IT1273512B - Composizione acida cristallina mesoporosa di un difosfonato-fosfito di un metallo tetravalente utile come catalizzatore - Google Patents

Composizione acida cristallina mesoporosa di un difosfonato-fosfito di un metallo tetravalente utile come catalizzatore

Info

Publication number
IT1273512B
IT1273512B ITMI950710A ITMI950710A IT1273512B IT 1273512 B IT1273512 B IT 1273512B IT MI950710 A ITMI950710 A IT MI950710A IT MI950710 A ITMI950710 A IT MI950710A IT 1273512 B IT1273512 B IT 1273512B
Authority
IT
Italy
Prior art keywords
tetravalent metal
diphosphonate
phosphite
mesoporous crystalline
catalyst
Prior art date
Application number
ITMI950710A
Other languages
English (en)
Inventor
Giulio Alberti
Riccardo Vivani
Vitali Chiara Antonini
Piergiorgio Zappelli
Original Assignee
Eniricerche Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche Spa filed Critical Eniricerche Spa
Publication of ITMI950710A0 publication Critical patent/ITMI950710A0/it
Priority to ITMI950710A priority Critical patent/IT1273512B/it
Priority to EP96104486A priority patent/EP0736539B1/en
Priority to DK96104486T priority patent/DK0736539T3/da
Priority to AT96104486T priority patent/ATE198204T1/de
Priority to DE69611260T priority patent/DE69611260T2/de
Priority to SI9630266T priority patent/SI0736539T1/xx
Priority to ES96104486T priority patent/ES2152446T3/es
Priority to JP8085504A priority patent/JPH0920507A/ja
Publication of ITMI950710A1 publication Critical patent/ITMI950710A1/it
Application granted granted Critical
Publication of IT1273512B publication Critical patent/IT1273512B/it
Priority to US08/942,484 priority patent/US5892080A/en
Priority to GR20010400001T priority patent/GR3035182T3/el

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3839—Polyphosphonic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/42—Tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/30—Non-coordinating groups comprising sulfur
    • B01J2540/32—Sulfonic acid groups or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00—Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/50—Non-coordinating groups comprising phosphorus
    • B01J2540/52—Phosphorus acid or phosphorus acid ester groups
    • B01J2540/525—Phosphorus acid or phosphorus acid ester groups being phosphorous acid (-ester) groups ((RO)P(OR')2) or the isomeric phosphonic acid (-ester) groups (R(R'O)2P=O), i.e. R= C, R'= C, H
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/069—Hybrid organic-inorganic polymers, e.g. silica derivatized with organic groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
ITMI950710A 1995-04-07 1995-04-07 Composizione acida cristallina mesoporosa di un difosfonato-fosfito di un metallo tetravalente utile come catalizzatore IT1273512B (it)

Priority Applications (10)

Application Number Priority Date Filing Date Title
ITMI950710A IT1273512B (it) 1995-04-07 1995-04-07 Composizione acida cristallina mesoporosa di un difosfonato-fosfito di un metallo tetravalente utile come catalizzatore
DE69611260T DE69611260T2 (de) 1995-04-07 1996-03-21 Mesoporöse-Kristalline-Säurezusammensetzung eines Diphosphonate-Phosphites von einem tetravalenten Metall anwendbar als Katalysator
DK96104486T DK0736539T3 (da) 1995-04-07 1996-03-21 Mesoporøs, krystallinsk syre-sammensætning af et diphosphonatphosphit af et tetravalent metal, som kan anvendes som en kata
AT96104486T ATE198204T1 (de) 1995-04-07 1996-03-21 Mesoporöse-kristalline-säurezusammensetzung eines diphosphonate-phosphites von einem tetravalenten metall anwendbar als katalysator
EP96104486A EP0736539B1 (en) 1995-04-07 1996-03-21 Mesoporous crystalline acid composition of a diphosphonate-phosphite of a tetravalent metal which can be used as a catalyst
SI9630266T SI0736539T1 (en) 1995-04-07 1996-03-21 Mesoporous crystalline acid composition of a diphosphonate-phosphite of a tetravalent metal which can be used as a catalyst
ES96104486T ES2152446T3 (es) 1995-04-07 1996-03-21 Composicion acida cristalina mesoporosa de un difosfonato-fosfito de un metal tetravalente, que se puede utilizar como catalizador.
JP8085504A JPH0920507A (ja) 1995-04-07 1996-04-08 中間細孔を有し、触媒として使用可能な、４価金属のジホスホン酸塩−亜リン酸塩の結晶性酸組成物
US08/942,484 US5892080A (en) 1995-04-07 1997-10-02 Mesoporous crystalline acid composition of a diphosphonate-phosphite of a tetravalent metal which can be used as a catalyst
GR20010400001T GR3035182T3 (en) 1995-04-07 2001-01-02 Mesoporous crystalline acid composition of a diphosphonate-phosphite of a tetravalent metal which can be used as a catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ITMI950710A IT1273512B (it) 1995-04-07 1995-04-07 Composizione acida cristallina mesoporosa di un difosfonato-fosfito di un metallo tetravalente utile come catalizzatore

Publications (3)

