JP2001157821A - Wet flue gas desulfurization equipment and method for operating the same - Google Patents

Wet flue gas desulfurization equipment and method for operating the same

Info

Publication number
JP2001157821A
JP2001157821A JP34514099A JP34514099A JP2001157821A JP 2001157821 A JP2001157821 A JP 2001157821A JP 34514099 A JP34514099 A JP 34514099A JP 34514099 A JP34514099 A JP 34514099A JP 2001157821 A JP2001157821 A JP 2001157821A
Authority
JP
Japan
Prior art keywords
absorption tower
internal support
flue gas
gas
inlet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP34514099A
Other languages
Japanese (ja)
Other versions
JP3623902B2 (en
Inventor
Atsushi Katagawa
篤 片川
Yasuki Hashimoto
泰樹 橋本
Hajime Okura
一 大倉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Power Ltd
Original Assignee
Babcock Hitachi KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Babcock Hitachi KK filed Critical Babcock Hitachi KK
Priority to JP34514099A priority Critical patent/JP3623902B2/en
Publication of JP2001157821A publication Critical patent/JP2001157821A/en
Application granted granted Critical
Publication of JP3623902B2 publication Critical patent/JP3623902B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

PROBLEM TO BE SOLVED: To prevent scales from being formed on an inner support provided in a gas inlet port of an absorption tower. SOLUTION: A washing water pipe 21 is provided to prevent scales from being formed on an inner support (inlet post) 20 provided in a gas inlet 19 for introducing exhaust gas of a wet flue gas desulfurization equipment. In the pipe 21, a spray nozzle is provided at two locations, that is, near the upper part of the inlet 19 and near the front side of the support 20, or washing water is supplied into the support 20 provided in the gas inlet 19 to cause the water to flow out of the upper part of the support 20. When a circulation pump is actuated to feed absorption liquid into an absorption tower from an absorption liquid reservoir at the start of the desulfurization equipment, a forced water cleaning is started and after gas is supplied, it is effective that water washing is carried out within the allowable water balance of the absorption tower.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は排煙脱硫装置に係
り、特に吸収塔のガス入口部に設けた内部サポート(入
口部ポスト)へのスケーリングを防止するのに好適な湿
式排煙脱硫装置とその運転方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a flue gas desulfurization apparatus, and more particularly to a wet flue gas desulfurization apparatus suitable for preventing scaling to an internal support (entrance post) provided at a gas inlet of an absorption tower. It relates to the driving method.

【0002】[0002]

【従来の技術】大気汚染防止のため、排ガス中の硫黄酸
化物の除去装置として、湿式石灰石−石膏脱硫装置が広
く実用化されている。この湿式石灰石−石膏脱硫装置の
従来技術を図3に示す。
2. Description of the Related Art In order to prevent air pollution, wet limestone-gypsum desulfurization apparatuses are widely used as apparatuses for removing sulfur oxides in exhaust gas. FIG. 3 shows a conventional technique of this wet limestone-gypsum desulfurization apparatus.

【0003】火力発電所のボイラ等から発生した硫黄酸
化物を含む排ガス1は脱硫装置の吸収塔2に導かれる。
吸収塔2では多数のスプレノズル4を備えたスプレヘッ
ダ3が設置されており、スプレノズル4から微細な液滴
として噴霧される吸収液と排ガス1を接触させること
で、排ガス中の硫黄酸化物は吸収液滴の表面で化学的に
除去される。排ガス流れに同伴する微小な液滴は吸収塔
2の上部に設置されたミストエリミネータ5で除去さ
れ、浄化ガス6は必要により吸収塔2の後流側に設置さ
れる図示していない再加熱設備により昇温されて、煙突
より大気中に排出される。
[0003] Exhaust gas 1 containing sulfur oxides generated from a boiler or the like of a thermal power plant is led to an absorption tower 2 of a desulfurizer.
The absorption tower 2 is provided with a spray header 3 having a large number of spray nozzles 4. By contacting the absorption liquid sprayed as fine droplets from the spray nozzles 4 with the exhaust gas 1, the sulfur oxides in the exhaust gas are absorbed by the absorption liquid. Chemically removed at the surface of the drop. Small droplets accompanying the exhaust gas flow are removed by a mist eliminator 5 installed on the upper part of the absorption tower 2, and the purification gas 6 is installed on a downstream side of the absorption tower 2 as necessary, if necessary. , And is discharged from the chimney into the atmosphere.

