IT1298616B1 - Complesso metallocenico pontato per la (co) polimerizzazione delle olefine - Google Patents

Complesso metallocenico pontato per la (co) polimerizzazione delle olefine

Info

Publication number
IT1298616B1
IT1298616B1 IT98MI000479A ITMI980479A IT1298616B1 IT 1298616 B1 IT1298616 B1 IT 1298616B1 IT 98MI000479 A IT98MI000479 A IT 98MI000479A IT MI980479 A ITMI980479 A IT MI980479A IT 1298616 B1 IT1298616 B1 IT 1298616B1
Authority
IT
Italy
Prior art keywords
olefins
polymerization
complex
bridged
group
Prior art date
Application number
IT98MI000479A
Other languages
English (en)
Italian (it)
Inventor
Roberto Santi
Antonio Proto
Giampietro Borsotti
Viviano Banzi
Paolo Biagini
Gianfranco Longhini
Francesco Masi
Original Assignee
Enichem Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to IT98MI000479A priority Critical patent/IT1298616B1/it
Application filed by Enichem Spa filed Critical Enichem Spa
Priority to AT99103742T priority patent/ATE248848T1/de
Priority to EP99103742A priority patent/EP0955304B1/en
Priority to ES99103742T priority patent/ES2207045T3/es
Priority to DE69910886T priority patent/DE69910886T2/de
Priority to DK99103742T priority patent/DK0955304T3/da
Priority to PT99103742T priority patent/PT955304E/pt
Priority to US09/262,318 priority patent/US6211110B1/en
Priority to CA002262868A priority patent/CA2262868C/en
Priority to JP06365399A priority patent/JP4372258B2/ja
Priority to CNB991056426A priority patent/CN1198835C/zh
Publication of ITMI980479A1 publication Critical patent/ITMI980479A1/it
Application granted granted Critical
Publication of IT1298616B1 publication Critical patent/IT1298616B1/it
Priority to US09/790,570 priority patent/US6417418B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/45Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with a bicyclo ring system containing nine carbon atoms
    • C07C13/465Indenes; Completely or partially hydrogenated indenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00Systems containing two condensed rings
    • C07C2602/02Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/09Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
IT98MI000479A 1998-03-10 1998-03-10 Complesso metallocenico pontato per la (co) polimerizzazione delle olefine IT1298616B1 (it)

Priority Applications (12)

Application Number Priority Date Filing Date Title
IT98MI000479A IT1298616B1 (it) 1998-03-10 1998-03-10 Complesso metallocenico pontato per la (co) polimerizzazione delle olefine
EP99103742A EP0955304B1 (en) 1998-03-10 1999-02-26 Bridged metallocene complexes for the (co)polymerization of olefins
ES99103742T ES2207045T3 (es) 1998-03-10 1999-02-26 Complejos de metaloceno con puente para la copolimerizacion de olefinas.
DE69910886T DE69910886T2 (de) 1998-03-10 1999-02-26 Verbrückte Metallocene für die (Co)Polymerisation von Olefinen
DK99103742T DK0955304T3 (da) 1998-03-10 1999-02-26 Metallocenkomplekser med bro til (co)polymerisation af olefiner
PT99103742T PT955304E (pt) 1998-03-10 1999-02-26 Complexo de metaloceno com pontes para a (co) polimerizacao de olefinas
AT99103742T ATE248848T1 (de) 1998-03-10 1999-02-26 Verbrückte metallocene für die (co)polymerisation von olefinen
US09/262,318 US6211110B1 (en) 1998-03-10 1999-03-04 Bridged metallocene complex for the (co)polymerization of olefins
CA002262868A CA2262868C (en) 1998-03-10 1999-03-08 Bridged metallocene complex for the (co)polymerization of olefins
JP06365399A JP4372258B2 (ja) 1998-03-10 1999-03-10 オレフィンの(共)重合用の架橋メタロセン錯体
CNB991056426A CN1198835C (zh) 1998-03-10 1999-03-10 用于烯烃(共)聚合的桥连金属茂配合物
US09/790,570 US6417418B2 (en) 1998-03-10 2001-02-23 Bridged metallocene complex for the (co)polymerization of olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT98MI000479A IT1298616B1 (it) 1998-03-10 1998-03-10 Complesso metallocenico pontato per la (co) polimerizzazione delle olefine

Publications (2)

Publication Number Publication Date
ITMI980479A1 ITMI980479A1 (it) 1999-09-10
IT1298616B1 true IT1298616B1 (it) 2000-01-12

Family

ID=11379246

Family Applications (1)

Application Number Title Priority Date Filing Date
IT98MI000479A IT1298616B1 (it) 1998-03-10 1998-03-10 Complesso metallocenico pontato per la (co) polimerizzazione delle olefine

Country Status (11)

