JP2001267446A - Package for containing semiconductor element and semiconductor device using it - Google Patents

Package for containing semiconductor element and semiconductor device using it

Info

Publication number
JP2001267446A
JP2001267446A JP2000078013A JP2000078013A JP2001267446A JP 2001267446 A JP2001267446 A JP 2001267446A JP 2000078013 A JP2000078013 A JP 2000078013A JP 2000078013 A JP2000078013 A JP 2000078013A JP 2001267446 A JP2001267446 A JP 2001267446A
Authority
JP
Japan
Prior art keywords
weight
semiconductor element
sealing material
region
external lead
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000078013A
Other languages
Japanese (ja)
Inventor
Yoshiaki Ito
吉明 伊藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kyocera Corp
Original Assignee
Kyocera Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyocera Corp filed Critical Kyocera Corp
Priority to JP2000078013A priority Critical patent/JP2001267446A/en
Publication of JP2001267446A publication Critical patent/JP2001267446A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/4805Shape
    • H01L2224/4809Loop shape
    • H01L2224/48091Arched
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/42Wire connectors; Manufacturing methods related thereto
    • H01L2224/47Structure, shape, material or disposition of the wire connectors after the connecting process
    • H01L2224/48Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
    • H01L2224/481Disposition
    • H01L2224/48151Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/48221Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/48245Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic
    • H01L2224/48247Connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being metallic connecting the wire to a bond pad of the item
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2924/00Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
    • H01L2924/15Details of package parts other than the semiconductor or other solid state devices to be connected
    • H01L2924/161Cap
    • H01L2924/1615Shape
    • H01L2924/16152Cap comprising a cavity for hosting the device, e.g. U-shaped cap

Abstract

PROBLEM TO BE SOLVED: To solve a problem that cracking takes place in a sealing material due to stress caused by difference in the coefficient of thermal expansion between the sealing material and an external lead terminal. SOLUTION: A semiconductor element 5 and an external lead terminal 3 connected with the semiconductor element 5 are arranged between an insulating basic body 1 and a cover body 2 and the insulating basic body 1, the cover body 2 and the external lead terminal 3 are bonded, respectively, through a sealing material 4 thus obtaining a package for containing the semiconductor element hermetically. The sealing material 4 has a first region 4a on the insulating basic body side and a second region 4b on the cover body side wherein the external lead terminal 3 is clamped by the first and second regions 4a, 4b of the sealing material 4 and coefficients of thermal expansion of the first and second regions 4a, 4b of the sealing material 4 are 4.5-5.5 ppm/ deg.C and 6.0-7.5 ppm/ deg.C, respectively.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は半導体素子を気密に
封止して収納するための半導体素子収納用パッケージに
関し、特に封止材にガラスを用いて封止を行う半導体素
子収納用パッケージおよびこれを用いた半導体装置に関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a semiconductor element housing package for hermetically sealing and housing a semiconductor element, and more particularly to a semiconductor element housing package in which glass is used as a sealing material and a semiconductor element housing package. And a semiconductor device using the same.

【0002】[0002]

【従来の技術】従来、半導体素子を収容するための半導
体素子収納用パッケージは、例えば酸化アルミニウム質
焼結体やムライト質焼結体、窒化珪素質焼結体、炭化珪
素質焼結体等の電気絶縁材料から成り、その上面の略中
央部に半導体素子を収容する空所を形成するための凹部
を有し、上面にガラスから成る封止材が被着された絶縁
基体と、同じく電気絶縁材料から成り、その下面の略中
央部に半導体素子を収容する空所を形成するための凹部
を有し、下面にガラスから成る封止材が被着された蓋体
と、内部に収容する半導体素子を外部電気回路に電気的
に接続する鉄−ニッケル合金や鉄−ニッケル−コバルト
合金等の金属材料から成る外部リード端子とにより構成
されており、絶縁基体の上面に外部リード端子を載置さ
せるとともにあらかじめ被着させておいたガラスから成
る封止材を溶融させることによって外部リード端子を絶
縁基体上に仮止めし、次に絶縁基体の凹部底面に半導体
素子を取着するとともに半導体素子の各電極をボンディ
ングワイヤを介して外部リード端子に接続し、しかる
後、絶縁基体と蓋体とをその相対向する主面に被着させ
ておいたそれぞれの封止材を溶融一体化させ、絶縁基体
と蓋体とから成る容器を封止することによって製品とし
ての半導体装置と成る。
2. Description of the Related Art Conventionally, semiconductor element housing packages for housing semiconductor elements include, for example, aluminum oxide sintered bodies, mullite sintered bodies, silicon nitride sintered bodies, silicon carbide sintered bodies, and the like. An insulating base made of an electrically insulating material, having a concave portion for forming a space for accommodating the semiconductor element in a substantially central portion of the upper surface, and a sealing material made of glass adhered to the upper surface; A lid having a concave portion for forming a cavity for accommodating a semiconductor element in a substantially central portion of a lower surface thereof, and a lower surface covered with a sealing material made of glass; and a semiconductor accommodated therein. An external lead terminal made of a metal material such as an iron-nickel alloy or an iron-nickel-cobalt alloy for electrically connecting the element to an external electric circuit, and the external lead terminal is placed on the upper surface of the insulating base. With you The external lead terminals are temporarily fixed on the insulating substrate by melting the sealing material made of glass previously adhered, and then the semiconductor element is attached to the bottom of the concave portion of the insulating substrate, and each of the semiconductor elements is removed. The electrodes are connected to the external lead terminals via bonding wires, and then the respective sealing materials having the insulating substrate and the lid adhered to the opposing main surfaces are melted and integrated to form the insulating substrate. A semiconductor device as a product is obtained by sealing a container including the lid and the lid.

【0003】なお、絶縁基体に蓋体を接合させる封止材
としては、例えば酸化鉛70重量%、酸化ホウ素8.6重量
%、酸化チタン7.8重量%、酸化ジルコニウム6.7重量%
を含む鉛−硼酸系の低温ガラスが使用されていた。
As a sealing material for joining the lid to the insulating base, for example, 70% by weight of lead oxide, 8.6% by weight of boron oxide, 7.8% by weight of titanium oxide, 6.7% by weight of zirconium oxide
Lead-boric acid based low-temperature glass containing

【0004】しかしながら、このような封止材は人体に
対し有害である酸化鉛を主成分としているため、最近で
は酸化鉛を含有しない、例えばSnO−ZnO−P25
系の低温封止ガラスが提案されている(特許第2628007
号、米国特許第390037903号)。
However, since such a sealing material contains lead oxide which is harmful to the human body as a main component, it does not contain lead oxide recently, for example, SnO—ZnO—P 2 O 5.
-Based low-temperature sealing glass has been proposed (Patent No. 2628007)
No. 390037903).

【0005】また、近年、半導体素子の高集積化に伴う
高発熱の問題に対応して、絶縁基体には熱放散性の良好
な材料が要求され、このような材料として高熱伝導性の
窒化アルミニウム質焼結体が用いられるようになってき
ており、さらに、蓋体には熱膨張係数が窒化アルミニウ
ム質焼結体の熱膨張係数に近似したムライト質焼結体が
用いられるようになってきている。
In recent years, in response to the problem of high heat generation accompanying the high integration of semiconductor elements, a material having good heat dissipation properties has been required for the insulating substrate. Sinters have been used, and further, mullite sintered bodies having a thermal expansion coefficient similar to that of aluminum nitride sinters have been used for lids. I have.