【0004】スプレノズル4から噴霧された大部分の液
滴は硫黄酸化物を吸収したのち吸収塔2の下部に設けら
れた吸収塔循環タンク7に落下する。吸収塔循環タンク
7からは循環ポンプ17により再びスプレノズル4に送
られ、噴霧される。
Most of the droplets sprayed from the spray nozzle 4 absorb the sulfur oxides and then fall into an absorption tower circulation tank 7 provided below the absorption tower 2. The water is again sent from the absorption tower circulation tank 7 to the spray nozzle 4 by the circulation pump 17 and sprayed.

【0005】吸収液に吸収された硫黄酸化物(SO
は、吸収液中に含まれる石灰石(CaCO)と反応
し、さらに吸収塔循環タンク7に供給される空気8によ
って酸化されて石膏(CaSO・2HO)となる。
吸収塔循環タンク7に供給される空気8は酸化用撹拌機
18で吸収液をかきまぜることによって、前記酸化反応
が促進される。この一連の反応は下記式によって表され
る。 SO+2HO+CaCO+1/2O→CaSO
・2HO+CO
[0005] Sulfur oxide (SO 2 ) absorbed in the absorbing solution
Reacts with limestone (CaCO 3 ) contained in the absorption liquid, and is further oxidized by air 8 supplied to the absorption tower circulation tank 7 to become gypsum (CaSO 4 .2H 2 O).
The air 8 supplied to the absorption tower circulation tank 7 is stirred by the oxidizing agitator 18 to absorb the absorbing liquid, thereby promoting the oxidizing reaction. This series of reactions is represented by the following formula. SO 2 + 2H 2 O + CaCO 3 + / O 2 → CaSO
4 · 2H 2 O + CO 2

【0006】一方、吸収剤である石灰石9は石灰石供給
設備10で石灰石スラリとして貯えられ、石灰石スラリ
ポンプ11より吸収塔循環ランク7へ供給される。ま
た、吸収塔2内で生成した石膏を回収するため、吸収塔
循環タンク7内の吸収液の一部を抜出しポンプ12によ
り石膏脱水設備13に送液し、吸収液中に含まれている
石膏14を煤塵と共に回収する。石膏14および煤塵の
脱水ろ液は、系内に不純物が濃縮するのを防ぐため一部
を排水ライン15を通って系外に排出され、残りの液は
石灰石供給設備10において石灰石スラリ製造用補給水
として使用され、残りは吸収塔2の吸収塔循環タンク7
へ脱水ろ液ライン16を経て送液される。
On the other hand, limestone 9 as an absorbent is stored as limestone slurry in a limestone supply facility 10 and supplied to an absorption tower circulation rank 7 from a limestone slurry pump 11. Further, in order to collect the gypsum generated in the absorption tower 2, a part of the absorption liquid in the absorption tower circulation tank 7 is withdrawn and sent to the gypsum dewatering equipment 13 by the pump 12, and the gypsum contained in the absorption liquid is removed. 14 is collected together with the dust. Part of the dehydrated filtrate of gypsum 14 and dust is discharged out of the system through a drain line 15 to prevent impurities from being concentrated in the system, and the remaining liquid is supplied to a limestone supply facility 10 for limestone slurry production. The remaining water is used as water, and the rest is
The liquid is sent via a dehydration filtrate line 16 to the liquid.

【0007】また、吸収塔2の排ガス入口部19には、
その強度を確保するために内部サポート(入口部ポス
ト)20(図4)が設置されている。
The exhaust gas inlet 19 of the absorption tower 2 has
An internal support (entrance post) 20 (FIG. 4) is provided to secure the strength.

