IL55733A - Method for the asymmetric hydrogenation of prochiral olefins by complexes of transition metals,supported on clayey minerals - Google Patents

Method for the asymmetric hydrogenation of prochiral olefins by complexes of transition metals,supported on clayey minerals

Info

Publication number
IL55733A
IL55733A IL55733A IL5573378A IL55733A IL 55733 A IL55733 A IL 55733A IL 55733 A IL55733 A IL 55733A IL 5573378 A IL5573378 A IL 5573378A IL 55733 A IL55733 A IL 55733A
Authority
IL
Israel
Prior art keywords
complexes
supported
transition metals
asymmetric hydrogenation
prochiral olefins
Prior art date
Application number
IL55733A
Other languages
English (en)
Other versions
IL55733A0 (en
Inventor
Marcello Mazzei
Mario Riocci
Walter Marconi
Original Assignee
Snam Progetti
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Snam Progetti filed Critical Snam Progetti
Publication of IL55733A0 publication Critical patent/IL55733A0/xx
Publication of IL55733A publication Critical patent/IL55733A/xx

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/1855—Triamide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/645—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
IL55733A 1977-10-17 1978-10-13 Method for the asymmetric hydrogenation of prochiral olefins by complexes of transition metals,supported on clayey minerals IL55733A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT28666/77A IT1087963B (it) 1977-10-17 1977-10-17 Idrogenazione asimmetrica di olefine prochirali mediante complessi di metalli di transazione immobilizzati in minerali argillosi.

Publications (2)

Publication Number Publication Date
IL55733A0 IL55733A0 (en) 1978-12-17
IL55733A true IL55733A (en) 1981-11-30

Family

ID=11223981

Family Applications (1)

Application Number Title Priority Date Filing Date
IL55733A IL55733A (en) 1977-10-17 1978-10-13 Method for the asymmetric hydrogenation of prochiral olefins by complexes of transition metals,supported on clayey minerals

Country Status (20)

Country Link
JP (1) JPS5466615A (cs)
AU (1) AU520574B2 (cs)
BE (1) BE871320A (cs)
CA (1) CA1148564A (cs)
CH (1) CH636589A5 (cs)
CS (1) CS208483B2 (cs)
DD (1) DD139251A5 (cs)
DE (1) DE2845216C2 (cs)
DK (1) DK461478A (cs)
FR (1) FR2405911A1 (cs)
GB (1) GB2006770B (cs)
HU (1) HU181953B (cs)
IL (1) IL55733A (cs)
IT (1) IT1087963B (cs)
LU (1) LU80370A1 (cs)
NL (1) NL7810236A (cs)
NO (1) NO148778C (cs)
SE (1) SE435923B (cs)
YU (1) YU237578A (cs)
ZA (1) ZA785486B (cs)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HU190864B (en) * 1983-12-08 1986-11-28 Alkaloida Vegyeszeti Gyar Process for production of phenil-alanin derivatives
GB8519008D0 (en) * 1985-07-27 1985-09-04 British Petroleum Co Plc Chemical process

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4008281A (en) * 1973-12-03 1977-02-15 Monsanto Company Asymmetric catalysis
CA1109074A (en) * 1976-04-26 1981-09-15 Mario Fiorini Asymmetrical hydrogenation and related means for this purpose

Also Published As

Publication number Publication date
SE7810776L (sv) 1979-04-18
NO783492L (no) 1979-04-18
GB2006770A (en) 1979-05-10
DK461478A (da) 1979-04-18
YU237578A (en) 1983-01-21
DD139251A5 (de) 1979-12-19
ZA785486B (en) 1979-09-26
NO148778B (no) 1983-09-05
LU80370A1 (fr) 1979-03-19
NL7810236A (nl) 1979-04-19
DE2845216A1 (de) 1979-04-19
SE435923B (sv) 1984-10-29
AU520574B2 (en) 1982-02-11
AU4025178A (en) 1980-04-03
JPS5466615A (en) 1979-05-29
HU181953B (en) 1983-11-28
CS208483B2 (en) 1981-09-15
CH636589A5 (it) 1983-06-15
IL55733A0 (en) 1978-12-17
FR2405911A1 (fr) 1979-05-11
GB2006770B (en) 1982-03-17
FR2405911B1 (cs) 1981-03-20
BE871320A (fr) 1979-04-17
IT1087963B (it) 1985-06-04
NO148778C (no) 1983-12-14
DE2845216C2 (de) 1984-05-10
CA1148564A (en) 1983-06-21

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