CN106986526A - A kind of glass water-permeable brick and preparation method thereof - Google Patents

A kind of glass water-permeable brick and preparation method thereof Download PDF

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Publication number
CN106986526A
CN106986526A CN201710366633.8A CN201710366633A CN106986526A CN 106986526 A CN106986526 A CN 106986526A CN 201710366633 A CN201710366633 A CN 201710366633A CN 106986526 A CN106986526 A CN 106986526A
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CN
China
Prior art keywords
glass
brick
permeable brick
water
particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710366633.8A
Other languages
Chinese (zh)
Inventor
王之宇
郭家林
冉卓
刘璇
南宁
刘明宝
赵威
魏威
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Shangluo University
Original Assignee
Shangluo University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shangluo University filed Critical Shangluo University
Priority to CN201710366633.8A priority Critical patent/CN106986526A/en
Publication of CN106986526A publication Critical patent/CN106986526A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/06Other methods of shaping glass by sintering, e.g. by cold isostatic pressing of powders and subsequent sintering, by hot pressing of powders, by sintering slurries or dispersions not undergoing a liquid phase reaction
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C11/00Multi-cellular glass ; Porous or hollow glass or glass particles
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C15/00Pavings specially adapted for footpaths, sidewalks or cycle tracks

Abstract

The present invention provides a kind of glass water-permeable brick, component meter by weight, the glass water-permeable brick includes 100 parts of glass particle, the particle diameter of the glass particle is 0.08~15mm, it is mutually cementing between the glass particle, adjacent glass particle is staggered to form hole, is mutually communicated and is uniformly distributed between the hole.Present invention also offers a kind of preparation method of the glass water-permeable brick, comprise the following steps:Glassware is crushed, glass particle is obtained;Glass particle is laid on fireproof die;Fireproof die is placed in heating furnace and is heated to certain temperature, is incubated, then cools down;Fireproof die is removed, glass water-permeable brick is obtained.The preparation method simple production process that the present invention is provided, firing temperature is low, and energy consumption is small, cost is low;The compression strength of the water-permeable brick obtained using the present invention is 25~50MPa, and coefficient of permeability is 1.2~10mm/s;The present invention can effectively improve the cyclic utilization rate of discarded glass.