Country Link
US (2) US6211110B1 (enExample)
EP (1) EP0955304B1 (enExample)
JP (1) JP4372258B2 (enExample)
CN (1) CN1198835C (enExample)
AT (1) ATE248848T1 (enExample)
CA (1) CA2262868C (enExample)
DE (1) DE69910886T2 (enExample)
DK (1) DK0955304T3 (enExample)
ES (1) ES2207045T3 (enExample)
IT (1) IT1298616B1 (enExample)
PT (1) PT955304E (enExample)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1293677A (zh) * 1998-11-20 2001-05-02 蒙特尔技术有限公司 桥连金属茂的制备和在催化体系中的应用
ITMI20011017A1 (it) * 2001-05-17 2002-11-17 Enichem Spa Procedimento per la preparazione di copolimeri e terpolimeri elastomerici ep (d) m
US7060765B2 (en) 2001-07-19 2006-06-13 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
DE60234353D1 (de) 2001-09-14 2009-12-24 Sumitomo Chemical Co Übergangsmetallkomplex, katalysator für die polymerisierung von olefinen und verfahren zur herstellung von olefinpolymeren unter anwendung desselben
JP3928394B2 (ja) * 2001-09-14 2007-06-13 住友化学株式会社 置換シクロペンタジエンおよびその製造方法
ITMI20012516A1 (it) 2001-11-30 2003-05-30 Enichem Spa Procedimento per la preparazione di copolimeri dell'etilene aventi una larga distribuzione dei pesi molecolari
US7223822B2 (en) * 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7550528B2 (en) * 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
BR0315341B1 (pt) 2002-10-15 2014-02-18 Adesivos compreendendo poliolefina.
US20040102311A1 (en) * 2002-11-21 2004-05-27 Abbas Razavi Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
JP5154748B2 (ja) * 2005-10-21 2013-02-27 三井化学株式会社 連続有機過酸化物架橋ゴム成形体への加工法およびその架橋ゴム成形体
JP2008231017A (ja) 2007-03-20 2008-10-02 Sumitomo Chemical Co Ltd 遷移金属錯体、その製造方法及び用途
KR100994252B1 (ko) * 2007-05-09 2010-11-12 주식회사 엘지화학 에틸렌 알파-올레핀 공중합체
CN102149384B (zh) * 2008-08-14 2014-08-20 南京奥昭生物科技有限公司 作为ep4受体拮抗剂的杂环酰胺衍生物
WO2013091837A1 (en) * 2011-12-19 2013-06-27 Saudi Basic Industries Corporation (Sabic) Process for the preparation of metallocene complexes
CN107721797A (zh) * 2011-12-19 2018-02-23 沙特基础工业公司 用于制备茂金属络合物的方法
JP6589233B2 (ja) * 2015-03-17 2019-10-16 株式会社カネカ トリアリールメタノールの製造方法
US12077506B2 (en) 2018-10-17 2024-09-03 Nikang Therapeutics, Inc. Indane derivatives as hypoxia inducible factor-2(α) inhibitors
CN109575300A (zh) * 2018-11-15 2019-04-05 三明学院 一种导电金属有机框架材料的合成方法
CN111793159B (zh) * 2020-01-16 2021-04-06 深圳市沃尔电力技术有限公司 高压绝缘直流电缆附件材料生产方法及其加工设备
EP4110834B1 (en) 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins
CN111620914B (zh) * 2020-07-09 2021-03-19 吉林大学 含中性苄杂原子配位基侧臂单茂四价过渡金属配合物及其用途

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1275777B1 (it) * 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
US5635437A (en) * 1995-07-28 1997-06-03 Exxon Chemicals Patents, Inc. Method for preparing metallocene catalyst systems
IT1282666B1 (it) 1996-02-22 1998-03-31 Enichem Spa Catalizzatore metallocenico sostituito per la (co) polimerizzazione delle olefine
IT1283630B1 (it) 1996-05-09 1998-04-23 Enichem Spa Procedimento per la preparazione di copolimeri elastomerici ep(d)m
IT1290856B1 (it) 1996-12-19 1998-12-14 Enichem Spa Metalloceni, loro preparazione ed uso nella polimerizzazione di alfa-olefine
US6087515A (en) * 1998-10-07 2000-07-11 Solvay Polyolefins Europe-Belgium (Societe Anonyme) Metallocenes and process for the preparation of metallocenes

Also Published As

Publication number Publication date
JP4372258B2 (ja) 2009-11-25
CN1198835C (zh) 2005-04-27
ITMI980479A1 (it) 1999-09-10
CA2262868C (en) 2009-08-18
US20010031885A1 (en) 2001-10-18
DE69910886D1 (de) 2003-10-09
US6211110B1 (en) 2001-04-03
EP0955304A2 (en) 1999-11-10
DK0955304T3 (da) 2004-01-05
US6417418B2 (en) 2002-07-09
DE69910886T2 (de) 2004-07-15
EP0955304B1 (en) 2003-09-03
CA2262868A1 (en) 1999-09-10
EP0955304A3 (en) 2000-06-21
JP2000038409A (ja) 2000-02-08
ES2207045T3 (es) 2004-05-16
PT955304E (pt) 2004-01-30
ATE248848T1 (de) 2003-09-15
CN1239098A (zh) 1999-12-22

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