IT1298616B1 - Complesso metallocenico pontato per la (co) polimerizzazione delle olefine - Google Patents
Complesso metallocenico pontato per la (co) polimerizzazione delle olefineInfo
- Publication number
- IT1298616B1 IT1298616B1 IT98MI000479A ITMI980479A IT1298616B1 IT 1298616 B1 IT1298616 B1 IT 1298616B1 IT 98MI000479 A IT98MI000479 A IT 98MI000479A IT MI980479 A ITMI980479 A IT MI980479A IT 1298616 B1 IT1298616 B1 IT 1298616B1
- Authority
- IT
- Italy
- Prior art keywords
- olefins
- polymerization
- complex
- bridged
- group
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 239000004711 α-olefin Substances 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/45—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
- C07C13/465—Indenes; Completely or partially hydrogenated indenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT98MI000479A IT1298616B1 (it) | 1998-03-10 | 1998-03-10 | Complesso metallocenico pontato per la (co) polimerizzazione delle olefine |
| EP99103742A EP0955304B1 (en) | 1998-03-10 | 1999-02-26 | Bridged metallocene complexes for the (co)polymerization of olefins |
| DK99103742T DK0955304T3 (da) | 1998-03-10 | 1999-02-26 | Metallocenkomplekser med bro til (co)polymerisation af olefiner |
| DE69910886T DE69910886T2 (de) | 1998-03-10 | 1999-02-26 | Verbrückte Metallocene für die (Co)Polymerisation von Olefinen |
| PT99103742T PT955304E (pt) | 1998-03-10 | 1999-02-26 | Complexo de metaloceno com pontes para a (co) polimerizacao de olefinas |
| AT99103742T ATE248848T1 (de) | 1998-03-10 | 1999-02-26 | Verbrückte metallocene für die (co)polymerisation von olefinen |
| ES99103742T ES2207045T3 (es) | 1998-03-10 | 1999-02-26 | Complejos de metaloceno con puente para la copolimerizacion de olefinas. |
| US09/262,318 US6211110B1 (en) | 1998-03-10 | 1999-03-04 | Bridged metallocene complex for the (co)polymerization of olefins |
| CA002262868A CA2262868C (en) | 1998-03-10 | 1999-03-08 | Bridged metallocene complex for the (co)polymerization of olefins |
| CNB991056426A CN1198835C (zh) | 1998-03-10 | 1999-03-10 | 用于烯烃（共）聚合的桥连金属茂配合物 |
| JP06365399A JP4372258B2 (ja) | 1998-03-10 | 1999-03-10 | オレフィンの（共）重合用の架橋メタロセン錯体 |
| US09/790,570 US6417418B2 (en) | 1998-03-10 | 2001-02-23 | Bridged metallocene complex for the (co)polymerization of olefins |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT98MI000479A IT1298616B1 (it) | 1998-03-10 | 1998-03-10 | Complesso metallocenico pontato per la (co) polimerizzazione delle olefine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ITMI980479A1 ITMI980479A1 (it) | 1999-09-10 |
| IT1298616B1 true IT1298616B1 (it) | 2000-01-12 |
Family
ID=11379246
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT98MI000479A IT1298616B1 (it) | 1998-03-10 | 1998-03-10 | Complesso metallocenico pontato per la (co) polimerizzazione delle olefine |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US6211110B1 (https=) |
| EP (1) | EP0955304B1 (https=) |
| JP (1) | JP4372258B2 (https=) |
| CN (1) | CN1198835C (https=) |
| AT (1) | ATE248848T1 (https=) |
| CA (1) | CA2262868C (https=) |
| DE (1) | DE69910886T2 (https=) |
| DK (1) | DK0955304T3 (https=) |
| ES (1) | ES2207045T3 (https=) |
| IT (1) | IT1298616B1 (https=) |
| PT (1) | PT955304E (https=) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6433203B1 (en) * | 1998-11-20 | 2002-08-13 | Basell Technology Company Bv | Bridged metallocenes, preparation, use in catalytic systems |
| ITMI20011017A1 (it) * | 2001-05-17 | 2002-11-17 | Enichem Spa | Procedimento per la preparazione di copolimeri e terpolimeri elastomerici ep (d) m |
| CA2454060A1 (en) * | 2001-07-19 | 2003-01-30 | Univation Technologies, Llc | Low comonomer incorporating metallocene catalyst compounds |
| US7439379B2 (en) | 2001-09-14 | 2008-10-21 | Sumitomo Chemical Co., Ltd. | Transition metal complex, catalyst for olefin polymerization, and process for producing olefin polymer with the same |
| JP3928394B2 (ja) * | 2001-09-14 | 2007-06-13 | 住友化学株式会社 | 置換シクロペンタジエンおよびその製造方法 |