Description

A kind of glass water-permeable brick and preparation method thereof
Technical field
The present invention relates to water-permeable brick technical field, more particularly to a kind of glass water-permeable brick and preparation method thereof.
Background technology
A large amount of scrap glasses can be all produced in industrial production and daily life, because intractability is big, recovery utilization rate is low, Cullet volume of cargo in storage is also being continuously increased.By taking beer bottle as an example, due to the decline of vial production cost, it is ready that recycling is old The beer producer of vial is fewer and fewer, causes a large amount of old reluctant situations of beer bottle, burden is brought to environment.In State patent CN200610159648.9 discloses a kind of method of utilization cullet low-firing crystallizing glass sheet material, using beer The cullet such as bottle fire crystallizing glass sheet material as raw material.Product made from the method that the patent is provided is devitrified glass, production Technique is more complicated, and the firing time is long, and high energy consumption, product does not possess pervious function, is mainly used in indoor high-grade decoration functions material Material field, it is difficult to use on a large scale.
It is at present that the materials such as rubble, cement are mixed compressing using wide common water-permeable brick, is mainly used in The ground pavement in the places such as common pavement, gardens, the major defect of this water-permeable brick is that product appearance is dull, and texture is common, Be not suitable for top grade place, wear no resistance, while being made a low multiple use to discarded object.Chinese patent CN201511006789.2 is carried Supplied a kind of production method of environment friendly composite ceramic water-permeable brick, use waste ceramic and include the industrial residue of combustible for Raw material prepares water-permeable brick.The production method that the patent is provided will be by the process, raw material such as dispensing, old, shaping, dry, sintering Composition complexity is, it is necessary to add binding agent, and sintering temperature reaches 1200 DEG C or so, and energy consumption is higher, and technological process is complicated.
The content of the invention
In view of this, the invention provides a kind of technological process is simple, energy consumption is low, can improve post consumer glass products utilization rate Glass water-permeable brick preparation method, additionally provide a kind of compression strength be 25~50MPa, coefficient of permeability be 1.2~10mm/s, Porosity is 10%~30% glass water-permeable brick.
The present invention provides a kind of glass water-permeable brick, by weight component meter, and the glass water-permeable brick includes glass particle 100 Part, the particle diameter of the glass particle is mutually cementing between 0.08~15mm, the glass particle, and adjacent glass particle interlocks It is mutually communicated and is uniformly distributed between arrangement form hole, the hole, a diameter of 0.01~3mm of the hole.
Further, the glass water-permeable brick is included inside upper brick face, lower brick face and brick body, and brick body is internally located at Between brick face and lower brick face, water is fashionable from upper brick surface current, can pass through hole, along brick body inside go out from lower brick surface current.
Further, the glass water-permeable brick is the polyhedral structure that upper brick face and lower brick face are parallel to each other.
Further, the particle diameter of the glass particle in the upper brick face is less than or equal to the particle diameter of the glass particle in lower brick face.
Further, the thickness of the glass water-permeable brick is 1~300mm.
Further, the porosity of the glass water-permeable brick is 10%~30%.
The present invention also provides a kind of preparation method of the glass water-permeable brick, comprises the following steps:
Glassware is crushed, glass particle is obtained;
Glass particle is laid on fireproof die;
Fireproof die is placed in heating furnace and is heated to certain temperature, is incubated, then cools down;
Fireproof die is removed, glass water-permeable brick is obtained.
Further, the glassware is the article being made up of glass material, and it includes waste and old beer bottle, discarded glass Tank, the inwall of the fireproof die scribbles high temperature resistant releasing agent or laying incombustible paper.
Further, when the particle diameter of the glass particle is 2.5~15mm or 0.7~2.5mm, glass particle will be covered with Fireproof die is placed in heating furnace, and heating furnace is warming up into 640~810 DEG C with 5 DEG C/min speed, is incubated 1h.
Further, when the particle diameter of the glass particle is 0.08~0.63mm, the fireproof die of glass particle will be covered with It is placed in heating furnace, heating furnace is warming up to 640~710 DEG C with 5 DEG C/min speed, is incubated 1h.
Compared with prior art, the present invention uses the glasswares such as discarded glass to prepare glass water-permeable brick for raw material, without Any other material and additive are added, cost of material is low, effectively increase the cyclic utilization rate of discarded glass;The present invention is provided Preparation method simple production process, firing temperature is low, and energy consumption is small, cost is low, can widely use;What the present invention was prepared Glass water-permeable brick surface is frosted shape, and with beautiful outward appearance, density is small, and wearability is good, and permeable sex expression is excellent, compression strength For 25~50MPa, coefficient of permeability is 1.2~10mm/s;It is small that the glass water-permeable brick that the present invention is provided can be used as shopping mall, house Area etc. builds the pavior brick in place, not only attractive in appearance, and can effectively prevent surface gathered water.
Brief description of the drawings
Fig. 1 is a kind of schematic diagram of glass water-permeable brick of the invention.
Fig. 2 is Fig. 1 close-up schematic view.
Fig. 3 is a kind of structural representation of embodiment of glass water-permeable brick one of the invention.
Fig. 4 is a kind of schematic flow sheet of the preparation method of glass water-permeable brick of the invention.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with accompanying drawing to embodiment party of the present invention Formula is further described.
