JP2000017784A - Roof material - Google Patents

Roof material

Info

Publication number
JP2000017784A
JP2000017784A JP10204426A JP20442698A JP2000017784A JP 2000017784 A JP2000017784 A JP 2000017784A JP 10204426 A JP10204426 A JP 10204426A JP 20442698 A JP20442698 A JP 20442698A JP 2000017784 A JP2000017784 A JP 2000017784A
Authority
JP
Japan
Prior art keywords
titanium oxide
cement
surface layer
slate
roof material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10204426A
Other languages
Japanese (ja)
Other versions
JP2918884B1 (en
Inventor
Naoto Ishii
尚登 石井
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP10204426A priority Critical patent/JP2918884B1/en
Application granted granted Critical
Publication of JP2918884B1 publication Critical patent/JP2918884B1/en
Publication of JP2000017784A publication Critical patent/JP2000017784A/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00586Roofing materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PROBLEM TO BE SOLVED: To purify the atmosphere by including titanium oxide powder in at least the surface layer having a specified thickness in a roof material of slate or the like mainly containing cement and molded into an optional form. SOLUTION: In a roof material of slate or the like mainly containing cement and molded into an optional form, at least the surface layer 0.5 mm thick contains titanium oxide powder. At least 0.5 mm is sufficient for the thickness of the surface layer, and when the thickness is smaller than this, uniform molding of the surface layer is difficult, and the quantity of titanium oxide is too insufficient to function as photocatalyst. When the thus-produced roof material of slate or the like is used to cover the roof with gradient of a house or factory according to ordinary method, the titanium oxide included in the surface layer of the roof material activates oxygen in the atmosphere when the surface of the roof material is exposed to the sunlight, and this oxygen decomposes dust or dirt, organic matters such as bacteria, and NOx the atmosphere to purify the atmosphere.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、大気の浄化機能
を備えたセメント瓦、スレート等のセメントを主成分と
する屋根材に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a roofing material mainly composed of cement, such as a cement tile and a slate, having an air purifying function.

【0002】[0002]

【従来の技術】最近になって酸化チタンの光触媒機能が
注目されるようになり、この酸化チタンの光触媒機能を
利用して大気中の汚れや雑菌等の有機物およびNOx を
分解し、大気を浄化することが種々の分野で試みられて
いる。例えば、セメントを主成分とする鋪道ブロックで
は、鋪道ブロックを構成するセメントモルタル中に酸化
チタンを配合することが行われている。しかしながら、
鋪道ブロックでは、その表面に塵埃や砂が付着し易く、
また人や建物で太陽光が遮られるため、鋪道ブロック内
の酸化チタンがその光触媒機能を十分に発揮できないと
いう問題があった。また、建物の外壁を構成するセメン
ト系壁材の表面に酸化チタンを含む塗料を塗布すること
が知られているが、この場合は、工程が複雑になり、コ
ストが嵩むという問題があった。
2. Description of the Related Art Recently, attention has been paid to the photocatalytic function of titanium oxide, and the photocatalytic function of titanium oxide is used to decompose organic substances such as dirt and germs in the air and NOx to purify the air. Has been attempted in various fields. For example, in a pavement block mainly composed of cement, titanium oxide is blended in cement mortar constituting the pavement block. However,
In the pavement block, dust and sand easily adhere to the surface,
In addition, since sunlight is blocked by people and buildings, there is a problem that titanium oxide in the pavement block cannot exert its photocatalytic function sufficiently. Further, it is known to apply a paint containing titanium oxide to the surface of a cement-based wall material constituting an outer wall of a building. However, in this case, there is a problem that the process becomes complicated and the cost increases.

【0003】[0003]

【発明が解決しようとする課題】この発明は、酸化チタ
ンの担体としてセメントを主成分とする瓦やスレート等
の屋根材を使用することにより、屋根に勾配があること
で表面に汚れや塵埃、砂等を溜まり難くし、仮に汚れ等
が付着しても雨で流れ易くし、かつ光を当たり易くして
酸化チタンの光触媒機能を十分に発揮させ、しかも製造
が容易で、コストの削減を可能にするものである。
SUMMARY OF THE INVENTION The present invention uses a roofing material such as a tile or a slate mainly composed of cement as a carrier of titanium oxide, so that the surface of the roof has dirt and dust. Makes it harder for sand to accumulate, makes it easy for rain to flow even if dirt adheres, and makes it easy to shine light so that the titanium oxide photocatalytic function can be fully demonstrated, and it is easy to manufacture and cost reduction is possible It is to be.

