JP2000086256A - Open pore type porous glass sintered body and its production - Google Patents

Open pore type porous glass sintered body and its production

Info

Publication number
JP2000086256A
JP2000086256A JP10297519A JP29751998A JP2000086256A JP 2000086256 A JP2000086256 A JP 2000086256A JP 10297519 A JP10297519 A JP 10297519A JP 29751998 A JP29751998 A JP 29751998A JP 2000086256 A JP2000086256 A JP 2000086256A
Authority
JP
Japan
Prior art keywords
glass
sintered body
mold
porous glass
inorganic binder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10297519A
Other languages
Japanese (ja)
Inventor
Toshio Hoshino
俊雄 星野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP10297519A priority Critical patent/JP2000086256A/en
Publication of JP2000086256A publication Critical patent/JP2000086256A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B32/00Artificial stone not provided for in other groups of this subclass
    • C04B32/005Artificial stone obtained by melting at least part of the composition, e.g. metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/06Other methods of shaping glass by sintering, e.g. by cold isostatic pressing of powders and subsequent sintering, by hot pressing of powders, by sintering slurries or dispersions not undergoing a liquid phase reaction
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00267Materials permeable to vapours or gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Processing Of Solid Wastes (AREA)
  • Glass Compositions (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain an open pore type porous glass sintered body having a specified apparent porosity, a specified bulk specific gravity and a specified bending strength by sintering granules obtained by crushing recovered glass articles by way of an inorganic binder. SOLUTION: The sintered body has 25-40% apparent porosity, a bulk specific gravity of 1.0-1.3 and 50-100 kgf/cm2 bending strength. A mixture of 100 pts.wt. granules obtained by crushing and 3-8 pts.wt. inorganic binder is press-molded in a mold, dried in the mold and fired at 600-800 deg.C to obtain the sintered body useful as a material for civil engineering and construction and for apparatus industry through simple producing steps as a recycled prodgct of waste at a low cost. The inorganic binder is preferably water glass and the grain size of the granules is preferably 8-200 mesh. Glass bottles 1 classified according to color are crushed to obtain glass granules 3, the granules 3 are sieved and the sieved glass granules 5 are mixed with an inorganic binder 6. The mixture is filled into a mold 9 and press-molded with a press 10, the resultant molding 11 is dried by heating and the solidified molding 13 is fired in a firing furnace 14. The resultant sintered body has high strength and high gas permeability and can be used at 500-600 deg.C.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本願発明は、一般廃棄物である回
収ガラス製品を粉砕し粒状化したものを主原料とする連
通多孔質ガラス焼結体に関するものであり、資源の有効
利用を目的とした連通多孔質ガラス焼結体及びその製造
方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a continuous porous glass sintered body whose main raw material is obtained by crushing and granulating recovered glass products as general waste. And a method for producing the same.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】回収ガ
ラス製品のうち色付きガラス製品は、再生が困難であ
り、その有効利用策が回収処理機関等で要望されてい
た。
2. Description of the Related Art Colored glass products among recovered glass products are difficult to regenerate, and there has been a demand for effective use of such products by recovery processing organizations.

【0003】[0003]

【課題を解決するための手段】本発明者は、上記課題を
解決すべ〈鋭意研究を行なった結果回収ガラスビンを粉
砕し篩分した粉砕粒を得て見掛け気孔率30〜40%、
カサ比重1.0〜13、曲げ強度50〜100kgf/
cmの物性を有す連通多孔質ガラス焼結体を製造する
ことに成功した。
Means for Solving the Problems The present inventor should solve the above-mentioned problems. As a result of intensive studies, the recovered glass bottles were crushed and sieved to obtain crushed granules to obtain an apparent porosity of 30 to 40%.
Casa specific gravity 1.0-13, bending strength 50-100kgf /
It succeeded in producing a communicating porous glass sintered body having physical properties of cm 2 .

【0004】すなわち、本願発明は以下のものである。 (1)素材が、回収ガラス製品粉砕粒の焼結体よりなる
ことを特徴とする連通多孔質ガラス焼結体。 (2)回収ガラス製品粉砕粒が無機結合材を介して焼結
されてなることを特徴とする連通多孔質ガラス焼結体。 (3)回収ガラス製品粉砕粒100重量部に対して無機
結合材3〜8重量部を添加混合し、焼結されてなること
を特徴とする連結多孔質ガラス焼結体。 (4)連結多孔質ガラス焼結体の物性値が、見掛け気孔
率30〜40%、カサ比重1.0〜1.3、曲げ強度5
0〜100kgf/cmであることを特徴とする請求
項1ないし3のいずれに記載の連通多孔質ガラス焼結
体。 (5)回収ガラスビン粉砕粒に結合材を添加混合し、そ
れを型に充填し、加圧成形後型内にて乾燥した後取り出
し、600〜800℃で焼成することを特徴とする連通
多孔質ガラス焼結体の製造方法。 (6)回収ガラスピン粉砕粒100重量部に対して重機
結合材3〜8重量部を添加混合し、それを型に充填し加
圧成形後型内にて乾燥した後取り出し、600〜800
℃で焼成することを特徴とする連通多孔質ガラス焼結体
の製造方法。 (7)回収ガラスビン粉砕粒の粒度が、8〜200メッ
シュであることを特徴とする請求項5又は6記載の連通
多孔質ガラス焼結体の製造方法。 (8)無機結合材が水ガラスであることを特徴とする請
求項5又は6記載の連通多孔質ガラス焼結体の製造方
法。 (9)無機結合材が水ガラス100号重量部に対して回
収ガラスビン粉砕粒の200メッシュ以下のもの100
〜150重量部を添加混合したスラリー状液体からなる
ことを特徴とする請求項5又は6記載の連通多孔質ガラ
ス焼結体の製造方法。 (10)回収ガラスビン粉砕粒が、例えば8〜20メッ
シュ、20〜30メッシュ等に区分され、それを1区分
又は2区分以上混合したものであることを特徴とする請
求項5又は6記載の連通多孔質ガラス焼結体の製造方
法。 (11)回収ガラスビン粉砕粒が、例えば8〜20メッ
シュ、20〜30メッシュ等に区分され、それを1区分
100重量部に対して無機結合材3〜8重量部を添加混
合したものを2区分以上型に積層充填し、加圧成形後型
内にて乾燥した後取り出し600〜800℃で焼成する
ことを特徴とする連通多孔質ガラス焼結体の製造方法。 (12)回収ガラスビン粉砕粒が、色毎に分別され、そ
れを1種類又は2種類以上混合したものであることを特
徴とする請求項10又は11の連通多孔質ガラス焼結
体。
That is, the present invention is as follows. (1) A communicating porous glass sintered body characterized in that the material is made of a sintered body of ground particles of recovered glass products. (2) A communicating porous glass sintered body characterized in that ground particles of recovered glass products are sintered via an inorganic binder. (3) A connected porous glass sintered body characterized in that 3 to 8 parts by weight of an inorganic binder is added to 100 parts by weight of the ground particles of recovered glass product, mixed, and sintered. (4) Physical properties of the connected porous glass sintered body are apparent porosity of 30 to 40%, bulk specific gravity of 1.0 to 1.3, and bending strength of 5
Communicating porous glass sintered body according to any of claims 1, characterized in that a 0~100kgf / cm 2 3. (5) An interconnected porous material characterized by adding a binder to the pulverized recovered glass bottle, mixing the mixture into a mold, filling the mold, pressing, drying in a mold, taking out and firing at 600 to 800 ° C. A method for manufacturing a glass sintered body. (6) 3 to 8 parts by weight of a heavy equipment binder is added to and mixed with 100 parts by weight of the recovered glass pin pulverized particles, and the mixture is filled in a mold, pressed, dried in a mold, and taken out.
A method for producing a communicating porous glass sintered body, characterized by firing at a temperature of ℃. (7) The method for producing a continuous porous glass sintered body according to claim 5 or 6, wherein the particle size of the collected glass bottle pulverized particles is 8 to 200 mesh. (8) The method according to claim 5 or 6, wherein the inorganic binder is water glass. (9) An inorganic binder having a size of 200 mesh or less of the crushed particles of the recovered glass bottle per 100 parts by weight of the water glass 100
The method for producing a continuous porous glass sintered body according to claim 5, comprising a slurry-like liquid obtained by adding and mixing 150 to 150 parts by weight. (10) The communication according to (5) or (6), wherein the crushed particles of the recovered glass bottle are divided into, for example, 8 to 20 mesh, 20 to 30 mesh, and the like, and one or two or more of these are mixed. A method for producing a porous glass sintered body. (11) The recovered glass bottle pulverized particles are divided into, for example, 8 to 20 mesh, 20 to 30 mesh, and the like. A method for producing a continuous porous glass sintered body, comprising laminating and filling a mold, drying in a mold after pressure molding, and taking out and firing at 600 to 800 ° C. (12) The communicating porous glass sintered body according to (10) or (11), wherein the pulverized particles of the recovered glass bottle are sorted for each color, and one kind or a mixture of two or more kinds thereof is used.