| ITMI20012516A1 (it) * | 2001-11-30 | 2003-05-30 | Enichem Spa | Procedimento per la preparazione di copolimeri dell'etilene aventi una larga distribuzione dei pesi molecolari |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
| US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US20040102311A1 (en) * | 2002-11-21 | 2004-05-27 | Abbas Razavi | Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof |
| JP5154748B2 (ja) * | 2005-10-21 | 2013-02-27 | 三井化学株式会社 | 連続有機過酸化物架橋ゴム成形体への加工法およびその架橋ゴム成形体 |
| JP2008231017A (ja) | 2007-03-20 | 2008-10-02 | Sumitomo Chemical Co Ltd | 遷移金属錯体、その製造方法及び用途 |
| KR100994252B1 (ko) * | 2007-05-09 | 2010-11-12 | 주식회사 엘지화학 | 에틸렌 알파-올레핀 공중합체 |
| JP5536773B2 (ja) * | 2008-08-14 | 2014-07-02 | ベータ・ファーマ・カナダ・インコーポレイテッド | Ｅｐ４受容体アンタゴニストとしてのヘテロ環式アミド誘導体 |
| PT2800754T (pt) * | 2011-12-19 | 2017-08-18 | Saudi Basic Ind Corp (Sabic) | Processo para a preparação de complexos metalocenos |
| CN104093730A (zh) * | 2011-12-19 | 2014-10-08 | 沙特基础工业公司 | 用于制备茂金属络合物的方法 |
| JP6589233B2 (ja) * | 2015-03-17 | 2019-10-16 | 株式会社カネカ | トリアリールメタノールの製造方法 |
| WO2020081695A1 (en) * | 2018-10-17 | 2020-04-23 | Nikang Therapeutics, Inc. | Indane derivatives as hypoxia inducible factor-2(alpha) inhibitors |
| CN109575300A (zh) * | 2018-11-15 | 2019-04-05 | 三明学院 | 一种导电金属有机框架材料的合成方法 |
| CN111793159B (zh) * | 2020-01-16 | 2021-04-06 | 深圳市沃尔电力技术有限公司 | 高压绝缘直流电缆附件材料生产方法及其加工设备 |
| CN115485311B (zh) | 2020-02-24 | 2024-12-06 | 埃克森美孚化学专利公司 | 用于生产乙烯叉基封端的聚α-烯烃的柄型-双(茚-2-基)催化剂 |
| CN111620914B (zh) * | 2020-07-09 | 2021-03-19 | 吉林大学 | 含中性苄杂原子配位基侧臂单茂四价过渡金属配合物及其用途 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1275777B1 (it) | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
| US5635437A (en) * | 1995-07-28 | 1997-06-03 | Exxon Chemicals Patents, Inc. | Method for preparing metallocene catalyst systems |
| IT1282666B1 (it) | 1996-02-22 | 1998-03-31 | Enichem Spa | Catalizzatore metallocenico sostituito per la (co) polimerizzazione delle olefine |
| IT1283630B1 (it) | 1996-05-09 | 1998-04-23 | Enichem Spa | Procedimento per la preparazione di copolimeri elastomerici ep(d)m |
| IT1290856B1 (it) | 1996-12-19 | 1998-12-14 | Enichem Spa | Metalloceni, loro preparazione ed uso nella polimerizzazione di alfa-olefine |
| US6087515A (en) * | 1998-10-07 | 2000-07-11 | Solvay Polyolefins Europe-Belgium (Societe Anonyme) | Metallocenes and process for the preparation of metallocenes |
-
1998
- 1998-03-10 IT IT98MI000479A patent/IT1298616B1/it active IP Right Grant
-
1999
- 1999-02-26 ES ES99103742T patent/ES2207045T3/es not_active Expired - Lifetime
- 1999-02-26 PT PT99103742T patent/PT955304E/pt unknown
- 1999-02-26 EP EP99103742A patent/EP0955304B1/en not_active Expired - Lifetime
- 1999-02-26 DE DE69910886T patent/DE69910886T2/de not_active Expired - Lifetime
- 1999-02-26 DK DK99103742T patent/DK0955304T3/da active
- 1999-02-26 AT AT99103742T patent/ATE248848T1/de active
- 1999-03-04 US US09/262,318 patent/US6211110B1/en not_active Expired - Lifetime
- 1999-03-08 CA CA002262868A patent/CA2262868C/en not_active Expired - Fee Related
- 1999-03-10 CN CNB991056426A patent/CN1198835C/zh not_active Expired - Lifetime
- 1999-03-10 JP JP06365399A patent/JP4372258B2/ja not_active Expired - Fee Related
-
2001
- 2001-02-23 US US09/790,570 patent/US6417418B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP4372258B2 (ja) | 2009-11-25 |
| DK0955304T3 (da) | 2004-01-05 |
| CN1239098A (zh) | 1999-12-22 |
| US6417418B2 (en) | 2002-07-09 |
| DE69910886D1 (de) | 2003-10-09 |
| EP0955304B1 (en) | 2003-09-03 |
| EP0955304A3 (en) | 2000-06-21 |
| PT955304E (pt) | 2004-01-30 |
| JP2000038409A (ja) | 2000-02-08 |
| ITMI980479A1 (it) | 1999-09-10 |
| US6211110B1 (en) | 2001-04-03 |
| EP0955304A2 (en) | 1999-11-10 |
| ES2207045T3 (es) | 2004-05-16 |
| ATE248848T1 (de) | 2003-09-15 |
| US20010031885A1 (en) | 2001-10-18 |
| CA2262868C (en) | 2009-08-18 |
| CN1198835C (zh) | 2005-04-27 |
| CA2262868A1 (en) | 1999-09-10 |
| DE69910886T2 (de) | 2004-07-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 0001 | Granted |