容量素子を形
成する作用をなす。
The pair of opposing electrodes 3 are made of, for example, a metal powder such as copper, silver, or gold bonded by a thermosetting resin or a thermoplastic resin. It functions to form a capacitance element having a capacitance according to the thickness of the insulating layer 1d.

【0047】対向電極3間に挟まれた絶縁層1dは、前述
したように比誘電率が30以上と高い誘電率を有すること
から、対向電極3間に極めて大きな静電容量の容量素子
を形成することができ、この大きな静電容量の容量素子
により半導体素子5の誤動作を有効に防止することがで
きる。また、絶縁層1dに含有する誘電体粉末の種類を変
更する等により絶縁層1dの比誘電率を大きくすることに
より、対向電極3の面積を小さくすることができ、配線
基板4を小型化することが可能となる。
Since the insulating layer 1d sandwiched between the opposing electrodes 3 has a high dielectric constant of 30 or more as described above, a capacitive element having an extremely large capacitance is formed between the opposing electrodes 3. The malfunction of the semiconductor element 5 can be effectively prevented by the capacitive element having the large capacitance. In addition, by increasing the relative dielectric constant of the insulating layer 1d by changing the type of dielectric powder contained in the insulating layer 1d, the area of the counter electrode 3 can be reduced, and the size of the wiring board 4 can be reduced. It becomes possible.

【0048】対向電極3に含有される金属粉末は、対向
電極3に導電性を付与する作用をなし、対向電極3にお
ける含有量が70重量%未満では対向電極3の導電性が低
下する傾向にあり、また含有量が95重量%を超えると金
属粉末を熱硬化性樹脂や熱可塑性樹脂で強固に結合する
ことが困難となる傾向がある。したがって、対向電極3
に含有される金属粉末は、70〜95重量%の範囲が好まし
い。
The metal powder contained in the counter electrode 3 acts to impart conductivity to the counter electrode 3, and when the content in the counter electrode 3 is less than 70% by weight, the conductivity of the counter electrode 3 tends to decrease. If the content exceeds 95% by weight, it tends to be difficult to firmly bond the metal powder with a thermosetting resin or a thermoplastic resin. Therefore, the counter electrode 3
Is preferably in the range of 70 to 95% by weight.

【0049】なお、絶縁層1a、1b、1c、1d、1eの表面に
形成される配線導体2や対向電極3を銅・金等から成る
金属箔で形成してもよく、絶縁層1a、1b、1c、1d、1eと
成る前駆体シートにあらかじめ転写法等により被着形成
してもよい。
The wiring conductor 2 and the counter electrode 3 formed on the surface of the insulating layers 1a, 1b, 1c, 1d, 1e may be formed of a metal foil made of copper, gold, or the like. , 1c, 1d, and 1e may be previously formed on the precursor sheet by a transfer method or the like.

【0050】さらに、半導体素子5を絶縁基体1の凹部
Aの底面に樹脂・ガラス・ロウ材等の接着剤を介して接
着固定するとともに半導体素子5の各電極をボンディン
グワイヤ7を介して凹部Aの段上部位に位置する配線導
体2に電気的に接続し、しかる後、半導体素子5を蓋体
8で凹部A内に気密に封止することにより製品としての
電子部品となる。
Further, the semiconductor element 5 is bonded and fixed to the bottom surface of the concave portion A of the insulating base 1 with an adhesive such as resin, glass, brazing material or the like, and each electrode of the semiconductor element 5 is bonded via the bonding wire 7 to the concave portion A. Then, the semiconductor element 5 is hermetically sealed in the recess A with the lid 8 to provide an electronic component as a product.

【0051】かくして本発明によれば、配線基板4が無
機絶縁粉末を靭性に優れる有機材料で結合することによ
って形成されていることから、耐衝撃性が良好な配線基
板4とすることができる。また、比誘電率が30以上の絶
縁層の上下面間に対向電極3が配設されていることか
ら、この対向電極3間に静電容量の大きな容量素子を形
成でき、小型の電子部品6とすることができる。
Thus, according to the present invention, since the wiring board 4 is formed by bonding the inorganic insulating powder with the organic material having excellent toughness, the wiring board 4 having good impact resistance can be obtained. Further, since the opposing electrode 3 is disposed between the upper and lower surfaces of the insulating layer having a relative dielectric constant of 30 or more, a capacitive element having a large capacitance can be formed between the opposing electrodes 3, and a small electronic component 6 can be formed. It can be.