【0008】脱硫装置の通常運転中は通ガスにより前記
入口部19の内部サポート20へは吸収液の飛散はあま
り生じないが、脱硫装置の起動時にはホットガスから吸
収塔2の内部を保護するため、先に循環ポンプ17を起
動し、その後に通ガスを開始する。このため、脱硫装置
の起動開始から通ガスまでの間に吸収塔2でスプレされ
た吸収液の一部が入口部19側へ再飛散するため、入口
部19の内部サポート20への石膏などのスケーリング
が生じていた。
During normal operation of the desulfurization unit, the gas does not scatter the absorption liquid to the internal support 20 at the inlet 19 due to the passing gas. However, when the desulfurization unit is started, the interior of the absorption tower 2 is protected from hot gas. First, the circulating pump 17 is started, and thereafter, gas flow is started. For this reason, a part of the absorption liquid sprayed in the absorption tower 2 from the start of the desulfurization device to the passage of gas is re-sprayed to the inlet 19 side. Scaling had occurred.

【0009】この入口部19の内部サポート20への石
膏スケール付着例を図4(図4(a)は入口部19の内
部サポート20に石膏スケール31が付着した状態を示
す吸収塔平面断面図、図4(b)は図4(a)のA−A
線矢視図)に示すが、吸収塔2の入口部19のガス流れ
断面方向に石膏スケール31が成長してくるため、吸収
塔2の入口部19の圧力損失が増大し、石膏スケール3
1の成長度合いが大きくなると、排ガス送風用の図示し
ないファンの容量をオーバーし、脱硫装置が運転不能と
なってしまう問題がある。
FIG. 4 shows an example of the gypsum scale attached to the internal support 20 of the inlet 19 (FIG. 4 (a) is a plan sectional view of an absorption tower showing a state where the gypsum scale 31 is attached to the internal support 20 of the inlet 19; FIG. 4B is a sectional view taken along a line AA in FIG.
As shown in the figure, since the gypsum scale 31 grows in the gas flow cross-sectional direction of the inlet section 19 of the absorption tower 2, the pressure loss at the inlet section 19 of the absorption tower 2 increases, and the gypsum scale 3
When the degree of growth of 1 is large, the capacity of a fan (not shown) for blowing exhaust gas is exceeded, and there is a problem that the desulfurization device becomes inoperable.

【0010】[0010]

【発明が解決しようとする課題】上記従来技術は、吸収
塔2でスプレされた吸収液の一部が吸収塔2の排ガス入
口部19側へ再飛散するため、前記入口部19の内部サ
ポート20へのスケーリングが生じる問題があった。
In the above prior art, a part of the absorbing solution sprayed in the absorption tower 2 re-sprays to the exhaust gas inlet 19 side of the absorption tower 2, so that the internal support 20 There was a problem that scaling to to occur.

【0011】本発明の課題は、吸収塔のガス入口部に設
けられる内部サポートへのスケーリングを防止すること
にある。
It is an object of the present invention to prevent scaling to an internal support provided at the gas inlet of an absorption tower.

【0012】[0012]

【課題を解決するための手段】上記本発明の課題は、側
壁面に設けたガス入口部から導入した排ガスと塔内にお
いて接触させるために一段または複数段設けた排ガス中
の煤塵の除去および硫黄酸化物を吸収除去する吸収液噴
霧用の複数のスプレノズルを有するスプレヘッダを設け
た吸収塔と該吸収塔の下部に設けた硫黄酸化物を吸収し
て亜硫酸塩を生成した吸収液を一時貯留する吸収塔循環
タンクと該吸収塔循環タンクに空気を供給して該亜硫酸
塩を酸化した吸収液を循環ポンプにより再び上記吸収塔
へ再循環させる湿式排煙脱硫装置において、上記吸収塔
のガス入口部を支持する内部サポートを設け、該内部サ
ポートへのスケーリング防止用の水洗ラインを設けた湿
式排煙脱硫装置により解決される。
SUMMARY OF THE INVENTION It is an object of the present invention to remove soot and sulfur in exhaust gas provided in one or more stages so as to be brought into contact with the exhaust gas introduced from a gas inlet provided on a side wall surface in a tower. An absorption tower provided with a spray header having a plurality of spray nozzles for spraying an absorption liquid for absorbing and removing oxides, and an absorption for temporarily storing an absorption liquid provided at a lower portion of the absorption tower, which absorbs sulfur oxides and generates sulfite. In a wet flue gas desulfurization apparatus in which air is supplied to a tower circulation tank and the absorption tower circulation tank to recirculate the oxidized absorbent of the sulfite to the absorption tower again by a circulation pump, the gas inlet of the absorption tower is The problem is solved by a wet flue gas desulfurization apparatus provided with an internal support for supporting and a washing line for preventing scaling of the internal support.