Fig. 1-Fig. 3 is refer to, The embodiment provides a kind of glass water-permeable brick, it includes brick face 11, lower brick 13 inside face 12 and brick body, 13 are located between upper brick face 11 and lower brick face 12 inside brick body, by weight component meter, glass water-permeable brick Including 100 parts of glass particle 14, mutually cementing between glass particle 14, adjacent glass particle 14 is staggered to form hole 15, it is mutually communicated and is uniformly distributed, a diameter of 0.01~3mm of hole 15 between hole 15, the particle diameter of glass particle 14 is 0.08~15mm, the porosity of glass water-permeable brick is 10%~30%.
When glass water-permeable brick is laid on into ground, water is flowed into from upper brick face 11, hole 15 can be passed through, along inside brick body 13 flow out from lower brick face 12, and the particle diameter of the glass particle 14 in upper brick face 11 is less than or equal to the grain of the glass particle 14 in lower brick face 12 Footpath.
The thickness of glass water-permeable brick is 1~300mm.
In the polyhedral structure that glass water-permeable brick is parallel to each other for upper brick face 11 and lower brick face 12, an embodiment, glass is saturating Water brick is rectangular parallelepiped structure.
Fig. 4 is refer to, embodiments of the invention additionally provide a kind of preparation method of glass water-permeable brick, including following step Suddenly:
Step S101, is crushed glassware using pulverizer, obtains glass particle 14;Glassware includes waste and old The article that beer bottle, discarded glass tank etc. are made up of glass material.
Step S102, glass particle 14 is laid on fireproof die, and the inwall of fireproof die scribbles high temperature resistant releasing agent Or laying incombustible paper.
Step S103, fireproof die is placed in heating furnace and is heated to certain temperature, insulation, is then cooled down;
When the particle diameter of glass particle 14 is 2.5~15mm or 0.7~2.5mm, fireproof die is placed in heating furnace and added Heat is incubated 1h to 640~810 DEG C;When the particle diameter of glass particle 14 is 0.08~0.63mm, fireproof die is placed in heating furnace In be heated to 640~710 DEG C, be incubated 1h.
Step S104, removes fireproof die, obtains glass water-permeable brick.
Several embodiments of the preparation method of the glass water-permeable brick of the present invention are given below, in conjunction with the embodiments to above-mentioned preparation Method is illustrated.
Embodiment 1:
Crushed after color is removed into impurity for the waste and old beer bottle of green, screen out the glass that particle diameter is 0.7~2.5mm Glass particle;High temperature resistant releasing agent is applied in the inwall of fireproof die, glass particle is laid in fireproof die, laying depth is 30mm;Fireproof die is placed in heating furnace, heating furnace is warming up to 760 DEG C with 5 DEG C/min speed, and is incubated 1h, then Cooling;Fireproof die is removed, is cut, glass water-permeable brick is obtained.
The thickness of the glass water-permeable brick obtained using embodiment 1 is 24mm, and color is bottle green, and it is saturating to measure glass through experiment The compression strength of water brick is 45.5MPa, and coefficient of permeability is 2.4mm/s.
Embodiment 2:
Crushed after color is removed into impurity for the waste and old beer bottle of green, screen out the glass that particle diameter is 2.5~15mm Glass particle;High temperature resistant releasing agent is applied in the inwall of fireproof die, glass particle is laid in fireproof die, laying depth is 30mm;Fireproof die is placed in heating furnace, heating furnace is warming up to 760 DEG C with 5 DEG C/min speed, and is incubated 1h, then Cooling;Fireproof die is removed, is cut, glass water-permeable brick is obtained.
The thickness of the glass water-permeable brick obtained using embodiment 2 is 27mm, and color is bottle green, and it is saturating to measure glass through experiment The compression strength of water brick is 43MPa, and coefficient of permeability is 3.6mm/s.
Embodiment 3:
Crushed after color is removed into impurity for the waste and old beer bottle of green, it is 0.25~0.63mm's to screen out particle diameter Glass particle;High temperature resistant releasing agent is applied in the inwall of fireproof die, glass particle is laid in fireproof die, laying depth is 30mm;Fireproof die is placed in heating furnace, heating furnace is warming up to 710 DEG C with 5 DEG C/min speed, and is incubated 1h, then Cooling;Fireproof die is removed, is cut, glass water-permeable brick is obtained.
The thickness of the glass water-permeable brick obtained using embodiment 3 is 22mm, and color is light green color, and it is saturating to measure glass through experiment The compression strength of water brick is 47MPa, and coefficient of permeability is 1.6mm/s.
The present invention uses the glasswares such as discarded glass to prepare glass water-permeable brick for raw material, without adding any other material And additive, cost of material is low, effectively increases the cyclic utilization rate of discarded glass;The preparation method production work that the present invention is provided Skill is simple, and firing temperature is low, and energy consumption is small, cost is low, can widely use;The glass water-permeable brick surface that the present invention is prepared is Frosted shape, with beautiful outward appearance, density is small, and wearability is good, and permeable sex expression is excellent, and compression strength is 25~50MPa, permeable Coefficient is 1.2~10mm/s;The glass water-permeable brick that the present invention is provided can be used as the road that place is built in shopping mall, residential quarters etc. Face brick, it is not only attractive in appearance, and can effectively prevent surface gathered water.
Herein, the involved noun of locality such as forward and backward, upper and lower is to be located at parts in accompanying drawing in figure and zero The position of part each other is intended merely to the clear of expression technology scheme and conveniently come what is defined.It should be appreciated that the noun of locality Use should not limit the claimed scope of the application.
In the case where not conflicting, the feature in embodiment and embodiment herein-above set forth can be combined with each other.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (10)