【0052】なお、本発明の配線基板は上述の実施例に
限定されるものではなく、本発明の要旨を逸脱しない範
囲であれば種々の変更は可能であり、たとえば、上述の
実施例では5層の絶縁層を積層することによって配線基
板を製作したが、4層以下、あるいは6層以上の絶縁層
を積層して配線基板を製作してもよい。また、絶縁層1
a、1b、1c、1d、1eの強度を高めるために補強材とし
て、絶縁層1a、1b、1c、1d、1eにガラス繊維や酸化珪素
・酸化アルミニウム・窒化アルミニウム等の無機質フィ
ラーを添加してもよい。無機質フィラーは絶縁層1a、1
b、1c、1d、1eの強度を補強するとともにその表面を平
滑にする作用をなし、好適には平均粒子径が10μm以下
の略球状の粉末が用いられる。
The wiring board of the present invention is not limited to the above-described embodiment, and various modifications can be made without departing from the scope of the present invention. Although the wiring board is manufactured by stacking the insulating layers, the wiring board may be manufactured by stacking four or less insulating layers or six or more insulating layers. Insulating layer 1
As a reinforcing material to increase the strength of a, 1b, 1c, 1d, 1e, an inorganic filler such as glass fiber or silicon oxide / aluminum oxide / aluminum nitride is added to the insulating layers 1a, 1b, 1c, 1d, 1e. Is also good. The inorganic filler is the insulating layer 1a, 1
It has the effect of reinforcing the strength of b, 1c, 1d, and 1e and smoothing the surface, and is preferably a substantially spherical powder having an average particle diameter of 10 μm or less.

【0053】さらに、熱安定性を改善するための酸化防
止剤や耐光性を改善するための紫外線吸収剤等の光安定
剤、難燃性を改善するためのハロゲン系もしくはリン酸
系の難燃性剤、アンチモン系化合物やホウ酸亜鉛・メタ
ホウ酸バリウム・酸化ジルコニウム等の難燃助剤、潤滑
性を改善するための高級脂肪酸や高級脂肪酸エステル・
高級脂肪酸金属塩・フルオロカーボン系界面活性剤等の
外部滑材硬化を有するもの等を1種以上添加してもよ
い。
Further, a light stabilizer such as an antioxidant for improving thermal stability and an ultraviolet absorber for improving light resistance, and a halogen-based or phosphoric-based flame retardant for improving flame retardancy. Agents, antimony compounds, flame retardant aids such as zinc borate, barium metaborate and zirconium oxide, higher fatty acids and higher fatty acid esters to improve lubricity.
One or more compounds having an external lubricant hardening such as a higher fatty acid metal salt or a fluorocarbon surfactant may be added.

【0054】[0054]

【発明の効果】本発明の配線基板によれば、絶縁基体が
無機絶縁粉末や誘電体粉末を靭性に優れる有機材料で結
合することによって形成されていることから、配線基板
同士あるいは配線基板と半導体装置製作自動ラインの一
部とが激しく衝突しても絶縁基体に欠けや割れ・クラッ
ク等が発生することはなく、また、比誘電率が30以上の
複合部材から成る絶縁層の上下面間に少なくとも一対の
対向電極を配設させたことから、その一対の対向電極間
に静電容量の大きな容量素子を得ることができる。
According to the wiring board of the present invention, since the insulating base is formed by bonding inorganic insulating powder or dielectric powder with an organic material having excellent toughness, the wiring boards or the wiring board and the semiconductor are formed. No chipping, cracking, or cracking occurs in the insulating substrate even when a part of the automatic device manufacturing line collides violently.In addition, between the upper and lower surfaces of the insulating layer made of a composite member with a relative dielectric constant of 30 or more Since at least a pair of opposed electrodes is provided, a capacitor having a large capacitance can be obtained between the pair of opposed electrodes.

【0055】また、本発明の電子部品によれば、大きな
静電容量を得るために対向電極の面積を必要以上に大き
くする必要はなく、小型の電子部品とすることができ
る。
According to the electronic component of the present invention, it is not necessary to increase the area of the counter electrode more than necessary in order to obtain a large capacitance.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の配線基板に電子素子として半導体素子
を搭載した場合の電子部品の一例を示す断面図である。
FIG. 1 is a cross-sectional view illustrating an example of an electronic component when a semiconductor element is mounted as an electronic element on a wiring board according to the present invention.