【0013】前記スケーリング防止用の水洗ラインは、
吸収塔のガス入口部の上方部分と内部サポート全面に向
けてそれぞれ水洗水を噴霧するスプレノズルを設ける
か、または吸収塔のガス入口部に設けた内部サポートの
内部に水洗水を供給し、該サポートの上部から水洗水を
流出させる構成とすることにより達成される。
[0013] The scaling-preventive washing line includes:
A spray nozzle for spraying washing water toward the upper part of the gas inlet of the absorption tower and the entire surface of the internal support is provided, or washing water is supplied to the inside of the internal support provided at the gas inlet of the absorption tower, and the support is provided. This is achieved by having a configuration in which the washing water flows out from the upper part.

【0014】なお、湿式排煙脱硫装置の起動時に循環ポ
ンプ起動により内部サポートの水洗を開始し、通ガス開
始以降は吸収塔の水バランスが許容できる範囲で前記水
洗を行うことが効果的である。
It is effective to start rinsing of the internal support by activating the circulation pump when the wet flue gas desulfurization apparatus is started, and to perform the rinsing as long as the water balance of the absorption tower is acceptable after the start of gas supply. .

【0015】[0015]

【作用】湿式排煙脱硫装置の起動時に循環ポンプ起動に
より吸収塔のガス入口部の内部サポート(入口部ポス
ト)の水洗を開始し、通ガス開始以降は吸収塔の水バラ
ンスが許容できる範囲で前記内部サポートの水洗を行う
ことにより、ガス入口部の内部サポートへの石膏スケー
リングを防止することが可能となる。
[Function] When the wet flue gas desulfurization unit is started, the circulation pump starts to start washing the internal support (entrance post) of the gas inlet of the absorption tower, and after the start of gas supply, the water balance of the absorption tower is within the allowable range. By washing the internal support with water, it is possible to prevent gypsum scaling of the internal support at the gas inlet.

【0016】[0016]

【発明の実施の形態】本発明の実施の形態を図面ととも
に説明する。本発明の実施の形態の脱硫装置は図3に示
すものと同一であり、図1には本発明の実施の形態の吸
収塔の排ガス入口部の部分平面断面図(図1(a))と
図1(a)のA−A線矢視図(図1(b))を示す。
Embodiments of the present invention will be described with reference to the drawings. The desulfurization apparatus according to the embodiment of the present invention is the same as that shown in FIG. 3, and FIG. 1 is a partial plan cross-sectional view (FIG. 1 (a)) of the exhaust gas inlet of the absorption tower according to the embodiment of the present invention. FIG. 1A is a view taken along line AA of FIG. 1A (FIG. 1B).

【0017】吸収塔のガス入口部19の内部の天井付近
に水洗水配管21を設け、ガス入口部19に鉛直方向に
複数本設けられた内部サポート20に向けて洗浄水をス
プレするスプレノズル22、23が取り付けてある。ス
プレノズル22、23は内部サポート20全体の前面を
水洗するノズル22と内部サポート20上部と吸収塔の
ガス入口部19の天井面との境界を水洗するノズル23
から構成されている。なお、内部サポート20が複数設
けられている場合はそれぞれの内部サポート20に対し
てスプレノズル22、23を設置している。
A washing water pipe 21 is provided near the ceiling inside the gas inlet portion 19 of the absorption tower, and spray nozzles 22 for spraying washing water toward internal supports 20 provided vertically in the gas inlet portion 19 are provided. 23 is attached. The spray nozzles 22 and 23 are provided for washing the entire front surface of the internal support 20 with water, and the nozzle 23 for washing the boundary between the upper portion of the internal support 20 and the ceiling of the gas inlet 19 of the absorption tower.
It is composed of When a plurality of internal supports 20 are provided, spray nozzles 22 and 23 are provided for each of the internal supports 20.