【0004】[0004]

【課題を解決するための手段】この発明は、請求項1に
記載のごとく、セメントを主成分とし任意形状に成形し
てなる瓦やスレート等の屋根材において、その少なくと
も厚み0.5mmの表面層が酸化チタンの粉末を含有する
ことを特徴とする屋根材である。
According to the present invention, there is provided a roofing material such as a tile or a slate formed of cement as a main component and formed into an arbitrary shape. A roofing material characterized in that the layer contains titanium oxide powder.

【0005】セメントを主成分とする屋根材としては、
セメント瓦やスレートが一般的であるが、この発明の屋
根材はそのいずれでもよい。そして、酸化チタンの粉末
は、上記屋根材を構成するセメント主体の混練物の全体
に均一に含有させてもよく、また表面層を構成する混練
物のみに含有させてもよい。全体に含有させる場合は、
製造工程が簡略化され、表面層のみに含有させる場合
は、酸化チタンの使用量が節約される。
[0005] Roofing materials mainly composed of cement include:
Cement tiles and slate are common, and the roofing material of the present invention may be any of them. The titanium oxide powder may be uniformly contained in the cement-based kneaded material constituting the roofing material, or may be contained only in the kneaded material constituting the surface layer. If you want to include it in the whole,
When the manufacturing process is simplified and only the surface layer is contained, the amount of titanium oxide used can be saved.

【0006】この発明では、上記表面層の厚みは、少な
くとも0.5mmあれば十分であり、これよりも薄くする
と、表面層の均一成形が困難になり、かつ酸化チタンの
量が不足して光触媒機能が果たせなくなる。また、酸化
チタンの配合量は、酸化チタンを表面層のみに含有させ
る場合および屋根材の全体に含有させる場合のいずれに
おいても、上記の表面層に相当する部分において、セメ
ント100重量部当たり5〜50重量部が好ましく、5
重量部未満では目的達成が困難であり、50重量部を超
えると不経済である。
In the present invention, it is sufficient that the thickness of the surface layer is at least 0.5 mm. If the thickness is less than 0.5 mm, it becomes difficult to form the surface layer uniformly, and the amount of titanium oxide is insufficient, so that the photocatalyst is insufficient. The function cannot be performed. In addition, in both cases where the titanium oxide is contained only in the surface layer and when the titanium oxide is contained in the entire roofing material, the amount of titanium oxide is 5 to 5 parts per 100 parts by weight of cement in the portion corresponding to the surface layer. Preferably 50 parts by weight
If it is less than 50 parts by weight, it is difficult to achieve the object, and if it exceeds 50 parts by weight, it is uneconomical.

【0007】セメント瓦は、セメントと細骨材を約1:
2の重量比で混ぜた混練物(モルタル)を型枠に充填
し、プレスおよび蒸気養生をして作られるが、この発明
では、上記型枠に充填される混練物全体に上記の酸化チ
タンを配合してもよく、表面層用の混練物を別に用意
し、これのみに酸化チタンを配合してもよい。また、表
面層用の混練物を用意する代わりに、セメントと酸化チ
タンの混合粉末を用意し、これを撒布し、ローラーで加
圧して、下層の混練物から水を吸わせるか、水を別に補
給してもよい。なお、セメント瓦の表面に顔料や陶器質
分を基材と共に成形する場合は、この顔料や陶器質分に
酸化チタンを添加配合することもできる。
[0007] Cement roof tiles consist of cement and fine aggregate of about 1:
The kneaded material (mortar) mixed at a weight ratio of 2 is filled in a mold, pressed and steam-cured. In the present invention, the titanium oxide is added to the entire kneaded material filled in the mold. Alternatively, a kneaded material for the surface layer may be separately prepared, and titanium oxide may be added to only this. Also, instead of preparing the kneaded material for the surface layer, prepare a mixed powder of cement and titanium oxide, spray it, and press it with a roller to absorb water from the lower kneaded material or separate water. May be replenished. When a pigment or pottery component is formed on the surface of the cement tile together with the base material, titanium oxide can be added to the pigment or pottery component.