【0006】上記本願発明で主原料として使用されるガ
ラス粒は、一般産業物である回収ガラスビンを粉砕した
ものである。特に色付きビンのようにビンとして再生出
来ないものは回収処理機関等に於いてその再利用が大き
な課題となっているが、本願発明により大いに活路が開
かれるものである。
The glass particles used as the main raw material in the present invention are obtained by pulverizing a recovered glass bottle which is a general industrial product. In particular, those that cannot be recycled as bins, such as colored bottles, have a great problem of being reused in collection and disposal facilities and the like.

【0007】粉砕し篩分けたガラス粒は、無機結合材を
介して点接触状態で焼結され為、連通多孔質となるもの
であり、ガラス粒の粒度を変えることによりその開孔径
が調整できるものである。さらに、無機結合材として水
ガラスを使用する為取り扱いが簡単でコストにも安価で
ある。又焼成時に有害ガスが発生しない。
The crushed and sieved glass particles are sintered in a point contact state via an inorganic binder, and thus become porous. The opening diameter can be adjusted by changing the particle size of the glass particles. Things. Furthermore, since water glass is used as the inorganic binder, the handling is simple and the cost is low. No harmful gas is generated during firing.

【0008】本願発明に於いては、水ガラス中に200
メッシュ以下のガラス粒を混合しスラリー状としたもの
を無機結合材として使用することに依り回収ガラスビン
の粉砕物ほとんど再利用可能となる。又焼結に依る結合
力が高められ高強度を有す連通多孔質ガラス焼結体の製
造が可能となる。
[0008] In the present invention, 200 in water glass
By using a slurry obtained by mixing glass particles having a mesh size or less as the inorganic binder, the crushed material of the recovered glass bottle can be almost reused. In addition, the bonding force due to sintering is increased, and it is possible to manufacture a continuous porous glass sintered body having high strength.

【0009】[0009]

【発明の実施の形態】次に本願発明の形態を図1に示す
連通多孔質ガラス焼結体の製造工程に基づいて説明す
る。回収したガラスビンのラベル、栓及びキャップ等を
除去し内外を水洗いし、乾燥する。(図示せず)次に、
色別に分類されたガラスビン1を粉砕機2にて粉砕し、
ガラス粒3を得る。次に振動篩4にて篩分けされたガラ
ス粒5を例えば20〜30メッシュのガラス粒100重
量部に対して無機結合材6を3〜8重量部添加し混合機
7にて十分混合し、混合物8を得る。この混合物8を型
9に充填し加圧成形機10にて加圧することにより加圧
成形体11を得る。この加圧成形体11は、型9と共に
乾燥器12にて100〜200℃の温度で加熱乾燥させ
ることにより、固化した成形体13を得る。その後、本
固化した成形体13を型9から取り出し焼成炉14にて
600〜800℃の温度で加熱焼成することにより高強
度で通気性の高い連通多孔質ガラス焼結体15を得る。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, an embodiment of the present invention will be described based on a manufacturing process of a communicating porous glass sintered body shown in FIG. The labels, stoppers, caps, etc. of the collected glass bottles are removed, and the inside and outside are washed with water and dried. (Not shown)
Glass bottles 1 classified by color are crushed by crusher 2,
Glass particles 3 are obtained. Next, 3 to 8 parts by weight of the inorganic binder 6 is added to the glass particles 5 sieved by the vibrating sieve 4 with respect to 100 parts by weight of, for example, 20 to 30 mesh glass particles, and sufficiently mixed by the mixer 7. A mixture 8 is obtained. The mixture 8 is filled in a mold 9 and pressed by a press forming machine 10 to obtain a press-formed body 11. The press-formed body 11 is heated and dried at a temperature of 100 to 200 ° C. in a dryer 12 together with the mold 9 to obtain a solidified formed body 13. Thereafter, the solidified molded body 13 is taken out of the mold 9 and heated and fired at a temperature of 600 to 800 ° C. in a firing furnace 14 to obtain a continuous porous glass sintered body 15 having high strength and high air permeability.

【0010】次に、本発明に係る連通多孔質ガラス焼結
体の製造の実施例を説明する。 実施例1:20〜30メッシュに篩分けたガラス粒10
0重量部に対して比重を35〜40ポーメ度に希釈した
水ガラス5重量部を添加混合し、その混合物を型に充填
後、加圧成形機にて加圧成形した。その成形体を型と共
に100℃にて乾燥後、固化した成形体を型より取り出
し800℃にて加熱焼成した。このようにして製造され
た連結多孔質ガラス焼結体は、カサ比重が1.2〜1.
3g/cm、見掛け気孔率が40%以上、曲げ強度が
50kgf/cm以上であった。
Next, an embodiment of the production of the communicating porous glass sintered body according to the present invention will be described. Example 1: Glass particles 10 sieved to 20-30 mesh
5 parts by weight of water glass diluted to a specific gravity of 35 to 40 pomes with respect to 0 parts by weight was added and mixed. The mixture was filled in a mold, and then subjected to pressure molding by a pressure molding machine. After drying the molded body together with the mold at 100 ° C., the solidified molded body was taken out from the mold and heated and fired at 800 ° C. The coupled porous glass sintered body thus produced has a bulk specific gravity of 1.2 to 1.
3 g / cm 3 , apparent porosity was 40% or more, and flexural strength was 50 kgf / cm 2 or more.