【0018】なお、水洗水配管21から噴霧する水洗水
は脱硫装置運転中は常時スプレすることを基本とし、特
に脱硫装置の起動時に循環ポンプ17を起動してから通
ガスするまでの間に水洗を実施することが望ましい。
The rinsing water sprayed from the rinsing water pipe 21 is basically sprayed at all times during the operation of the desulfurization apparatus. In particular, the rinsing water is supplied between the time when the circulation pump 17 is started and the time when gas is passed when the desulfurization apparatus is started. It is desirable to carry out.

【0019】スプレノズル22、23から噴霧された水
洗水により、ガス入口部19に設けられた内部サポート
20は水洗された状態となり、吸収液が内部サポート2
0に飛散しても水洗されるために内部サポート20に石
膏スケール31が生成することを防止できる。
The internal support 20 provided at the gas inlet 19 is washed by the washing water sprayed from the spray nozzles 22 and 23, and the absorbing liquid is washed by the internal support 2
The gypsum scale 31 can be prevented from being formed on the internal support 20 because the gypsum scale 31 is washed with water even if it is scattered to zero.

【0020】また、通ガス中は吸収塔2へ向かうガス流
れにより、内部サポート20側へ飛散する吸収液は少な
いが、脱硫装置の起動時に循環ポンプ17を起動してか
ら通ガスするまでの間は、吸収液をスプレノズル4から
噴霧することにより吸収塔のガス入口部19側へも多く
の吸収液ミストが舞い上がり、内部サポート20へも吸
収液ミストが付着する。この状態で通ガスした時に、内
部サポート20に付着した吸収液がドライアップして石
膏スケール31が生成する。
During the passage of the gas, a small amount of the absorbing liquid is scattered toward the internal support 20 due to the gas flow toward the absorption tower 2. By spraying the absorbing liquid from the spray nozzle 4, a large amount of the absorbing liquid mist soars toward the gas inlet 19 of the absorption tower, and the absorbing liquid mist adheres to the internal support 20. When gas is passed in this state, the absorbent adhering to the internal support 20 is dried up, and the gypsum scale 31 is generated.

【0021】このため、内部サポート20のスケール3
1生成を防止するためには、特に脱硫装置の起動時に循
環ポンプ17を起動してから通ガスするまでの間は水洗
を実施することが望ましい。また、脱硫装置の運転停止
時にも通ガス停止後に循環ポンプ17を停止させるが、
この間も同様に内部サポート20の水洗を実施すること
が望ましい。
For this reason, the scale 3 of the internal support 20
In order to prevent the generation of 1, it is desirable to perform water washing particularly from the time when the circulation pump 17 is started to the time when gas is passed when the desulfurization device is started. In addition, when the operation of the desulfurization device is stopped, the circulation pump 17 is stopped after the gas supply is stopped.
During this time, it is desirable that the internal support 20 be similarly washed with water.

【0022】本発明によるその他の実施の形態を図2に
示す。図2には、吸収塔2のガス入口部19の部分平面
断面図(図2(a))と図2(a)のA−A線矢視図
(図2(b))と図2(b)の円B内の拡大図(図2
(c))を示す。
FIG. 2 shows another embodiment of the present invention. FIG. 2 is a partial plan cross-sectional view of the gas inlet portion 19 of the absorption tower 2 (FIG. 2A), a view taken along the line AA of FIG. FIG. 2B is an enlarged view of the circle B (FIG. 2)
(C)) is shown.