【0008】また、スレートは、セメント100重量部
に付き、石綿、パルプ等の繊維を5〜15重量部加えて
混練し、次いでシート化し、これを複数枚重ねて所定の
厚みとし、平板または波板に成形し、加圧、裁断、養生
を行って作られるが、この発明では、混練物の全体に酸
化チタンを含有させてもよく、また表面層用の混練物の
みに酸化チタンを添加配合してもよい。
The slate is prepared by adding 5 to 15 parts by weight of fibers such as asbestos and pulp to 100 parts by weight of cement, kneading the mixture, and then forming a sheet. It is made by molding into a plate, pressing, cutting and curing.In this invention, titanium oxide may be contained in the whole kneaded material, or titanium oxide is added and compounded only to the kneaded material for the surface layer. May be.

【0009】こうして作られたセメント瓦、スレート等
の屋根材を用い、常法にしたがって家屋や工場の勾配付
き屋根を葺くと、太陽光が上記屋根材の表面に当たった
際、屋根材の表面層に含まれる酸化チタンが大気中の酸
素を活性化し、この酸素が大気中の塵埃や汚れ、細菌等
の有機物およびNOx を分解し、清浄化する。そして、
屋根は鋪道に比べて塵埃が溜まり難く、仮に溜まって
も、勾配がついているため、雨で流失し易く、また人や
車が通らず、他の建物で太陽光が遮られることが少な
く、そのため酸化チタンの光触媒機能が効率的に働いて
大気を浄化する。
When roofs such as cement tiles and slate made in this manner are used to cover sloped roofs of houses and factories in accordance with a conventional method, when sunlight hits the surface of the roofing materials, The titanium oxide contained in the surface layer activates oxygen in the atmosphere, and this oxygen decomposes and cleans dust and dirt in the atmosphere, organic matter such as bacteria, and NOx. And
The roof is less likely to accumulate dust than a pavement, and even if it accumulates, it is easy to wash away due to rain because it has a slope, and people and cars do not pass, and sunlight is less blocked in other buildings, so The photocatalytic function of titanium oxide works efficiently to purify the atmosphere.

【0010】[0010]

【発明の実施の形態】実施形態1 ポルトランドセメント100重量部に付き細骨材を20
0〜250重量部、酸化チタン粉末を5〜50重量部お
よび水を40〜50重量部加えて混練する。得られたセ
メント混練物をセメント瓦用の型枠に充填し、プレスお
よび蒸気養生を施し、表面から裏面に至る全体に酸化チ
タン粉末がほぼ均一に分散するセメント瓦を得る。この
セメント瓦は、通常のセメント瓦と同様に使用すること
により、大気を清浄化することができる。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Embodiment 1 Fine aggregate is added to 100 parts by weight of Portland cement.
0 to 250 parts by weight, 5 to 50 parts by weight of titanium oxide powder and 40 to 50 parts by weight of water are added and kneaded. The obtained cement kneaded material is filled in a mold for cement tile, and subjected to pressing and steam curing to obtain a cement tile in which titanium oxide powder is substantially uniformly dispersed from the front to the back. The use of this cement tile in the same manner as a normal cement tile can purify the atmosphere.

【0011】実施形態2 実施形態1のセメント混練物から酸化チタンを除く以外
は実施形態1と同様のセメント混練物を実施形態1の型
枠に表面側の一部(深さ0.5〜3.0mmの部分)が残
るように充填し、しかるのち上記型枠の表面側空所に上
記実施形態1の混練物を充填し、以下実施形態1と同様
にして表面層のみに酸化チタンを含有するセメント瓦を
製造する。また、このセメント瓦は、通常のセメント瓦
と同様に使用することにより、実施形態1と同様に大気
を清浄化することができる。なお、セメント瓦の表面に
凹凸が存在する場合は、表面層の厚みを均一にする必要
はなく、酸化チタンを含まない混練物を上面が平坦にな
るように充填し、その上に酸化チタンを含む混練物を充
填して凹凸を形成することができ、この場合は凹部の厚
みが0.5mm以上に形成される。
Embodiment 2 A cement kneaded material similar to that of Embodiment 1 except that titanium oxide is removed from the cement kneaded material of Embodiment 1 is partially placed on the mold of Embodiment 1 on the surface side (depth 0.5 to 3). 2.0 mm), and then the kneaded material of the above-described embodiment 1 is filled in the surface side space of the above-mentioned mold, and the titanium oxide is contained only in the surface layer in the same manner as in the embodiment 1. To manufacture cement roof tiles. Further, by using this cement roof tile in the same manner as a normal cement roof tile, the air can be cleaned as in the first embodiment. In addition, when unevenness is present on the surface of the cement tile, it is not necessary to make the thickness of the surface layer uniform, and a kneaded material not containing titanium oxide is filled so that the upper surface becomes flat, and titanium oxide is further placed thereon. The kneaded material containing the mixture can be filled to form irregularities, and in this case, the thickness of the concave portion is formed to be 0.5 mm or more.