【0011】実施例2:20〜30メッシュに篩分けた
ガラス粒100重量部に対して比重を35〜40ポーメ
ー度に希釈した水ガラス5重量部を200メッシュ以下
に篩分けたガラス粒2重量部を加えスラリーを添加混合
しその混合物を型に充填後、加圧成形機にて加圧成形し
た。その成形体を型と共に100℃乾燥後、固化した成
形体を型より取り出し800℃にて加熱焼成した。この
ようにして製造された連通多孔質ガラス焼結体は、カサ
比重が1.3〜1.4g/cm、見掛け気孔率が35
%以上、曲げ強度が70kgf/cm以上であった。
Example 2: 100 parts by weight of glass particles sieved to 20 to 30 mesh, 5 parts by weight of water glass diluted to a specific gravity of 35 to 40 poem 2 parts by weight of glass particles sieved to 200 mesh or less Then, the slurry was added and mixed, the mixture was filled in a mold, and then subjected to pressure molding by a pressure molding machine. After drying the molded body together with the mold at 100 ° C., the solidified molded body was taken out of the mold and heated and fired at 800 ° C. The communicating porous glass sintered body thus manufactured has a bulk specific gravity of 1.3 to 1.4 g / cm 3 and an apparent porosity of 35.
% Or more, and the bending strength was 70 kgf / cm 2 or more.

【0012】実施例3:100〜200メッシュに篩分
けたガラス粒100重量部に対して比重を35〜40ポ
ーメ度に希釈した水ガラス7重量部を添加混合しその混
合物を型に充填後、加圧成形機にて加圧成形した。その
成形体を型と共に100℃乾燥後、固化した成形体を型
より取り出し700℃にて加熱焼成した。このようにし
て製造された連通多孔質ガラス焼結体は、カサ比重が
1.1〜1.2g/cm、見掛け気孔率が25%以
上、曲げ強度が65kgf/cm以上であった。以上
実施例をガラスビンに説明したが、ガラスビン以外のガ
ラス製品例えばガラス板、他などにも実施出来ることは
もちろんである。
Example 3: 7 parts by weight of water glass diluted to a specific gravity of 35 to 40 pomes were added to 100 parts by weight of glass particles sieved to 100 to 200 mesh, and the mixture was filled in a mold. Pressure molding was performed with a pressure molding machine. After drying the molded body together with the mold at 100 ° C., the solidified molded body was taken out from the mold and heated and fired at 700 ° C. The porous sintered glass sintered body thus manufactured had a bulk specific gravity of 1.1 to 1.2 g / cm 3 , an apparent porosity of 25% or more, and a bending strength of 65 kgf / cm 2 or more. Although the embodiment has been described above with reference to the glass bottle, it goes without saying that the present invention can be applied to glass products other than the glass bottle, for example, a glass plate and the like.

【0013】[0013]

【発明の効果】以上の本願発明によれば連通多孔質ガラ
ス焼結体は、下記のような優れた作用効果を発揮するも
のである。 600〜800℃という低い温度で焼結製造されるガ
ラス又はセラミック系連通多孔質焼結体は、他に商品化
されていない。 水ガラスという取り扱いが簡単で安価な無機結合材を
使用しており、又無機質である為、焼成時に有毒ガスが
発生しない。 ガラス粒の粒度を変えることにより連通多孔質焼結体
の孔径が調整できる。 色別に分類されたガラス粒の1種又は2種以上を混合
することにより他の着色材料を使用することなしに各種
の色を持つ連通多孔質ガラス焼結体が製造できる。 製造工程が非常に簡単である為、廃棄物のリサイクル
品としてコスト的に安〈出来る。又、ガラスに係わる専
門的な知識、技術をほとんど必要としない為、企業化が
容易である。 回収ガラスビンを粉砕したガラス粒のほとんどがリサ
イクルできる。 500〜600℃程度の高温雰囲気にて使用可能であ
り、土木建築用資材としての外壁材、吸音材、透水ブロ
ック材等の他、装置産業に使用部材等に使用する部材例
えばフィルター、吸収板用途が考えられる。 特に、色付きガラスビンのようにビンとして再生出来
ないものの再利用に大いに貢献するものである。
According to the present invention described above, the communicating porous glass sintered body exhibits the following excellent functions and effects. Glass or ceramic continuous porous sintered bodies produced by sintering at a low temperature of 600 to 800 ° C. have not been commercialized. It uses water glass, an inorganic binder that is easy and inexpensive to handle, and because it is inorganic, no toxic gas is generated during firing. The pore size of the communicating porous sintered body can be adjusted by changing the particle size of the glass particles. By mixing one or more of the glass particles classified by color, a continuous porous glass sintered body having various colors can be produced without using other coloring materials. Since the manufacturing process is very simple, it can be reduced in cost as a recycled product of waste. Moreover, since it requires little technical knowledge and technology related to glass, it is easy to commercialize. Most of the glass particles obtained by crushing the recovered glass bottle can be recycled. It can be used in a high-temperature atmosphere of about 500 to 600 ° C, and is used as a material for civil engineering and construction, in addition to an outer wall material, a sound absorbing material, a water-permeable block material, etc. Can be considered. In particular, it greatly contributes to recycling of glass bottles that cannot be regenerated as bottles.

【0014】[0014]

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明実施の形態の連通多孔質ガラス焼結体の
製造工程
FIG. 1 is a manufacturing process of a communicating porous glass sintered body according to an embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1:回収ガラスビン 2:粉砕機 3:粉砕ガラス粒 4:振動篩 5:篩分けされたガラス粒 6:無機結合材 7:混合機 8:混合物 9:型 10:加圧成形機 11:加圧成形体 12:乾燥器 13:固化した成形体 14:焼成炉 15:連結多孔質ガラス焼結体 1: recovered glass bottle 2: crusher 3: crushed glass particle 4: vibrating sieve 5: sieved glass particle 6: inorganic binder 7: mixer 8: mixture 9: mold 10: pressing machine 11: pressing Molded body 12: Dryer 13: Solidified molded body 14: Firing furnace 15: Sintered porous glass sintered body

─────────────────────────────────────────────────────
────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成10年9月26日(1998.9.2
6)
[Submission Date] September 26, 1998 (1998.9.2)
6)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】全文[Correction target item name] Full text

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【書類名】 明細書[Document Name] Statement

【発明の名称】 連通多孔質ガラス焼結体及びその製造
方法
Patent application title: Sintered porous glass sintered body and method for producing the same

【特許請求の範囲】[Claims]

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【産業上の利用分野】本願発明は、一般廃棄物である回
収ガラス製品を粉砕し粒状化したものを主原料とする連
通多孔質ガラス焼結体に関するものであり、資源の有効
利用を目的とした連通多孔質ガラス焼結体及びその製造
方法に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a continuous porous glass sintered body whose main raw material is obtained by crushing and granulating recovered glass products as general waste. And a method for producing the same.