【0023】図2に示す吸収塔2の内部サポート20
は、その内部が空洞になっており、水洗水は、入口部1
9の外側であって内部サポート20の上方から内部サポ
ート20の内側に水洗水配管24から供給され、該サポ
ート20の側面の高さ方向に複数設けた下向きに開口し
た小径管25から内部サポート20の外表面に流出させ
る構造となっている。
The internal support 20 of the absorption tower 2 shown in FIG.
Has a hollow inside, and the washing water is
The inner support 20 is supplied from the washing water pipe 24 to the inside of the inner support 20 from above the inner support 20 from above and below the inner support 20, and from a plurality of downwardly opening small-diameter pipes 25 provided in the height direction of the side surface of the support 20. The structure is designed to flow out to the outer surface of the device.

【0024】この構造により、図1に示すような吸収塔
入口部19の内部に水洗水配管21を設けることなく内
部サポート20の水洗を実施することが可能となる。
With this structure, it is possible to wash the internal support 20 without providing the washing water pipe 21 inside the absorption tower inlet 19 as shown in FIG.

【0025】[0025]

【発明の効果】本発明によれば、吸収塔入口部の内部サ
ポートへの石膏スケール生成を防止でき、吸収塔のドラ
フトロス増加の問題を解決できる。特に、脱硫装置起動
停止を頻繁に繰り返すプラントに対して本発明は有効で
ある。
According to the present invention, the formation of gypsum scale on the internal support at the inlet of the absorption tower can be prevented, and the problem of increasing the draft loss of the absorption tower can be solved. In particular, the present invention is effective for a plant in which the start and stop of the desulfurization device are frequently repeated.

【図面の簡単な説明】[Brief description of the drawings]

【図1】 本発明の実施の形態の説明図FIG. 1 is an explanatory diagram of an embodiment of the present invention.

【図2】 本発明の他の実施の形態の説明図FIG. 2 is an explanatory view of another embodiment of the present invention.

【図3】 従来技術の説明図FIG. 3 is an explanatory view of a conventional technique.

【図4】 吸収塔入口サポートへの石膏スケール付着例
を示す図
FIG. 4 is a diagram showing an example of gypsum scale adhesion to an absorption tower entrance support.

【符号の説明】[Explanation of symbols]

1 排ガス 2 吸収塔 3 スプレヘッダ 4 スプレノズル 5 ミストエリミネータ 6 浄化ガス 7 吸収塔循環タンク 8 空気 9 石灰石 10 石灰石供給設
備 11 石灰石スラリポンプ 12 抜出しポンプ 13 石膏脱水設備 14 石膏 15 排水ライン 16 脱水ろ液ライ
ン 17 循環ポンプ 18 酸化用攪拌機 19 ガス入口部 20 内部サポート 21、24 水洗水配管 22、23 スプレ
ノズル 25 小径管 31 石膏スケール
DESCRIPTION OF SYMBOLS 1 Exhaust gas 2 Absorption tower 3 Spray header 4 Spray nozzle 5 Mist eliminator 6 Purification gas 7 Absorption tower circulation tank 8 Air 9 Limestone 10 Limestone supply equipment 11 Limestone slurry pump 12 Extraction pump 13 Gypsum dewatering equipment 14 Gypsum 15 Drainage line 16 Dehydration filtrate line 17 Circulation pump 18 Oxidizing stirrer 19 Gas inlet 20 Internal support 21, 24 Rinsing water pipe 22, 23 Spray nozzle 25 Small diameter pipe 31 Gypsum scale

───────────────────────────────────────────────────── フロントページの続き (72)発明者 大倉 一 広島県呉市宝町6番9号 バブコック日立 株式会社呉事業所内 Fターム(参考) 4D002 AA02 AB01 AC01 AC10 BA02 BA05 BA14 BA16 CA01 CA11 CA13 DA05 DA16 EA03 FA03 HA05 4D020 AA06 BA02 BA09 BB03 BB05 CB25 CC05 CC07 CC18 CC30 CD02  ────────────────────────────────────────────────── ─── Continuing on the front page (72) Inventor Kazu Okura 6-9 Takara-cho, Kure-shi, Hiroshima Fab term in Babcock-Hitachi Kure Plant (reference) 4D002 AA02 AB01 AC01 AC10 BA02 BA05 BA14 BA16 CA01 CA11 CA13 DA05 DA16 EA03 FA03 HA05 4D020 AA06 BA02 BA09 BB03 BB05 CB25 CC05 CC07 CC18 CC18 CC30 CD02