【0006】[0006]

【発明が解決しようとする課題】しかしながら、上記の
SnO−ZnO−P25系封止ガラスは、その熱膨張係
数が約10ppm/℃であり、外部リード端子を形成する
鉄−ニッケル合金等の金属材料の熱膨張係数(約5pp
m/℃)と大きく相違することから、絶縁基体と蓋体と
を間に外部リード端子を挟み込んで封止材を介して接合
させる際、封止材と外部リード端子との間にそれぞれの
熱膨張係数の相違に起因して大きな応力が発生するとと
もにこの応力が封止材に作用して封止材にクラックが入
ってしまい、その結果、半導体素子収納用パッケージの
気密封止が破れ、内部に収容する半導体素子を長期間に
わたり正常、かつ安定に作動させることができないとい
う問題点を有していた。
[SUMMARY OF THE INVENTION However, the above-mentioned SnO-ZnO-P 2 O 5 Keifutome glass, its thermal expansion coefficient is about 10 ppm / ° C., the iron to form the external lead terminals - nickel alloy Thermal expansion coefficient (about 5pp
m / ° C.), when the insulating base and the lid are joined to each other with the external lead terminal interposed therebetween with the sealing material interposed therebetween, each heat is generated between the sealing material and the external lead terminal. A large stress is generated due to the difference in the expansion coefficient, and this stress acts on the sealing material to cause cracks in the sealing material. As a result, the hermetic sealing of the semiconductor element storage package is broken, and There is a problem that the semiconductor element housed in the semiconductor device cannot be operated normally and stably for a long period of time.

【0007】また、SnO−ZnO−P25系封止ガラ
スの熱膨張係数が蓋体として使用されるムライト質焼結
体の熱膨張係数(4.0〜4.3ppm/℃)とも大きく相違
すること、ならびに、ムライト質焼結体の機械的強度が
窒化アルミニウム質焼結体やアルミニウム質焼結体等に
較べて低いことから、蓋体の厚みを0.6mm程度までし
か薄くできず、その結果、半導体素子収納用パッケージ
を薄型化できないという問題点も有していた。
Further, the thermal expansion coefficient of the SnO—ZnO—P 2 O 5 based sealing glass is significantly different from the thermal expansion coefficient (4.0 to 4.3 ppm / ° C.) of the mullite sintered body used as the lid. Since the mechanical strength of the mullite sintered body is lower than that of the aluminum nitride sintered body or the aluminum sintered body, the thickness of the lid can be reduced to only about 0.6 mm. As a result, There is also a problem that the semiconductor device housing package cannot be made thinner.

【0008】本発明は上記問題点に鑑み案出されたもの
で、その目的は、絶縁基体と蓋体とから成る容器の内部
に半導体素子を気密に封止し、その特性に劣化を招来す
ることがなく、半導体素子を長期間にわたり正常かつ安
定に作動させることができ、かつ薄型の半導体素子収納
用パッケージおよびこれを用いた半導体装置を提供する
ことにある。
The present invention has been devised in view of the above problems, and has as its object to hermetically seal a semiconductor element inside a container formed of an insulating base and a lid, thereby deteriorating its characteristics. An object of the present invention is to provide a thin semiconductor element housing package which can operate a semiconductor element normally and stably for a long period of time and a thin semiconductor device using the same.

【0009】[0009]

【課題を解決するための手段】本発明の半導体素子収納
用パッケージは、半導体素子の搭載部を有する絶縁基体
に、搭載部を取り囲み、内側に半導体素子を収容する空
所を形成するための蓋体を、間に半導体素子が電気的に
接続される外部リード端子を挟んで封止材で接合して成
り、空所に半導体素子を気密に封止する半導体素子収納
用パッケージであって、封止材は絶縁基体側の第1領域
と蓋体側の第2領域とで外部リード端子を挟持してお
り、封止材の第1領域および第2領域の熱膨張係数がそ
れぞれ4.5〜5.5ppm/℃および6.0〜7.5ppm/℃で
あることを特徴とするものである。
According to the present invention, there is provided a package for accommodating a semiconductor element, wherein a cover for surrounding the mounting section and forming a space for accommodating the semiconductor element is formed inside an insulating base having a mounting section for the semiconductor element. A semiconductor element housing package for hermetically sealing the semiconductor element in an empty space, wherein the semiconductor element is hermetically sealed with an external lead terminal between which the semiconductor element is electrically connected. The stopper has an external lead terminal sandwiched between the first region on the insulating substrate side and the second region on the lid side, and the first and second regions of the sealing material have a thermal expansion coefficient of 4.5 to 5.5 ppm / each. ° C and 6.0 to 7.5 ppm / ° C.

【0010】また、本発明の半導体装置は、上記の半導
体素子収納用パッケージの搭載部に半導体素子を搭載し
て外部リード端子に電気的に接続するとともに、蓋体を
前記封止材で接合したことを特徴とするものである。
In the semiconductor device according to the present invention, the semiconductor element is mounted on the mounting portion of the package for housing the semiconductor element and is electrically connected to external lead terminals, and the lid is joined with the sealing material. It is characterized by the following.

【0011】本発明の半導体素子収納用パッケージによ
れば、封止材の第1領域の熱膨張係数を4.5〜5.5ppm
/℃、第2領域の熱膨張係数を6.0〜7.5ppm/℃とし
て外部リード端子の熱膨張係数に近似させ、このような
封止材の第1領域と第2領域とで外部リード端子を挟み
込んで接合したことから、これらの間に熱膨張係数の相
違に起因して大きな応力が発生することはなく、これに
よって封止材にクラックが入るのが有効に防止され、半
導体素子収納用パッケージの気密封止を完全として内部
に収容する半導体素子を長期間にわたり正常、かつ安定
に作動させることが可能となる。
According to the semiconductor device housing package of the present invention, the thermal expansion coefficient of the first region of the sealing material is 4.5 to 5.5 ppm.
/ ° C, the thermal expansion coefficient of the second region is set to 6.0 to 7.5 ppm / ° C to approximate the thermal expansion coefficient of the external lead terminal, and the external lead terminal is sandwiched between the first region and the second region of such a sealing material. Therefore, a large stress does not occur due to a difference in the coefficient of thermal expansion between them, thereby effectively preventing cracks from entering the sealing material. It is possible to normally and stably operate the semiconductor element housed therein with the hermetic sealing being completed for a long period of time.

【0012】また、第2領域の封止材の熱膨張係数を6.
0〜7.5ppm/℃と、ムライト質焼結体に較べてその機
械的強度の高い酸化アルミニウム質焼結体の熱膨張係数
に近似させたことから、蓋体として酸化アルミニウム質
焼結体を用いたとしても、封止材の第2領域と蓋体との
間にそれぞれの熱膨張係数の相違に起因して大きな応力
が発生することはなく、その結果、蓋体の厚みを0.25m
m程度と薄いものとすることができ、半導体素子収納用
パッケージを薄型化できる。
The thermal expansion coefficient of the sealing material in the second region is set to 6.
Since the thermal expansion coefficient of 0 to 7.5 ppm / ° C was approximated to the coefficient of thermal expansion of the aluminum oxide sintered body having higher mechanical strength than that of the mullite sintered body, the aluminum oxide sintered body was used as the lid. Even if it does, a large stress does not occur between the second region of the sealing material and the lid due to the difference in the coefficient of thermal expansion, and as a result, the thickness of the lid becomes 0.25 m.
m, and the thickness of the semiconductor device housing package can be reduced.

