IT1289904B1 - Composizione cristallina mesoporosa ad alta area superficiale di un metallo tetravalente utile come catalizzatore - Google Patents

Composizione cristallina mesoporosa ad alta area superficiale di un metallo tetravalente utile come catalizzatore

Info

Publication number
IT1289904B1
IT1289904B1 IT97MI000074A ITMI970074A IT1289904B1 IT 1289904 B1 IT1289904 B1 IT 1289904B1 IT 97MI000074 A IT97MI000074 A IT 97MI000074A IT MI970074 A ITMI970074 A IT MI970074A IT 1289904 B1 IT1289904 B1 IT 1289904B1
Authority
IT
Italy
Prior art keywords
tetravalent metal
surface area
high surface
catalyst
crystalline composition
Prior art date
Application number
IT97MI000074A
Other languages
English (en)
Inventor
Piergiorgio Zappella
Giulio Alberti
Mario Casciola
Fabio Marmottini
Riccardo Vivani
Original Assignee
Eniricerche Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eniricerche Spa filed Critical Eniricerche Spa
Priority to IT97MI000074A priority Critical patent/IT1289904B1/it
Priority to DE69704258T priority patent/DE69704258T2/de
Priority to AT97122457T priority patent/ATE199661T1/de
Priority to EP97122457A priority patent/EP0855217B1/en
Priority to US08/999,263 priority patent/US5993768A/en
Publication of ITMI970074A1 publication Critical patent/ITMI970074A1/it
Application granted granted Critical
Publication of IT1289904B1 publication Critical patent/IT1289904B1/it

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3839—Polyphosphonic acids
    • C07F9/3843—Polyphosphonic acids containing no further substituents than -PO3H2 groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/38—Condensed phosphates
    • C01B25/42—Pyrophosphates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
IT97MI000074A 1997-01-16 1997-01-16 Composizione cristallina mesoporosa ad alta area superficiale di un metallo tetravalente utile come catalizzatore IT1289904B1 (it)

Priority Applications (5)

Application Number Priority Date Filing Date Title
IT97MI000074A IT1289904B1 (it) 1997-01-16 1997-01-16 Composizione cristallina mesoporosa ad alta area superficiale di un metallo tetravalente utile come catalizzatore
DE69704258T DE69704258T2 (de) 1997-01-16 1997-12-19 Mesoporöse kristalline Zusammensetzung mit hoher spezifischer Oberfläche eines tetravalenten Metalles verwendbar als Katalysator
AT97122457T ATE199661T1 (de) 1997-01-16 1997-12-19 Mesoporöse kristalline zusammensetzung mit hoher spezifischer oberfläche eines tetravalenten metalles verwendbar als katalysator
EP97122457A EP0855217B1 (en) 1997-01-16 1997-12-19 Mesoporous crystalline composition with a high surface area of a tetravalent metal which can be used as catalyst
US08/999,263 US5993768A (en) 1997-01-16 1997-12-29 Mesoporous crystalline composition with a high surface area of a tetravalent metal which can be used as catalyst

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT97MI000074A IT1289904B1 (it) 1997-01-16 1997-01-16 Composizione cristallina mesoporosa ad alta area superficiale di un metallo tetravalente utile come catalizzatore

Publications (2)

Publication Number Publication Date
ITMI970074A1 ITMI970074A1 (it) 1998-07-16
IT1289904B1 true IT1289904B1 (it) 1998-10-19

Family

ID=11375634

Family Applications (1)

Application Number Title Priority Date Filing Date
IT97MI000074A IT1289904B1 (it) 1997-01-16 1997-01-16 Composizione cristallina mesoporosa ad alta area superficiale di un metallo tetravalente utile come catalizzatore

Country Status (5)