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 側壁面に設けたガス入口部から導入した
排ガスと塔内において接触させるために一段または複数
段設けた排ガス中の煤塵の除去および硫黄酸化物を吸収
除去する吸収液噴霧用の複数のスプレノズルを有するス
プレヘッダを設けた吸収塔と該吸収塔の下部に設けた硫
黄酸化物を吸収して亜硫酸塩を生成した吸収液を一時貯
留する吸収塔循環タンクと該吸収塔循環タンクに空気を
供給して該亜硫酸塩を酸化した吸収液を循環ポンプによ
り再び上記吸収塔へ再循環させる湿式排煙脱硫装置にお
いて、 上記吸収塔のガス入口部に、該入口部を支持する内部サ
ポートを設け、該内部サポートへのスケーリング防止用
の水洗ラインを設けたことを特徴とする湿式排煙脱硫装
置。
1. A method for removing dust in exhaust gas and for absorbing and removing sulfur oxides in exhaust gas provided in one or more stages so as to contact the exhaust gas introduced from a gas inlet provided on a side wall surface with the inside of the tower. An absorption tower provided with a spray header having a plurality of spray nozzles, an absorption tower circulating tank provided at the lower part of the absorption tower for temporarily storing an absorbing solution that absorbs sulfur oxides and generates sulfite, and air is supplied to the absorption tower circulating tank. In the wet flue gas desulfurization apparatus for supplying the oxidized sulfite and recirculating the absorbent oxidized by the circulation pump to the absorption tower, an internal support for supporting the inlet is provided at the gas inlet of the absorber. A wet-type flue gas desulfurization apparatus, wherein a water washing line for preventing scaling is provided on the internal support.
【請求項2】 吸収塔のガス入口部に設けた内部サポー
トへのスケーリング防止用の水洗ラインは、吸収塔のガ
ス入口部の上方部分と内部サポート全面に向けてそれぞ
れ水洗水を噴霧するスプレノズルを設けたことを特徴と
する請求項1記載の湿式排煙脱硫装置。
2. A rinsing line for preventing scaling of an internal support provided at a gas inlet of an absorption tower includes a spray nozzle for spraying rinsing water toward an upper portion of the gas inlet of the absorption tower and a whole surface of the internal support. The wet flue gas desulfurization device according to claim 1, wherein the device is provided.
【請求項3】 吸収塔のガス入口部に設けた内部サポー
トの内部に水洗水を供給し、該サポートの上部から水洗
水を流出させることを特徴とする請求項1記載の湿式排
煙脱硫装置。
3. The wet flue gas desulfurization apparatus according to claim 1, wherein washing water is supplied into an internal support provided at a gas inlet of the absorption tower, and the washing water flows out from an upper portion of the support. .
【請求項4】 湿式排煙脱硫装置の起動時に循環ポンプ
起動により内部サポートの水洗を開始し、通ガス開始以
降は吸収塔の水バランスが許容できる範囲で前記水洗を
行うことを特徴とする請求項1記載の湿式排煙脱硫装置
の運転方法。
4. The method according to claim 1, wherein when the wet flue gas desulfurization apparatus is started, the circulating pump is started to wash the internal support, and after the start of gas passage, the washing is performed within an allowable range of the water balance of the absorption tower. Item 4. An operation method of the wet flue gas desulfurization device according to Item 1.
JP34514099A 1999-12-03 1999-12-03 Wet flue gas desulfurization device and its operation method Expired - Lifetime JP3623902B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP34514099A JP3623902B2 (en) 1999-12-03 1999-12-03 Wet flue gas desulfurization device and its operation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP34514099A JP3623902B2 (en) 1999-12-03 1999-12-03 Wet flue gas desulfurization device and its operation method