【0013】さらに、本発明の半導体装置によれば、封
止材を酸化鉛を含まない五酸化燐35〜55重量%、一酸化
錫20〜40重量%、酸化亜鉛10〜20重量%、酸化アルミニ
ウム2〜4重量%、酸化珪素1〜3重量%および酸化ホ
ウ素1〜6重量%から成るガラス成分にフィラーとして
コージェライト系化合物を外添加で40〜45重量%添加し
た第1領域と、五酸化燐35〜55重量%、一酸化錫20〜40
重量%、酸化亜鉛10〜20重量%、酸化アルミニウム2〜
4重量%、酸化珪素1〜3重量%および酸化ホウ素1〜
6重量%から成るガラス成分にフィラーとしてコージェ
ライト系化合物を外添加で16〜30重量%添加した第2領
域とで構成したことから、人体に害を与えたり地球環境
に負荷を与えることはなく、またその封止温度が430℃
程度と低いことから絶縁基体と蓋体とを接合させ、半導
体素子収納用パッケージを気密に封止する際の温度を低
温と成すことができ、その結果、封止材を溶融させる熱
が内部に収容する半導体素子に作用しても半導体素子の
特性に劣化を招来することはなく、半導体素子を長期間
にわたり正常、かつ安定に作動させることができる。
Further, according to the semiconductor device of the present invention, the encapsulant is made of 35 to 55% by weight of phosphorus pentoxide containing no lead oxide, 20 to 40% by weight of tin monoxide, 10 to 20% by weight of zinc oxide, A first region in which a cordierite-based compound is externally added as a filler to a glass component consisting of 2 to 4% by weight of aluminum, 1 to 3% by weight of silicon oxide, and 1 to 6% by weight of boron oxide; 35-55% by weight phosphorus oxide, 20-40 tin oxide
Wt%, zinc oxide 10 ~ 20wt%, aluminum oxide 2 ~
4% by weight, 1 to 3% by weight of silicon oxide and 1 to 3% of boron oxide
Since it is composed of a glass component consisting of 6% by weight and a cordierite-based compound as a filler in a second region where 16-30% by weight is externally added, there is no harm to the human body and no load on the global environment. , And its sealing temperature is 430 ℃
Since the temperature is low, the temperature at which the insulating base and the lid are joined to each other to seal the semiconductor device housing package hermetically can be reduced to a low temperature. As a result, heat for melting the sealing material is generated inside. Even if it acts on the semiconductor element to be housed, the characteristics of the semiconductor element do not deteriorate, and the semiconductor element can be operated normally and stably for a long period of time.

【0014】[0014]

【発明の実施の形態】次に、本発明を添付の図面に基づ
き詳細に説明する。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the present invention will be described in detail with reference to the accompanying drawings.

【0015】図1は本発明の半導体素子収納用パッケー
ジおよびこれを用いた半導体装置の実施の形態の一例を
示す断面図であり、1は絶縁基体、2は蓋体、3は外部
リード端子、4は封止材、5は半導体素子である。これ
らのうち、絶縁基体1と蓋体2・外部リード端子3・封
止材4とで本発明の半導体素子収納用パッケージが構成
されており、この半導体素子収納用パッケージと半導体
素子5とで本発明の半導体装置が構成されている。
FIG. 1 is a cross-sectional view showing an embodiment of a semiconductor element housing package and a semiconductor device using the same according to the present invention, wherein 1 is an insulating base, 2 is a lid, 3 is an external lead terminal, 4 is a sealing material and 5 is a semiconductor element. Among these, the semiconductor element housing package of the present invention is constituted by the insulating base 1, the lid 2, the external lead terminals 3, and the encapsulant 4. The semiconductor device according to the invention is configured.

【0016】絶縁基体1は、窒化アルミニウム質焼結体
等の電気絶縁材料から成り、その上面の略中央部に半導
体素子5を収容する空所を形成するための凹部1aが設
けてあり、この凹部1aの底面には半導体素子5がガラ
ス、樹脂、ロウ材等から成る接着材を介して接着固定さ
れる。
The insulating base 1 is made of an electrically insulating material such as an aluminum nitride sintered body, and has a recess 1a for forming a space for accommodating the semiconductor element 5 at a substantially central portion of the upper surface thereof. The semiconductor element 5 is bonded and fixed to the bottom surface of the concave portion 1a via an adhesive made of glass, resin, brazing material or the like.

【0017】絶縁基体1は、例えば窒化アルミニウム質
焼結体から成る場合であれば、窒化アルミニウム・酸化
イットリウム・酸化エルビウム・酸化セリウム等の原料
粉末に適当な有機バインダ・溶剤・可塑剤・分散剤等を
添加混合して泥漿物を作り、この泥漿物を従来周知のド
クターブレード法やカレンダーロール法等のシート成形
法を採用しシート状に成形してセラミックグリーンシー
ト(セラミック生シート)を得、しかる後、それらセラ
ミックグリーンシートに適当な打ち抜き加工を施すとと
もにこれを複数枚積層し、約1700℃の高温で焼成するこ
とによって製作される。
When the insulating substrate 1 is made of, for example, an aluminum nitride sintered body, an organic binder, a solvent, a plasticizer, and a dispersant suitable for a raw material powder such as aluminum nitride, yttrium oxide, erbium oxide, and cerium oxide. The mixture is added and mixed to form a slurry, and the slurry is formed into a sheet using a sheet forming method such as a doctor blade method or a calender roll method, which is conventionally known, to obtain a ceramic green sheet (ceramic green sheet). Thereafter, the ceramic green sheet is manufactured by subjecting the ceramic green sheet to appropriate punching processing, laminating a plurality of the sheets, and firing at a high temperature of about 1700 ° C.

【0018】また、絶縁基体1の上面外周部には鉄−ニ
ッケル合金や鉄−ニッケル−コバルト合金等の金属材料
から成る外部リード端子3の一端が封止材4の第1領域
4aを介して仮止めされている。このような外部リード
端子3は、鉄−ニッケル−コバルト合金等のインゴット
(塊)を従来周知の打抜き加工法等を採用し、所定の形
状に形成することによって形成される。
One end of an external lead terminal 3 made of a metal material such as an iron-nickel alloy or an iron-nickel-cobalt alloy is provided on the outer peripheral portion of the upper surface of the insulating base 1 via the first region 4a of the sealing material 4. Temporarily fixed. Such an external lead terminal 3 is formed by forming an ingot (a lump) such as an iron-nickel-cobalt alloy into a predetermined shape by using a conventionally known punching method or the like.

【0019】外部リード端子3は、内部に収容する半導
体素子5を外部電気回路に接続する作用をなし、その一
端には半導体素子5の各電極がボンディングワイヤを介
して接続され、外部リード端子3を外部電気回路に接続
することによって半導体素子5は外部電気回路と電気的
に接続される。
The external lead terminal 3 has a function of connecting the semiconductor element 5 housed therein to an external electric circuit, and one end of each of the electrodes of the semiconductor element 5 is connected via a bonding wire. Is connected to an external electric circuit, whereby the semiconductor element 5 is electrically connected to the external electric circuit.

【0020】なお、外部リード端子3はその表面にニッ
ケル、金等の良導電性で耐蝕性およびロウ材との濡れ性
が良好な金属をめっき法により1〜20μmの厚みに被着
させておくと、外部リード端子3の酸化腐蝕を有効に防
止することができるとともに外部リード端子3と外部電
気回路との電気的接続を良好となすことができる。従っ
て、外部リード端子3の酸化腐蝕を防止し、外部リード
端子3と外部電気回路との電気的接続を良好となすに
は、外部リード端子3の表面にニッケル、金等をめっき
法により1〜20μmの厚みに被着させておくことが好ま
しい。
The surface of the external lead terminal 3 is coated with a metal such as nickel or gold having good conductivity, good corrosion resistance and good wettability with the brazing material to a thickness of 1 to 20 μm by plating. Thus, oxidation corrosion of the external lead terminal 3 can be effectively prevented, and good electrical connection between the external lead terminal 3 and the external electric circuit can be achieved. Therefore, in order to prevent the external lead terminal 3 from being oxidized and corroded and to make a good electrical connection between the external lead terminal 3 and an external electric circuit, nickel, gold or the like is plated on the surface of the external lead terminal 3 by plating. Preferably, it is applied to a thickness of 20 μm.