Country Link
US (1) US5993768A (it)
EP (1) EP0855217B1 (it)
AT (1) ATE199661T1 (it)
DE (1) DE69704258T2 (it)
IT (1) IT1289904B1 (it)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITPG20020013A1 (it) * 2002-03-13 2003-09-15 Fuma Tech Membrane a conduzione protonica contenenti fosfato di zirconio o fosfati solfoarilenfosfonati di zirconio dispersi in una matrice polimerica
US7589041B2 (en) 2004-04-23 2009-09-15 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
ES2319007B1 (es) * 2006-12-07 2010-02-16 Rive Technology, Inc. Metodos para fabricar materiales zeoliticos mesoestructurados.
US8206498B2 (en) * 2007-10-25 2012-06-26 Rive Technology, Inc. Methods of recovery of pore-forming agents for mesostructured materials
US8524625B2 (en) * 2009-01-19 2013-09-03 Rive Technology, Inc. Compositions and methods for improving the hydrothermal stability of mesostructured zeolites by rare earth ion exchange
CN102333728A (zh) 2009-01-19 2012-01-25 里福技术股份有限公司 在低Si/Al沸石中引入介孔
US8685875B2 (en) * 2009-10-20 2014-04-01 Rive Technology, Inc. Methods for enhancing the mesoporosity of zeolite-containing materials
US20110171121A1 (en) * 2010-01-08 2011-07-14 Rive Technology, Inc. Compositions and methods for making stabilized mesoporous materials
AU2012240093B2 (en) 2011-04-08 2015-06-11 W. R. Grace & Co.-Conn. Mesoporous framework-modified zeolites
US9376324B2 (en) 2012-01-13 2016-06-28 Rive Technology, Inc. Introduction of mesoporosity into zeolite materials with sequential acid, surfactant, and base treatment
CN103930369A (zh) 2012-01-13 2014-07-16 瑞弗科技有限公司 低硅沸石的中孔隙率的引入
US8765660B1 (en) 2013-03-08 2014-07-01 Rive Technology, Inc. Separation of surfactants from polar solids
US9662640B2 (en) 2013-12-27 2017-05-30 Rive Technology, Inc. Introducing mesoporosity into zeolite materials with a modified acid pre-treatment step
CN107001056B (zh) 2014-12-11 2019-04-02 瑞弗科技有限公司 以减少的处理制备介孔沸石
US10626019B2 (en) 2014-12-30 2020-04-21 W. R. Grace & Co.-Conn. Methods for preparing zeolites with surfactant-templated mesoporosity and tunable aluminum content

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4180551A (en) * 1971-04-08 1979-12-25 Texas A&M University System Modified zirconium phosphates
IT1154308B (it) * 1982-05-17 1987-01-21 Consiglio Nazionale Ricerche Pellicole inorganiche a scambio ionico costituite da sali acidi insolubili di metalli tetravalenti con struttura a strati e/o loro derivati e relativo procedimento di preparazione
IT1200018B (it) * 1983-08-01 1989-01-05 Anic Spa Scambiatori cationici inorganici e procedimento per la loro preparazione
US4721738A (en) * 1985-10-07 1988-01-26 Occidental Research Corporation Polymeric compositions including microwave energy sensitizing additives
IT1243781B (it) * 1990-08-03 1994-06-28 Eniricerche Spa Composizione solida cristallina mesoporosa di difosfonato-fosfito di un metallo tetravalente, con una stretta distribuzione di mesopori
IT1244485B (it) * 1990-12-21 1994-07-15 Eniricerche Spa Composizione solida cristallina microporosa di difosfonato-fosfito di un metallo tetravalente con una stretta distribuzione di micropori
GB9107655D0 (en) * 1991-04-11 1991-05-29 Interox Chemicals Ltd Selective hydroxylation
IT1273512B (it) * 1995-04-07 1997-07-08 Eniricerche Spa Composizione acida cristallina mesoporosa di un difosfonato-fosfito di un metallo tetravalente utile come catalizzatore

Also Published As

Publication number Publication date
EP0855217A1 (en) 1998-07-29
DE69704258T2 (de) 2001-07-05
ATE199661T1 (de) 2001-03-15
EP0855217B1 (en) 2001-03-14
US5993768A (en) 1999-11-30
DE69704258D1 (de) 2001-04-19
ITMI970074A1 (it) 1998-07-16

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