【0002】[0002]

【従来の技術及び発明が解決しようとする課題】回収ガ
ラス製品のうち色付きガラス製品は、再生が困難であ
り、その有効利用策が回収処理機関等で要望されてい
た。
2. Description of the Related Art Colored glass products among recovered glass products are difficult to regenerate, and there has been a demand for effective use of such products by recovery processing organizations.

【0003】[0003]

【課題を解決するための手段】本発明者は、上記課題を
解決すべく鋭意研究を行なった結果、回収ガラスビンを
粉砕し篩分した粉砕粒を得て見掛け気孔率25〜40
%、カサ比重1.0〜1.3、曲げ強度50〜100k
gf/cmの物性を有す連通多孔質ガラス焼結体を製
造することに成功した。
Means for Solving the Problems The inventor of the present invention has made intensive studies to solve the above-mentioned problems, and as a result, obtained a crushed recovered glass bottle and obtained sieved particles to obtain an apparent porosity of 25 to 40.
%, Bulk specific gravity 1.0-1.3, bending strength 50-100k
It succeeded in producing a continuous porous glass sintered body having physical properties of gf / cm 2 .

【0004】すなわち、本願発明は以下のものである。 (1)素材が、回収ガラス製品粉砕粒の焼結体よりなる
ことを特徴とする連通多孔質ガラス焼結体。 (2)回収ガラス製品粉砕粒が、無機結合材を介して焼
結されてなることを特徴とする連通多孔質ガラス焼結
体。 (3)回収ガラス製品粉砕粒100重量部に対して無機
結合材3〜8重量部を添加混合し、焼結されてなること
を特徴とする連通多孔質ガラス焼結体。 (4)連通多孔質ガラス焼結体の物性値が、見掛け気孔
率25〜40%、カサ比重1.0〜1.3、曲げ強度5
0〜100kgf/cmであることを特徴とする請求
項1ないし3のいずれかに記載の連通多孔質ガラス焼結
体。
That is, the present invention is as follows. (1) A communicating porous glass sintered body characterized in that the material is made of a sintered body of ground particles of recovered glass products. (2) A communicating porous glass sintered body, wherein the ground particles of the recovered glass product are sintered via an inorganic binder. (3) A communicating porous glass sintered body characterized in that 3 to 8 parts by weight of an inorganic binder is added to 100 parts by weight of the crushed particles of the recovered glass product, mixed and sintered. (4) The physical properties of the communicating porous glass sintered body are apparent porosity 25-40%, bulk specific gravity 1.0-1.3, and bending strength 5
0~100kgf / cm claims 1, characterized in that 2 is to communicate porous glass sintered body according to any one of 3.

【0005】(5)回収ガラス製品粉砕粒に無機結合材
を添加混合し、それを型に充填し、加圧成形後型内にて
乾燥した後取り出し、600〜800℃で焼成すること
を特徴とする連通多孔質ガラス焼結体の製造方法。 (6)回収ガラス製品粉砕粒100重量部に対して無機
結合材3〜8重量部を添加混合し、それを型に充填し加
圧成形後型内にて乾燥した後取り出し、600〜800
℃で焼成することを特徴とする連通多孔質ガラス焼結体
の製造方法。 (7)回収ガラス製品粉砕粒の粒度が、8〜200メッ
シュであることを特徴とする請求項5又は6記載の連通
多孔質ガラス焼結体の製造方法。 (8)無機結合材が水ガラスであることを特徴とする請
求項5又は6記載の連通多孔質ガラス焼結体の製造方
法。 (9)無機結合材が水ガラス100重量部に対して回収
ガラス製品粉砕粒200メッシュ以下のもの100〜1
50重量部を添加混合したスラリー状液体からなること
を特徴とする請求項5又は6記載の連通多孔質ガラス焼
結体の製造方法。 (10)回収ガラス製品粉砕粒が、例えば8〜20メッ
シュ、20〜30メッシュ等に区分され、それを1区分
又は2区分以上混合あるいは積層したものであることを
特徴とする請求項5又は6記載の連通多孔質ガラス焼結
体の製造方法。 (11)回収ガラス製品粉砕粒が、色毎に分別され、そ
れを1種類又は2種類以上混合したものであることを特
徴とする請求項10記載の連通多孔質ガラス焼結体の製
造方法。
(5) An inorganic binder is added to the crushed particles of the recovered glass product, mixed, filled in a mold, dried in a mold after pressure molding, taken out, and fired at 600 to 800 ° C. A method for producing a communicating porous glass sintered body. (6) 3 to 8 parts by weight of an inorganic binder is added to and mixed with 100 parts by weight of the crushed particles of the recovered glass product, and the mixture is filled in a mold, pressed, dried in a mold, and taken out.
A method for producing a communicating porous glass sintered body, characterized by firing at a temperature of ℃. (7) The method for producing a communicating porous glass sintered body according to claim 5 or 6, wherein the particle size of the ground particles of the recovered glass product is 8 to 200 mesh. (8) The method according to claim 5 or 6, wherein the inorganic binder is water glass. (9) 100 to 100 parts by weight of the inorganic glass binder is 200 mesh or less of the recovered glass product pulverized particles per 100 parts by weight of water glass
The method for producing a continuous porous glass sintered body according to claim 5, comprising a slurry-like liquid to which 50 parts by weight is added and mixed. (10) The recovered glass product pulverized particles are divided into, for example, 8 to 20 mesh, 20 to 30 mesh, or the like, and one or more sections are mixed or laminated. A method for producing the communicating porous glass sintered body according to the above. (11) The method for producing a continuous porous glass sintered body according to (10), wherein the pulverized particles of the recovered glass product are separated for each color, and one kind or a mixture of two or more kinds is obtained.

【0006】上記本願発明で、主原料として使用される
ガラス粒は、一般廃棄物である回収ガラス製品を粉砕し
たものである。特に色付きビンのようにビンとして再生
出来ないものは回収処理機関等に於いてその再利用が大
きな課題となっているが、本願発明により大いに活路が
開かれるものである。
In the present invention, the glass particles used as a main raw material are obtained by pulverizing recovered glass products, which are general waste. In particular, those that cannot be recycled as bins, such as colored bottles, have a great problem of being reused in collection and disposal facilities and the like.