【0021】さらに、外部リード端子3が仮止めされた
絶縁基体1はその上面に蓋体2が、蓋体2の下面に被着
させた封止材4の第2領域4bと絶縁基体1の上面に被
着させた封止材4の第1領域とを溶融一体化させること
によって接合され、これによって絶縁基体1と蓋体2と
から成る容器6に半導体素子5が気密に封止されるとと
もに絶縁基体1と蓋体2との間に外部リード端子3が固
定される。
Further, the insulating base 1 to which the external lead terminals 3 are temporarily fixed is provided with a cover 2 on the upper surface thereof, and a second region 4b of the sealing material 4 attached to the lower surface of the cover 2 and the insulating base 1. The first region of the sealing material 4 adhered to the upper surface is joined by being melted and integrated, whereby the semiconductor element 5 is hermetically sealed in the container 6 including the insulating base 1 and the lid 2. At the same time, the external lead terminals 3 are fixed between the insulating base 1 and the lid 2.

【0022】蓋体2は、酸化アルミニウム質焼結体等の
電気絶縁材料から成り、例えば酸化アルミニウム質焼結
体から成る場合であれば、酸化アルミニウム、酸化珪
素、酸化マグネシウム、酸化カルシウム等の原料粉末に
適当な有機バインダ、溶剤、可塑剤、分散剤等を添加混
合して泥漿物を作り、この泥漿物を従来周知のドクター
ブレード法やカレンダーロール法等のシート成形法を採
用しシート状に成形してセラミックグリーンシート(セ
ラミック生シート)を得、しかる後、それらセラミック
グリーンシートに適当な打抜き加工を施すとともにこれ
を複数枚積層し、約1600℃の高温で焼成することにより
製作される。あるいは酸化アルミニウム等の原料粉末に
適当な有機溶剤・溶媒を添加混合して原料粉末を調整す
るとともにこの原料粉末をプレス成形によって所定形状
に成形し、しかる後、この成形体を約1600℃の温度で焼
成することによって製作される。
The lid 2 is made of an electrically insulating material such as an aluminum oxide sintered body. For example, when the lid 2 is made of an aluminum oxide sintered body, a raw material such as aluminum oxide, silicon oxide, magnesium oxide, calcium oxide or the like is used. An appropriate organic binder, a solvent, a plasticizer, a dispersant, etc. are added to the powder and mixed to form a slurry, and the slurry is formed into a sheet by employing a sheet forming method such as a doctor blade method or a calender roll method which is well known in the art. The ceramic green sheet (ceramic green sheet) is obtained by molding, and thereafter, the ceramic green sheet is subjected to an appropriate punching process, and a plurality of the green sheets are laminated and fired at a high temperature of about 1600 ° C. Alternatively, a raw material powder such as aluminum oxide is added and mixed with an appropriate organic solvent / solvent to prepare the raw material powder, and the raw material powder is formed into a predetermined shape by press molding. Thereafter, the formed body is heated to a temperature of about 1600 ° C. It is manufactured by firing.

【0023】絶縁基体1と蓋体2とを接合する封止材4
は、熱膨張係数が4.5〜5.5ppm/℃の絶縁基体1側の
第1領域4aと熱膨張係数が6.0〜7.5ppm/℃の蓋体
2側の第2領域4bとから成っており、これらの第1領
域4aと第2領域4bとで外部リード端子3を挟み込ん
で接合している。
A sealing material 4 for joining the insulating base 1 and the lid 2
Consists of a first region 4a on the side of the insulating substrate 1 having a thermal expansion coefficient of 4.5 to 5.5 ppm / ° C. and a second region 4b on the side of the lid 2 having a thermal expansion coefficient of 6.0 to 7.5 ppm / ° C. The external lead terminal 3 is sandwiched and joined between the first region 4a and the second region 4b.

【0024】本発明においては、この封止材4の第1領
域4aと第2領域4bの熱膨張係数を外部リード端子3
の熱膨張係数と近似させたことから、封止材4と外部リ
ード端子3の間に熱膨張係数の相違に起因して大きな応
力が発生することはなく、これによって封止材にクラッ
クが入るのが有効に防止され、半導体素子収納用パッケ
ージの気密封止を完全として内部に収容する半導体素子
を長期間にわたり正常、かつ安定に作動させることが可
能となる。
In the present invention, the thermal expansion coefficients of the first region 4a and the second region 4b
, A large stress is not generated between the sealing material 4 and the external lead terminal 3 due to the difference in the thermal expansion coefficient, and the sealing material is cracked. This is effectively prevented, and the hermetic sealing of the package for accommodating the semiconductor element is completely completed, so that the semiconductor element accommodated therein can be operated normally and stably for a long period of time.

【0025】また、蓋体2側の第2領域4bの封止材4
の熱膨張係数を6.0〜7.5ppm/℃と酸化アルミニウム
質焼結体の熱膨張係数と近似させたことから、酸化アル
ミニウム質焼結体からなる蓋体2と封止材4の第2領域
4bとの間にそれぞれの熱膨張係数の相違に起因して大
きな応力が発生することはなく、その結果、蓋体2の厚
みを0.25mm程度と薄いものとすることができ、半導体
素子収納用パッケージを薄型化できる。
The sealing material 4 in the second region 4b on the lid 2 side
Has a coefficient of thermal expansion of 6.0 to 7.5 ppm / ° C., which is close to the coefficient of thermal expansion of the aluminum oxide sintered body, so that the lid 2 made of the aluminum oxide sintered body and the second region 4 b of the sealing material 4 A large stress is not generated due to the difference in the coefficient of thermal expansion between them, and as a result, the thickness of the lid 2 can be made as thin as about 0.25 mm. Can be made thinner.

【0026】さらに、本発明の半導体素子収納用パッケ
ージによれば、封止材を酸化鉛を含まない五酸化燐35〜
55重量%、一酸化錫20〜40重量%、酸化亜鉛10〜20重量
%、酸化アルミニウム2〜4重量%、酸化珪素1〜3重
量%および酸化ホウ素1〜6重量%から成るガラス成分
にフィラとしてコージェライト系化合物を外添加で40〜
45重量%添加した第1領域と、五酸化燐35〜55重量%、
一酸化錫20〜40重量%、酸化亜鉛10〜20重量%、酸化ア
ルミニウム2〜4重量%、酸化珪素1〜3重量%および
酸化ホウ素1〜6重量%から成るガラス成分にフィラと
してコージェライト系化合物を外添加で16〜30重量%添
加した第2領域とで構成したことから、人体に害を与え
たり地球環境に負荷を与えることはなく、またその封止
温度が 430℃程度と低いことから絶縁基体と蓋体とを接
合させ、半導体素子収納用パッケージを気密に封止する
際の温度を低温と成すことができ、その結果、封止材を
溶融させる熱が内部に収容する半導体素子に作用しても
半導体素子の特性に劣化を招来することはなく、半導体
素子を長期間にわたり正常、かつ安定に作動させること
が可能となる。
Further, according to the package for accommodating a semiconductor element of the present invention, the encapsulant is made of phosphorus pentoxide containing no lead oxide.
A glass composition comprising 55% by weight, 20-40% by weight of tin monoxide, 10-20% by weight of zinc oxide, 2-4% by weight of aluminum oxide, 1-3% by weight of silicon oxide and 1-6% by weight of boron oxide As an external addition of cordierite compounds as 40 ~
45% by weight of the first region, 35 to 55% by weight of phosphorus pentoxide,
Cordierite as a filler in a glass component consisting of 20 to 40% by weight of tin monoxide, 10 to 20% by weight of zinc oxide, 2 to 4% by weight of aluminum oxide, 1 to 3% by weight of silicon oxide and 1 to 6% by weight of boron oxide Since it is composed of the second region to which 16 to 30% by weight of the compound is added by external addition, it does not harm the human body or load the global environment, and its sealing temperature is as low as 430 ° C. And the lid is joined to the insulating base, so that the temperature at which the semiconductor element housing package is hermetically sealed can be reduced to a low temperature, and as a result, the heat for melting the sealing material is housed inside. Does not cause deterioration of the characteristics of the semiconductor element, and allows the semiconductor element to operate normally and stably for a long period of time.

