IT1127301B - Recovering molybdenum in prepn. of molybdenum-iron catalyst - Google Patents
Recovering molybdenum in prepn. of molybdenum-iron catalystInfo
- Publication number
- IT1127301B IT1127301B IT28224/79A IT2822479A IT1127301B IT 1127301 B IT1127301 B IT 1127301B IT 28224/79 A IT28224/79 A IT 28224/79A IT 2822479 A IT2822479 A IT 2822479A IT 1127301 B IT1127301 B IT 1127301B
- Authority
- IT
- Italy
- Prior art keywords
- molybdenum
- water
- ppte
- wash
- prepn
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title 1
- 108010038629 Molybdoferredoxin Proteins 0.000 title 1
- HBELESVMOSDEOV-UHFFFAOYSA-N [Fe].[Mo] Chemical compound [Fe].[Mo] HBELESVMOSDEOV-UHFFFAOYSA-N 0.000 title 1
- 229910052750 molybdenum Inorganic materials 0.000 title 1
- 239000011733 molybdenum Substances 0.000 title 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 239000003513 alkali Substances 0.000 abstract 2
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000012452 mother liquor Substances 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 1
- 239000008367 deionised water Substances 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 239000012610 weak anion exchange resin Substances 0.000 abstract 1
Landscapes
- Catalysts (AREA)
Abstract
In the prepn. of a catalyst contg. oxides of Mo and of Fe, for oxidn. of methanol to HCHO, a ppte. is obtd. from an aq. medium contg. a sol. Mo cpd. and a sol. ferric salt, the ppte. is sepd. from the mother liquor, the ppte. is washed with de-ionised water, and is processed to an active catalyst, the mother liquor and the wash water are contacted with a weak anion-exchange resin which has been converted to the salt form with an acid, and the Mo ions adhering to the resin are recovered as an aq. alkali molybdate soln. by treating the resin with an aq. soln. of an alkali hydroxide. The Mo is recovered from the wash-water, contg. up to 1000 mg of Mo/litre. The ammonium ion content of the wash-water is lowered to below 0.05 mg/kg. The alkali molybdate can be converted to a suitable form and recycled.
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT28224/79A IT1127301B (en) | 1979-12-19 | 1979-12-19 | Recovering molybdenum in prepn. of molybdenum-iron catalyst |
| GB8039750A GB2069859B (en) | 1979-12-19 | 1980-12-11 | Process for preparing catalysts based on polybdenum and iron oxide |
| NLAANVRAGE8006808,A NL180280C (en) | 1979-12-19 | 1980-12-16 | PROCESS FOR PREPARING A CATALYST BASED ON MOLYBDENE AND IRON OXIDE FOR THE OXIDATION OF METHANOL TO FORMALDEHYDE. |
| DE19803047591 DE3047591A1 (en) | 1979-12-19 | 1980-12-17 | METHOD FOR PRODUCING CATALYSTS BASED ON MOLYBDA AND IRON OXIDES |
| BR8008328A BR8008328A (en) | 1979-12-19 | 1980-12-18 | PROCESS TO PREPARE A CATALYST, THE MOLYBDENUM OXIDES AND IRON BASE, AND ACTIVE IN THE METHANOL OXIDATION TO FORMALDEIDE |
| DK539280A DK539280A (en) | 1979-12-19 | 1980-12-18 | PROCEDURE FOR THE PREPARATION OF A MALYBDEN AND IRON OXIDES CATALYST |
| ES497890A ES8200635A1 (en) | 1979-12-19 | 1980-12-18 | Process for preparing catalysts based on molybdenum and iron oxides |
| AT0619180A AT380807B (en) | 1979-12-19 | 1980-12-18 | METHOD FOR INCREASING THE MOLYBDA EXHAUST IN THE METHOD FOR PRODUCING CATALYSTS BASED ON MOLYBDA AND IRON OXIDES |
| FR808026956A FR2471808A1 (en) | 1979-12-19 | 1980-12-18 | PROCESS FOR THE PREPARATION OF A CATALYST BASED ON MOLYBDENE OXIDES AND IRON |
| US06/218,224 US4331567A (en) | 1979-12-19 | 1980-12-19 | Process for preparing catalysts based on molybdenum and iron oxides |
| IN1407/CAL/80A IN153611B (en) | 1979-12-19 | 1980-12-19 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT28224/79A IT1127301B (en) | 1979-12-19 | 1979-12-19 | Recovering molybdenum in prepn. of molybdenum-iron catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| IT7928224A0 IT7928224A0 (en) | 1979-12-19 |
| IT1127301B true IT1127301B (en) | 1986-05-21 |
Family
ID=11223178
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT28224/79A IT1127301B (en) | 1979-12-19 | 1979-12-19 | Recovering molybdenum in prepn. of molybdenum-iron catalyst |
Country Status (1)
| Country | Link |
|---|---|
| IT (1) | IT1127301B (en) |
-
1979
- 1979-12-19 IT IT28224/79A patent/IT1127301B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| IT7928224A0 (en) | 1979-12-19 |
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