【0012】実施形態3 実施形態2と同様にして酸化チタンを含まない混練物を
型枠に充填し、その表面側空所にセメントと酸化チタン
の混合粉末を充填してロールでプレスし、必要に応じて
水を補給し、以下実施形態1と同様にして表面層のみに
酸化チタンを含有するセメント瓦を製造する。このセメ
ント瓦も、通常のセメント瓦と同様に使用することによ
り、実施形態1と同様に大気を清浄化することができ
る。
Embodiment 3 In the same manner as in Embodiment 2, a kneaded material containing no titanium oxide is filled in a mold, and the surface side space is filled with a mixed powder of cement and titanium oxide and pressed with a roll. Water is supplied in accordance with the above, and a cement tile containing titanium oxide only in the surface layer is manufactured in the same manner as in the first embodiment. By using this cement roof tile in the same manner as a normal cement roof tile, the air can be cleaned as in the first embodiment.

【0013】実施形態4 ポルトランドセメント100重量部に付き石綿を5〜1
0重量部、パルプを3〜5重量部、酸化チタン粉末を5
〜50重量部および水を15〜20重量部加えて混練す
る。得られたセメント混練物を厚み1〜1.5mmの紙状
シートとし、これを複数枚重ねて所望の厚みとし、さら
に平板または波板に成形し、加圧、裁断、養生を施して
厚み4〜6mmのセメントスレートを製造する。このセメ
ントスレートは、従来のセメントスレートと同様にして
屋根を葺くのに使用することができ、実施形態1〜3の
セメント瓦と同様に大気の浄化に有効である。
Embodiment 4 5 to 1 asbestos per 100 parts by weight of Portland cement
0 parts by weight, 3 to 5 parts by weight of pulp, 5 parts by weight of titanium oxide powder
-50 parts by weight and 15-20 parts by weight of water are added and kneaded. The obtained cement kneaded material is formed into a paper-like sheet having a thickness of 1 to 1.5 mm, a plurality of the sheets are stacked to a desired thickness, and further formed into a flat plate or corrugated sheet, and subjected to pressure, cutting, and curing to obtain a sheet having a thickness of 4 mm. Produce cement slate of ~ 6mm. This cement slate can be used for roofing in the same manner as a conventional cement slate, and is effective in purifying the air similarly to the cement tiles of the first to third embodiments.

【0014】実施形態5 実施形態4のセメント混練物において、酸化チタン粉末
を含有しないことを除き、他は実施形態4と同様のセメ
ント混練物を用意し、これを用いて実施形態4と同様の
紙状シートを複数枚製造し、これを重ねる。そして、そ
の上に実施形態4のセメント混練物を用いて成形された
1枚の表面層用の紙状シートを重ね、以下実施形態4と
同様に成形、加圧、裁断、養生を行ってセメントスレー
トを製造する。このセメントスレートは、従来のセメン
トスレートと同様にして屋根を葺くのに使用することが
でき、実施形態4のセメントスレートと同様に大気の浄
化に有効である。
Embodiment 5 In the cement kneaded material of Embodiment 4, except that the titanium oxide powder is not contained, a cement kneaded material similar to that of Embodiment 4 is prepared. A plurality of paper-like sheets are manufactured and stacked. Then, one paper sheet for the surface layer formed using the cement kneaded material of the fourth embodiment is stacked thereon, and the molding, pressing, cutting, and curing are performed in the same manner as in the fourth embodiment. Produce slate. This cement slate can be used for roofing in the same manner as the conventional cement slate, and is effective in purifying the air similarly to the cement slate of the fourth embodiment.