【0027】なお、封止材4の第1領域4aのガラス成
分は、五酸化燐の量が35重量%未満であるとガラスの軟
化溶融温度が高くなって、低温での容器6の気密封止が
困難となる傾向があり、他方、55重量%を超えるとガラ
スの耐薬品性が劣化して、容器4の気密封止の信頼性が
大きく低下してしまう傾向がある。したがって、五酸化
燐の量は35〜55重量%の範囲であることが好ましい。
If the amount of phosphorus pentoxide in the first region 4a of the sealing material 4 is less than 35% by weight, the softening and melting temperature of the glass increases, and the container 6 is hermetically sealed at a low temperature. If it exceeds 55% by weight, the chemical resistance of the glass tends to deteriorate, and the reliability of hermetic sealing of the container 4 tends to decrease significantly. Therefore, the amount of phosphorus pentoxide is preferably in the range of 35-55% by weight.

【0028】また、一酸化錫の量は20重量%未満である
とガラスの軟化溶融温度が高くなって、低温での容器6
の気密封止が困難となる傾向があり、他方、40重量%を
超えると、ガラスの耐薬品性が低下し、容器6の気密封
止の信頼性が大きく低下してしまう傾向がある。したが
って、一酸化錫の量は20〜40重量%の範囲であることが
好ましい。
If the amount of tin monoxide is less than 20% by weight, the softening and melting temperature of the glass increases, and
Tends to be difficult. On the other hand, if it exceeds 40% by weight, the chemical resistance of the glass tends to decrease, and the reliability of the hermetic sealing of the container 6 tends to greatly decrease. Therefore, the amount of tin monoxide is preferably in the range of 20-40% by weight.

【0029】酸化亜鉛の量が10重量%未満であるとガラ
スの軟化溶融温度が高くなって、低温での容器6の気密
封止が困難となる傾向があり、他方、20重量%を超える
とガラスの結晶化が進み、低温での気密封止が困難とな
る傾向がある。したがって、酸化亜鉛の量は10〜20重量
%の範囲であることが好ましい。
If the amount of zinc oxide is less than 10% by weight, the softening and melting temperature of the glass tends to be high, and the hermetic sealing of the container 6 at low temperatures tends to be difficult, while if it exceeds 20% by weight. Crystallization of the glass proceeds, and hermetic sealing at low temperatures tends to be difficult. Therefore, the amount of zinc oxide is preferably in the range of 10 to 20% by weight.

【0030】酸化アルミニウムが2重量%未満であると
ガラスの耐湿性が低下し、容器6の気密封止の信頼性が
大きく低下してしまう傾向があり、他方、4重量%を超
えるとガラスの軟化溶融温度が高くなって、低温での容
器6の気密封止が困難となる傾向がある。したがって、
酸化アルミニウムの量は2〜4重量%の範囲であること
が好ましい。
If the aluminum oxide content is less than 2% by weight, the moisture resistance of the glass tends to decrease, and the reliability of hermetic sealing of the container 6 tends to decrease significantly. The softening / melting temperature tends to be high, and it tends to be difficult to hermetically seal the container 6 at a low temperature. Therefore,
Preferably, the amount of aluminum oxide is in the range of 2-4% by weight.

【0031】酸化珪素が1重量%未満であるとガラスの
熱膨張係数が大きくなり、基体1の熱膨張係数と大きく
相違してしまう傾向があり、他方、3重量%を超えると
ガラスの軟化溶融温度が高くなって、低温での容器6の
気密封止が困難となる傾向がある。したがって、酸化珪
素の量は1〜3重量%の範囲であることが好ましい。
If the silicon oxide content is less than 1% by weight, the thermal expansion coefficient of the glass tends to be large and significantly different from the thermal expansion coefficient of the substrate 1, while if it exceeds 3% by weight, the softening and melting of the glass As the temperature increases, it tends to be difficult to hermetically seal the container 6 at a low temperature. Therefore, the amount of silicon oxide is preferably in the range of 1 to 3% by weight.

【0032】酸化ホウ素が1重量%未満であるとガラス
の軟化溶融温度が高くなって、低温での容器6の気密封
止が困難となる傾向があり、他方、6重量%を超えると
ガラスの耐薬品性が劣化して、容器4の気密封止の信頼
性が大きく低下してしまう傾向がある。したがって、酸
化ホウ素の量は1〜6重量%の範囲であることが好まし
い。
If the content of boron oxide is less than 1% by weight, the softening and melting temperature of the glass tends to be high, and it becomes difficult to hermetically seal the container 6 at a low temperature. There is a tendency that the chemical resistance is deteriorated and the reliability of hermetic sealing of the container 4 is greatly reduced. Therefore, the amount of boron oxide is preferably in the range of 1 to 6% by weight.

【0033】また、コージェライト系化合物のフィラー
は封止材4の第1領域4aの熱膨張係数を調整するとと
もにその流動性を調整する作用を成す。このフィラーの
含有量が40重量%未満である封止材4の第1領域4aの
熱膨張係数が絶縁基体1の熱膨張係数に対して大きく相
違してしまい、封止材4の第1領域4aを絶縁基体1に
強固に接合させることができなくなる傾向がある。他
方、45重量%を超えると封止材4の第1領域4aの流動
性が低下して、低温での外部リード端子3の接合が困難
と成る傾向にある。したがって、フィラーの含有量は40
〜45重量%の範囲であることが好ましい。
The filler of the cordierite-based compound functions to adjust the coefficient of thermal expansion of the first region 4a of the sealing material 4 and to adjust the fluidity thereof. When the content of the filler is less than 40% by weight, the thermal expansion coefficient of the first region 4a of the sealing material 4 greatly differs from the thermal expansion coefficient of the insulating base 1, and the first region of the sealing material 4 4a tends to be unable to be firmly joined to the insulating substrate 1. On the other hand, if it exceeds 45% by weight, the fluidity of the first region 4a of the sealing material 4 decreases, and it tends to be difficult to bond the external lead terminals 3 at a low temperature. Therefore, the filler content is 40
Preferably, it is in the range of ~ 45% by weight.

【0034】さらに、コージェライト系化合物フィラー
の平均粒径が3μm未満であると封止材4の第1領域4
aの流動性が低下して容器6の気密封止が困難となる傾
向があり、他方、9μmを超えると封止材4の第1領域
4aの機械的強度が低下する傾向にある。したがって、
コージェライト系化合物フィラーはその平均粒径を3〜
9μmの範囲とすることが好ましい。
Further, when the average particle size of the cordierite-based compound filler is less than 3 μm, the first region 4
The fluidity of “a” tends to decrease and the hermetic sealing of the container 6 tends to be difficult. On the other hand, if it exceeds 9 μm, the mechanical strength of the first region 4 a of the sealing material 4 tends to decrease. Therefore,
Cordierite-based compound fillers have an average particle size of 3 to
It is preferred to be in the range of 9 μm.