【0007】粉砕し篩分けたガラス粒は、無機結合材を
介して点接触状態で焼結される為、連通多孔質となるも
のであり、ガラス粒の粒度を変えることによりその開孔
径が調整できるものである。さらに、無機結合材として
水ガラスを使用する為、取り扱いが簡単でコスト的にも
安価である。又焼成時に有害ガスが発生しない。
[0007] The crushed and sieved glass particles are sintered in a point contact state via an inorganic binder, so that they become porous, and the opening diameter is adjusted by changing the particle size of the glass particles. You can do it. Further, since water glass is used as the inorganic binder, the handling is simple and the cost is low. No harmful gas is generated during firing.

【0008】本願発明に於いては、水ガラス中に200
メッシュ以下のガラス粒を混合しスラリー状としたもの
を無機結合材として使用することに依り、回収ガラス製
品の粉砕物ほとんどが再利用可能となる。又焼結に依る
結合力が高められ高強度を有す連通多孔質ガラス焼結体
の製造が可能となる。
[0008] In the present invention, 200 in water glass
By using a slurry obtained by mixing glass particles having a size equal to or smaller than the mesh as an inorganic binder, most of the crushed collected glass products can be reused. In addition, the bonding force due to sintering is increased, and it is possible to manufacture a continuous porous glass sintered body having high strength.

【0009】[0009]

【発明の実施の形態】次に、本願発明の形態を図1に示
す連通多孔質ガラス焼結体の製造工程に基づいて説明す
る。回収したガラスビンのラベル、栓及びキャップ等を
除去し内外を水洗いし、乾燥する。(図示せず。)次
に、色別に分類されたガラスビン1を粉砕機2にて粉砕
し、ガラス粒3を得る。次に振動篩4にて篩分けされた
ガラス粒5を例えば20〜30メッシュのガラス粒10
0重量部に対して無機結合材6を3〜8重量部添加し混
合機7にて十分混合し、混合物8を得る。この混合物8
を型9に充填し加圧成形機10にて加圧することにより
加圧成形体11を得る。この加圧成形体11は、型9と
共に乾燥器12にて100〜200℃の温度で加熱乾燥
させることにより、固化した成形体13を得る。その
後、本固化した成形体13を型9から取り出し焼成炉1
4にて600〜800℃の温度で加熱焼成することによ
り高強度で通気性の高い連通多孔質ガラス焼結体15を
得る。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, an embodiment of the present invention will be described based on a manufacturing process of a communicating porous glass sintered body shown in FIG. The labels, stoppers, caps, etc. of the collected glass bottles are removed, and the inside and outside are washed with water and dried. (Not shown) Next, the glass bottles 1 classified by color are pulverized by a pulverizer 2 to obtain glass particles 3. Next, the glass particles 5 sieved by the vibrating sieve 4 are replaced with glass particles 10 of, for example, 20 to 30 mesh.
A mixture 8 is obtained by adding 3 to 8 parts by weight of the inorganic binder 6 to 0 parts by weight and sufficiently mixing with the mixer 7. This mixture 8
Into a mold 9 and pressurized by a press forming machine 10 to obtain a press-formed body 11. The press-formed body 11 is heated and dried at a temperature of 100 to 200 ° C. in a dryer 12 together with the mold 9 to obtain a solidified formed body 13. Then, the solidified compact 13 is taken out of the mold 9 and the firing furnace 1
By heating and baking at a temperature of 600 to 800 ° C. in step 4, a continuous porous glass sintered body 15 having high strength and high air permeability is obtained.

【0010】次に、本発明に係る連通多孔質ガラス焼結
体の製造の実施例を説明する。 実施例1:20〜30メッシュに篩分けたガラス粒10
0重量部に対して比重を35〜40ボーメ度に希釈した
水ガラス5重量部を添加混合し、その混合物を型に充填
後、加圧成形機にて5kgf/cmで加圧成形した。
その成形体を型と共に100℃にて乾燥後、固化した成
形体を型より取り出し800℃にて加熱焼成した。この
ようにして製造された連通多孔質ガラス焼結体は、カサ
比重が1.1〜1.2、見掛け気孔率が40%以上、曲
げ強度が50kgf/cm以上であった。
Next, an embodiment of the production of the communicating porous glass sintered body according to the present invention will be described. Example 1: Glass particles 10 sieved to 20-30 mesh
5 parts by weight of water glass whose specific gravity was diluted to 35 to 40 Baume degrees with respect to 0 parts by weight was added and mixed. After filling the mixture into a mold, the mixture was pressure-formed at 5 kgf / cm 2 by a pressure-forming machine.
After drying the molded body together with the mold at 100 ° C., the solidified molded body was taken out from the mold and heated and fired at 800 ° C. The communicating porous glass sintered body thus manufactured had a bulk specific gravity of 1.1 to 1.2, an apparent porosity of 40% or more, and a bending strength of 50 kgf / cm 2 or more.

【0011】実施例2:20〜30メッシュに篩分けた
ガラス粒100重量部に対して比重を35〜40ボーメ
度に希釈した水ガラス5重量部に200メッシュ以下に
篩分けたガラス粒5重量部を加えスラリー状としたもの
を添加混合し、その混合物を型に充填後、加圧成形機に
て5kgf/cmで加圧成形した。その成形体を型と
共に100℃にて乾燥後、固化した成形体を型より取り
出し800℃にて加熱焼成した。このようにして製造さ
れた連通多孔質ガラス焼結体は、カサ比重が1.1〜
1.2、見掛け気孔率が35%以上、曲げ強度が70k
gf/cm以上であった。
Example 2: 5 parts by weight of glass particles sieved to 200 mesh or less in 5 parts by weight of water glass diluted to a specific gravity of 35 to 40 Baume per 100 parts by weight of glass particles sieved to 20 to 30 mesh Then, a slurry was added and mixed, and the mixture was filled in a mold, followed by pressure molding with a pressure molding machine at 5 kgf / cm 2 . After drying the molded body together with the mold at 100 ° C., the solidified molded body was taken out from the mold and heated and fired at 800 ° C. The sintered porous glass sintered body thus manufactured has a bulk specific gravity of 1.1 to 1.1.
1.2, apparent porosity is 35% or more, bending strength is 70k
gf / cm 2 or more.

【0012】実施例3 100〜200メッシュに篩分けたガラス粒100重量
部に対して比重を35〜40ボーメ度に希釈した水ガラ
ス7重量部を添加混合し、その混合物を型に充填後、加
圧成形機にて10kgf/cmで加圧成形した。その
成形体を型と共に100℃にて乾燥後、固化した成形体
を型より取り出し700℃にて加熱焼成した。このよう
にして製造された連通多孔質ガラス焼結体は、カサ比重
が1.2〜1.3、見掛け気孔率が25%以上、曲げ強
度が80kgf/cm以上であった。
Example 3 7 parts by weight of water glass diluted to a specific gravity of 35 to 40 Baume were added to 100 parts by weight of glass particles sieved to 100 to 200 mesh, and the mixture was filled in a mold. Pressure molding was performed with a pressure molding machine at 10 kgf / cm 2 . After drying the molded body together with the mold at 100 ° C, the solidified molded body was taken out of the mold and heated and fired at 700 ° C. The porous sintered glass sintered body thus produced had a bulk specific gravity of 1.2 to 1.3, an apparent porosity of 25% or more, and a bending strength of 80 kgf / cm 2 or more.

