IT1401192B1 - Reattore a membrana per il trattamento di gas contenenti trizio - Google Patents

Reattore a membrana per il trattamento di gas contenenti trizio

Info

Publication number
IT1401192B1
IT1401192B1 ITRM2010A000330A ITRM20100330A IT1401192B1 IT 1401192 B1 IT1401192 B1 IT 1401192B1 IT RM2010A000330 A ITRM2010A000330 A IT RM2010A000330A IT RM20100330 A ITRM20100330 A IT RM20100330A IT 1401192 B1 IT1401192 B1 IT 1401192B1
Authority
IT
Italy
Prior art keywords
trizio
treatment
gas containing
membrane reactor
reactor
Prior art date
Application number
ITRM2010A000330A
Other languages
English (en)
Inventor
Fabrizio Marini
Silvano Tosti
Fabio Borgognoni
Alessia Santucci
Pierre Trabuc
Karine Liger
Original Assignee
Enea Agenzia Naz Per Le Nuove Tecnologie L En E Lo Sviluppo Economico Sostenibile
Commissariat Energie Atomique
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to ITRM2010A000330A priority Critical patent/IT1401192B1/it
Application filed by Enea Agenzia Naz Per Le Nuove Tecnologie L En E Lo Sviluppo Economico Sostenibile, Commissariat Energie Atomique filed Critical Enea Agenzia Naz Per Le Nuove Tecnologie L En E Lo Sviluppo Economico Sostenibile
Priority to CN201180029989.3A priority patent/CN102985357B/zh
Priority to KR1020127032742A priority patent/KR101736530B1/ko
Priority to EP11739190.4A priority patent/EP2582618B1/en
Priority to ES11739190.4T priority patent/ES2494265T3/es
Priority to RU2013100180/05A priority patent/RU2558888C2/ru
Priority to JP2013514843A priority patent/JP5798187B2/ja
Priority to PCT/IT2011/000205 priority patent/WO2011158275A1/en
Priority to CA2802208A priority patent/CA2802208C/en
Priority to US13/704,706 priority patent/US8979984B2/en
Publication of ITRM20100330A1 publication Critical patent/ITRM20100330A1/it
Application granted granted Critical
Publication of IT1401192B1 publication Critical patent/IT1401192B1/it

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/04—Tubular membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D59/00—Separation of different isotopes of the same chemical element
    • B01D59/28—Separation by chemical exchange
    • B01D59/32—Separation by chemical exchange by exchange between fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D63/00—Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/06—Tubular membrane modules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/003—Membrane bonding or sealing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • B01D71/02231—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1893—Membrane reactors
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C01B3/505—Membranes containing palladium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B4/00—Hydrogen isotopes; Inorganic compounds thereof prepared by isotope exchange, e.g. NH3 + D2 → NH2D + HD
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/94—Non-porous diffusion electrodes, e.g. palladium membranes, ion exchange membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/13—Use of sweep gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/02—Specific tightening or locking mechanisms
    • B01D2313/025—Specific membrane holders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2313/00—Details relating to membrane modules or apparatus
    • B01D2313/34—Energy carriers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0254—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • B01J2219/0286—Steel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0681—Reactant purification by the use of electrochemical cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0687—Reactant purification by the use of membranes or filters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
ITRM2010A000330A 2010-06-16 2010-06-16 Reattore a membrana per il trattamento di gas contenenti trizio IT1401192B1 (it)

Priority Applications (10)

Application Number Priority Date Filing Date Title
ITRM2010A000330A IT1401192B1 (it) 2010-06-16 2010-06-16 Reattore a membrana per il trattamento di gas contenenti trizio
KR1020127032742A KR101736530B1 (ko) 2010-06-16 2011-06-16 삼중 수소를 함유한 가스를 처리하는 멤브레인 반응기
EP11739190.4A EP2582618B1 (en) 2010-06-16 2011-06-16 Membrane reactor for treating gases containing tritium
ES11739190.4T ES2494265T3 (es) 2010-06-16 2011-06-16 Reactor de membrana para el tratamiento de gases con tritio
CN201180029989.3A CN102985357B (zh) 2010-06-16 2011-06-16 用于处理含氚气体的膜反应器
RU2013100180/05A RU2558888C2 (ru) 2010-06-16 2011-06-16 Мембранный реактор для очистки газов, содержащих тритий
JP2013514843A JP5798187B2 (ja) 2010-06-16 2011-06-16 トリチウム含有ガスを処理するための膜反応器
PCT/IT2011/000205 WO2011158275A1 (en) 2010-06-16 2011-06-16 Membrane reactor for treating gases containing tritium
CA2802208A CA2802208C (en) 2010-06-16 2011-06-16 Membrane reactor for treating gases containing tritium
US13/704,706 US8979984B2 (en) 2010-06-16 2011-06-16 Membrane reactor for treating gases containing tritium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITRM2010A000330A IT1401192B1 (it) 2010-06-16 2010-06-16 Reattore a membrana per il trattamento di gas contenenti trizio

