JOP20190138A1 - مادة عضوية متوسطة المسام، مفيدة بشكل خاص في استخلاص اليورانيوم (vi) من وسائط مائية بما فيها حمض الفوسفوريك، واستخداماتها - Google Patents

مادة عضوية متوسطة المسام، مفيدة بشكل خاص في استخلاص اليورانيوم (vi) من وسائط مائية بما فيها حمض الفوسفوريك، واستخداماتها

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Publication number
JOP20190138A1
JOP20190138A1 JOP/2019/0138A JOP20190138A JOP20190138A1 JO P20190138 A1 JOP20190138 A1 JO P20190138A1 JO P20190138 A JOP20190138 A JO P20190138A JO P20190138 A1 JOP20190138 A1 JO P20190138A1
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Jordan
Prior art keywords
phosphoric acid
organic material
cross
useful
including phosphoric
Prior art date
Application number
JOP/2019/0138A
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English (en)
Inventor
Cecile Marie
Frederic Cuer
Manon Marbet
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Commissariat Energie Atomique
Orano Mining
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Publication date
Application filed by Commissariat Energie Atomique, Orano Mining filed Critical Commissariat Energie Atomique
Publication of JOP20190138A1 publication Critical patent/JOP20190138A1/ar

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    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/02Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing phosphorus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • B01J20/261Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078Pore diameter
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/26Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
    • C22B60/0221Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching
    • C22B60/0226Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors
    • C22B60/0243Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes by leaching using acidic solutions or liquors phosphorated ion as active agent
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    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B60/00Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
    • C22B60/02Obtaining thorium, uranium, or other actinides
    • C22B60/0204Obtaining thorium, uranium, or other actinides obtaining uranium
    • C22B60/0217Obtaining thorium, uranium, or other actinides obtaining uranium by wet processes
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F2303/16Regeneration of sorbents, filters
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/04Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/046Elimination of a polymeric phase
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    • C08J2201/04Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
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Abstract

يتعلق الاختراع الحالي بمواد عضوية متوسطة المسام التي تجعل من الممكن، باستخدام تقنية الاستخراج الصلبة السائلة، استخراج اليورانيوم<span dir="LTR"> (VI) </span>الموجود في وسط مائي بما في ذلك حمض الفوسفوريك، بكفاءة عالية وانتقائية عالية للحديد الذي يمكن أن يحتويه هذا الوسط. ويتعلق الاختراع أيضًا باستخدامات المادة المذكورة. ويمكن الحصول على المادة عن طريق بلمرة الارتباط المتشابك لمونومر له الصيغة<span dir="LTR"> (I) </span>أدناه، حيث: <span dir="LTR">R<sup>1</sup></span>، و <span dir="LTR">R<sup>2</sup></span> و<span dir="LTR">R<sup>3</sup></span>، بشكل مستقل عن بعضهم البعض، هي <span dir="LTR">H</span>، ومجموعة <span dir="LTR">C1</span> إلى<span dir="LTR"> C12 </span>مشبعة أو غير مشبعة، هيدروكربونات خطية أو متفرعة، أو مجموعة قابلة للبلمرة، بشرط أن يكون واحد على الأقل من <span dir="LTR">R<sup>1</sup></span> و<span dir="LTR"> R<sup>2</sup> </span>و<span dir="LTR"> R<sup>3</sup> </span>عبارة عن مجموعة قابلة للبلمرة؛ و <span dir="LTR">R<sup>4</sup></span> و <span dir="LTR">R<sup>5</sup></span>هما، بشكل مستقل عن بعضهما البعض، عبارة عن <span dir="LTR">H </span> أو مجموعة<span dir="LTR"> C1 </span>إلى<span dir="LTR"> C8 </span>مشبعة أو غير مشبعة، خطية أو متفرعة؛ يتم تنفيذ بلمرة الارتباط المتشابك في وجود عامل ارتباط متشابك وعامل أو أكثر من عوامل تشكيل المسام. ويمكن استخدام الاختراع في معالجة الفوسفات الطبيعي بهدف استخراج اليورانيوم<span dir="LTR"> (VI) </span>الموجود في هذه الفوسفات<span dir="LTR">.</span> <img src="file:///C:\Users\mohammad.tw\AppData\Local\Temp\msohtmlclip1\01\clip_image002.png" />
JOP/2019/0138A 2016-12-13 2017-06-16 مادة عضوية متوسطة المسام، مفيدة بشكل خاص في استخلاص اليورانيوم (vi) من وسائط مائية بما فيها حمض الفوسفوريك، واستخداماتها JOP20190138A1 (ar)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1662377A FR3060006B1 (fr) 2016-12-13 2016-12-13 Materiau organique mesoporeux, utile notamment pour extraire l'uranium(vi) de milieux aqueux comprenant de l'acide phosphorique, et ses utilisations