1. a kind of glass water-permeable brick, it is characterised in that component meter by weight, the glass water-permeable brick includes 100 parts of glass particle, The particle diameter of the glass particle is glass particle staggered row mutually cementing, adjacent between 0.08~15mm, the glass particle Row, which are formed between hole, the hole, to be mutually communicated and is uniformly distributed, a diameter of 0.01~3mm of the hole.
2. glass water-permeable brick as claimed in claim 1, it is characterised in that the glass water-permeable brick includes upper brick face, lower brick face Inside brick body, brick body is internally located between brick face and lower brick face, and water is fashionable from upper brick surface current, can pass through hole, Go out inside along brick body from lower brick surface current.
3. glass water-permeable brick as claimed in claim 2, it is characterised in that the glass water-permeable brick is upper brick face and lower brick face phase Mutual parallel polyhedral structure.
4. glass water-permeable brick as claimed in claim 2, it is characterised in that the particle diameter of the glass particle in the upper brick face be less than or Equal to the particle diameter of the glass particle in lower brick face.
5. glass water-permeable brick as claimed in claim 1, it is characterised in that the thickness of the glass water-permeable brick is 1~300mm.
6. glass water-permeable brick as claimed in claim 1, it is characterised in that the porosity of the glass water-permeable brick is 10%~ 30%.
7. the preparation method of the glass water-permeable brick described in a kind of any one of claim 1 to 6, it is characterised in that including following step Suddenly:
Glassware is crushed, glass particle is obtained;
Glass particle is laid on fireproof die;
Fireproof die is placed in heating furnace and is heated to certain temperature, is incubated, then cools down;
Fireproof die is removed, glass water-permeable brick is obtained.
8. the preparation method of glass water-permeable brick as claimed in claim 7, it is characterised in that the glassware is by glass material Expect the article that is made, it includes waste and old beer bottle, discarded glass tank, the inwall of the fireproof die scribble high temperature resistant releasing agent or Lay incombustible paper.
9. the preparation method of glass water-permeable brick as claimed in claim 7, it is characterised in that the particle diameter of the glass particle is During 2.5~15mm or 0.7~2.5mm, the fireproof die for being covered with glass particle is placed in heating furnace, with 5 DEG C/min speed Heating furnace is warming up to 640~810 DEG C, 1h is incubated.
10. the preparation method of glass water-permeable brick as claimed in claim 7, it is characterised in that the particle diameter of the glass particle is During 0.08~0.63mm, the fireproof die for being covered with glass particle is placed in heating furnace, with 5 DEG C/min speed by heating furnace liter Temperature is incubated 1h to 640~710 DEG C.
CN201710366633.8A 2017-05-23 2017-05-23 A kind of glass water-permeable brick and preparation method thereof Pending CN106986526A (en)