Publication Number Publication Date
ITMI950710A0 ITMI950710A0 (it) 1995-04-07
ITMI950710A1 ITMI950710A1 (it) 1996-10-07
IT1273512B true IT1273512B (it) 1997-07-08

Family

ID=11371248

Family Applications (1)

Application Number Title Priority Date Filing Date
ITMI950710A IT1273512B (it) 1995-04-07 1995-04-07 Composizione acida cristallina mesoporosa di un difosfonato-fosfito di un metallo tetravalente utile come catalizzatore

Country Status (10)

Country Link
US (1) US5892080A (it)
EP (1) EP0736539B1 (it)
JP (1) JPH0920507A (it)
AT (1) ATE198204T1 (it)
DE (1) DE69611260T2 (it)
DK (1) DK0736539T3 (it)
ES (1) ES2152446T3 (it)
GR (1) GR3035182T3 (it)
IT (1) IT1273512B (it)
SI (1) SI0736539T1 (it)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1289904B1 (it) * 1997-01-16 1998-10-19 Eniricerche Spa Composizione cristallina mesoporosa ad alta area superficiale di un metallo tetravalente utile come catalizzatore
ITPG20020015A1 (it) * 2002-03-22 2003-09-22 Giulio Alberti Un metodo innovativo per la preparazione di membrane nanopolimeriche a conduzione protonica per usi in celle a combustibile o in reattori ca
ITPG20030005A1 (it) * 2003-02-19 2004-08-20 Giulio Alberti Preparazione di nuovi fosfati acidi di metalli tetravalenti
US7589041B2 (en) * 2004-04-23 2009-09-15 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
ES2319007B1 (es) * 2006-12-07 2010-02-16 Rive Technology, Inc. Metodos para fabricar materiales zeoliticos mesoestructurados.
US7973109B2 (en) 2007-03-29 2011-07-05 Kabushiki Kaisha Toyota Chuo Kenkyusho Crosslinked type layered metal phosphonate compound, production process therefor, non-crosslinked type layered metal phosphonate compound, production process therefor, as well as stock solution
US8206498B2 (en) * 2007-10-25 2012-06-26 Rive Technology, Inc. Methods of recovery of pore-forming agents for mesostructured materials
US8524625B2 (en) * 2009-01-19 2013-09-03 Rive Technology, Inc. Compositions and methods for improving the hydrothermal stability of mesostructured zeolites by rare earth ion exchange
CN102333728A (zh) 2009-01-19 2012-01-25 里福技术股份有限公司 在低Si/Al沸石中引入介孔
US8685875B2 (en) 2009-10-20 2014-04-01 Rive Technology, Inc. Methods for enhancing the mesoporosity of zeolite-containing materials
US20110171121A1 (en) * 2010-01-08 2011-07-14 Rive Technology, Inc. Compositions and methods for making stabilized mesoporous materials
AU2012240093B2 (en) 2011-04-08 2015-06-11 W. R. Grace & Co.-Conn. Mesoporous framework-modified zeolites
CN102838098A (zh) * 2011-06-24 2012-12-26 中国科学技术大学苏州研究院 一种稀土金属次磷酸盐及其制备方法与应用
US9376324B2 (en) 2012-01-13 2016-06-28 Rive Technology, Inc. Introduction of mesoporosity into zeolite materials with sequential acid, surfactant, and base treatment
CN103930369A (zh) 2012-01-13 2014-07-16 瑞弗科技有限公司 低硅沸石的中孔隙率的引入
US8765660B1 (en) 2013-03-08 2014-07-01 Rive Technology, Inc. Separation of surfactants from polar solids
US9662640B2 (en) 2013-12-27 2017-05-30 Rive Technology, Inc. Introducing mesoporosity into zeolite materials with a modified acid pre-treatment step
CA2957307C (en) 2014-12-11 2019-04-16 Rive Technology, Inc. Preparation of mesoporous zeolites with reduced processing
US10626019B2 (en) 2014-12-30 2020-04-21 W. R. Grace & Co.-Conn. Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1243781B (it) * 1990-08-03 1994-06-28 Eniricerche Spa Composizione solida cristallina mesoporosa di difosfonato-fosfito di un metallo tetravalente, con una stretta distribuzione di mesopori
IT1244485B (it) * 1990-12-21 1994-07-15 Eniricerche Spa Composizione solida cristallina microporosa di difosfonato-fosfito di un metallo tetravalente con una stretta distribuzione di micropori

Also Published As

Publication number Publication date
EP0736539A3 (en) 1997-04-02
ATE198204T1 (de) 2001-01-15
DK0736539T3 (da) 2001-03-19
DE69611260T2 (de) 2001-05-03
SI0736539T1 (en) 2001-04-30
EP0736539A2 (en) 1996-10-09
DE69611260D1 (de) 2001-01-25
EP0736539B1 (en) 2000-12-20
ITMI950710A0 (it) 1995-04-07
JPH0920507A (ja) 1997-01-21
GR3035182T3 (en) 2001-04-30
US5892080A (en) 1999-04-06
ES2152446T3 (es) 2001-02-01
ITMI950710A1 (it) 1996-10-07

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