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JOP20190138A1 true JOP20190138A1 (ar) 2019-06-11

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US (1) US11365462B2 (ar)
EP (1) EP3555158B1 (ar)
AU (1) AU2017374664B2 (ar)
BR (1) BR112019011976A2 (ar)
CA (1) CA3046550A1 (ar)
FR (1) FR3060006B1 (ar)
IL (1) IL267240B (ar)
JO (1) JOP20190138A1 (ar)
MA (1) MA48599B1 (ar)
PE (1) PE20191645A1 (ar)
SA (1) SA519402200B1 (ar)
WO (1) WO2018109382A1 (ar)

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CN113209933B (zh) * 2021-04-15 2022-07-01 中国工程物理研究院材料研究所 一种MXene气凝胶的制备方法及其对磷和铀酰的吸附应用
CN115090270B (zh) * 2022-06-07 2024-03-29 烟台哈尔滨工程大学研究院 一种多孔聚合物铀吸附材料及其制备方法

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WO2003013444A1 (en) * 2001-08-10 2003-02-20 Dentsply International Inc. One-part self-priming dental adhesive
FR2990206B1 (fr) 2012-05-07 2014-06-06 Commissariat Energie Atomique Nouveaux composes bifonctionnels utiles comme ligands de l'uranium(vi), leurs procedes de synthese et leurs utilisations
FR3002463B1 (fr) * 2013-02-25 2016-08-19 Commissariat Energie Atomique Materiau hybride organique-inorganique, utile pour extraire l'uranium(vi) de milieux aqueux contenant de l'acide phosphorique, ses procedes de preparation et ses utilisations
FR3002951B1 (fr) * 2013-03-11 2015-04-17 Areva Mines Utilisation de composes a fonctions amide et phosphonate pour extraire l'uranium(vi) de solutions aqueuses d'acide sulfurique, issues notamment de la lixiviation sulfurique de minerais uraniferes
FR3013059B1 (fr) 2013-11-08 2016-01-01 Commissariat Energie Atomique Utilisation d'un materiau hybride organique-inorganique pour extraire l'uranium(vi) d'une solution aqueuse d'acide sulfurique, issue notamment de la lixiviation sulfurique d'un minerai uranifere
CA2982423C (en) * 2015-04-17 2024-01-16 Hetero Labs Ltd Polymorphs and process for the preparation of quinazolinyl derivatives
FR3044006B1 (fr) * 2015-11-19 2020-03-06 Orano Mining Nouveau materiau organique pour extraire l'uranium d'une solution aqueuse d'acide phosphorique, procedes d'extraction et de recuperation de l'uranium associes et precurseur d'un tel materiau organique

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IL267240A (en) 2019-08-29
EP3555158B1 (fr) 2020-12-09
BR112019011976A2 (pt) 2019-11-05
CA3046550A1 (fr) 2018-06-21
SA519402200B1 (ar) 2023-02-01
MA48599B1 (fr) 2021-03-31
AU2017374664B2 (en) 2022-07-28
IL267240B (en) 2022-04-01
FR3060006A1 (fr) 2018-06-15
AU2017374664A1 (en) 2019-07-04
WO2018109382A1 (fr) 2018-06-21
US11365462B2 (en) 2022-06-21
FR3060006B1 (fr) 2020-02-28
US20190316226A1 (en) 2019-10-17
PE20191645A1 (es) 2019-11-07
EP3555158A1 (fr) 2019-10-23

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