【符号の説明】[Explanation of symbols]

1・・・・・・・・・・・・絶縁基体 1a、1b、1c、1e・・・・・・絶縁層 1d・・・・・・・・・・・・上下面方向の比誘電率が30
以上の絶縁層 2・・・・・・・・・・・・配線導体 3・・・・・・・・・・・・対向電極 4・・・・・・・・・・・・配線基板 5・・・・・・・・・・・・半導体素子 6・・・・・・・・・・・・電子部品
1 ... insulating base 1a, 1b, 1c, 1e ... insulating layer 1d ... relative dielectric constant in the vertical direction Is 30
The above insulating layer 2 ... wiring conductor 3 ... counter electrode 4 ... wiring board 5・ ・ ・ ・ ・ Semiconductor devices 6 ・ ・ ・ ・ Electronic components

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) H05K 3/46 H01L 23/14 R Fターム(参考) 4E351 AA01 AA07 BB01 BB03 BB24 BB29 BB31 DD48 GG02 4J002 BB031 BC031 BH021 CC031 CD001 CF061 CF081 CF211 CG001 CH071 CH091 CL001 CM031 CM041 CN011 CN031 DE086 DE096 DE136 DE146 DF006 DJ006 GQ05 5E346 AA12 AA13 AA15 AA23 AA38 BB02 BB03 BB04 BB16 BB20 CC08 CC16 CC21 CC31 DD02 DD34 EE01 FF45 GG28 HH01 HH11 HH22 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) H05K 3/46 H01L 23/14 RF term (Reference) 4E351 AA01 AA07 BB01 BB03 BB24 BB29 BB31 DD48 GG02 4J002 BB031 BC031 BH021 CC031 CD001 CF061 CF081 CF211 CG001 CH071 CH091 CL001 CM031 CM041 CN011 CN031 DE086 DE096 DE136 DE146 DF006 DJ006 GQ05 5E346 AA12 AA13 AA15 AA23 AA38 BB02 BB03 BB04 BB16 HBB BB20 CC08 CC16 DD21

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 10〜70重量%の無機絶縁粉末と30
〜90重量%の有機材料とから成り、前記無機絶縁粉末
を前記有機材料により結合して成る絶縁層を複数層、上
下に積層させるとともに前記絶縁層間および/または露
出する絶縁層表面に配線導体を被着して成る配線基板で
あって、前記絶縁層は少なくとも一層の上下面方向の比
誘電率が30以上であり、かつその上下面間に少なくと
も一対の対向電極が配設されていることを特徴とする配
線基板。
1 to 10% by weight of inorganic insulating powder and 30% by weight.
To 90% by weight of an organic material, and a plurality of insulating layers formed by bonding the inorganic insulating powder with the organic material. The insulating layers are vertically stacked, and a wiring conductor is formed on the insulating layer and / or on the surface of the exposed insulating layer. A wiring substrate formed by attaching the insulating layer, wherein at least one of the insulating layers has a relative dielectric constant of 30 or more in the upper and lower surface directions, and at least one pair of opposing electrodes is disposed between upper and lower surfaces thereof. Characteristic wiring board.
【請求項2】 前記上下面方向の比誘電率が30以上の
絶縁層は、10〜70重量%の誘電体粉末と30〜90
重量%の異方誘電性を有する有機材料とから成り、かつ
その比誘電率が最大と成る方向の比誘電率が前記誘電体
粉末の比誘電率の1/100〜1/2であることを特徴
とする請求項1記載の配線基板。
2. The insulating layer having a relative dielectric constant of 30 or more in the upper and lower surface directions comprises 10 to 70% by weight of dielectric powder and 30 to 90% by weight.
% By weight of an organic material having anisotropic dielectric property, and the relative permittivity in the direction in which the relative permittivity is the maximum is 1/100 to 1/2 of the relative permittivity of the dielectric powder. The wiring board according to claim 1, wherein:
【請求項3】 請求項1または請求項2記載の配線基板
と、前記配線基板に搭載され、前記配線導体と電気的に
接続された電子素子とから成ることを特徴とする電子部
3. An electronic component, comprising: the wiring board according to claim 1; and an electronic element mounted on the wiring board and electrically connected to the wiring conductor.
JP2000114314A 2000-04-14 2000-04-14 Wiring substrate and electronic component using the same Pending JP2001298126A (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000114314A JP2001298126A (en) 2000-04-14 2000-04-14 Wiring substrate and electronic component using the same

Publications (1)

Publication Number Publication Date
JP2001298126A true JP2001298126A (en) 2001-10-26

Family

ID=18626139

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

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JP2021073694A (en) * 2021-01-05 2021-05-13 日本精工株式会社 Thermoelectric conversion element

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2021073694A (en) * 2021-01-05 2021-05-13 日本精工株式会社 Thermoelectric conversion element
JP7092217B2 (en) 2021-01-05 2022-06-28 日本精工株式会社 Thermoelectric conversion element

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