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Application Number Priority Date Filing Date Title
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107349686A (en) * 2017-06-30 2017-11-17 陕西科技大学 A kind of seepy material and preparation method thereof
CN108147664A (en) * 2017-12-29 2018-06-12 商洛学院 A kind of method that glass water-permeable brick is prepared using tailing
CN109970348A (en) * 2019-05-05 2019-07-05 商洛学院 A method of glass water-permeable brick is prepared using hot pressing sintering method
CN111018357A (en) * 2019-12-19 2020-04-17 江西璞晶新材料股份有限公司 Microcrystal water permeable brick and preparation method thereof
CN111087170A (en) * 2019-12-19 2020-05-01 江西璞晶新材料股份有限公司 Microcrystal water permeable and water retaining brick and preparation method thereof

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10298903A (en) * 1997-04-25 1998-11-10 Jiyanisu Kogyo Kk Block for pavement, and its manufacture
JPH1160325A (en) * 1997-08-12 1999-03-02 Toto Ltd Building material and structural material and its production
JP2000086256A (en) * 1998-09-10 2000-03-28 Toshio Hoshino Open pore type porous glass sintered body and its production
JP2004168563A (en) * 2002-11-18 2004-06-17 Shinagawa Refract Co Ltd Method for manufacturing translucent refractory tile using waste glass
CN1558879A (en) * 2001-11-08 2004-12-29 迈克尔・J・豪恩 Method for making product from waste glass
TWM290888U (en) * 2005-05-06 2006-05-21 Feng Chiou Structure of environmentally friendly water-permeable brick
CN2823312Y (en) * 2005-07-25 2006-10-04 秦文隆 Improvement of permeable brick structure
WO2010004049A1 (en) * 2008-07-10 2010-01-14 Geofusion Group Limited Building product material
CN103482874A (en) * 2013-09-22 2014-01-01 天津中材工程研究中心有限公司 Method for firing glass-ceramic sheet material by using waste glass at low temperature

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10298903A (en) * 1997-04-25 1998-11-10 Jiyanisu Kogyo Kk Block for pavement, and its manufacture
JPH1160325A (en) * 1997-08-12 1999-03-02 Toto Ltd Building material and structural material and its production
JP2000086256A (en) * 1998-09-10 2000-03-28 Toshio Hoshino Open pore type porous glass sintered body and its production
CN1558879A (en) * 2001-11-08 2004-12-29 迈克尔・J・豪恩 Method for making product from waste glass
JP2004168563A (en) * 2002-11-18 2004-06-17 Shinagawa Refract Co Ltd Method for manufacturing translucent refractory tile using waste glass
TWM290888U (en) * 2005-05-06 2006-05-21 Feng Chiou Structure of environmentally friendly water-permeable brick
CN2823312Y (en) * 2005-07-25 2006-10-04 秦文隆 Improvement of permeable brick structure
WO2010004049A1 (en) * 2008-07-10 2010-01-14 Geofusion Group Limited Building product material
CN103482874A (en) * 2013-09-22 2014-01-01 天津中材工程研究中心有限公司 Method for firing glass-ceramic sheet material by using waste glass at low temperature

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107349686A (en) * 2017-06-30 2017-11-17 陕西科技大学 A kind of seepy material and preparation method thereof
CN108147664A (en) * 2017-12-29 2018-06-12 商洛学院 A kind of method that glass water-permeable brick is prepared using tailing
CN109970348A (en) * 2019-05-05 2019-07-05 商洛学院 A method of glass water-permeable brick is prepared using hot pressing sintering method
CN111018357A (en) * 2019-12-19 2020-04-17 江西璞晶新材料股份有限公司 Microcrystal water permeable brick and preparation method thereof
CN111087170A (en) * 2019-12-19 2020-05-01 江西璞晶新材料股份有限公司 Microcrystal water permeable and water retaining brick and preparation method thereof
CN111087170B (en) * 2019-12-19 2022-05-03 江西璞晶新材料股份有限公司 Microcrystal water permeable and water retaining brick and preparation method thereof

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Application publication date: 20170728

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