【0035】なお、このような封止材4の第1領域4a
は100μm未満の厚みであると、封止材4の第1領域4
aおよび第2領域4bの熱膨張係数の相違により、封止
時に絶縁基体1と封止材4の第1領域4aとの界面に剥
離応力が発生してしまい、気密封止の信頼性が低下して
しまう傾向がある。他方、厚みが300μmを超えると封
止時の流動性が低下して、低温での気密封止が困難とな
る傾向がある。したがって、封止材4の第1領域4aの
厚みは100〜300μmの範囲であることが好ましい。
The first region 4a of such a sealing material 4
Is less than 100 μm, the first region 4 of the sealing material 4
Due to the difference in the thermal expansion coefficient between the first region 4a and the second region 4b, peeling stress is generated at the interface between the insulating base 1 and the first region 4a of the sealing material 4 during sealing, and the reliability of hermetic sealing is reduced. Tend to do so. On the other hand, when the thickness exceeds 300 μm, the fluidity at the time of sealing decreases, and air-tight sealing at a low temperature tends to be difficult. Therefore, the thickness of the first region 4a of the sealing material 4 is preferably in the range of 100 to 300 μm.

【0036】さらに、封止材4の第2領域4bのガラス
成分は、五酸化燐の量が35重量%未満であるとガラスの
軟化溶融温度が高くなって、低温での容器6の気密封止
が困難となる傾向があり、他方、55重量%を超えるとガ
ラスの耐薬品性が劣化して、容器4の気密封止の信頼性
が大きく低下してしまう傾向がある。したがって、五酸
化燐の量は35〜55重量%の範囲であることが好ましい。
Further, when the amount of phosphorus pentoxide is less than 35% by weight, the glass component in the second region 4b of the sealing material 4 has a high softening and melting temperature of the glass, and the container 6 is hermetically sealed at a low temperature. If it exceeds 55% by weight, the chemical resistance of the glass tends to deteriorate, and the reliability of hermetic sealing of the container 4 tends to decrease significantly. Therefore, the amount of phosphorus pentoxide is preferably in the range of 35-55% by weight.

【0037】また、一酸化錫の量は20重量%未満である
とガラスの軟化溶融温度が高くなって、低温での容器6
の気密封止が困難となる傾向があり、他方、40重量%を
超えると、ガラスの耐薬品性が低下し、容器6の気密封
止の信頼性が大きく低下してしまう傾向がある。したが
って、一酸化錫の量は20〜40重量%の範囲であることが
好ましい。
If the amount of tin monoxide is less than 20% by weight, the softening and melting temperature of the glass becomes high, and
Tends to be difficult. On the other hand, if it exceeds 40% by weight, the chemical resistance of the glass tends to decrease, and the reliability of the hermetic sealing of the container 6 tends to greatly decrease. Therefore, the amount of tin monoxide is preferably in the range of 20-40% by weight.

【0038】酸化亜鉛の量が10重量%未満であるとガラ
スの軟化溶融温度が高くなって、低温での容器6の気密
封止が困難となる傾向があり、他方、20重量%を超える
とガラスの結晶化が進み、低温での気密封止が困難とな
る傾向がある。したがって、酸化亜鉛の量は10〜20重量
%の範囲であることが好ましい。
If the amount of zinc oxide is less than 10% by weight, the softening and melting temperature of the glass tends to be high, and it becomes difficult to hermetically seal the container 6 at a low temperature, while if it exceeds 20% by weight. Crystallization of the glass proceeds, and hermetic sealing at low temperatures tends to be difficult. Therefore, the amount of zinc oxide is preferably in the range of 10 to 20% by weight.

【0039】酸化アルミニウムが2重量%未満であると
ガラスの耐湿性が低下し、容器6の気密封止の信頼性が
大きく低下してしまう傾向があり、他方、4重量%を超
えるとガラスの軟化溶融温度が高くなって、低温での容
器6の気密封止が困難となる傾向がある。したがって、
酸化アルミニウムの量は2〜4重量%の範囲であること
が好ましい。
If the aluminum oxide content is less than 2% by weight, the moisture resistance of the glass tends to decrease, and the reliability of hermetic sealing of the container 6 tends to decrease significantly. The softening / melting temperature tends to be high, and it tends to be difficult to hermetically seal the container 6 at a low temperature. Therefore,
Preferably, the amount of aluminum oxide is in the range of 2-4% by weight.

【0040】酸化珪素が1重量%未満であるとガラスの
熱膨張係数が大きくなり、基体1の熱膨張係数と大きく
相違してしまう傾向があり、他方、3重量%を超えると
ガラスの軟化溶融温度が高くなって、低温での容器6の
気密封止が困難となる傾向がある。したがって、酸化珪
素の量は1〜3重量%の範囲であることが好ましい。
If the silicon oxide content is less than 1% by weight, the coefficient of thermal expansion of the glass tends to be large and significantly different from the thermal expansion coefficient of the substrate 1, while if it exceeds 3% by weight, the softening and melting of the glass As the temperature increases, it tends to be difficult to hermetically seal the container 6 at a low temperature. Therefore, the amount of silicon oxide is preferably in the range of 1 to 3% by weight.

【0041】酸化ホウ素が1重量%未満であるとガラス
の軟化溶融温度が高くなって、低温での容器6の気密封
止が困難となる傾向があり、他方、6重量%を超えると
ガラスの耐薬品性が劣化して、容器4の気密封止の信頼
性が大きく低下してしまう傾向がある。したがって、酸
化ホウ素の量は1〜6重量%の範囲であることが好まし
い。
If the content of boron oxide is less than 1% by weight, the softening and melting temperature of the glass tends to be high, which makes it difficult to hermetically seal the container 6 at a low temperature. There is a tendency that the chemical resistance is deteriorated and the reliability of hermetic sealing of the container 4 is greatly reduced. Therefore, the amount of boron oxide is preferably in the range of 1 to 6% by weight.

【0042】また、コージェライト系化合物のフィラー
は封止材4の第2領域4bの熱膨張係数を調整するとと
もにその流動性を調整する作用を成す。このフィラーの
含有量が16重量%未満である封止材4の第2領域4bの
熱膨張係数が蓋体2の熱膨張係数に対して大きく相違し
てしまい、封止材4の第2領域4bを蓋体2に強固に接
合させることができなくなる傾向がある。他方、30重量
%を超えると封止材4の第2領域4bの流動性が低下し
て、低温での外部リード端子3の接合が困難と成る傾向
にある。したがって、フィラーの含有量は16〜30重量%
の範囲であることが好ましい。
The filler of the cordierite-based compound functions to adjust the coefficient of thermal expansion of the second region 4b of the sealing material 4 and to adjust the fluidity thereof. The thermal expansion coefficient of the second region 4b of the sealing material 4 in which the content of the filler is less than 16% by weight is largely different from the thermal expansion coefficient of the lid 2, and the second region of the sealing material 4 4b tends not to be able to be firmly joined to the lid 2. On the other hand, if it exceeds 30% by weight, the fluidity of the second region 4b of the sealing material 4 decreases, and it tends to be difficult to bond the external lead terminals 3 at low temperatures. Therefore, the filler content is 16-30% by weight
Is preferably within the range.

【0043】さらに、コージェライト系化合物フィラー
の平均粒径が3μm未満であると封止材4の第2領域4
bの流動性が低下して容器6の気密封止が困難となる傾
向があり、他方、9μmを超えると封止材4の第2領域
4bの機械的強度が低下する傾向にある。したがって、
コージェライト系化合物フィラーはその平均粒径を3〜
9μmの範囲とすることが好ましい。
Further, if the average particle size of the cordierite-based compound filler is less than 3 μm, the second region 4
The fluidity of b tends to decrease, making the hermetic sealing of the container 6 difficult. On the other hand, if it exceeds 9 μm, the mechanical strength of the second region 4b of the sealing material 4 tends to decrease. Therefore,
Cordierite-based compound fillers have an average particle size of 3 to
It is preferred to be in the range of 9 μm.