Publications (2)

Publication Number Publication Date
JP2001157821A true JP2001157821A (en) 2001-06-12
JP3623902B2 JP3623902B2 (en) 2005-02-23

Family

ID=18374559

Family Applications (1)

Application Number Title Priority Date Filing Date
JP34514099A Expired - Lifetime JP3623902B2 (en) 1999-12-03 1999-12-03 Wet flue gas desulfurization device and its operation method

Country Status (1)

Country Link
JP (1) JP3623902B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005152745A (en) * 2003-11-25 2005-06-16 Babcock Hitachi Kk Wet flue gas desulfurization method and wet flue gas desulfurizer
JP2007301519A (en) * 2006-05-15 2007-11-22 Mitsubishi Materials Corp Clogging inhibition method of flue for sulfur containing exhaust gas, and flue for sulfur containing exhaust gas

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005152745A (en) * 2003-11-25 2005-06-16 Babcock Hitachi Kk Wet flue gas desulfurization method and wet flue gas desulfurizer
JP4587197B2 (en) * 2003-11-25 2010-11-24 バブコック日立株式会社 Wet flue gas desulfurization method and apparatus
JP2007301519A (en) * 2006-05-15 2007-11-22 Mitsubishi Materials Corp Clogging inhibition method of flue for sulfur containing exhaust gas, and flue for sulfur containing exhaust gas
JP4715629B2 (en) * 2006-05-15 2011-07-06 三菱マテリアル株式会社 Method for preventing clogging of flue for sulfur-containing exhaust gas and flue for sulfur-containing exhaust gas

Also Published As

Publication number Publication date
JP3623902B2 (en) 2005-02-23

Similar Documents

Publication Publication Date Title
JP4785006B2 (en) Wet flue gas desulfurization equipment
US5779999A (en) Method for scrubbing flue gases
JPH0372913A (en) Method and apparatus for treating exhaust gas
JP3757437B2 (en) Activated carbon catalytic reactor, flue gas desulfurization apparatus and desulfurization method using the same
US4986966A (en) Retrofit flue gas scrubber system
WO1988009695A1 (en) Flue gas scrubber system
JP3623902B2 (en) Wet flue gas desulfurization device and its operation method
JP2000024461A (en) Method and system for flue gas desulfurization
JPH11104449A (en) Spray absorption tower and wet flue gas desulfurization apparatus having the same
JP2003103139A (en) Wet process flue gas desulfurizer
JP2006320828A (en) Wet-type flue gas desulfurization apparatus
JPH1133352A (en) Absorption tower for flue gas desulfurization equipment
KR200412134Y1 (en) Wet flue gas desulfurization apparatus
JP2008080261A (en) Exhaust gas treatment method
JP2000288337A (en) Wet exhaust gas desulfurization apparatus
JP2002153727A (en) Double chamber type wet flue gas desulfurization device
JP2003190739A (en) Wet-type flue-gas desulfurization equipment
JP3610437B2 (en) Exhaust gas treatment method and apparatus
JP2001120946A (en) Wet stack gas desulfurizing device and its operation method
JP3333031B2 (en) Wet exhaust gas desulfurization method
JPH0663353A (en) Wet flue gas desulfurizer and its method
JP3483008B2 (en) Flue gas desulfurization equipment
JP2003210935A (en) Wet-type flue-gas desulfurization equipment
JP3498803B2 (en) Wet flue gas desulfurization equipment
JPH0929059A (en) Flue gas desulfurization and device therefor

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20040406

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20041105

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20041116

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20041126

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

Ref document number: 3623902

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20071203

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20081203

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091203

Year of fee payment: 5

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20091203

Year of fee payment: 5

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101203

Year of fee payment: 6

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20101203

Year of fee payment: 6

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20111203

Year of fee payment: 7

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20121203

Year of fee payment: 8

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20131203

Year of fee payment: 9

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313111

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

EXPY Cancellation because of completion of term