【0015】[0015]

【発明の効果】上記のとおり、請求項1〜2に記載の発
明は、従来のセメント瓦やセメントスレートと同様にし
て屋根を葺くのに使用することができ、その際、太陽光
を受けて大気を清浄化する。そして、屋根は鋪道に比べ
て塵埃が溜まり難く、仮に溜まっても、勾配がついてい
るため、雨で流失し易く、また人や車が通らず、他の建
物で太陽光が遮られることが少なく、そのため酸化チタ
ンの光触媒機能が効率的になる。しかも、セメント混練
物に酸化チタンを加えて混練するだけでよく、従来の製
造工程をほとんど変更する必要がないので、経済的であ
る。
As described above, the inventions according to claims 1 to 2 can be used for roofing in the same manner as conventional cement tiles and cement slate, in which case sunlight is received. To clean the atmosphere. The roof is less likely to collect dust than a pavement, and even if it accumulates, it has a slope, so it is easily washed away by rain, and people and cars do not pass, so sunlight is not blocked by other buildings. Therefore, the photocatalytic function of titanium oxide becomes efficient. Moreover, it is only necessary to add titanium oxide to the cement kneaded material and knead it, and it is economical because there is almost no need to change the conventional manufacturing process.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 セメントを主成分とし任意形状に成形し
てなる瓦やスレート等の屋根材において、その少なくと
も厚み0.5mmの表面層が酸化チタンの粉末を含有する
ことを特徴とする屋根材。
1. A roofing material such as a roof tile or a slate which is mainly made of cement and formed into an arbitrary shape, wherein at least a surface layer having a thickness of 0.5 mm contains a powder of titanium oxide. .
【請求項2】 表面層における酸化チタンの含有料がセ
メント100重量部当たり5〜50重量部である請求項
1記載の屋根材。
2. The roofing material according to claim 1, wherein the content of titanium oxide in the surface layer is 5 to 50 parts by weight per 100 parts by weight of cement.
JP10204426A 1998-07-03 1998-07-03 Roofing material Expired - Fee Related JP2918884B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10204426A JP2918884B1 (en) 1998-07-03 1998-07-03 Roofing material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10204426A JP2918884B1 (en) 1998-07-03 1998-07-03 Roofing material

Publications (2)

Publication Number Publication Date
JP2918884B1 JP2918884B1 (en) 1999-07-12
JP2000017784A true JP2000017784A (en) 2000-01-18

Family

ID=16490351

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10204426A Expired - Fee Related JP2918884B1 (en) 1998-07-03 1998-07-03 Roofing material

Country Status (1)

Country Link
JP (1) JP2918884B1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005193118A (en) * 2004-01-06 2005-07-21 Daiken Kagaku Kogyo Kk Photocatalytic particle, photocatalytic solution, atomizer, air cleaner and photocatalytic base material
GB2425075A (en) * 2005-04-15 2006-10-18 Marley Eternit Ltd Concrete roof tile or wall cladding element
JP2007524012A (en) * 2003-12-24 2007-08-23 スリーエム イノベイティブ プロパティズ カンパニー Energy efficient building surface
US7300514B2 (en) * 2002-10-03 2007-11-27 Ciments Francais Photocatalytic granular mixture for mortar and concrete and its use
EP2275391A1 (en) 2009-07-16 2011-01-19 Redco S.A. Air-purifying fiber reinforced cementitious building material.

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US7300514B2 (en) * 2002-10-03 2007-11-27 Ciments Francais Photocatalytic granular mixture for mortar and concrete and its use
US7556683B2 (en) 2002-10-03 2009-07-07 Ciments Francais Photocatalytic granular mixture for mortar and concrete and its use
JP2007524012A (en) * 2003-12-24 2007-08-23 スリーエム イノベイティブ プロパティズ カンパニー Energy efficient building surface
JP2012017651A (en) * 2003-12-24 2012-01-26 Three M Innovative Properties Co Energy efficient building surface
KR101385896B1 (en) * 2003-12-24 2014-04-15 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Energy Efficient Roofing Granule
JP2005193118A (en) * 2004-01-06 2005-07-21 Daiken Kagaku Kogyo Kk Photocatalytic particle, photocatalytic solution, atomizer, air cleaner and photocatalytic base material
GB2425075A (en) * 2005-04-15 2006-10-18 Marley Eternit Ltd Concrete roof tile or wall cladding element
GB2425075B (en) * 2005-04-15 2010-12-22 Marley Eternit Ltd Concrete Roof Tiles And Wall Cladding Elements
EP2275391A1 (en) 2009-07-16 2011-01-19 Redco S.A. Air-purifying fiber reinforced cementitious building material.

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