【0044】このような絶縁基体1と蓋体2との接合封
止は、次に述べる方法により行なわれる。まず、絶縁基
体1の蓋体2との接合領域に第1領域4aと成る封止材
4を従来周知のスクリーン印刷法等を採用してあらかじ
め被着させる。この後、外部リード端子3を第1領域4
aと成る封止材4に載置するとともに約400℃の温度で
焼成することにより、第1領域4aと成る封止材4を絶
縁基体1へ溶融被着させるとともに外部リード端子3を
第1領域4aと成る封止材4に仮止めする。次に、あら
かじめ第2領域4bと成る封止材4を従来周知のスクリ
ーン印刷法等を採用して被着させた蓋体2を、第1領域
4aと成る封止材4と第2領域4bと成る封止材4とが
重なるように絶縁基体1に重ね合わせ、その後、約430
℃の温度で溶融一体化させることによって絶縁基体1と
蓋体2とを接合する。これによって絶縁基体1と蓋体2
とから成る容器6に半導体素子5が気密に封止されると
ともに絶縁基体1と蓋体2との間に外部リード端子3が
固定される。
The bonding and sealing of the insulating base 1 and the lid 2 are performed by the following method. First, a sealing material 4 serving as a first region 4a is previously applied to a bonding region of the insulating base 1 with the lid 2 by using a conventionally known screen printing method or the like. Thereafter, the external lead terminal 3 is connected to the first region 4
a, and by baking at a temperature of about 400 ° C., the sealing material 4 to be the first region 4 a is melt-adhered to the insulating base 1 and the external lead terminals 3 are connected to the first lead 4. It temporarily fixes to the sealing material 4 which becomes the area | region 4a. Next, the cover 2 on which the sealing material 4 serving as the second region 4b has been applied in advance by using a conventionally known screen printing method or the like is replaced with the sealing material 4 serving as the first region 4a and the second region 4b. Are overlapped on the insulating substrate 1 so that the sealing material 4 becomes
The insulating base 1 and the lid 2 are joined by melting and integrating at a temperature of ° C. Thereby, the insulating base 1 and the lid 2
The semiconductor element 5 is hermetically sealed in a container 6 composed of the following, and the external lead terminal 3 is fixed between the insulating base 1 and the lid 2.

【0045】かくして上述の半導体素子収納用パッケー
ジによれば、絶縁基体1の凹部1a底面に半導体素子5
をガラス、樹脂、ロウ材等から成る接着材を介して接着
固定するとともに半導体素子5の各電極をボンディング
ワイヤにより外部リード端子3に接続させ、しかる後、
絶縁基体1と蓋体2との間に外部リード端子3を挟み封
止材4を介して接合させることによって絶縁基体1と蓋
体2とから成る容器6の内部に半導体素子5を気密に収
容することによって最終製品としての半導体装置が完成
する。
Thus, according to the above-described package for accommodating a semiconductor element, the semiconductor element 5
Is bonded and fixed via an adhesive made of glass, resin, brazing material, or the like, and each electrode of the semiconductor element 5 is connected to the external lead terminal 3 by a bonding wire.
The semiconductor element 5 is hermetically accommodated in a container 6 composed of the insulating base 1 and the lid 2 by sandwiching the external lead terminals 3 between the insulating base 1 and the lid 2 and joining them via the sealing material 4. By doing so, a semiconductor device as a final product is completed.

【0046】なお、本発明は上述の実施の形態に限定さ
れるものではなく、本発明の要旨を逸脱しない範囲であ
れば種々の変更は可能であり、例えば上述の例では絶縁
基体の材料として窒化アルミニウム質焼結体を例示した
が、熱伝導性の良好な炭化珪素を用いてもよい。
It should be noted that the present invention is not limited to the above-described embodiment, and various changes can be made without departing from the scope of the present invention. Although the aluminum nitride sintered body has been exemplified, silicon carbide having good thermal conductivity may be used.

【0047】[0047]

【発明の効果】本発明の半導体素子収納用パッケージに
よれば、封止材の第1領域の熱膨張係数を4.5〜5.5pp
m/℃、第2領域の熱膨張係数を6.0〜7.5ppm/℃と
して外部リード端子の熱膨張係数に近似させ、このよう
な封止材の第1領域と第2領域とで外部リード端子を挟
み込んで接合したことから、これらの間に熱膨張係数の
相違に起因して大きな応力が発生することはなく、これ
によって封止材にクラックが入るのが有効に防止され、
半導体素子収納用パッケージの気密封止を完全として内
部に収容する半導体素子を長期間にわたり正常、かつ安
定に作動させることが可能となる。
According to the semiconductor device housing package of the present invention, the thermal expansion coefficient of the first region of the sealing material is 4.5 to 5.5 pp.
m / ° C., the thermal expansion coefficient of the second region is set to 6.0 to 7.5 ppm / ° C. to approximate the thermal expansion coefficient of the external lead terminal, and the external lead terminal is formed between the first region and the second region of such a sealing material. Since the members are sandwiched and joined, a large stress does not occur due to a difference in the coefficient of thermal expansion between them, thereby effectively preventing cracks from entering the sealing material,
It is possible to make the semiconductor device housing package completely hermetically sealed and to operate the semiconductor device housed therein normally and stably for a long period of time.

【0048】また、第2領域の封止材の熱膨張係数を6.
0〜7.5ppm/℃と、ムライト質焼結体に較べてその機
械的強度の高い酸化アルミニウム質焼結体の熱膨張係数
に近似させたことから、蓋体として酸化アルミニウム質
焼結体を用いたとしても、封止材の第2領域と蓋体との
間にそれぞれの熱膨張係数の相違に起因して大きな応力
が発生することはなく、その結果、蓋体の厚みを0.25m
m程度と薄いものとすることができ、半導体素子収納用
パッケージを薄型化できる。
The thermal expansion coefficient of the sealing material in the second region is set to 6.
Since the thermal expansion coefficient of 0 to 7.5 ppm / ° C was approximated to the coefficient of thermal expansion of the aluminum oxide sintered body having higher mechanical strength than that of the mullite sintered body, the aluminum oxide sintered body was used as the lid. Even if it does, a large stress does not occur between the second region of the sealing material and the lid due to the difference in the coefficient of thermal expansion, and as a result, the thickness of the lid becomes 0.25 m.
m, and the thickness of the semiconductor device housing package can be reduced.