Publications (2)

Publication Number Publication Date
ITRM20100330A1 ITRM20100330A1 (it) 2011-12-17
IT1401192B1 true IT1401192B1 (it) 2013-07-12

Family

ID=43498621

Family Applications (1)

Application Number Title Priority Date Filing Date
ITRM2010A000330A IT1401192B1 (it) 2010-06-16 2010-06-16 Reattore a membrana per il trattamento di gas contenenti trizio

Country Status (10)

Country Link
US (1) US8979984B2 (it)
EP (1) EP2582618B1 (it)
JP (1) JP5798187B2 (it)
KR (1) KR101736530B1 (it)
CN (1) CN102985357B (it)
CA (1) CA2802208C (it)
ES (1) ES2494265T3 (it)
IT (1) IT1401192B1 (it)
RU (1) RU2558888C2 (it)
WO (1) WO2011158275A1 (it)

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DE202012013304U1 (de) * 2012-09-27 2016-02-15 Mahnken & Partner GmbH Vorrichtung zur Gewinnung von Wasserstoff
US10381121B2 (en) 2013-11-13 2019-08-13 Savannah River Nuclear Solutions, Llc Decontamination of tritiated water
EP3275530A4 (en) 2015-03-24 2019-03-06 ARSTROMA Co., Ltd. FLUID SEPARATION APPARATUS COMPRISING A FLUID SEPARATION MEMBRANE, AND FLUID SEPARATION MEMBRANE MODULE
CA2941293A1 (en) * 2015-10-09 2017-04-09 Kurion, Inc. Advanced tritium system and advanced permeation system for separation of tritium from radioactive wastes
LT3414425T (lt) * 2016-02-08 2022-11-25 Proton Technologies Inc. Būdas in situ vandeniliui iš požeminių angliandenilio rezervuarų gauti
CN105903349B (zh) * 2016-06-07 2017-06-27 中国工程物理研究院核物理与化学研究所 一种用于氢同位素分离的大面积钯膜装置
CN107469628B (zh) * 2017-09-21 2019-10-01 中国科学院上海应用物理研究所 一种去除熔盐中气态氚及其同位素的装置及方法
CN107879312B (zh) * 2017-12-07 2021-04-06 中国工程物理研究院核物理与化学研究所 一种用于氢同位素交换的波纹状膜反应器装置
RU186241U1 (ru) * 2018-06-01 2019-01-14 Федеральное государственное бюджетное образовательное учреждение высшего образования - Российский химико-технологический университет имени Д.И. Менделеева (РХТУ им. Д.И. Менделеева) Контактное устройство для изотопного обмена газа с водой
US11058994B2 (en) 2019-01-18 2021-07-13 Savannah River National Solutions, LLC Tritium cleanup system and method
CN113578222A (zh) * 2021-07-12 2021-11-02 浙江大学 基于瞬时高温焦耳热法的纳米复合材料合成装置及制备方法和应用
US11697099B2 (en) * 2021-11-22 2023-07-11 Schneider Electric Systems Usa, Inc. Direct electrical heating of catalytic reactive system

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Also Published As

Publication number Publication date
CA2802208A1 (en) 2011-12-22
EP2582618B1 (en) 2014-05-14
JP5798187B2 (ja) 2015-10-21
KR20130129823A (ko) 2013-11-29
WO2011158275A8 (en) 2013-01-10
CN102985357B (zh) 2015-06-10
ITRM20100330A1 (it) 2011-12-17
EP2582618A1 (en) 2013-04-24
WO2011158275A1 (en) 2011-12-22
US8979984B2 (en) 2015-03-17
KR101736530B1 (ko) 2017-05-16
ES2494265T3 (es) 2014-09-15
JP2013536404A (ja) 2013-09-19
CN102985357A (zh) 2013-03-20
US20130108517A1 (en) 2013-05-02
CA2802208C (en) 2017-10-31
RU2013100180A (ru) 2014-07-27
RU2558888C2 (ru) 2015-08-10

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