【0013】[0013]

【発明の効果】以上の本願発明によれば連通多孔質ガラ
ス焼結体は、下記のような優れた作用効果を発揮するも
のである。 600〜800℃という低い温度で焼結製造されるガ
ラス又はセラミック系連通多孔質焼結体は、他に商品化
されていない。 水ガラスという取り扱いが簡単で安価な無機結合材を
使用しており、又無機質である為、焼成時に有害ガスが
発生しない。 ガラス粒の粒度を変えることにより連通多孔質焼結体
の孔径が調整できる。 色別に分類されたガラス粒の1種又は2種以上を混合
することにより他の着色材料を使用することなしに各種
の色を持つ連通多孔質ガラス焼結体が製造できる。 製造工程が非常に簡単である為、廃棄物のリサイクル
品としてコスト的に安く出来る。又、ガラスに係わる専
門的な知識、技術をほとんど必要としない為、企業化が
容易である。 回収ガラス製品を粉砕したガラス粒のほとんどがリサ
イクルできる。 500〜600℃程度の高温雰囲気にて使用可能であ
り、土木建築用資材としての外壁材、吸音材、透水ブロ
ック材等の他、装置産業に使用される部材例えばフィル
ター、吸収板等の用途が考えられる。 特に、色付きガラスビンのようにビンとして再生出来
ないものの再利用に大いに貢献するものである。
According to the present invention described above, the communicating porous glass sintered body exhibits the following excellent functions and effects. Glass or ceramic continuous porous sintered bodies produced by sintering at a low temperature of 600 to 800 ° C. have not been commercialized. It uses water glass, an inorganic binder that is easy and inexpensive to handle, and because it is inorganic, no harmful gas is generated during firing. The pore size of the communicating porous sintered body can be adjusted by changing the particle size of the glass particles. By mixing one or more of the glass particles classified by color, a continuous porous glass sintered body having various colors can be produced without using other coloring materials. Since the manufacturing process is very simple, the cost can be reduced as a recycled product of waste. Moreover, since it requires little technical knowledge and technology related to glass, it is easy to commercialize. Most of the glass particles obtained by grinding the recovered glass products can be recycled. It can be used in a high-temperature atmosphere of about 500 to 600 ° C., and is used for materials such as outer wall materials, sound absorbing materials, and water-permeable block materials as civil engineering and building materials, as well as members used in the equipment industry, such as filters and absorption plates. Conceivable. In particular, it greatly contributes to recycling of glass bottles that cannot be regenerated as bottles.

【0014】[0014]

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明実施の形態の連通多孔質ガラス焼結体の
製造工程
FIG. 1 is a manufacturing process of a communicating porous glass sintered body according to an embodiment of the present invention.

【符号の説明】 1:回収ガラスビン 2:粉砕機 3:粉砕ガラス粒 4:振動篩 5:篩分けされたガラス粒 6:無機結合材 7:混合機 8:混合物 9:型 10:加圧成形機 11:加圧成形体 12:乾燥器 13:固化した成形体 14:焼成炉 15:連通多孔質ガラス焼結体[Explanation of Signs] 1: Recovered glass bottle 2: crusher 3: crushed glass particle 4: vibrating screen 5: sieved glass particle 6: inorganic binder 7: mixer 8: mixture 9: mold 10: pressure molding Machine 11: Press molded body 12: Dryer 13: Solidified molded body 14: Firing furnace 15: Sintered porous glass sintered body

【手続補正3】[Procedure amendment 3]

【補正対象書類名】図面[Document name to be amended] Drawing

【補正対象項目名】全図[Correction target item name] All figures

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【図1】 ─────────────────────────────────────────────────────
FIG. ────────────────────────────────────────────────── ───

【手続補正書】[Procedure amendment]

【提出日】平成10年11月6日(1998.11.
6)
[Submission date] November 6, 1998 (1998.11.
6)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】請求項12[Correction target item name] Claim 12

【補正方法】誓誓[Correction method] Oath

【補正内容】[Correction contents]

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0005[Correction target item name] 0005

【補正方法】誓誓[Correction method] Oath

【補正内容】[Correction contents]

【0005】(12)無機結合材が水ガラス100重量
部に対して粘土例えばカオリナイト、ハロイサイト等を
20〜40重量部を添加混合したスラリー状液体からな
ることを特徴とする請求項5又は6記載の連通多孔質ガ
ラス焼結体の製造方法。
(12) The inorganic binder comprises a slurry liquid obtained by adding and mixing 20 to 40 parts by weight of clay such as kaolinite, halloysite or the like to 100 parts by weight of water glass. A method for producing the communicating porous glass sintered body according to the above.

【手続補正書】[Procedure amendment]

【提出日】平成11年3月2日(1999.3.2)[Submission date] March 2, 1999 (1999.3.2)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】特許請求の範囲[Correction target item name] Claims

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【特許請求の範囲】[Claims]

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0005[Correction target item name] 0005