【0049】さらに、本発明の半導体装置によれば、封
止材を酸化鉛を含まない五酸化燐35〜55重量%、一酸化
錫20〜40重量%、酸化亜鉛10〜20重量%、酸化アルミニ
ウム2〜4重量%、酸化珪素1〜3重量%および酸化ホ
ウ素1〜6重量%から成るガラス成分にフィラーとして
コージェライト系化合物を外添加で40〜45重量%添加し
た第1領域と、五酸化燐35〜55重量%、一酸化錫20〜40
重量%、酸化亜鉛10〜20重量%、酸化アルミニウム2〜
4重量%、酸化珪素1〜3重量%および酸化ホウ素1〜
6重量%から成るガラス成分にフィラーとしてコージェ
ライト系化合物を外添加で16〜30重量%添加した第2領
域とで構成したことから、人体に害を与えたり地球環境
に負荷を与えることはなく、またその封止温度が430℃
程度と低いことから絶縁基体と蓋体とを接合させ、半導
体素子収納用パッケージを気密に封止する際の温度を低
温と成すことができ、その結果、封止材を溶融させる熱
が内部に収容する半導体素子に作用しても半導体素子の
特性に劣化を招来することはなく、半導体素子を長期間
にわたり正常、かつ安定に作動させることができる。
Further, according to the semiconductor device of the present invention, the encapsulant is made of 35 to 55% by weight of phosphorus pentoxide containing no lead oxide, 20 to 40% by weight of tin monoxide, 10 to 20% by weight of zinc oxide, A first region in which a cordierite-based compound is externally added as a filler to a glass component consisting of 2 to 4% by weight of aluminum, 1 to 3% by weight of silicon oxide, and 1 to 6% by weight of boron oxide; 35-55% by weight phosphorus oxide, 20-40 tin oxide
Wt%, zinc oxide 10 ~ 20wt%, aluminum oxide 2 ~
4% by weight, 1 to 3% by weight of silicon oxide and 1 to 3% of boron oxide
Since it is composed of a glass component consisting of 6% by weight and a cordierite-based compound as a filler in a second region where 16-30% by weight is externally added, there is no harm to the human body and no load on the global environment. , And its sealing temperature is 430 ℃
Since the temperature is low, the temperature at which the insulating base and the lid are joined to each other to seal the semiconductor device housing package hermetically can be reduced to a low temperature. As a result, heat for melting the sealing material is generated inside. Even if it acts on the semiconductor element to be housed, the characteristics of the semiconductor element do not deteriorate, and the semiconductor element can be operated normally and stably for a long period of time.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の半導体素子収納用パッケージの実施の
形態の一例を示す断面図である。
FIG. 1 is a cross-sectional view showing an example of an embodiment of a semiconductor element storage package according to the present invention.

【符号の説明】[Explanation of symbols]

1・・・・・・・・・絶縁基体 1a・・・・・・・・凹部 2・・・・・・・・・蓋体 3・・・・・・・・・外部リード端子 4・・・・・・・・・封止材 4a・・・・・・・・封止材の第1領域 4b・・・・・・・・封止材の第2領域 5・・・・・・・・・半導体素子 1 ... insulating base 1a ... recess 2 ... lid 3 ... external lead terminal 4 ... ······················································································································································ ..Semiconductor elements

───────────────────────────────────────────────────── フロントページの続き Fターム(参考) 4G062 AA08 AA09 AA15 BB09 DA03 DB03 DC03 DD01 DE04 DF05 DF06 EA01 EA10 EB01 EC01 ED01 EE01 EF01 EG01 FA01 FB01 FC01 FD01 FE04 FE05 FF01 FG01 FH01 FJ01 FK01 FL01 GA01 GA10 GB01 GC01 GD01 GE01 HH01 HH03 HH05 HH07 HH09 HH11 HH13 HH15 HH17 HH20 JJ01 JJ03 JJ05 JJ07 JJ10 KK01 KK03 KK05 KK07 KK10 MM08 NN29 PP06 ──────────────────────────────────────────────────続 き Continued on the front page F term (reference) 4G062 AA08 AA09 AA15 BB09 DA03 DB03 DC03 DD01 DE04 DF05 DF06 EA01 EA10 EB01 EC01 ED01 EE01 EF01 EG01 FA01 FB01 FC01 FD01 FE04 FE05 FE05 FF01 FG01 GA01 F0101 HH01 HH03 HH05 HH07 HH09 HH11 HH13 HH15 HH17 HH20 JJ01 JJ03 JJ05 JJ07 JJ10 KK01 KK03 KK05 KK07 KK10 MM08 NN29 PP06

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 半導体素子の搭載部を有する絶縁基体
に、前記搭載部を取り囲み、内側に前記半導体素子を収
容する空所を形成するための蓋体を、間に前記半導体素
子が電気的に接続される外部リード端子を挟んで封止材
で接合して成り、前記空所に前記半導体素子を気密に封
止する半導体素子収納用パッケージであって、前記封止
材は前記絶縁基体側の第1領域と前記蓋体側の第2領域
とで前記外部リード端子を挟持しており、前記封止材の
第1領域および第2領域の熱膨張係数がそれぞれ4.5
〜5.5ppm/℃および6.0〜7.5ppm/℃で
あることを特徴とする半導体素子収納用パッケージ
1. An insulating base having a mounting portion for a semiconductor element, a cover for surrounding the mounting portion and forming a space for accommodating the semiconductor element therein, and the semiconductor element electrically interposed therebetween. A semiconductor element housing package that is formed by joining with a sealing material across an external lead terminal to be connected, and hermetically seals the semiconductor element in the space, wherein the sealing material is provided on the insulating base side. The first region and the second region on the lid side sandwich the external lead terminal, and the first region and the second region of the sealing material have a thermal expansion coefficient of 4.5.
-5.5 ppm / ° C. and 6.0-7.5 ppm / ° C.
【請求項2】 前記封止材は五酸化燐35〜55重量
%、一酸化錫20〜40重量%、酸化亜鉛10〜20重
量%、酸化アルミニウム2〜4重量%、酸化珪素1〜3
重量%および酸化ホウ素1〜6重量%のガラス成分から
なり、さらに前記第1領域および第2領域にはそれぞれ
外添加で40〜45重量%および16〜30重量%のコ
ージェライト系化合物のフィラーが添加されていること
を特徴とする請求項1記載の半導体素子収納用パッケー
ジ。
2. The sealing material comprises 35 to 55% by weight of phosphorus pentoxide, 20 to 40% by weight of tin monoxide, 10 to 20% by weight of zinc oxide, 2 to 4% by weight of aluminum oxide, and 1 to 3% by weight of silicon oxide.
% And a glass component of 1 to 6% by weight of boron oxide, and the first region and the second region further contain 40 to 45% by weight and 16 to 30% by weight of a cordierite-based compound filler by external addition. The package for accommodating a semiconductor element according to claim 1, wherein the package is added.
【請求項3】 前記フィラーの平均粒径が3〜9μmで
あることを特徴とする請求項2記載の半導体素子収納用
パッケージ。
3. The package according to claim 2, wherein the filler has an average particle size of 3 to 9 μm.
【請求項4】 請求項1乃至請求項3記載の半導体素子
収納用パッケージの前記搭載部に前記半導体素子を搭載
して前記外部リード端子に電気的に接続するとともに、
前記蓋体を前記封止材で接合したことを特徴とする半導
体装置。
4. The semiconductor element storage package according to claim 1, wherein the semiconductor element is mounted on the mounting portion and is electrically connected to the external lead terminals.
A semiconductor device, wherein the lid is joined with the sealing material.
JP2000078013A 2000-03-21 2000-03-21 Package for containing semiconductor element and semiconductor device using it Pending JP2001267446A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000078013A JP2001267446A (en) 2000-03-21 2000-03-21 Package for containing semiconductor element and semiconductor device using it

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000078013A JP2001267446A (en) 2000-03-21 2000-03-21 Package for containing semiconductor element and semiconductor device using it

Publications (1)

Publication Number Publication Date
JP2001267446A true JP2001267446A (en) 2001-09-28

Family

ID=18595481

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000078013A Pending JP2001267446A (en) 2000-03-21 2000-03-21 Package for containing semiconductor element and semiconductor device using it

Country Status (1)

Country Link
JP (1) JP2001267446A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016042535A (en) * 2014-08-18 2016-03-31 積水化学工業株式会社 Electronic component device and bonding material for ceramic package
JP2017088712A (en) * 2015-11-07 2017-05-25 山陽色素株式会社 Pigment dispersion and coloring composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016042535A (en) * 2014-08-18 2016-03-31 積水化学工業株式会社 Electronic component device and bonding material for ceramic package
JP2017088712A (en) * 2015-11-07 2017-05-25 山陽色素株式会社 Pigment dispersion and coloring composition

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