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0005】(5)回収ガラス製品粉砕粒に無機結合材
を添加混合し、それを型に充填し、加圧成形後型内にて
乾燥した後取り出し、600〜800℃で焼成すること
を特徴とする連通多孔質ガラス焼結体の製造方法。 (6)回収ガラス製品粉砕粒100重量部に対して無機
結合材3〜8重量部を添加混合し、それを型に充填し加
圧成形後型内にて乾燥した後取り出し、600〜800
℃で焼成することを特徴とする連通多孔質ガラス焼結体
の製造方法。 (7)回収ガラス製品粉砕粒の粒度が、8〜200メッ
シュであることを特徴とする請求項5又は6記載の連通
多孔質ガラス焼結体の製造方法。 (8)無機結合材が水ガラスであることを特徴とする請
求項5又は6記載の連通多孔質ガラス焼結体の製造方
法。 (9)無機結合材が水ガラス100重量部に対して回収
ガラス製品粉砕粒200メッシュ以下のもの100〜1
50重量部を添加混合したスラリー状液体からなること
を特徴とする請求項5又は6記載のの連通多孔質ガラス
焼結体の製造方法。 (10)回収ガラス製品粉砕粒が、例えば8〜20メッ
シュ、20〜30メッシュ等に区分され、それを1区分
又は2区分以上混合あるいは積層したものであることを
特徴とする請求項5又は6記載の連通多孔質ガラス焼結
体の製造方法。 (11)回収ガラス製品粉砕粒が、色毎に分別され、そ
れを1種類又は2種類以上混合したものであることを特
徴とする請求項10記載の連通多孔質ガラス焼結体の製
造方法。 (12)無機結合材が水ガラス100重量部に対して粘
土例えばカオリナイト、ハロイサイト等を20〜40重
量部を添加混合したスラリー状液体からなることを特徴
とする請求項5又は6記載の連通多孔質ガラス焼結体の
製造方法。
(5) An inorganic binder is added to the crushed particles of the recovered glass product, mixed, filled in a mold, dried in a mold after pressure molding, taken out, and fired at 600 to 800 ° C. A method for producing a communicating porous glass sintered body. (6) 3 to 8 parts by weight of an inorganic binder is added to and mixed with 100 parts by weight of the crushed particles of the recovered glass product, and the mixture is filled in a mold, pressed, dried in a mold, and taken out.
A method for producing a communicating porous glass sintered body, characterized by firing at a temperature of ℃. (7) The method for producing a communicating porous glass sintered body according to claim 5 or 6, wherein the particle size of the ground particles of the recovered glass product is 8 to 200 mesh. (8) The method according to claim 5 or 6, wherein the inorganic binder is water glass. (9) 100 to 100 parts by weight of the inorganic glass binder is 200 mesh or less of the recovered glass product pulverized particles per 100 parts by weight of water glass
7. The method for producing a communicating porous glass sintered body according to claim 5, wherein the method comprises a slurry-like liquid to which 50 parts by weight is added and mixed. (10) The recovered glass product pulverized particles are divided into, for example, 8 to 20 mesh, 20 to 30 mesh, or the like, and one or more sections are mixed or laminated. A method for producing the communicating porous glass sintered body according to the above. (11) The method for producing a continuous porous glass sintered body according to (10), wherein the pulverized particles of the recovered glass product are separated for each color, and one kind or a mixture of two or more kinds is obtained. (12) The communication according to (5) or (6), wherein the inorganic binder is a slurry liquid obtained by adding and mixing 20 to 40 parts by weight of clay such as kaolinite, halloysite or the like with respect to 100 parts by weight of water glass. A method for producing a porous glass sintered body.

【手続補正書】[Procedure amendment]

【提出日】平成11年5月14日(1999.5.1
4)
[Submission date] May 14, 1999 (1999.5.1
4)

【手続補正1】[Procedure amendment 1]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】特許請求の範囲[Correction target item name] Claims

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【特許請求の範囲】[Claims]

【手続補正2】[Procedure amendment 2]

【補正対象書類名】明細書[Document name to be amended] Statement

【補正対象項目名】0005[Correction target item name] 0005

【補正方法】変更[Correction method] Change

【補正内容】[Correction contents]

【0005】(5)回収ガラス製品粉砕粒に無機結合材
を添加混合し、それを型に充填し、加圧成形後型内にて
乾燥した後取り出し、600〜800℃で焼成すること
を特徴とする連通多孔質ガラス焼結体の製造方法。 (6)回収ガラス製品粉砕粒100重量部に対して無機
結合材3〜8重量部を添加混合し、それを型に充填し加
圧成形後型内にて乾燥した後取り出し、600〜800
℃で焼成することを特徴とする連通多孔質ガラス焼結体
の製造方法。 (7)回収ガラス製品粉砕粒の粒度が、8〜200メッ
シュであることを特徴とする請求項5又は6記載の連通
多孔質ガラス焼結体の製造方法。 (8)無機結合材が水ガラスであることを特徴とする請
求項5又は6記載の連通多孔質ガラス焼結体の製造方
法。 (9)無機結合材が水ガラス100重量部に対して回収
ガラス製品粉砕粒200メッシュ以下のもの100〜1
50重量部を添加混合したスラリー状液体からなること
を特徴とする請求項5又は6記載のの連通多孔質ガラス
焼結体の製造方法。 (10)回収ガラス製品粉砕粒が、例えば8〜20メッ
シュ、20〜30メッシュ等に区分され、それを1区分
又は2区分以上混合あるいは積層したものであることを
特徴とする請求項5又は6記載の連通多孔質ガラス焼結
体の製造方法。 (11)回収ガラス製品粉砕粒が、色毎に分別され、そ
れを1種類又は2種類以上混合したものであることを特
徴とする請求項10記載の連通多孔質ガラス焼結体の製
造方法。 (12)無機結合材が水ガラス100重量部に対して粘
土例えばカオリナイト、ハロイサイト等を20〜40重
量部を添加混合したスラリー状液体からなることを特徴
とする請求項5又は6記載の連通多孔質ガラス焼結体の
製造方法。 (13)無機結合材が水ガラス100重量部に対して非
晶質シリカ微粉末を10〜20重量部添加混合したスラ
リー状液体からなることを特徴とする請求項5又は6記
載の連通多孔質ガラス焼結体の製造方法。 (14)無機結合材が水ガラス100重量部に対して鉱
炉スラグ微粉末を30〜80重量部添加混合したスラリ
ー状液体からなることを特徴とする請求項5又は6記載
の連通多孔質ガラス焼結体の製造方法。
(5) An inorganic binder is added to the crushed particles of the recovered glass product, mixed, filled in a mold, dried in a mold after pressure molding, taken out, and fired at 600 to 800 ° C. A method for producing a communicating porous glass sintered body. (6) 3 to 8 parts by weight of an inorganic binder is added to and mixed with 100 parts by weight of the crushed particles of the recovered glass product, and the mixture is filled in a mold, pressed, dried in a mold, and taken out.
A method for producing a communicating porous glass sintered body, characterized by firing at a temperature of ℃. (7) The method for producing a communicating porous glass sintered body according to claim 5 or 6, wherein the particle size of the ground particles of the recovered glass product is 8 to 200 mesh. (8) The method according to claim 5 or 6, wherein the inorganic binder is water glass. (9) 100 to 100 parts by weight of the inorganic glass binder is 200 mesh or less of the recovered glass product pulverized particles per 100 parts by weight of water glass.
7. The method for producing a communicating porous glass sintered body according to claim 5, wherein the method comprises a slurry-like liquid to which 50 parts by weight is added and mixed. (10) The recovered glass product crushed particles are divided into, for example, 8 to 20 mesh, 20 to 30 mesh, and the like, and one or two or more sections are mixed or laminated. A method for producing the communicating porous glass sintered body according to the above. (11) The method for producing a continuous porous glass sintered body according to claim 10, wherein the recovered glass product crushed particles are separated for each color and are one kind or a mixture of two or more kinds. (12) The communication according to (5) or (6), wherein the inorganic binder is a slurry liquid obtained by adding and mixing 20 to 40 parts by weight of clay such as kaolinite, halloysite or the like with respect to 100 parts by weight of water glass. A method for producing a porous glass sintered body. (13) The communicating porous material according to (5) or (6), wherein the inorganic binder is a slurry-like liquid in which 10 to 20 parts by weight of amorphous silica fine powder is added to and mixed with 100 parts by weight of water glass. A method for manufacturing a glass sintered body. (14) The communicating porous glass according to (5) or (6), wherein the inorganic binder is a slurry-like liquid obtained by adding and mixing 30 to 80 parts by weight of a fine furnace slag powder with respect to 100 parts by weight of water glass. A method for manufacturing a sintered body.

Claims (11)

【特許請求の範囲】[Claims] 【請求項1】素材が、回収ガラス製品粉砕粒の焼結体よ
りなることを特徴とする連通多孔質ガラス焼結体。
1. A communicating porous glass sintered body characterized in that the raw material is a sintered body of ground particles of recovered glass products.
【請求項2】回収ガラス製品粉砕粒が、無機結合材を介
して焼結されてなることを特徴とする連通多孔質ガラス
焼結体。
2. A communicating porous glass sintered body characterized in that ground particles of recovered glass product are sintered via an inorganic binder.
【請求項3】回収ガラス製品粉砕粒100重量部に対し
て無機結合材3〜8重量部を添加混合し、焼結されてな
ることを特徴とする連通多孔質ガラス焼結体。
3. A continuous porous glass sintered body characterized in that 3 to 8 parts by weight of an inorganic binder is added to 100 parts by weight of the crushed particles of the recovered glass product, mixed and sintered.
【請求項4】連通多孔質ガラス焼結体の物性値が、見掛
け気孔率30〜40%、カサ比重1.0〜1.3、曲げ
強度50〜100kgf/cmであることを特徴とす
る請求項1ないし3のいずれかに記載の連通多孔質ガラ
ス焼結体。
4. The physical properties of the sintered porous glass have an apparent porosity of 30 to 40%, a bulk specific gravity of 1.0 to 1.3, and a bending strength of 50 to 100 kgf / cm 2. The communicating porous glass sintered body according to claim 1.
【請求項5】回収ガラス製品粉砕粒に結合材を添加混合
し、それを型に充填し、加圧成形後型内にて乾燥した後
取り出し、600〜800℃で焼成することを特徴とす
る連通多孔質ガラス焼結体の製造方法。
5. A method in which a binder is added to the crushed particles of the recovered glass product, mixed, filled in a mold, dried in a mold after pressure molding, taken out, and fired at 600 to 800 ° C. A method for producing a communicating porous glass sintered body.
【請求項6】回収ガラス製品粉砕粒100重量部に対し
て無機結合材3〜8重量部を添加混合し、それを型に充
填し5〜20kgf/cmで加圧成形後型内て乾燥し
た後取り出し600〜800℃で焼成することを特徴と
する連通多孔質ガラス焼結体の製造方法。
6. Addition and mixing of 3 to 8 parts by weight of an inorganic binder with respect to 100 parts by weight of the crushed particles of the recovered glass product, filling the mixture into a mold, press-molding at 5 to 20 kgf / cm 2 and drying in the mold And then firing at 600 to 800 ° C.
【請求項7】回収ガラス製品粉砕粒の粒度が8〜200
メッシュであることを特徴とする請求項5又は6記載の
連通多孔質ガラス焼結体の製造方法。
7. The recovered glass product has a particle size of from 8 to 200.
The method for producing a communicating porous glass sintered body according to claim 5, wherein the method is a mesh.
【請求項8】無機結合材が水ガラスであることを特徴と
する請求項5又は6記載の連通多孔質ガラス焼結体の製
造方法。
8. The method for producing a communicating porous glass sintered body according to claim 5, wherein the inorganic binder is water glass.
【請求項9】無機結合材が水ガラス100重量部に対し
て回収ガラス製品粉砕粒200メッシュ以下のもの10
0〜150重量部を添加混合したスラリー状液体からな
ることを特徴とする請求項5又は6記載の連通多孔質ガ
ラス焼結体の製造方法。
9. A method wherein the inorganic binder is not more than 200 mesh of crushed particles of recovered glass product per 100 parts by weight of water glass.
The method for producing a communicating porous glass sintered body according to claim 5, comprising a slurry-like liquid to which 0 to 150 parts by weight is added and mixed.
【請求項10】回収ガラス製品粉砕粒が例えば8〜20
メッシュ、20〜30メッシュ等に区分され、それを1
区分又は2区分以上混合したものであることを特徴とす
る請求項5又は、6記載の連通多孔質ガラス焼結体の製
造方法。
10. The recovered glass product crushed particles are, for example, from 8 to 20.
Mesh, 20-30 mesh, etc.
The method for producing a continuous porous glass sintered body according to claim 5 or 6, wherein the porous glass sintered body is a section or a mixture of two or more sections.
【請求項11】回収ガラス製品粉砕粒が、色毎に分別さ
れ、それを1種類又は2種類以上混合したものであるこ
とを特徴とする請求項10記載の連通多孔質ガラス焼結
体の製造方法。
11. The production of a continuous porous glass sintered body according to claim 10, wherein the crushed particles of the recovered glass product are separated for each color and are one kind or a mixture of two or more kinds. Method.
JP10297519A 1998-09-10 1998-09-10 Open pore type porous glass sintered body and its production Pending JP2000086256A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10297519A JP2000086256A (en) 1998-09-10 1998-09-10 Open pore type porous glass sintered body and its production

Publications (1)

Publication Number Publication Date
JP2000086256A true JP2000086256A (en) 2000-03-28

Family

ID=17847582

Family Applications (1)

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Country Status (1)

Country Link
JP (1) JP2000086256A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003074437A1 (en) * 2002-03-06 2003-09-12 Be Inc. Porous glass moldings and method for production thereof
CN106986526A (en) * 2017-05-23 2017-07-28 商洛学院 A kind of glass water-permeable brick and preparation method thereof
WO2018127696A1 (en) * 2017-01-05 2018-07-12 Gent Tim A glass briquette and forming system
CN108640485A (en) * 2018-04-18 2018-10-12 南京卡佛科学仪器有限公司 A kind of production method of porous glass plate for gas absorption tube
GB2565261A (en) * 2017-01-05 2019-02-13 Gent Tim A glass Briquette forming system
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003074437A1 (en) * 2002-03-06 2003-09-12 Be Inc. Porous glass moldings and method for production thereof
CN1294093C (en) * 2002-03-06 2007-01-10 Be株式会社 Porous glass moldings and method for production thereof
KR100812576B1 (en) * 2002-03-06 2008-03-13 가부시키가이샤 비 Porous glass moldings and method for production thereof
WO2018127696A1 (en) * 2017-01-05 2018-07-12 Gent Tim A glass briquette and forming system
GB2565261A (en) * 2017-01-05 2019-02-13 Gent Tim A glass Briquette forming system
GB2565261B (en) * 2017-01-05 2021-05-19 Gent Tim A glass Briquette forming system
CN106986526A (en) * 2017-05-23 2017-07-28 商洛学院 A kind of glass water-permeable brick and preparation method thereof
CN108640485A (en) * 2018-04-18 2018-10-12 南京卡佛科学仪器有限公司 A kind of production method of porous glass plate for gas absorption tube
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